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Quantitative investigation on micro-parameters of cemented paste backfill and its sensitivity analysis 被引量:12
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作者 LIU Lang ZHOU Peng +2 位作者 FENG Yan ZHANG Bo SONG Ki-il 《Journal of Central South University》 SCIE EI CAS CSCD 2020年第1期267-276,共10页
The mechanical properties of cemented paste backfill(CPB) depend heavily on its pore structural characteristics and micro-structural changes. In order to explore the variation mechanisms of macro-mechanical characteri... The mechanical properties of cemented paste backfill(CPB) depend heavily on its pore structural characteristics and micro-structural changes. In order to explore the variation mechanisms of macro-mechanical characteristics and micro-structure of CPB. CPB specimens with different mass concentrations prepared from the full tailings of Xianglushan Tungsten Ore were micro-tests. Moreover, acquired pore digital images were processed by using the pores(particles) and cracks analysis system(PCAS), and a sensitivity analysis was performed. The results show that as the mass concentration of CPB increases from 70% to 78%, the porosity, the average pore area and the number of pores drop overall, leading to a decline in the pores opening degree and enhancing the mechanical characteristics. As the mass concentration of CPB increases, the trend of fractal dimension, probability entropy and roundness is reduced, constant and increased, which can result in an enhancement of the uniformity, an unchanged directionality and more round pores. According to the definition of sensitivity, the sensitivities of various micro-parameters were calculated and can be ranked as porosity > average pore area > number of pores > roundness > fractal dimension > probability entropy. 展开更多
关键词 cemented paste backfill mass concentration sensitivity analysis micro-parameters
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Effects of temperatures and pH values on rheological properties of cemented paste backfill 被引量:9
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作者 ZHANG Qin-li LI Yi-teng +3 位作者 CHEN Qiu-song LIU Yi-kai FENG Yan WANG Dao-lin 《Journal of Central South University》 SCIE EI CAS CSCD 2021年第6期1707-1723,共17页
In this study,different influence mechanisms associated with temperatures and pH values were investigated through cemented paste backfill(CPB)systems.CPB samples were prepared with temperatures ranging from 10 to 50℃... In this study,different influence mechanisms associated with temperatures and pH values were investigated through cemented paste backfill(CPB)systems.CPB samples were prepared with temperatures ranging from 10 to 50℃ in 10℃ increments and pH values of 3,7,and 13.Then,the CPB mixture were subjected to rheological tests,thermogravimetric analysis(TG),derivative thermogravimetry analysis(DTG),Fourier-transform infrared spectroscopy(FT-IR),and scanning electron microscopy(SEM).Results demonstrated that the temperatures had significant effects on the rheological properties of CPB,whereas the effects of pH values were relatively unapparent.Higher temperatures(over 20℃)were prone to bring higher shear stress,yield stress,and apparent viscosity with the same pH value condition.However,an overly high temperature(50℃)cannot raise the apparent viscosity.Non-neutral conditions,for pH values of 3 and 13,could strengthen the shear stress and apparent viscosity at the same temperature.Two different yield stress curves could be discovered by uprising pH values,which also led to apparent viscosity of two various curves under the same temperatures(under 50℃).Microscopically,rheological properties of CPB were affected by temperatures and pH values which enhanced or reduced the cement hydration procedures,rates,products and space structures. 展开更多
