The phase transformation of galena in H_(2)SO_(4)-Fe_(2)(SO_(4))_(3) system under oxygen pressure was investigated.Results indicated that the critical conditions for the phase transformation of galena into lead jarosi...The phase transformation of galena in H_(2)SO_(4)-Fe_(2)(SO_(4))_(3) system under oxygen pressure was investigated.Results indicated that the critical conditions for the phase transformation of galena into lead jarosite(Pb-J)were 130℃,30 g/L H_(2)SO_(4),15 g/L Fe^(3+),and an oxygen partial pressure of 0.4 MPa.Furthermore,increased Fe^(3+)concentration and oxygen partial pressure did not enhance jarosite formation.Conversely,lowering the temperature and increasing the H_(2)SO_(4) concentration facilitated PbSO_(4) formation and inhibited its further conversion to Pb-J.Additionally,the effects of potassium sulfate,sodium sulfate,and high concentrations of zinc sulfate on the phase transformation of galena were examined through leaching tests,XRD,SEM-EDS,and FT-IR analyses.All three sulfates inhibited the conversion of galena to Pb-J.Among these,potassium sulfate prevented Pb-J formation and converted it more thoroughly into potassium jarosite.However,high concentrations of zinc sulfate facilitated the crystallization of both PbSO_(4) and Pb-J,which altered the morphology of the product.Zinc ions coprecipitated with Pb-J,thereby integrating into the product.展开更多
As clean energy,the microwave is commonly used to pretreat various ores.In this work,the microwave dielectric properties of limonitic laterite ore were measured by resonant cavity perturbation technique and the effect...As clean energy,the microwave is commonly used to pretreat various ores.In this work,the microwave dielectric properties of limonitic laterite ore were measured by resonant cavity perturbation technique and the effects from microwave were systematically investigated.Results indicated that limonitic laterite had high microwave absorbance.After microwave pretreatment,the microstructure of the laterite became less aggregated and more porous and the main phase transformed from goethite to hematite that improved leaching in nitric acid(1.2 kg HNO3/kg ore);Ni,Co,Fe,and Mg extraction ratios were 95.2%,98.1%,1.8%and 15%,respectively,after leaching for 60 min at 200°C and 500 r/min.Furthermore,in the process of goethite to hematite by microwave pretreatment,the nickel-containing mineral is activated,which makes nickel be leached easily.The leaching process has high Ni extraction ratio compared to that without microwave(82%)and conventional pretreatment(90.4%).Therefore,microwave pretreatment of limonitic laterite before nitric acid pressure leaching is an effective way to improve the selectivity and extraction of the leach.展开更多
The application of microwave irradiation for pretreatment of copper anode slime with high nickel content prior to pressure sulfuric acid leaching has been proposed.The microwave-assisted pretreatment is a rapid and ef...The application of microwave irradiation for pretreatment of copper anode slime with high nickel content prior to pressure sulfuric acid leaching has been proposed.The microwave-assisted pretreatment is a rapid and efficient process.Through the technology of microwave assisted pretreatment-pressure leaching of copper anode slime,copper,tellurium,selenium and nickel are almost completely recovered.Under optimal conditions,the leaching efficiencies of copper,tellurium,selenium and nickel are 97.12%,95.97%,95.37% and 93.90%,respectively.The effect of microwave radiation on the temperature of copper anode slime and leaching solution is investigated.It is suggested that the enhancement on the recoveries of copper,tellurium and selenium can be attributed to the temperature gradient which is caused by shallow microwave penetration depth and super heating occurring at the solid–liquid interface.The kinetic study shows that the pressure leaching of copper anode slime,with and without microwave assisted pretreatment,are both controlled by chemical reactions on the surfaces of particles.It is found that the activation energy calculated for microwave-assisted pretreatment-pressure leaching(49.47 kJ/mol) is lower than that for pressure leaching which is without microwave assisted pretreatment(60.57 kJ/mol).展开更多
To recover zinc from electric arc furnace(EAF)dust,a process of primary normal pressure leaching and secondary alkaline pressure leaching is proposed.First,under the alkaline pressure leaching system,the experiment of...To recover zinc from electric arc furnace(EAF)dust,a process of primary normal pressure leaching and secondary alkaline pressure leaching is proposed.First,under the alkaline pressure leaching system,the experiment of pure zinc ferrite being reduced by iron powder was carried out.Under the optimal reduction conditions(i.e.,temperature of 260℃,NaOH concentration of 6 mol/L,liquid-to-solid ratio of 50 mL/g,and a 5-fold excess of iron powder),89%of zinc was extracted.The iron in the reduced residue exists as a magnetite phase.Subsequently,the normal pressure leaching experiment was carried out with EAF dust as raw material,and 66%zinc was leached.The main phase of zinc in normal leaching residue was determined to be zinc ferrite.Then,the normal leaching residue was reduced by iron powder under the alkaline pressure leaching system,and 66.5%of zinc was extracted.After the two-stage leaching process,the leaching rate of zinc in EAF dust can achieve 88.7%.The alkaline pressure leaching solution can be returned as the normal pressure leaching solution,and the magnetite in the alkaline pressure leaching residue can be recovered by magnetic separation.展开更多
