Tribovoltaic nanogenerators(TVNGs)have the characteristics of high current density,low matched impedance and continuous output,which is expected to solve the problem of power supply for small electronic devices.Howeve...Tribovoltaic nanogenerators(TVNGs)have the characteristics of high current density,low matched impedance and continuous output,which is expected to solve the problem of power supply for small electronic devices.However,wear occurrence in friction interface will seriously reduce the performance of TVNGs as well as lifetime.Here,we employ MXene solution as lubricate to improve output current density and lifetime of TVNG simultaneously,where a high value of 754 mA m^(-2)accompanied with a record durability of 90,000 cycles were achieved.By comparing multiple liquid lubricates with different polarity,we show that conductive polar liquid with MXene as additive plays a crucial role in enhancing the electrical output performance and durability of TVNG.Moreover,the universality of MXene solution is well demonstrated in various TVNGs with Cu and P-type Si,and Cu and N-GaAs as material pairs.This work may guide and accelerates the practical application of TVNG in future.展开更多
The effect of plasma and brine lubricants on the friction and wear behavior of UHMWPE were studied by using the geometry of a Si3N4 ball sliding on a UHMWPE disc under patterns of uni-directional reciprocation and bi-...The effect of plasma and brine lubricants on the friction and wear behavior of UHMWPE were studied by using the geometry of a Si3N4 ball sliding on a UHMWPE disc under patterns of uni-directional reciprocation and bi-directional sliding motions. The worn surface and wear particles produced in these two lubricants were analyzed. Sliding motion pattern affected the friction coefficients lubricated with plasma,while seldom affected that lubricated with brine. UHMWPE lubricated with plasma showed about half of the wear rate of that lubricated with brine. The two rates were 0.75 pg/m and 2.19 pg/m for the two motion patterns,respectively. However,wear particles generated in plasma included a greater amount of small particles,compared to that in brine. In uni-directional reciprocation,the main wear mechanism is ploughing both in plasma and in brine. In bi-directional sliding modes,the significant characteristic is ripples on the worn surface in plasma,while there are oriented fibers on the worn surface in brine.展开更多
The design and fabrication of high toughness electromagnetic interference(EMI)shielding composite films with diminished reflection are an imperative task to solve electromagnetic pollution problem.Ternary MXene/ANF(ar...The design and fabrication of high toughness electromagnetic interference(EMI)shielding composite films with diminished reflection are an imperative task to solve electromagnetic pollution problem.Ternary MXene/ANF(aramid nanofibers)–MoS_(2)composite films with nacre-like layered structure here are fabricated after the introduction of MoS_(2)into binary MXene/ANF composite system.The introduction of MoS_(2)fulfills an impressive“kill three birds with one stone”improvement effect:lubrication toughening mechanical performance,reduction in secondary reflection pollution of electromagnetic wave,and improvement in the performance of photothermal conversion.After the introduction of MoS_(2)into binary MXene/ANF(mass ratio of 50:50),the strain to failure and tensile strength increase from 22.1±1.7%and 105.7±6.4 MPa and to 25.8±0.7%and 167.3±9.1 MPa,respectively.The toughness elevates from 13.0±4.1 to 26.3±0.8 MJ m^(−3)(~102.3%)simultaneously.And the reflection shielding effectiveness(SE_(R))of MXene/ANF(mass ratio of 50:50)decreases~10.8%.EMI shielding effectiveness(EMI SE)elevates to 41.0 dB(8.2–12.4 GHz);After the introduction of MoS_(2)into binary MXene/ANF(mass ratio of 60:40),the strain to failure increases from 18.3±1.9%to 28.1±0.7%(~53.5%),the SE_(R)decreases~22.2%,and the corresponding EMI SE is 43.9 dB.The MoS_(2)also leads to a more efficient photothermal conversion performance(~45 to~55℃).Additionally,MXene/ANF–MoS_(2)composite films exhibit excellent electric heating performance,quick temperature elevation(15 s),excellent cycle stability(2,2.5,and 3 V),and long-term stability(2520 s).Combining with excellent mechanical performance with high MXene content,electric heating performance,and photothermal conversion performance,EMI shielding ternary MXene/ANF–MoS_(2)composite films could be applied in many industrial areas.This work broadens how to achieve a balance between mechanical properties and versatility of composites in the case of high-function fillers.展开更多
With the growth of deep drilling and the complexity of the well profile,the requirements for a more complete and efficient exploitation of productive formations increase,which increases the risk of various complicatio...With the growth of deep drilling and the complexity of the well profile,the requirements for a more complete and efficient exploitation of productive formations increase,which increases the risk of various complications.Currently,reagents based on modified natural polymers(which are naturally occurring compounds)and synthetic polymers(SPs)which are polymeric compounds created industrially,are widely used to prevent emerging complications in the drilling process.However,compared to modified natural polymers,SPs form a family of high-molecular-weight compounds that are fully synthesized by undergoing chemical polymerization reactions.SPs provide substantial flexibility in their design.Moreover,their size and chemical composition can be adjusted to provide properties for nearly all the functional objectives of drilling fluids.They can be classified based on chemical