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Optimizing electronic structure through point defect engineering for enhanced electrocatalytic energy conversion
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作者 Wei Ma Jiahao Yao +6 位作者 Fang Xie Xinqi Wang Hao Wan Xiangjian Shen Lili Zhang Menggai Jiao Zhen Zhou 《Green Energy & Environment》 SCIE EI CAS 2025年第1期109-131,共23页
Point defect engineering endows catalysts with novel physical and chemical properties,elevating their electrocatalytic efficiency.The introduction of defects emerges as a promising strategy,effectively modifying the e... Point defect engineering endows catalysts with novel physical and chemical properties,elevating their electrocatalytic efficiency.The introduction of defects emerges as a promising strategy,effectively modifying the electronic structure of active sites.This optimization influences the adsorption energy of intermediates,thereby mitigating reaction energy barriers,altering paths,enhancing selectivity,and ultimately improving the catalytic efficiency of electrocatalysts.To elucidate the impact of defects on the electrocatalytic process,we comprehensively outline the roles of various point defects,their synthetic methodologies,and characterization techniques.Importantly,we consolidate insights into the relationship between point defects and catalytic activity for hydrogen/oxygen evolution and CO_(2)/O_(2)/N_(2) reduction reactions by integrating mechanisms from diverse reactions.This underscores the pivotal role of point defects in enhancing catalytic performance.At last,the principal challenges and prospects associated with point defects in current electrocatalysts are proposed,emphasizing their role in advancing the efficiency of electrochemical energy storage and conversion materials. 展开更多
关键词 point defect engineering DOPING VACANCY ELECTROCATALYSIS Electronic structure
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Universality of percolation at dynamic pseudocritical point
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作者 Qiyuan Shi Shuo Wei +1 位作者 Youjin Deng Ming Li 《Chinese Physics B》 2025年第4期304-310,共7页
Universality,encompassing critical exponents,scaling functions,and dimensionless quantities,is fundamental to phase transition theory.In finite systems,universal behaviors are also expected to emerge at the pseudocrit... Universality,encompassing critical exponents,scaling functions,and dimensionless quantities,is fundamental to phase transition theory.In finite systems,universal behaviors are also expected to emerge at the pseudocritical point.Focusing on two-dimensional percolation,we show that the size distribution of the largest cluster asymptotically approaches to a Gumbel form in the subcritical phase,a Gaussian form in the supercritical phase,and transitions within the critical finite-size scaling window.Numerical results indicate that,at consistently defined pseudocritical points,this distribution exhibits a universal form across various lattices and percolation models(bond or site),within error bars,yet differs from the distribution at the critical point.The critical polynomial,universally zero for two-dimensional percolation at the critical point,becomes nonzero at pseudocritical points.Nevertheless,numerical evidence suggests that the critical polynomial,along with other dimensionless quantities such as wrapping probabilities and Binder cumulants,assumes fixed values at the pseudocritical point that are independent of the percolation type(bond or site)but vary with lattice structures.These findings imply that while strict universality breaks down at the pseudocritical point,certain extreme-value statistics and dimensionless quantities exhibit quasi-universality,revealing a subtle connection between scaling behaviors at critical and pseudocritical points. 展开更多
关键词 PERCOLATION UNIVERSALITY extreme-value statistics pseudocritical point
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基于PointNet++的建筑物室内部件分割方法
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作者 高飞 《长江信息通信》 2025年第2期192-195,共4页
