A novel power and cooling system combined system which coupled organic Rankine cycle(ORC) with vapor compression refrigeration cycle(VCRC) was proposed. R245 fa and butane were selected as the working fluid for the po...A novel power and cooling system combined system which coupled organic Rankine cycle(ORC) with vapor compression refrigeration cycle(VCRC) was proposed. R245 fa and butane were selected as the working fluid for the power and refrigeration cycle, respectively. A performance comparison and analysis for the combined system was presented. The results show that dual-pressure ORC-VCRC system can achieve an increase of 7.1% in thermal efficiency and 6.7% in exergy efficiency than that of basic ORC-VCRC. Intermediate pressure is a key parameter to both net power and exergy efficiency of dual-pressure ORC-VCRC system. Combined system can produce maximum net power and exergy efficiency at 0.85 MPa for intermediate pressure and 2.4 MPa for high pressure, respectively. However, superheated temperature at expander inlet has little impact on the two indicators. It can achieve higher overall COP, net power and exergy efficiency at smaller difference between condensation temperature and evaporation temperature of VCRC.展开更多
Organic Rankine cycle(ORC) is applicable for the heat-work conversion. Whereas, there also exist a lot issues that influence the efficiency and the cost of the system. In this work, eleven pure working fluids(as categ...Organic Rankine cycle(ORC) is applicable for the heat-work conversion. Whereas, there also exist a lot issues that influence the efficiency and the cost of the system. In this work, eleven pure working fluids(as categorized into alkanes, and fluorinated alkanes) are investigated based on the first and second law of thermodynamics. The major objective is to obtain the most suitable working fluid for the latent heat source. The results show that the working fluid is an important factor of the system performance. The heat absorption of the working fluid in the evaporator is inversely proportional to the evaporating temperature, but the thermal and exergetic efficiencies are just the opposite. RC318 has the highest net power output and the lowest outlet temperature of the heat source, but its global warming potential(GWP) value is too high. The cyclohexane shows the highest thermal efficiency among the fluids investigated. Moreover, the figure of merit(FOM) of the isobutane is higher than that of other working fluids. Overall, the cyclohexane shows that the optimal comprehensive performance is more feasible for medium grade heat source in engineering applications.展开更多
Exhaust hot water(EHW)is widely used for various industrial processes.However,the excess heat carried by EHW is typically ignored and discharged into the environment,resulting in heat loss and heat pollution.An organi...Exhaust hot water(EHW)is widely used for various industrial processes.However,the excess heat carried by EHW is typically ignored and discharged into the environment,resulting in heat loss and heat pollution.An organic Rankine cycle(ORC)is an attractive technology to recycle heat from low-temperature energy carriers.Herein,ORC was used to recycle the heat carried by EHW.To investigate the energy and exergy recovery effects of EHW,a mathematical model was developed and a parametric study was conducted.The energy efficiency and exergy efficiency of the EHW-driven ORC system were modeled with R245fa,R113 and R123 as the working fluids.The results demonstrate that the EHW and evaporation temperatures have significant effects on the energy and exergy efficiencies of the EHW-driven ORC system.Under given EHW conditions,an optimum evaporation temperature exists corresponding to the highest exergy efficiency.To further use the low-temperature EHW,a configuration retrofitted to the ORC by combining with flash evaporation(FE)was conducted.For an EHW at 120℃ and 0.2 MPa,the maximum exergy efficiency of the FE-ORC system is 45.91%at a flash pressure of 0.088 MPa.The FE-ORC performs better in exergy efficiency than the basic FE and basic EHW-driven ORC.展开更多
Organic Rankine cycle(ORC)is widely used for the low grade geothermal power generation.However,a large amount of irreversible loss results in poor technical and economic performance due to its poor matching between th...Organic Rankine cycle(ORC)is widely used for the low grade geothermal power generation.However,a large amount of irreversible loss results in poor technical and economic performance due to its poor matching between the heat source/sink and the working medium in the condenser and the evaporator.The condensing temperature,cooling water temperature difference and pinch point temperature difference are often fixed according to engineering experience.In order to optimize the ORC system comprehensively,the coupling effect of evaporation and condensation process was proposed in this paper.Based on the laws of thermodynamics,the energy analysis,exergy analysis and entropy analysis were adopted to investigate the ORC performance including net output power,thermal efficiency,exergy efficiency,thermal conductivity,irreversible loss,etc.,using geothermal water at a temperature of 120℃as the heat source and isobutane as the working fluid.The results show that there exists a pair of optimal evaporating temperature and condensing temperatures to maximize the system performance.The net power output and the system comprehensive performance achieve their highest values at the same evaporating temperature,but the system comprehensive performance corresponds to a lower condensing temperature than the net power output.展开更多
