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Strong electronic metal-support interactions for enhanced hydroformylation activity and stability over Rh single-atom catalysts through phosphorus doping
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作者 Boyang Fu Ping Ma +11 位作者 Xiaoyang Ding Kaifu Cai Limin Sun Yujin Zhu Qiwei Yin Yihao Sun Tianle Liu Yuzhen Li Yuxing Xu Jian Gu Haowen Ma Junling Lu 《中国科学技术大学学报》 北大核心 2025年第3期2-10,1,I0001,共11页
By simplifying catalyst-product separation and reducing phosphorus waste,heterogeneous hydroformylation offers a more sustainable alternative to homogeneous processes.However,heterogeneous hydroformylation catalysts d... By simplifying catalyst-product separation and reducing phosphorus waste,heterogeneous hydroformylation offers a more sustainable alternative to homogeneous processes.However,heterogeneous hydroformylation catalysts developed thus far still suffer from the issues of much lower activity and metal leaching,which severely hinder their practical application.Here,we demonstrate that incorporating phosphorus(P)atoms into graphitic carbon nitride(PCN)supports facilitates charge transfer from Rh to the PCN support,thus largely enhancing electronic metal-support interactions(EMSIs).In the styrene hydroformylation reaction,the activity of Rh_(1)/PCN single-atom catalysts(SACs)with varying P contents exhibited a volcano-shaped relationship with P doping,where the Rh_(1)/PCN SAC with optimal P doping showed exceptional activity,approximately 5.8-and 3.3-fold greater than that of the Rh_(1)/g-C_(3)N_(4)SAC without P doping and the industrial homogeneous catalyst HRh(CO)(PPh_(3))_(3),respectively.In addition,the optimal Rh_(1)/PCN SAC catalyst also demonstrated largely enhanced multicycle stability without any visible metal aggregation owing to the increased EMSIs,which sharply differed from the severe metal aggregation of large nanoparticles on the Rh_(1)/g-C_(3)N_(4)SAC.Mechan-istic studies revealed that the enhanced catalytic performance could be attributed to electron-deficient Rh species,which reduced CO adsorption while simultaneously promoting alkene adsorption through increased EMSIs.These findings suggest that tuning EMSIs is an effective way to achieve SACs with high activity and durability. 展开更多
关键词 heterogeneous hydroformylation Rh single-atom catalysts electronic metal-support interactions phosphorus doping
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Numerical Modeling of Ship-Ice-Water Interaction for Freerunning Ships in Pack Ice
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作者 ZOU Ming ZOU Zao−jian +1 位作者 ZOU Lu ZHU Sheng−tao 《船舶力学》 北大核心 2025年第6期878-887,共10页
Ice-going ships play a crucial role in polar transportation and resource extraction.Different from the existing modeling approach which assumes that ships remain stationary,dynamic overset grid technology and DFBI(Dyn... Ice-going ships play a crucial role in polar transportation and resource extraction.Different from the existing modeling approach which assumes that ships remain stationary,dynamic overset grid technology and DFBI(Dynamic Fluid-Body Interaction)method are employed in this paper to enable the free-running motion of the ship in modeling.A numerical model capable of simulating a ship navigating through pack ice area is proposed,which uses Computational Fluid Dynamics(CFD)method to solve the flow field and applies the Discrete Element Method(DEM)to simulate ship-ice and ice-ice interactions.Besides,the proposed high-precision method for generating pack ice area can be used in conjunction with the proposed numerical model.By comparing the numerical results with the available model test data and experimental observations,the effectiveness of the numerical model is validated,demonstrating its strong capability of predicting resistance and simulating ship navigation in pack ice,as well as its significant potential and applicability for further studies. 展开更多
关键词 pack ice ship-ice-water interaction CFD-DEM dynamic overset grid technology ship resistance
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Design of commonly-resonated extended interaction circuits for submillimeter-wave phase-locked oscillators
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作者 BI Liang-Jie LI Hai-Long +2 位作者 WANG Bin MENG Lin YIN Yong 《红外与毫米波学报》 北大核心 2025年第4期553-561,共9页
In this paper,a scheme of commonly-resonated extended interaction circuit system based on high order TMn,mode is proposed to lock the phases of two extended interaction oscillators(EIOs)for generating high power at G-... In this paper,a scheme of commonly-resonated extended interaction circuit system based on high order TMn,mode is proposed to lock the phases of two extended interaction oscillators(EIOs)for generating high power at G-band.Two separate EIOs are coupled through a specific single-gap coupling field supported by a designed gap waveguide with length Lg,which form the phase-locked EIOs based on the commonly-resonated system.As a whole system,the system has been focused on with mode analysis based on different single-gap coupling fields,mode hopping,which present the variation of phase difference between the two-beam-wave interactions when changing Lg.To demonstrate the effectiveness of the proposed circuit system in producing the phase locking,we conducted particle-in-cell(PIC)simulations to show that the interesting mode hopping occurs with the phase difference of O and r between the output signals from two output ports,corresponding to the excitation of the TMn mode with different n.Simulation results show that 1)the oscillator can deliver two times of the output power obtained from one single oscillator at 220 GHz,2)the two EIOs can still deliver output signals with phase difference of O and when the currents of the two beams are different or the fabrication errors of the two EIO cavities are taken into account.The proposed scheme is promising in extending to phase locking between multiple EIOs,and generating higher power at millimeter-wave and higher frequencies. 展开更多