三维激光点云能够直观完整地表达建筑物室内物体的总体构造,但是室内点云数据具有无序、庞大的特点。扫描获得的室内三维点云数据若直接用于室内物体部件分割需要耗费大量的时间,增加项目的运行成本。因此,如何准确快速的分割室内物体... 三维激光点云能够直观完整地表达建筑物室内物体的总体构造,但是室内点云数据具有无序、庞大的特点。扫描获得的室内三维点云数据若直接用于室内物体部件分割需要耗费大量的时间,增加项目的运行成本。因此,如何准确快速的分割室内物体是点云分割的研究热点。点云中具有三维坐标信息、RGB色彩信息和深度信息等,通过对这些信息的分析研究,有助于对室内物体进行部件分割。为此,文章提出了一种基于PointNet++改进的建筑物室内部件分割方法F-PointNet++,该方法主要分为3个步骤,首先,对数据集进行预处理,为原始点云数据加入曲率信息;其次,改进PointNet++算法,加入曲率作为特征,重构深度网络;最后,通过F-PointNet++网络训练,使用平均准确度(eval accuracy)和平均交并比(mIoU)作为评估指标,验证F-PointNet++网络在室内点云部件分割问题上的性能。结果表明,该方法能够有效提高PointNet++在室内部件分割上的能力,提取精度良好。 展开更多
关键词 深度学习 三维彩色点云 室内部件 部件分割
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基于PointNet++的邻域特征增强点云语义分割方法 被引量:1
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作者 李松 张安思 +1 位作者 伍婕 张保 《激光杂志》 CAS 北大核心 2024年第7期174-179,共6页
随着智能驾驶、机器人导航等以点云为基础的应用蓬勃发展,点云语义分割逐渐成为研究热点。然而,现有的点云语义分割方法存在局部特征提取不充分、特征融合不完整的缺陷。针对这些不足,提出了对应的解决方案。对于局部特征提取不充分的现... 随着智能驾驶、机器人导航等以点云为基础的应用蓬勃发展,点云语义分割逐渐成为研究热点。然而,现有的点云语义分割方法存在局部特征提取不充分、特征融合不完整的缺陷。针对这些不足,提出了对应的解决方案。对于局部特征提取不充分的现象,通过嵌入邻域点的坐标、方向、距离等相关信息去关联邻域点的显式特征。对于特征融合不完整的现象,提出了一种最大池化与自注意力池化相结合的混合池化方法。网络架构基于PointNet++,并结合提出的局部特征提取和融合方法,在S3DIS数据集上的实验结果表明,与基线方法PointNet++相比,各评价指标都有不同程度的提高,证实了新方法的有效性和优越性。 展开更多
关键词 三维点云 语义分割 特征提取 深度学习
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基于改进PointNet++的船体分段合拢面构件智能识别算法研究 被引量:1
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作者 李瑞 赵怡荣 +2 位作者 霍世霖 汪骥 史卫东 《中国舰船研究》 CSCD 北大核心 2024年第6期173-179,共7页
[目的]三维扫描仪获得的船体分段合拢面点云数据,具有精度高、数据量大的优势,能够很好地反映分段合拢面的建造状况。由于现有的PointNet++网络无法处理大容量点云数据,因此提出一种基于改进PointNet++的船体分段合拢面构件智能识别算法... [目的]三维扫描仪获得的船体分段合拢面点云数据,具有精度高、数据量大的优势,能够很好地反映分段合拢面的建造状况。由于现有的PointNet++网络无法处理大容量点云数据,因此提出一种基于改进PointNet++的船体分段合拢面构件智能识别算法,实现针对大容量船体分段合拢面点云数据构件的智能识别。[方法]基于超体素生长理论对船体分段合拢面点云数据进行分割及简化,构建船体分段合拢面点云数据集,并使用该数据集训练基于深度学习理论改进的PointNet++网络。[结果]网络模型在船体分段合拢面点云数据训练集和测试集上的收敛结果趋于稳定,在测试集上识别准确率达到90.012%。[结论]该方法具有良好的识别能力,能够完成船体分段合拢面构件的智能识别。 展开更多
关键词 船舶建造 人工智能 船体分段合拢面 点云数据 超体素生长 pointNet++ 智能识别
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基于Point Transformer v2的点云枝叶分离方法研究
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作者 马津 陈一平 +3 位作者 韩汀 王朝磊 张小海 张吴明 《航天返回与遥感》 CSCD 北大核心 2024年第3期62-72,共11页
准确高效的点云枝叶分离对精确计算森林树木的垂直参数至关重要。然而,当前的研究方法计算成本高,且依赖先验知识导致泛化能力不足。针对以上问题,文章提出利用基于点特征的Transformer网络进行自动化的森林场景三维点云的枝叶分离研究... 准确高效的点云枝叶分离对精确计算森林树木的垂直参数至关重要。然而,当前的研究方法计算成本高,且依赖先验知识导致泛化能力不足。针对以上问题,文章提出利用基于点特征的Transformer网络进行自动化的森林场景三维点云的枝叶分离研究。该方法使用Point Transformer v2网络,首先利用网格编码模块提取可学习的局部结构关系,保留点云的几何拓扑结构;其次使用分组注意力实现多通道联合学习,降低特征的冗余度,提高计算的效率;最后构建了基于点的Transformer网络实现高精度森林树木三维点云语义分割,降低了对于先验知识的需求。使用地基激光扫描仪获取的加拿大和芬兰7个不同树种样地的三维点云数据,进行枝叶分离实验和精度评价。实验结果表明,网络整体精度(OA)为94.42%,mIoU为78.89%,能够适应不同树种、不同点云密度的森林场景的枝叶分离。 展开更多
关键词 三维点云 深度学习 枝叶分离 point TRANSFORMER V2
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基于PointNet++进行附属设施语义分割的隧道收敛变形分析 被引量:1
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作者 卞政 石波 +3 位作者 吴凡 王静 赵凯 杨兴宜 《铁道科学与工程学报》 EI CAS CSCD 北大核心 2024年第11期4827-4839,共13页
随着城市轨道交通日趋广泛,隧道结构变形引起的地铁安全事故凸显,亟需对运营期隧道进行变形检测。隧道衬砌作为隧道变形分析的研究对象,衬砌内表面存在的大量附属设施影响隧道收敛变形分析精度。为了提高变形分析精度,解决点云处理环节... 随着城市轨道交通日趋广泛,隧道结构变形引起的地铁安全事故凸显,亟需对运营期隧道进行变形检测。隧道衬砌作为隧道变形分析的研究对象,衬砌内表面存在的大量附属设施影响隧道收敛变形分析精度。为了提高变形分析精度,解决点云处理环节中存在的自动化程度低的问题,提出基于PointNet++点云语义分割的隧道收敛变形分析方法。首先利用深度学习方法进行点云语义分割,对隧道衬砌附属设施进行自动滤除。然后对隧道衬砌进行断面提取,利用随机抽样一致性算法(Random Sample Consensus,RANSAC)对隧道断面点云进行采样,分析隧道收敛变形程度,从Z+F PROFILER 9012A激光断面扫描仪获取山东省济南市地铁盾构隧道点云实测数据上并进行应用。研究结果表明:所提出的处理方法可以有效地将大规模隧道衬砌与连接紧密的附属设施分离出来,隧道附属设施总体分类精度达到96%,滤波结果较好地保留了隧道衬砌原始形态特征。在对隧道整体和局部收敛变形分析的重复性验证中,测试区间内隧道整体变形精度往返测长半轴平均偏差为1.04 mm,短半轴平均偏差为0.9 mm,测试区间内隧道局部收敛变形往返测标准差最小为0.773 mm,最大为0.938 mm,可以满足隧道收敛变形分析的精度需求。研究结果可以有效提升处理大规模隧道数据的自动化程度,具有良好的有效性与可靠性,对运营期地铁隧道收敛变形检测或监测有较好的实践应用意义。 展开更多
关键词 轨道交通隧道 激光点云 收敛变形分析 点云深度学习 随机抽样一致性
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DiriNet:An Estimation Network for Spectral Response Function and Point Spread Function 被引量:1
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作者 Ting Hu Siyuan Cheng Chang Liu 《Journal of Beijing Institute of Technology》 EI CAS 2024年第4期287-297,共11页