Taking the ratio of heat transfer area to net power and heat recovery efficiency into account, a multi-objective mathematical model was developed for organic Rankine cycle （ORC）. Working fluids considered were R123,...Taking the ratio of heat transfer area to net power and heat recovery efficiency into account, a multi-objective mathematical model was developed for organic Rankine cycle （ORC）. Working fluids considered were R123, R134a, R141b, R227ea and R245fa. Under the given conditions, the parameters including evaporating and condensing pressures, working fluid and cooling water velocities were optimized by simulated annealing algorithm. The results show that the optimal evaporating pressure increases with the heat source temperature increasing. Compared with other working fluids, R123 is the best choice for the temperature range of 100--180℃ and R141 b shows better performance when the temperature is higher than 180 ℃. Economic characteristic of system decreases rapidly with the decrease of heat source temperature. ORC system is uneconomical for the heat source temperature lower than 100℃.展开更多
Organic Rankine cycle(ORC) power plant operating with supercritical parameters supplied by low temperature slag-washing water(SWW) of blast furnace was investigated.A schematic of such installation was presented with ...Organic Rankine cycle(ORC) power plant operating with supercritical parameters supplied by low temperature slag-washing water(SWW) of blast furnace was investigated.A schematic of such installation was presented with a description of its operation and the algorithm of calculations of a supercritical power plant.Two typical organic fluids with sufficiently low critical parameters were selected as candidate working fluids in the plant to study the efficiency of the system with different organic fluids.An analysis of the influence on the effectiveness of operation of a plant was carried out.With the same temperature of slag-washing water,the specific work in turbine of fluid R143a is 45% higher than that obtained for the fluid R125,however,the specific work in pump of fluid R143a is approximate equal into that one of the fluid R125.展开更多
To promote the fuel utilization efficiency of IC engine, an approach was proposed for IC engine coolant energy recovery based on low-temperature organic Rankine cycle(ORC). The ORC system uses IC engine coolant as hea...To promote the fuel utilization efficiency of IC engine, an approach was proposed for IC engine coolant energy recovery based on low-temperature organic Rankine cycle(ORC). The ORC system uses IC engine coolant as heat source, and it is coupled to the IC engine cooling system. After various kinds of organic working media were compared, R124 was selected as the ORC working medium. According to IC engine operating conditions and coolant energy characteristics, the major parameters of ORC system were preliminary designed. Then, the effects of various parameters on cycle performance and recovery potential of coolant energy were analyzed via cycle process calculation. The results indicate that cycle efficiency is mainly influenced by the working pressure of ORC, while the maximum working pressure is limited by IC engine coolant temperature. At the same working pressure, cycle efficiency is hardly affected by both the mass flow rate and temperature of working medium. When the bottom cycle working pressure arrives at the maximum allowable value of 1.6 MPa, the fuel utilization efficiency of IC engine could be improved by 12.1%.All these demonstrate that this low-temperature ORC is a useful energy-saving technology for IC engine.展开更多
The group-contribution (GC) methods suffer from a limitation concerning to the prediction of process-related indexes, e.g., thermal efficiency. Recently developed analytical models for thermal efficiency of organic Ra...The group-contribution (GC) methods suffer from a limitation concerning to the prediction of process-related indexes, e.g., thermal efficiency. Recently developed analytical models for thermal efficiency of organic Rankine cycles (ORCs) provide a possibility of overcoming the limitation of the GC methods because these models formulate thermal efficiency as functions of key thermal properties. Using these analytical relations together with GC methods, more than 60 organic fluids are screened for medium-low temperature ORCs. The results indicate that the GC methods can estimate thermal properties with acceptable accuracy (mean relative errors are 4.45%-11.50%);the precision, however, is low because the relative errors can vary from less than 0.1% to 45.0%. By contrast, the GC-based estimation of thermal efficiency has better accuracy and precision. The relative errors in thermal efficiency have an arithmetic mean of about 2.9% and fall within the range of 0-24.0%. These findings suggest that the analytical equations provide not only a direct way of estimating thermal efficiency but an accurate and precise approach to evaluating working fluids and guiding computer-aided molecular design of new fluids for ORCs using GC methods.展开更多
