Femtosecond laser processing is an important machining method for micro-optical components such as Fresnel zone plate(FZP).However,the low processing efficiency of the femtosecond laser restricts its application.Here,...Femtosecond laser processing is an important machining method for micro-optical components such as Fresnel zone plate(FZP).However,the low processing efficiency of the femtosecond laser restricts its application.Here,a femtosecond laser Bessel beam is proposed to process micro-FZP,which is modulated from a Gaussian beam to a Bessel annular beam.The processing time for FZP with an outer diameter of 60μm is reduced from 30 min to 1.5 min on an important semiconductor material gallium arsenide(GaAs),which significantly improves the processing efficiency.In the modulation process,a central ablation hole that has an adverse effect on the diffraction performance is produced,and the adverse effect is eliminated by superimposing the blazed grating hologram.Meanwhile,the FZP machined by spatial light modulator(SLM)has good morphology and higher diffraction efficiency,which provides a strong guarantee for the application of micro-FZP in computed tomography and solar photovoltaic cells.展开更多
In the high speed target environment,there exists serious Doppler effect in the low pulse repetition frequency（LPRF） modulated frequency stepped frequency（MFSF） radar signal.The velocity range of the target is lar...In the high speed target environment,there exists serious Doppler effect in the low pulse repetition frequency（LPRF） modulated frequency stepped frequency（MFSF） radar signal.The velocity range of the target is large and the velocity is high ambiguous,so the single method is difficult to satisfy the velocity measurement requirement.For this problem,a novel method is presented,it is a combination of cross-correlation inner frame velocity measurement and range-Doppler coupling velocity measurement.The cross-correlation inner frame method,overcoming the low Doppler tolerance of the cross-correlation between frames,can obtain the coarse velocity of the high speed target,and then the precision velocity can be obtained with the range-Doppler coupling method.The simulation results confirm the method is effective,and also it is well real-time and easy to the project application.展开更多
With appropriate geometry configuration, helicopter- borne rotating synthetic aperture radar （ROSAR） can break through the limitations of monostatic synthetic aperture radar （SAR） on forward-looking imaging. With ...With appropriate geometry configuration, helicopter- borne rotating synthetic aperture radar （ROSAR） can break through the limitations of monostatic synthetic aperture radar （SAR） on forward-looking imaging. With this capability, ROSAR has extensive potential applications, such as self-navigation and self-landing. Moreover, it has many advantages if combined with the frequency modulated continuous wave （FMCW） technology. A novel geometric configuration and an imaging algorithm for helicopter-borne FMCW-ROSAR are proposed. Firstly, by per- forming the equivalent phase center principle, the separated trans- mitting and receiving antenna system is equalized to the case of system configuration with antenna for both transmitting and receiving signals. Based on this, the accurate two-dimensional spectrum is obtained and the Doppler frequency shift effect in- duced by the continuous motion of the platform during the long pulse duration is compensated. Next, the impacts of the velocity approximation error on the imaging algorithm are analyzed in de- tail, and the system parameters selection and resolution analysis are presented. The well-focused SAR image is then obtained by using the improved Omega-K algorithm incorporating the accurate compensation method for the velocity approximation error. FJnally, correctness of the analysis and effectiveness of the proposed al- gorithm are demonstrated through simulation results.展开更多