Hyper-and multi-spectral image fusion is an important technology to produce hyper-spectral and hyper-resolution images,which always depends on the spectral response function andthe point spread function.However,few wo... Hyper-and multi-spectral image fusion is an important technology to produce hyper-spectral and hyper-resolution images,which always depends on the spectral response function andthe point spread function.However,few works have been payed on the estimation of the two degra-dation functions.To learn the two functions from image pairs to be fused,we propose a Dirichletnetwork,where both functions are properly constrained.Specifically,the spatial response function isconstrained with positivity,while the Dirichlet distribution along with a total variation is imposedon the point spread function.To the best of our knowledge,the neural network and the Dirichlet regularization are exclusively investigated,for the first time,to estimate the degradation functions.Both image degradation and fusion experiments demonstrate the effectiveness and superiority of theproposed Dirichlet network. 展开更多
关键词 Dirichlet network point spread function spectral response function hyper-spectralimage multi-spectral image
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Coexistence of Dirac and Weyl points in non-centrosymmetric semimetal NbIrTe_(4)
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作者 刘清馨 付阳 +4 位作者 丁鹏飞 马欢 郭朋杰 雷和畅 王善才 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第4期146-151,共6页
Using angle-resolved photoemission spectroscopy and density functional theory calculations methods,we investigate the electronic structures and topological properties of ternary tellurides NbIrTe_(4),a candidate for t... Using angle-resolved photoemission spectroscopy and density functional theory calculations methods,we investigate the electronic structures and topological properties of ternary tellurides NbIrTe_(4),a candidate for type-II Weyl semimetal.We demonstrate the presence of several Fermi arcs connecting their corresponding Weyl points on both termination surfaces of the topological material.Our analysis reveals the existence of Dirac points,in addition to Weyl points,giving both theoretical and experimental evidences of the coexistence of Dirac and Weyl points in a single material.These findings not only confirm NbIrTe_(4) as a unique topological semimetal but also open avenues for exploring novel electronic devices based on its coexisting Dirac and Weyl fermions. 展开更多
关键词 Fermi arc Weyl point Dirac point angle-resolved photoemission spectroscopy
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基于知识蒸馏和定位引导的Pointpillars点云检测网络 被引量:1
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作者 赵晶 李少博 +3 位作者 郭杰龙 俞辉 张剑锋 李杰 《液晶与显示》 CSCD 北大核心 2024年第1期79-88,共10页
激光雷达数据由于其几何特性,被广泛应用于三维目标检测任务中。由于点云数据的稀疏性和不规则性,难以实现特征提取的质量和推理速度间的平衡。本文提出一种基于体柱特征编码的三维目标检测算法,以Pointpillars网络为基础,设计Teacher-S... 激光雷达数据由于其几何特性,被广泛应用于三维目标检测任务中。由于点云数据的稀疏性和不规则性,难以实现特征提取的质量和推理速度间的平衡。本文提出一种基于体柱特征编码的三维目标检测算法,以Pointpillars网络为基础,设计Teacher-Student模型框架对回归框尺度进行蒸馏,增加蒸馏损失,优化训练网络模型,提升特征提取的质量。为进一步提高模型检测效果,设计定位引导分类项,增加分类预测和回归预测之间的相关性,提高物体识别准确率。本网络所做改进没有引入额外的网络嵌入。算法在KITTI数据集上的实验结果表明,相比于基准网络,在三维模式下的平均精度值从60.65%提升到了64.69%,鸟瞰图模式下的平均精度值从67.74%提升到70.24%。模型推理速度为45 FPS,在提升检测精度的同时满足了实时性要求。 展开更多
关键词 激光点云 三维目标检测 知识蒸馏 分类置信度
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Exceptional points and quantum dynamics in a non-Hermitian two-qubit system
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作者 张益玺 张振涛 +2 位作者 杨震山 魏晓志 梁宝龙 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第6期212-218,共7页
We study the exceptional-point(EP) structure and the associated quantum dynamics in a system consisting of a non-Hermitian qubit and a Hermitian qubit. We find that the system possesses two sets of EPs, which divide t... We study the exceptional-point(EP) structure and the associated quantum dynamics in a system consisting of a non-Hermitian qubit and a Hermitian qubit. We find that the system possesses two sets of EPs, which divide the systemparameter space into PT-symmetry unbroken, partially broken and fully broken regimes, each with distinct quantumdynamics characteristics. Particularly, in the partially broken regime, while the PT-symmetry is generally broken in the whole four-dimensional Hilbert space, it is preserved in a two-dimensional subspace such that the quantum dynamics in the subspace are similar to those in the PT-symmetry unbroken regime. In addition, we reveal that the competition between the inter-qubit coupling and the intra-qubit driving gives rise to a complex pattern in the EP variation with system parameters. 展开更多