关键词 electron physics phase-locked extended interaction oscillator(EIO) PIC simulations distributed beam high order mode
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Research progress on metal-support interactions over Ni-based catalysts for CH_(4)-CO_(2)reforming reaction
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作者 SUN Kai JIANG Jianfei +4 位作者 LIU Zixuan GENG Shiqi LIU Zhenmin YANG Jiaqian LI Shasha 《燃料化学学报(中英文)》 北大核心 2025年第4期434-451,共18页
With ongoing global warming and increasing energy demands,the CH_(4)-CO_(2)reforming reaction(dry reforming of methane,DRM)has garnered significant attention as a promising carbon capture and utilization technology.Ni... With ongoing global warming and increasing energy demands,the CH_(4)-CO_(2)reforming reaction(dry reforming of methane,DRM)has garnered significant attention as a promising carbon capture and utilization technology.Nickel-based catalysts are renowned for their outstanding activity and selectivity in this process.The impact of metal-support interaction(MSI),on Ni-based catalyst performance has been extensively researched and debated recently.This paper reviews the recent research progress of MSI on Ni-based catalysts and their characterization and modulation strategies in catalytic reactions.From the perspective of MSI,the effects of different carriers(metal oxides,carbon materials and molecular sieves,etc.)are introduced on the dispersion and surface structure of Ni active metal particles,and the effect of MSI on the activity and stability of DRM reactions on Ni-based catalysts is discussed in detail.Future research should focus on better understanding and controlling MSI to improve the performance and durability of nickel-based catalysts in CH_(4)-CO_(2)reforming,advancing cleaner energy technologies. 展开更多
关键词 CO_(2)utilization CH_(4)-CO_(2)reforming Ni-based catalysts metal-support interactions supports
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A comprehensive review on elucidating the host disease resistance mechanism from the perspective of the interaction between cotton and Verticillium dahliae
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作者 ZHANG Yalin ZHAO Lihong +8 位作者 LI Dongpo LI Ziming FENG Hongjie FENG Zili WEI Feng ZHOU Jinglong MA Zhiying YANG Jun ZHU Heqin 《Journal of Cotton Research》 2025年第1期129-142,共14页
Verticillium wilt,caused by the infamous pathogen Verticillium dahliae,presents a primary constraint on cotton cul-tivation worldwide.The complexity of disease resistance in cotton and the largely unexplored interacti... Verticillium wilt,caused by the infamous pathogen Verticillium dahliae,presents a primary constraint on cotton cul-tivation worldwide.The complexity of disease resistance in cotton and the largely unexplored interaction dynamics between the cotton plant host and V.dahliae pathogen pose a crucial predicament for effectively managing cotton Verticillium wilt.Nevertheless,the most cost-effective approach to controlling this disease involves breeding and cul-tivating resistant cotton varieties,demanding a meticulous analysis of the mechanisms underlying cotton’s resistance to Verticillium wilt and the identification of pivotal genes.These aspects constitute focal points in disease-resistance breeding programs.In this review,we comprehensively discuss genetic inheritance associated with Verticillium wilt resistance in cotton,the advancements in molecular markers for disease resistance,the functional investiga-tion of resistance genes in cotton,the analysis of pathogenicity genes in V.dahliae,as well as the intricate interplay between cotton and this fungus.Moreover,we delve into the future prospects of cutting-edge research on cotton Verticillium wilt,aiming to proffer valuable insights for the effective management of this devastating fungus. 展开更多
关键词 Cotton Verticillium wilt Verticillium dahliae Resistance inheritance Disease resistance mechanism interaction mechanism
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Analytic method of skin friction for plum blossom pile foundations considering pile-soil interaction under vertical load
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作者 LI Long JIANG Quan DENG You-sheng 《Journal of Central South University》 2025年第9期3336-3347,共12页