The leaching results of bismuth sulfide concentrate containing molybdenum and tungsten in air-H2O2-NaOH system, pressure-O2-Na2CO3 system and pressure-O2-NaOH system were investigated. The results show that the extrac...The leaching results of bismuth sulfide concentrate containing molybdenum and tungsten in air-H2O2-NaOH system, pressure-O2-Na2CO3 system and pressure-O2-NaOH system were investigated. The results show that the extraction of molybdenum, tungsten and sulfur goes up with the increase of NaOH concentration, oxygen partial pressure and reaction time. The extraction of molybdenum and tungsten also rises up with temperature, but the leaching ratio of sulfur increases initially to a peak of 98% at 150℃ and then decreases with the increase of temperature. Under the optimal conditions, the extraction of molybdenum, tungsten and sulfur is more than 95.6%, 93.8% and 96.0%, respectively, and the main phases of residue are Bi2O3 and Fe2O3. Therefore, the method of pressure leaching in alkaline solution is provided as an effective separation of molybdenum, tungsten and sulfur from bismuth and a beneficial pretreatment for consequent process.展开更多
The treatment of the Gacun complex Cu concentrate with high contents of Pb,Zn,Ag,etc by oxygen pressure acid leaching was studied.It is unusual that tetrahedrite,whose treatment was rarely studied,is the primary coppe...The treatment of the Gacun complex Cu concentrate with high contents of Pb,Zn,Ag,etc by oxygen pressure acid leaching was studied.It is unusual that tetrahedrite,whose treatment was rarely studied,is the primary copper mineral of the concentrates.Most of silver also occurs in the mineral.The optimum operating parameters of oxygen pressure acid leaching were established by conditional tests.Pilot scale test was carried out under the parameters,and the leaching rates of copper and zinc are as high as 97.10% and 89.83% while lead and silver are transformed into sulfate and sulfide respectively and stay in leaching residue.The copper and zinc in lixivium were reclaimed by extraction-electrowinning and purification-electrowinning,respectively,and the lead and silver in the residue were reclaimed separately by chloride leaching and thiourea leaching.The extraction rate of copper achieves 96%,and the leaching rates of lead and silver reach 90% and 95%,respectively.展开更多
基金Projects(2023AG05008,202302AB080012)supported by the Yunnan Major Scientific and Technological Program,ChinaProject(202405AC350015)supported by the Science and Technology Talent Programme of Yunnan Province,China。
文摘The phase transformation of galena in H_(2)SO_(4)-Fe_(2)(SO_(4))_(3) system under oxygen pressure was investigated.Results indicated that the critical conditions for the phase transformation of galena into lead jarosite(Pb-J)were 130℃,30 g/L H_(2)SO_(4),15 g/L Fe^(3+),and an oxygen partial pressure of 0.4 MPa.Furthermore,increased Fe^(3+)concentration and oxygen partial pressure did not enhance jarosite formation.Conversely,lowering the temperature and increasing the H_(2)SO_(4) concentration facilitated PbSO_(4) formation and inhibited its further conversion to Pb-J.Additionally,the effects of potassium sulfate,sodium sulfate,and high concentrations of zinc sulfate on the phase transformation of galena were examined through leaching tests,XRD,SEM-EDS,and FT-IR analyses.All three sulfates inhibited the conversion of galena to Pb-J.Among these,potassium sulfate prevented Pb-J formation and converted it more thoroughly into potassium jarosite.However,high concentrations of zinc sulfate facilitated the crystallization of both PbSO_(4) and Pb-J,which altered the morphology of the product.Zinc ions coprecipitated with Pb-J,thereby integrating into the product.
基金Project(51974025)supported by the National Natural Science Foundation of ChinaProject(2018IA055)supported by the International Cooperation Project of Key Research and Development Plan of Yunan Province,ChinaProject(JKY2019-09)supported by State Key Laboratory of Nickel and Cobalt Resources Comprehensive Utilization,China。
文摘As clean energy,the microwave is commonly used to pretreat various ores.In this work,the microwave dielectric properties of limonitic laterite ore were measured by resonant cavity perturbation technique and the effects from microwave were systematically investigated.Results indicated that limonitic laterite had high microwave absorbance.After microwave pretreatment,the microstructure of the laterite became less aggregated and more porous and the main phase transformed from goethite to hematite that improved leaching in nitric acid(1.2 kg HNO3/kg ore);Ni,Co,Fe,and Mg extraction ratios were 95.2%,98.1%,1.8%and 15%,respectively,after leaching for 60 min at 200°C and 500 r/min.Furthermore,in the process of goethite to hematite by microwave pretreatment,the nickel-containing mineral is activated,which makes nickel be leached easily.The leaching process has high Ni extraction ratio compared to that without microwave(82%)and conventional pretreatment(90.4%).Therefore,microwave pretreatment of limonitic laterite before nitric acid pressure leaching is an effective way to improve the selectivity and extraction of the leach.
