Gradient magnetic heterointerfaces have injected infinite vitality in optimizing impedance matching,adjusting dielectric/magnetic resonance and promoting electromagnetic(EM)wave absorption,but still exist a significan...Gradient magnetic heterointerfaces have injected infinite vitality in optimizing impedance matching,adjusting dielectric/magnetic resonance and promoting electromagnetic(EM)wave absorption,but still exist a significant challenging in regulating local phase evolution.Herein,accordion-shaped Co/Co_(3)O_(4)@N-doped carbon nanosheets(Co/Co_(3)O_(4)@NC)with gradient magnetic heterointerfaces have been fabricated via the cooperative high-temperature carbonization and lowtemperature oxidation process.The results indicate that the surface epitaxial growth of crystal Co_(3)O_(4) domains on local Co nanoparticles realizes the adjustment of magnetic-heteroatomic components,which are beneficial for optimizing impedance matching and interfacial polarization.Moreover,gradient magnetic heterointerfaces simultaneously realize magnetic coupling,and long-range magnetic diffraction.Specifically,the synthesized Co/Co_(3)O_(4)@NC absorbents display the strong electromagnetic wave attenuation capability of−53.5 dB at a thickness of 3.0 mm with an effective absorption bandwidth of 5.36 GHz,both are superior to those of single magnetic domains embedded in carbon matrix.This design concept provides us an inspiration in optimizing interfacial polarization,regulating magnetic coupling and promoting electromagnetic wave absorption.展开更多
Lead chalcogenides represent a significant class of materials that exhibit intriguing physical phenomena,including remarkable thermoelectric properties and superconductivity.In this study,we present a comprehensive in...Lead chalcogenides represent a significant class of materials that exhibit intriguing physical phenomena,including remarkable thermoelectric properties and superconductivity.In this study,we present a comprehensive investigation on the superconductivity of PbSe single crystal under high pressure.The signature of superconducting(SC)transition starts to appear at 7.2 K under 16.5 GPa.Upon further compression,the SC temperature(T_(c))decreases,and it is reduced to 3.5 K at 45.0 GPa.The negative pressure dependent behavior of T_(c)is consistent with the trend of T_(c)-P relations observed in other lead chalcogenides.The highest T_(c)is 8.0 K observed at 20.5 GPa during decompression process,which is also the highest record among all other PbSe derivatives,such as doped samples,superlattices,and so on.The phase boundaries of the structural and electronic transitions are well defined by Raman spectroscopy,and then phase diagrams are plotted for both compression and decompression processes.This work corrects the previous claim of positive pressure dependence of T_(c)in PbSe and provides clear phase diagrams for intrinsic superconductivity in PbSe under pressure.展开更多
Understanding the evolution of microstructures in nuclear fuels under high-burn-up conditions is critical for extending fuel refueling cycles and enhancing nuclear reactor safety.In this study,a phase-field model is p...Understanding the evolution of microstructures in nuclear fuels under high-burn-up conditions is critical for extending fuel refueling cycles and enhancing nuclear reactor safety.In this study,a phase-field model is proposed to examine the evolution of high-burn-up structures in polycrystalline UO_(2).The formation and growth of recrystallized grains were initially investigated.It was demonstrated that recrystallization kinetics adhere to the Kolmogorov–Johnson–Mehl–Avrami(KJMA)equation,and that recrystallization represents a process of free-energy reduction.Subsequently,the microstructural evolution in UO_(2) was analyzed as the burn up increased.Gas bubbles acted as additional nucleation sites,thereby augmenting the recrystallization kinetics,whereas the presence of recrystallized grains accelerated bubble growth by increasing the number of grain boundaries.The observed variations in the recrystallization kinetics and porosity with burn-up closely align with experimental findings.Furthermore,the influence of grain size on microstructure evolution was investigated.Larger grain sizes were found to decrease porosity and the occurrence of high-burn-up structures.展开更多
The degradation and nonlinear interactions of a two-breather solution of the Mel’nikov equation are analyzed.By modulating the phase shift and limit method,we prove that in different regions near the non-singular bou...The degradation and nonlinear interactions of a two-breather solution of the Mel’nikov equation are analyzed.By modulating the phase shift and limit method,we prove that in different regions near the non-singular boundaries,there are four kinds of solutions with repulsive interaction or attractive interaction in addition to the two-breather solution.They are the interaction solution between soliton and breather,the two-soliton solution,and the two-breather solution with small amplitude,which all exhibit repulsive interactions;and the two-breather solution with small amplitude,which exhibits attractive interaction.Interestingly,a new breather acts as a messenger to transfer energy during the interaction between two breather solutions with small amplitude.展开更多
Photonic computing has emerged as a promising technology for the ever-increasing computational demands of machine learning and artificial intelligence.Due to the advantages in computing speed,integrated photonic chips...Photonic computing has emerged as a promising technology for the ever-increasing computational demands of machine learning and artificial intelligence.Due to the advantages in computing speed,integrated photonic chips have attracted wide research attention on performing convolutional neural network algorithm.Programmable photonic chips are vital for achieving practical applications of photonic computing.Herein,a programmable photonic chip based on ultrafast laser-induced phase change is fabricated for photonic computing.Through designing the ultrafast laser pulses,the Sb film integrated into photonic waveguides can be reversibly switched between crystalline and amorphous phase,resulting in a large contrast in refractive index and extinction coefficient.As a consequence,the light transmission of waveguides can be switched between write and erase states.To determine the phase change time,the transient laser-induced phase change dynamics of Sb film are revealed at atomic scale,and the time-resolved transient reflectivity is measured.Based on the integrated photonic chip,photonic convolutional neural networks are built to implement machine learning algorithm,and images recognition task is achieved.This work paves a route for fabricating programmable photonic chips by designed ultrafast laser,which will facilitate the application of photonic computing in artificial intelligence.展开更多
