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High temperature shock synthesis of Ni-N-C single-atom catalysts for efficient CO_(2) electroreduction to CO
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作者 PANG Peiqi XU Changjian +5 位作者 LI Ruizhu GAO Na DU Xianlong LI Tao WANG Jianqiang XIAO Guoping 《燃料化学学报(中英文)》 北大核心 2025年第8期1162-1172,共11页
Electrocatalytic reduction of carbon dioxide(CO_(2))to carbon monoxide(CO)is an effective strategy to achieve carbon neutrality.High selective and low-cost catalysts for the electrocatalytic reduction of CO_(2)have re... Electrocatalytic reduction of carbon dioxide(CO_(2))to carbon monoxide(CO)is an effective strategy to achieve carbon neutrality.High selective and low-cost catalysts for the electrocatalytic reduction of CO_(2)have received increasing attention.In contrast to the conventional tube furnace method,the high-temperature shock(HTS)method enables ultra-fast thermal processing,superior atomic efficiency,and a streamlined synthesis protocol,offering a simplified method for the preparation of high-performance single-atom catalysts(SACs).The reports have shown that nickel-based SACs can be synthesized quickly and conveniently using the HTS method,making their application in CO_(2)reduction reactions(CO_(2)RR)a viable and promising avenue for further exploration.In this study,the effect of heating temperature,metal loading and different nitrogen(N)sources on the catalyst morphology,coordination environment and electrocatalytic performance were investigated.Under optimal conditions,0.05Ni-DCD-C-1050 showed excellent performance in reducing CO_(2)to CO,with CO selectivity close to 100%(−0.7 to−1.0 V vs RHE)and current density as high as 130 mA/cm^(2)(−1.1 V vs RHE)in a flow cell under alkaline environment. 展开更多
关键词 CO_(2)electrocatalytic reduction high temperature shock method single atom catalysts coordination
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A strength reduction method based on double reduction parameters and its application 被引量:45
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作者 袁维 白冰 +1 位作者 李小春 汪海滨 《Journal of Central South University》 SCIE EI CAS 2013年第9期2555-2562,共8页
In the traditional strength reduction method,the cohesion and the friction angle adopt the same reduction parameter,resulting in equivalent proportional reduction.This method does not consider the different effects of... In the traditional strength reduction method,the cohesion and the friction angle adopt the same reduction parameter,resulting in equivalent proportional reduction.This method does not consider the different effects of the cohesion and friction angle on the stability of the same slope and is defective to some extent.Regarding this defect,a strength reduction method based on double reduction parameters,which adopts different reduction parameters,is proposed.The core of the double-parameter reduction method is the matching reduction principle of the slope with different angles.This principle is represented by the ratio of the reduction parameter of the cohesion to that of the friction angle,described as η.With the increase in the slopeangle,ηincreases; in particular,when the slope angle is 45°,tηis 1.0.Through the matching reduction principle,different safety margin factors can be calculated for the cohesion and friction angle.In combination with these two safety margin factors,a formula for calculating the overall safety factor of the slope is proposed,reflecting the different contributions of the cohesion and friction angle to the slope stability.Finally,it is shown that the strength reduction method based on double reduction parameters acquires a larger safety factor than the classic limit equilibrium method,but the calculation results are very close to those obtained by the limit equilibrium method. 展开更多
