Lithium metal stands out as an exceptionally promising anode material,boasting an extraordinarily high theoretical capacity and impressive energy density.Despite these advantageous characters,the issues of dendrite fo...Lithium metal stands out as an exceptionally promising anode material,boasting an extraordinarily high theoretical capacity and impressive energy density.Despite these advantageous characters,the issues of dendrite formation and volume expansion of lithium metal anodes lead to performance decay and safety concerns,significantly impeding their advancement towards widespread commercial viability.Herein,a lithium-rich Li-B-In composite anode with abundant lithophilic sites and outstanding structural stability is reported to address the mentioned challenges.The evenly distributed Li-In alloy in the bulk phase of anodes act as mixed ion/electron conductors and nucleation sites,facilitating accelerated Li ions transport dynamics and suppressing lithium dendrite formation.Additionally,these micron-sized Li-In particles in LiB fibers framework can enhance overall structural integrity and provide sufficient interior space to accommodate the volume changes during cycling.The electrochemical performance of Li-B-In composite anode exhibits long-term cyclability,superior rate performance and high-capacity retention.This work confirms that the synergy between a 3 D skeleton and hetero-metallic lithiophilic sites can achieve stable and durable lithium metal anodes,offering innovative insights for the practical deployment of lithium metal batteries.展开更多
淮河是一条对华夏文明具有重大意义的河流。但相较于黄河与长江流域,淮河流域的考古及古环境研究较为滞后。桥头遗址是淮河上游一处以石家河文化为主的重要遗址。本研究通过对桥头遗址区及其临近区域的地层调查和室内样品的测试分析,对...淮河是一条对华夏文明具有重大意义的河流。但相较于黄河与长江流域,淮河流域的考古及古环境研究较为滞后。桥头遗址是淮河上游一处以石家河文化为主的重要遗址。本研究通过对桥头遗址区及其临近区域的地层调查和室内样品的测试分析,对该遗址生成前后的环境变化以及古洪水事件与遗址的存续关系等展开了研究。研究发现:桥头遗址生成前大约在8.1~4.6 ka BP(9.1~5.4 cal.ka BP),遗址所在至少方圆2 km的范围区一直被湖沼所覆盖;4.6 ka BP(5.4 cal.ka BP)以后,温暖湿润的气候、地势较高的湖沼相沉积高地以及紧邻作为遗址水源地的母子河等优越的自然环境,吸引了先民来桥头区域生活;4.0 ka BP的气候异常事件、3.5 ka BP(3.9 cal.ka BP)的气候波动所带来的洪水灾害和3.2 ka BP(3.6 cal.ka BP)的淮河改道等自然环境的频繁变动,使得石家河文化以后的1000年时间内遗址区不适宜人类居住。3 ka BP(3.3 cal.ka BP)之后,桥头遗址所在区域的气温逐渐升高变暖,先人再次在此定居;2.5 ka BP(1.8 cal.ka BP)后,气候的剧烈波动、洪水的频繁泛滥再次威胁到人类在桥头遗址区域生产生活,先人从此地再次迁徙。展开更多
基金Project(2023YFC3905904)supported by the National Key Research and Development Program,ChinaProject(2220197000221)supported by the Team of Foshan National Hi-Tech Industrial Development Zone Industrialization Entrepreneurial Teams Program,ChinaProject(2024ZZTS0373)supported by the Central South University Graduate Student Autonomous Exploration Innovative Programme,China。
文摘Lithium metal stands out as an exceptionally promising anode material,boasting an extraordinarily high theoretical capacity and impressive energy density.Despite these advantageous characters,the issues of dendrite formation and volume expansion of lithium metal anodes lead to performance decay and safety concerns,significantly impeding their advancement towards widespread commercial viability.Herein,a lithium-rich Li-B-In composite anode with abundant lithophilic sites and outstanding structural stability is reported to address the mentioned challenges.The evenly distributed Li-In alloy in the bulk phase of anodes act as mixed ion/electron conductors and nucleation sites,facilitating accelerated Li ions transport dynamics and suppressing lithium dendrite formation.Additionally,these micron-sized Li-In particles in LiB fibers framework can enhance overall structural integrity and provide sufficient interior space to accommodate the volume changes during cycling.The electrochemical performance of Li-B-In composite anode exhibits long-term cyclability,superior rate performance and high-capacity retention.This work confirms that the synergy between a 3 D skeleton and hetero-metallic lithiophilic sites can achieve stable and durable lithium metal anodes,offering innovative insights for the practical deployment of lithium metal batteries.
文摘淮河是一条对华夏文明具有重大意义的河流。但相较于黄河与长江流域,淮河流域的考古及古环境研究较为滞后。桥头遗址是淮河上游一处以石家河文化为主的重要遗址。本研究通过对桥头遗址区及其临近区域的地层调查和室内样品的测试分析,对该遗址生成前后的环境变化以及古洪水事件与遗址的存续关系等展开了研究。研究发现:桥头遗址生成前大约在8.1~4.6 ka BP(9.1~5.4 cal.ka BP),遗址所在至少方圆2 km的范围区一直被湖沼所覆盖;4.6 ka BP(5.4 cal.ka BP)以后,温暖湿润的气候、地势较高的湖沼相沉积高地以及紧邻作为遗址水源地的母子河等优越的自然环境,吸引了先民来桥头区域生活;4.0 ka BP的气候异常事件、3.5 ka BP(3.9 cal.ka BP)的气候波动所带来的洪水灾害和3.2 ka BP(3.6 cal.ka BP)的淮河改道等自然环境的频繁变动,使得石家河文化以后的1000年时间内遗址区不适宜人类居住。3 ka BP(3.3 cal.ka BP)之后,桥头遗址所在区域的气温逐渐升高变暖,先人再次在此定居;2.5 ka BP(1.8 cal.ka BP)后,气候的剧烈波动、洪水的频繁泛滥再次威胁到人类在桥头遗址区域生产生活,先人从此地再次迁徙。