The discovery of phase changings in two-dimensional(2D)materials driven by external stimuli not only helps to understand the various intriguing phases in 2D materials but also provides directions for constructing new ...The discovery of phase changings in two-dimensional(2D)materials driven by external stimuli not only helps to understand the various intriguing phases in 2D materials but also provides directions for constructing new functional devices.Here,by combining angle-resolved photoemission spectroscopy(ARPES)and in-situ alkali-metal deposition,we studied how alkali-metal adatoms affect the electronic structure of T_(d)-WTe_(2)on two different cleaved surfaces.We found that depending on the polarization direction of the cleaved surface,the alkali-metal deposition triggered two successive phase transitions on one surface of WTe_(2),while on the other surface,no phase transition was found.We attributed the observed phase transitions to a Td↑-1T′-Td↓structural transition driven by an alkali-metal induced sliding of WTe2layers.By comparing the band structure obtained in different structural phases of WTe_(2),we found that the evolution of band structure across different phases is characterized by an energy scale that could be related to the degree of orbital hybridization between two adjacent WTe_(2)layers.Our results demonstrate a method that manipulates the surface structure of bulk 2D materials.It also builds a direct correlation between the electronic structure and the degree of interlayer misalignment in this intriguing 2D material.展开更多
We study the influence of disorder on the Moore–Read state by principal component analysis(PCA),which is one of the ground state candidates for the 5/2 fractional Hall state.By using PCA,the topological features of t...We study the influence of disorder on the Moore–Read state by principal component analysis(PCA),which is one of the ground state candidates for the 5/2 fractional Hall state.By using PCA,the topological features of the ground state wave functions with different disorder strengths can be distilled.As the disorder strength increases,the Moore–Read state will be destroyed.We explore the phase transition by analyzing the overlaps between the random sample wave functions and the topologically distilled state.The cross-point between the amplitudes of the principal component and its counterpart is the phase transition point.Additionally,the origin of the second component comes from the excited states,which is different from the Laughlin state.展开更多
Based on the principles of thermodynamics, we elucidate the fundamental reasons behind the hysteresis of spontaneous polarization in ferroelectric materials during heating and cooling processes. By utilizing the effec...Based on the principles of thermodynamics, we elucidate the fundamental reasons behind the hysteresis of spontaneous polarization in ferroelectric materials during heating and cooling processes. By utilizing the effective Hamiltonian method in conjuction with the phase-field model, we have successfully reproduced the thermal hysteresis observed in ferroelectric materials during phase transitions. The computational results regarding the electrocaloric effect from these two different computational scales closely align with experimental measurements. Furthermore, we analyze how the first-order ferroelectric phase transition gradually diminishes with an increasing applied electric field, exhibiting characteristics of second-order-like phase transition. By employing the characteristic parameters of thermal hysteresis, we have established a pathway for calculations across different computational scales, thereby providing theoretical support for further investigations into the properties of ferroelectric materials through concurrent multiscale simulations.展开更多
Rapid advances in thermal management technology and the increasing need for multi-energy conversion have placed stringent energy efficiency requirements on next-generation shape-stable composite phase change materials...Rapid advances in thermal management technology and the increasing need for multi-energy conversion have placed stringent energy efficiency requirements on next-generation shape-stable composite phase change materials(PCMs).Magnetically-responsive phase change thermal storage materials are considered an emerging concept for energy storage systems,enabling PCMs to perform unprecedented functions(such as green energy utilization,magnetic thermotherapy,drug release,etc.).The combination of multifunctional magnetic nanomaterials and PCMs is a milestone in the creation of advanced multifunctional composite PCMs.However,a timely and comprehensive review of composite PCMs based on magnetic nanoparticle modification is still missing.Herein,we furnish an exhaustive exposition elucidating the cutting-edge advancements in magnetically responsive composite PCMs.We delve deeply into the multifarious roles assumed by distinct nanoparticles within composite PCMs of varying dimensions,meticulously scrutinizing the intricate interplay between their architectures and thermophysical attributes.Moreover,we prognosticate future research trajectories,delineate alternative stratagems,and illuminate prospective avenues.This review is intended to stimulate broader academic interest in interdisciplinary fields and provide valuable insights into the development of next-generation magnetically-responsive composite PCMs.展开更多
Energy storage and conservation are receiving increased attention due to rising global energy demands.Therefore,the development of energy storage materials is crucial.Thermal energy storage(TES)systems based on phase ...Energy storage and conservation are receiving increased attention due to rising global energy demands.Therefore,the development of energy storage materials is crucial.Thermal energy storage(TES)systems based on phase change materials(PCMs)have increased in prominence over the past two decades,not only because of their outstanding heat storage capacities but also their superior thermal energy regulation capability.However,issues such as leakage and low thermal conductivity limit their applicability in a variety of settings.Carbon-based materials such as graphene and its derivatives can be utilized to surmount these obstacles.This study examines the recent advancements in graphene-based phase change composites(PCCs),where graphene-based nanostructures such as graphene,graphene oxide(GO),functionalized graphene/GO,and graphene aerogel(GA)are incorporated into PCMs to substantially enhance their shape stability and thermal conductivity that could be translated to better storage capacity,durability,and temperature response,thus boosting their attractiveness for TES systems.In addition,the applications of these graphene-based PCCs in various TES disciplines,such as energy conservation in buildings,solar utilization,and battery thermal management,are discussed and summarized.展开更多