关键词 double reduction parameter strength reduction method matching reduction principle slope stability
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A new double reduction method for slope stability analysis 被引量:16
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作者 白冰 袁维 李小春 《Journal of Central South University》 SCIE EI CAS 2014年第3期1158-1164,共7页
The core of strength reduction method(SRM) involves finding a critical strength curve that happens to make the slope globally fail and a definition of factor of safety(FOS). A new double reduction method, including a ... The core of strength reduction method(SRM) involves finding a critical strength curve that happens to make the slope globally fail and a definition of factor of safety(FOS). A new double reduction method, including a detailed calculation procedure and a definition of FOS for slope stability was developed based on the understanding of SRM. When constructing the new definition of FOS, efforts were made to make sure that it has concise physical meanings and fully reflects the shear strength of the slope. Two examples, slopes A and B with the slope angles of 63° and 34° respectively, were given to verify the method presented. It is found that, for these two slopes, the FOSs from original strength reduction method are respectively 1.5% and 38% higher than those from double reduction method. It is also found that the double reduction method predicts a deeper potential slide line and a larger slide mass. These results show that on one hand, the double reduction method is comparative to the traditional methods and is reasonable, and on the other hand, the original strength reduction method may overestimate the safety of a slope. The method presented is advised to be considered as an additional option in the practical slope stability evaluations although more useful experience is required. 展开更多
关键词 slope stability strength reduction method double strength reduction method factor of safety limit equilibrium method
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Limit analysis of vertical anti-pulling screw pile group under inclined loading on 3D elastic-plastic finite element strength reduction method 被引量:12
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作者 董天文 郑颖人 《Journal of Central South University》 SCIE EI CAS 2014年第3期1165-1175,共11页
Based on the functional theory, catastrophe theory, simultaneity principle and the idea of strength reduction method (SRM), the bearing capacity functional anti SRM of pile group foundation were established, and the... Based on the functional theory, catastrophe theory, simultaneity principle and the idea of strength reduction method (SRM), the bearing capacity functional anti SRM of pile group foundation were established, and the criteria of ultimate load and the concept of safety storage coefficient (Css) were advanced. The inclined ultimate loads by the static loading test, load increment method (LIM) and SRM are compared. Theoretically, the ultimate load of piles does not change with the loading levels when it is calculated by SRM. When the one strength reduction parameter is applied in the calculation boundary, there are calculating errors because the bearing capacity action of soils happened in the finite zone. The inclined 10adings are 108, 132 and 144 kN, and SSC are 1.07, 0.94 and 0.79, respectively, so the calculation values of ultimate loads are about 115.56, 124.08 and 113.76 kN, respectively. The error between calculations and observation values is less than 6%. But .the error between calculations of LIM and observations is 20%. Because of the effect of inclined loading, the push-rotation phenomenon of screw pile group appears. Under this testing, the ultimate bearing capacity of piles is mostly determined by the horizontal ultimate bearing capacity, and the effect of the vertical component of inclined load should also be considered. 展开更多
