Phase change material(PCM)can reduce the indoor temperature fluctuation and humidity control material can adjust relative humidity used in buildings.In this study,a kind of composite phase change material particles(CP...Phase change material(PCM)can reduce the indoor temperature fluctuation and humidity control material can adjust relative humidity used in buildings.In this study,a kind of composite phase change material particles(CPCMPs)were prepared by vacuum impregnation method with expanded perlite(EP)as supporting material and paraffin as phase change material.Thus,a PCM plate was fabricated by mould pressing method with CPCMPs and then composite phase change humidity control wallboard(CPCHCW)was prepared by spraying the diatom mud on the surface of PCM plate.The composition,thermophysical properties and microstructure were characterized using X-ray diffraction instrument(XRD),differential scanning calorimeter(DSC)and scanning electron microscope(SEM).Additionally,the hygrothermal performance of CPCHCW was characterized by temperature and humidity collaborative test.The results can be summarized as follows:(1)CPCMPs have suitable phase change parameters with melting/freezing point of 18.23°C/29.42°C and higher latent heat of 54.66 J/g/55.63 J/g;(2)the diatom mud can control the humidity of confined space with a certain volume;(3)the combination of diatom mud and PCM plate in CPCHCW can effectively adjust the indoor temperature and humidity.The above conclusions indicate the potential of CPCHCW in the application of building energy efficiency.展开更多
A binary eutectic mixture composed of tetradecanol(TD)and myristic acid(MA)was maximally absorbed into the microstructures of expanded perlite(EP)and expanded vermiculite(EVMT),respectively,through a self-made vacuum ...A binary eutectic mixture composed of tetradecanol(TD)and myristic acid(MA)was maximally absorbed into the microstructures of expanded perlite(EP)and expanded vermiculite(EVMT),respectively,through a self-made vacuum adsorption roller to prepare phase change material(PCM)particle(PCP).Then EP and EVMT-based composite PCM plates were respectively fabricated through a mold pressing method.The thermal property,chemical stability,microstructure and durability were characterized by differential scanning calorimeter(DSC),Fourier transform infrared spectroscope(FT-IR),scanning electron microscope(SEM)and thermal cycling tests,respectively.The results show that both PCPs have high latent heats with 110 J/g for EP-based PCP and more than 130 J/g for EVMT-based PCP,compact microstructure without PCM leakage,stable chemical property and good durability.The research results have proved the feasibility for the vacuum adsorption roller used in the composite PCM fabrication.Results of thermal storage performance experiment indicate that the fabricated PCM plates have better thermal inertia than common building materials,and the thermal storage performance of PCM plates has nonlinearly changed with outside air velocity and temperature increase.Therefore,PCM plates show a significant potential for the practical application of building thermal storage.展开更多
The heat transfer performance of the phase change materials used in free cooling and air conditioning applications is low,due to the poor thermal conductivity of the materials.The recent phenomenal advancement in nano...The heat transfer performance of the phase change materials used in free cooling and air conditioning applications is low,due to the poor thermal conductivity of the materials.The recent phenomenal advancement in nano technology provides an opportunity for an appreciable enhancement in the thermal conductivity of the phase change materials.In order to explore the possibilities of using nano technology for various applications,a detailed parametric study is carried out,to analyse the heat transfer enhancement potential with the thermal conductivity of the conventional phase change materials and nano enhanced phase change materials under various flow conditions of the heat transfer fluid.Initially,the theoretical equation,used to determine the time for outward cylindrical solidification of the phase change material,is validated with the experimental results.It is inferred from the parametric studies,that for paraffinic phase change materials with air as the heat transfer fluid,the first step should be to increase the heat transfer coefficient to the maximum extent,before making any attempt to increase the thermal conductivity of the phase change materials,with the addition of nano particles.When water is used as the phase change material,the addition of nano particles is recommended to achieve better heat transfer,when a liquid is used as the heat transfer fluid.展开更多