Dynamic performance is important to the controlling and monitoring of the organic Rankine cycle(ORC) system so to avoid the occurrence of unwanted conditions. A small scale waste heat recovery system with organic Rank...Dynamic performance is important to the controlling and monitoring of the organic Rankine cycle(ORC) system so to avoid the occurrence of unwanted conditions. A small scale waste heat recovery system with organic Rankine cycle was constructed and the dynamic behavior was presented. In the dynamic test, the pump was stopped and then started. In addition, there was a step change of the flue gas volume flow rate and the converter frequency of multistage pump, respectively. The results indicate that the working fluid flow rate has the shortest response time, followed by the expander inlet pressure and the expander inlet temperature.The operation frequency of pump is a key parameter for the ORC system. Due to a step change of pump frequency(39.49-35.24 Hz),the expander efficiency and thermal efficiency drop by 16% and 21% within 2 min, respectively. Besides, the saturated mixture can lead to an increase of the expander rotation speed.展开更多
To improve energy conversion efficiency, optimization of the working fluids in organic Rankine cycles(ORCs) was explored in the range of low-temperature heat sources. The concept of unit-heat-exchange-area(UHEA) net p...To improve energy conversion efficiency, optimization of the working fluids in organic Rankine cycles(ORCs) was explored in the range of low-temperature heat sources. The concept of unit-heat-exchange-area(UHEA) net power, embodying the cost/performance ratio of an ORC system, was proposed as a new indicator to judge the suitability of ORC working fluids on a given condition. The heat exchange area was computed by an improved evaporator model without fixing the minimum temperature difference between working fluid and hot fluid, and the flow pattern transition during heat exchange was also taken into account. The maximum UHEA net powers obtained show that dry organic fluids are more suitable for ORCs than wet organic fluids to recover low-temperature heat. The organic fluid 1-butene is recommended if the inlet temperature of hot fluid is 353.15-363.15 K or443.15-453.15 K, heptane is more suitable at 373.15-423.15 K, and R245 ca is a good option at 483.15-503.15 K.展开更多
A comparison on subcritical and transcritical organic Rankine cycle（ORC） system with a heat source of 110 ℃ geothermal water was presented. The net power output, thermal and exergy efficiencies and the products of ...A comparison on subcritical and transcritical organic Rankine cycle（ORC） system with a heat source of 110 ℃ geothermal water was presented. The net power output, thermal and exergy efficiencies and the products of the heat transfer coefficient（U） and the total heat exchange area（A）（UA values） were calculated for parametric optimization. Nine candidate working fluids were investigated and compared. Under the given conditions, transcritical systems have higher net power outputs than subcritical ones. The highest net power output of transcritical systems is 18.63 k W obtained by R218, and that of subcritical systems is 13.57 k W obtained by R600 a. Moreover, with the increase of evaporating pressure, the thermal and exergy efficiencies of transcritical systems increase at first and then decrease, but the efficiencies of subcritical ones increase. As a result, the efficiencies of transcritical systems cannot always outperform those of the subcritical ones. However, the subcritical systems have lower minimum UA values and lower expansion ratios than the transcritical ones at the maximum net power output. In addition, the transcritical cycles have higher expansion ratios than the subcritical ones at their maximum net power output.展开更多
In order to improve the efficiency of a geothermal power plant, oil wells in the high water cut stage were used as geothermal wells, thereby improving the recovery ratio and economic benefit. A new function that refle...In order to improve the efficiency of a geothermal power plant, oil wells in the high water cut stage were used as geothermal wells, thereby improving the recovery ratio and economic benefit. A new function that reflects both the technical and economic performances was put forward and used as the objective function. An organic Rankine cycle (ORC) was analyzed through the energetic and exergetic analyses, and the reasons for low efficiency were pinpointed. Results indicate that geothermal water directly transferring heat to the working fluid reduces energy dissipation and increases cycle efficiencies. The net power output with an internal heat exchanger (IHE) is averagely 5.3% higher than that without an IHE. R601a and R601 can be used to replace R123 for geothermal water below 110℃. Moreover, the modified ORC dramatically outperforms the actual one.展开更多
基金Project(12C0379)supported by the Scientific Research Fund of Hunan Province,ChinaProject(13QDZ04)supported by the Scientific Research Foundation for Doctors of Xiangtan University,China
文摘A novel power and cooling system combined system which coupled organic Rankine cycle(ORC) with vapor compression refrigeration cycle(VCRC) was proposed. R245 fa and butane were selected as the working fluid for the power and refrigeration cycle, respectively. A performance comparison and analysis for the combined system was presented. The results show that dual-pressure ORC-VCRC system can achieve an increase of 7.1% in thermal efficiency and 6.7% in exergy efficiency than that of basic ORC-VCRC. Intermediate pressure is a key parameter to both net power and exergy efficiency of dual-pressure ORC-VCRC system. Combined system can produce maximum net power and exergy efficiency at 0.85 MPa for intermediate pressure and 2.4 MPa for high pressure, respectively. However, superheated temperature at expander inlet has little impact on the two indicators. It can achieve higher overall COP, net power and exergy efficiency at smaller difference between condensation temperature and evaporation temperature of VCRC.