关键词 strength reduction method screw pile group ultimate load inclined loading
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Slope analysis based on local strength reduction method and variable-modulus elasto-plastic model 被引量:5
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作者 杨光华 钟志辉 +3 位作者 傅旭东 张玉成 温勇 张明飞 《Journal of Central South University》 SCIE EI CAS 2014年第5期2041-2050,共10页
Employing an ideal elasto-plastic model,the typically used strength reduction method reduced the strength of all soil elements of a slope.Therefore,this method was called the global strength reduction method(GSRM).How... Employing an ideal elasto-plastic model,the typically used strength reduction method reduced the strength of all soil elements of a slope.Therefore,this method was called the global strength reduction method(GSRM).However,the deformation field obtained by GSRM could not reflect the real deformation of a slope when the slope became unstable.For most slopes,failure occurs once the strength of some regional soil is sufficiently weakened; thus,the local strength reduction method(LSRM)was proposed to analyze slope stability.In contrast with GSRM,LSRM only reduces the strength of local soil,while the strength of other soil remains unchanged.Therefore,deformation by LSRM is more reasonable than that by GSRM.In addition,the accuracy of the slope's deformation depends on the constitutive model to a large degree,and the variable-modulus elasto-plastic model was thus adopted.This constitutive model was an improvement of the Duncan–Chang model,which modified soil's deformation modulus according to stress level,and it thus better reflected the plastic feature of soil.Most importantly,the parameters of the variable-modulus elasto-plastic model could be determined through in-situ tests,and parameters determination by plate loading test and pressuremeter test were introduced.Therefore,it is easy to put this model into practice.Finally,LSRM and the variable-modulus elasto-plastic model were used to analyze Egongdai ancient landslide.Safety factor,deformation field,and optimal reinforcement measures for Egongdai ancient landslide were obtained based on the proposed method. 展开更多
关键词 slope stability local strength reduction method variable-modulus elasto-plastic model in-situ test
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Reduction of Oxygen Bound with Hemoglobin by Electrolytic Method Using Hydrogen Gas in Phosphate-buffered Solution
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作者 YbuinHuang ShinjiTakeoka 《应用化学》 CAS CSCD 北大核心 2002年第4期307-309,共3页
Hemoglobin(Hb) is important as an oxygen carrier. The trace amount of oxygen in Hb was reduced by an electrolytic method using hydrogen as an electron donor. The deoxygenated Hb(deoxyHb) was stable against heat treatm... Hemoglobin(Hb) is important as an oxygen carrier. The trace amount of oxygen in Hb was reduced by an electrolytic method using hydrogen as an electron donor. The deoxygenated Hb(deoxyHb) was stable against heat treatment at 60 ℃ with little precipitant. This method is safe, fast, and would be of potential use for large scale purification of Hb. 展开更多
关键词 电化学方法 血红蛋白 氢气 还原
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One-step green method to prepare progressive burning gun propellant through gradient denitration strategy 被引量:8
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作者 Shi-ying Li Yu Li +2 位作者 Ya-jun Ding Hao Liang Zhong-liang Xiao 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2023年第4期135-143,共9页
