In this study,thyme essential oil(TEO)nanoemulsion(tPTNs)was constructed with transglutaminase(TGase)-modified potato protein,and its antibacterial activity and mechanism of action were evaluated and explored.Results ...In this study,thyme essential oil(TEO)nanoemulsion(tPTNs)was constructed with transglutaminase(TGase)-modified potato protein,and its antibacterial activity and mechanism of action were evaluated and explored.Results indicated that tPTNs exhibited great antibacterial activity against both Staphylococcus aureus and Escherichia coli,with minimal inhibitory concentration(MIC)and minimum bactericidal concentration(MBC)of 2.5 and 5.0 mg/mL,respectively.Also,the antibacterial effects of tPTNs were concentration-dependent.We observed a significant decrease in the absolute value of the zeta potential,and significant increases in particle size,cell membrane hydrophobicity,conductivity,the release of metal ions,and the leakage of nucleic acid as the concentration of tPTNs increased from 0 mg/mL to MBC.Furthermore,sodium dodecyl sulphate-polyacrylamide gel electrophoresis(SDS-PAGE)demonstrated that protein synthesis was inhibited or even disrupted.Analysis by liquid chromatography-mass spectrometry(LC-MS)indicated that treatment with tPTNs caused significant changes in bacterial metabolites,1117 and 692 differential metabolites being found for S.aureus and E.coli,respectively.The differential metabolites were involved in nucleotide metabolism,amino acid metabolism,tricarboxylic acid cycle and other metabolic pathways.These findings provide valuable insights for the application of thyme essential oil as an efficient antibacterial agent and for the understanding of its mechanism of action.展开更多
Cyperus esculentus root oil(CEL)is a plant of significant economic value,rich in unsaturated fatty acids like oleic acid,linoleic acid,and linolenic acid.In this study,human dermal fibroblasts(HSF)were used to create ...Cyperus esculentus root oil(CEL)is a plant of significant economic value,rich in unsaturated fatty acids like oleic acid,linoleic acid,and linolenic acid.In this study,human dermal fibroblasts(HSF)were used to create an inflammatory model,and the impact of coldpressed oil from CEL on the secretion of inflammatory factors was assessed.The results showed that CEL significantly inhibited IL-6 and IL-1βthat were secreted by HSF cells induced by tumor necrosis factor-α(TNF-α)(P<0.0001),with inhibition rates of 50.79%and 20.26%,respectively.Furthermore,CEL markedly enhanced the secretion of the anti-inflammatory factor IL-10(P<0.01),with an improvement rate of 94.42%.The study further explored the impact of CEL on collagen type I(Col-I)and hyaluronic acid(HA)secretion in the cells.The results demonstrated that CEL effectively increased Col-I secretion by 26.15%(P<0.0001)and HA by 30.2%(P<0.0001)when it was administered at a maximum safe mass fraction of 6%,which consequently showed its potential anti-aging and moisturizing properties.Additionally,fluorescence real-time quantitative polymerase chain reaction(PCR)experiments confirmed that CEL significantly inhibited the TNF-α-induced expression of IL-6,IL-1β,and matrix metalloproteinases(MMP-1,3,9)in HSF cells,while promoted the mRNA expression levels of IL-10 and hyaluronic acid synthase.This modulation suggested that CEL exerted anti-inflammatory and anti-aging effects.Finally,the oil’s anti-inflammatory,anti-senility,and moisturizing effects were validated through the clinical evaluations.In summary,CEL,as a natural raw material abundant in unsaturated fatty acids,shows promising potential for further development and usage in cosmetics due to its anti-inflammatory,anti-aging,and moisturizing properties in personal care.展开更多
Needle coke,a highperformance artificial carbon material,requires precise composition control of its raw materials as this critically determines the structural characteristics and performance of the final product.In t...Needle coke,a highperformance artificial carbon material,requires precise composition control of its raw materials as this critically determines the structural characteristics and performance of the final product.In this study,needle coke samples were prepared from coal direct liquefaction pitch(CDLP)and waste engine oil(WEO)through component optimization and a cocarbonization process.The microstructure and properties were investigated using the following characterization techniques:Fourier Transform Infrared Spectroscopy(FT-IR),Polarized Light Microscopy(PLM),Scanning Electron Microscopy(SEM),X-ray Diffraction(XRD),Raman Spectroscopy,Thermogravimetric Analysis(TGA),Micro-Strength(MS)and Powder Resistivity(PR).The co-carbonization mechanism of CDLP and WEO was systematically investigated.The results indicated that the incorporation of WEO significantly reduced the viscosity of the co-carbonization system,and its abundant aliphatic structures provided alkyl radicals and active sites.The synergistic interaction of aromatic components between the CDLP and WEO effectively promoted the growth and order accumulation of aromatic carbon layers.When 50%WEO was introduced,the prepared needle coke exhibited an excellent microstructure and properties.The fibrous and leaflet structure content reached 76.2%,the ideal graphite lattice content reached 89.7%.These results demonstrated remarkable oxidation resistance and electrical conductivity,with a powder resistivity of 605.1 mΩ·mm.This work establishes a process with cost advantages for the production of needle coke.展开更多