基金Project(2012BAE06B05)supported by the National Science and Technology Support Program of ChinaProject(N130602004)supported by the Fundamental Research Funds for the Central Universities of China
文摘The application of microwave irradiation for pretreatment of copper anode slime with high nickel content prior to pressure sulfuric acid leaching has been proposed.The microwave-assisted pretreatment is a rapid and efficient process.Through the technology of microwave assisted pretreatment-pressure leaching of copper anode slime,copper,tellurium,selenium and nickel are almost completely recovered.Under optimal conditions,the leaching efficiencies of copper,tellurium,selenium and nickel are 97.12%,95.97%,95.37% and 93.90%,respectively.The effect of microwave radiation on the temperature of copper anode slime and leaching solution is investigated.It is suggested that the enhancement on the recoveries of copper,tellurium and selenium can be attributed to the temperature gradient which is caused by shallow microwave penetration depth and super heating occurring at the solid–liquid interface.The kinetic study shows that the pressure leaching of copper anode slime,with and without microwave assisted pretreatment,are both controlled by chemical reactions on the surfaces of particles.It is found that the activation energy calculated for microwave-assisted pretreatment-pressure leaching(49.47 kJ/mol) is lower than that for pressure leaching which is without microwave assisted pretreatment(60.57 kJ/mol).
基金Project(51504292)supported by National Natural Science Foundation of ChinaProject(2018JJ3678)supported by the Natural Science Foundation of Hunan Province,China。
文摘To recover zinc from electric arc furnace(EAF)dust,a process of primary normal pressure leaching and secondary alkaline pressure leaching is proposed.First,under the alkaline pressure leaching system,the experiment of pure zinc ferrite being reduced by iron powder was carried out.Under the optimal reduction conditions(i.e.,temperature of 260℃,NaOH concentration of 6 mol/L,liquid-to-solid ratio of 50 mL/g,and a 5-fold excess of iron powder),89%of zinc was extracted.The iron in the reduced residue exists as a magnetite phase.Subsequently,the normal pressure leaching experiment was carried out with EAF dust as raw material,and 66%zinc was leached.The main phase of zinc in normal leaching residue was determined to be zinc ferrite.Then,the normal leaching residue was reduced by iron powder under the alkaline pressure leaching system,and 66.5%of zinc was extracted.After the two-stage leaching process,the leaching rate of zinc in EAF dust can achieve 88.7%.The alkaline pressure leaching solution can be returned as the normal pressure leaching solution,and the magnetite in the alkaline pressure leaching residue can be recovered by magnetic separation.
文摘The leaching results of bismuth sulfide concentrate containing molybdenum and tungsten in air-H2O2-NaOH system, pressure-O2-Na2CO3 system and pressure-O2-NaOH system were investigated. The results show that the extraction of molybdenum, tungsten and sulfur goes up with the increase of NaOH concentration, oxygen partial pressure and reaction time. The extraction of molybdenum and tungsten also rises up with temperature, but the leaching ratio of sulfur increases initially to a peak of 98% at 150℃ and then decreases with the increase of temperature. Under the optimal conditions, the extraction of molybdenum, tungsten and sulfur is more than 95.6%, 93.8% and 96.0%, respectively, and the main phases of residue are Bi2O3 and Fe2O3. Therefore, the method of pressure leaching in alkaline solution is provided as an effective separation of molybdenum, tungsten and sulfur from bismuth and a beneficial pretreatment for consequent process.
基金Project(2007BAB22B01) supported by the National Science and Technology Pillar Program during the 11th Five-year Plan Period of China
文摘The treatment of the Gacun complex Cu concentrate with high contents of Pb,Zn,Ag,etc by oxygen pressure acid leaching was studied.It is unusual that tetrahedrite,whose treatment was rarely studied,is the primary copper mineral of the concentrates.Most of silver also occurs in the mineral.The optimum operating parameters of oxygen pressure acid leaching were established by conditional tests.Pilot scale test was carried out under the parameters,and the leaching rates of copper and zinc are as high as 97.10% and 89.83% while lead and silver are transformed into sulfate and sulfide respectively and stay in leaching residue.The copper and zinc in lixivium were reclaimed by extraction-electrowinning and purification-electrowinning,respectively,and the lead and silver in the residue were reclaimed separately by chloride leaching and thiourea leaching.The extraction rate of copper achieves 96%,and the leaching rates of lead and silver reach 90% and 95%,respectively.
