The deformation energy(Wd)of soil-like tectonic coal is crucial for investigating the mechanism of coal and gas outbursts.Tectonic coal has a significant nonlinear constitutive relationship,which makes traditional ela...The deformation energy(Wd)of soil-like tectonic coal is crucial for investigating the mechanism of coal and gas outbursts.Tectonic coal has a significant nonlinear constitutive relationship,which makes traditional elastic-based models for computing Wdunsuitable.Inspired by critical state soil mechanics,this study theoretically established a new calculation model of Wdsuitable for the coal with nonlinear deformation characteristics.In the new model,the relationship between energy and stress no longer follows the square law(observed in traditional linear elastic models)but exhibits a power function,with the theoretical value of the power exponent ranging between 1 and 2.Hydrostatic cyclic loading and unloading experiments were conducted on four groups of tectonic coal samples and one group of intact coal samples.The results indicated that the relationship between Wdand stress for both intact and tectonic coal follows a power law.The exponents for intact and tectonic coal are close to 2 and 1,respectively.The stress-strain curve of intact coal exhibits small deformation and linear characteristics,whereas the stress-strain curves of tectonic coal show large deformation and nonlinear characteristics.The study specifically investigates the role of coal viscosity in the cyclic loading/unloading process.The downward bending in the unloading curves can be attributed to the time-dependent characteristics of coal,particularly its viscoelastic behavior.Based on experimental statistics,the calculation model of Wdwas further simplified.The simplified model involves only one unknown parameter,which is the power exponent between Wdand stress.The measured Wdof the coal samples increases with the number of load cycles.This phenomenon is attributed to coal's viscoelastic deformation.Within the same stress,the Wdof tectonic coal is an order of magnitude greater than that of intact coal.The calculation model of Wdproposed in this paper provides a new tool for studying the energy principle of coal and gas outbursts.展开更多
On the basis of analysis and selection of factors influencing operation cost of coal resources development, fuzzy set method and artificial neural network (ANN) were adopted to set up the classification analysis model...On the basis of analysis and selection of factors influencing operation cost of coal resources development, fuzzy set method and artificial neural network (ANN) were adopted to set up the classification analysis model of coal resources. The collected samples were classified by using this model. Meanwhile, the pattern recognition model for classifying of the coal resources was built according to the factors influencing operation cost. Based on the results achieved above, in the light of the theory of information diffusion, the calculation model for operation cost of coal resources development has been presented and applied in practice, showing that these models are reasonable.展开更多
Understanding the nature of Pt active sites is of great importance for the structure-sensitive base-free oxidation of glycerol. In the present work, the remarkable Pt particle size effects on glycerol conversion and p...Understanding the nature of Pt active sites is of great importance for the structure-sensitive base-free oxidation of glycerol. In the present work, the remarkable Pt particle size effects on glycerol conversion and products formation from the oxidation of the primary and the secondary hydroxyl groups are understood by combining the model calculations and DFT calculations, aiming to discriminate the corresponding dominant Pt active sites. The Pt(100) facet is demonstrated to be the dominant active sites for the glycerol conversion and the products formation from the two routes. The insights revealed here could shed new light on fundamental understanding of the Pt particle size effects and then guiding the design and optimization of Pt-catalyzed base-free oxidation of glycerol toward targeted products.展开更多
In response to the lack of global quantitative research on the potential and scale prediction of CO_(2) capture,utilization and storage(CCUS)in China under the background of carbon peak and carbon neutrality goals,thi...In response to the lack of global quantitative research on the potential and scale prediction of CO_(2) capture,utilization and storage(CCUS)in China under the background of carbon peak and carbon neutrality goals,this study predicts the future economic costs of different links of ccUS technologies and the carbon capture needs of different industries in the scenario of fossil energy continuation.Based on the CO_(2) utilization and storage potential and spatial distribution in China,a cost-scale calculation model for different regions in China in 206o is constructed to predict the whole-process economic cost and its corresponding scale potential of CCUs.The results show that a local+remote storage mode is preferred,together with