Dual-phase and three-phase grating x-ray interference is a promising new technique for grating-based x-ray differential phase contrast imaging.Dual-phase grating interferometers have been relatively completely studied...Dual-phase and three-phase grating x-ray interference is a promising new technique for grating-based x-ray differential phase contrast imaging.Dual-phase grating interferometers have been relatively completely studied and discussed.In this paper,the corresponding imaging fringe formula of the three-phase grating interferometer is provided.At the same time,the similarities and differences between the three-phase grating interferometer and the dual-phase grating interferometer are investigated and verified,and that the three-phase grating interferometer can produce large-period moiréfringes without using the analyzing grating is demonstrated experimentally.Finally,a simple method of designing three-phase grating and multi-grating imaging systems from geometric optics based on the thin-lens theory of gratings is presented.These theoretical formulas and experimental results provide optimization tools for designing three-phase grating interferometer systems.展开更多
The Mn-based oxide cathode with enriched crystal phase structure and component diversity can provide the excellent chemistry structure for Na-ion batteries.Nevertheless,the broad application prospect is obstructed by ...The Mn-based oxide cathode with enriched crystal phase structure and component diversity can provide the excellent chemistry structure for Na-ion batteries.Nevertheless,the broad application prospect is obstructed by the sluggish Na^(+)kinetics and the phase transitions upon cycling.Herein,we establish the thermodynamically stable phase diagram of various Mn-based oxide composites precisely controlled by sodium content tailoring strategy coupling with co-doping and solid-state reaction.The chemical environment of the P2/P'3 and P2/P3 biphasic composites indicate that the charge compensation mechanism stems from the cooperative contribution of anions and cations.Benefiting from the no phase transition to scavenge the structure strain,P2/P'3 electrode can deliver long cycling stability(capacity retention of 73.8%after 1000 cycles at 10 C)and outstanding rate properties(the discharge capacity of 84.08 mA h g^(-1)at 20 C)than P2/P3 electrode.Furthermore,the DFT calculation demonstrates that the introducing novel P'3 phase can significantly regulate the Na^(+)reaction dynamics and modify the local electron configuration of Mn.The effective phase engineering can provide a reference for designing other high-performance electrode materials for Na-ion batteries.展开更多
The severe dependence of traditional phase change materials(PCMs)on the temperature-response and lattice deficiencies in versatility cannot satisfy demand for using such materials in complex application scenarios.Here...The severe dependence of traditional phase change materials(PCMs)on the temperature-response and lattice deficiencies in versatility cannot satisfy demand for using such materials in complex application scenarios.Here,we introduced metal ions to induce the self-assembly of MXene nanosheets and achieve their ordered arrangement by combining suction filtration and rapid freezing.Subsequently,a series of MXene/K^(+)/paraffin wax(PW)phase change composites(PCCs)were obtained via vacuum impregnation in molten PW.The prepared MXene-based PCCs showed versatile applications from macroscale technologies,successfully transforming solar,electric,and magnetic energy into thermal energy stored as latent heat in the PCCs.Moreover,due to the absence of binder in the MXene-based aerogel,MK3@PW exhibits a prime solar-thermal conversion efficiency(98.4%).Notably,MK3@PW can further convert the collected heat energy into electric energy through thermoelectric equipment and realize favorable solar-thermal-electric conversion(producing 206 mV of voltage with light radiation intensity of 200 mw cm^(−2)).An excellent Joule heat performance(reaching 105℃with an input voltage of 2.5 V)and responsive magnetic-thermal conversion behavior(a charging time of 11.8 s can achieve a thermal insulation effect of 285 s)for contactless thermotherapy were also demonstrated by the MK3@PW.Specifically,as a result of the ordered arrangement of MXene nanosheet self-assembly induced by potassium ions,MK3@PW PCC exhibits a higher electromagnetic shielding efficiency value(57.7 dB)than pure MXene aerogel/PW PCC(29.8 dB)with the same MXene mass.This work presents an opportunity for the multi-scene response and practical application of PCMs that satisfy demand of next-generation multifunctional PCCs.展开更多
Herein,the impact of the independent control of processing additives on vertical phase separation in sequentially deposited (SD) organic photovoltaics (OPVs) and its subsequent effects on charge carrier kinetics at th...Herein,the impact of the independent control of processing additives on vertical phase separation in sequentially deposited (SD) organic photovoltaics (OPVs) and its subsequent effects on charge carrier kinetics at the electron donor-acceptor interface are investigated.The film morphology exhibits notable variations,significantly depending on the layer to which 1,8-diiodooctane (DIO) was applied.Grazing incidence wide-angle X-ray scattering analysis reveals distinctly separated donor/acceptor phases and vertical crystallinity details in SD films.Time-of-flight secondary ion mass spectrometry analysis is employed to obtain component distributions in diverse vertical phase structures of SD films depending on additive control.In addition,nanosecond transient absorption spectroscopy shows that DIO control significantly affects the dynamics of separated charges in SD films.In SD OPVs,DIO appears to act through distinct mechanisms with minimal restriction,depending on the applied layer.This study emphasizes the significance of morphological optimization in improving device performance and underscores the importance of independent additive control in the advancement of OPV technology.展开更多