For the quantitative analysis of lube oil base oil components,three oil components,mineral oil(KN4010),hydrocarbon-based synthetic oil(PAO40),and synthetic ester(PriEco 3000)were selected as quantitative analysis obje...For the quantitative analysis of lube oil base oil components,three oil components,mineral oil(KN4010),hydrocarbon-based synthetic oil(PAO40),and synthetic ester(PriEco 3000)were selected as quantitative analysis objects,and then the mid-infrared spectral data of lube oil base oil samples formulated in different ratios were collected.The synergy interval partial least squares-binary grey wolf optimization algorithm(SiPLS-BGWO)combination optimization method was used to screen the characteristic wavenumbers in the full range to eliminate redundant invalid information and reduce the search space dimension.By optimizing the selection of characteristic wavenumbers,the SiPLS-BGWO approach not only enhanced the prediction accuracy but also demonstrated its ability to address challenges associated with overlapping spectral features in complex mixtures.The test results showed that the combined optimization model’s error indexes were significantly improved for the content prediction of mineral oil,hydrocarbonbased synthetic oil,and polyol ester.The RMSE(root mean square error)was reduced by up to 60.58% compared to using all spectral wavenumbers,and the fit indexes’R^(2) values were higher than 99%.The significant reduction in RMSE underscored the method’s capability to identify and eliminate irrelevant or noisy spectral information,ensuring that the predictive model focused only on relevant features.In addition,the SiPLS-BGWO method had reduced the number of characteristic wavenumbers to less than 40,significantly reducing the operational burden and effectively improving the accuracy and applicability of the quantitative analysis model for multi-matter components.The ability to reduce the number of characteristic wavenumbers to below 40 demonstrated the algorithm’s efficiency in dimensionality reduction while retaining essential predictive information.The results affirmed that the SiPLS-BGWO model was a powerful tool for predictive modeling,providing a balance between accuracy and efficiency in the quantitative analysis of multicomponent systems.And a novel framework for bridging the gap between spectral data complexity and actionable chemical insights,setting a precedent for future developments in the field.展开更多
The oblique transfer zone in the Fushan Sag, a syndepositional dome sandwiched between the Bailian and Huangtong sub-sags, has been the most important exploration target. The major oil observation occurs in the E_2l_1...The oblique transfer zone in the Fushan Sag, a syndepositional dome sandwiched between the Bailian and Huangtong sub-sags, has been the most important exploration target. The major oil observation occurs in the E_2l_1^(L+M) and the E_2l_3~U. 46 oil and rock samples reveal that the oil in the transfer zone is mostly contributed by the Bailian sub-sag, though the source rock conditions, hydrocarbon generation and expulsion histories of the Bailian and Huangtong sub-sags are similar. The E_2l_3~U oil, characterized by high maturity, Pr/Ph ratio and oleanane/C_(30)-hopane ratio, shows a close genetic affinity with the E_2l_3~b source rocks, while the E_2l_1^(L+M) oil, characterized by lower maturity, Pr/Ph ratio and oleanane/C_(30)-hopane ratio, is suggested to be derived from the E_2l_(1+2)~b source rocks. The homogenization temperatures of aqueous fluid inclusions, taking the burial history of the reservoirs into account, reflect that the oil charge mainly occurred from mid-Miocene to Pliocene in the oblique transfer zone. The oil transporting passages include connected sand bodies, unconformities and faults in the Fushan Sag. Of these, the faults are the most complicated and significant. The faults differ sharply in the west area, the east area and the oblique transfer zone, resulting in different influence on the oil migration and accumulation. During the main hydrocarbon charge stage, the faults in the west area are characterized by bad vertical sealing and spatially dense distribution. As a result, the oil generated by the Huangtong source rocks is mostly lost along the faults during the vertical migration in the west area. This can be the mechanism proposed to explain the little contribution of the Huangtong source rocks to the oil in the oblique transfer zone. Eventually, an oil migration and accumulation model is built in the oblique transfer zone, which may provide theoretical and practical guides for the oil exploration.展开更多
Engineering property of kaolin clay contaminated by diesel oil was studied through a series of laboratory experiments.Oil contents(mass fraction) of 4%,8%,12%,16% and 20% were selected to represent different contamina...Engineering property of kaolin clay contaminated by diesel oil was studied through a series of laboratory experiments.Oil contents(mass fraction) of 4%,8%,12%,16% and 20% were selected to represent different contamination degrees,and the soil specimens were manually prepared through mixing and static compaction method.Initial water content and dry density of the test kaolin clay were controlled at 10% and 1.58 g/cm^3,respectively.Test results indicate that since part of the diesel oil will be released from soil by evaporation,the real water content should be derived through calibration of the quasi water content obtained by traditional test method.As contamination degree of the kaolin clay increases,both liquid limit and plastic limit decrease,but there's only a slight increase for plasticity index.Swelling pressure of contaminated kaolin clay under confined condition will be lowered when oil-content gets higher.Unconfined compressive strength(UCS) of the oil-contaminated kaolin clay is influenced by not only oil content but also curing period.Increase of contamination degree will continually lower UCS of the kaolin clay specimen.In addition,electrical resistivity of the contaminated kaolin clay with given water content decreases with the increase of oil content.However,soil resistivity is in good relationship with oil content and UCS.Finally,oil content of 8% is found to be a critical value for engineering property of kaolin clay to transit from water-dominated towards oil-dominated characteristics.展开更多