In electromagnetic countermeasures circumstances,synthetic aperture radar(SAR)imagery usually suffers from severe quality degradation from modulated interrupt sampling repeater jamming(MISRJ),which usually owes consid...In electromagnetic countermeasures circumstances,synthetic aperture radar(SAR)imagery usually suffers from severe quality degradation from modulated interrupt sampling repeater jamming(MISRJ),which usually owes considerable coherence with the SAR transmission waveform together with periodical modulation patterns.This paper develops an MISRJ suppression algorithm for SAR imagery with online dictionary learning.In the algorithm,the jamming modulation temporal properties are exploited with extracting and sorting MISRJ slices using fast-time autocorrelation.Online dictionary learning is followed to separate real signals from jamming slices.Under the learned representation,time-varying MISRJs are suppressed effectively.Both simulated and real-measured SAR data are also used to confirm advantages in suppressing time-varying MISRJs over traditional methods.展开更多
We propose the quadratic constrained formulas for the design of linear phase cosine modulated paraunitary filter banks given in references . Using these formulae, we can, directly, optimize the prototype filter coeff...We propose the quadratic constrained formulas for the design of linear phase cosine modulated paraunitary filter banks given in references . Using these formulae, we can, directly, optimize the prototype filter coefficients in a quadratic form. A design example is also given to demonstrate these formulae in this paper.展开更多
在雷达通信一体化领域,设计出既能实现雷达探测功能又能实现通信信息传输功能的同波形信号是至关重要的一个环节。针对在雷达信号脉冲内对通信信息调制后自相关性能低的问题,提出一种高频带利用率以及低自相关旁瓣的基于非线性调频(NLFM...在雷达通信一体化领域,设计出既能实现雷达探测功能又能实现通信信息传输功能的同波形信号是至关重要的一个环节。针对在雷达信号脉冲内对通信信息调制后自相关性能低的问题,提出一种高频带利用率以及低自相关旁瓣的基于非线性调频(NLFM)信号的雷达通信一体化信号形式。将NLFM信号作为16阶正交幅度调制(16QAM)信号的载波,建立NLFM-16QAM雷达通信一体化信号模型,分析该信号的模糊函数以及相关的雷达与通信性能。在此基础上,针对所提出的NLFM-16QAM信号因其通信基带信号的随机性使雷达功能受到影响,从而降低了运动目标探测性能这一问题,将一体化系统的接收端作出改进,提出小波包降噪联合自然梯度算法对NLFM-16QAM信号进行接收处理。仿真结果表明,所提信号的频带利用率明显高于低阶调制的雷达通信一体化信号的频带利用率,在自相关性能方面,所提信号比16QAM-LFM信号的积分旁瓣比降低了23.07 d B,峰值旁瓣比降低了26.08 d B,NLFM-16QAM信号在经过改进接收端的联合算法处理后,运动目标的检测结果获得显著改善。展开更多
The Nd Fe B/Co multilayer films were prepared by magnetron sputtering. After that, the samples were annealed at 600 ℃ for 20 min. The surface morphology, phase structures and magnetic properties of Mo（50 nm）/[Nd F...The Nd Fe B/Co multilayer films were prepared by magnetron sputtering. After that, the samples were annealed at 600 ℃ for 20 min. The surface morphology, phase structures and magnetic properties of Mo（50 nm）/[Nd Fe B（100 nm）/Co（y）]×10/Mo（50 nm） thin films were researched by AFM, XRD and VSM, respectively. The results show that the films show stronger perpendicular magnetic anisotropy. When the thickness of Co layers is 10 nm, the coercivity Hc⊥ is the maximum, 295 k A/m. However, for y=10-20, the reduced remanence M/Ms of films has increased. When the thickness of Co layers is 20-30 nm, the Nd Fe B/Co multilayer films obtained more superior magnetic properties with M/Ms =0.95.展开更多
A 3D temperature field distribution of biological tissue for superficial hyperthermia using a pulse modulated microwave （PMMW） was presented. A 3D sliced homogeneous phantom was radiated by the PMMW and an infrared ...A 3D temperature field distribution of biological tissue for superficial hyperthermia using a pulse modulated microwave （PMMW） was presented. A 3D sliced homogeneous phantom was radiated by the PMMW and an infrared thermal imager was applied to image temperature distribution throughout the phantom. The period of the PMMW is 3 s and the output power is 35 W. The temperature rises by at least 3 ℃ in the phantom when the duty cycle varies from 1/3, 1/2, 2/3 to 1 （denoted by scenarios 1-4）. Both the accumulative temperature-volume histogram and the relative depth-area ratio histogram show that the maximum temperature rise （MTR） is 6.6 and 8 ℃ in scenarios 2 and 3, and they are superior to scenarios 1 and 4. Furthermore, the PMMW can control temperature field distribution of biological tissue. It provides both preliminary basis for thermal volume control and new technology for temperature control and monitor in superficial hyperthermia.展开更多