ingredients,type of reaction,and their responses to heating.However,some of SPs,due to their structural characteristics,have a high cost,a poor temperature and salt resistance in drilling fluids,and degradation begins when the temperature reaches 130℃.These drawbacks prevent SP use in some medium and deep wells.Thus,this review addresses the historical development,the characteristics,manufacturing methods,classification,and the applications of SPs in drilling fluids.The contributions of SPs as additives to drilling fluids to enhance rheology,filtrate generation,carrying of cuttings,fluid lubricity,and clay/shale stability are explained in detail.The mechanisms,impacts,and advances achieved when SPs are added to drilling fluids are also described.The typical challenges encountered by SPs when deployed in drilling fluids and their advantages and drawbacks are also discussed.Economic issues also impact the applications of SPs in drilling fluids.Consequently,the cost of the most relevant SPs,and the monomers used in their synthesis,are assessed.Environmental impacts of SPs when deployed in drilling fluids,and their manufacturing processes are identified,together with advances in SP-treatment methods aimed at reducing those impacts.Recommendations for required future research addressing SP property and performance gaps are provided.展开更多
Due to the mutual repulsion between their hydrophilic surface terminations and the high surface energy facilitating their ran-dom restacking,2D MXene nanosheets usually cannot self-assemble into 3D macroscopic gels wi...Due to the mutual repulsion between their hydrophilic surface terminations and the high surface energy facilitating their ran-dom restacking,2D MXene nanosheets usually cannot self-assemble into 3D macroscopic gels with various applications in the absence of proper linking agents.In this work,a rapid spontaneous gelation of Ti3C2Tx MXene with a very low dispersion concentration of 0.5 mg mL^(-1) into multifunctional architectures under moderate centrifugation is illustrated.The as-prepared MXene gels exhibit reconfigurable internal structures and tunable rheological,tribological,electrochemical,infrared-emissive and photothermal-conversion properties based on the pH-induced changes in the surface chemistry of Ti_(3)C_(2)T_(x) nanosheets.By adopting a gel with optimized pH value,high lubrication,exceptional specific capacitances(~635 and~408 F g^(-1) at 5 and 100 mV s^(-1),respectively),long-term capacitance retention(~96.7%after 10,000 cycles)and high-precision screen-or extrusion-printing into different high-resolution anticounterfeiting patterns can be achieved,thus displaying extensive potential applications in the fields of semi-solid lubrication,control-lable devices,supercapacitors,information encryption and infrared camouflaging.展开更多
To overcome the limitations of traditional experimental“trial and error”methods in lubricant additive design,a new molecular design method based on molecular structure parameters is established here.The molecular me...To overcome the limitations of traditional experimental“trial and error”methods in lubricant additive design,a new molecular design method based on molecular structure parameters is established here.The molecular mechanism of the antioxidant reaction of hindered phenol,diphenylamine,and alkyl sulfide are studied via molecular simulations.Calculation results show that the strong electron-donating ability and high hydrogen-donating activity of the antioxidant molecule and the low hydrogen-abstracting activity of free radicals formed after dehydrogenation are the internal molecular causes of the shielding of phenol and diphenylamine from scavenging peroxy free radicals,and the strong electron-donating ability is the internal molecular cause of the high activity of thioether in decomposing alkyl hydrogen peroxide.Based on this antioxidant molecular mechanism,a molecular design rule of antioxidant is proposed,namely“high EHOMO,large Q(S),low bond dissociation energy BDE(O—H)and BDE(N—H)”.Two new antioxidants,PAS-I and PAS-II,are designed and prepared by chemical bonding of hindered phenol,diphenylamine,and sulfur atoms.Experimental results show that these antioxidants both have excellent antioxidant effects in lubricating oil,and that PAS-II is the superior antioxidant,consistent with theoretical predictions.展开更多
This study prepared four types of ionic liquid-modified polypyrrole(IL-modified PPy)as conductive additives and investigated their tribological performance and conductivity in polytetrafluoroethylene lubricating greas...This study prepared four types of ionic liquid-modified polypyrrole(IL-modified PPy)as conductive additives and investigated their tribological performance and conductivity in polytetrafluoroethylene lubricating grease.The results indicated that IL-modified PPy effectively enhanced the anti-wear performance and conductivity of the base grease.Among the additives,1-octyl-3-methylimidazolium tetrafluoroborate([OMIm][BF4])modified PPy showed superior performance compared to the other three additives,with the best effect observed at a mass fraction of 0.5%.X-ray photoelectron spectroscopy analysis revealed that IL-modified PPy forms a stable friction chemical film during the friction process,effectively enhancing the lubrication performance and conductivity of the base grease.This indicates broad potential applications in the field of conductive lubrication.展开更多