Water alternating gas(WAG)injection is a widely used strategy for enhancing oil recovery(EOR)during gas flooding,and the mechanisms,operating parameters,and influencing factors of which have been extensively studied.H...Water alternating gas(WAG)injection is a widely used strategy for enhancing oil recovery(EOR)during gas flooding,and the mechanisms,operating parameters,and influencing factors of which have been extensively studied.However,with respect to its capacity in expanding macroscopic sweep volume under varying heterogeneities,the related results appear inadequate.In this research,three cores with different heterogeneities were used and flooded by the joint water and CO_(2) WAG,then the effects of heterogeneity on oil recovery were determined.More importantly,the cores after CO_(2) WAG injection were investigated using the nuclear magnetic resonance(NMR)technique for remaining oil distribution research,which could help us to understand the capacity of CO_(2) WAG in enlarging sweep volume at different heterogeneities.The results show that the presence of heterogeneity may largely weaken the effectiveness of water flooding,the more severe the heterogeneity,the worse the water flooding.The WAG injection of CO_(2) performs well in EOR after water flooding for all the cores with different heterogeneities;however,it could barely form a complete or full sweep throughout the low-permeability region,and un-swept bypassed regions remain.The homogeneous core is better developed by the injection of the joint water and CO_(2) WAG than the heterogeneous and fractured cases.展开更多
For the purpose of improving efficiency and realizing start–stop function, an electric oil pump(EOP) is integrated into an 8-speed automatic transmission(AT). A mathematical model is built to calculate the transmissi...For the purpose of improving efficiency and realizing start–stop function, an electric oil pump(EOP) is integrated into an 8-speed automatic transmission(AT). A mathematical model is built to calculate the transmission power loss and the hydraulic system leakage. Based on this model, a flow-based control strategy is developed for EOP to satisfy the system flow requirement. This control strategy is verified through the forward driving simulation. The results indicate that there is a best combination for the size of mechanical oil pump(MOP) and EOP in terms of minimum energy consumption. In order to get a quick and smooth starting process, control strategies of the EOP and the on-coming clutch are proposed. The test environment on a prototype vehicle is built to verify the feasibility of the integrated EOP and its control strategies. The results show that the selected EOP can satisfy the flow requirement and a quick and smooth starting performance is achieved in the start–stop function. This research has a high value for the forward design of EOP in automatic transmissions with respect to efficiency improvement and start–stop function.展开更多
Soybean is generally recognized as a source of edible and the deoiled meal is seen as a source of protein in animal feed.In recent years.However,more interest has been directed toward using soy meal as a protein souce...Soybean is generally recognized as a source of edible and the deoiled meal is seen as a source of protein in animal feed.In recent years.However,more interest has been directed toward using soy meal as a protein souce for human consumption.Extrusion expelling of soybean provides an opportunity in this direction.The main focus of this study was to maximize the oil recovery from extruded soybean processed using three different kinds of extrudates and processing conditions.These extruded samples were later pressed uniaxially in a specifically designed test cell and the oil recovery was recorded over time.The effects of process variables,including applied pressure,pressing temperature and sample height,were investigated.Results indicated that over90% of the available oil could be recovered from pressing of extruded soy samples.The information generated is likedly to be useful in interpreting the effect of precess variables and extruding equipment for pretreatment of soybean for subsequent mechanical oil expression.展开更多
In order to solve the failure of fuel system when using petroleum coke oil slurry (PCOS) in a R180 diesel engine directly,a petroleum coke oil slurry fuel system (PCOSFS) was developed and installed in R180 engine,whi...In order to solve the failure of fuel system when using petroleum coke oil slurry (PCOS) in a R180 diesel engine directly,a petroleum coke oil slurry fuel system (PCOSFS) was developed and installed in R180 engine,which was called PCOS engine.In order to analyze performances and emissions of the PCOS engine,a comparative experiment between PCOS engine fueled with PCOS and R180 engine fueled with diesel oil was carried out.The results show that the PCOS engine can run smoothly,the maximum output power decreases by about 6.2% and 19.0% and the maximum brake thermal efficiency reduces by around 5.85% and 4.13% as compared to R180 engine under the conditions of 1 200 and 1 600 r/min.The HC emissions of PCOS engine are lower than those of R180 engine at 1 200 r/min,and are close to those of R180 engine at 1 600 r/min.The CO emissions are similar to R180 engine at 1 200 and 1 600 r/min.The smoke intensity is close to R180 engine at 1 200 r/min,and is higher than R180 engine at 1 600 r/min.The particles emitted from PCOS engine array sparsely,but particles emitted from R180 engine array closely,cohering together.展开更多