关键词 non-Hermitian system exceptional point PT-SYMMETRY
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Melting points of ionic liquids:Review and evaluation
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作者 Zhengxing Dai Lei Wang +1 位作者 Xiaohua Lu Xiaoyan Ji 《Green Energy & Environment》 SCIE EI CAS CSCD 2024年第12期1802-1811,共10页
The melting points of ionic liquids(ILs)reported since 2020 were surveyed,collected,and reviewed,which were further combined with the previous data to provide a database with 3129 ILs ranging from 177.15 to 645.9 K in... The melting points of ionic liquids(ILs)reported since 2020 were surveyed,collected,and reviewed,which were further combined with the previous data to provide a database with 3129 ILs ranging from 177.15 to 645.9 K in melting points.In addition,the factors that affect the melting point of ILs from macro,micro,and thermodynamic perspectives were summarized and analyzed.Then the development of the quantitative structure-property relationship(QSPR),group contribution method(GCM),and conductor-like screening model for realistic solvents(COSMO-RS)for predicting the melting points of ILs were reviewed and further analyzed.Combined with the evaluation together with the preliminary study conducted in this work,it shows that COSMO-RS is more promising and possible to further improve its performance,and a framework was thus proposed. 展开更多
关键词 Ionic liquids Melting point COSMO-RS QSPR GCM
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Prediction of collapse process and tipping points for mutualistic and competitive networks with k-core method
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作者 段东立 毕菲菲 +3 位作者 李思凡 吴成星 吕长春 蔡志强 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第5期173-180,共8页
Ecosystems generally have the self-adapting ability to resist various external pressures or disturbances,which is always called resilience.However,once the external disturbances exceed the tipping points of the system... Ecosystems generally have the self-adapting ability to resist various external pressures or disturbances,which is always called resilience.However,once the external disturbances exceed the tipping points of the system resilience,the consequences would be catastrophic,and eventually lead the ecosystem to complete collapse.We capture the collapse process of ecosystems represented by plant-pollinator networks with the k-core nested structural method,and find that a sufficiently weak interaction strength or a sufficiently large competition weight can cause the structure of the ecosystem to collapse from its smallest k-core towards its largest k-core.Then we give the tipping points of structure and dynamic collapse of the entire system from the one-dimensional dynamic function of the ecosystem.Our work provides an intuitive and precise description of the dynamic process of ecosystem collapse under multiple interactions,and provides theoretical insights into further avoiding the occurrence of ecosystem collapse. 展开更多
关键词 complex networks tipping points dimension reduction k-core
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Triple points and phase transitions of D-dimensional dyonic Ad S black holes with quasitopological electromagnetism in Einstein–Gauss–Bonnet gravity
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作者 牟平辉 蒋青权 +1 位作者 何柯腱 李国平 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第6期272-287,共16页