To address the problem of identifying multiple types of additives in lubricating oil,a method based on midinfrared spectral band selection using the eXtreme Gradient Boosting(XGBoost)algorithm combined with the ant co...To address the problem of identifying multiple types of additives in lubricating oil,a method based on midinfrared spectral band selection using the eXtreme Gradient Boosting(XGBoost)algorithm combined with the ant colony optimization(ACO)algorithm is proposed.The XGBoost algorithm was used to train and test three additives,T534(alkyl diphenylamine),T308(isooctyl acid thiophospholipid octadecylamine),and T306(trimethylphenol phosphate),separately,in order to screen for the optimal combination of spectral bands for each additive.The ACO algorithm was used to optimize the parameters of the XGBoost algorithm to improve the identification accuracy.During this process,the support vector machine(SVM)and hybrid bat algorithms(HBA)were included as a comparison,generating four models:ACO-XGBoost,ACO-SVM,HBA-XGboost,and HBA-SVM.The results showed that all four models could identify the three additives efficiently,with the ACO-XGBoost model achieving 100%recognition of all three additives.In addition,the generalizability of the ACO-XGBoost model was further demonstrated by predicting a lubricating oil containing the three additives prepared in our laboratory and a collected sample of commercial oil currently in use。展开更多
The intermediate gearbox of a helicopter operates under splash lubrication.If the bearing produces metal particles due to insufficient lubrication or wear,whether it can be adsorbed by the metal particles signal at th...The intermediate gearbox of a helicopter operates under splash lubrication.If the bearing produces metal particles due to insufficient lubrication or wear,whether it can be adsorbed by the metal particles signal at the bottom of the gearbox and alarm directly affects the flight safety of the helicopter.Based on the CFD method,the factors affecting the accessibility of metal particles are analyzed by using the volume of fluid-discrete phase model(VOFDPM)coupling model,the RNG k-ɛturbulence model and the dynamic grid technology.Furthermore,the optimization research on the casing structure is conducted.Experimental results show that the accessibility of metal particles is optimal when the gear speed is 6000 rad/min or the immersion depth is 24 mm.The density of metal particles exhibits a nonlinear relationship with their accessibility,and the particle size has a relatively small impact on their accessibility without an order of magnitude change.展开更多
Tilting pad gas journal bearing is one of the most widely used types of aerodynamic bearings due to its inherent excellent stability in high speed applications.A practical method for analyzing and calculating the per-...Tilting pad gas journal bearing is one of the most widely used types of aerodynamic bearings due to its inherent excellent stability in high speed applications.A practical method for analyzing and calculating the per- formances of such bearings is presented as well as its rotordynamics based on the computer aided technique.The method of calculation and the philosophy of programming with a microcomputer for the computer aided analysis are highlighted.展开更多
To better understand and know the roles of cooling/lubrication medium in the cutting process and expand their applicability,uncoated cemented carbide tools are used in high-speed turning Ti6Al4V.Dry,cold air,minimal q...To better understand and know the roles of cooling/lubrication medium in the cutting process and expand their applicability,uncoated cemented carbide tools are used in high-speed turning Ti6Al4V.Dry,cold air,minimal quantity lubrication（MQL）,cryogenic MQL,and ionized air as the cooling/lubrication conditions are studied.Experimental results show that at speed 120 m/min turning Ti6Al4V,the cutting force under ionized air is smallest under all lubricant conditions,and tool life is best,next is cryogenic MQL.MQL and cold air almost have the same effect,a little better than dry.Meanwhile the smallest surface roughness is also obtained under ionized air condition.Flank wear and crater wear are the dominant failure modes when high-speed turning Ti6Al4V by SEM analysis.Finally the conclusion is drawn that ionized air and cryogenic MQL have better cooling/lubrication effects and can effectively improve the tool life.展开更多
In order to enhance the tribological properties of lubricating oil, suitable surfactants such as Tween-20, Tween-60, Span-20 and Sodium sodecylbenzenesulfonate were selected and lubricating oils containing CeO2 and Ti...In order to enhance the tribological properties of lubricating oil, suitable surfactants such as Tween-20, Tween-60, Span-20 and Sodium sodecylbenzenesulfonate were selected and lubricating oils containing CeO2 and TiO2 nanoparticles were prepared. The morphology and size of CeO2 and TiO2 nanoparticles were examined with a transmission electron microscope （TEM）. The tribological properties of the oils were tested using an MRS-1J four-ball tribotester. The research results show that when the proportion by weight of CeO2 nanoparticles to TiO2 nanoparticles is 1：3, and the total weight fraction is 0.6%, the lubricating oil has optimal anti-wear and friction reducing properties. The addition of CeO2 nanoparticles reduces the required amount of TiO2 nanoparticles.展开更多
The oil film clutch, which is superior in speed adjustment, is capable of being used in the belt conveyor to carry out soft start operation. According to running properties of both belt conveyor and oil film clutch...The oil film clutch, which is superior in speed adjustment, is capable of being used in the belt conveyor to carry out soft start operation. According to running properties of both belt conveyor and oil film clutch, equations that are used to decide the lubricating oil flow and the number of oil films (i.e. the number of rotating and stationary plates) are deduced theoretically. Also key parameters are provided for the design of the hydraulic system. All these together provide the theoretical basis for the soft start design of the belt conveyor and references for the application of the oil film clutch in similar fields.展开更多