Digital in-line holographic microscopy(DIHM)is a widely used interference technique for real-time reconstruction of living cells’morphological information with large space-bandwidth product and compact setup.However,...Digital in-line holographic microscopy(DIHM)is a widely used interference technique for real-time reconstruction of living cells’morphological information with large space-bandwidth product and compact setup.However,the need for a larger pixel size of detector to improve imaging photosensitivity,field-of-view,and signal-to-noise ratio often leads to the loss of sub-pixel information and limited pixel resolution.Additionally,the twin-image appearing in the reconstruction severely degrades the quality of the reconstructed image.The deep learning(DL)approach has emerged as a powerful tool for phase retrieval in DIHM,effectively addressing these challenges.However,most DL-based strategies are datadriven or end-to-end net approaches,suffering from excessive data dependency and limited generalization ability.Herein,a novel multi-prior physics-enhanced neural network with pixel super-resolution(MPPN-PSR)for phase retrieval of DIHM is proposed.It encapsulates the physical model prior,sparsity prior and deep image prior in an untrained deep neural network.The effectiveness and feasibility of MPPN-PSR are demonstrated by comparing it with other traditional and learning-based phase retrieval methods.With the capabilities of pixel super-resolution,twin-image elimination and high-throughput jointly from a single-shot intensity measurement,the proposed DIHM approach is expected to be widely adopted in biomedical workflow and industrial measurement.展开更多
Deconvolution is a commonly employed technique for enhancing image quality in optical imaging methods.Unfortu-nately,its application in optical coherence tomography(OCT)is often hindered by sensitivity to noise,which ...Deconvolution is a commonly employed technique for enhancing image quality in optical imaging methods.Unfortu-nately,its application in optical coherence tomography(OCT)is often hindered by sensitivity to noise,which leads to ad-ditive ringing artifacts.These artifacts considerably degrade the quality of deconvolved images,thereby limiting its effect-iveness in OCT imaging.In this study,we propose a framework that integrates numerical random phase masks into the deconvolution process,effectively eliminating these artifacts and enhancing image clarity.The optimized joint operation of an iterative Richardson-Lucy deconvolution and numerical synthesis of random phase masks(RPM),termed as De-conv-RPM,enables a 2.5-fold reduction in full width at half-maximum(FWHM).We demonstrate that the Deconv-RPM method significantly enhances image clarity,allowing for the discernment of previously unresolved cellular-level details in nonkeratinized epithelial cells ex vivo and moving blood cells in vivo.展开更多
Developing technologies that can be applied simultaneously in battery thermal management(BTM)and thermal runaway(TR)mitigation is significant to improving the safety of lithium-ion battery systems.Inorganic phase chan...Developing technologies that can be applied simultaneously in battery thermal management(BTM)and thermal runaway(TR)mitigation is significant to improving the safety of lithium-ion battery systems.Inorganic phase change material(PCM)with nonflammability has the potential to achieve this dual function.This study proposed an encapsulated inorganic phase change material(EPCM)with a heat transfer enhancement for battery systems,where Na_(2)HPO_(4)·12H_(2)O was used as the core PCM encapsulated by silica and the additive of carbon nanotube(CNT)was applied to enhance the thermal conductivity.The microstructure and thermal properties of the EPCM/CNT were analyzed by a series of characterization tests.Two different incorporating methods of CNT were compared and the proper CNT adding amount was also studied.After preparation,the battery thermal management performance and TR propagation mitigation effects of EPCM/CNT were further investigated on the battery modules.The experimental results of thermal management tests showed that EPCM/CNT not only slowed down the temperature rising of the module but also improved the temperature uniformity during normal operation.The peak battery temperature decreased from 76℃to 61.2℃at 2 C discharge rate and the temperature difference was controlled below 3℃.Moreover,the results of TR propagation tests demonstrated that nonflammable EPCM/CNT with good heat absorption could work as a TR barrier,which exhibited effective mitigation on TR and TR propagation.The trigger time of three cells was successfully delayed by 129,474 and 551 s,respectively and the propagation intervals were greatly extended as well.展开更多
A time-resolved x-ray diffraction technique is employed to monitor the structural transformation of laser-shocked bismuth.Results reveal a retarded transformation from the shock-induced Bi-Ⅴphase to a metastable Bi-...A time-resolved x-ray diffraction technique is employed to monitor the structural transformation of laser-shocked bismuth.Results reveal a retarded transformation from the shock-induced Bi-Ⅴphase to a metastable Bi-Ⅳphase during the shock release,instead of the thermodynamically stable Bi-Ⅲphase.The emergence of the metastable Bi-Ⅳphase is understood by the competitive interplay between two transformation pathways towards the Bi-Ⅳand Bi-Ⅲ,respectively.The former is more rapid than the latter because the Bi-Ⅴto B-Ⅳtransformation is driven by interaction between the closest atoms while the Bi-Ⅴto B-Ⅲtransformation requires interaction between the second-closest atoms.The nucleation time for the Bi-Ⅴto Bi-Ⅳtransformation is determined to be 5.1±0.9 ns according to a classical nucleation model.This observation demonstrates the importance of the formation of the transient metastable phases,which can change the phase transformation pathway in a dynamic process.展开更多
基金financially supported by the National Natural Science Foundation of China(52373271)Science,Technology and Innovation Commission of Shenzhen Municipality under Grant(KCXFZ20201221173004012)+1 种基金National Key Research and Development Program of Shaanxi Province(No.2023-YBNY-271)Open Testing Foundation of the Analytical&Testing Center of Northwestern Polytechnical University(2023T019).
