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Hardening mechanism and thermal-solid coupling model of laminar plasma surface hardening of 65 Mn steel
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作者 Xiuquan CAO Lin WANG +2 位作者 Haoming XU Guangzhong HU Chao LI 《Plasma Science and Technology》 SCIE EI CAS CSCD 2024年第12期110-120,共11页
In the present work,the laminar plasma surface hardening method is employed to enhance the service life of metal components fabricated from 65 Mn steel.The mechanical and wear behaviors of the laminar plasma surface h... In the present work,the laminar plasma surface hardening method is employed to enhance the service life of metal components fabricated from 65 Mn steel.The mechanical and wear behaviors of the laminar plasma surface hardened 65 Mn steel were analyzed.The martensite transition transformation of the temperature of the laminar plasma-hardened 65 ferrite Mn steel was determined by a thermal-solid coupling model.Based on the orthogonal experimental results,the optimal hardening parameters were confirmed.The scanning velocity,quenching distance and arc current are 130 mm/min,50 mm and 120 A,respectively.The pearlites and ferrites are transformed into martensites in the hardened zone,while the ratio of martensite in the heataffected zone decreases with the increase in the hardening depth.Compared to the untreated 65Mn steel,the average hardness increases from 220 HV_(0.2)to 920 HV_(0.2)in the hardened zone and the corresponding absorbed power increases from 118.7 J to 175.5 J.At the same time,the average coefficient of friction(COF)decreases from 0.763 to 0.546,and the wear rate decreases from 5.39×10^(-6)mm^(3)/(N·m)to 2.95×10^(-6)mm^(3)/(N·m),indicating that the wear resistance of 65Mn steel could be significantly improved by using laminar surface hardening.With the same hardening parameters,the depth and width of the hardened zone predicted by the thermal-solid coupling model are 1.85 mm and 11.20 mm,respectively,which are in accordance with the experimental results;depth is 1.83 mm and width is 11.15 mm.In addition,the predicted hardness distributions of the simulation model are in accordance with the experimental results.These results indicate that the simulation model could effectively predict the microstructure characteristics of 65 Mn steel. 展开更多
关键词 65 Mn steel laminar plasma surface hardening hardening mechanism microstructure characteristics thermal-solid coupling model
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Flow Control with Intermittent Disturbance for the Laminar Separation Bubble on a NACA633-421 Airfoil
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作者 SIPKADUWA MADUWA GURUGE Supun Induwara Perera LI Linkai WANG Shilong 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI CSCD 2024年第S01期1-12,共12页
This study investigates the aerodynamic performance of the NACA 633-421 airfoil and the effectiveness and feasibility of intermittent disturbance flow control methods on laminar separation bubbles(LSBs).It is found th... This study investigates the aerodynamic performance of the NACA 633-421 airfoil and the effectiveness and feasibility of intermittent disturbance flow control methods on laminar separation bubbles(LSBs).It is found that the average velocity and influence range of the synthetic jet actuator increase with the increasing of driving frequency and driving amplitude.LSB occurs at Re=1.0×10^(5),and ruptures atα=6°.But with intermittent disturbance control,the stall angle of attack(AoA)increases while significantly reducing drag.Research shows that although certain disturbance cannot fully recover from LSB stall,decreasing driving amplitude partially restores wing aerodynamic performance,more effectively than increasing driving amplitude. 展开更多
关键词 laminar separation bubble intermittent disturbance control driving frequency driving amplitude synthetic jet actuator
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Analytical Solution for Laminar Viscous Flow inthe Gap Between Two Parallel Rotary Disks 被引量:2
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作者 刘淑艳 阎为革 《Journal of Beijing Institute of Technology》 EI CAS 1998年第2期113-119,共7页