The effects of soil texture, initial water content and bulk density on diesel oil infiltration in fine sand and silty clay loam materials were evaluated. Three physical and two empirical equations express diesel oil i...The effects of soil texture, initial water content and bulk density on diesel oil infiltration in fine sand and silty clay loam materials were evaluated. Three physical and two empirical equations express diesel oil infiltration through soils with time, with coefficients of determination greater than 0.99. Diesel oil infiltrates more quickly in the fine sand than in the silty clay loam material. Diesel oil infiltration rates are found to decrease with increasing initial water content and bulk density for the silty clay loam material. The infiltration rate of diesel oil in the fine sand material increases slightly with increasing initial water content. The diesel oil saturated conductivity(Kdiesel) decreases with increasing bulk density for the silty clay loam column. Diesel oil sorptivity(S) decreases linearly with increased initial water content and bulk density of the silty clay loam material. Changes in empirical parameters relative to initial water content and bulk density are similar to the parameter S.展开更多
It's not easy for traditional standards such as STEP to describe product information in a semantic way, andthese limitations result in difficulties in knowledge-based product information integration. In addition, ...It's not easy for traditional standards such as STEP to describe product information in a semantic way, andthese limitations result in difficulties in knowledge-based product information integration. In addition, contemporarycomputing environment needs a Web-based language to describe product information, while STEP standard and itsEXPRESS language have no such features however. The development of Semantic Web is making itself be an impor-tant method to facilitate the knowledge-based information integration. This paper presents a new semantic Web lan-guage, DAML+OIL, and tries to use it to describe product information. It is proved that using DAML+OIL to de-scribe product information is quite a feasible way.展开更多
Nano-copper used as lubrication oil additive has good tribological property and active self-repairing effect for friction pairs. The reduction in liquid phase for preparing nano-additive is one of the most common meth...Nano-copper used as lubrication oil additive has good tribological property and active self-repairing effect for friction pairs. The reduction in liquid phase for preparing nano-additive is one of the most common method. Nano-copper was prepared by reduction in liquid phase. The different project and routine practice for preparing nano-copper were researched. The dispersion problem of nano-copper was investigated by surface treatment and high dispersion. The particles dimension, the dispersion stability and the purity of nano-copper were characterized by TEM and XRD. The conclusion indicates that the methods of the preparation and dispersion can obtain 20nm copper additive with good dispersion property in lubrication oil.展开更多
The composition of a collector directly affects its collecting performance in mineral flotation.In this study,three vegetable oils were used as the collectors,the flotation performance of scheelite and the differentia...The composition of a collector directly affects its collecting performance in mineral flotation.In this study,three vegetable oils were used as the collectors,the flotation performance of scheelite and the differential analysis were studied through flotation experiments,zeta potential,contact angle measurement and Fourier transform infrared spectrum(FTIR)analysis.Flotation results show that the recovery of scheelite increases in the order of oleic acid<rapeseed oil<rice bran oil<soybean oil,especially in the pH range of 5-8.The distinction in the scheelite recovery is due to the different compositions of these collectors.The addition of LA,LNA and PA(<5%)can increase the recovery of scheelite with OA,but the addition of SA deteriorates the scheelite flotation.Results of zeta potential,contact angle measurement and FTIR analysis indicate that the collector adsorption on scheelite surface is enhanced when using the three vegetable oils.For the raw ore with 0.086%WO3,a rough concentrate containing 1.423%WO3 with the recovery of 84.22%is obtained using soybean oil as the collector.展开更多
Through using mineral oil and synthetic oil to deploy the semisynthesis base oil, modifying the surfaces of ultrafine tungsten disulfide grains by surface chemical embellishment and adsorption embellishment to make th...Through using mineral oil and synthetic oil to deploy the semisynthesis base oil, modifying the surfaces of ultrafine tungsten disulfide grains by surface chemical embellishment and adsorption embellishment to make them suspended steadily in the base oil as solid lubricating additive, and adding some function additives, the tungsten disulfide motor oil was prepared. The tribological characteristics of this kind motor oil and the well-known motor oils in our country and overseas were studied. The results show that the oil film strength of this kind of motor oil is respectively 1.06 and 1.38 times of that of shell helix ultra motor oil and great wall motor oil, and its sintering load is 1.75 and 2.33 times of that of them, and when tested under 392 N, 1 450 r/rain and 30 min, the friction coefficients of friction pairs lubricated by the tungsten disulfide motor oil decrease with the increase of time, meanwhile, the diameter of worn spot is small, and the surface of worn spot is smooth, and no obvious furrows appear. The experiments indicate that the tungsten disulfide motor oil has the better antiwear, antifriction and extreme pressure properties than the well-known motor oils.展开更多
