Because of an unfortunate mistake by authors,the Project(5227010679)of Foundation item was wrong.The corrected Project is shown as follows:Project(52271073).
Effects of nickel component,thiourea,glue and chloride ions and their interactions on the passivation of copper–nickel based alloy scrap anodes were investigated by combining conventional electrochemical techniques.R...Effects of nickel component,thiourea,glue and chloride ions and their interactions on the passivation of copper–nickel based alloy scrap anodes were investigated by combining conventional electrochemical techniques.Results obtained from chronopotentiometry and linear voltammetry curves showed that the Ni component made electrochemical stability of the anode strong and difficult to be corroded,caused by the adsorption of generated Cu2O,NiO or copper powder to the anode surface.The Ni2+reducing Cu2+to Cu+or copper powder aggravated the anode passivation.In a certain range of the glue concentration≤8×10–6 or thiourea concentration≤4×10–6,the increase of glue or thiourea concentration increases the anode passivation time.Over this range,glue and thiourea played an adverse effect.The increase of chloride ions concentration led to the increase in passivation time.展开更多
Inconel 718 and Waspaloy, Nickel-based super-heat-resistant alloy, are high-strength, thermal-resistant and corrosion-resistant alloy that are widely used in parts of gas turbines and airplane engines. Due to their ex...Inconel 718 and Waspaloy, Nickel-based super-heat-resistant alloy, are high-strength, thermal-resistant and corrosion-resistant alloy that are widely used in parts of gas turbines and airplane engines. Due to their extremely tough and thermal-resistant nature, they are well known as materials that are difficult to cut. Shape holes on a disc of an aircraft engine, made of Ni-based super-heat-resistant alloy, are required with good surface integrity and geometric accuracy. This kind of shape hole is produced by EDM (Electro-discharge machining) currently. It is necessary to investigate an alternative machining process to reduce the process time and improve the surface quality. This paper presents an experimental study on the machining methods for the shape hole of Ni-base super-heat-resistant alloy Inconel 718 and Waspaloy. The feasibility using milling or/and grinding as an alternative for currently EDM process to machine shape holes is assessed by observing the wear and breakage of the cutting tools and grinder and analyzing the hole surface integrity and geometric accuracy. The results show that the milling process of Inconel 718 and Waspaloy can produce shape holes with acceptable surface roughness and geometric accuracy efficiently. The machined Waspaloy shape holes reveal a slight decrease tendency in section dimension from the top of the its bottom. There is a larger deviation from the nominal profile at the segment with smaller radius. A thin softened surface layer with thickness smaller than 60 μm occurs on the machined Waspaloy shape holes. The softening and work hardening become remarkable with the progress of tool wear.展开更多
文摘Because of an unfortunate mistake by authors,the Project(5227010679)of Foundation item was wrong.The corrected Project is shown as follows:Project(52271073).
基金Project(51574135)supported by the National Natural Science Foundation of ChinaProject(KKPT201563022)supported by the Collaborative Innovation Center of Kunming University of Science and Technology,China
文摘Effects of nickel component,thiourea,glue and chloride ions and their interactions on the passivation of copper–nickel based alloy scrap anodes were investigated by combining conventional electrochemical techniques.Results obtained from chronopotentiometry and linear voltammetry curves showed that the Ni component made electrochemical stability of the anode strong and difficult to be corroded,caused by the adsorption of generated Cu2O,NiO or copper powder to the anode surface.The Ni2+reducing Cu2+to Cu+or copper powder aggravated the anode passivation.In a certain range of the glue concentration≤8×10–6 or thiourea concentration≤4×10–6,the increase of glue or thiourea concentration increases the anode passivation time.Over this range,glue and thiourea played an adverse effect.The increase of chloride ions concentration led to the increase in passivation time.
文摘Inconel 718 and Waspaloy, Nickel-based super-heat-resistant alloy, are high-strength, thermal-resistant and corrosion-resistant alloy that are widely used in parts of gas turbines and airplane engines. Due to their extremely tough and thermal-resistant nature, they are well known as materials that are difficult to cut. Shape holes on a disc of an aircraft engine, made of Ni-based super-heat-resistant alloy, are required with good surface integrity and geometric accuracy. This kind of shape hole is produced by EDM (Electro-discharge machining) currently. It is necessary to investigate an alternative machining process to reduce the process time and improve the surface quality. This paper presents an experimental study on the machining methods for the shape hole of Ni-base super-heat-resistant alloy Inconel 718 and Waspaloy. The feasibility using milling or/and grinding as an alternative for currently EDM process to machine shape holes is assessed by observing the wear and breakage of the cutting tools and grinder and analyzing the hole surface integrity and geometric accuracy. The results show that the milling process of Inconel 718 and Waspaloy can produce shape holes with acceptable surface roughness and geometric accuracy efficiently. The machined Waspaloy shape holes reveal a slight decrease tendency in section dimension from the top of the its bottom. There is a larger deviation from the nominal profile at the segment with smaller radius. A thin softened surface layer with thickness smaller than 60 μm occurs on the machined Waspaloy shape holes. The softening and work hardening become remarkable with the progress of tool wear.