The weak interface interaction and solid-solid phase transition have long been a conundrum for 1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane(HMX)-based polymer-bonded explosives(PBX).A two-step strategy that involves...The weak interface interaction and solid-solid phase transition have long been a conundrum for 1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane(HMX)-based polymer-bonded explosives(PBX).A two-step strategy that involves the pretreatment of HMX to endow—OH groups on the surface via polyalcohol bonding agent modification and in situ coating with nitrate ester-containing polymer,was proposed to address the problem.Two types of energetic polyether—glycidyl azide polymer(GAP)and nitrate modified GAP(GNP)were grafted onto HMX crystal based on isocyanate addition reaction bridged through neutral polymeric bonding agent(NPBA)layer.The morphology and structure of the HMX-based composites were characterized in detail and the core-shell structure was validated.The grafted polymers obviously enhanced the adhesion force between HMX crystals and fluoropolymer(F2314)binder.Due to the interfacial reinforcement among the components,the two HMX-based composites exhibited a remarkable increment of phase transition peak temperature by 10.2°C and 19.6°C with no more than 1.5%shell content,respectively.Furthermore,the impact and friction sensitivity of the composites decreased significantly as a result of the barrier produced by the grafted polymers.These findings will enhance the future prospects for the interface design of energetic composites aiming to solve the weak interface and safety concerns.展开更多
Ce O2@Si O2 core-shell nanoparticles were prepared by microemulsion method, and metalloporphyrins were immobilized on the Ce O2@Si O2 core-shell nanoparticles surface via amide bond. The supported metalloporphyrin cat...Ce O2@Si O2 core-shell nanoparticles were prepared by microemulsion method, and metalloporphyrins were immobilized on the Ce O2@Si O2 core-shell nanoparticles surface via amide bond. The supported metalloporphyrin catalysts were characterized by N2 adsorption-desorption isotherm(BET), scanning electron microscopy(SEM), transmission electron microscopy(TEM), X-ray diffraction(XRD), ultraviolet and visible spectroscopy(UV-Vis), and Fourier transform infrared spectroscopy(FT-IR). The results show that the morphology of Ce O2@Si O2 nanoparticles is core-shell microspheres with about 30 nm in diameter, and metalloporphyrins are immobilized on the Ce O2@Si O2 core-shell nanoparticles via amide bond. Especially, the core-shell structure contains multi Ce O2 core and thin Si O2 shell, which may benefit the synergistic effect between the Ce O2 core and the porphyrin anchored on the very thin Si O2 shell. As a result, this supported metalloporphyrin catalysts present comparably high catalytic activity and stability for oxidation of ethylbenzene with molecular oxygen, namely, ethylbenzene conversion remains around 12% with identical selectivity of about 80% for acetophenone even after six-times reuse of the catalyst.展开更多
Fe/C multilayer thin films were deposited by magnetron sputtering. Small angle X-ray diffraction measurements show very well periodicity of the samples. The modulation period determined from a modified Bragg equation ...Fe/C multilayer thin films were deposited by magnetron sputtering. Small angle X-ray diffraction measurements show very well periodicity of the samples. The modulation period determined from a modified Bragg equation agrees well with that determined from deposition rate. The interfacial roughness parameter ξof several samples calculated by X-ray diffraction is between 3.5(?) and 5.6(?).展开更多
In order to further investigate the surface flashover mechanism in vacuum, the surface flashover and electric field distribution of multilayer organic insulation structure are studied and developed based on the previo...In order to further investigate the surface flashover mechanism in vacuum, the surface flashover and electric field distribution of multilayer organic insulation structure are studied and developed based on the previous studies. The samples of multilayer organic insulation structure are prepared by inserting multilayer organic composite material with different relative permittivity between the electrode and the dielectric. Two multilayer organic