关键词 cemented paste backfill(CPB) rheological properties TEMPERATURES pH values cement hydration microscopic analysis
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Influence of ultra-fine fly ash on hydration shrinkage of cement paste 被引量:15
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作者 高英力 周士琼 《Journal of Central South University of Technology》 EI 2005年第5期596-600,共5页
Hydration shrinkage generated by cement hydration is the cause of autogenous shrinkage of high strength concrete. It may result in the volume change and even cracking of mortar and concrete. According to the data anal... Hydration shrinkage generated by cement hydration is the cause of autogenous shrinkage of high strength concrete. It may result in the volume change and even cracking of mortar and concrete. According to the data analysis in a series of experimental studies, the influence of ultra-fine fly ash on the hydration shrinkage of composite cementitious materials was investigated. It is found that ultra-fine fly ash can reduce the hydration shrinkage of cement paste effectively, and the more the ultra-fine fly ash, the less the hydration shrinkage. Compared with cement paste without the ultra-fine fly ash, the shrinkage ratio of cement paste reduces from 23.4% to 39.7% when the ultra-fine fly ash replaces cement from 20% to 50%. Moreover, the microscopic mechanism of the ultra-fine fly ash restraining the hydration shrinkage was also studied by scanning electron microscopy, X-ray diffraction and hydrated equations. The results show that the hydration shrinkage can be restrained to a certain degree because the ultra-fine fly ash does not participate in the hydration at the early stage and the secondary hydration products are different at the later stage. 展开更多
关键词 ultra-fine fly ash cement paste hydration shrinkage MECHANISM
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Hydration phase and pore structure evolution of hardened cement paste at elevated temperature 被引量:5
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作者 XIANG Yu XIE You-jun +1 位作者 LONG Guang-cheng HE Fu-qiang 《Journal of Central South University》 SCIE EI CAS CSCD 2021年第6期1665-1678,共14页
To understand the effect of steam curing temperature on the hydrate and microstructure of hardened cement paste,several measuring methods including X-ray diffraction(XRD),atomic absorption spectroscopy(ASS),ion chroma... To understand the effect of steam curing temperature on the hydrate and microstructure of hardened cement paste,several measuring methods including X-ray diffraction(XRD),atomic absorption spectroscopy(ASS),ion chromatography,conductivity meter,alternating-current impedance spectroscopy and nuclear magnetic resonance(NMR)are employed to investigate the hydration characteristics,pore solution composition and conductivity,resistivity and pore structure during the steam curing process.Experimental results show that steam curing promotes the hydration process,greatly raises the resistivity,and decreases the porosity of specimen at early age.Compared with being treated at 45℃,higher temperature leads to a fast decomposition of ettringite at initial stage of the constant temperature treatment period,which improves the relative content and ionic activity of the conductive ions in pore solution.Furthermore,the number of pores larger than 200 nm increases significantly,which reduces the resistivity of the hardened cement paste.Cement paste treated at 45℃ has a more stable and denser microstructure with less damages. 展开更多