By considering the negative cosmological constant Λ as a thermodynamic pressure, we study the thermodynamics and phase transitions of the D-dimensional dyonic Ad S black holes(BHs) with quasitopological electromagnet... By considering the negative cosmological constant Λ as a thermodynamic pressure, we study the thermodynamics and phase transitions of the D-dimensional dyonic Ad S black holes(BHs) with quasitopological electromagnetism in Einstein–Gauss–Bonnet(EGB) gravity. The results indicate that the small/large BH phase transition that is similar to the van der Waals(vdW) liquid/gas phase transition always exists for any spacetime dimensions. Interestingly, we then find that this BH system exhibits a more complex phase structure in 6-dimensional case that is missed in other dimensions.Specifically, it shows for D = 6 that we observed the small/intermediate/large BH phase transitions in a specific parameter region with the triple point naturally appeared. Moreover, when the magnetic charge turned off, we still observed the small/intermediate/large BH phase transitions and triple point only in 6-dimensional spacetime, which is consistent with the previous results. However, for the dyonic Ad S BHs with quasitopological electromagnetism in Einstein–Born–Infeld(EBI) gravity, the novel phase structure composed of two separate coexistence curves observed by Li et al. [Phys. Rev. D105 104048(2022)] disappeared in EGB gravity. This implies that this novel phase structure is closely related to gravity theories, and seems to have nothing to do with the effect of quasitopological electromagnetism. In addition, it is also true that the critical exponents calculated near the critical points possess identical values as mean field theory. Finally, we conclude that these findings shall provide some deep insights into the intriguing thermodynamic properties of the dyonic Ad S BHs with quasitopological electromagnetism in EGB gravity. 展开更多
关键词 AdS black hole phase transition triple point
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Influence of acceleration stage electrode voltage on the performance of double-stage Hall effect thruster with adjustable zero magnetic point
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作者 陈龙 高维富 +5 位作者 崔作君 段萍 许雪松 阚子晨 檀聪琦 陈俊宇 《Plasma Science and Technology》 SCIE EI CAS CSCD 2024年第6期60-69,共10页
The configuration of electrode voltage and zero magnetic point position has a significant impact on the performance of the double-stage Hall effect thruster. A 2D-3V model is established based on the two-magnetic peak... The configuration of electrode voltage and zero magnetic point position has a significant impact on the performance of the double-stage Hall effect thruster. A 2D-3V model is established based on the two-magnetic peak type double-stage Hall thruster configuration, and a particle-in-cell simulation is carried out to investigate the influences of both acceleration electrode voltage value and zero magnetic point position on the thruster discharge characteristics and performances.The results indicate that increasing the acceleration voltage leads to a larger potential drop in the acceleration stage, allowing ions to gain higher energy, while electrons are easily absorbed by the intermediate electrode, resulting in a decrease in the anode current and ionization rate. When the acceleration voltage reaches 500 V, the thrust and efficiency are maximized, resulting in a 15%increase in efficiency. After the acceleration voltage exceeds 500 V, a potential barrier forms within the channel, leading to a decrease in thruster efficiency. Further study shows that as the second zero magnetic point moves towards the outlet of the channel, more electrons easily traverse the zero magnetic field region, participating in the ionization. The increase in the ionization rate leads to a gradual enhancement in both thrust and efficiency. 展开更多
关键词 Hall thruster particle-in-cell simulation intermediate electrode zero magnetic point
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Estimating wood quality attributes from dense airborne LiDAR point clouds
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作者 Nicolas Cattaneo Stefano Puliti +1 位作者 Carolin Fischer Rasmus Astrup 《Forest Ecosystems》 SCIE CSCD 2024年第2期226-235,共10页