Aim To get the analytical for laminar viscous flow in the gap of two parallel rotating disks. Methods By estimating the order of magnitude of each term in the Navier-Stokes equations to drop small terms and achieve... Aim To get the analytical for laminar viscous flow in the gap of two parallel rotating disks. Methods By estimating the order of magnitude of each term in the Navier-Stokes equations to drop small terms and achieve the required simplified differential equations, and by integrating the equations to obtain the solution for theflow between two rotary disks. Results Parameters related to the laminar viscous flow in the gap between two parallel rotary disks, such as the velocity, the pressure, the flowrate, the force, the shearing stress, the torque and the power derived. Conclusion The result provides a theoretical basis and an effective method for the designs of the devices connected with the laminar viscous flow in the gap between two parallel rotary disks. 展开更多
关键词 laminar viscous flow rotary disk GAP
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Arc Voltage Fluctuation in DC Laminar and Turbulent Plasma Jets Generation 被引量:4
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作者 潘文霞 孟显 吴承康 《Plasma Science and Technology》 SCIE EI CAS CSCD 2006年第4期416-421,共6页
Arc voltage fluctuations in a direct current (DC) non-transferred arc plasma generator are experimentally studied, in generating a jet in the laminar, transitional and turbulent regimes. The study is with a view tow... Arc voltage fluctuations in a direct current (DC) non-transferred arc plasma generator are experimentally studied, in generating a jet in the laminar, transitional and turbulent regimes. The study is with a view toward elucidating the mechanism of the fluctuations and their relationship with the generating parameters, arc root movement and flow regimes. Results indicate that the existence of a 300 Hz alternating current (AC) component in the power supply ripples does not cause the transition of the laminar plasma jet into a turbulent state. There exists a high frequency fluctuation at 4 kHz in the turbulent jet regime. It may be related to the rapid movement of the anode attachment point of the arc. 展开更多
关键词 DC plasma jet fluctuation characteristics laminar flow turbulent flow experimental study
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A two-dimension laminar composite protective layer for dendrite-free lithium metal anode 被引量:4
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作者 Xiang-Qun Xu Rui Xu +4 位作者 Xin-Bing Cheng Ye Xiao Hong-Jie Peng Hong Yuan Fangyang Liu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2021年第5期391-394,共4页
Lithium(Li)metal anodes with the high theoretical specific capacity(3860 mAh g^(-1))and most negative reduction potential(-3.04 V vs.standard hydrogen electrode)have been considered as an ultimate choice for energy st... Lithium(Li)metal anodes with the high theoretical specific capacity(3860 mAh g^(-1))and most negative reduction potential(-3.04 V vs.standard hydrogen electrode)have been considered as an ultimate choice for energy storage devices with high energy density[1-4].However,the practical applications of Li metalbased batteries(LMBs)are confronted with two tough issues:Li dendrite growth induced by uneven Li depositions and unstable solid electrolyte interphase(SEI)(Fig.1a)[5,6]. 展开更多
关键词 Lithium metal anode Artificial protective layer 2D materials Vermiculite sheets laminar arrangement
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Influence of the Laminar Plasma Torch Construction on the Jet Characteristics 被引量:2
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作者 曹修全 余德平 +2 位作者 向勇 姚进 苗建国 《Plasma Science and Technology》 SCIE EI CAS CSCD 2016年第7期740-743,共4页