关键词 cement paste high-temperature curing pore structure AC impedance nuclear magnetic resonance
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Evaluation of time-dependent rheological properties of cemented paste backfill incorporating superplasticizer with special focus on thixotropy and static yield stress 被引量:4
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作者 WANG Xiao-lin WANG Hong-jiang +3 位作者 WU Ai-xiang JIANG Hai-qiang PENG Qing-song ZHANG Xi 《Journal of Central South University》 SCIE EI CAS CSCD 2022年第4期1239-1249,共11页
Superplasticizers are widely used to reduce the pipe flow resistance of cemented paste backfill(CPB), which is characterised by high concentration and high yield stress. This study aimed to assess the time-dependent r... Superplasticizers are widely used to reduce the pipe flow resistance of cemented paste backfill(CPB), which is characterised by high concentration and high yield stress. This study aimed to assess the time-dependent rheological properties of CPB containing superplasticizer, with special focus on static yield stress and thixotropy. The results indicate that with the increase of the superplasticizer dosage, the static yield stress, dynamic yield stress and thixotropy of CPB decreased significantly, while the plastic viscosity decreased slightly. The curing time has a significant effect on the static yield stress, dynamic yield stress and thixotropy of CPB containing superplasticizer, which increase by 46.6%-87.1%,15.2%-35.6% and 79.4%-138.2%, respectively, within 2 h. The static yield stress, dynamic yield stress and thixotropy of CPB without superplasticizer only increase by 4.9%, 6.3% and 16.1%, respectively, within 2 h. The curing time has a significant influence on the plastic viscosity of CPB regardless of superplasticizer addition, the plastic viscosity increases by 13.2%-19.7% within 2 h. Regardless of superplasticizer dosage, plotting of both static yield stress and dynamic yield stress versus thixotropy produces clearly linear curves. The findings of this study are conducive to the design of pipe transportation of CPB containing superplasticizer. 展开更多
关键词 cemented paste backfill SUPERPLASTICIZER curing time yield stress THIXOTROPY
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Experimental investigation on flow properties of cemented paste backfill through L-pipe and loop-pipe tests 被引量:4
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作者 LIU Hong-lei HOU Chen +2 位作者 LI Lei DU Jia-fa YAN Bao-xu 《Journal of Central South University》 SCIE EI CAS CSCD 2021年第9期2830-2842,共13页
With the gradual depletion of available ore at shallow depth,deep mines have been widely operated around the world and therefore need a longer distance to transport the backfill to the underground stope.In this case,t... With the gradual depletion of available ore at shallow depth,deep mines have been widely operated around the world and therefore need a longer distance to transport the backfill to the underground stope.In this case,the determination of pressure drop is more important in the pipeline transportation system design.As the pilot loop systems require a large amount of capital and manual investment,even its results are reliable,there is an urgent need to find an alternative simple and cost-saving