Gradiently denitrated gun propellant(GDGP)prepared by a“gradient denitration”strategy is obviously superior in progressive burning performance to the traditional deterred gun propellant.Currently,the preparation of ... Gradiently denitrated gun propellant(GDGP)prepared by a“gradient denitration”strategy is obviously superior in progressive burning performance to the traditional deterred gun propellant.Currently,the preparation of GDGP employed a tedious two-step method involving organic solvents,which hinders the large-scale preparation of GDGP.In this paper,GDGP was successfully prepared via a novelty and environmentally friendly one-step method.The obtained samples were characterized by FT-IR,Raman,SEM and XPS.The results showed that the content of nitrate groups gradiently increased from the surface to the core in the surface layer of GDGP and the surface layer of GDGP exhibited a higher compaction than that of raw gun propellant,with a well-preserved nitrocellulose structure.The denitration process enabled the propellant surface with regressive energy density and good progressive burning performance,as confirmed by oxygen bomb and closed bomb test.At the same time,the effects of different solvents on the component loss of propellant were compared.The result showed that water caused the least component loss.Finally,the stability of GDGP was confirmed by methyl-violet test.This work not only provided environmentally friendly,simple and economic preparation of GDGP,but also confirmed the stability of GDGP prepared by this method. 展开更多
关键词 Gradiently denitrated gun propellant one-step green method DENITRATION Progressive burning Stability
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Upper bound analysis of slope stability with nonlinear failure criterion based on strength reduction technique 被引量:25
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作者 赵炼恒 李亮 +2 位作者 杨峰 罗强 刘项 《Journal of Central South University》 SCIE EI CAS 2010年第4期836-844,共9页
Based on the upper bound limit analysis theorem and the shear strength reduction technique, the equation for expressing critical limit-equilibrium state was employed to define the safety factor of a given slope and it... Based on the upper bound limit analysis theorem and the shear strength reduction technique, the equation for expressing critical limit-equilibrium state was employed to define the safety factor of a given slope and its corresponding critical failure mechanism by means of the kinematical approach of limit analysis theory. The nonlinear shear strength parameters were treated as variable parameters and a kinematically admissible failure mechanism was considered for calculation schemes. The iterative optimization method was adopted to obtain the safety factors. Case study and comparative analysis show that solutions presented here agree with available predictions when nonlinear criterion reduces to linear criterion, and the validity of present method could be illuminated. From the numerical results, it can also be seen that nonlinear parameter rn, slope foot gradient ,β, height of slope H, slope top gradient a and soil bulk density γ have significant effects on the safety factor of the slope. 展开更多
关键词 nonlinear failure criterion strength reduction method upper-bound theorem of limit analysis slope stability analysis factor of safety
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Selective catalytic reduction of NO with NH_3 over sol-gel-derived CuO-CeO_2-MnO_x/γ-Al_2O_3 catalysts 被引量:2
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作者 赵清森 向军 +3 位作者 孙路石 石金明 苏胜 胡松 《Journal of Central South University》 SCIE EI CAS 2009年第3期513-519,共7页