The finite element method （FEM） is introduced to calculate the oil film pressure and temperature distribution of a journal bearing. The perturbation is performed directly on the finite element equation. Consequently...The finite element method （FEM） is introduced to calculate the oil film pressure and temperature distribution of a journal bearing. The perturbation is performed directly on the finite element equation. Consequently, the Jacobian matrices of the oil film forces are concisely obtained. The equilibrium position of the bearing with a given static load is found by the Newton-Raphson method. As byproducts, dynamic coefficients are obtained simultaneously without any extra computing time. From the numerical results, it is concluded that the effects of film temperature on stiffness coefficients are bigger than those on damping coefficients. With the increase of rotational speed, the load capacity and the stiffness coefficients of the journal bearing are increased when the eccentricity is small, while decreased when the eccentricity is big.展开更多
Friction and lubrication simulation analysis of internal combustion engine bearings are studied. A series of software implementary precepts for mathematical modeling, to analytic calculating and realizing simulation o...Friction and lubrication simulation analysis of internal combustion engine bearings are studied. A series of software implementary precepts for mathematical modeling, to analytic calculating and realizing simulation outcome are brought forward. As a dynamic simulating technique is introduced into the process of engine bearing design, simulation models of the oil film are built and the emulational analysis of the shaft center track is carried out. A software program package “Engine Bearing Friction and Lubrication Dynamic Simulation System” is developed to realize the real time simulation of the working status of bearing during the design process. Through developing virtualized products, the defects of the product design can be found in time and improve the products at once. Thus the purpose of predicting and controlling the cost, quality and design period of the products can be achieved.展开更多
The dynamic performances of floating-ring bearing with hydrodynamic/hydrostatic gas lubrication are studied theoretically and some calculated charts of dynamic coefficients are given in the paper. The method of stabil...The dynamic performances of floating-ring bearing with hydrodynamic/hydrostatic gas lubrication are studied theoretically and some calculated charts of dynamic coefficients are given in the paper. The method of stability analysis is also presented and it is proved that the high speed stability of such bearings is better than other types of gas bearings.展开更多
The inspection of engine lubricating oil can give an indication of the internal condition of an engine. By means of the Object-Oriented Programming (OOP), an expert system is developed in this paper to computerize the...The inspection of engine lubricating oil can give an indication of the internal condition of an engine. By means of the Object-Oriented Programming (OOP), an expert system is developed in this paper to computerize the inspection. The traditional components of an expert system, such us knowledge base, inference engine and user interface are reconstructed and integrated, based on the Microsoft Foundation Class (MFC) library. To testify the expert system, an inspection example is given at the end of this paper.展开更多
In the fault prediction of mechanical equipments through spectromectric oil analysis for worn off debris, a method for the determination of the limiting value of wear is proposed and discussed. In order to diagnose th...In the fault prediction of mechanical equipments through spectromectric oil analysis for worn off debris, a method for the determination of the limiting value of wear is proposed and discussed. In order to diagnose the impending failure and to predict the fault modes and locate the fault spots, a comprehensive approach is studied and outlined on the basis of methods of discriminative analysis and fuzzy logic. A fault diagnosis expert system OAFDS developed by the authors for the nonitoring of working conditions of the ND5 locomotive diesel engine Nd5 is briefly introduced.展开更多
The effectiveness of variable parameter squeeze oil film damper (VPSFD) in the steady and transient unbalance response control of flexible rotors is examined.First, a preliminary property design of VPSFD is presente...The effectiveness of variable parameter squeeze oil film damper (VPSFD) in the steady and transient unbalance response control of flexible rotors is examined.First, a preliminary property design of VPSFD is presented on the improved finite length bearing theory.VPSFD is different from the conventional squeeze film damper, and is designed to possess continuous changeable oil film clearance and land length. These parameters can be exactly adjusted on a computer by sending commends to a special control device. Then, a simple rotor system with VPSFD is investigated. The experimental results show that VPSFD can attenuate the rotor system resonance peak due to unbalance.展开更多
基金Research was supported by the National Key R&D Project from Minister of Science and Technology(2021YFA1201602)National Natural Science Foundation of China(Grant no.61774016,22109013,62204017)+1 种基金Fundamental Research Funds for the Central Universities(E1E46802)China Postdoctoral Science Foundation(2021M703172,2021M703171).