The relationships among compression ratio and stress, compression ratio and residual oil of cake in pressing process of castor beans were studied using the test equipment under different states of oilseeds and ways of...The relationships among compression ratio and stress, compression ratio and residual oil of cake in pressing process of castor beans were studied using the test equipment under different states of oilseeds and ways of pressing manners. The results show that variation of stress increases nonlinearly and residual oil rate decreases with the increase of compression ratio. Lower residual oil of cake was obtained by pressing gently and frequently. Curve fitting on both relationships had been built and parameters for the model were obtained by least square procedure and deepening research on pressing process of the castor beans for castor oil. By assuming that the value of oil production is equivalent to the value of energy consumption, the critical compression ratio of intact seeds is 6.2 while that of crushed seeds is 3.6.展开更多
文摘In this study,thyme essential oil(TEO)nanoemulsion(tPTNs)was constructed with transglutaminase(TGase)-modified potato protein,and its antibacterial activity and mechanism of action were evaluated and explored.Results indicated that tPTNs exhibited great antibacterial activity against both Staphylococcus aureus and Escherichia coli,with minimal inhibitory concentration(MIC)and minimum bactericidal concentration(MBC)of 2.5 and 5.0 mg/mL,respectively.Also,the antibacterial effects of tPTNs were concentration-dependent.We observed a significant decrease in the absolute value of the zeta potential,and significant increases in particle size,cell membrane hydrophobicity,conductivity,the release of metal ions,and the leakage of nucleic acid as the concentration of tPTNs increased from 0 mg/mL to MBC.Furthermore,sodium dodecyl sulphate-polyacrylamide gel electrophoresis(SDS-PAGE)demonstrated that protein synthesis was inhibited or even disrupted.Analysis by liquid chromatography-mass spectrometry(LC-MS)indicated that treatment with tPTNs caused significant changes in bacterial metabolites,1117 and 692 differential metabolites being found for S.aureus and E.coli,respectively.The differential metabolites were involved in nucleotide metabolism,amino acid metabolism,tricarboxylic acid cycle and other metabolic pathways.These findings provide valuable insights for the application of thyme essential oil as an efficient antibacterial agent and for the understanding of its mechanism of action.
文摘Cyperus esculentus root oil(CEL)is a plant of significant economic value,rich in unsaturated fatty acids like oleic acid,linoleic acid,and linolenic acid.In this study,human dermal fibroblasts(HSF)were used to create an inflammatory model,and the impact of coldpressed oil from CEL on the secretion of inflammatory factors was assessed.The results showed that CEL significantly inhibited IL-6 and IL-1βthat were secreted by HSF cells induced by tumor necrosis factor-α(TNF-α)(P<0.0001),with inhibition rates of 50.79%and 20.26%,respectively.Furthermore,CEL markedly enhanced the secretion of the anti-inflammatory factor IL-10(P<0.01),with an improvement rate of 94.42%.The study further explored the impact of CEL on collagen type I(Col-I)and hyaluronic acid(HA)secretion in the cells.The results demonstrated that CEL effectively increased Col-I secretion by 26.15%(P<0.0001)and HA by 30.2%(P<0.0001)when it was administered at a maximum safe mass fraction of 6%,which consequently showed its potential anti-aging and moisturizing properties.Additionally,fluorescence real-time quantitative polymerase chain reaction(PCR)experiments confirmed that CEL significantly inhibited the TNF-α-induced expression of IL-6,IL-1β,and matrix metalloproteinases(MMP-1,3,9)in HSF cells,while promoted the mRNA expression levels of IL-10 and hyaluronic acid synthase.This modulation suggested that CEL exerted anti-inflammatory and anti-aging effects.Finally,the oil’s anti-inflammatory,anti-senility,and moisturizing effects were validated through the clinical evaluations.In summary,CEL,as a natural raw material abundant in unsaturated fatty acids,shows promising potential for further development and usage in cosmetics due to its anti-inflammatory,anti-aging,and moisturizing properties in personal care.
基金Supported by the National Natural Science Foundation of China(22208138)the Nature Science Foundation of Liaoning Province(2024-MS-179)the Fundamental Research Funds for the Liaoning Universities(LJ222410146051,LJ212410146018).
文摘Needle coke,a highperformance artificial carbon material,requires precise composition control of its raw materials as this critically determines the structural characteristics and performance of the final product.In this study,needle coke samples were prepared from coal direct liquefaction pitch(CDLP)and waste engine oil(WEO)through component optimization and a cocarbonization process.The microstructure and properties were investigated using the following characterization techniques:Fourier Transform Infrared Spectroscopy(FT-IR),Polarized Light Microscopy(PLM),Scanning Electron Microscopy(SEM),X-ray Diffraction(XRD),Raman Spectroscopy,Thermogravimetric Analysis(TGA),Micro-Strength(MS)and Powder Resistivity(PR).The co-carbonization mechanism of CDLP and WEO was systematically investigated.The results indicated that the incorporation of WEO significantly reduced the viscosity of the co-carbonization system,and its abundant aliphatic structures provided alkyl radicals and active sites.The synergistic interaction of aromatic components between the CDLP and WEO effectively promoted the growth and order accumulation of aromatic carbon layers.When 50%WEO was introduced,the prepared needle coke exhibited an excellent microstructure and properties.The fibrous and leaflet structure content reached 76.2%,the ideal graphite lattice content reached 89.7%.These results demonstrated remarkable oxidation resistance and electrical conductivity,with a powder resistivity of 605.1 mΩ·mm.This work establishes a process with cost advantages for the production of needle coke.