文摘Gradient magnetic heterointerfaces have injected infinite vitality in optimizing impedance matching,adjusting dielectric/magnetic resonance and promoting electromagnetic(EM)wave absorption,but still exist a significant challenging in regulating local phase evolution.Herein,accordion-shaped Co/Co_(3)O_(4)@N-doped carbon nanosheets(Co/Co_(3)O_(4)@NC)with gradient magnetic heterointerfaces have been fabricated via the cooperative high-temperature carbonization and lowtemperature oxidation process.The results indicate that the surface epitaxial growth of crystal Co_(3)O_(4) domains on local Co nanoparticles realizes the adjustment of magnetic-heteroatomic components,which are beneficial for optimizing impedance matching and interfacial polarization.Moreover,gradient magnetic heterointerfaces simultaneously realize magnetic coupling,and long-range magnetic diffraction.Specifically,the synthesized Co/Co_(3)O_(4)@NC absorbents display the strong electromagnetic wave attenuation capability of−53.5 dB at a thickness of 3.0 mm with an effective absorption bandwidth of 5.36 GHz,both are superior to those of single magnetic domains embedded in carbon matrix.This design concept provides us an inspiration in optimizing interfacial polarization,regulating magnetic coupling and promoting electromagnetic wave absorption.
基金supported by the National Natural Science Foundation of China(Grant Nos.12374050,12004014,U1930401,and 12375304)the National Key R&D Program of China(Grant Nos.2021YFA1400300 and 2023YFA1608900)the Major Program of the National Natural Science Foundation of China(Grant No.22090041).
文摘Lead chalcogenides represent a significant class of materials that exhibit intriguing physical phenomena,including remarkable thermoelectric properties and superconductivity.In this study,we present a comprehensive investigation on the superconductivity of PbSe single crystal under high pressure.The signature of superconducting(SC)transition starts to appear at 7.2 K under 16.5 GPa.Upon further compression,the SC temperature(T_(c))decreases,and it is reduced to 3.5 K at 45.0 GPa.The negative pressure dependent behavior of T_(c)is consistent with the trend of T_(c)-P relations observed in other lead chalcogenides.The highest T_(c)is 8.0 K observed at 20.5 GPa during decompression process,which is also the highest record among all other PbSe derivatives,such as doped samples,superlattices,and so on.The phase boundaries of the structural and electronic transitions are well defined by Raman spectroscopy,and then phase diagrams are plotted for both compression and decompression processes.This work corrects the previous claim of positive pressure dependence of T_(c)in PbSe and provides clear phase diagrams for intrinsic superconductivity in PbSe under pressure.
基金supported by the National Natural Science Foundation of China(Grant Nos.U20B2013 and 12205286)the National Key Research and Development Program of China(Grant No.2022YFB1902401)。
文摘Understanding the evolution of microstructures in nuclear fuels under high-burn-up conditions is critical for extending fuel refueling cycles and enhancing nuclear reactor safety.In this study,a phase-field model is proposed to examine the evolution of high-burn-up structures in polycrystalline UO_(2).The formation and growth of recrystallized grains were initially investigated.It was demonstrated that recrystallization kinetics adhere to the Kolmogorov–Johnson–Mehl–Avrami(KJMA)equation,and that recrystallization represents a process of free-energy reduction.Subsequently,the microstructural evolution in UO_(2) was analyzed as the burn up increased.Gas bubbles acted as additional nucleation sites,thereby augmenting the recrystallization kinetics,whereas the presence of recrystallized grains accelerated bubble growth by increasing the number of grain boundaries.The observed variations in the recrystallization kinetics and porosity with burn-up closely align with experimental findings.Furthermore,the influence of grain size on microstructure evolution was investigated.Larger grain sizes were found to decrease porosity and the occurrence of high-burn-up structures.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.52171251 and U21062251)Program of Science and Technology Innovation of Dalian(Grant No.2022JJ12GX036).
文摘The degradation and nonlinear interactions of a two-breather solution of the Mel’nikov equation are analyzed.By modulating the phase shift and limit method,we prove that in different regions near the non-singular boundaries,there are four kinds of solutions with repulsive interaction or attractive interaction in addition to the two-breather solution.They are the interaction solution between soliton and breather,the two-soliton solution,and the two-breather solution with small amplitude,which all exhibit repulsive interactions;and the two-breather solution with small amplitude,which exhibits attractive interaction.Interestingly,a new breather acts as a messenger to transfer energy during the interaction between two breather solutions with small amplitude.
基金supported by the National Key R&D Program of China(2024YFB4609801)the National Natural Science Foundation of China(52075289)the Tsinghua-Jiangyin Innovation Special Fund(TJISF,2023JYTH0104).
文摘Photonic computing has emerged as a promising technology for the ever-increasing computational demands of machine learning and artificial intelligence.Due to the advantages in computing speed,integrated photonic chips have attracted wide research attention on performing convolutional neural network algorithm.Programmable photonic chips are vital for achieving practical applications of photonic computing.Herein,a programmable photonic chip based on ultrafast laser-induced phase change is fabricated for photonic computing.Through designing the ultrafast laser pulses,the Sb film integrated into photonic waveguides can be reversibly switched between crystalline and amorphous phase,resulting in a large contrast in refractive index and extinction coefficient.As a consequence,the light transmission of waveguides can be switched between write and erase states.To determine the phase change time,the transient laser-induced phase change dynamics of Sb film are revealed at atomic scale,and the time-resolved transient reflectivity is measured.Based on the integrated photonic chip,photonic convolutional neural networks are built to implement machine learning algorithm,and images recognition task is achieved.This work paves a route for fabricating programmable photonic chips by designed ultrafast laser,which will facilitate the application of photonic computing in artificial intelligence.