insulation structures are prepared in this study. One is the cylindrical samples, the other is 45° samples. The impulse (1.2/50 μs) and DC flashover voltages in vacuum are tested, and the electric field distributions of two insulation structures are analyzed by ANSYS. It is found that these two insulation structure could effectively improve the surface flashover performance in vacuum. The results indicate that the highest impulse first flashover voltage of cylindrical samples reaches 65 kV and increases by 25% under im- pulse voltage. The highest first flashover voltage of /c samples reaches 81 kV and increases by 32% under impulse voltage. The results of electric field simulation demonstrate that different mechanisms exist between 45° insulation structure and cylindrical structure.展开更多
An indoor location system based on multilayer artificial neural network（ANN） with area division is proposed.The characteristics of recorded signal strength（RSS）,or signal to noise ratio（SNR） from each available ...An indoor location system based on multilayer artificial neural network（ANN） with area division is proposed.The characteristics of recorded signal strength（RSS）,or signal to noise ratio（SNR） from each available access points（APs）,are utilized to establish the radio map in the off-line phase.And in the on-line phase,the two or three dimensional coordinates of mobile terminals（MTs） are estimated according to the similarity between the new recorded RSS or SNR and fingerprints pre-stored in radio map.Although the feed-forward ANN with three layers is sufficient to describe any nonlinear mapping relationship between inputs and outputs with finite discontinuous points,the efficient inputs for better training performances are difficult to be determined because of complex and dynamic indoor environment.Then,the discussion of distance relativity for different signal characteristics and optimal strategies for multi-mode phenomenon avoidance is presented.And also,the feasibility and effectiveness of this method are verified based on the experimental comparison with normal ANN without area division,K-nearest neighbor（KNN） and probability methods in typical office environment.展开更多
The core-shell 2,4,6,8,10,12-Hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane/2,4,6-Trinitrotoluene(CL-20/TNT)composite was prepared by spray-drying method in which sensitive high energy explosive(CL-20)was coated with in...The core-shell 2,4,6,8,10,12-Hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane/2,4,6-Trinitrotoluene(CL-20/TNT)composite was prepared by spray-drying method in which sensitive high energy explosive(CL-20)was coated with insensitive explosive(TNT).The structure and properties of different formulations of CL-20/TNT composite and CL-20/TNT mixture were characterized by scanning electron microscopy(SEM),Transmission electron microscopy(TEM),Laser particle size analyzer,X-ray photoelectron spectroscopy(XPS),X-ray diffraction(XRD),differential scanning calorimetry(DSC),impact sensitivity test and detonation performance.The results of SEM,TEM,XPS and XRD show that e-CL-20 particles are coated by TNT.When the ratio of CL-20/TNT is 75/25,core-shell structure is well formed,and thickness of the shell is about 20e30 nm.And the analysis of heat and impact show that with the increase of TNT content,the TNT coating on the core-shell composite material can not only catalyze the thermal decomposition of core material(CL-20),but also greatly reduce the impact sensitivity.Compared with the CL-20/TNT mixture(75/25)at the same ratio,the characteristic drop height of core-shell CL-20/TNT composite(75/25)increased by 47.6%and the TNT coating can accelerate the nuclear decomposition in the CL-20/TNT composites.Therefore,the preparation of the core-shell composites can be regarded as a unique means,by which the composites are characterized by controllable decomposition rate,high energy and excellent mechanical sensitivity and could be applied to propellants and other fields.展开更多
