The oxidation behavior of ferrovanadium spinel(FeV_(2)O_(4)),synthesized via high-temperature solid-state reaction,was investigated using thermogravimetry,X-ray diffractometry,and X-ray photoelectron spectroscopy over...The oxidation behavior of ferrovanadium spinel(FeV_(2)O_(4)),synthesized via high-temperature solid-state reaction,was investigated using thermogravimetry,X-ray diffractometry,and X-ray photoelectron spectroscopy over the temperature range of 450–700℃.The results revealed that the oxidation process of FeV_(2)O_(4)can be divided into three stages with the second stage being responsible for maximum weight gain due to oxidation.Three classical methods were employed to analyze the reaction mechanisms and model functions for distinct oxidation stages.The random nucleation and subsequent growth(A_(3))kinetic model was found to be applicable to both initial and secondary stage.The third stage of oxidation was consistent with the three-dimensional diffusion,spherical symmetry(D_(3))kinetic mode.Both the model-function method and the model-free method were utilized to investigate the apparent activation energy of the oxidation reaction at each stage.It was found that the intermediates including Fe_(3)O_(4),VO_(2),V_(2)O_(3),and Fe_(2.5)V_(7.11)O_(16),played significant roles in the oxidation process prior to the final formation of FeVO_(4)and V_(2)O_(5)through oxidation of FeV_(2)O_(4).展开更多
The kintic and activation energy of mass loss of two grades of melted TNT explosive, grade A and grade B, with freezing points of 80.57 and 78.15 ℃, respectively, were studied by isothermal and nonisothermal gravimet...The kintic and activation energy of mass loss of two grades of melted TNT explosive, grade A and grade B, with freezing points of 80.57 and 78.15 ℃, respectively, were studied by isothermal and nonisothermal gravimetric methods. In isothermal method, the mass loss of samples in containers of glass and aluminum was followed in temperatures of 80, 90 and 100 ℃. The kinetic of the mass loss of the samples in the aluminum container was higher than the kinetic of it in the glass container that can be related to the effects of heat transfer and catalytic of aluminm metal. Also, the presence of impurities in grade B was due to increasing of kinetic of mass loss of it versus grade A. The non-isothermal curves were obtained in range of 30-330 ℃ at heating rates of 10,15 and 20 ℃·min^(-1).The TG/DTG data were used for determination of activation energy(E_a) of mass loss of TNT samples upon degradation by using Ozawa, Kissinger, Ozawa-Flynn-Wall(OFW) and Kissinger-Akahira-Sunose(KAS) methods as model free methods. The activation energies of grades of A and B of TNT was obtained 99-120 and 66-70 kJ mol^(-1)respectively. The lower values of activation energy of the degradation reaction of grade B confirm the effect of impurities in the kinetics of mass loss of this grade.展开更多
The microstructure and Gd-rich phase evolution of as-cast AZ31-xGd(x=0,1.5 wt.%,2.0 wt.%and 2.5 wt.%)magnesium alloys during semi-solid isothermal heat treatment were investigated deeply in the present work.Results sh...The microstructure and Gd-rich phase evolution of as-cast AZ31-xGd(x=0,1.5 wt.%,2.0 wt.%and 2.5 wt.%)magnesium alloys during semi-solid isothermal heat treatment were investigated deeply in the present work.Results showed that the lamellar(Mg,Al)3Gd phases transformed into the particle-like Al2Gd phases in AZ31 magnesium alloys with Gd addition during semi-solid isothermal heat treatment,leading to yielding more sphericalα-Mg grains.When Gd content is 2.0 wt.%,the size of semi-solid spherical grains reaches the minimum.The main mechanism of grain refinement lies in the remelting of dendritic branches as well as the auxiliary effect of a small number of Al2Gd particles as grain refining inoculants.Meanwhile,Al2Gd particles enriched at the solid-liquid interfaces can remarkably retard the growth rate ofα-Mg grains.A reduction of deformation resistance has been successfully achieved in AZ31-2.0Gd magnesium alloy after semi-solid isothermal heat treatment,which shows a moderate compressive deformation resistance(230 MPa),comparing to the as-cast AZ31 magnesium alloy(280 MPa)and semi-solid AZ31 magnesium alloy(209 MPa).展开更多
The ablation properties of C/C composites with four different needled preforms prepared by isothermal chemical vapor infiltration （ICVI）, which are super-thin mat lay-up, 0°/90° weftless fabric lay-up, 0&#...The ablation properties of C/C composites with four different needled preforms prepared by isothermal chemical vapor infiltration （ICVI）, which are super-thin mat lay-up, 0°/90° weftless fabric lay-up, 0°/45° weftless fabric lay-up and 0°/45° twill fabric lay-up, were quantitatively evaluated by performing the ablation tests with an engine torch. And their ablation discrepancies were analyzed according to the surface characteristic, porosity and thermal diffusivity. The results show that the 0°/45° weftless composite has a fiat eroded surface with no obvious macroscopic pits. Its thickness and mass erosion rates are decreased by about 46.8% and 34.8%, 25.0% and 27.5%, and 17.5% and 19.4% compared with those of the mat, the 0°/90° weftless and the 0°/45° twill composites, respectively. The ablation properties are mainly controlled by the thermo-chemical effect （oxidation）, and a little by the thermo-mechanical effect （mechanical denudation）. The needling fiber bundles play an important role in accelerating the ablation process and resulting in the heterogeneous ablation.展开更多
Large complex 7A85 aluminum wing-body joint was forged employing isothermal forging process and its mechanical properties were studied.The tensile strength after forging is up to 587.5 MPa in longitudinal direction,15...Large complex 7A85 aluminum wing-body joint was forged employing isothermal forging process and its mechanical properties were studied.The tensile strength after forging is up to 587.5 MPa in longitudinal direction,15% higher than that using free forging.Moreover,the tensile strength of the forging is almost the same in three directions.Isothermal forging also performs well on overall fracture toughness,with a maximum value of 39.8 MPa·m1/2,and that of short transverse direction all reaches 36 MPa·m1/2 and above,with a maximum relative error of only 3.6%.The results indicate that the isothermal forging leads to better performance as well as higher uniformity in mechanical properties.展开更多