a local utilization mode,to meet China's 27×10^(8)t/a CO_(2) emission reduction demand under the scenario of fossil energy continuation.Specifically,about 5×10^(8) t CO_(2) emission is reduced by capture utilization,and the whole-process cost is about-1400-200 RMB/t;about 22×10^(8) t CO_(2) emission is reduced by capture storage,and the whole-process cost is about 200-450 RMB/t.According to the model results,it is recommended to develop the chemical utilization industry based on P2X(Power to X,where X is raw material)technology,construct the CcUs industrial cluster,and explore a multi-party win-win cooperation mode.A scheme of national trunk pipeline network connecting areas connecting intensive emission reduction demand areas and target storage areas is suggested.The emission reduction cost of thermal power based on CCUS is calculated to be 0.16 RMB/(kW.h).展开更多
In this paper, we present a simple theoretical approach to calculate the multiple ionization of big atoms and molecules induced by very high-q fast projectiles in a strong coupling regime （q/v 〉 1）. The results obt...In this paper, we present a simple theoretical approach to calculate the multiple ionization of big atoms and molecules induced by very high-q fast projectiles in a strong coupling regime （q/v 〉 1）. The results obtained from this approach are in excellent agreement with the available experimental data. A probable scenario of molecular multiple ionization by fast and very high-q projectiles is discussed. The very small computational time required here and the good agreement with the existing experimental data make it a good candidate for studying the multiple ionization of complex molecules under high linear energy transfers.展开更多
Based on miniaturized components＇ characteristics, the method of assembling miniaturized gear and shaft together with corresponding calculating model of the interference amount are proposed. On the basis of main effe...Based on miniaturized components＇ characteristics, the method of assembling miniaturized gear and shaft together with corresponding calculating model of the interference amount are proposed. On the basis of main effecting factors analysis on the gear and shaft assembling interference amount, calculating formula including all factors effective on the interference amount necessary for reliable system running was built up. The methods of reverse calculating theoretical model was used to build up the equivalent simulation model of the theoretical one, together with simulation verification and case study for calculating formula. The results show that the cold assembling method is applicable for miniaturized gear and shaft, but in the assembling process, the interference amount compensating the shape error of contacting surfaces takes a large proportion, which is the main cause of stress variance on contacting surfaces.展开更多
基金supported by the Fundamental Research Funds for the Central Universities(No.2024QN11072)National Natural Science Foundation of China(Nos.52404264 and 52174217)State Key Program of the National Natural Science Foundation of China(No.52034008)。
文摘The deformation energy(Wd)of soil-like tectonic coal is crucial for investigating the mechanism of coal and gas outbursts.Tectonic coal has a significant nonlinear constitutive relationship,which makes traditional elastic-based models for computing Wdunsuitable.Inspired by critical state soil mechanics,this study theoretically established a new calculation model of Wdsuitable for the coal with nonlinear deformation characteristics.In the new model,the relationship between energy and stress no longer follows the square law(observed in traditional linear elastic models)but exhibits a power function,with the theoretical value of the power exponent ranging between 1 and 2.Hydrostatic cyclic loading and unloading experiments were conducted on four groups of tectonic coal samples and one group of intact coal samples.The results indicated that the relationship between Wdand stress for both intact and tectonic coal follows a power law.The exponents for intact and tectonic coal are close to 2 and 1,respectively.The stress-strain curve of intact coal exhibits small deformation and linear characteristics,whereas the stress-strain curves of tectonic coal show large deformation and nonlinear characteristics.The study specifically investigates the role of coal viscosity in the cyclic loading/unloading process.The downward bending in the unloading curves can be attributed to the time-dependent characteristics of coal,particularly its viscoelastic behavior.Based on experimental statistics,the calculation model of Wdwas further simplified.The simplified model involves only one unknown parameter,which is the power exponent between Wdand stress.The measured Wdof the coal samples increases with the number of load cycles.This phenomenon is attributed to coal's viscoelastic deformation.Within the same stress,the Wdof tectonic coal is an order of magnitude greater than that of intact coal.The calculation model of Wdproposed in this paper provides a new tool for studying the energy principle of coal and gas outbursts.