文摘Tribovoltaic nanogenerators(TVNGs)have the characteristics of high current density,low matched impedance and continuous output,which is expected to solve the problem of power supply for small electronic devices.However,wear occurrence in friction interface will seriously reduce the performance of TVNGs as well as lifetime.Here,we employ MXene solution as lubricate to improve output current density and lifetime of TVNG simultaneously,where a high value of 754 mA m^(-2)accompanied with a record durability of 90,000 cycles were achieved.By comparing multiple liquid lubricates with different polarity,we show that conductive polar liquid with MXene as additive plays a crucial role in enhancing the electrical output performance and durability of TVNG.Moreover,the universality of MXene solution is well demonstrated in various TVNGs with Cu and P-type Si,and Cu and N-GaAs as material pairs.This work may guide and accelerates the practical application of TVNG in future.
基金Project 50535050 supported by the National Natural Science Foundation of China
文摘The effect of plasma and brine lubricants on the friction and wear behavior of UHMWPE were studied by using the geometry of a Si3N4 ball sliding on a UHMWPE disc under patterns of uni-directional reciprocation and bi-directional sliding motions. The worn surface and wear particles produced in these two lubricants were analyzed. Sliding motion pattern affected the friction coefficients lubricated with plasma,while seldom affected that lubricated with brine. UHMWPE lubricated with plasma showed about half of the wear rate of that lubricated with brine. The two rates were 0.75 pg/m and 2.19 pg/m for the two motion patterns,respectively. However,wear particles generated in plasma included a greater amount of small particles,compared to that in brine. In uni-directional reciprocation,the main wear mechanism is ploughing both in plasma and in brine. In bi-directional sliding modes,the significant characteristic is ripples on the worn surface in plasma,while there are oriented fibers on the worn surface in brine.
基金supported by the Talent Fund of Beijing Jiaotong University(No,2023XKRC015)the National Natural Science Foundation of China(Nos.52172081,52073010 and 52373259).
文摘The design and fabrication of high toughness electromagnetic interference(EMI)shielding composite films with diminished reflection are an imperative task to solve electromagnetic pollution problem.Ternary MXene/ANF(aramid nanofibers)–MoS_(2)composite films with nacre-like layered structure here are fabricated after the introduction of MoS_(2)into binary MXene/ANF composite system.The introduction of MoS_(2)fulfills an impressive“kill three birds with one stone”improvement effect:lubrication toughening mechanical performance,reduction in secondary reflection pollution of electromagnetic wave,and improvement in the performance of photothermal conversion.After the introduction of MoS_(2)into binary MXene/ANF(mass ratio of 50:50),the strain to failure and tensile strength increase from 22.1±1.7%and 105.7±6.4 MPa and to 25.8±0.7%and 167.3±9.1 MPa,respectively.The toughness elevates from 13.0±4.1 to 26.3±0.8 MJ m^(−3)(~102.3%)simultaneously.And the reflection shielding effectiveness(SE_(R))of MXene/ANF(mass ratio of 50:50)decreases~10.8%.EMI shielding effectiveness(EMI SE)elevates to 41.0 dB(8.2–12.4 GHz);After the introduction of MoS_(2)into binary MXene/ANF(mass ratio of 60:40),the strain to failure increases from 18.3±1.9%to 28.1±0.7%(~53.5%),the SE_(R)decreases~22.2%,and the corresponding EMI SE is 43.9 dB.The MoS_(2)also leads to a more efficient photothermal conversion performance(~45 to~55℃).Additionally,MXene/ANF–MoS_(2)composite films exhibit excellent electric heating performance,quick temperature elevation(15 s),excellent cycle stability(2,2.5,and 3 V),and long-term stability(2520 s).Combining with excellent mechanical performance with high MXene content,electric heating performance,and photothermal conversion performance,EMI shielding ternary MXene/ANF–MoS_(2)composite films could be applied in many industrial areas.This work broadens how to achieve a balance between mechanical properties and versatility of composites in the case of high-function fillers.