文摘For the quantitative analysis of lube oil base oil components,three oil components,mineral oil(KN4010),hydrocarbon-based synthetic oil(PAO40),and synthetic ester(PriEco 3000)were selected as quantitative analysis objects,and then the mid-infrared spectral data of lube oil base oil samples formulated in different ratios were collected.The synergy interval partial least squares-binary grey wolf optimization algorithm(SiPLS-BGWO)combination optimization method was used to screen the characteristic wavenumbers in the full range to eliminate redundant invalid information and reduce the search space dimension.By optimizing the selection of characteristic wavenumbers,the SiPLS-BGWO approach not only enhanced the prediction accuracy but also demonstrated its ability to address challenges associated with overlapping spectral features in complex mixtures.The test results showed that the combined optimization model’s error indexes were significantly improved for the content prediction of mineral oil,hydrocarbonbased synthetic oil,and polyol ester.The RMSE(root mean square error)was reduced by up to 60.58% compared to using all spectral wavenumbers,and the fit indexes’R^(2) values were higher than 99%.The significant reduction in RMSE underscored the method’s capability to identify and eliminate irrelevant or noisy spectral information,ensuring that the predictive model focused only on relevant features.In addition,the SiPLS-BGWO method had reduced the number of characteristic wavenumbers to less than 40,significantly reducing the operational burden and effectively improving the accuracy and applicability of the quantitative analysis model for multi-matter components.The ability to reduce the number of characteristic wavenumbers to below 40 demonstrated the algorithm’s efficiency in dimensionality reduction while retaining essential predictive information.The results affirmed that the SiPLS-BGWO model was a powerful tool for predictive modeling,providing a balance between accuracy and efficiency in the quantitative analysis of multicomponent systems.And a novel framework for bridging the gap between spectral data complexity and actionable chemical insights,setting a precedent for future developments in the field.
基金Project(41272122)supported by the National Natural Science Foundation of China
文摘The oblique transfer zone in the Fushan Sag, a syndepositional dome sandwiched between the Bailian and Huangtong sub-sags, has been the most important exploration target. The major oil observation occurs in the E_2l_1^(L+M) and the E_2l_3~U. 46 oil and rock samples reveal that the oil in the transfer zone is mostly contributed by the Bailian sub-sag, though the source rock conditions, hydrocarbon generation and expulsion histories of the Bailian and Huangtong sub-sags are similar. The E_2l_3~U oil, characterized by high maturity, Pr/Ph ratio and oleanane/C_(30)-hopane ratio, shows a close genetic affinity with the E_2l_3~b source rocks, while the E_2l_1^(L+M) oil, characterized by lower maturity, Pr/Ph ratio and oleanane/C_(30)-hopane ratio, is suggested to be derived from the E_2l_(1+2)~b source rocks. The homogenization temperatures of aqueous fluid inclusions, taking the burial history of the reservoirs into account, reflect that the oil charge mainly occurred from mid-Miocene to Pliocene in the oblique transfer zone. The oil transporting passages include connected sand bodies, unconformities and faults in the Fushan Sag. Of these, the faults are the most complicated and significant. The faults differ sharply in the west area, the east area and the oblique transfer zone, resulting in different influence on the oil migration and accumulation. During the main hydrocarbon charge stage, the faults in the west area are characterized by bad vertical sealing and spatially dense distribution. As a result, the oil generated by the Huangtong source rocks is mostly lost along the faults during the vertical migration in the west area. This can be the mechanism proposed to explain the little contribution of the Huangtong source rocks to the oil in the oblique transfer zone. Eventually, an oil migration and accumulation model is built in the oblique transfer zone, which may provide theoretical and practical guides for the oil exploration.
基金Projects(41330641,41272311,41202192)supported by the National Natural Science Foundation of ChinaProject(BK2010060)supported by the Key Project of Natural Science Foundation of Jiangsu Province,China
文摘Engineering property of kaolin clay contaminated by diesel oil was studied through a series of laboratory experiments.Oil contents(mass fraction) of 4%,8%,12%,16% and 20% were selected to represent different contamination degrees,and the soil specimens were manually prepared through mixing and static compaction method.Initial water content and dry density of the test kaolin clay were controlled at 10% and 1.58 g/cm^3,respectively.Test results indicate that since part of the diesel oil will be released from soil by evaporation,the real water content should be derived through calibration of the quasi water content obtained by traditional test method.As contamination degree of the kaolin clay increases,both liquid limit and plastic limit decrease,but there's only a slight increase for plasticity index.Swelling pressure of contaminated kaolin clay under confined condition will be lowered when oil-content gets higher.Unconfined compressive strength(UCS) of the oil-contaminated kaolin clay is influenced by not only oil content but also curing period.Increase of contamination degree will continually lower UCS of the kaolin clay specimen.In addition,electrical resistivity of the contaminated kaolin clay with given water content decreases with the increase of oil content.However,soil resistivity is in good relationship with oil content and UCS.Finally,oil content of 8% is found to be a critical value for engineering property of kaolin clay to transit from water-dominated towards oil-dominated characteristics.
