Selenium distillation slag(SDS)is a high-value-added secondary resource with a high recovery value.This paper aims to investigate the leaching behavior and kinetics of selenium,tellurium,and copper in the SDS acid oxi...Selenium distillation slag(SDS)is a high-value-added secondary resource with a high recovery value.This paper aims to investigate the leaching behavior and kinetics of selenium,tellurium,and copper in the SDS acid oxidation leaching process with H_(2)SO_(4) and H_(2)O_(2).The experimental results showed that under the optimum conditions,the contents of selenium,tellurium,and copper in the SDS were reduced from 22.13 wt%,3.58 wt%,and 6.42 wt%to 3.06 wt%,0.27 wt%,and 0.33 wt%,respectively.Correspondingly,the recovery rates are 87.08%,97.15%and 99.7%.The leaching processes of selenium and tellurium were controlled by diffusion and chemical reactions,and the leaching behavior of copper was controlled by chemical reactions.Below 45℃,the activation energies for selenium,tellurium,and copper were found to be 26.47,62.18 and 19.67 kJ/mol,respectively.In addition,the contents of lead,silver and gold in the leaching residue are increased to 46.8 wt%,8.35 wt%and 0.27 wt%,respectively.These substances can be utilized as raw materials for the recovery of these valuable metals.Importantly,the entire process does not generate toxic or harmful waste,making it a green and environmentally friendly method for resource recovery.展开更多
LEACH(Low Energy Adaptive Clustering Hierarchy)是一种经典的WSN分层路由协议,它采取自适应分簇算法,一定程度上延长了网络生存期。然而LEACH路由协议的簇头随机产生,没有考虑节点的剩余能量,未达到簇头最优。LEACH簇头与基站直接通...LEACH(Low Energy Adaptive Clustering Hierarchy)是一种经典的WSN分层路由协议,它采取自适应分簇算法,一定程度上延长了网络生存期。然而LEACH路由协议的簇头随机产生,没有考虑节点的剩余能量,未达到簇头最优。LEACH簇头与基站直接通信,如果两者距离较远,则会带来较大的能量损耗。结合LEACH及LEACH现有的一些改进算法,提出了一种新的路由协议(Advance-Leach)。它综合考虑了节点的剩余能量和簇首节点数目,簇头和基站之间采用单跳和多跳结合策略,有效地降低了能耗,保证了网络负载的平衡。仿真结果表明:该协议的能耗、数据成功接收率等性能得到了有效提高,延长了节点和网络的生命周期。展开更多
针对Leach(low energy adaptive clustering hierarchy)协议在大规模网络中存在着数据传输效率不高和网络生命周期短的问题,提出了一种LEACH-CM-NGO优化算法。该方法通过在簇头选取阶段优化簇头数在所有节点中占比,引进能量密度因子和...针对Leach(low energy adaptive clustering hierarchy)协议在大规模网络中存在着数据传输效率不高和网络生命周期短的问题,提出了一种LEACH-CM-NGO优化算法。该方法通过在簇头选取阶段优化簇头数在所有节点中占比,引进能量密度因子和能耗因子改进阈值公式优化簇头分布,并在数据传输阶段,由原本的单跳传输改为多跳方式传输数据,引入基于立方映射方法,自适应权重策略和柯西变异的北方苍鹰优化算法改进簇头间数据传输路径,以提高网络的能效和数据传输效率。仿真结果表明,所提出的方法在减少能耗的同时,显著延长了网络的生命周期并提高了数据传输的成功率。展开更多
The phase transformation of galena in H_(2)SO_(4)-Fe_(2)(SO_(4))_(3) system under oxygen pressure was investigated.Results indicated that the critical conditions for the phase transformation of galena into lead jarosi...The phase transformation of galena in H_(2)SO_(4)-Fe_(2)(SO_(4))_(3) system under oxygen pressure was investigated.Results indicated that the critical conditions for the phase transformation of galena into lead jarosite(Pb-J)were 130℃,30 g/L H_(2)SO_(4),15 g/L Fe^(3+),and an oxygen partial pressure of 0.4 MPa.Furthermore,increased Fe^(3+)concentration and oxygen partial pressure did not enhance jarosite formation.Conversely,lowering the temperature and increasing the H_(2)SO_(4) concentration facilitated PbSO_(4) formation and inhibited its further conversion to Pb-J.Additionally,the effects of potassium sulfate,sodium sulfate,and high concentrations of zinc sulfate on the phase transformation of galena were examined through leaching tests,XRD,SEM-EDS,and FT-IR analyses.All three sulfates inhibited the conversion of galena to Pb-J.Among these,potassium sulfate prevented Pb-J formation and converted it more thoroughly into potassium jarosite.However,high concentrations of zinc sulfate facilitated the crystallization of both PbSO_(4) and Pb-J,which altered the morphology of the product.Zinc ions coprecipitated with Pb-J,thereby integrating into the product.展开更多