A facile and economical approach was developed for the large-scale production of powdered core-shell structured PTFE/Al (CS-PA) energetic materials through ultrasonic-assisted mixing. The low-cost micrometer-sized PTF...A facile and economical approach was developed for the large-scale production of powdered core-shell structured PTFE/Al (CS-PA) energetic materials through ultrasonic-assisted mixing. The low-cost micrometer-sized PTFE and Al particles were used as starting materials. Under high-power ultrasonic waves, the PTFE powder was dispersed into nano-to sub-micrometer-sized particles and then encapsulated the Al microparticles to form the core-shell structure. The heat of combustion, burning rate, and pressurization rate of the powdered CS-PA were measured. The thermal-initiated reaction behavior was further evaluated using thermogravimetry-differential scanning calorimetry. Subsequently, the bulk CS-PA with a uniform microstructure was obtained via cold isostatic pressing of the powdered CS-PA followed by vacuum sintering. For the bulk CS-PA, the quasi-static compression behavior was characterized, and the impact-initiated reaction processes were conducted using the Split Hopkinson Pressure Bar (SHPB) and evaluated by a high-speed camera. Compared to physically mixed PTFE/Al materials, the powdered and bulk CS-PA demonstrated enhanced thermal- and impact-initiated reaction characteristics respectively, proving the effectiveness of our approach for constructing core-shell structures.展开更多
通过流变特性和3D打印特性评估,筛选叶黄素负载层和空载层乳液凝胶的制备参数,运用双喷头3D打印技术将叶黄素负载层与空载层间隔交错打印,构建不同间隔多层结构的3D打印凝胶体系,探究间隔多层结构的间隔层数和空载层定位对叶黄素的释放...通过流变特性和3D打印特性评估,筛选叶黄素负载层和空载层乳液凝胶的制备参数,运用双喷头3D打印技术将叶黄素负载层与空载层间隔交错打印,构建不同间隔多层结构的3D打印凝胶体系,探究间隔多层结构的间隔层数和空载层定位对叶黄素的释放特性和生物可及性的影响。结果表明,通过提升油相体积分数、分离乳清蛋白(Whey Protein Isolate,WPI)浓度以及叶黄素载量,可以有效地提高叶黄素乳液凝胶的表观黏度、储能模量和损耗模量,同时降低蠕变恢复应变,增强叶黄素乳液凝胶的黏弹性和抵抗形变的能力,从而显著提升了叶黄素乳液凝胶的打印精确度和稳定性;当油相体积分数为15%、WPI浓度为10%和叶黄素载量为1.5%时,叶黄素乳液凝胶的3D打印效果最佳,打印精确性和稳定性分别为96.94%和97.60%。经体外模拟消化发现,间隔多层结构设计可有效改变叶黄素的释放行为,显著降低了叶黄素在胃消化阶段的释放率,从21.61%最低降至7.26%,使叶黄素在肠消化阶段表现出一定的时滞性,并显著提高叶黄素的生物可及性,最高达到了47.97%。本研究将为解决叶黄素生物可及性低的问题和运载工具的设计提供新的思路和理论依据。展开更多
Broadband near-infrared(NIR)luminescent materials have shown great promise in applications such as optical communication,biomedicine,and optoelectronic devices.However,the current research is focused on phos⁃phors and...Broadband near-infrared(NIR)luminescent materials have shown great promise in applications such as optical communication,biomedicine,and optoelectronic devices.However,the current research is focused on phos⁃phors and glasses,and it is important to develop broadband NIR luminescent nanomaterials.Here,we report an erbi⁃um-sensitized core-shell nanocrystal design for broadband NIR emission.Based on the structural design with suitable dopings of Tm^(3+)and Ho^(3+),the broadband NIR emission covering 1.5-2.1μm region is achieved under 980 nm and 808 nm excitations.Moreover,the emission intensity is further enhanced by introducing Yb^(3+)and Nd^(3+)into the sam⁃ple,respectively,and the energy transfer processes between them are systematically discussed.Our results present a novel approach for developing broadband NIR luminescent materials and devices.展开更多
基金the support for this work by National Natural Science Foundation of China(Grant Nos.22175139 and 22105156)。
文摘The weak interface interaction and solid-solid phase transition have long been a conundrum for 1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane(HMX)-based polymer-bonded explosives(PBX).A two-step strategy that involves the pretreatment of HMX to endow—OH groups on the surface via polyalcohol bonding agent modification and in situ coating with nitrate ester-containing polymer,was proposed to address the problem.Two types of energetic polyether—glycidyl azide polymer(GAP)and nitrate modified GAP(GNP)were grafted onto HMX crystal based on isocyanate addition reaction bridged through neutral polymeric bonding agent(NPBA)layer.The morphology and structure of the HMX-based composites were characterized in detail and the core-shell structure was validated.The grafted polymers obviously enhanced the adhesion force between HMX crystals and fluoropolymer(F2314)binder.Due to the interfacial reinforcement among the components,the two HMX-based composites exhibited a remarkable increment of phase transition peak temperature by 10.2°C and 19.6°C with no more than 1.5%shell content,respectively.Furthermore,the impact and friction sensitivity of the composites decreased significantly as a result of the barrier produced by the grafted polymers.These findings will enhance the future prospects for the interface design of energetic composites aiming to solve the weak interface and safety concerns.