Granular CuO-CeO2-MnOx/γ-Al2O3 catalysts were synthesized by the sol-gel method. The performance of the CuO-CeO2-MnOx/γ-Al2O3 catalysts for the selective catalytic reduction (SCR) was studied in a fixed bed system. ... Granular CuO-CeO2-MnOx/γ-Al2O3 catalysts were synthesized by the sol-gel method. The performance of the CuO-CeO2-MnOx/γ-Al2O3 catalysts for the selective catalytic reduction (SCR) was studied in a fixed bed system. Preliminary tests were carried out to analyze the behavior of NH3 and NO over catalyst in the presence of oxygen. The optimum temperature range for SCR over the CuO-CeO2-MnOx/γ-Al2O3 catalysts is 300-400 ℃ . The catalysts maintain nearly 100% NO conversion at 350 ℃. The NH3 oxidation experiments show that both NO and N2O are produced gradually with the increase of temperature. The catalysts in this experiment have a stronger oxidation property on NH3, which improves the denitrification activity at low temperature. The over-oxidation of NH3 at high temperature is the main cause leading to a decrease in the NO conversion. The NH3 and NO desorption experiments show that NH3 and NO can be adsorbed on CuO-CeO2-MnOx/γ-Al2O3 granular catalysts. The transient response of NH3 and NO indicates that the SCR reaction proceeds in accordance with the Eley-Rideal mechanism. The adsorbed NO has little influence on the denitrification activity in SCR process. 展开更多
关键词 sol-gel method CuO-CeO2-MnOx/γ-Al2O3 NH3 NO CONVERSION selective catalytic reduction (SCR)
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Resistance optimization of flexes in aluminum reduction cells 被引量:1
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作者 李劼 刘杰 +3 位作者 刘伟 赖延清 王志刚 伍玉云 《Journal of Central South University of Technology》 EI 2008年第1期20-24,共5页
The resistance arrangements of the flexes connecting with the cathode bus bar in aluminum reduction cells were generalized as three modes. In each mode the universal method to select proper resistivity of the flexes w... The resistance arrangements of the flexes connecting with the cathode bus bar in aluminum reduction cells were generalized as three modes. In each mode the universal method to select proper resistivity of the flexes was induced respectively to insure that the current in local group of flexes was equal. Furthermore, a 350 kA aluminum reduction cell based electric field model was developed by finite element method to evaluate the effect of the method. Suggestions on selection of three modes were also put forward. The results show that the methods of resistance optimization can reduce the current variation about 180 A compared with that in original case. 展开更多
关键词 bus bar design aluminum reduction cell electric field finite element method
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Agitator tank device and drag reduction agent evaluation
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作者 张帆 肖博元 +1 位作者 汤养浩 罗旗荣 《Journal of Central South University》 SCIE EI CAS 2008年第S1期329-332,共4页
The device that consists of tank and disk agitator for evaluation drag reduction agents(DRA) was established.The effect of DRA was defined by testing the changes of agitator torque that drives the disk rotation.The HG... The device that consists of tank and disk agitator for evaluation drag reduction agents(DRA) was established.The effect of DRA was defined by testing the changes of agitator torque that drives the disk rotation.The HG-DRA for oil pipeline from Linyi to Puyang was studied by agitator tank device.The relationships between the drag reduction rate and Reynolds number,concentration,balance time were studied.The best concentration and the highest Renords number for the best drag reduction rate were confirmed.The results show that the drag reduction rate tested in agitator tank is close to that in pipeline.The maximum error of drag reduction rate between pipeline and agitator tank is 18.3%,which indicates that the agitator tank device is available to evaluate the effect of DRA for pipeline and it also has the advantages of simple,easy to be operated and using small volume of oil.Those are very helpful for operaters to know the properties of DRA and operate pipeline well. 展开更多