Based on two typical laminar plasma torches (LPT), i.e. a multi-electrode plasma torch (MEPT) with segmented anode structure and a two-electrode plasma torch (TEPT) with conventional structure, this paper studie... Based on two typical laminar plasma torches (LPT), i.e. a multi-electrode plasma torch (MEPT) with segmented anode structure and a two-electrode plasma torch (TEPT) with conventional structure, this paper studied the influence of the LPTs construction on the jet characteristics. Experiments were designed to measure their arc voltage, jet length, thermal efficiency and specific enthalpy using a home-made data acquisition system. With them, the jet characteristics of the two different LPTs were compared in detail. Results show that different plasma torch construction leads to distinctively different characteristics of the generated plasma jet. Based on the different jet characteristics, a plasma torch with appropriate construction could be used to meet the different application requirements. 展开更多
关键词 laminar plasma torch jet characteristics thermal efficiency specific enthalpy
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Numerical Investigation of Hydrodynamic Flow Over an AUV Moving in the Water-surface Vicinity Considering the Laminar-turbulent Transition 被引量:3
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作者 Mahmoud Salari Amin Rava 《Journal of Marine Science and Application》 CSCD 2017年第3期298-304,共7页
Nowadays, Autonomous Underwater Vehicles(AUVs) are frequently used for exploring the oceans. The hydrodynamics of AUVs moving in the vicinity of the water surface are significantly different at higher depths. In this ... Nowadays, Autonomous Underwater Vehicles(AUVs) are frequently used for exploring the oceans. The hydrodynamics of AUVs moving in the vicinity of the water surface are significantly different at higher depths. In this paper, the hydrodynamic coefficients of an AUV in non-dimensional depths of 0.75, 1, 1.5, 2, and 4D are obtained for movement close to the free-surface. Reynolds Averaged Navier Stokes Equations(RANS) are discretized using the finite volume approach and the water-surface effects modeled using the Volume of Fraction(VOF) method. As the operating speeds of AUVs are usually low, the boundary layer over them is not fully laminar or fully turbulent, so the effect of boundary layer transition from laminar to turbulent flow was considered in the simulations. Two different turbulence/transition models were used: 1) a full-turbulence model, the k-ε model, and 2) a turbulence/transition model, Menter's Transition-SST model. The results show that the Menter's Transition-SST model has a better consistency with experimental results. In addition, the wave-making effects of these bodies are studied at different immersion depths in the sea-surface vicinity or at finite depths. It is observed that the relevant pitch moments and lift coefficients are non-zero for these axi-symmetric bodies when they move close to the sea-surface. This is not expected for greater depths. 展开更多
关键词 autonomous underwater vehicles sea surface effects computational fluid dynamics HYDRODYNAMICS laminar to turbulent transition
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Preliminary Studies of Practicability of Laminar Plasma Surface Treatment Process 被引量:1
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作者 马维 潘文霞 吴承康 《Plasma Science and Technology》 SCIE EI CAS CSCD 2006年第3期316-320,共5页
The basic remelting and cladding tests with laminar plasma technology on metals have been conducted in order to demonstrate the possibility of the technology applied in material surface modification. The experimental ... The basic remelting and cladding tests with laminar plasma technology on metals have been conducted in order to demonstrate the possibility of the technology applied in material surface modification. The experimental results show that the properties of the modified layers of the cast iron surface can be improved notably by the remelting treatment and those of the stainless steel by the cladding treatment. The related results are also verified by microscopic studies such as scanning electron microscopic (SEM) observations, energy dispersive spectra (EDS) analysis and the Vickers hardness measurements of the surface modified layers. 展开更多
关键词 REMELTING CLADDING laminar plasma technology surface modification microscopic studies
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A GPU-Accelerated Discontinuous Galerkin Method for Solving Two-Dimensional Laminar Flows 被引量:2
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作者 GAO Huanqin CHEN Hongquan +2 位作者 ZHANG Jiale XU Shengguan GAO Yukun 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI CSCD 2022年第4期450-466,共17页