基金Project(KFJJ-TZ-2019-3)supported by the Open Project of Shaanxi Key Laboratory of Advanced Stimulation Technology for Oil&Gas Reservoirs,ChinaProjects(51504275,51974344)supported by the National Natural Science Foundation of China。
文摘Water alternating gas(WAG)injection is a widely used strategy for enhancing oil recovery(EOR)during gas flooding,and the mechanisms,operating parameters,and influencing factors of which have been extensively studied.However,with respect to its capacity in expanding macroscopic sweep volume under varying heterogeneities,the related results appear inadequate.In this research,three cores with different heterogeneities were used and flooded by the joint water and CO_(2) WAG,then the effects of heterogeneity on oil recovery were determined.More importantly,the cores after CO_(2) WAG injection were investigated using the nuclear magnetic resonance(NMR)technique for remaining oil distribution research,which could help us to understand the capacity of CO_(2) WAG in enlarging sweep volume at different heterogeneities.The results show that the presence of heterogeneity may largely weaken the effectiveness of water flooding,the more severe the heterogeneity,the worse the water flooding.The WAG injection of CO_(2) performs well in EOR after water flooding for all the cores with different heterogeneities;however,it could barely form a complete or full sweep throughout the low-permeability region,and un-swept bypassed regions remain.The homogeneous core is better developed by the injection of the joint water and CO_(2) WAG than the heterogeneous and fractured cases.
基金Project(51405010)supported by the National Natural Science Foundation of ChinaProject(2011BAG09B00)supported by the National Science and Technology Support Program of China
文摘For the purpose of improving efficiency and realizing start–stop function, an electric oil pump(EOP) is integrated into an 8-speed automatic transmission(AT). A mathematical model is built to calculate the transmission power loss and the hydraulic system leakage. Based on this model, a flow-based control strategy is developed for EOP to satisfy the system flow requirement. This control strategy is verified through the forward driving simulation. The results indicate that there is a best combination for the size of mechanical oil pump(MOP) and EOP in terms of minimum energy consumption. In order to get a quick and smooth starting process, control strategies of the EOP and the on-coming clutch are proposed. The test environment on a prototype vehicle is built to verify the feasibility of the integrated EOP and its control strategies. The results show that the selected EOP can satisfy the flow requirement and a quick and smooth starting performance is achieved in the start–stop function. This research has a high value for the forward design of EOP in automatic transmissions with respect to efficiency improvement and start–stop function.
文摘Soybean is generally recognized as a source of edible and the deoiled meal is seen as a source of protein in animal feed.In recent years.However,more interest has been directed toward using soy meal as a protein souce for human consumption.Extrusion expelling of soybean provides an opportunity in this direction.The main focus of this study was to maximize the oil recovery from extruded soybean processed using three different kinds of extrudates and processing conditions.These extruded samples were later pressed uniaxially in a specifically designed test cell and the oil recovery was recorded over time.The effects of process variables,including applied pressure,pressing temperature and sample height,were investigated.Results indicated that over90% of the available oil could be recovered from pressing of extruded soy samples.The information generated is likedly to be useful in interpreting the effect of precess variables and extruding equipment for pretreatment of soybean for subsequent mechanical oil expression.
基金Project(2007BAA09B05)supported by the National Key Technology Research and Development Program of ChinaProject(50804004)supported by the National Natural Science Foundation of China
文摘In order to solve the failure of fuel system when using petroleum coke oil slurry (PCOS) in a R180 diesel engine directly,a petroleum coke oil slurry fuel system (PCOSFS) was developed and installed in R180 engine,which was called PCOS engine.In order to analyze performances and emissions of the PCOS engine,a comparative experiment between PCOS engine fueled with PCOS and R180 engine fueled with diesel oil was carried out.The results show that the PCOS engine can run smoothly,the maximum output power decreases by about 6.2% and 19.0% and the maximum brake thermal efficiency reduces by around 5.85% and 4.13% as compared to R180 engine under the conditions of 1 200 and 1 600 r/min.The HC emissions of PCOS engine are lower than those of R180 engine at 1 200 r/min,and are close to those of R180 engine at 1 600 r/min.The CO emissions are similar to R180 engine at 1 200 and 1 600 r/min.The smoke intensity is close to R180 engine at 1 200 r/min,and is higher than R180 engine at 1 600 r/min.The particles emitted from PCOS engine array sparsely,but particles emitted from R180 engine array closely,cohering together.