关键词 drag reduction AGITATION REYNOLDS NUMBER EVALUATION method
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Reinforcement strength reduction in FEM for mechanically stabilized earth structures
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作者 薛剑峰 陈建峰 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第7期2691-2698,共8页
The factor of safety of mechanically stabilized earth(MSE) structures can be analyzed either using limit equilibrium method(LEM) or strength reduction method(SRM) in finite element/difference method. In LEM, the stren... The factor of safety of mechanically stabilized earth(MSE) structures can be analyzed either using limit equilibrium method(LEM) or strength reduction method(SRM) in finite element/difference method. In LEM, the strengths of the reinforcement members and soils are reduced with the same factor. While using the SRM, only soil strength is reduced during the calculation of the factor of safety. This causes inconsistence in calculating the factor of safety of the MSE structures. To overcome this, an iteration method is proposed to consider the strength reduction of the reinforcements in SRM. The method is demonstrated by using PLAXIS, a finite element software. The results show that the factor of safety converges after a few iterations. The reduction of strength has different effects on the factor of safety depending on the properties of the reinforcements and the soil, and failure modes. 展开更多
关键词 mechanically stabilized earth structures factor of safety strength reduction method iterative method
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延性抗震设计理念的发展及应用研究综述 被引量:2
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作者 贾良玖 罗旭亮 +1 位作者 王立军 项平 《东南大学学报(自然科学版)》 北大核心 2025年第1期30-40,共11页
延性抗震设计旨在通过结构发生较大弹塑性变形来降低结构地震响应。这一抗震设计理念广泛应用于大多数国家抗震规范中,其核心思路是通过使用强度折减系数对设防地震反应谱进行折减,使结构通过非弹性变形耗散地震能量。强度折减系数主要... 延性抗震设计旨在通过结构发生较大弹塑性变形来降低结构地震响应。这一抗震设计理念广泛应用于大多数国家抗震规范中,其核心思路是通过使用强度折减系数对设防地震反应谱进行折减,使结构通过非弹性变形耗散地震能量。强度折减系数主要由延性折减系数和结构超强系数决定。同时,能力设计法是实现延性抗震的主要工具,该方法要求体系内的非延性构件在延性构件进入非线性阶段前后都保持弹性,以实现整个结构体系的延性设计。通过梳理延性抗震设计理念的研究历史,简要介绍了延性系数、结构周期、场地条件、阻尼比等因素对延性折减系数的影响,阐述了现有强度折减系数的组成和计算方法。最后,总结了中国、美国、欧洲、日本抗震规范中延性设计的应用情况。 展开更多
关键词 延性抗震设计 能力设计法 强度折减系数 延性折减系数 抗震设计规范
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地下结构排水盲沟减压抗浮简化设计方法
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作者 潘泓 刘荣照 +2 位作者 骆冠勇 彭斯格 曹洪 《岩土工程学报》 北大核心 2025年第4期685-694,共10页
目前,排水盲沟减压抗浮系统中排水盲沟设计主要采用数值法分析计算,尚无简单实用的简化计算方法。基于盲沟为等水头边界及入渗量均布于盲沟单元等假定,建立排水盲沟网格简化模型,得到平面布置为矩形的盲沟单元水头分布解析解,给出入渗... 目前,排水盲沟减压抗浮系统中排水盲沟设计主要采用数值法分析计算,尚无简单实用的简化计算方法。基于盲沟为等水头边界及入渗量均布于盲沟单元等假定,建立排水盲沟网格简化模型,得到平面布置为矩形的盲沟单元水头分布解析解,给出入渗量、单元几何尺寸等参数即可算得盲沟单元内水头分布。提出均匀入渗和非均匀入渗情况下底板入渗量分布的计算模式。通过算例验证,简化方法适用前提为盲沟及结构底板底部布置有渗透性远大于土体的疏水层,简化算法与有限元结果的相对误差较小且结果偏于保守,可用于盲沟布置的设计。对典型土层算例对比发现:若底板下部地层为弱透水层中夹有一层强透水层,底板入渗量会均匀分布,盲沟可等间距均匀布置;若下部地层无强透水层,入渗量大部分集中在距帷幕1倍~1.5倍坑底含水层厚度范围内,盲沟间距应在该范围内减小,在底板中部增大。 展开更多
关键词 抗浮 排水减压 排水盲沟 渗流 简化方法
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精密微动缩小机构设计与刚度分析
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作者 杨满芝 王悦 +3 位作者 张晓栋 张传伟 韩飞燕 冯斌 《农业机械学报》 北大核心 2025年第3期531-538,共8页
精密微动缩小机构能够提供较小空间内精密运动位移,可广泛应用于微电子、医疗器械和芯片封装等精密操作领域。本文基于柔性铰链杠杆原理和无附加运动原理设计一种精密微动缩小机构,该机构能够将输入位移按照2∶1精密缩小,且在运动过程... 精密微动缩小机构能够提供较小空间内精密运动位移,可广泛应用于微电子、医疗器械和芯片封装等精密操作领域。本文基于柔性铰链杠杆原理和无附加运动原理设计一种精密微动缩小机构,该机构能够将输入位移按照2∶1精密缩小,且在运动过程中无附加力及位移。通过等效刚度法对所设计的精密微动缩小机构进行刚度分析,计算得到该机构理论刚度为75.72 N/μm;采用有限元法分析得到精密微动缩小机构刚度为74.06 N/μm;采用实验法测得到精密微动缩小机构刚度为68.86 N/μm。理论分析结果与有限元分析结果误差为2.19%,理论分析结果与实验结果误差为9.06%,分析结果验证了等效刚度法分析方法的有效性及精确性。研究结果对精密微动机构设计及刚度分析具有重要的理论参考价值。 展开更多
