Solid-state batteries have received increasing attention in scientific and industrial communities,which benefits from the intrinsically safe solid electrolytes(SEs).Although much effort has been devoted to designing S...Solid-state batteries have received increasing attention in scientific and industrial communities,which benefits from the intrinsically safe solid electrolytes(SEs).Although much effort has been devoted to designing SEs with high ionic conductivities,it is extremely difficult to fully understand the ionic diffusion mechanisms in SEs through conventional experimental and theoretical methods.Herein,the temperature-dependent concerted diffusion mechanism of ions in SEs is explored through machinelearning molecular dynamics,taking Li_(10)GeP_(2)S_(12) as a prototype.Weaker diffusion anisotropy,more disordered Li distributions,and shorter residence time are observed at a higher temperature.Arrhenius-type temperature dependence is maintained within a wide temperature range,which is attributed to the linear temperature dependence of jump frequencies of various concerted diffusion modes.These results provide a theoretical framework to understand the ionic diffusion mechanisms in SEs and deepen the understanding of the chemical origin of temperature-dependent concerted diffusions in SEs.展开更多
Chiral metamaterial absorbers(CMMAs),a particular class of chiral metamaterials that refuse the transmission of incident radiation and exhibit different optical responses upon interactions with left and right circular...Chiral metamaterial absorbers(CMMAs),a particular class of chiral metamaterials that refuse the transmission of incident radiation and exhibit different optical responses upon interactions with left and right circularly polarized(RCP)light,have gained research traction in recent years.CMMAs demonstrate numerous exotic and specialized applications owing to their achievable compatibility with various physical,chemical,and biomolecular systems.Aside from their well-evolved fabrication modalities for a broad range of frequencies,CMMAs exhibit strong chiroptical effects,making them central to various detection,imaging,and energy harvesting applications.Consequently,within the past decade,studies encompassing the design,optimization,and fabrication,as well as demonstrating the diverse applications of CMMAs have emerged.In this review,the theory,design,and fabrication of CMMAs are discussed,highlighting their top-down fabrication techniques as well as recent algorithmic and machine-learning(ML)-based approaches to the design and optimization.Some of their broad-spectrum applications are also discussed,spanning their roles in enantioselective photodetection,chiral imaging,generation of hot electrons,selective temperature sensing,and active chiral plasmonics.展开更多
基金supported by the National Key Research and Development Program(2021YFB2500210)the Beijing Municipal Natural Science Foundation(Z20J00043)+4 种基金the National Natural Science Foundation of China(22109086 and 21825501)the China Postdoctoral Science Foundation(2021TQ0161 and 2021 M691709)the Guoqiang Institute at Tsinghua University(2020GQG1006)the support from the Shuimu Tsinghua Scholar Program of Tsinghua Universitythe support from the Tsinghua National Laboratory for Information Science and Technology for theoretical simulations。
文摘Solid-state batteries have received increasing attention in scientific and industrial communities,which benefits from the intrinsically safe solid electrolytes(SEs).Although much effort has been devoted to designing SEs with high ionic conductivities,it is extremely difficult to fully understand the ionic diffusion mechanisms in SEs through conventional experimental and theoretical methods.Herein,the temperature-dependent concerted diffusion mechanism of ions in SEs is explored through machinelearning molecular dynamics,taking Li_(10)GeP_(2)S_(12) as a prototype.Weaker diffusion anisotropy,more disordered Li distributions,and shorter residence time are observed at a higher temperature.Arrhenius-type temperature dependence is maintained within a wide temperature range,which is attributed to the linear temperature dependence of jump frequencies of various concerted diffusion modes.These results provide a theoretical framework to understand the ionic diffusion mechanisms in SEs and deepen the understanding of the chemical origin of temperature-dependent concerted diffusions in SEs.
基金the China Postdoctoral Science Foundation under Grant No.2019M663467the National Natural Science Foundation of China under Grant No.62005037+2 种基金the Sichuan Science and Technology Program under Grant No.2020YJ0041the National Key Research and Development Program under Grant No.2019YFB2203400the“111 Project”under Grant No.B20030.
文摘Chiral metamaterial absorbers(CMMAs),a particular class of chiral metamaterials that refuse the transmission of incident radiation and exhibit different optical responses upon interactions with left and right circularly polarized(RCP)light,have gained research traction in recent years.CMMAs demonstrate numerous exotic and specialized applications owing to their achievable compatibility with various physical,chemical,and biomolecular systems.Aside from their well-evolved fabrication modalities for a broad range of frequencies,CMMAs exhibit strong chiroptical effects,making them central to various detection,imaging,and energy harvesting applications.Consequently,within the past decade,studies encompassing the design,optimization,and fabrication,as well as demonstrating the diverse applications of CMMAs have emerged.In this review,the theory,design,and fabrication of CMMAs are discussed,highlighting their top-down fabrication techniques as well as recent algorithmic and machine-learning(ML)-based approaches to the design and optimization.Some of their broad-spectrum applications are also discussed,spanning their roles in enantioselective photodetection,chiral imaging,generation of hot electrons,selective temperature sensing,and active chiral plasmonics.