基金Project supported by the National Key Research and Development Program of China(Grant No.2022YFA1403502)the National Natural Science Foundation of China(Grant No.11888101)。
文摘The discovery of phase changings in two-dimensional(2D)materials driven by external stimuli not only helps to understand the various intriguing phases in 2D materials but also provides directions for constructing new functional devices.Here,by combining angle-resolved photoemission spectroscopy(ARPES)and in-situ alkali-metal deposition,we studied how alkali-metal adatoms affect the electronic structure of T_(d)-WTe_(2)on two different cleaved surfaces.We found that depending on the polarization direction of the cleaved surface,the alkali-metal deposition triggered two successive phase transitions on one surface of WTe_(2),while on the other surface,no phase transition was found.We attributed the observed phase transitions to a Td↑-1T′-Td↓structural transition driven by an alkali-metal induced sliding of WTe2layers.By comparing the band structure obtained in different structural phases of WTe_(2),we found that the evolution of band structure across different phases is characterized by an energy scale that could be related to the degree of orbital hybridization between two adjacent WTe_(2)layers.Our results demonstrate a method that manipulates the surface structure of bulk 2D materials.It also builds a direct correlation between the electronic structure and the degree of interlayer misalignment in this intriguing 2D material.
基金supported by the National Natural Science Foundation of China(Grant Nos.12104075 and 12347101).
文摘We study the influence of disorder on the Moore–Read state by principal component analysis(PCA),which is one of the ground state candidates for the 5/2 fractional Hall state.By using PCA,the topological features of the ground state wave functions with different disorder strengths can be distilled.As the disorder strength increases,the Moore–Read state will be destroyed.We explore the phase transition by analyzing the overlaps between the random sample wave functions and the topologically distilled state.The cross-point between the amplitudes of the principal component and its counterpart is the phase transition point.Additionally,the origin of the second component comes from the excited states,which is different from the Laughlin state.
基金Project supported financially by the National Natural Science Foundation of China (Grant No. 52372100)the National Key Research and Development Program of China (Grant No. 2019YFA0307900)。
文摘Based on the principles of thermodynamics, we elucidate the fundamental reasons behind the hysteresis of spontaneous polarization in ferroelectric materials during heating and cooling processes. By utilizing the effective Hamiltonian method in conjuction with the phase-field model, we have successfully reproduced the thermal hysteresis observed in ferroelectric materials during phase transitions. The computational results regarding the electrocaloric effect from these two different computational scales closely align with experimental measurements. Furthermore, we analyze how the first-order ferroelectric phase transition gradually diminishes with an increasing applied electric field, exhibiting characteristics of second-order-like phase transition. By employing the characteristic parameters of thermal hysteresis, we have established a pathway for calculations across different computational scales, thereby providing theoretical support for further investigations into the properties of ferroelectric materials through concurrent multiscale simulations.
基金financially supported by the National Natural Science Foundation of China(No.51902025).
文摘Rapid advances in thermal management technology and the increasing need for multi-energy conversion have placed stringent energy efficiency requirements on next-generation shape-stable composite phase change materials(PCMs).Magnetically-responsive phase change thermal storage materials are considered an emerging concept for energy storage systems,enabling PCMs to perform unprecedented functions(such as green energy utilization,magnetic thermotherapy,drug release,etc.).The combination of multifunctional magnetic nanomaterials and PCMs is a milestone in the creation of advanced multifunctional composite PCMs.However,a timely and comprehensive review of composite PCMs based on magnetic nanoparticle modification is still missing.Herein,we furnish an exhaustive exposition elucidating the cutting-edge advancements in magnetically responsive composite PCMs.We delve deeply into the multifarious roles assumed by distinct nanoparticles within composite PCMs of varying dimensions,meticulously scrutinizing the intricate interplay between their architectures and thermophysical attributes.Moreover,we prognosticate future research trajectories,delineate alternative stratagems,and illuminate prospective avenues.This review is intended to stimulate broader academic interest in interdisciplinary fields and provide valuable insights into the development of next-generation magnetically-responsive composite PCMs.
基金the support from Grant No.2022VBA0023 funded by the Chinese Academy of Sciences President's International Fellowship Initiative.
文摘Energy storage and conservation are receiving increased attention due to rising global energy demands.Therefore,the development of energy storage materials is crucial.Thermal energy storage(TES)systems based on phase change materials(PCMs)have increased in prominence over the past two decades,not only because of their outstanding heat storage capacities but also their superior thermal energy regulation capability.However,issues such as leakage and low thermal conductivity limit their applicability in a variety of settings.Carbon-based materials such as graphene and its derivatives can be utilized to surmount these obstacles.This study examines the recent advancements in graphene-based phase change composites(PCCs),where graphene-based nanostructures such as graphene,graphene oxide(GO),functionalized graphene/GO,and graphene aerogel(GA)are incorporated into PCMs to substantially enhance their shape stability and thermal conductivity that could be translated to better storage capacity,durability,and temperature response,thus boosting their attractiveness for TES systems.In addition,the applications of these graphene-based PCCs in various TES disciplines,such as energy conservation in buildings,solar utilization,and battery thermal management,are discussed and summarized.