关键词 微动缩小机构 刚度分析 等效刚度法 杠杆原理
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碳化硅原料粉体制备的研究进展
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作者 冯东 刘悦 +3 位作者 丁国强 茹红强 罗旭东 游杰刚 《航空制造技术》 北大核心 2025年第3期92-101,共10页
碳化硅(SiC)材料因具有优异的物理化学性能,已被广泛应用于航空航天、工程陶瓷和半导体等领域。目前,SiC粉体的合成方法众多,其中碳热还原法是工业生产SiC粉体的主要方法,但在生产过程中,SiC粉体的颗粒度和杂质含量均会影响最终产物的... 碳化硅(SiC)材料因具有优异的物理化学性能,已被广泛应用于航空航天、工程陶瓷和半导体等领域。目前,SiC粉体的合成方法众多,其中碳热还原法是工业生产SiC粉体的主要方法,但在生产过程中,SiC粉体的颗粒度和杂质含量均会影响最终产物的各项性能。因此,如何对SiC粉体进行细化和纯化处理成为制备高性能SiC材料需要探索的问题。本文首先介绍了SiC粉体合成技术的种类、原理和特点;然后,详细阐述了近年来SiC粉体细化技术的研究进展,并对SiC粉体中无定形碳和金属及金属氧化物的纯化技术进行重点介绍;最后分析了目前制备SiC粉体需要解决的问题,并对其发展前景进行展望。 展开更多
关键词 碳化硅(SiC)粉体 SiC合成 碳热还原法 粉体细化 粉体纯化
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红土镍矿碳热还原制备负载型铁镍双金属及其活化过硫酸盐去除四环素研究
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作者 陈江安 黄金秋 +1 位作者 万志豪 余文 《有色金属(中英文)》 北大核心 2025年第8期1430-1438,共9页
以红土镍矿和无烟煤为原料,利用碳热还原法制备硅酸盐负载铁镍双金属材料(SiO_(2)@Fe-Ni),并将其用于活化过硫酸盐(PS)去除四环素。首先利用X射线衍射仪、扫描电子显微镜和能谱分析仪对SiO_(2)@Fe-Ni进行表征,结果表明,SiO_(2)@Fe-Ni中... 以红土镍矿和无烟煤为原料,利用碳热还原法制备硅酸盐负载铁镍双金属材料(SiO_(2)@Fe-Ni),并将其用于活化过硫酸盐(PS)去除四环素。首先利用X射线衍射仪、扫描电子显微镜和能谱分析仪对SiO_(2)@Fe-Ni进行表征,结果表明,SiO_(2)@Fe-Ni中主要物相为铁纹石、镍纹石、石英、镁铁橄榄石等,Fe-Ni合金颗粒尺寸呈微纳米尺度(数十至数百纳米),且均匀分散在硅酸盐矿物表面。研究了反应条件对SiO_(2)@Fe-Ni/PS体系去除四环素的影响,结果表明,在溶液温度为30℃、SiO_(2)@Fe-Ni用量0.2 g/L、溶液初始pH值7.3、PS用量2 mM、四环素初始浓度为50 mg/L的条件下,60 min后四环素去除率达到68 36%。对活性自由基种类进行鉴定,并阐述其产生以及作用机理,结果表明,SiO_(2)@Fe-Ni/PS体系中硫酸根自由基(SO_(4)^(-)·)和羟基自由基(·OH)均存在,且·OH是主要的活性自由基;SO_(4)^(-)·的产生是通过材料表面的Fe^(2+)和Ni^(2+)活化PS得来的,·OH是通过SO_(4)^(-)·与溶液中的H_(2)O或OH^(-)反应生成的。总有机碳分析仪结果表明四环素矿化率60 24%。 展开更多
关键词 红土镍矿 碳热还原法 铁镍双金属 过硫酸盐 四环素
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基于最远点法的Q355含裂纹损伤钢构件屈服强度折减系数法研究
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作者 昌毅 李英豪 +3 位作者 马东杰 吴仁彬 邱森贵 李革新 《塑性工程学报》 北大核心 2025年第9期227-234,共8页
以Q355钢的含裂纹损伤钢构件为研究对象,通过试验和最远点法对比分析,探究含裂纹损伤钢构件屈服强度的变化规律,并分析了试验和最远点法计算含裂纹损伤钢构件屈服强度的不足。在最远点法的基础上,考虑裂纹对Q355含裂纹损伤钢构件屈服强... 以Q355钢的含裂纹损伤钢构件为研究对象,通过试验和最远点法对比分析,探究含裂纹损伤钢构件屈服强度的变化规律,并分析了试验和最远点法计算含裂纹损伤钢构件屈服强度的不足。在最远点法的基础上,考虑裂纹对Q355含裂纹损伤钢构件屈服强度的影响,通过引入折减系数,提出了基于最远点法的折减系数法来评价此类含裂纹损伤钢构件的屈服强度。结果表明:随着相对裂纹长度的逐渐增大,折减系数逐渐减小,变化速率逐渐增大。在相对裂纹长度一定时,随着裂纹角度的增大,折减系数逐渐减小,变化速率逐渐减小。综上,针对Q355钢含裂纹损伤钢构件的屈服强度,本文所提出方法具有较高精度,与试验结果相比屈服强度的最大误差为5.72%,平均误差为2.25%。 展开更多
关键词 裂纹损伤 钢构件 屈服强度 最远点法 折减系数法
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基于LCA的温拌再生融合技术节能减排效果分析
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作者 杨彦海 时铭阳 +1 位作者 杨野 金鑫 《重庆交通大学学报(自然科学版)》 北大核心 2025年第4期52-57,共6页
为了准确评估温拌再生融合技术的环境效益,基于生命周期法确定路面建设期间环境效益的边界范围,建立碳排放计算模型。通过现场调查及数据分析,运用模型分别计算温拌再生技术与热拌技术的能耗及温室气体排放。最终对比分析了温拌再生融... 为了准确评估温拌再生融合技术的环境效益,基于生命周期法确定路面建设期间环境效益的边界范围,建立碳排放计算模型。通过现场调查及数据分析,运用模型分别计算温拌再生技术与热拌技术的能耗及温室气体排放。最终对比分析了温拌再生融合技术的节能减排效益。结果表明:温拌再生路面施工过程中,原材料生产能耗324.47 MJ,温室气体排放为19.65 kg CO_(2e),混合料拌和能耗为217.28 MJ,温室气体排放为18.15 kg CO_(2e)。与热拌技术相比,温拌再生融合技术在混合料拌和阶段能耗和温室气体排放都有减少,RAP掺量为40%时,温拌再生路面建设期能耗节约33.33%,CO_(2)排放降低20.11%。 展开更多
关键词 道路工程 生命周期分析法 温拌再生融合技术 节能减排 温室气体
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绿色金融如何实现城市减污降碳协同推进——基于绿色金融改革创新试验区的经验证据
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作者 张超 胡宗光 《商业研究》 北大核心 2025年第2期51-62,共12页
协同推进减污降碳是实现绿色发展的关键举措,而加强金融支持是其中的重要保障。本文通过构建一般均衡模型,系统阐释了绿色金融与减污降碳之间的理论关系,并基于2011—2022年中国281个城市的面板数据,运用渐进双重差分模型实证考察了绿... 协同推进减污降碳是实现绿色发展的关键举措,而加强金融支持是其中的重要保障。本文通过构建一般均衡模型,系统阐释了绿色金融与减污降碳之间的理论关系,并基于2011—2022年中国281个城市的面板数据,运用渐进双重差分模型实证考察了绿色金融改革创新试验区政策对城市减污降碳的影响效应及其作用机制。研究发现,试验区政策显著促进了城市减污降碳进程,且这一效应在资源型城市、“胡焕庸线”西北部城市以及非城市群城市中表现更为突出。机制分析发现,试验区政策通过缓解融资约束和推动技术进步两个渠道促进城市减污降碳,但微观层面的作用效果仅对污染行业产生显著影响。空间计量分析表明,试验区政策的减污降碳效应在考虑空间因素后得到明显提升,但尚未形成对周边城市的空间溢出效应。 展开更多
关键词 绿色金融改革创新试验区 减污降碳 一般均衡模型 双重差分法 溢出效应
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