Paraffin/γ-Al2O3 composites as phase change energy storage materials were prepared by absorbing paraffin in porous network of γ-Al2O3.In the composite materials,paraffin was used as a phase change material(PCM)for t...Paraffin/γ-Al2O3 composites as phase change energy storage materials were prepared by absorbing paraffin in porous network of γ-Al2O3.In the composite materials,paraffin was used as a phase change material(PCM)for thermal energy storage,and γ-Al2O3 acted as supporting materials.Characterizations were conducted to evaluate the energy storage performance of the composites,and differential scanning calorimeter results showed that the PCM-3 composite has melting latent heat of 112.9 kJ/kg with a melting temperature of 62.9 ℃.Due to strong capillary force and surface tension between paraffin and γ-Al2O3,the leakage of melted paraffin from the composites can be effectively prevented.Therefore,the paraffin/γ-Al2O3 composites have a good thermal stability and can be used repeatedly.展开更多
Based on the phase change material (PCM) thermal characteristic,some testing methods such as differential scanning calorimeter (DSC) etc were used to select the low melting mixture of capric and lauric acid as PCM of ...Based on the phase change material (PCM) thermal characteristic,some testing methods such as differential scanning calorimeter (DSC) etc were used to select the low melting mixture of capric and lauric acid as PCM of phase change wallboard (PCW). The PCW room was established,and some contrast analysis of the storage and exchange thermal characteristic of PCW room and ordinary wall room were made under different conditions. The results show that the fluctuation of indoor air temperature in PCW room is smaller than that in ordinary room obviously. The exchange energy of PCM room with outdoor is less than that of ordinary wall room. In the winter condition,PCW room utilizes valley period electricity to storage energy in the night,while releases at peak period electricity in daytime,which can divert 40% of peak load. In the summer condition,PCW room can reduce the peak cooling load by 25% compared with ordinary wall room.展开更多
To solve the fundamental problem of insufficient heat available during defrosting while ensuring the efficient and safe system operation for air-source heat pumps (ASHPs). A novel reverse-cycle defrosting (NRCD) metho...To solve the fundamental problem of insufficient heat available during defrosting while ensuring the efficient and safe system operation for air-source heat pumps (ASHPs). A novel reverse-cycle defrosting (NRCD) method based on thermal energy storage to eliminate frost off the outdoor coil surface was developed. Comparative experiments using both the stand reverse cycle defrosting (SRCD) method and the NRCD method were carried out on an experimental ASHP unit with a nominal 2.5 kW heating capacity. The results indicate that during defrosting operation, using the NRCD method improves discharge and suction pressures by 0.24 MPa and 0.19 MPa, respectively, shortens defrosting duration by 60%, and reduces the defrosting energy consumption by 48.1% in the experimental environment, compared with those by the use of SRCD method. Therefore, using the NRCD method can shorten the defrosting duration, improve the indoor thermal comfort, and reduce the defrosting energy consumption in defrosting.展开更多
基金Project(51408184)supported by the National Natural Science Foundation of ChinaProject(E2017202136)supported by the Natural Science Foundation of Hebei Province,China+1 种基金Project(BSBE2017-05)supported by the Opening Funds of State Key Laboratory of Building Safety and Built Environment and National Engineering Research Center of Building Technology,ChinaProject(QG2018-3)supported by Hebei Provincial Department of Transportation,China
文摘Phase change material(PCM)can reduce the indoor temperature fluctuation and humidity control material can adjust relative humidity used in buildings.In this study,a kind of composite phase change material particles(CPCMPs)were prepared by vacuum impregnation method with expanded perlite(EP)as supporting material and paraffin as phase change material.Thus,a PCM plate was fabricated by mould pressing method with CPCMPs and then composite phase change humidity control wallboard(CPCHCW)was prepared by spraying the diatom mud on the surface of PCM plate.The composition,thermophysical properties and microstructure were characterized using X-ray diffraction instrument(XRD),differential scanning calorimeter(DSC)and scanning electron microscope(SEM).Additionally,the hygrothermal performance of CPCHCW was characterized by temperature and humidity collaborative test.The results can be summarized as follows:(1)CPCMPs have suitable phase change parameters with melting/freezing point of 18.23°C/29.42°C and higher latent heat of 54.66 J/g/55.63 J/g;(2)the diatom mud can control the humidity of confined space with a certain volume;(3)the combination of diatom mud and PCM plate in CPCHCW can effectively adjust the indoor temperature and humidity.The above conclusions indicate the potential of CPCHCW in the application of building energy efficiency.