method to determine the pressure drop.Hence,laboratory L-pipe and a pilot-loop tests were employed to study the flow properties of cemented paste backfill cured at various solid and binder content.The results indicate that the L-pipe test presented a similar trend to the loop test,but the L-pipe was characterized by higher pressure drop values for various solid and cement contents.As cement content increased beyond 0%,the paste in the L-pipe showed a slighter difference in pressure drop evolution compared to the paste in the loop-pipe.These results suggest that the simple L-pipe is a workable substitute for semi-industrial loop tests and can provide guidance for designing practical CPB pipeline systems in deep mines. 展开更多
关键词 pressure drop cemented paste backfill(CPB) L-pipe test pipe-loop test
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Characterization of microstructure evolution of cement paste by micro computed tomography 被引量:3
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作者 何永佳 Jason Mote David A. Lange 《Journal of Central South University》 SCIE EI CAS 2013年第4期1115-1121,共7页
Micro computed tomography (Micro-CT) was applied to obtain three-dimensional images of the microstructure of cement paste (water-to-cement mass ratio of 0.5) at different ages. By using the Amira software, component p... Micro computed tomography (Micro-CT) was applied to obtain three-dimensional images of the microstructure of cement paste (water-to-cement mass ratio of 0.5) at different ages. By using the Amira software, component phases of the cement paste such as pores, hydration products, and unhydrated clinker particles were segmented from each other based on their 3D image grey levels; their relative contents were also calculated with the software, and the data are 61.2%, 0% and 38.8% at the beginning of hydration and 11.8%, 78.5% and 9.7% at 28 d age, respectively. The hydration degree of cement paste at different ages was compared with the experimental data acquired by loss on ignition (LOI) tests. The results show that the calculated and measured data reasonably agree with each other, which indicates that micro-CT is a useful and reliable approach to characterize the micro structure evolution of hydrating cement paste. 展开更多
关键词 Micro computed tomography (Micro-CT) 3D image MICROSTRUCTURE cement paste
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Size effect on cubic and prismatic compressive strength of cement paste 被引量:1
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作者 苏捷 叶缙垚 +1 位作者 方志 赵明华 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第10期4090-4096,共7页
A series of compression tests were conducted on 150 groups of cement paste specimens with side lengths ranging from 40 mm to 200 mm. The specimens include cube specimens and prism specimens with height to width ratio ... A series of compression tests were conducted on 150 groups of cement paste specimens with side lengths ranging from 40 mm to 200 mm. The specimens include cube specimens and prism specimens with height to width ratio of 2. The experiment results show that size effect exists in the cubic compressive strength and prismatic compressive strength of the cement paste, and larger specimens resist less in terms of strength than smaller ones. The cubic compressive strength and the prismatic compressive strength of the specimens with side length of 200 mm are respectively about 91% and 89% of the compressive strength of the specimens with the side length of 40 mm. Water to binder ratio has a significant influence on the size