基金Project(51406130) supported by the National Natural Science Foundation of China
文摘Organic Rankine cycle(ORC) is applicable for the heat-work conversion. Whereas, there also exist a lot issues that influence the efficiency and the cost of the system. In this work, eleven pure working fluids(as categorized into alkanes, and fluorinated alkanes) are investigated based on the first and second law of thermodynamics. The major objective is to obtain the most suitable working fluid for the latent heat source. The results show that the working fluid is an important factor of the system performance. The heat absorption of the working fluid in the evaporator is inversely proportional to the evaporating temperature, but the thermal and exergetic efficiencies are just the opposite. RC318 has the highest net power output and the lowest outlet temperature of the heat source, but its global warming potential(GWP) value is too high. The cyclohexane shows the highest thermal efficiency among the fluids investigated. Moreover, the figure of merit(FOM) of the isobutane is higher than that of other working fluids. Overall, the cyclohexane shows that the optimal comprehensive performance is more feasible for medium grade heat source in engineering applications.
基金Projects(51704069,51734004,71403175)supported by the National Natural Science Foundation of ChinaProject(N162504011)supported by the Fundamental Research Funds for the Central Universities,China
文摘Exhaust hot water(EHW)is widely used for various industrial processes.However,the excess heat carried by EHW is typically ignored and discharged into the environment,resulting in heat loss and heat pollution.An organic Rankine cycle(ORC)is an attractive technology to recycle heat from low-temperature energy carriers.Herein,ORC was used to recycle the heat carried by EHW.To investigate the energy and exergy recovery effects of EHW,a mathematical model was developed and a parametric study was conducted.The energy efficiency and exergy efficiency of the EHW-driven ORC system were modeled with R245fa,R113 and R123 as the working fluids.The results demonstrate that the EHW and evaporation temperatures have significant effects on the energy and exergy efficiencies of the EHW-driven ORC system.Under given EHW conditions,an optimum evaporation temperature exists corresponding to the highest exergy efficiency.To further use the low-temperature EHW,a configuration retrofitted to the ORC by combining with flash evaporation(FE)was conducted.For an EHW at 120℃ and 0.2 MPa,the maximum exergy efficiency of the FE-ORC system is 45.91%at a flash pressure of 0.088 MPa.The FE-ORC performs better in exergy efficiency than the basic FE and basic EHW-driven ORC.
基金Project(2018YFB1501805)supported by the National Key Research and Development Program of ChinaProject(51406130)supported by the National Natural Science Foundation of ChinaProject(201604-504)supported by the Key Laboratory of Efficient Utilization of Low and Medium Grade Energy(Tianjin University),China
文摘Organic Rankine cycle(ORC)is widely used for the low grade geothermal power generation.However,a large amount of irreversible loss results in poor technical and economic performance due to its poor matching between the heat source/sink and the working medium in the condenser and the evaporator.The condensing temperature,cooling water temperature difference and pinch point temperature difference are often fixed according to engineering experience.In order to optimize the ORC system comprehensively,the coupling effect of evaporation and condensation process was proposed in this paper.Based on the laws of thermodynamics,the energy analysis,exergy analysis and entropy analysis were adopted to investigate the ORC performance including net output power,thermal efficiency,exergy efficiency,thermal conductivity,irreversible loss,etc.,using geothermal water at a temperature of 120℃as the heat source and isobutane as the working fluid.The results show that there exists a pair of optimal evaporating temperature and condensing temperatures to maximize the system performance.The net power output and the system comprehensive performance achieve their highest values at the same evaporating temperature,but the system comprehensive performance corresponds to a lower condensing temperature than the net power output.