Dimmers are very widely applied in theatres,cinemas,dancing-parties, auditoriums and signal systems.They are usually supplied by single-stage AC/AC converters in the past with voltage regulation technique with the dis...Dimmers are very widely applied in theatres,cinemas,dancing-parties, auditoriums and signal systems.They are usually supplied by single-stage AC/AC converters in the past with voltage regulation technique with the disadvantages of high total harmonic distortion,low power factor and poor power transfer efficiency.This paper introduces a novel method-DC-modulation that implements DC/DC conversion technology into AC/AC converters.The DC-modulated single-stage PFC AC/AC converters effectively improved the power factor up to 0.999 and the power transfer efficiency up to 97.8 %.The experimental results verified our design and calculation.This technique will be widely used in light dimming and other industrial applications.展开更多
针对间歇采样转发干扰产生的假目标和目标高速运动产生的多普勒频移导致雷达脉压性能急剧下降的问题,提出一种高多普勒容限的线性调频离散相位编码(linear frequency modulation-discrete phase coding,LFM-DPC)复合调制相干波形集设计...针对间歇采样转发干扰产生的假目标和目标高速运动产生的多普勒频移导致雷达脉压性能急剧下降的问题,提出一种高多普勒容限的线性调频离散相位编码(linear frequency modulation-discrete phase coding,LFM-DPC)复合调制相干波形集设计方法。在一定多普勒频移范围内,以最小化未转发信号自模糊函数旁瓣能量以及未转发信号与转发信号互模糊函数能量建立优化模型,并设计一种基于KKT(Karush-Kuhn-Tucker)最优性条件的迭代算法对模型求解。仿真实验表明,相比于遗传算法和单一调制的LFM和DPC信号,基于KKT最优性条件的交替迭代优化算法优化的LFM-DPC波形集有更好的抗间歇采样转发干扰性能。展开更多
Target occlusion poses a significant challenge in computer vision,particularly in agricultural applications,where occlusion of crops can obscure key features and impair the model’s recognition performance.To address ...Target occlusion poses a significant challenge in computer vision,particularly in agricultural applications,where occlusion of crops can obscure key features and impair the model’s recognition performance.To address this challenge,a mushroom recognition method was proposed based on an erase module integrated into the EL-DenseNet model.EL-DenseNet,an extension of DenseNet,incorporated an erase attention module designed to enhance sensitivity to visible features.The erase module helped eliminate complex backgrounds and irrelevant information,allowing the mushroom body to be preserved and increasing recognition accuracy in cluttered environments.Considering the difficulty in distinguishing similar mushroom species,label smoothing regularization was employed to mitigate mislabeling errors that commonly arose from human observers.This strategy converted hard labels into soft labels during training,reducing the model’s overreliance on noisy labels and improving its generalization ability.Experimental results showed that the proposed EL-DenseNet,when combined with transfer learning,achieved a recognition accuracy of 96.7%for mushrooms in occluded and complex backgrounds.Compared with the original DenseNet and other classic models,this approach demonstrated superior accuracy and robustness,providing a promising solution for intelligent mushroom recognition.展开更多
针对多雷达辐射源脉冲交错背景下,线性调频(Linear Frequency Modulation,LFM)信号低信噪比导致的脉冲分裂带来原始信号参数难以估计的问题,本文提出了基于深度神经网络和直方图统计的LFM信号两阶段提取与参数估计方法。首先利用双向长...针对多雷达辐射源脉冲交错背景下,线性调频(Linear Frequency Modulation,LFM)信号低信噪比导致的脉冲分裂带来原始信号参数难以估计的问题,本文提出了基于深度神经网络和直方图统计的LFM信号两阶段提取与参数估计方法。首先利用双向长短时记忆网络挖掘原始脉冲流中LFM信号与非LFM信号的调制模式差异并进行分类;其次通过序列调频斜率直方图寻找LFM信号分裂脉冲序列间隐含的原始信号调频斜率信息,提取不同调频斜率的LFM信号脉冲子序列;最后在每个子序列中分别估计原始信号的参数。仿真实验结果表明,相较于传统的序列差值直方图算法和循环神经网络分选方法,本文所提方法能够更准确地提取出LFM脉冲信号,并得到较为精确的参数估计结果。展开更多