Mapping individual tree quality parameters from high-density LiDAR point clouds is an important step towards improved forest inventories.We present a novel machine learning-based workflow that uses individual tree poi... Mapping individual tree quality parameters from high-density LiDAR point clouds is an important step towards improved forest inventories.We present a novel machine learning-based workflow that uses individual tree point clouds from drone laser scanning to predict wood quality indicators in standing trees.Unlike object reconstruction methods,our approach is based on simple metrics computed on vertical slices that summarize information on point distances,angles,and geometric attributes of the space between and around the points.Our models use these slice metrics as predictors and achieve high accuracy for predicting the diameter of the largest branch per log (DLBs) and stem diameter at different heights (DS) from survey-grade drone laser scans.We show that our models are also robust and accurate when tested on suboptimal versions of the data generated by reductions in the number of points or emulations of suboptimal single-tree segmentation scenarios.Our approach provides a simple,clear,and scalable solution that can be adapted to different situations both for research and more operational mapping. 展开更多
关键词 UAV laser scanning Wood quality Machine learning point cloud metrics
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Analysis on the turning point of dynamic in-plane compressive strength for a plain weave composite
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作者 Xiaoyu Wang Zhixing Li +2 位作者 Licheng Guo Zhenxin Wang Jiuzhou Zhao 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第2期485-495,共11页
Experimental investigations on dynamic in-plane compressive behavior of a plain weave composite were performed using the split Hopkinson pressure bar. A quantitative criterion for calculating the constant strain rate ... Experimental investigations on dynamic in-plane compressive behavior of a plain weave composite were performed using the split Hopkinson pressure bar. A quantitative criterion for calculating the constant strain rate of composites was established. Then the upper limit of strain rate, restricted by stress equilibrium and constant loading rate, was rationally estimated and confirmed by tests. Within the achievable range of 0.001/s-895/s, it was found that the strength increased first and subsequently decreased as the strain rate increased. This feature was also reflected by the turning point(579/s) of the bilinear model for strength prediction. The transition in failure mechanism, from local opening damage to completely splitting destruction, was mainly responsible for such strain rate effects. And three major failure modes were summarized under microscopic observations: fiber fracture, inter-fiber fracture, and interface delamination. Finally, by introducing a nonlinear damage variable, a simplified ZWT model was developed to characterize the dynamic mechanical response. Excellent agreement was shown between the experimental and simulated results. 展开更多
关键词 Plain weave composite Dynamic strength Quantitative criterion Turning point Failure mechanism
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A high-flash-point quasi-solid polymer electrolyte for stable nickel-rich lithium metal batteries
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作者 Yu-Kun Liu Xue-Yan Huang +11 位作者 Jun-Dong Zhang Wei-Jin Kong Juan Du Ximin Zhai Xiaofe Bie Huanli Sun Hao Zhang Chong Yan Xuechun Hao Lizhen Fan Ai-Bing Chen Chen-Zi Zhao 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第12期149-158,共10页
In the exploration of next-generation high-energy–density batteries,lithium metal is regarded as an ideal candidate for anode materials.However,lithium metal batteries (LMBs) face challenges in practical applications... In the exploration of next-generation high-energy–density batteries,lithium metal is regarded as an ideal candidate for anode materials.However,lithium metal batteries (LMBs) face challenges in practical applications due to the risks associated with organic liquid electrolytes,among which their low flash points are one of the major safety concerns.The adoption of high flash point quasi-solid polymer electrolytes(QSPE) that is compatible with the lithium metal anode and high-voltage cathode is therefore a promising strategy for exploring high-performance and high-safety LMBs.Herein,we employed the in-situ polymerization of poly (epoxidized soya fatty acid Bu esters-isooctyl acrylate-ditrimethylolpropane tetraacrylate)(PEID) to gel the liquid electrolyte that formed a PEID-based