基金Projects(40272108,41402208)supported by the National Natural Science Foundation of ChinaProjects(ZR2012DL05,ZR2015EL044)supported by Shandong Provincial Natural Science Foundation,China+1 种基金Project(4072-114017)supported by Young Teachers’ Development of Shandong University of Technology,ChinaProject(J12LC51)supported by Shandong Province Higher Educational Science and Technology Program,China
文摘The effects of soil texture, initial water content and bulk density on diesel oil infiltration in fine sand and silty clay loam materials were evaluated. Three physical and two empirical equations express diesel oil infiltration through soils with time, with coefficients of determination greater than 0.99. Diesel oil infiltrates more quickly in the fine sand than in the silty clay loam material. Diesel oil infiltration rates are found to decrease with increasing initial water content and bulk density for the silty clay loam material. The infiltration rate of diesel oil in the fine sand material increases slightly with increasing initial water content. The diesel oil saturated conductivity(Kdiesel) decreases with increasing bulk density for the silty clay loam column. Diesel oil sorptivity(S) decreases linearly with increased initial water content and bulk density of the silty clay loam material. Changes in empirical parameters relative to initial water content and bulk density are similar to the parameter S.
文摘It's not easy for traditional standards such as STEP to describe product information in a semantic way, andthese limitations result in difficulties in knowledge-based product information integration. In addition, contemporarycomputing environment needs a Web-based language to describe product information, while STEP standard and itsEXPRESS language have no such features however. The development of Semantic Web is making itself be an impor-tant method to facilitate the knowledge-based information integration. This paper presents a new semantic Web lan-guage, DAML+OIL, and tries to use it to describe product information. It is proved that using DAML+OIL to de-scribe product information is quite a feasible way.
文摘Nano-copper used as lubrication oil additive has good tribological property and active self-repairing effect for friction pairs. The reduction in liquid phase for preparing nano-additive is one of the most common method. Nano-copper was prepared by reduction in liquid phase. The different project and routine practice for preparing nano-copper were researched. The dispersion problem of nano-copper was investigated by surface treatment and high dispersion. The particles dimension, the dispersion stability and the purity of nano-copper were characterized by TEM and XRD. The conclusion indicates that the methods of the preparation and dispersion can obtain 20nm copper additive with good dispersion property in lubrication oil.
基金Project(2016RS2016) supported by Provincial Science and Technology Leader Program,Hunan,ChinaProject(2017zzts807) supported by Postgraduate Innovative Research Projects of Central South University,China
文摘The composition of a collector directly affects its collecting performance in mineral flotation.In this study,three vegetable oils were used as the collectors,the flotation performance of scheelite and the differential analysis were studied through flotation experiments,zeta potential,contact angle measurement and Fourier transform infrared spectrum(FTIR)analysis.Flotation results show that the recovery of scheelite increases in the order of oleic acid<rapeseed oil<rice bran oil<soybean oil,especially in the pH range of 5-8.The distinction in the scheelite recovery is due to the different compositions of these collectors.The addition of LA,LNA and PA(<5%)can increase the recovery of scheelite with OA,but the addition of SA deteriorates the scheelite flotation.Results of zeta potential,contact angle measurement and FTIR analysis indicate that the collector adsorption on scheelite surface is enhanced when using the three vegetable oils.For the raw ore with 0.086%WO3,a rough concentrate containing 1.423%WO3 with the recovery of 84.22%is obtained using soybean oil as the collector.
文摘Through using mineral oil and synthetic oil to deploy the semisynthesis base oil, modifying the surfaces of ultrafine tungsten disulfide grains by surface chemical embellishment and adsorption embellishment to make them suspended steadily in the base oil as solid lubricating additive, and adding some function additives, the tungsten disulfide motor oil was prepared. The tribological characteristics of this kind motor oil and the well-known motor oils in our country and overseas were studied. The results show that the oil film strength of this kind of motor oil is respectively 1.06 and 1.38 times of that of shell helix ultra motor oil and great wall motor oil, and its sintering load is 1.75 and 2.33 times of that of them, and when tested under 392 N, 1 450 r/rain and 30 min, the friction coefficients of friction pairs lubricated by the tungsten disulfide motor oil decrease with the increase of time, meanwhile, the diameter of worn spot is small, and the surface of worn spot is smooth, and no obvious furrows appear. The experiments indicate that the tungsten disulfide motor oil has the better antiwear, antifriction and extreme pressure properties than the well-known motor oils.
基金Project(201304608)supported by the State Forestry Administration of ChinaProject(31470594)supported by the National Natural Science Foundation of China
文摘The relationships among compression ratio and stress, compression ratio and residual oil of cake in pressing process of castor beans were studied using the test equipment under different states of oilseeds and ways of pressing manners. The results show that variation of stress increases nonlinearly and residual oil rate decreases with the increase of compression ratio. Lower residual oil of cake was obtained by pressing gently and frequently. Curve fitting on both relationships had been built and parameters for the model were obtained by least square procedure and deepening research on pressing process of the castor beans for castor oil. By assuming that the value of oil production is equivalent to the value of energy consumption, the critical compression ratio of intact seeds is 6.2 while that of crushed seeds is 3.6.