Plum blossom pile is a new type of special-shaped pile, which is proposed based on the principle of maximum perimeter with the same cross-sectional area. To advance this technique, primarily for the design of plum blo... Plum blossom pile is a new type of special-shaped pile, which is proposed based on the principle of maximum perimeter with the same cross-sectional area. To advance this technique, primarily for the design of plum blossom piles, it is important to investigate the skin friction behavior of plum blossom pile foundations precluding any straightforward constitutive model. In this work, an analytic method dependent on the cross-sectional geometry and the vertical shearing effects is proposed by means of equilibrium analysis to calculate the effective vertical stress in the surrounding soil, the skin friction/negative skin friction, and the axial force/dragload of a plum blossom pile. Additionally, the curves of skin friction of piles are investigated with the same conditions. The results show that the curves of skin friction of piles deduced according to the developed analytic method agree well with the FEM results and related literature solution, which validates the solution. The axial force of the pile decreases with the increase of the shear action coefficient in the buried depth direction under the vertical concentrated load when considering the vertical shearing effects on the pile-soil interfaces. 展开更多
关键词 plum blossom pile skin friction pile-soil interaction vertical shearing effects negative skin friction
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Seismic pseudo-static stability analysis of bedding jointed rock slope stability under the interaction of the upper dangerous rock mass and lower stepped slope mass based on acceleration assessment
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作者 LI De-jian XIAO Yu +3 位作者 YANG Yan-song YU Peng-cheng ZHANG Ying-bin ZHAO Lian-heng 《Journal of Central South University》 2025年第7期2619-2637,共19页
In the practical slope engineering,the stability of lower sliding mass(region A)with back tensile cracks of the jointed rock slope attracts more attentions,but the upper rock mass(region B)may also be unstable.Therefo... In the practical slope engineering,the stability of lower sliding mass(region A)with back tensile cracks of the jointed rock slope attracts more attentions,but the upper rock mass(region B)may also be unstable.Therefore,in this study,based on the stepped failure mode of bedding jointed rock slopes,considering the influence of the upper rock mass on the lower stepped sliding mass,the improved failure model for analyzing the interaction force(F_(AB))between two regions is constructed,and the safety factors(F_(S))of two regions and whole region are derived.In addition,this paper proposes a method to determine the existence of F_(AB) using their respective acceleration values(a_(A) and a_(B))when regions A and B are unstable.The influences of key parameters on two regions and the whole region are analyzed.The results show that the variation of the F_(AB) and F_(S) of two regions can be obtained accurately based on the improved failure model.The accuracy of the improved failure model is verified by comparative analysis.The research results can explain the interaction mechanism of two regions and the natural phenomenon of slope failure caused by the development of cracks. 展开更多
关键词 bedding jointed rock slope upper dangerous rock mass stepped sliding interaction mechanism stability analysis
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A comprehensive study method for lifeline system interaction under seismic conditions 被引量:9
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作者 姚保华 谢礼立 火恩杰 《地震学报》 CSCD 北大核心 2004年第2期193-202,共10页
The mechanism of lifeline system interaction is analyzed and the method and its corresponding result for categorizing the lifeline system in terms of interaction are presented. Various methods for the different kind o... The mechanism of lifeline system interaction is analyzed and the method and its corresponding result for categorizing the lifeline system in terms of interaction are presented. Various methods for the different kind of interaction are reviewed in this paper. For the function interaction of the lifeline system, an all-round study method is recommended. A WebGIS based aided decision-making method for the post-earthquake restoration of multi-lifeline system is also presented. Meanwhile, some key-points for lifeline system interaction are discussed. 展开更多
关键词 生命线系统 相互作用 WEBGIS 地震
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化繁为简 神秘“感应”——《Interaction—for 3 piccolos & 3 suite-drums》音乐分析
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作者 张延莉 《音乐创作》 北大核心 2010年第1期126-127,共2页
作者从音乐结构、和声、音响、内容等方面分析了钱仁平的作品《Interaction》,作者认为这是一首化繁为简、返璞归真的,穿着无调性音乐的外衣却蕴藏着传统的音乐元素、人丈精神的优秀中国新音乐作品,它貌似夸张另类,实则传统质朴,... 作者从音乐结构、和声、音响、内容等方面分析了钱仁平的作品《Interaction》,作者认为这是一首化繁为简、返璞归真的,穿着无调性音乐的外衣却蕴藏着传统的音乐元素、人丈精神的优秀中国新音乐作品,它貌似夸张另类,实则传统质朴,融传统与现代于一体。 展开更多
关键词 interaction 短笛 康加鼓 音级集合 感应
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Symmetry breaking of photonic spin-orbit interactions in metasurfaces 被引量:15
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作者 Fei Zhang Mingbo Pu +2 位作者 Jun Luo Honglin Yu Xiangang Luo 《光电工程》 CAS CSCD 北大核心 2017年第3期319-325,共7页