Full-component pyrolysis can process organic components and reduce cathode materials, making it a key focus in green recycling of lithium-ion batteries (LIBs). However, the leaching mechanism and kinetics of pyrolyzed...Full-component pyrolysis can process organic components and reduce cathode materials, making it a key focus in green recycling of lithium-ion batteries (LIBs). However, the leaching mechanism and kinetics of pyrolyzed black powder in organic acid systems remain unclear, with most research still at the laboratory stage. This study pioneers the exploration of the leaching behavior and reaction mechanism of valuable metal extraction from industrial-scale pyrolyzed black powder using citric acid. The effects of various leaching conditions on the extraction of metals were investigated by single factor experiments and response surface method. Under optimal conditions, the leaching efficiencies of Li, Ni, Co, and Mn all exceeded 97%. Kinetic analysis revealed that the leaching process was controlled by internal diffusion, with the apparent activation energies for Li, Ni, Co, and Mn being 17.89, 23.14, 20.27, and 15.21 kJ/mol, respectively. Additionally, residue characterization identified FePO4 formation as the primary inhibitor of iron dissolution.展开更多
In view of the difference in coordination capacity of the glycine ion(Gly−),a selective leaching process for treating with spent lithium-ion batteries(LIBs)in the alkaline glycinate system was proposed.The effects of ...In view of the difference in coordination capacity of the glycine ion(Gly−),a selective leaching process for treating with spent lithium-ion batteries(LIBs)in the alkaline glycinate system was proposed.The effects of retention time,leaching temperature,concentration of glycine ligand,liquid-solid ratio(L/S),pH,stirring speed,and H_(2)O_(2) dosage on the leaching efficiency of valuable metals and the dissolution of impurities were investigated.When the spent LIBs were leached in 3 mol/L glycine aqueous solution with pH of 8,L/S of 5 mL:1 g and H_(2)O_(2) dosage of 5 vol.%at 90℃and stirring speed of 400 r/min for 3 h,lithium,cobalt,nickel,and manganese recoveries were 96.31%,83.18%,91.56%,and 31.16%,respectively,but Ca,Al,Fe,and Cu were almost insoluble.Meanwhile,the kinetic study showed that the activation energies for the leaching of Li,Co,Ni,and Mn were all in the range of 45−61 kJ/mol.The results indicate that the leaching process is all controlled by chemical reactions.展开更多
In this study,a synergistic sulfidation-acid leaching process was proposed to recover valuable metals from gypsum residue and zinc-containing fume.The equilibrium phase composition of the sulfidation reaction and calc...In this study,a synergistic sulfidation-acid leaching process was proposed to recover valuable metals from gypsum residue and zinc-containing fume.The equilibrium phase composition of the sulfidation reaction and calculations of the thermodynamic stability region show that 89.36%Zn,>99%Pb and>99%Cu of gypsum residue and zinc-containing fume can be sulfured to ZnS,PbS and Cu 2 S,under sufficient sulfur partial pressure,low oxygen partial pressure and 400-1000℃.Sulfidation roasting experiments show that the sulfidation rate of Cu,Pb and Zn reach 81.43%,88.25% and 92.31%,respectively,under the roasting conditions of material mass ratio of 30 g:10 g,carbon dosage of 3.75 g,roasting temperature of 800℃ for 3 h.E−pH plots show that ZnS,PbS and Cu_(2)S can be enriched in the leaching residue,under leaching conditions at 25℃,pH<4 and-0.4 V<φ(E)<0.04 V.The leaching experiments showed that the sulfide is retained in the leaching residue,while the leaching rates of Cu,Pb and Zn are 1.94%,2.05% and 1.51%,respectively,under the conditions of 25℃,C_(HCl) of 0.5 mol/L,L/S of 5 mL/g,stirring rate of 300 r/min,and stirring time of 30 min.This study provides a new approach for the synergistic disposal of gypsum residue and zinc containing fume.展开更多