effect of the compressive strengths of the cement paste. With a decrease in the water to binder ratio, the size effect is significantly enhanced. When the water to binder ratio is 0.2, the size effects of the cubic compressive strength and the prismatic compressive strength of the cement paste are 1.6 and 1.4 times stronger than those of a water to binder ratio of 0.6. Furthermore, a series of formulas are proposed to calculate the size effect of the cubic compressive strength and the prismatic compressive strength of cement paste, and the results of the size effect predicted by the formulas are in good agreement with the experiment results. 展开更多
关键词 size effect cement paste water to binder ratio cubic compressive strength prismatic compressive strength
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Influence of CaO-based expansive agent,superabsorbent polymers and curing temperature on pore structure evolution of early-age cement paste
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作者 ZHAO Hai-tao LI Xiao-long +5 位作者 XIE Dong-sheng DI Yun-fei HUANG Jie XU Wen WANG Peng-gang ZUO Jun-qing 《Journal of Central South University》 SCIE EI CAS CSCD 2022年第5期1663-1673,共11页
Cracks easily generate in concrete at early age owing to the shrinkage deformation.CaO-based expansion agent(CEA)and superabsorbent polymers(SAP)have been extensively used for the mitigation of concrete shrinkage.The ... Cracks easily generate in concrete at early age owing to the shrinkage deformation.CaO-based expansion agent(CEA)and superabsorbent polymers(SAP)have been extensively used for the mitigation of concrete shrinkage.The macroscopic properties of concrete are highly determined by the microstructure.In this study,the influence of CEA and SAP addition on the pore structure evolution of cement paste under different curing temperatures was evaluated via low-field nuclear magnetic resonance spectroscopy.Test results indicated that,in cement paste,a higher CEA content led to a higher porosity and a larger most probable pore diameter(MPPD).Meanwhile,SAP addition increased the porosity and MPPD of CEA cement paste at early age but decreased them after 7 d,and a higher SAP content always brought a higher porosity and MPPD.Furthermore,the addition of SAP led to a lower porosity and MPPD of CEA cement paste than that of plain cement paste after 14 d.Moreover,the porosity and MPPD of CEA cement paste decreased first and subsequently increased as the curing temperature raised. 展开更多
关键词 cement paste pore structure CaO-based expansion agent superabsorbent polymers curing temperature low-field nuclear magnetic
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Pore structure formation and hydration characteristics of cement paste with temperature rising inhibitor
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作者 ZHAO Hai-tao XIANG Yu +6 位作者 ZHANG Hao SHEN De-jian CHEN Xiao-dong HUANG Jie XU Wen LI Hua WANG Yu-jiang 《Journal of Central South University》 SCIE EI CAS CSCD 2022年第5期1674-1685,共12页
The early-age thermal cracking easily generates and severely impairs the durability of concrete.The temperature rising inhibitor(TRI)was utilized to regulate the temperature evolution by controlling the cement hydrati... The early-age thermal cracking easily generates and severely impairs the durability of concrete.The temperature rising inhibitor(TRI)was utilized to regulate the temperature evolution by controlling the cement hydration process.This paper aimed to investigate the pore structure formation and hydration characteristics of