Energetic compounds bearing the trinitromethyl group are garnering broad attraction as potential candidates for a new generation of high energy dense oxidizers.In this work,an effective dual modulation strategy involv...Energetic compounds bearing the trinitromethyl group are garnering broad attraction as potential candidates for a new generation of high energy dense oxidizers.In this work,an effective dual modulation strategy involving both molecular isomerization and crystal morphology control was employed to design and optimize trinitromethyl-oxadiazole with improved comprehensive performance.Utilizing this dual strategy,3,5-bis(trinitromethyl)-1,2,4-oxadiazole(3)was synthesized,resulting in the formation of two distinct crystal morphologies(needle and sheet)corresponding to two crystal forms(3-a and3-b).Encouragingly,while maintaining ultra-high oxygen balance(21.73%),3 achieves impressive densities(1.97-1.98 g/cm^(3)).To our knowledge,the density of 1.98 g/cm^(3)for 3-a sets a new record among that of nitrogen-rich monocyclic compounds.Notably,practical crystal morphology prediction was creatively introduced to guide the experimental crystallization conditions of 3,increasing the impact sensitivity and friction sensitivity from 1 J to 80 N(3-a)to 10 J and 240 N(3-b),respectively.Additionally,the crystal structural analyses and theoretical calculations were conducted to elucidate the reasons of differences between 3-a and 3-b in density and stability.This work provides an efficient strategy to enhance performance of trinitromethyl derivatives,broadening the path and expanding the toolbox for energetic materials.展开更多
A generalized multiple-mode prolate spherical wave functions (PSWFs) multi-carrier with index modulation approach is proposed with the purpose of improving the spectral efficiency of PSWFs multi-carrier systems. The p...A generalized multiple-mode prolate spherical wave functions (PSWFs) multi-carrier with index modulation approach is proposed with the purpose of improving the spectral efficiency of PSWFs multi-carrier systems. The proposed method,based on the optimized multi-index modulation, does not limit the number of signals in the first and second constellations and abandons the concept of limiting the number of signals in different constellations. It successfully increases the spectrum efficiency of the system while expanding the number of modulation symbol combinations and the index dimension of PSWFs signals. The proposed method outperforms the PSWFs multi-carrier index modulation method based on optimized multiple indexes in terms of spectrum efficiency, but at the expense of system computational complexity and bit error performance. For example, with n=10 subcarriers and a bit error rate of 1×10^(-5),spectral efficiency can be raised by roughly 12.4%.展开更多
基金Projects(51875584,51875585,51975590)supported by the National Natural Science Foundation of China。
文摘Femtosecond laser processing is an important machining method for micro-optical components such as Fresnel zone plate(FZP).However,the low processing efficiency of the femtosecond laser restricts its application.Here,a femtosecond laser Bessel beam is proposed to process micro-FZP,which is modulated from a Gaussian beam to a Bessel annular beam.The processing time for FZP with an outer diameter of 60μm is reduced from 30 min to 1.5 min on an important semiconductor material gallium arsenide(GaAs),which significantly improves the processing efficiency.In the modulation process,a central ablation hole that has an adverse effect on the diffraction performance is produced,and the adverse effect is eliminated by superimposing the blazed grating hologram.Meanwhile,the FZP machined by spatial light modulator(SLM)has good morphology and higher diffraction efficiency,which provides a strong guarantee for the application of micro-FZP in computed tomography and solar photovoltaic cells.