A graphics processing unit(GPU)-accelerated discontinuous Galerkin(DG)method is presented for solving two-dimensional laminar flows.The DG method is ported from central processing unit to GPU in a way of achieving GPU... A graphics processing unit(GPU)-accelerated discontinuous Galerkin(DG)method is presented for solving two-dimensional laminar flows.The DG method is ported from central processing unit to GPU in a way of achieving GPU speedup through programming under the compute unified device architecture(CUDA)model.The CUDA kernel subroutines are designed to meet with the requirement of high order computing of DG method.The corresponding data structures are constructed in component-wised manners and the thread hierarchy is manipulated in cell-wised or edge-wised manners associated with related integrals involved in solving laminar Navier-Stokes equations,in which the inviscid and viscous flux terms are computed by the local lax-Friedrichs scheme and the second scheme of Bassi&Rebay,respectively.A strong stability preserving Runge-Kutta scheme is then used for time marching of numerical solutions.The resulting GPU-accelerated DG method is first validated by the traditional Couette flow problems with different mesh sizes associated with different orders of approximation,which shows that the orders of convergence,as expected,can be achieved.The numerical simulations of the typical flows over a circular cylinder or a NACA 0012 airfoil are then carried out,and the results are further compared with the analytical solutions or available experimental and numerical values reported in the literature,as well as with a performance analysis of the developed code in terms of GPU speedups.This shows that the costs of computing time of the presented test cases are significantly reduced without losing accuracy,while impressive speedups up to 69.7 times are achieved by the present method in comparison to its CPU counterpart. 展开更多
关键词 discontinuous Galerkin GPU compute unified device architecture(CUDA) Navier-Stokes equation laminar flows
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Design and characteristics of a new type laminar plasma torch for materials processing 被引量:1
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作者 Xiuquan CAO Lin CHEN 《Plasma Science and Technology》 SCIE EI CAS CSCD 2020年第1期24-32,共9页
Laminar plasma jet(LPJ)generated by laminar plasma torch(LPT)has a favorable temperature and velocity distribution.Thus,it is superior to the turbulent plasma jet in material processing.However,most of the reported LP... Laminar plasma jet(LPJ)generated by laminar plasma torch(LPT)has a favorable temperature and velocity distribution.Thus,it is superior to the turbulent plasma jet in material processing.However,most of the reported LPTs usually operate at a relatively low output power with a relatively low arc voltage and thermal efficiency,which limits its capabilities.In this context,this paper attempts to design a new type of high-power LPT with a relatively low arc current and a high thermal efficiency.In the first section,the design principle of the main components is studied and discussed in detail,and a new high-power LPT is proposed.Then,the experimental characteristics of the proposed high-power LPT are examined.Experimental results reveal the following characteristics of the proposed LPT.(1)The max jet length of the proposed LPT reaches at 540 mm.(2)Its mean arc voltage is higher than 290 V when the LPT works with arc currents lower than 200 A.leading to an output power greater than 50 kW.(3)The mean thermal efficiency is higher than 509f.Lastly,the proposed LPT has been applied to spheroidize the aluminum oxide powers.The experiment results for the production of spherical powders show that the proposed LPT hits a good characteristic for material processing. 展开更多
关键词 laminar plasma torch design principles high arc voltage with a low arc current spheroidisation
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A Review of the Attachment Line Instability for Hybrid Laminar Flow Control 被引量:2
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作者 张馨元 《民用飞机设计与研究》 2017年第4期42-51,共10页