无线传感器网络(WSN)数据传输离不开路由协议,路由协议是其组网的基础.由于WSN是一种资源受限网络,尤其是能量的受限,因此路由协议必须维持较小的路由信息并尽可能的减少能耗.文中从其体系结构、协议栈、网络层次等几个方面分析介绍了...无线传感器网络(WSN)数据传输离不开路由协议,路由协议是其组网的基础.由于WSN是一种资源受限网络,尤其是能量的受限,因此路由协议必须维持较小的路由信息并尽可能的减少能耗.文中从其体系结构、协议栈、网络层次等几个方面分析介绍了无线传感器网络,在对传感器网络路由协议作了充分了解的基础上深入研究了经典的聚类路由算法——LEACH(Low Energy Adaptive Clustering Hierarchy),提出了对它的改进方案并用OPNET对改进前后的算法进行了仿真比较.仿真结果证明了改进后算法的有效性,并且在能耗和网络生存时间上比LEACH有了提高.展开更多
基金Project(2022YFC2904900) supported by the National Key Research and Development Program of ChinaProject(U1902221) supported by the National Natural Science Foundation of China。
文摘Selenium distillation slag(SDS)is a high-value-added secondary resource with a high recovery value.This paper aims to investigate the leaching behavior and kinetics of selenium,tellurium,and copper in the SDS acid oxidation leaching process with H_(2)SO_(4) and H_(2)O_(2).The experimental results showed that under the optimum conditions,the contents of selenium,tellurium,and copper in the SDS were reduced from 22.13 wt%,3.58 wt%,and 6.42 wt%to 3.06 wt%,0.27 wt%,and 0.33 wt%,respectively.Correspondingly,the recovery rates are 87.08%,97.15%and 99.7%.The leaching processes of selenium and tellurium were controlled by diffusion and chemical reactions,and the leaching behavior of copper was controlled by chemical reactions.Below 45℃,the activation energies for selenium,tellurium,and copper were found to be 26.47,62.18 and 19.67 kJ/mol,respectively.In addition,the contents of lead,silver and gold in the leaching residue are increased to 46.8 wt%,8.35 wt%and 0.27 wt%,respectively.These substances can be utilized as raw materials for the recovery of these valuable metals.Importantly,the entire process does not generate toxic or harmful waste,making it a green and environmentally friendly method for resource recovery.
文摘LEACH(Low Energy Adaptive Clustering Hierarchy)是一种经典的WSN分层路由协议,它采取自适应分簇算法,一定程度上延长了网络生存期。然而LEACH路由协议的簇头随机产生,没有考虑节点的剩余能量,未达到簇头最优。LEACH簇头与基站直接通信,如果两者距离较远,则会带来较大的能量损耗。结合LEACH及LEACH现有的一些改进算法,提出了一种新的路由协议(Advance-Leach)。它综合考虑了节点的剩余能量和簇首节点数目,簇头和基站之间采用单跳和多跳结合策略,有效地降低了能耗,保证了网络负载的平衡。仿真结果表明:该协议的能耗、数据成功接收率等性能得到了有效提高,延长了节点和网络的生命周期。
文摘针对Leach(low energy adaptive clustering hierarchy)协议在大规模网络中存在着数据传输效率不高和网络生命周期短的问题,提出了一种LEACH-CM-NGO优化算法。该方法通过在簇头选取阶段优化簇头数在所有节点中占比,引进能量密度因子和能耗因子改进阈值公式优化簇头分布,并在数据传输阶段,由原本的单跳传输改为多跳方式传输数据,引入基于立方映射方法,自适应权重策略和柯西变异的北方苍鹰优化算法改进簇头间数据传输路径,以提高网络的能效和数据传输效率。仿真结果表明,所提出的方法在减少能耗的同时,显著延长了网络的生命周期并提高了数据传输的成功率。
基金Projects(2023AG05008,202302AB080012)supported by the Yunnan Major Scientific and Technological Program,ChinaProject(202405AC350015)supported by the Science and Technology Talent Programme of Yunnan Province,China。
文摘The phase transformation of galena in H_(2)SO_(4)-Fe_(2)(SO_(4))_(3) system under oxygen pressure was investigated.Results indicated that the critical conditions for the phase transformation of galena into lead jarosite(Pb-J)were 130℃,30 g/L H_(2)SO_(4),15 g/L Fe^(3+),and an oxygen partial pressure of 0.4 MPa.Furthermore,increased Fe^(3+)concentration and oxygen partial pressure did not enhance jarosite formation.Conversely,lowering the temperature and increasing the H_(2)SO_(4) concentration facilitated PbSO_(4) formation and inhibited its further conversion to Pb-J.Additionally,the effects of potassium sulfate,sodium sulfate,and high concentrations of zinc sulfate on the phase transformation of galena were examined through leaching tests,XRD,SEM-EDS,and FT-IR analyses.All three sulfates inhibited the conversion of galena to Pb-J.Among these,potassium sulfate prevented Pb-J formation and converted it more thoroughly into potassium jarosite.However,high concentrations of zinc sulfate facilitated the crystallization of both PbSO_(4) and Pb-J,which altered the morphology of the product.Zinc ions coprecipitated with Pb-J,thereby integrating into the product.