QSPE (PEID-QSPE).The flash point of PEID-QSPE rises from 25 to 82℃ after gelation,contributing to enhanced safety of the battery at elevated temperatures,whereas the electrochemical window increases to 4.9 V.Moreover,the three-dimensional polymer framework of PEID-QSPE is validated to facilitate the uniform growth of the solid electrolyte interphase on the anode,thereby improving the cycling stability of the battery.By employing PEID-QSPE,the Li|LiNi_(0.9)Co_(0.05)Mn_(0.05)O_(2) cell achieved long-term cycling stability (Coulombic efficiency,99.8%;>200 cycles at 0.1 C) even with a high cathode loading (~5 mg cm^(-2)) and an ultrathin Li(~50μm).This electrolyte is expected to afford inspiring insights for the development of safe and long-term cyclability LMBs. 展开更多
关键词 Solid-state batteries Lithium metal anodes Quasi-solid polymer electrolytes High flash points Cross-linking polymerization
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Research on BIM Model Reshaping Method Based on 3D Point Cloud Recognition
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作者 SHI Jin-yu YU Xian-feng +1 位作者 SI Zhan-jun ZHANG Ying-xue 《印刷与数字媒体技术研究》 CAS 北大核心 2024年第4期125-135,共11页
In view of the limitations of traditional measurement methods in the field of building information,such as complex operation,low timeliness and poor accuracy,a new way of combining three-dimensional scanning technolog... In view of the limitations of traditional measurement methods in the field of building information,such as complex operation,low timeliness and poor accuracy,a new way of combining three-dimensional scanning technology and BIM(Building Information Modeling)model was discussed.Focused on the efficient acquisition of building geometric information using the fast-developing 3D point cloud technology,an improved deep learning-based 3D point cloud recognition method was proposed.The method optimised the network structure based on RandLA-Net to adapt to the large-scale point cloud processing requirements,while the semantic and instance features of the point cloud were integrated to significantly improve the recognition accuracy and provide a precise basis for BIM model remodeling.In addition,a visual BIM model generation system was developed,which systematically transformed the point cloud recognition results into BIM component parameters,automatically constructed BIM models,and promoted the open sharing and secondary development of models.The research results not only effectively promote the automation process of converting 3D point cloud data to refined BIM models,but also provide important technical support for promoting building informatisation and accelerating the construction of smart cities,showing a wide range of application potential and practical value. 展开更多
关键词 3D point cloud RandLA-Net network BIM model OSG engine
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Quantitative determination of the critical points of Mott metal–insulator transition in strongly correlated systems
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作者 牛月坤 倪煜 +4 位作者 王建利 陈雷鸣 邢晔 宋筠 冯世平 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第1期647-652,共6页
Mottness is at the heart of the essential physics in a strongly correlated system as many novel quantum phenomena occur in the metallic phase near the Mott metal–insulator transition. We investigate the Mott transiti... Mottness is at the heart of the essential physics in a strongly correlated system as many novel quantum phenomena occur in the metallic phase near the Mott metal–insulator transition. We investigate the Mott transition in a Hubbard model by using the dynamical mean-field theory and introduce the local quantum state fidelity to depict the Mott metal–insulator transition. The local quantum state fidelity provides a convenient approach to determining the critical point of the Mott transition. Additionally, it presents a consistent description of the two distinct forms of the Mott transition points. 展开更多
关键词 critical point metal–insulator transition local quantum state fidelity strongly correlated system quasiparticle coherent weight
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