This paper focuses on the investigation of the attachment line instability for Hybrid Laminar Flow Control(HLFC),one of the most promising drag reduction technologies for modern transport aircraft respect to high Reyn... This paper focuses on the investigation of the attachment line instability for Hybrid Laminar Flow Control(HLFC),one of the most promising drag reduction technologies for modern transport aircraft respect to high Reynolds numbers and large sweep angles.The attachment line instability also plays an important role during laminar-turbulent transition control and HLFC design on a swept wing.The overview of historical research is presented and knowledge gaps are pointed out as the conclusion. 展开更多
关键词 attachment line hybrid laminar flow control(HLFC) boundary layer subcritical instability leading edge
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Measurement of laminar burning velocities and Markstein lengths near rich propane/air flammability limits under microgravity conditions
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作者 胡俊 任坦 《Journal of Beijing Institute of Technology》 EI CAS 2011年第4期466-471,共6页
A small cubic closed vessel with schlieren measurement technique combined with high-speed video camera were used to study limit flame properties under microgravity conditions at atmospheric pressure and room temperatu... A small cubic closed vessel with schlieren measurement technique combined with high-speed video camera were used to study limit flame properties under microgravity conditions at atmospheric pressure and room temperature.The rich flammability limit of C3H8/air was determined to be 9.2% C3H8.Stretched flame propagation speeds,stretched laminar burning velocities and unstretched laminar burning velocities near rich C3H8/air flammability limits were measured at different equivalence ratios.Outwardly propagating spherical flames were used to study the sensitivities of the flame propagation speeds and laminar burning velocities to flame stretch using Markstein lengths.Unstretched laminar burning velocity at rich flammability limit was determined to be 1.09cm/s.Lewis numbers were less than unity in rich C3H8/air and negative Markstein lengths were concluded.Absolute values of Markstein lengths were found to decrease linearly with equivalence ratios increase. 展开更多
关键词 laminar burning velocity Markstein lengths rich flammability limit flame stretch
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NUMERICAL STUDY ON EFFECT OF OPERATING TABLE PROTECTED BY HORIZONTAL LAMINAR FLOW SCREEN
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作者 范菊莉 杨晓静 +1 位作者 王思涵 郑小漪 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI 2013年第3期292-296,共5页
Transmission of airborne bacteria is the main factor causing surgical site infection(SSI),which is harmful to patients′health and even lives.Numerical study is conducted on the effect of the operating table protected... Transmission of airborne bacteria is the main factor causing surgical site infection(SSI),which is harmful to patients′health and even lives.Numerical study is conducted on the effect of the operating table protected by horizontal laminar flow screen.Discrete phase model(DPM)is used.Numerical simulation is carried out to evaluate particle trajectories with the Lagrange approach.As a result,the protecting effect of horizontal laminar flow screen is established,and the protecting parameters of the air velocity supplied by the screen and the protecting distance are optimized.The optimized air velocity supplied by the screen should be at 0.4—0.6 m/s.And the protecting distance should be less than 1.3 m.This work provides references for the study on the depuration of operating table or room. 展开更多
关键词 laminar flow screen particle trajectories discrete phase model operating table
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THEORETICAL ANALYSIS ON HYDRAULIC TRANSIENT RESULTED BY SUDDEN INCREASE OF INLET PRESSURE FOR LAMINAR PIPELINE FLOW 被引量:1
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作者 邓松圣 周绍骑 +2 位作者 廖振方 邱正阳 曾顺鹏 《应用数学和力学》 EI CSCD 北大核心 2004年第6期614-620,共7页