文摘On the basis of analysis and selection of factors influencing operation cost of coal resources development, fuzzy set method and artificial neural network (ANN) were adopted to set up the classification analysis model of coal resources. The collected samples were classified by using this model. Meanwhile, the pattern recognition model for classifying of the coal resources was built according to the factors influencing operation cost. Based on the results achieved above, in the light of the theory of information diffusion, the calculation model for operation cost of coal resources development has been presented and applied in practice, showing that these models are reasonable.
基金financially supported by the Natural Science Foundation of China (21776077)the Shanghai Natural Science Foundation (17ZR1407300 and 17ZR1407500)+5 种基金the Program for Professor of Special Appointment (Eastern Scholar) at Shanghai Institutions of Higher Learningthe Shanghai Rising-Star Program (17QA1401200)the Open Project of State Key Laboratory of Chemical Engineering (SKLChe-15C03)the State Key Laboratory of Organic– Inorganic Composites (oic-201801007)the Fundamental Research Funds for the Central Universities (222201718003)the 111 Project of the Ministry of Education of China (B08021)
文摘Understanding the nature of Pt active sites is of great importance for the structure-sensitive base-free oxidation of glycerol. In the present work, the remarkable Pt particle size effects on glycerol conversion and products formation from the oxidation of the primary and the secondary hydroxyl groups are understood by combining the model calculations and DFT calculations, aiming to discriminate the corresponding dominant Pt active sites. The Pt(100) facet is demonstrated to be the dominant active sites for the glycerol conversion and the products formation from the two routes. The insights revealed here could shed new light on fundamental understanding of the Pt particle size effects and then guiding the design and optimization of Pt-catalyzed base-free oxidation of glycerol toward targeted products.
基金Supported by the National Natural Science Foundation of China(72140006)GEIDCO Independent Research Project(ZY2023008).
文摘In response to the lack of global quantitative research on the potential and scale prediction of CO_(2) capture,utilization and storage(CCUS)in China under the background of carbon peak and carbon neutrality goals,this study predicts the future economic costs of different links of ccUS technologies and the carbon capture needs of different industries in the scenario of fossil energy continuation.Based on the CO_(2) utilization and storage potential and spatial distribution in China,a cost-scale calculation model for different regions in China in 206o is constructed to predict the whole-process economic cost and its corresponding scale potential of CCUs.The results show that a local+remote storage mode is preferred,together with a local utilization mode,to meet China's 27×10^(8)t/a CO_(2) emission reduction demand under the scenario of fossil energy continuation.Specifically,about 5×10^(8) t CO_(2) emission is reduced by capture utilization,and the whole-process cost is about-1400-200 RMB/t;about 22×10^(8) t CO_(2) emission is reduced by capture storage,and the whole-process cost is about 200-450 RMB/t.According to the model results,it is recommended to develop the chemical utilization industry based on P2X(Power to X,where X is raw material)technology,construct the CcUs industrial cluster,and explore a multi-party win-win cooperation mode.A scheme of national trunk pipeline network connecting areas connecting intensive emission reduction demand areas and target storage areas is suggested.The emission reduction cost of thermal power based on CCUS is calculated to be 0.16 RMB/(kW.h).
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11174116 and 11175075)
文摘In this paper, we present a simple theoretical approach to calculate the multiple ionization of big atoms and molecules induced by very high-q fast projectiles in a strong coupling regime （q/v 〉 1）. The results obtained from this approach are in excellent agreement with the available experimental data. A probable scenario of molecular multiple ionization by fast and very high-q projectiles is discussed. The very small computational time required here and the good agreement with the existing experimental data make it a good candidate for studying the multiple ionization of complex molecules under high linear energy transfers.
基金Sponsored bythe Ministerial Level Advanced Research Foundation (K130306068)
文摘Based on miniaturized components＇ characteristics, the method of assembling miniaturized gear and shaft together with corresponding calculating model of the interference amount are proposed. On the basis of main effecting factors analysis on the gear and shaft assembling interference amount, calculating formula including all factors effective on the interference amount necessary for reliable system running was built up. The methods of reverse calculating theoretical model was used to build up the equivalent simulation model of the theoretical one, together with simulation verification and case study for calculating formula. The results show that the cold assembling method is applicable for miniaturized gear and shaft, but in the assembling process, the interference amount compensating the shape error of contacting surfaces takes a large proportion, which is the main cause of stress variance on contacting surfaces.