文摘With the growth of deep drilling and the complexity of the well profile,the requirements for a more complete and efficient exploitation of productive formations increase,which increases the risk of various complications.Currently,reagents based on modified natural polymers(which are naturally occurring compounds)and synthetic polymers(SPs)which are polymeric compounds created industrially,are widely used to prevent emerging complications in the drilling process.However,compared to modified natural polymers,SPs form a family of high-molecular-weight compounds that are fully synthesized by undergoing chemical polymerization reactions.SPs provide substantial flexibility in their design.Moreover,their size and chemical composition can be adjusted to provide properties for nearly all the functional objectives of drilling fluids.They can be classified based on chemical ingredients,type of reaction,and their responses to heating.However,some of SPs,due to their structural characteristics,have a high cost,a poor temperature and salt resistance in drilling fluids,and degradation begins when the temperature reaches 130℃.These drawbacks prevent SP use in some medium and deep wells.Thus,this review addresses the historical development,the characteristics,manufacturing methods,classification,and the applications of SPs in drilling fluids.The contributions of SPs as additives to drilling fluids to enhance rheology,filtrate generation,carrying of cuttings,fluid lubricity,and clay/shale stability are explained in detail.The mechanisms,impacts,and advances achieved when SPs are added to drilling fluids are also described.The typical challenges encountered by SPs when deployed in drilling fluids and their advantages and drawbacks are also discussed.Economic issues also impact the applications of SPs in drilling fluids.Consequently,the cost of the most relevant SPs,and the monomers used in their synthesis,are assessed.Environmental impacts of SPs when deployed in drilling fluids,and their manufacturing processes are identified,together with advances in SP-treatment methods aimed at reducing those impacts.Recommendations for required future research addressing SP property and performance gaps are provided.
基金This work is financially supported by the Hundred Talents Program of Chinese Academy of Sciences(E30247YB)the Special Talents Program of Lanzhou Institute of Chemical Physics(E0SX0282)+1 种基金the National Natural Science Foundation of Shandong Province(ZR2022QB190)the Innovative Research Funds of Shandong Laboratory of Advanced Materials and Green Manufacturing at Yantai(E1R06SXM07,E1R06SXM09 and E2R06SXM14).
文摘Due to the mutual repulsion between their hydrophilic surface terminations and the high surface energy facilitating their ran-dom restacking,2D MXene nanosheets usually cannot self-assemble into 3D macroscopic gels with various applications in the absence of proper linking agents.In this work,a rapid spontaneous gelation of Ti3C2Tx MXene with a very low dispersion concentration of 0.5 mg mL^(-1) into multifunctional architectures under moderate centrifugation is illustrated.The as-prepared MXene gels exhibit reconfigurable internal structures and tunable rheological,tribological,electrochemical,infrared-emissive and photothermal-conversion properties based on the pH-induced changes in the surface chemistry of Ti_(3)C_(2)T_(x) nanosheets.By adopting a gel with optimized pH value,high lubrication,exceptional specific capacitances(~635 and~408 F g^(-1) at 5 and 100 mV s^(-1),respectively),long-term capacitance retention(~96.7%after 10,000 cycles)and high-precision screen-or extrusion-printing into different high-resolution anticounterfeiting patterns can be achieved,thus displaying extensive potential applications in the fields of semi-solid lubrication,control-lable devices,supercapacitors,information encryption and infrared camouflaging.
文摘To overcome the limitations of traditional experimental“trial and error”methods in lubricant additive design,a new molecular design method based on molecular structure parameters is established here.The molecular mechanism of the antioxidant reaction of hindered phenol,diphenylamine,and alkyl sulfide are studied via molecular simulations.Calculation results show that the strong electron-donating ability and high hydrogen-donating activity of the antioxidant molecule and the low hydrogen-abstracting activity of free radicals formed after dehydrogenation are the internal molecular causes of the shielding of phenol and diphenylamine from scavenging peroxy free radicals,and the strong electron-donating ability is the internal molecular cause of the high activity of thioether in decomposing alkyl hydrogen peroxide.Based on this antioxidant molecular mechanism,a molecular design rule of antioxidant is proposed,namely“high EHOMO,large Q(S),low bond dissociation energy BDE(O—H)and BDE(N—H)”.Two new antioxidants,PAS-I and PAS-II,are designed and prepared by chemical bonding of hindered phenol,diphenylamine,and sulfur atoms.Experimental results show that these antioxidants both have excellent antioxidant effects in lubricating oil,and that PAS-II is the superior antioxidant,consistent with theoretical predictions.