Hydraulic transient, which is resulted from sudden increase of inlet pressure for laminar pipeline flow, is studied. The partial differential equation, initial and boundary conditions for transient pressure were const... Hydraulic transient, which is resulted from sudden increase of inlet pressure for laminar pipeline flow, is studied. The partial differential equation, initial and boundary conditions for transient pressure were constructed, and the theoretical solution was obtained by variable-separation method. The partial differential equation, initial and boundary conditions for flow rate were obtained in accordance with the constraint correlation between flow rate and pressure while the transient flow rate distribution was also solved by variable-separation method. The theoretical solution conforms to numerical solution obtained by method of characteristics (MOC) very well. 展开更多
关键词 层流 管流 水力瞬变 理论解
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低雷诺数下偏心扭转圆柱涡激振动特性研究
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作者 孙旭 SUHC.Steve 张家忠 《力学与实践》 2025年第1期87-97,共11页
横掠外流冲击下细长圆柱结构涡激振动问题在工程中广泛存在,已有研究多关注圆柱沿横向和/或流向的振动响应,对涡激扭转振动研究较少。本文采用流-固耦合数值模拟研究了偏心扭转圆柱在层流中的涡激振动特性。首先,建立了偏心扭转圆柱涡... 横掠外流冲击下细长圆柱结构涡激振动问题在工程中广泛存在,已有研究多关注圆柱沿横向和/或流向的振动响应,对涡激扭转振动研究较少。本文采用流-固耦合数值模拟研究了偏心扭转圆柱在层流中的涡激振动特性。首先,建立了偏心扭转圆柱涡激振动力学模型,推导了控制方程和边界条件。然后,将基于特征线算子分裂的有限元解法、双时间步法、边弹簧近似法、广义-α方法和松耦合迭代解法相结合,针对层流诱发刚体扭转振动开发了一种通用流-固耦合解法,并采用基准算例进行了验证。最后,通过流-固耦合数值模拟,系统分析了偏心距、雷诺数、质量比对层流中偏心扭转圆柱涡激振动振幅、频率、流体载荷的影响规律及机理。 展开更多
关键词 圆柱 层流 涡激扭转振动 流-固耦合 数值模拟
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对流边界条件下超临界流体层流边界层相似解
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作者 李桢 杨瑞 +1 位作者 赵玉新 汪元 《推进技术》 北大核心 2025年第1期50-59,共10页
在超燃冲压发动机中,燃烧室和尾喷管内的高温燃气使再生冷却通道中的流体达到超临界状态,即在对流边界条件下形成超临界流体边界层,但其基本特性尚未明晰。为此,本文通过相似性解法计算了具有对流边界条件的超临界二氧化碳(SCO_(2))平... 在超燃冲压发动机中,燃烧室和尾喷管内的高温燃气使再生冷却通道中的流体达到超临界状态,即在对流边界条件下形成超临界流体边界层,但其基本特性尚未明晰。为此,本文通过相似性解法计算了具有对流边界条件的超临界二氧化碳(SCO_(2))平板层流边界层,来流压力为8 MPa。文中定义了热对流系数Mθ和局部对流换热常数c,它们分别与平板下表面热流体的温度及对流换热系数呈正相关,并分析了Mθ和c对边界层速度及温度剖面的影响。当c极小时,该问题可退化为绝热壁工况;相反,当c足够大时,它的表征类似于等温壁工况。随着Mθ和c的增大,壁面热流也增大;若来流温度为亚临界,此时边界层将出现跨临界机制,使壁面努塞尔数加剧降低。 展开更多
关键词 超临界流体 对流边界条件 层流边界层 相似解 壁面传热
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济阳坳陷古近系沙三下—沙四上亚段咸化湖盆证据及页岩油气地质意义 被引量:3
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作者 王勇 《中国石油大学学报(自然科学版)》 EI CAS CSCD 北大核心 2024年第3期27-36,共10页
济阳坳陷是渤海湾盆地常规油气最为富集的坳陷之一,也是页岩油获得全面战略性勘探突破的坳陷,古近系沙河街组发育沙三下亚段、沙四上亚段2套主力烃源岩,其沉积环境颇受争议。利用页岩系统取芯井岩石学、元素地球化学、同位素和包裹体等... 济阳坳陷是渤海湾盆地常规油气最为富集的坳陷之一,也是页岩油获得全面战略性勘探突破的坳陷,古近系沙河街组发育沙三下亚段、沙四上亚段2套主力烃源岩,其沉积环境颇受争议。利用页岩系统取芯井岩石学、元素地球化学、同位素和包裹体等资料对页岩沉积环境进行系统研究。结果表明:古近系沙三下—沙四上亚段页岩为气候控制下的咸化湖盆的产物,主要发育富碳酸盐纹层状岩相,碳酸盐矿物质量分数高,多呈纹层状、透镜状产出,平均质量分数为43%,背散射扫描电镜下部分页岩样品发现NaCl、BaSO_(4)和SrSO_(4)典型的咸化湖盆标志性矿物,页岩沉积期水体盐度相对较高;水体环境的w(Sr)/w(Ba)大于1,Sr元素质量分数大于500μg/g,B元素质量分数大于75×10^(-6),相当硼质量分数主要分布在300×10^(-6)~700×10^(-6),均显示为咸化环境;页岩w(^(87)Sr)/w(^(86)Sr)为0.710 7~0.712 4,明显高于同期海水的w(^(87)Sr)/w(^(86)Sr),结合对应稀土元素Ce正异常特征,认为沉积期水体条件受控于盆地自身环境,与海侵没有必然联系;碳酸盐矿物δ^(18)O主要分布在-11‰~-3‰,δ^(13)C主要分布在0~6‰,δ^(18)O、δ^(13)C均偏大,与沉积期湖盆气候相对干旱、湖水蒸发作用增强有关;页岩中检测到气液两相原生盐水包裹体均一化温度范围在32.5~45.3℃,对应盐度范围为19.21%~27.78%,成岩早期地层流体盐度较高;气候控制下的咸水环境为富碳酸盐页岩形成提供条件,奠定济阳坳陷古近系沙三下—沙四上亚段页岩油富集高产的基础。 展开更多
关键词 济阳坳陷 常规油气 页岩油 咸化湖盆 富碳酸盐纹层状岩相
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管内充分发展流动与传热数值模拟的教学方法探讨 被引量:1
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作者 毛宇飞 上官燕琴 肖洪 《力学与实践》 2024年第1期194-200,共7页
由于缺乏数值计算的基础理论知识,工科本科生在学习流体流动与传热过程的数值模拟方法并进行程序设计时,往往觉得难度较大。本文围绕圆管内不可压缩流体充分发展流动与传热,采用边界层积分法,推导出无量纲控制方程组;针对层流工况和湍... 由于缺乏数值计算的基础理论知识,工科本科生在学习流体流动与传热过程的数值模拟方法并进行程序设计时,往往觉得难度较大。本文围绕圆管内不可压缩流体充分发展流动与传热,采用边界层积分法,推导出无量纲控制方程组;针对层流工况和湍流工况,开发出相应的数值方法。基于该方法的程序代码易于理解,且计算结果表明该方法具有预测精度高、收敛速度快的优点。本文的工作可以为计算流体力学、数值传热学及热工计算等系列课程的本科教学提供参考。 展开更多
关键词 边界层积分 层流 湍流 传热 数值模拟
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Discovery of nano organo-clay complex pore-fractures in shale and its scientific significance:A case study of Cretaceous Qingshankou Formation shale,Songliao Basin,NE China 被引量:1
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作者 SUN Longde WANG Fenglan +5 位作者 BAI Xuefeng FENG Zihui SHAO Hongmei ZENG Huasen GAO Bo WANG Yongchao 《Petroleum Exploration and Development》 SCIE 2024年第4期813-825,共13页