基金Project supported by LingChuang Research Project of China National Nuclear Corporationthe National Natural Science Foundation of China(Grant No.12027812)。
文摘Dual-phase and three-phase grating x-ray interference is a promising new technique for grating-based x-ray differential phase contrast imaging.Dual-phase grating interferometers have been relatively completely studied and discussed.In this paper,the corresponding imaging fringe formula of the three-phase grating interferometer is provided.At the same time,the similarities and differences between the three-phase grating interferometer and the dual-phase grating interferometer are investigated and verified,and that the three-phase grating interferometer can produce large-period moiréfringes without using the analyzing grating is demonstrated experimentally.Finally,a simple method of designing three-phase grating and multi-grating imaging systems from geometric optics based on the thin-lens theory of gratings is presented.These theoretical formulas and experimental results provide optimization tools for designing three-phase grating interferometer systems.
基金supported by the National Natural Science Foundation of China (52173273)Fundamental Research Funds for the Central Universities (2022CX11013)+2 种基金Shanxi Province Science Foundation for Youths (No.202203021212391)the Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi (No.2022L253)Institute Foundation Project of China Academy of Railway Sciences Corporation Limited Metals and Chemistry Research Institute (No.2023SJ02)。
文摘The Mn-based oxide cathode with enriched crystal phase structure and component diversity can provide the excellent chemistry structure for Na-ion batteries.Nevertheless,the broad application prospect is obstructed by the sluggish Na^(+)kinetics and the phase transitions upon cycling.Herein,we establish the thermodynamically stable phase diagram of various Mn-based oxide composites precisely controlled by sodium content tailoring strategy coupling with co-doping and solid-state reaction.The chemical environment of the P2/P'3 and P2/P3 biphasic composites indicate that the charge compensation mechanism stems from the cooperative contribution of anions and cations.Benefiting from the no phase transition to scavenge the structure strain,P2/P'3 electrode can deliver long cycling stability(capacity retention of 73.8%after 1000 cycles at 10 C)and outstanding rate properties(the discharge capacity of 84.08 mA h g^(-1)at 20 C)than P2/P3 electrode.Furthermore,the DFT calculation demonstrates that the introducing novel P'3 phase can significantly regulate the Na^(+)reaction dynamics and modify the local electron configuration of Mn.The effective phase engineering can provide a reference for designing other high-performance electrode materials for Na-ion batteries.
基金the National Natural Science Foundation of China[grant numbers 52203038,52173036 and 52073107]the National Key Technology R&D Program of China[grant number 2022YFC3901904,2022YFC3901903,and 2020YFB1709301]the Central University Basic Research Fund of China[grant number 2021XXJS035].
文摘The severe dependence of traditional phase change materials(PCMs)on the temperature-response and lattice deficiencies in versatility cannot satisfy demand for using such materials in complex application scenarios.Here,we introduced metal ions to induce the self-assembly of MXene nanosheets and achieve their ordered arrangement by combining suction filtration and rapid freezing.Subsequently,a series of MXene/K^(+)/paraffin wax(PW)phase change composites(PCCs)were obtained via vacuum impregnation in molten PW.The prepared MXene-based PCCs showed versatile applications from macroscale technologies,successfully transforming solar,electric,and magnetic energy into thermal energy stored as latent heat in the PCCs.Moreover,due to the absence of binder in the MXene-based aerogel,MK3@PW exhibits a prime solar-thermal conversion efficiency(98.4%).Notably,MK3@PW can further convert the collected heat energy into electric energy through thermoelectric equipment and realize favorable solar-thermal-electric conversion(producing 206 mV of voltage with light radiation intensity of 200 mw cm^(−2)).An excellent Joule heat performance(reaching 105℃with an input voltage of 2.5 V)and responsive magnetic-thermal conversion behavior(a charging time of 11.8 s can achieve a thermal insulation effect of 285 s)for contactless thermotherapy were also demonstrated by the MK3@PW.Specifically,as a result of the ordered arrangement of MXene nanosheet self-assembly induced by potassium ions,MK3@PW PCC exhibits a higher electromagnetic shielding efficiency value(57.7 dB)than pure MXene aerogel/PW PCC(29.8 dB)with the same MXene mass.This work presents an opportunity for the multi-scene response and practical application of PCMs that satisfy demand of next-generation multifunctional PCCs.
基金supported by the National Research Foundation of Korea(NRF)grant funded by the Korea government(MSIT)(No.RS-2023-00213920,NRF-2021R1A4A1031761).
文摘Herein,the impact of the independent control of processing additives on vertical phase separation in sequentially deposited (SD) organic photovoltaics (OPVs) and its subsequent effects on charge carrier kinetics at the electron donor-acceptor interface are investigated.The film morphology exhibits notable variations,significantly depending on the layer to which 1,8-diiodooctane (DIO) was applied.Grazing incidence wide-angle X-ray scattering analysis reveals distinctly separated donor/acceptor phases and vertical crystallinity details in SD films.Time-of-flight secondary ion mass spectrometry analysis is employed to obtain component distributions in diverse vertical phase structures of SD films depending on additive control.In addition,nanosecond transient absorption spectroscopy shows that DIO control significantly affects the dynamics of separated charges in SD films.In SD OPVs,DIO appears to act through distinct mechanisms with minimal restriction,depending on the applied layer.This study emphasizes the significance of morphological optimization in improving device performance and underscores the importance of independent additive control in the advancement of OPV technology.