文摘In the high speed target environment,there exists serious Doppler effect in the low pulse repetition frequency（LPRF） modulated frequency stepped frequency（MFSF） radar signal.The velocity range of the target is large and the velocity is high ambiguous,so the single method is difficult to satisfy the velocity measurement requirement.For this problem,a novel method is presented,it is a combination of cross-correlation inner frame velocity measurement and range-Doppler coupling velocity measurement.The cross-correlation inner frame method,overcoming the low Doppler tolerance of the cross-correlation between frames,can obtain the coarse velocity of the high speed target,and then the precision velocity can be obtained with the range-Doppler coupling method.The simulation results confirm the method is effective,and also it is well real-time and easy to the project application.
基金supported by the National Basic Research Program of China(2011CB707001)the Fundamental Research Funds for the Central Universities(106112015CDJXY500001CDJZR165505)
文摘With appropriate geometry configuration, helicopter- borne rotating synthetic aperture radar （ROSAR） can break through the limitations of monostatic synthetic aperture radar （SAR） on forward-looking imaging. With this capability, ROSAR has extensive potential applications, such as self-navigation and self-landing. Moreover, it has many advantages if combined with the frequency modulated continuous wave （FMCW） technology. A novel geometric configuration and an imaging algorithm for helicopter-borne FMCW-ROSAR are proposed. Firstly, by per- forming the equivalent phase center principle, the separated trans- mitting and receiving antenna system is equalized to the case of system configuration with antenna for both transmitting and receiving signals. Based on this, the accurate two-dimensional spectrum is obtained and the Doppler frequency shift effect in- duced by the continuous motion of the platform during the long pulse duration is compensated. Next, the impacts of the velocity approximation error on the imaging algorithm are analyzed in de- tail, and the system parameters selection and resolution analysis are presented. The well-focused SAR image is then obtained by using the improved Omega-K algorithm incorporating the accurate compensation method for the velocity approximation error. FJnally, correctness of the analysis and effectiveness of the proposed al- gorithm are demonstrated through simulation results.
基金supported by the National Natural Science Foundation of China(61771372,61771367,62101494)the National Outstanding Youth Science Fund Project(61525105)+1 种基金Shenzhen Science and Technology Program(KQTD20190929172704911)the Aeronautic al Science Foundation of China(2019200M1001)。
文摘In electromagnetic countermeasures circumstances,synthetic aperture radar(SAR)imagery usually suffers from severe quality degradation from modulated interrupt sampling repeater jamming(MISRJ),which usually owes considerable coherence with the SAR transmission waveform together with periodical modulation patterns.This paper develops an MISRJ suppression algorithm for SAR imagery with online dictionary learning.In the algorithm,the jamming modulation temporal properties are exploited with extracting and sorting MISRJ slices using fast-time autocorrelation.Online dictionary learning is followed to separate real signals from jamming slices.Under the learned representation,time-varying MISRJs are suppressed effectively.Both simulated and real-measured SAR data are also used to confirm advantages in suppressing time-varying MISRJs over traditional methods.
文摘We propose the quadratic constrained formulas for the design of linear phase cosine modulated paraunitary filter banks given in references . Using these formulae, we can, directly, optimize the prototype filter coefficients in a quadratic form. A design example is also given to demonstrate these formulae in this paper.