A new pore type,nano-scale organo-clay complex pore-fracture was first discovered based on argon ion polishing-field emission scanning electron microscopy,energy dispersive spectroscopy and three-dimensional reconstru... A new pore type,nano-scale organo-clay complex pore-fracture was first discovered based on argon ion polishing-field emission scanning electron microscopy,energy dispersive spectroscopy and three-dimensional reconstruction by focused ion-scanning electron in combination with analysis of TOC,R_(o)values,X-ray diffraction etc.in the Cretaceous Qingshankou Formation shale in the Songliao Basin,NE China.Such pore characteristics and evolution study show that:(1)Organo-clay complex pore-fractures are developed in the shale matrix and in the form of spongy and reticular aggregates.Different from circular or oval organic pores discovered in other shales,a single organo-clay complex pore is square,rectangular,rhombic or slaty,with the pore diameter generally less than 200 nm.(2)With thermal maturity increasing,the elements(C,Si,Al,O,Mg,Fe,etc.)in organo-clay complex change accordingly,showing that organic matter shrinkage due to hydrocarbon generation and clay mineral transformation both affect organo-clay complex pore-fracture formation.(3)At high thermal maturity,the Qingshankou Formation shale is dominated by nano-scale organo-clay complex pore-fractures with the percentage reaching more than 70%of total pore space.The spatial connectivity of organo-clay complex pore-fractures is significantly better than that of organic pores.It is suggested that organo-complex pore-fractures are the main pore space of laminar shale at high thermal maturity and are the main oil and gas accumulation space in the core area of continental shale oil.The discovery of nano-scale organo-clay complex pore-fractures changes the conventional view that inorganic pores are the main reservoir space and has scientific significance for the study of shale oil formation and accumulation laws. 展开更多
关键词 Songliao Basin Cretaceous Qingshankou Formation laminar shale oil nanoscale organo-clay complex pore-fractures organo-clay complex diagenesis
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Thin polymer electrolyte with MXene functional layer for uniform Li^(+) deposition in all-solid-state lithium battery 被引量:1
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作者 Weijie Kou Yafang Zhang +3 位作者 Wenjia Wu Zibiao Guo Quanxian Hua Jingtao Wang 《Green Energy & Environment》 SCIE EI CAS CSCD 2024年第1期71-80,共10页
Solid polymer electrolyte(SPE) shows great potential for all-solid-state batteries because of the inherent safety and flexibility;however, the unfavourable Li+deposition and large thickness hamper its development and ... Solid polymer electrolyte(SPE) shows great potential for all-solid-state batteries because of the inherent safety and flexibility;however, the unfavourable Li+deposition and large thickness hamper its development and application. Herein, a laminar MXene functional layer-thin SPE layer-cathode integration(MXene-PEO-LFP) is designed and fabricated. The MXene functional layer formed by stacking rigid MXene nanosheets imparts higher compressive strength relative to PEO electrolyte layer. And the abundant negatively-charged groups on MXene functional layer effectively repel anions and attract cations to adjust the charge distribution behavior at electrolyte–anode interface. Furthermore,the functional layer with rich lithiophilic groups and outstanding electronic conductivity results in low Li nucleation overpotential and nucleation energy barrier. In consequence, the cell assembled with MXene-PEO-LFP, where the PEO electrolyte layer is only 12 μm, much thinner than most solid electrolytes, exhibits uniform, dendrite-free Li+deposition and excellent cycling stability. High capacity(142.8 mAh g-1), stable operation of 140 cycles(capacity decay per cycle, 0.065%), and low polarization potential(0.5 C) are obtained in this Li|MXene-PEO-LFP cell,which is superior to most PEO-based electrolytes under identical condition. This integrated design may provide a strategy for the large-scale application of thin polymer electrolytes in all-solid-state battery. 展开更多
关键词 MXene nanosheet laminar functional layer Thin polymer electrolyte Dendrite-free Liþdeposition All-solid-state lithium battery
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