基金Project(2009GK2009) supported by Science and Technology Department Funds of Hunan Province,ChinaProject(08C26224302178) supported by Innovation Fund for Technology Based Firms of China
文摘Taking the ratio of heat transfer area to net power and heat recovery efficiency into account, a multi-objective mathematical model was developed for organic Rankine cycle （ORC）. Working fluids considered were R123, R134a, R141b, R227ea and R245fa. Under the given conditions, the parameters including evaporating and condensing pressures, working fluid and cooling water velocities were optimized by simulated annealing algorithm. The results show that the optimal evaporating pressure increases with the heat source temperature increasing. Compared with other working fluids, R123 is the best choice for the temperature range of 100--180℃ and R141 b shows better performance when the temperature is higher than 180 ℃. Economic characteristic of system decreases rapidly with the decrease of heat source temperature. ORC system is uneconomical for the heat source temperature lower than 100℃.
基金Project(2011FZ050) supported by the Applied Basic Research Program of Yunnan Provincial Science and Technology Department,ChinaProject(2011J084) supported by the Master Program of Yunnan Province Education Department,China
文摘Organic Rankine cycle(ORC) power plant operating with supercritical parameters supplied by low temperature slag-washing water(SWW) of blast furnace was investigated.A schematic of such installation was presented with a description of its operation and the algorithm of calculations of a supercritical power plant.Two typical organic fluids with sufficiently low critical parameters were selected as candidate working fluids in the plant to study the efficiency of the system with different organic fluids.An analysis of the influence on the effectiveness of operation of a plant was carried out.With the same temperature of slag-washing water,the specific work in turbine of fluid R143a is 45% higher than that obtained for the fluid R125,however,the specific work in pump of fluid R143a is approximate equal into that one of the fluid R125.
基金Project(2011CB707201)supported by the National Basic Research Program of ChinaProject(51376057)supported by the National Natural Science Foundation of China
文摘To promote the fuel utilization efficiency of IC engine, an approach was proposed for IC engine coolant energy recovery based on low-temperature organic Rankine cycle(ORC). The ORC system uses IC engine coolant as heat source, and it is coupled to the IC engine cooling system. After various kinds of organic working media were compared, R124 was selected as the ORC working medium. According to IC engine operating conditions and coolant energy characteristics, the major parameters of ORC system were preliminary designed. Then, the effects of various parameters on cycle performance and recovery potential of coolant energy were analyzed via cycle process calculation. The results indicate that cycle efficiency is mainly influenced by the working pressure of ORC, while the maximum working pressure is limited by IC engine coolant temperature. At the same working pressure, cycle efficiency is hardly affected by both the mass flow rate and temperature of working medium. When the bottom cycle working pressure arrives at the maximum allowable value of 1.6 MPa, the fuel utilization efficiency of IC engine could be improved by 12.1%.All these demonstrate that this low-temperature ORC is a useful energy-saving technology for IC engine.
基金Project(51778626) supported by the National Natural Science Foundation of China
文摘The group-contribution (GC) methods suffer from a limitation concerning to the prediction of process-related indexes, e.g., thermal efficiency. Recently developed analytical models for thermal efficiency of organic Rankine cycles (ORCs) provide a possibility of overcoming the limitation of the GC methods because these models formulate thermal efficiency as functions of key thermal properties. Using these analytical relations together with GC methods, more than 60 organic fluids are screened for medium-low temperature ORCs. The results indicate that the GC methods can estimate thermal properties with acceptable accuracy (mean relative errors are 4.45%-11.50%);the precision, however, is low because the relative errors can vary from less than 0.1% to 45.0%. By contrast, the GC-based estimation of thermal efficiency has better accuracy and precision. The relative errors in thermal efficiency have an arithmetic mean of about 2.9% and fall within the range of 0-24.0%. These findings suggest that the analytical equations provide not only a direct way of estimating thermal efficiency but an accurate and precise approach to evaluating working fluids and guiding computer-aided molecular design of new fluids for ORCs using GC methods.