基金Project(51408184)supported by the National Natural Science Foundation of ChinaProject(E2017202136)supported by the Natural Science Foundation of Hebei Province,China+1 种基金Project(BSBE2017-05)supported by Opening Funds of State Key Laboratory of Building Safety and Built Environment and National Engineering Research Center of Building Technology,ChinaProject(QG2018-3)supported by Hebei Provincial Department of Transportation,China
文摘A binary eutectic mixture composed of tetradecanol(TD)and myristic acid(MA)was maximally absorbed into the microstructures of expanded perlite(EP)and expanded vermiculite(EVMT),respectively,through a self-made vacuum adsorption roller to prepare phase change material(PCM)particle(PCP).Then EP and EVMT-based composite PCM plates were respectively fabricated through a mold pressing method.The thermal property,chemical stability,microstructure and durability were characterized by differential scanning calorimeter(DSC),Fourier transform infrared spectroscope(FT-IR),scanning electron microscope(SEM)and thermal cycling tests,respectively.The results show that both PCPs have high latent heats with 110 J/g for EP-based PCP and more than 130 J/g for EVMT-based PCP,compact microstructure without PCM leakage,stable chemical property and good durability.The research results have proved the feasibility for the vacuum adsorption roller used in the composite PCM fabrication.Results of thermal storage performance experiment indicate that the fabricated PCM plates have better thermal inertia than common building materials,and the thermal storage performance of PCM plates has nonlinearly changed with outside air velocity and temperature increase.Therefore,PCM plates show a significant potential for the practical application of building thermal storage.
文摘The heat transfer performance of the phase change materials used in free cooling and air conditioning applications is low,due to the poor thermal conductivity of the materials.The recent phenomenal advancement in nano technology provides an opportunity for an appreciable enhancement in the thermal conductivity of the phase change materials.In order to explore the possibilities of using nano technology for various applications,a detailed parametric study is carried out,to analyse the heat transfer enhancement potential with the thermal conductivity of the conventional phase change materials and nano enhanced phase change materials under various flow conditions of the heat transfer fluid.Initially,the theoretical equation,used to determine the time for outward cylindrical solidification of the phase change material,is validated with the experimental results.It is inferred from the parametric studies,that for paraffinic phase change materials with air as the heat transfer fluid,the first step should be to increase the heat transfer coefficient to the maximum extent,before making any attempt to increase the thermal conductivity of the phase change materials,with the addition of nano particles.When water is used as the phase change material,the addition of nano particles is recommended to achieve better heat transfer,when a liquid is used as the heat transfer fluid.
文摘Paraffin/γ-Al2O3 composites as phase change energy storage materials were prepared by absorbing paraffin in porous network of γ-Al2O3.In the composite materials,paraffin was used as a phase change material(PCM)for thermal energy storage,and γ-Al2O3 acted as supporting materials.Characterizations were conducted to evaluate the energy storage performance of the composites,and differential scanning calorimeter results showed that the PCM-3 composite has melting latent heat of 112.9 kJ/kg with a melting temperature of 62.9 ℃.Due to strong capillary force and surface tension between paraffin and γ-Al2O3,the leakage of melted paraffin from the composites can be effectively prevented.Therefore,the paraffin/γ-Al2O3 composites have a good thermal stability and can be used repeatedly.
基金Project(50878133) supported by the National Natural Science Foundation of ChinaProject (2007R37) supported by Excellent Talents in Liaoning Province+1 种基金Project (2008S193) supported by the Key Laboratory Fund of Education Department in Liaoning ProvinceProject(1071211-1-00) supported by the Scientific and Technical Fund Project Subsidy of Shenyang Province
文摘Based on the phase change material (PCM) thermal characteristic,some testing methods such as differential scanning calorimeter (DSC) etc were used to select the low melting mixture of capric and lauric acid as PCM of phase change wallboard (PCW). The PCW room was established,and some contrast analysis of the storage and exchange thermal characteristic of PCW room and ordinary wall room were made under different conditions. The results show that the fluctuation of indoor air temperature in PCW room is smaller than that in ordinary room obviously. The exchange energy of PCM room with outdoor is less than that of ordinary wall room. In the winter condition,PCW room utilizes valley period electricity to storage energy in the night,while releases at peak period electricity in daytime,which can divert 40% of peak load. In the summer condition,PCW room can reduce the peak cooling load by 25% compared with ordinary wall room.
基金Project(50606007) supported by the National Natural Science Foundation of China
文摘To solve the fundamental problem of insufficient heat available during defrosting while ensuring the efficient and safe system operation for air-source heat pumps (ASHPs). A novel reverse-cycle defrosting (NRCD) method based on thermal energy storage to eliminate frost off the outdoor coil surface was developed. Comparative experiments using both the stand reverse cycle defrosting (SRCD) method and the NRCD method were carried out on an experimental ASHP unit with a nominal 2.5 kW heating capacity. The results indicate that during defrosting operation, using the NRCD method improves discharge and suction pressures by 0.24 MPa and 0.19 MPa, respectively, shortens defrosting duration by 60%, and reduces the defrosting energy consumption by 48.1% in the experimental environment, compared with those by the use of SRCD method. Therefore, using the NRCD method can shorten the defrosting duration, improve the indoor thermal comfort, and reduce the defrosting energy consumption in defrosting.