Spin-orbit optical phenomena pertain to the wider class of electromagnetic effects originating from the interaction of the photon spin with the spatial structure and propagation characteristics of an optical wave,medi... Spin-orbit optical phenomena pertain to the wider class of electromagnetic effects originating from the interaction of the photon spin with the spatial structure and propagation characteristics of an optical wave,mediated by suitable optical media.There are many emerging photonic applications of spin-orbit interactions(SOI)of light,such as control of the optical wave propagation via the spin,enhanced optical manipulation,and generation of structured optical fields.Unfortunately,current applications are based on symmetric SOI,that is,the behaviours of polarized photons with two opposite spins are opposite,leading to the limit of spin-based multiplexers.The symmetry of SOI can be broken in our proposed metasurfaces,consisting of spatially varying birefringence,which can arbitrarily and independently build SOI for two opposite spins without reduction of optical energy usage.We obtain three kinds of dual-functional metasurfaces at visible and infrared wavelengths with high efficiency.Our concept of generation of asymmetric SOI for two spins,using anisotropic metasurfaces,will open new degrees of freedoms for building new types of spin-controlled multifunctional shared-aperture devices for the generation of complex structured optical fields. 展开更多
关键词 metasurfaces METAMATERIALS spin-orbit interactions
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Developments of numerical methods for linear and nonlinear fluid-solid interaction dynamics with applications 被引量:9
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作者 Jing Tang XING 《力学进展》 EI CSCD 北大核心 2016年第1期95-139,共45页
关键词 linear and nonlinear fluid-solid interactions MIXED FE-substructuremethod MIXED FE-BE METHOD MIXED FE-FD METHOD MIXED FE-SP METHOD fluidsloshing acoustic volume—structure coupling breaking WAVE simulations pressurewaves in fluids LNG ship VLFS-water interaction WAVE energy harvesting
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Complex experimental analysis of rifle-shooter interaction 被引量:3
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作者 Michal Taraszewski Janusz Ewertowski 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2017年第5期346-352,共7页
In this study, a complex analysis of a man-weapon interaction based on experimental effort is presented.The attention is focused on how a shooter can influence on a rifle, opposite to generally considered in literatur... In this study, a complex analysis of a man-weapon interaction based on experimental effort is presented.The attention is focused on how a shooter can influence on a rifle, opposite to generally considered in literature rifle's impact on a shooter. It is shown, based on the kbk AKM weapon, that each support point of the rifle has an substantial impact on the system. It is said that identifying human reactions on weapon may let to describe gun movement and thus may be applied to weapon accuracy determination. 展开更多
关键词 Rifle-shooter interaction Man-weapon forces MUZZLE CLIMB FIREARM Recoil Accuracy
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Interactions between gas flow and reversible chemical reaction in porous media 被引量:2
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作者 JIANG Yuan-yong XU Zeng-he +1 位作者 ZHANG Meng-zhou BAI Li-yuan 《Journal of Central South University》 SCIE EI CAS CSCD 2017年第5期1144-1154,共11页
Taking into consideration the gas compressibility and chemical reaction reversibility, a model was developed to study the interactions between gas flow and chemical reaction in porous media and resolved by the finite ... Taking into consideration the gas compressibility and chemical reaction reversibility, a model was developed to study the interactions between gas flow and chemical reaction in porous media and resolved by the finite volume method on the basis of the gas-solid reaction aA(g)+bB(s)cC(g)+dD(s).The numerical analysis shows that the equilibrium constant is an important factor influencing the process of gas-solid reaction. The stoichiometric coefficients, molar masses of reactant gas, product gas and inert gas are the main factors influencing the density of gas mixture. The equilibrium constant influences the gas flow in porous media obviously when the stoichiometric coefficients satisfy a/c≠1. 展开更多
关键词 POROUS MEDIA COMPRESSIBLE gas flow REVERSIBLE chemical reaction interaction
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Interaction model of artificial fish in virtual environment 被引量:2
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作者 Meng Xiangsong Ban Xiaojuan Yin Yixin 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2008年第5期982-987,共6页
Conventional artificial fish has some shortages on the interaction with environment, other fish, and the animator. This article proposes a multi-tier interaction control model of artificial fish, realizes the interact... Conventional artificial fish has some shortages on the interaction with environment, other fish, and the animator. This article proposes a multi-tier interaction control model of artificial fish, realizes the interaction model through integration of virtual reality technology and Markov sequence, and provides a virtual marine world to describe the interaction between artificial fish and the virtual environment and the interaction between the artificial fish and the animator. Simulation results show that the interaction model owns not only the basic characteristics of virtual biology, but also has high trueness interaction function. 展开更多
关键词 artificial life artificial fish interaction model Markov sequence.