cement paste containing TRI by low-field nuclear magnetic resonance.The experiment showed that the T_(2) peak of cement paste shifted from 7.32 ms to 0.23 ms regardless of TRI addition.But the pattern of pore structure formation was changed with TRI addition,that is,the pore structure formation was delayed,and the pore successively shifted to left in two parts.In addition,TRI addition significantly prolonged the duration of gel pore formation and greatly decreased the increase rate of gel water,which implied that TRI introduction hindered the growth of C-S-H,and subsequently decreased the hydration rates and delayed the main hydration peak.Meanwhile,TRI dissolved and diffused rapidly at 40℃,delaying the hydration of cement paste seriously.Moreover,TRI brought about the C-S-H nucleation homogeneous and the ion concentration uniform,which might reduce the localized curvature occurring on the sheet of C-S-H,and then decreased the T_(2) intensity of capillary water and gel water. 展开更多
关键词 pore structure formation hydration characteristics temperature rising inhibitor low-field nuclear magnetic resonance cement paste
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Texture features analysis on micro-structure of paste backfill based on image analysis technology 被引量:8
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作者 YIN Sheng-hua SHAO Ya-jian +2 位作者 WU Ai-xiang WANG Yi-ming GAO Zhi-yong 《Journal of Central South University》 SCIE EI CAS CSCD 2018年第10期2360-2372,共13页
The strength of cement-based materials,such as mortar,concrete and cement paste backfill(CPB),depends on its microstructures(e.g.pore structure and arrangement of particles and skeleton).Numerous studies on the relati... The strength of cement-based materials,such as mortar,concrete and cement paste backfill(CPB),depends on its microstructures(e.g.pore structure and arrangement of particles and skeleton).Numerous studies on the relationship between strength and pore structure(e.g.,pore size and its distribution)were performed,but the micro-morphology characteristics have been rarely concerned.Texture describing the surface properties of the sample is a global feature,which is an effective way to quantify the micro-morphological properties.In statistical analysis,GLCM features and Tamura texture are the most representative methods for characterizing the texture features.The mechanical strength and section image of the backfill sample prepared from three different solid concentrations of paste were obtained by uniaxial compressive strength test and scanning electron microscope,respectively.The texture features of different SEM images were calculated based on image analysis technology,and then the correlation between these parameters and the strength was analyzed.It was proved that the method is effective in the quantitative analysis on the micro-morphology characteristics of CPB.There is a significant correlation between the texture features and the unconfined compressive strength,and the prediction of strength is feasible using texture parameters of the CPB microstructure. 展开更多
关键词 microstructure texture feature Tamura texture GLCM feature unconfined compressive strength quantitative analysis cement paste backfill
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不同脱氯工艺提钛尾渣对水泥浆体性能的影响
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作者 王淑萍 钟静雄 +3 位作者 徐银清 辛云涛 吕学伟 曾冠武 《湖南大学学报(自然科学版)》 北大核心 2025年第3期180-188,共9页