基金The authors would like to appreciate the financial support extended for this academic work by the Beijing Natural Science Foundation(Grants 2172053,2232066)the Open Project Foundation of State Key Laboratory of Solid Lubrication(Grant LSL-2212).
文摘This study prepared four types of ionic liquid-modified polypyrrole(IL-modified PPy)as conductive additives and investigated their tribological performance and conductivity in polytetrafluoroethylene lubricating grease.The results indicated that IL-modified PPy effectively enhanced the anti-wear performance and conductivity of the base grease.Among the additives,1-octyl-3-methylimidazolium tetrafluoroborate([OMIm][BF4])modified PPy showed superior performance compared to the other three additives,with the best effect observed at a mass fraction of 0.5%.X-ray photoelectron spectroscopy analysis revealed that IL-modified PPy forms a stable friction chemical film during the friction process,effectively enhancing the lubrication performance and conductivity of the base grease.This indicates broad potential applications in the field of conductive lubrication.
基金the Beijing Natural Science Foundation(Grant No.2232066)the Open Project Foundation of State Key Laboratory of Solid Lubrication(Grant LSL-2212).
文摘To address the problem of identifying multiple types of additives in lubricating oil,a method based on midinfrared spectral band selection using the eXtreme Gradient Boosting(XGBoost)algorithm combined with the ant colony optimization(ACO)algorithm is proposed.The XGBoost algorithm was used to train and test three additives,T534(alkyl diphenylamine),T308(isooctyl acid thiophospholipid octadecylamine),and T306(trimethylphenol phosphate),separately,in order to screen for the optimal combination of spectral bands for each additive.The ACO algorithm was used to optimize the parameters of the XGBoost algorithm to improve the identification accuracy.During this process,the support vector machine(SVM)and hybrid bat algorithms(HBA)were included as a comparison,generating four models:ACO-XGBoost,ACO-SVM,HBA-XGboost,and HBA-SVM.The results showed that all four models could identify the three additives efficiently,with the ACO-XGBoost model achieving 100%recognition of all three additives.In addition,the generalizability of the ACO-XGBoost model was further demonstrated by predicting a lubricating oil containing the three additives prepared in our laboratory and a collected sample of commercial oil currently in use。
基金supported by the Na‑tional Natural Science Foundation of China(No.52075241)the National Key Laboratory of Science and Technology on Helicopter Transmission(Nanjing University of Aeronau‑tics and Astronautics)(Nos.HTL-A-22K04 and HTL-O21G13).
文摘The intermediate gearbox of a helicopter operates under splash lubrication.If the bearing produces metal particles due to insufficient lubrication or wear,whether it can be adsorbed by the metal particles signal at the bottom of the gearbox and alarm directly affects the flight safety of the helicopter.Based on the CFD method,the factors affecting the accessibility of metal particles are analyzed by using the volume of fluid-discrete phase model(VOFDPM)coupling model,the RNG k-ɛturbulence model and the dynamic grid technology.Furthermore,the optimization research on the casing structure is conducted.Experimental results show that the accessibility of metal particles is optimal when the gear speed is 6000 rad/min or the immersion depth is 24 mm.The density of metal particles exhibits a nonlinear relationship with their accessibility,and the particle size has a relatively small impact on their accessibility without an order of magnitude change.
文摘Tilting pad gas journal bearing is one of the most widely used types of aerodynamic bearings due to its inherent excellent stability in high speed applications.A practical method for analyzing and calculating the per- formances of such bearings is presented as well as its rotordynamics based on the computer aided technique.The method of calculation and the philosophy of programming with a microcomputer for the computer aided analysis are highlighted.
基金Supported by the National Natural Science Foundation of China(50975141,51005118)~~
文摘To better understand and know the roles of cooling/lubrication medium in the cutting process and expand their applicability,uncoated cemented carbide tools are used in high-speed turning Ti6Al4V.Dry,cold air,minimal quantity lubrication（MQL）,cryogenic MQL,and ionized air as the cooling/lubrication conditions are studied.Experimental results show that at speed 120 m/min turning Ti6Al4V,the cutting force under ionized air is smallest under all lubricant conditions,and tool life is best,next is cryogenic MQL.MQL and cold air almost have the same effect,a little better than dry.Meanwhile the smallest surface roughness is also obtained under ionized air condition.Flank wear and crater wear are the dominant failure modes when high-speed turning Ti6Al4V by SEM analysis.Finally the conclusion is drawn that ionized air and cryogenic MQL have better cooling/lubrication effects and can effectively improve the tool life.