基金Project(2009Gk2009)supported by the Science and Technology Department Funds of Hunan Province,ChinaProject(12C0379)supported by the Scientific Research Fund of Hunan Province,ChinaProject(13QDZ04)supported by the Scientific Research Foundation for Doctors of Xiang Tan University,China
文摘Dynamic performance is important to the controlling and monitoring of the organic Rankine cycle(ORC) system so to avoid the occurrence of unwanted conditions. A small scale waste heat recovery system with organic Rankine cycle was constructed and the dynamic behavior was presented. In the dynamic test, the pump was stopped and then started. In addition, there was a step change of the flue gas volume flow rate and the converter frequency of multistage pump, respectively. The results indicate that the working fluid flow rate has the shortest response time, followed by the expander inlet pressure and the expander inlet temperature.The operation frequency of pump is a key parameter for the ORC system. Due to a step change of pump frequency(39.49-35.24 Hz),the expander efficiency and thermal efficiency drop by 16% and 21% within 2 min, respectively. Besides, the saturated mixture can lead to an increase of the expander rotation speed.
基金Projects(U0937604,50876116)supported by the National Natural Science Foundation of ChinaProjects(2010QZZD0107,2014zzts192)supported by the Fundamental Research Funds for the Central Universities of China
文摘To improve energy conversion efficiency, optimization of the working fluids in organic Rankine cycles(ORCs) was explored in the range of low-temperature heat sources. The concept of unit-heat-exchange-area(UHEA) net power, embodying the cost/performance ratio of an ORC system, was proposed as a new indicator to judge the suitability of ORC working fluids on a given condition. The heat exchange area was computed by an improved evaporator model without fixing the minimum temperature difference between working fluid and hot fluid, and the flow pattern transition during heat exchange was also taken into account. The maximum UHEA net powers obtained show that dry organic fluids are more suitable for ORCs than wet organic fluids to recover low-temperature heat. The organic fluid 1-butene is recommended if the inlet temperature of hot fluid is 353.15-363.15 K or443.15-453.15 K, heptane is more suitable at 373.15-423.15 K, and R245 ca is a good option at 483.15-503.15 K.
基金Project(2012AA053001) supported by the National High Technology Research and Development Program of China
文摘A comparison on subcritical and transcritical organic Rankine cycle（ORC） system with a heat source of 110 ℃ geothermal water was presented. The net power output, thermal and exergy efficiencies and the products of the heat transfer coefficient（U） and the total heat exchange area（A）（UA values） were calculated for parametric optimization. Nine candidate working fluids were investigated and compared. Under the given conditions, transcritical systems have higher net power outputs than subcritical ones. The highest net power output of transcritical systems is 18.63 k W obtained by R218, and that of subcritical systems is 13.57 k W obtained by R600 a. Moreover, with the increase of evaporating pressure, the thermal and exergy efficiencies of transcritical systems increase at first and then decrease, but the efficiencies of subcritical ones increase. As a result, the efficiencies of transcritical systems cannot always outperform those of the subcritical ones. However, the subcritical systems have lower minimum UA values and lower expansion ratios than the transcritical ones at the maximum net power output. In addition, the transcritical cycles have higher expansion ratios than the subcritical ones at their maximum net power output.
基金Project(2012AA052804) supported by the National High Technology Research and Development Program of China
文摘In order to improve the efficiency of a geothermal power plant, oil wells in the high water cut stage were used as geothermal wells, thereby improving the recovery ratio and economic benefit. A new function that reflects both the technical and economic performances was put forward and used as the objective function. An organic Rankine cycle (ORC) was analyzed through the energetic and exergetic analyses, and the reasons for low efficiency were pinpointed. Results indicate that geothermal water directly transferring heat to the working fluid reduces energy dissipation and increases cycle efficiencies. The net power output with an internal heat exchanger (IHE) is averagely 5.3% higher than that without an IHE. R601a and R601 can be used to replace R123 for geothermal water below 110℃. Moreover, the modified ORC dramatically outperforms the actual one.