基金Projects(52174269, 52374293) supported by the National Natural Science Foundation of ChinaProjects(2024CK1009, 2022RC1123) supported by the Science and Technology Innovation Program of Hunan Province,China。
文摘Full-component pyrolysis can process organic components and reduce cathode materials, making it a key focus in green recycling of lithium-ion batteries (LIBs). However, the leaching mechanism and kinetics of pyrolyzed black powder in organic acid systems remain unclear, with most research still at the laboratory stage. This study pioneers the exploration of the leaching behavior and reaction mechanism of valuable metal extraction from industrial-scale pyrolyzed black powder using citric acid. The effects of various leaching conditions on the extraction of metals were investigated by single factor experiments and response surface method. Under optimal conditions, the leaching efficiencies of Li, Ni, Co, and Mn all exceeded 97%. Kinetic analysis revealed that the leaching process was controlled by internal diffusion, with the apparent activation energies for Li, Ni, Co, and Mn being 17.89, 23.14, 20.27, and 15.21 kJ/mol, respectively. Additionally, residue characterization identified FePO4 formation as the primary inhibitor of iron dissolution.
基金Projects(51974137,52274299)supported by the National Natural Science Foundation of ChinaProject(2023M733190)supported by the China Postdoctoral Science Foundation。
文摘In view of the difference in coordination capacity of the glycine ion(Gly−),a selective leaching process for treating with spent lithium-ion batteries(LIBs)in the alkaline glycinate system was proposed.The effects of retention time,leaching temperature,concentration of glycine ligand,liquid-solid ratio(L/S),pH,stirring speed,and H_(2)O_(2) dosage on the leaching efficiency of valuable metals and the dissolution of impurities were investigated.When the spent LIBs were leached in 3 mol/L glycine aqueous solution with pH of 8,L/S of 5 mL:1 g and H_(2)O_(2) dosage of 5 vol.%at 90℃and stirring speed of 400 r/min for 3 h,lithium,cobalt,nickel,and manganese recoveries were 96.31%,83.18%,91.56%,and 31.16%,respectively,but Ca,Al,Fe,and Cu were almost insoluble.Meanwhile,the kinetic study showed that the activation energies for the leaching of Li,Co,Ni,and Mn were all in the range of 45−61 kJ/mol.The results indicate that the leaching process is all controlled by chemical reactions.
基金Projects(52174269,52374293)supported by the National Natural Science Foundation of ChinaProject(2022RC1123)supported by the Science and Technology Innovation Program of Hunan Province,China。
文摘In this study,a synergistic sulfidation-acid leaching process was proposed to recover valuable metals from gypsum residue and zinc-containing fume.The equilibrium phase composition of the sulfidation reaction and calculations of the thermodynamic stability region show that 89.36%Zn,>99%Pb and>99%Cu of gypsum residue and zinc-containing fume can be sulfured to ZnS,PbS and Cu 2 S,under sufficient sulfur partial pressure,low oxygen partial pressure and 400-1000℃.Sulfidation roasting experiments show that the sulfidation rate of Cu,Pb and Zn reach 81.43%,88.25% and 92.31%,respectively,under the roasting conditions of material mass ratio of 30 g:10 g,carbon dosage of 3.75 g,roasting temperature of 800℃ for 3 h.E−pH plots show that ZnS,PbS and Cu_(2)S can be enriched in the leaching residue,under leaching conditions at 25℃,pH<4 and-0.4 V<φ(E)<0.04 V.The leaching experiments showed that the sulfide is retained in the leaching residue,while the leaching rates of Cu,Pb and Zn are 1.94%,2.05% and 1.51%,respectively,under the conditions of 25℃,C_(HCl) of 0.5 mol/L,L/S of 5 mL/g,stirring rate of 300 r/min,and stirring time of 30 min.This study provides a new approach for the synergistic disposal of gypsum residue and zinc containing fume.
文摘无线传感器网络(WSN)数据传输离不开路由协议,路由协议是其组网的基础.由于WSN是一种资源受限网络,尤其是能量的受限,因此路由协议必须维持较小的路由信息并尽可能的减少能耗.文中从其体系结构、协议栈、网络层次等几个方面分析介绍了无线传感器网络,在对传感器网络路由协议作了充分了解的基础上深入研究了经典的聚类路由算法——LEACH(Low Energy Adaptive Clustering Hierarchy),提出了对它的改进方案并用OPNET对改进前后的算法进行了仿真比较.仿真结果证明了改进后算法的有效性,并且在能耗和网络生存时间上比LEACH有了提高.