提钛尾渣是含钛高炉渣提钛后所排放的废渣,具有潜在水硬活性,但因含有氯离子,其资源化利用受到限制,需进一步脱氯处理.本文分析了不同脱氯工艺下提钛尾渣的掺量对水泥浆体的性能影响.结果表明,掺入提钛尾渣会降低水泥浆体的流动性;提钛... 提钛尾渣是含钛高炉渣提钛后所排放的废渣,具有潜在水硬活性,但因含有氯离子,其资源化利用受到限制,需进一步脱氯处理.本文分析了不同脱氯工艺下提钛尾渣的掺量对水泥浆体的性能影响.结果表明,掺入提钛尾渣会降低水泥浆体的流动性;提钛尾渣中的氯离子对水泥浆体有促凝作用,且随着掺量的增加,凝结时间缩短明显.在相同掺量下,几种不同脱氯工艺的提钛尾渣按对水泥浆体凝结时间的缩短程度从大到小排序为:未脱氯渣>水洗脱氯渣>煅烧脱氯渣.掺入20%以内提钛尾渣对水泥浆体强度影响较小,但当掺量进一步提高时,强度逐渐下降.提钛尾渣中的氯离子主要以Friedel盐形式存在于水泥浆体中;掺入提钛尾渣后水化产物的Si―O键伸缩振动峰向低波数方向偏移.提钛尾渣的推荐掺量范围为10%~20%. 展开更多
关键词 提钛尾渣 脱氯 水泥浆体 凝结 抗压强度 微观结构
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不同加载速率下胶结充填体声发射及裂纹演化特征
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作者 尹升华 周昀 +2 位作者 杨晓炳 陈威 陈俊伟 《煤炭科学技术》 北大核心 2025年第6期250-262,共13页
为探究加载速率v对胶结充填体裂纹演化机制的动态调控规律,开展了v=0.002,0.004,0.008,0.010 mm/s下的单轴压缩同步声发射试验。通过分析声发射振铃计数、平均频率(AF)、上升时间−幅值比(RA)及r值(RA/AF)的时变特征,并结合高斯混合模型(... 为探究加载速率v对胶结充填体裂纹演化机制的动态调控规律,开展了v=0.002,0.004,0.008,0.010 mm/s下的单轴压缩同步声发射试验。通过分析声发射振铃计数、平均频率(AF)、上升时间−幅值比(RA)及r值(RA/AF)的时变特征,并结合高斯混合模型(GMM)与移动平均滤波算法对RA-AF数据集进行无监督聚类,以识别裂纹类型及其演化规律。研究结果表明:①峰值应力(σ_(f))附近,充填体的声发射振铃计数呈现区间震荡现象,随着v增大,充填体的弹性变形及塑性屈服阶段的振铃计数波动率减小;②v从0.002增至0.010 mm/s时,AF分布集中范围随速率增加由0~150 kHz压缩至0~100 kHz,RA分布集中范围由0~5 ms/V扩展至0~10 ms/V,且高RA信号集中于AF<80 kHz窄带;③v增大对峰后破坏模式具有显著影响,剪切裂纹比例由19.11%(v=0.002 mm/s)跃升至64.23%(v=0.010 mm/s),表明v增大会驱动破坏机制从拉伸破坏主导向拉伸−剪切复合型破坏转化;④以加载应力阶段为界限,GMM聚类分析可将充填体的裂纹演化分为拉伸裂纹主导(0~20%σ_(f))、拉伸−剪切裂纹转化(20%σ_(f)~80%σ_(f))、剪切裂纹快速增长(80%σ_(f)~100%σ_(f))和剪切−拉伸裂纹共同主导(峰后破坏)4个阶段,其中剪切裂纹在80%σ_(f)~100%σ_(f)处的快速增长是充填体局部失稳破坏的前兆特征。研究可为充填体的稳定性分析与破坏预测提供理论支持。 展开更多
关键词 加载速率 胶结充填体 声发射 r值特征 裂纹演化
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采−选−冶−化固废基充填材料制备及综合性能研究综述
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作者 张钦礼 陶云波 +4 位作者 冯岩 陈秋松 高凌志 张芋杰 王道林 《煤炭科学技术》 北大核心 2025年第6期65-81,共17页
固废基胶结充填技术作为实现绿色矿山建设与工业固废协同处置的核心载体,其材料设计与性能调控已成为矿业工程领域的研究热点。针对采−选−冶−化多源工业固废(采掘废石、选矿尾砂、冶金炉渣、化工废料等)物化特性差异显著导致的充填体性... 固废基胶结充填技术作为实现绿色矿山建设与工业固废协同处置的核心载体,其材料设计与性能调控已成为矿业工程领域的研究热点。针对采−选−冶−化多源工业固废(采掘废石、选矿尾砂、冶金炉渣、化工废料等)物化特性差异显著导致的充填体性能离散化问题,系统综述了多源固废在充填材料中的角色差异,以及不同固废基充填材料在流变、强度、环境方面的综合性能。主要包括:系统综述了不同工业固废基充填材料的来源、性能及用途,发现典型工业固废(尾砂、钢渣、粉煤灰等)的化学组分呈现显著互补性,SiO_(2)、CaO和Al_(2)O_(3)的梯度分布为协同胶凝提供了物质基础;总结了不同工业固废基充填材料的流变性能、管输阻力计算方式、强度分布及优化手段,分析了固废基充填材料的屈服应力、黏度及抗压强度的分布范围及规律,发现粒径级配优化与聚羧酸减水剂的复合调控可有效降低管道输送阻力,选用恰当的激发剂和辅助胶凝材配比可有效提高充填体强度;评价了固废基充填材料在不同时间尺度下的环境污染风险,系统梳理了固废基充填材料中有害元素的浸出机制和固化机制,总结了矿山充填污染治理现状,发现提高固废基充填材料的水化反应进程和添加多孔物质可有效控制污染元素的扩散。研究成果对于推动采−选−冶−化行业的可持续发展、缓解固废处置压力、提升资源综合利用率以及促进绿色矿山建设具有重要意义。 展开更多
关键词 多源工业固废 固废基充填材料 流变与管输 强度性能 环境影响
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低水灰比水泥基材料早期塑性收缩研究 被引量:2
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作者 王佃超 鲁正 +2 位作者 王远航 谭淇航 朱黎明 《建筑科学与工程学报》 北大核心 2025年第1期131-138,共8页
为研究混凝土早期塑性收缩发展机制,探究不同的减缩抑制剂对混凝土收缩及裂缝发展的控制效果,分析水泥净浆的裂缝发展状态及主应变变化规律,分别选用再生混凝土微粉、碳化再生混凝土微粉、氧化镁基膨胀剂、聚乙烯纤维作为掺入材料,按照... 为研究混凝土早期塑性收缩发展机制,探究不同的减缩抑制剂对混凝土收缩及裂缝发展的控制效果,分析水泥净浆的裂缝发展状态及主应变变化规律,分别选用再生混凝土微粉、碳化再生混凝土微粉、氧化镁基膨胀剂、聚乙烯纤维作为掺入材料,按照相应配合比拌合水泥净浆;通过二维非接触数字图像方法(2D-DIC)研究了不同净浆的收缩裂缝发展历程,定量评价了不同工况下试件中线位置最大主应变的变化趋势;最后通过扫描电镜对不同掺料作用下的裂缝开展状态进行评估。结果表明:不同材料对混凝土早期塑性收缩的裂缝发展影响不同;掺入再生混凝土微粉与碳化再生混凝土微粉均能有效抑制水泥净浆的早期塑性收缩,碳化后的再生混凝土微粉较普通再生混凝土微粉能够进一步提升水泥净浆的收缩控制效果,裂缝出现时间延迟了10 min;加入聚乙烯纤维可有效提高塑性开裂的发展时间并减少裂缝的开展宽度;随着浇筑时间的增加,最大主应变逐渐增大,在4.5 h后达到0.03380;不同掺加剂对主应变的发展趋势影响各不相同,掺入碳化再生混凝土微粉工况下最大主应变在4.5 h时为0.02795,能够使塑性最大主应变降低17.30%;无掺加剂的水泥净浆中裂缝往往呈现主裂缝贯通、其余裂缝分散分布的特征;掺入碳化再生混凝土微粉的情况下,裂缝之间的连接性增强,表明碳化再生混凝土微粉的掺入有效降低了水泥基材料的早期塑性开裂程度。 展开更多
关键词 塑性收缩 数字图像 水泥净浆 碳化再生混凝土微粉 裂缝分布 最大主应变
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磷酸钾镁水泥基涂料浆体抗NaCl溶液的侵蚀能力 被引量:1
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作者 吕寅 李涛 +1 位作者 唐磊 任凡凡 《建筑材料学报》 北大核心 2025年第1期19-25,共7页