文摘在雷达通信一体化领域,设计出既能实现雷达探测功能又能实现通信信息传输功能的同波形信号是至关重要的一个环节。针对在雷达信号脉冲内对通信信息调制后自相关性能低的问题,提出一种高频带利用率以及低自相关旁瓣的基于非线性调频(NLFM)信号的雷达通信一体化信号形式。将NLFM信号作为16阶正交幅度调制(16QAM)信号的载波,建立NLFM-16QAM雷达通信一体化信号模型,分析该信号的模糊函数以及相关的雷达与通信性能。在此基础上,针对所提出的NLFM-16QAM信号因其通信基带信号的随机性使雷达功能受到影响,从而降低了运动目标探测性能这一问题,将一体化系统的接收端作出改进,提出小波包降噪联合自然梯度算法对NLFM-16QAM信号进行接收处理。仿真结果表明,所提信号的频带利用率明显高于低阶调制的雷达通信一体化信号的频带利用率,在自相关性能方面,所提信号比16QAM-LFM信号的积分旁瓣比降低了23.07 d B,峰值旁瓣比降低了26.08 d B,NLFM-16QAM信号在经过改进接收端的联合算法处理后,运动目标的检测结果获得显著改善。
文摘The Nd Fe B/Co multilayer films were prepared by magnetron sputtering. After that, the samples were annealed at 600 ℃ for 20 min. The surface morphology, phase structures and magnetic properties of Mo（50 nm）/[Nd Fe B（100 nm）/Co（y）]×10/Mo（50 nm） thin films were researched by AFM, XRD and VSM, respectively. The results show that the films show stronger perpendicular magnetic anisotropy. When the thickness of Co layers is 10 nm, the coercivity Hc⊥ is the maximum, 295 k A/m. However, for y=10-20, the reduced remanence M/Ms of films has increased. When the thickness of Co layers is 20-30 nm, the Nd Fe B/Co multilayer films obtained more superior magnetic properties with M/Ms =0.95.
基金Project(50977064) supported by the National Natural Science Foundation of China
文摘A 3D temperature field distribution of biological tissue for superficial hyperthermia using a pulse modulated microwave （PMMW） was presented. A 3D sliced homogeneous phantom was radiated by the PMMW and an infrared thermal imager was applied to image temperature distribution throughout the phantom. The period of the PMMW is 3 s and the output power is 35 W. The temperature rises by at least 3 ℃ in the phantom when the duty cycle varies from 1/3, 1/2, 2/3 to 1 （denoted by scenarios 1-4）. Both the accumulative temperature-volume histogram and the relative depth-area ratio histogram show that the maximum temperature rise （MTR） is 6.6 and 8 ℃ in scenarios 2 and 3, and they are superior to scenarios 1 and 4. Furthermore, the PMMW can control temperature field distribution of biological tissue. It provides both preliminary basis for thermal volume control and new technology for temperature control and monitor in superficial hyperthermia.
文摘Dimmers are very widely applied in theatres,cinemas,dancing-parties, auditoriums and signal systems.They are usually supplied by single-stage AC/AC converters in the past with voltage regulation technique with the disadvantages of high total harmonic distortion,low power factor and poor power transfer efficiency.This paper introduces a novel method-DC-modulation that implements DC/DC conversion technology into AC/AC converters.The DC-modulated single-stage PFC AC/AC converters effectively improved the power factor up to 0.999 and the power transfer efficiency up to 97.8 %.The experimental results verified our design and calculation.This technique will be widely used in light dimming and other industrial applications.
文摘针对间歇采样转发干扰产生的假目标和目标高速运动产生的多普勒频移导致雷达脉压性能急剧下降的问题,提出一种高多普勒容限的线性调频离散相位编码(linear frequency modulation-discrete phase coding,LFM-DPC)复合调制相干波形集设计方法。在一定多普勒频移范围内,以最小化未转发信号自模糊函数旁瓣能量以及未转发信号与转发信号互模糊函数能量建立优化模型,并设计一种基于KKT(Karush-Kuhn-Tucker)最优性条件的迭代算法对模型求解。仿真实验表明,相比于遗传算法和单一调制的LFM和DPC信号,基于KKT最优性条件的交替迭代优化算法优化的LFM-DPC波形集有更好的抗间歇采样转发干扰性能。
文摘Target occlusion poses a significant challenge in computer vision,particularly in agricultural applications,where occlusion of crops can obscure key features and impair the model’s recognition performance.To address this challenge,a mushroom recognition method was proposed based on an erase module integrated into the EL-DenseNet model.EL-DenseNet,an extension of DenseNet,incorporated an erase attention module designed to enhance sensitivity to visible features.The erase module helped eliminate complex backgrounds and irrelevant information,allowing the mushroom body to be preserved and increasing recognition accuracy in cluttered environments.Considering the difficulty in distinguishing similar mushroom species,label smoothing regularization was employed to mitigate mislabeling errors that commonly arose from human observers.This strategy converted hard labels into soft labels during training,reducing the model’s overreliance on noisy labels and improving its generalization ability.Experimental results showed that the proposed EL-DenseNet,when combined with transfer learning,achieved a recognition accuracy of 96.7%for mushrooms in occluded and complex backgrounds.Compared with the original DenseNet and other classic models,this approach demonstrated superior accuracy and robustness,providing a promising solution for intelligent mushroom recognition.