基金National Natural Science Foundation of China (62275267, 62335018, 12127805, 62105359)National Key Research and Development Program of China (2021YFF0700303, 2022YFE0100700)Youth Innovation Promotion Association, CAS (2021401)
文摘Digital in-line holographic microscopy(DIHM)is a widely used interference technique for real-time reconstruction of living cells’morphological information with large space-bandwidth product and compact setup.However,the need for a larger pixel size of detector to improve imaging photosensitivity,field-of-view,and signal-to-noise ratio often leads to the loss of sub-pixel information and limited pixel resolution.Additionally,the twin-image appearing in the reconstruction severely degrades the quality of the reconstructed image.The deep learning(DL)approach has emerged as a powerful tool for phase retrieval in DIHM,effectively addressing these challenges.However,most DL-based strategies are datadriven or end-to-end net approaches,suffering from excessive data dependency and limited generalization ability.Herein,a novel multi-prior physics-enhanced neural network with pixel super-resolution(MPPN-PSR)for phase retrieval of DIHM is proposed.It encapsulates the physical model prior,sparsity prior and deep image prior in an untrained deep neural network.The effectiveness and feasibility of MPPN-PSR are demonstrated by comparing it with other traditional and learning-based phase retrieval methods.With the capabilities of pixel super-resolution,twin-image elimination and high-throughput jointly from a single-shot intensity measurement,the proposed DIHM approach is expected to be widely adopted in biomedical workflow and industrial measurement.
基金supported by the Guangdong Natural Science Fund General Program (2023A1515011289)Singapore Ministry of Health's National Medical Research Council under its Open Fund Individual Research Grant (MOH-OFIRG19may-0009)+2 种基金Ministry of Education Singapore under its Academic Research Fund Tier 1 (RG35/22)Academic Research Funding Tier 2 (MOE-T2EP30120-0001)China-Singapore International Joint Research Institute (203-A022001).
文摘Deconvolution is a commonly employed technique for enhancing image quality in optical imaging methods.Unfortu-nately,its application in optical coherence tomography(OCT)is often hindered by sensitivity to noise,which leads to ad-ditive ringing artifacts.These artifacts considerably degrade the quality of deconvolved images,thereby limiting its effect-iveness in OCT imaging.In this study,we propose a framework that integrates numerical random phase masks into the deconvolution process,effectively eliminating these artifacts and enhancing image clarity.The optimized joint operation of an iterative Richardson-Lucy deconvolution and numerical synthesis of random phase masks(RPM),termed as De-conv-RPM,enables a 2.5-fold reduction in full width at half-maximum(FWHM).We demonstrate that the Deconv-RPM method significantly enhances image clarity,allowing for the discernment of previously unresolved cellular-level details in nonkeratinized epithelial cells ex vivo and moving blood cells in vivo.
基金financially supported by the National Key Research and Development Program(Grant No.2022YFE0207400)the National Natural Science Foundation of China(Grant No.U22A20168 and 52174225)。
文摘Developing technologies that can be applied simultaneously in battery thermal management(BTM)and thermal runaway(TR)mitigation is significant to improving the safety of lithium-ion battery systems.Inorganic phase change material(PCM)with nonflammability has the potential to achieve this dual function.This study proposed an encapsulated inorganic phase change material(EPCM)with a heat transfer enhancement for battery systems,where Na_(2)HPO_(4)·12H_(2)O was used as the core PCM encapsulated by silica and the additive of carbon nanotube(CNT)was applied to enhance the thermal conductivity.The microstructure and thermal properties of the EPCM/CNT were analyzed by a series of characterization tests.Two different incorporating methods of CNT were compared and the proper CNT adding amount was also studied.After preparation,the battery thermal management performance and TR propagation mitigation effects of EPCM/CNT were further investigated on the battery modules.The experimental results of thermal management tests showed that EPCM/CNT not only slowed down the temperature rising of the module but also improved the temperature uniformity during normal operation.The peak battery temperature decreased from 76℃to 61.2℃at 2 C discharge rate and the temperature difference was controlled below 3℃.Moreover,the results of TR propagation tests demonstrated that nonflammable EPCM/CNT with good heat absorption could work as a TR barrier,which exhibited effective mitigation on TR and TR propagation.The trigger time of three cells was successfully delayed by 129,474 and 551 s,respectively and the propagation intervals were greatly extended as well.
基金supported by the National Natural Science Foundation of China (Grant No.12072331)the Science Challenge Project (Grant No.TZ2018001)+2 种基金the Japan Society for the Promotion of Science (Grant Nos.17H04820 and 21H01677)the Foundation of the United Laboratory of High-Pressure Physics and Earthquake Scienceperformed under the approval of the Photon Factory Program Advisory Committee (Proposal Nos.2016S2-006 and 2020G680)。
文摘A time-resolved x-ray diffraction technique is employed to monitor the structural transformation of laser-shocked bismuth.Results reveal a retarded transformation from the shock-induced Bi-Ⅴphase to a metastable Bi-Ⅳphase during the shock release,instead of the thermodynamically stable Bi-Ⅲphase.The emergence of the metastable Bi-Ⅳphase is understood by the competitive interplay between two transformation pathways towards the Bi-Ⅳand Bi-Ⅲ,respectively.The former is more rapid than the latter because the Bi-Ⅴto B-Ⅳtransformation is driven by interaction between the closest atoms while the Bi-Ⅴto B-Ⅲtransformation requires interaction between the second-closest atoms.The nucleation time for the Bi-Ⅴto Bi-Ⅳtransformation is determined to be 5.1±0.9 ns according to a classical nucleation model.This observation demonstrates the importance of the formation of the transient metastable phases,which can change the phase transformation pathway in a dynamic process.