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STUDY ON INTERACTION ENERGY BETWEEN FLOTATION REAGENT AND MINERAL SURFACE 被引量:1
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作者 Chen Jianhua Feng Qiming Lu Yiping Chen Jin (Department of Mineral Engineering, Central South University of Technology, Changsha 410083, China) 《Journal of Central South University》 SCIE EI CAS 1998年第2期35-39,共5页
The interaction between a flotation reagent and mineral surface not only depends on the bonding atom, but also depends on the adjacent atom of mineral surface, a flotation reagent and the medium in the system of flota... The interaction between a flotation reagent and mineral surface not only depends on the bonding atom, but also depends on the adjacent atom of mineral surface, a flotation reagent and the medium in the system of flotation. Energy equation of a reagent interacting with mineral surface has been deduced from this model. Results of the studies indicate that the interaction energy between mineral surface and a reagent is about several dozen kJ/mol, and the relationship between adsorbing concentration of xanthate on mineral surface and interaction energy is the exponent form. 展开更多
关键词 FLOTATION REAGENT MINERAL SURFACE interaction
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Using Oral Communicative Activities to Promote Interaction in EFL Classroom
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作者 徐莉莉 《兰州大学学报(社会科学版)》 CSSCI 北大核心 2009年第S1期134-137,共4页
Those monotonous exercises manipulated in EFL classroom,although labeled as'communicative', often result in predictable outcomes:student boredom,frustration,and even very limited progress toward mastery of the... Those monotonous exercises manipulated in EFL classroom,although labeled as'communicative', often result in predictable outcomes:student boredom,frustration,and even very limited progress toward mastery of the foreign language.This paper will introduce some oral communicative activities that can motivate students to practice conversation skills and promote interaction. 展开更多
关键词 COMMUNICATIVE ACTIVITIES interaction EFL
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Beam-track interaction of high-speed railway bridge with ballast track 被引量:19
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作者 闫斌 戴公连 张华平 《Journal of Central South University》 SCIE EI CAS 2012年第5期1447-1453,共7页
Based on the construction bridge of Xiamen-Shenzhen high-speed railway(9-32 m simply-supported beam + 6×32 m continuous beam),the pier-beam-track finite element model,where the continuous beam of the ballast trac... Based on the construction bridge of Xiamen-Shenzhen high-speed railway(9-32 m simply-supported beam + 6×32 m continuous beam),the pier-beam-track finite element model,where the continuous beam of the ballast track and simply-supported beam are combined with each other,was established.The laws of the track stress,the pier longitudinal stress and the beam-track relative displacement were analyzed.The results show that reducing the longitudinal resistance can effectively reduce the track stress and the pier stress of the continuous beam,and increase the beam-track relative displacement.Increasing the rigid pier stiffness of continuous beam can reduce the track braking stress,increase the pier longitudinal stress and reduce the beam-track relative displacement,Increasing the rigid pier stiffness of simply-supported beam can reduce the track braking stress,the rigid pier longitudinal stress and the beam-track relative displacement. 展开更多
关键词 high-speed railway beam-track interaction ballast track rail longitudinal force continuous beam
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Cost-Effective Machining of Granite by Reducing Tribological Interactions 被引量:1
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作者 LI Yuan 1, HUANG Hui 1, SHEN Jian-yun 1, XU Xi-peng 1, GAO Yong-sheng 2 (1. Province Key Lab of Stone Machining, Huaqiao University, Quanzhou 362011, China 2. Department of Mechanical Engineering, Hong Kong University of Science and T echnology, Hong Kong, China) 《厦门大学学报(自然科学版)》 CAS CSCD 北大核心 2002年第S1期123-,共1页