文摘针对多雷达辐射源脉冲交错背景下,线性调频(Linear Frequency Modulation,LFM)信号低信噪比导致的脉冲分裂带来原始信号参数难以估计的问题,本文提出了基于深度神经网络和直方图统计的LFM信号两阶段提取与参数估计方法。首先利用双向长短时记忆网络挖掘原始脉冲流中LFM信号与非LFM信号的调制模式差异并进行分类;其次通过序列调频斜率直方图寻找LFM信号分裂脉冲序列间隐含的原始信号调频斜率信息,提取不同调频斜率的LFM信号脉冲子序列;最后在每个子序列中分别估计原始信号的参数。仿真实验结果表明,相较于传统的序列差值直方图算法和循环神经网络分选方法,本文所提方法能够更准确地提取出LFM脉冲信号,并得到较为精确的参数估计结果。
基金supported by the National Natural Science Foundation of China(No.22375021,22235003,22261132516&22205021)the BIT Research and Innovation 265 Promoting Project(Grant No.2023YCXZ017)。
文摘Energetic compounds bearing the trinitromethyl group are garnering broad attraction as potential candidates for a new generation of high energy dense oxidizers.In this work,an effective dual modulation strategy involving both molecular isomerization and crystal morphology control was employed to design and optimize trinitromethyl-oxadiazole with improved comprehensive performance.Utilizing this dual strategy,3,5-bis(trinitromethyl)-1,2,4-oxadiazole(3)was synthesized,resulting in the formation of two distinct crystal morphologies(needle and sheet)corresponding to two crystal forms(3-a and3-b).Encouragingly,while maintaining ultra-high oxygen balance(21.73%),3 achieves impressive densities(1.97-1.98 g/cm^(3)).To our knowledge,the density of 1.98 g/cm^(3)for 3-a sets a new record among that of nitrogen-rich monocyclic compounds.Notably,practical crystal morphology prediction was creatively introduced to guide the experimental crystallization conditions of 3,increasing the impact sensitivity and friction sensitivity from 1 J to 80 N(3-a)to 10 J and 240 N(3-b),respectively.Additionally,the crystal structural analyses and theoretical calculations were conducted to elucidate the reasons of differences between 3-a and 3-b in density and stability.This work provides an efficient strategy to enhance performance of trinitromethyl derivatives,broadening the path and expanding the toolbox for energetic materials.
基金supported by the China National Postdoctoral Program for Innovative Talents(BX20200039)the Special Fund Project of“Mount Taishan Scholars”Construction Project in Shandong Province(ts20081130).
文摘A generalized multiple-mode prolate spherical wave functions (PSWFs) multi-carrier with index modulation approach is proposed with the purpose of improving the spectral efficiency of PSWFs multi-carrier systems. The proposed method,based on the optimized multi-index modulation, does not limit the number of signals in the first and second constellations and abandons the concept of limiting the number of signals in different constellations. It successfully increases the spectrum efficiency of the system while expanding the number of modulation symbol combinations and the index dimension of PSWFs signals. The proposed method outperforms the PSWFs multi-carrier index modulation method based on optimized multiple indexes in terms of spectrum efficiency, but at the expense of system computational complexity and bit error performance. For example, with n=10 subcarriers and a bit error rate of 1×10^(-5),spectral efficiency can be raised by roughly 12.4%.