磷酸钾镁水泥基(MKPC)涂料浆体经NaCl溶液和水长期浸泡后,测试了其强度、吸水率、物相组成和微结构的变化.结果表明:经NaCl溶液浸泡540 d后,MKPC涂料浆体试件的抗折和抗压强度剩余率明显高于经水浸泡后的试件,排除水腐蚀的因素后,NaCl... 磷酸钾镁水泥基(MKPC)涂料浆体经NaCl溶液和水长期浸泡后,测试了其强度、吸水率、物相组成和微结构的变化.结果表明:经NaCl溶液浸泡540 d后,MKPC涂料浆体试件的抗折和抗压强度剩余率明显高于经水浸泡后的试件,排除水腐蚀的因素后,NaCl溶液对MKPC硬化体有增强作用;经硅微粉和水玻璃改性的MKPC涂料浆体试件抗折和抗压强度剩余率均高于未改性试件,水玻璃和硅微粉的改性能够改善MKPC硬化体对NaCl溶液的抗侵蚀性能;在水和NaCl溶液中浸泡540 d后,经硅微粉和水玻璃改性的MKPC涂料浆体试件孔结构劣化程度较未改性试件明显减轻. 展开更多
关键词 磷酸镁钾水泥基涂料浆体 水玻璃 硅微粉 溶液浸泡 强度 吸水率
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低速水流作用下水泥净浆缝面溶蚀的试验研究
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作者 高文龙 王少伟 +2 位作者 吴佳雯 夏群 胡坤 《水电能源科学》 北大核心 2025年第1期79-83,共5页
为探究低速水流作用下水泥净浆缝面流速与加速钙溶蚀效应之间的定量关系,使用1 moL/L NH_4Cl溶液作为溶蚀介质,在0.0、0.3、0.6、1.2、2.4 m/s流速下对水泥净浆单裂缝表面开展静态和动态溶蚀试验,研究缝面溶蚀—冲蚀深度、钙离子溶出量... 为探究低速水流作用下水泥净浆缝面流速与加速钙溶蚀效应之间的定量关系,使用1 moL/L NH_4Cl溶液作为溶蚀介质,在0.0、0.3、0.6、1.2、2.4 m/s流速下对水泥净浆单裂缝表面开展静态和动态溶蚀试验,研究缝面溶蚀—冲蚀深度、钙离子溶出量、质量损失率、曲折度、粗糙度和剩余固相钙含量6种评价指标的时变规律,并通过SEM/EDS和XRD进行微观机理解释。结果表明,2.4 m/s范围内的净浆缝面动态溶蚀过程仍满足Fick扩散定律,流动水对缝面无明显冲蚀作用,加速溶蚀效应与流速之间呈负指数函数型增长关系;流动水仅在溶蚀初期会引起缝面曲折度和粗糙度的显著降低,后期几乎无影响;流动水仅加速缝面溶蚀过程,不同流速下的最终缝面剩余固相钙含量相近。 展开更多
关键词 水泥净浆 低速水流 单裂缝缝面 加速溶蚀效应
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窄条带充填料浆流动扩展解析几何模型及接顶优化
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作者 朱梦博 罗屹骁 +5 位作者 刘浪 巫侯琴 何军 屈慧升 蔚保宁 何伟 《煤炭科学技术》 北大核心 2025年第8期226-239,共14页
充填体的接顶率对充填体整体质量及采空区稳定性有重要影响。充填体接顶率欠佳,在采空区顶部形成的欠接顶区域会带来许多安全隐患,如易引发顶板冒顶、片帮,地表沉降,有害气体集聚等问题。为探究欠接顶区域的成因及影响因素,优化充填接... 充填体的接顶率对充填体整体质量及采空区稳定性有重要影响。充填体接顶率欠佳,在采空区顶部形成的欠接顶区域会带来许多安全隐患,如易引发顶板冒顶、片帮,地表沉降,有害气体集聚等问题。为探究欠接顶区域的成因及影响因素,优化充填接顶工艺,基于多点分层充填工艺下充填料浆的扩展规律进行解析几何分析,并对窄条带多点分层充填工艺进行分析。量化表征了充填料浆触顶前及充填料浆触顶后的流动扩展规律,同时根据成因将充填料浆触顶后的封闭区划分为“Ⅰ型封闭区”和“Ⅱ型封闭区”,建立了欠接顶区的判别式。在窄条带充填料浆扩展解析几何模型研究基础上,建立了窄条带多点分层充填分析模型并开展近水平窄条带充填模拟试验,得到不同工艺下的封闭区长度;合理的下料点间距及接顶充填高度对提高充填接顶率具有重要影响。针对充填封闭区,提出了全域排气/排水方法,该管道单向透水/透气不透浆。搭建了特厚煤层窄条带充填物理相似试验台,开展充填多点分层充填试验和全域排水/排气试验。同时,采用地质雷达探测某充填矿井窄条带欠接顶区的分布规律,开展全域排水/排气优化接顶现场试验。物理模拟试验、现场试验欠接顶区分布规律与窄条带多点分层充填分析模型结果一致,全域排水/排气方法可以有效提高窄条带充填接顶效果。 展开更多
关键词 欠接顶 充填膏体 巷式开采 充填工艺 接顶优化
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胶结充填体-围岩组合体接触面力学特性研究
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作者 王奕仁 吴爱祥 +2 位作者 阮竹恩 卢宏建 武晓军 《中南大学学报(自然科学版)》 北大核心 2025年第6期2383-2395,共13页
为深入了解同时考虑接触面倾角和粗糙界面下胶结充填体-围岩组合体接触面的力学特性,基于粗糙接触面下不同接触面倾角(0°、15°、30°、45°、60°、75°和90°)和灰砂比(1:4和1:8)的组合体试块在单轴压... 为深入了解同时考虑接触面倾角和粗糙界面下胶结充填体-围岩组合体接触面的力学特性,基于粗糙接触面下不同接触面倾角(0°、15°、30°、45°、60°、75°和90°)和灰砂比(1:4和1:8)的组合体试块在单轴压缩条件下的破裂特征分析,建立接触面单元理论分析模型,并提出含凸齿接触面的3种应力破坏模式,研究组合体不同倾角接触面的应力特性及粗糙界面抗剪特性。研究结果表明:1)粗糙接触面下界面凸齿处的裂纹扩展是导致组合体强度劣化的关键,接触面倾角和灰砂比对裂纹扩展方式影响显著,当接触面倾角增大时,其破坏形式由充填体剪切破坏逐渐过渡为整体的张拉剪切组合破坏,当灰砂比增大时,充填体表面裂纹增多,围岩组块的破坏程度降低;2)界面约束应力与两组块材料的变形能力有关,在灰砂比不变的前提下,随接触角的增大,界面约束应力先减小后增大,在60°时达到最小;3)基于含围岩凸齿接触面在轴向压缩下的3种破坏模式,通过分析接触单元在凸齿处的抗剪特性,可确定接触面发生剪切破坏时的界面摩擦因数和抗剪强度力学指标的取值范围。该研究结果可为嗣后充填采场揭露充填体稳定性研究及充填体强度设计提供一定的理论依据。 展开更多
关键词 胶结充填体-围岩组合体 接触面倾角 粗糙界面 力学特性
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机械活化干法制备高效减水剂羧甲基-β-环糊精工艺及减水性能
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作者 杨家添 苗雨 +5 位作者 韦梦婷 王宁 黎以起 陈渊 覃峰 胡华宇 《应用化学》 北大核心 2025年第4期499-510,共12页
为了优化羧甲基β-环糊精(CM-β-CD)制备工艺、利于工业化生产,以β-环糊精(β-CD)和氯乙酸钠(C_(2)H_(2)ClNaO_(2))为原料,采用机械活化干法制备CM-β-CD。优化了CM-β-CD的工艺条件、表征了CM-β-CD的结构和测定了CM-β-CD的减水性能... 为了优化羧甲基β-环糊精(CM-β-CD)制备工艺、利于工业化生产,以β-环糊精(β-CD)和氯乙酸钠(C_(2)H_(2)ClNaO_(2))为原料,采用机械活化干法制备CM-β-CD。优化了CM-β-CD的工艺条件、表征了CM-β-CD的结构和测定了CM-β-CD的减水性能。最佳工艺条件为:n(C_(2)H_(2)ClNaO_(2))∶n(β-CD)为4∶1、NaOH质量分数20%、球磨温度40℃和球磨时间3 h时,此条件下制备得到的CM-β-CD的取代度(DS)为0.72,水泥净浆流动度达到237 mm(添加质量分数0.8%的CM-β-CD)。与普通干法制备的CM-β-CD相比,机械活化干法制备CM-β-CD的减水性能更优越。添加CM-β-CD质量分数为0.8%时,水泥砂浆减水率为20.40%,水泥养护时间28 d时的抗压抗折强度达到60.50和7.98 MPa。CM-β-CD是一种具有应用前景的绿色性能混凝土减水剂。 展开更多
关键词 羧甲基β-环糊精 机械活化干法 取代度 水泥净浆流动度 高效减水剂
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