In order to implement cost-effective machining of gr anite materials with diamond impregnated tools, we should realize low tool w ear, low energy consumption, and high cutting efficiency, while the accuracy of the wor... In order to implement cost-effective machining of gr anite materials with diamond impregnated tools, we should realize low tool w ear, low energy consumption, and high cutting efficiency, while the accuracy of the workpiece surfaces are maintained to be satisfactory. It is understood that the main factors affecting the tool wear, the energy, and the efficiency during the machining process are related to the tribological interactions that occur at the interface between the diamond tool surface and the workpiece. Based on this consideration, we propose a new machining method to machine granite materia ls to achieve improved cost effectiveness. In the proposed method, the tribologi cal interactions are maintained to a minimum. Based on the analyses of the experimental results, the following conclusions can be drawn: The wear performance is greatly dependent on the machining parameters and their combination. Therefore, optimum machining parameters must be set up at first in order to optimize the tribological characteristics of segments and thereby sawbl ade performance. These may be realized by balancing the energy expended by frict ion and the mechanical load on diamond crystal. The geometry and structure of diamond segments are another important criterion f or the diamond saw blade. Using a seven-layer structure for multi-blades sawin g and applying segments with side slots for trimming application had greatly red uced the frictions in the sawing processes. The wetting and bonding between diamonds and matrix alloys have been considered as the prerequisite for high wear performance of the segments. Diamonds coated w ith Ti-Cr alloy by a unique technique can effectively improve its wetting c apability and provide more storage space for debris, thereby reducing friction i nteractions. 展开更多
关键词 GRANITE SAWING friction interaction cost-effe ctive
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Experiment study on water-rock interaction about gold activation and migration in different solutions 被引量:2
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作者 DAI Ta gen, GU Li, QIU Dong sheng, XIE Wen bing (College of Resources, Environment and Civil Engineering, Central South University, Changsha 410083, China) 《Journal of Central South University of Technology》 2001年第2期105-107,共3页
The interactions on gold active and migratory quantities and rates between tuffaceous slate and solu tions with different compositions were experimentally studied at 200 ℃, 20 MPa, in a high pressure apparatus. After... The interactions on gold active and migratory quantities and rates between tuffaceous slate and solu tions with different compositions were experimentally studied at 200 ℃, 20 MPa, in a high pressure apparatus. After reaction, tuffaceous slate became light colored and soft, and its mass density reduced. The amount of gold extracted from tuffaceous slate ranges widely, from 0 027 to 0 234 μg/g. Chlorine solution may activate appreciable amount of gold, and the gold migratory rate is high enough, from 50 70% to 92 30%, which reveals that sulphur and chlorine work together in solutions to accelerate gold activation and migration, and to realize gold mineralization in favorable places. 展开更多
关键词 water rock interaction ACTIVATION MIGRATION CHLORINE SULPHUR GOLD
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Application of molecular interaction volume model in separation of Sn-Zn alloy by vacuum distillation 被引量:1
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作者 孔令鑫 杨斌 +4 位作者 李一夫 徐宝强 韩龙 刘大春 戴永年 《Journal of Central South University》 SCIE EI CAS 2013年第12期3372-3378,共7页
The activity of components of Sn-Zn binary alloy system was predicted based on the molecular interaction volume model (MIVM). The calculated values are in good agreement with available experimental data of activitie... The activity of components of Sn-Zn binary alloy system was predicted based on the molecular interaction volume model (MIVM). The calculated values are in good agreement with available experimental data of activities, which indicates that this model is of stability and reliability because the MIVM has a good physical basis. The vapor-liquid phase equilibrium of Sn-Zn alloy system in vacuum distillation was calculated as a function of the activity coefficient. The results show that the content of Sn in vapor phase is 4.2x 10-7 (mass fraction) while in liquid phase it is 90% (mass fraction) at 1 073 K, and the content of Sn in vapor phase increases with increasing the melt temperature and content of Sn in liquid phase. Vacuum distillation experiments were carried out on Sn-Zn alloy for the proper interpretation of the results of the MIVM in the temperature range of 973-1 273 K under pressures of 15-200 Pa. The experimental results show that the content of Sn in vapor phase is 5x 10 6 (mass fraction) while in liquid phase it is 90% (mass fraction) under the operational condition of 1 073 K, 100 rain and 15 Pa. The experimental results are in good agreement with the predicted values of the MIVM for Zn-Sn binary alloy system. 展开更多
关键词 vacuum distillation molecular interaction volume model (MIVM) SEPARATION
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