基金Projects(J21103045,J1210040,J1103312) supported by the National Natural Science Foundation of ChinaProject supported by the Fundamental Research Funds for the Central Universities of China
文摘Ce O2@Si O2 core-shell nanoparticles were prepared by microemulsion method, and metalloporphyrins were immobilized on the Ce O2@Si O2 core-shell nanoparticles surface via amide bond. The supported metalloporphyrin catalysts were characterized by N2 adsorption-desorption isotherm(BET), scanning electron microscopy(SEM), transmission electron microscopy(TEM), X-ray diffraction(XRD), ultraviolet and visible spectroscopy(UV-Vis), and Fourier transform infrared spectroscopy(FT-IR). The results show that the morphology of Ce O2@Si O2 nanoparticles is core-shell microspheres with about 30 nm in diameter, and metalloporphyrins are immobilized on the Ce O2@Si O2 core-shell nanoparticles via amide bond. Especially, the core-shell structure contains multi Ce O2 core and thin Si O2 shell, which may benefit the synergistic effect between the Ce O2 core and the porphyrin anchored on the very thin Si O2 shell. As a result, this supported metalloporphyrin catalysts present comparably high catalytic activity and stability for oxidation of ethylbenzene with molecular oxygen, namely, ethylbenzene conversion remains around 12% with identical selectivity of about 80% for acetophenone even after six-times reuse of the catalyst.
文摘Fe/C multilayer thin films were deposited by magnetron sputtering. Small angle X-ray diffraction measurements show very well periodicity of the samples. The modulation period determined from a modified Bragg equation agrees well with that determined from deposition rate. The interfacial roughness parameter ξof several samples calculated by X-ray diffraction is between 3.5(?) and 5.6(?).
基金Project supported by National Science Fund for Outstanding Young Scholars of China (50625721)National Basic Research Program of China (973 Program) (2011CB 209404)
文摘In order to further investigate the surface flashover mechanism in vacuum, the surface flashover and electric field distribution of multilayer organic insulation structure are studied and developed based on the previous studies. The samples of multilayer organic insulation structure are prepared by inserting multilayer organic composite material with different relative permittivity between the electrode and the dielectric. Two multilayer organic insulation structures are prepared in this study. One is the cylindrical samples, the other is 45° samples. The impulse (1.2/50 μs) and DC flashover voltages in vacuum are tested, and the electric field distributions of two insulation structures are analyzed by ANSYS. It is found that these two insulation structure could effectively improve the surface flashover performance in vacuum. The results indicate that the highest impulse first flashover voltage of cylindrical samples reaches 65 kV and increases by 25% under im- pulse voltage. The highest first flashover voltage of /c samples reaches 81 kV and increases by 32% under impulse voltage. The results of electric field simulation demonstrate that different mechanisms exist between 45° insulation structure and cylindrical structure.
基金supported by the National High Technology Research and Development Program of China (863 Program)(2008AA12Z305)
文摘An indoor location system based on multilayer artificial neural network（ANN） with area division is proposed.The characteristics of recorded signal strength（RSS）,or signal to noise ratio（SNR） from each available access points（APs）,are utilized to establish the radio map in the off-line phase.And in the on-line phase,the two or three dimensional coordinates of mobile terminals（MTs） are estimated according to the similarity between the new recorded RSS or SNR and fingerprints pre-stored in radio map.Although the feed-forward ANN with three layers is sufficient to describe any nonlinear mapping relationship between inputs and outputs with finite discontinuous points,the efficient inputs for better training performances are difficult to be determined because of complex and dynamic indoor environment.Then,the discussion of distance relativity for different signal characteristics and optimal strategies for multi-mode phenomenon avoidance is presented.And also,the feasibility and effectiveness of this method are verified based on the experimental comparison with normal ANN without area division,K-nearest neighbor（KNN） and probability methods in typical office environment.