基金Supported by the Shanghai Municipal Education Commission(06FZ008)Shanghai Municipal Education Commission Key Disciplines(J50603)
文摘In order to enhance the tribological properties of lubricating oil, suitable surfactants such as Tween-20, Tween-60, Span-20 and Sodium sodecylbenzenesulfonate were selected and lubricating oils containing CeO2 and TiO2 nanoparticles were prepared. The morphology and size of CeO2 and TiO2 nanoparticles were examined with a transmission electron microscope （TEM）. The tribological properties of the oils were tested using an MRS-1J four-ball tribotester. The research results show that when the proportion by weight of CeO2 nanoparticles to TiO2 nanoparticles is 1：3, and the total weight fraction is 0.6%, the lubricating oil has optimal anti-wear and friction reducing properties. The addition of CeO2 nanoparticles reduces the required amount of TiO2 nanoparticles.
文摘The oil film clutch, which is superior in speed adjustment, is capable of being used in the belt conveyor to carry out soft start operation. According to running properties of both belt conveyor and oil film clutch, equations that are used to decide the lubricating oil flow and the number of oil films (i.e. the number of rotating and stationary plates) are deduced theoretically. Also key parameters are provided for the design of the hydraulic system. All these together provide the theoretical basis for the soft start design of the belt conveyor and references for the application of the oil film clutch in similar fields.
基金Supported by the National″111″Project(B07050)the China Postdoctoral Science Foundation(20100471634)~~
文摘The finite element method （FEM） is introduced to calculate the oil film pressure and temperature distribution of a journal bearing. The perturbation is performed directly on the finite element equation. Consequently, the Jacobian matrices of the oil film forces are concisely obtained. The equilibrium position of the bearing with a given static load is found by the Newton-Raphson method. As byproducts, dynamic coefficients are obtained simultaneously without any extra computing time. From the numerical results, it is concluded that the effects of film temperature on stiffness coefficients are bigger than those on damping coefficients. With the increase of rotational speed, the load capacity and the stiffness coefficients of the journal bearing are increased when the eccentricity is small, while decreased when the eccentricity is big.
文摘Friction and lubrication simulation analysis of internal combustion engine bearings are studied. A series of software implementary precepts for mathematical modeling, to analytic calculating and realizing simulation outcome are brought forward. As a dynamic simulating technique is introduced into the process of engine bearing design, simulation models of the oil film are built and the emulational analysis of the shaft center track is carried out. A software program package “Engine Bearing Friction and Lubrication Dynamic Simulation System” is developed to realize the real time simulation of the working status of bearing during the design process. Through developing virtualized products, the defects of the product design can be found in time and improve the products at once. Thus the purpose of predicting and controlling the cost, quality and design period of the products can be achieved.
文摘The dynamic performances of floating-ring bearing with hydrodynamic/hydrostatic gas lubrication are studied theoretically and some calculated charts of dynamic coefficients are given in the paper. The method of stability analysis is also presented and it is proved that the high speed stability of such bearings is better than other types of gas bearings.
文摘The inspection of engine lubricating oil can give an indication of the internal condition of an engine. By means of the Object-Oriented Programming (OOP), an expert system is developed in this paper to computerize the inspection. The traditional components of an expert system, such us knowledge base, inference engine and user interface are reconstructed and integrated, based on the Microsoft Foundation Class (MFC) library. To testify the expert system, an inspection example is given at the end of this paper.
文摘In the fault prediction of mechanical equipments through spectromectric oil analysis for worn off debris, a method for the determination of the limiting value of wear is proposed and discussed. In order to diagnose the impending failure and to predict the fault modes and locate the fault spots, a comprehensive approach is studied and outlined on the basis of methods of discriminative analysis and fuzzy logic. A fault diagnosis expert system OAFDS developed by the authors for the nonitoring of working conditions of the ND5 locomotive diesel engine Nd5 is briefly introduced.
文摘The effectiveness of variable parameter squeeze oil film damper (VPSFD) in the steady and transient unbalance response control of flexible rotors is examined.First, a preliminary property design of VPSFD is presented on the improved finite length bearing theory.VPSFD is different from the conventional squeeze film damper, and is designed to possess continuous changeable oil film clearance and land length. These parameters can be exactly adjusted on a computer by sending commends to a special control device. Then, a simple rotor system with VPSFD is investigated. The experimental results show that VPSFD can attenuate the rotor system resonance peak due to unbalance.