文摘The core-shell 2,4,6,8,10,12-Hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane/2,4,6-Trinitrotoluene(CL-20/TNT)composite was prepared by spray-drying method in which sensitive high energy explosive(CL-20)was coated with insensitive explosive(TNT).The structure and properties of different formulations of CL-20/TNT composite and CL-20/TNT mixture were characterized by scanning electron microscopy(SEM),Transmission electron microscopy(TEM),Laser particle size analyzer,X-ray photoelectron spectroscopy(XPS),X-ray diffraction(XRD),differential scanning calorimetry(DSC),impact sensitivity test and detonation performance.The results of SEM,TEM,XPS and XRD show that e-CL-20 particles are coated by TNT.When the ratio of CL-20/TNT is 75/25,core-shell structure is well formed,and thickness of the shell is about 20e30 nm.And the analysis of heat and impact show that with the increase of TNT content,the TNT coating on the core-shell composite material can not only catalyze the thermal decomposition of core material(CL-20),but also greatly reduce the impact sensitivity.Compared with the CL-20/TNT mixture(75/25)at the same ratio,the characteristic drop height of core-shell CL-20/TNT composite(75/25)increased by 47.6%and the TNT coating can accelerate the nuclear decomposition in the CL-20/TNT composites.Therefore,the preparation of the core-shell composites can be regarded as a unique means,by which the composites are characterized by controllable decomposition rate,high energy and excellent mechanical sensitivity and could be applied to propellants and other fields.
基金This work was supported by the National Natural Science Foundation of China(No.51571033,11804022)the Science and Technology on Transient Impact Laboratory Foundation(No.6142606183208).
文摘A facile and economical approach was developed for the large-scale production of powdered core-shell structured PTFE/Al (CS-PA) energetic materials through ultrasonic-assisted mixing. The low-cost micrometer-sized PTFE and Al particles were used as starting materials. Under high-power ultrasonic waves, the PTFE powder was dispersed into nano-to sub-micrometer-sized particles and then encapsulated the Al microparticles to form the core-shell structure. The heat of combustion, burning rate, and pressurization rate of the powdered CS-PA were measured. The thermal-initiated reaction behavior was further evaluated using thermogravimetry-differential scanning calorimetry. Subsequently, the bulk CS-PA with a uniform microstructure was obtained via cold isostatic pressing of the powdered CS-PA followed by vacuum sintering. For the bulk CS-PA, the quasi-static compression behavior was characterized, and the impact-initiated reaction processes were conducted using the Split Hopkinson Pressure Bar (SHPB) and evaluated by a high-speed camera. Compared to physically mixed PTFE/Al materials, the powdered and bulk CS-PA demonstrated enhanced thermal- and impact-initiated reaction characteristics respectively, proving the effectiveness of our approach for constructing core-shell structures.
文摘通过流变特性和3D打印特性评估,筛选叶黄素负载层和空载层乳液凝胶的制备参数,运用双喷头3D打印技术将叶黄素负载层与空载层间隔交错打印,构建不同间隔多层结构的3D打印凝胶体系,探究间隔多层结构的间隔层数和空载层定位对叶黄素的释放特性和生物可及性的影响。结果表明,通过提升油相体积分数、分离乳清蛋白(Whey Protein Isolate,WPI)浓度以及叶黄素载量,可以有效地提高叶黄素乳液凝胶的表观黏度、储能模量和损耗模量,同时降低蠕变恢复应变,增强叶黄素乳液凝胶的黏弹性和抵抗形变的能力,从而显著提升了叶黄素乳液凝胶的打印精确度和稳定性;当油相体积分数为15%、WPI浓度为10%和叶黄素载量为1.5%时,叶黄素乳液凝胶的3D打印效果最佳,打印精确性和稳定性分别为96.94%和97.60%。经体外模拟消化发现,间隔多层结构设计可有效改变叶黄素的释放行为,显著降低了叶黄素在胃消化阶段的释放率,从21.61%最低降至7.26%,使叶黄素在肠消化阶段表现出一定的时滞性,并显著提高叶黄素的生物可及性,最高达到了47.97%。本研究将为解决叶黄素生物可及性低的问题和运载工具的设计提供新的思路和理论依据。
文摘Broadband near-infrared(NIR)luminescent materials have shown great promise in applications such as optical communication,biomedicine,and optoelectronic devices.However,the current research is focused on phos⁃phors and glasses,and it is important to develop broadband NIR luminescent nanomaterials.Here,we report an erbi⁃um-sensitized core-shell nanocrystal design for broadband NIR emission.Based on the structural design with suitable dopings of Tm^(3+)and Ho^(3+),the broadband NIR emission covering 1.5-2.1μm region is achieved under 980 nm and 808 nm excitations.Moreover,the emission intensity is further enhanced by introducing Yb^(3+)and Nd^(3+)into the sam⁃ple,respectively,and the energy transfer processes between them are systematically discussed.Our results present a novel approach for developing broadband NIR luminescent materials and devices.