After a standard heat treatment,the microstructural evolution with time during isothermal aging at 850°C and its effect on the creep rupture properties of the Ni-base superalloy M4706 at 870°C and 370 MPa ar...After a standard heat treatment,the microstructural evolution with time during isothermal aging at 850°C and its effect on the creep rupture properties of the Ni-base superalloy M4706 at 870°C and 370 MPa are investigated.It is found that as the aging time increases from 0 to 5000 h,the average diameter of coarseγ′increases from 241 to 484 nm,and the distribution of the carbides at grain boundaries changes from discontinuous to continuous.Moreover,experimental observations on the microstructures of all the crept specimens reveal that dislocation bypassing controls the creep deformation.Thus,it is concluded that the transitions in the microstructures result in the degeneration of the creep rupture properties of the experimental alloy with aging time.展开更多
Carbon-carbon composite （C/C） materials are prone to severe oxidation and volatilization problems. To address these issues, mullite （3Al2O3.2SiO2）/silicon carbide （SIC） coatings were deposited on C/C composite s...Carbon-carbon composite （C/C） materials are prone to severe oxidation and volatilization problems. To address these issues, mullite （3Al2O3.2SiO2）/silicon carbide （SIC） coatings were deposited on C/C composite substrates characterized into high and low densities. The coatings were applied by a two-step approach： pack cementation and silica sol based slurry coating processes. The relationship between the microstructure of 3Al2O3·2SiO2/SiC coatings and C/C substrates during isothermal oxidation cycle at 1 500 ℃ was investigated using X-ray diffractometer （XRD） and scanning electron microscope （SEM） mounted with energy dispersive spectrometer （EDS）. The results indicate that the density of the substrates has a marked effect on the coatings. Dense, thick and well-bonded coatings are obtained in the high density substrate. After 106 h of isothermal oxidation, the high density substrate with 3Al2O3-2SiO2/SiC coating offers effective protection as compared to low density substrate suffering recession.展开更多
Martensitic transformation behavior was studied for zirconia containing 4%～10% CeO2 (in mole fraction) by using a dilatometric method. The Ms (Martensite start temperature) decreased near linearly with increasing CeO...Martensitic transformation behavior was studied for zirconia containing 4%～10% CeO2 (in mole fraction) by using a dilatometric method. The Ms (Martensite start temperature) decreased near linearly with increasing CeO2. Different transformation modes were observed depending on the composition and cooling rate. ZrO2 containing 6% CeO2 showed isothermal transformation behavior, whereas ZrO2 containing 9% and 10% CeO2 showed athermal transformation behavior. However, ZrO2 containing 8% CeO2 showed either isothermal or athermal transformations behavior depending on the cooling rate. A TTT (Time-Temperature-Transformation) diagram was proposed for ZrO2 containing 8% CeO2.展开更多
The fracture behaviour and morphologies of high-strength boron steel were investigated at different temperatures at a constant strain rate of 0.1 s-1 based on isothermal tensile tests. Fracture mechanisms were also an...The fracture behaviour and morphologies of high-strength boron steel were investigated at different temperatures at a constant strain rate of 0.1 s-1 based on isothermal tensile tests. Fracture mechanisms were also analyzed based on the relationship between microstructure transformation and continuous cooling transformation(CCT) curves. It is found that 1) fractures of the investigated steel at high temperatures are dimple fractures; 2) the deformation of high-strength boron steel at high temperatures accelerates diffusion transformations; thus, to obtain full martensite, a higher cooling rate is needed; and 3) the investigated steel has the best plasticity when the deformation temperature is 750 °C.展开更多
When the loop-mediated isothermal amplification(LAMP)assay is used for detecting target genes,DNA extraction is unnecessary in many cases.Simple pretreatment(e.g.heating)is enough to obtain rather sensitive responses....When the loop-mediated isothermal amplification(LAMP)assay is used for detecting target genes,DNA extraction is unnecessary in many cases.Simple pretreatment(e.g.heating)is enough to obtain rather sensitive responses.Even test samples without any pretreatment can be used as template.This feature suggests that LAMP is superior to PCR in developing point-of-care test strategies.In this study,using Stx1 gene from E.coli as model,we verified that viable cells,dead cells and extracellular DNA could function as template in the LAMP assay.In the incubation at 63℃,viable bacteria in the LAMP reaction mixture lysed completely within 2 min,providing DNA template for nucleic acid amplification.The Stx1 gene in diluted culture medium,spiked tap water,spiked seawater and real seawater all could be detected,with or without the step of DNA extraction.We found that the complex substances in real sample(e.g.natural seawater)exhibited considerable inhibitory effect on the sensitivity of the LAMP assay.These outcomes are meaningful for building a point-of-care strategy by employing the LAMP assay for environmental monitoring,bio-resource surveys,food safety,etc.in particular those based on environmental DNA.展开更多
The isothermal section of Ag-Ti-Zr ternary system at 1023 K was determined by diffusion triple and electron probe microanalysis. The results indicate that four binary intermetallic phases of AgTi, AgTi2, AgZr and AgZr...The isothermal section of Ag-Ti-Zr ternary system at 1023 K was determined by diffusion triple and electron probe microanalysis. The results indicate that four binary intermetallic phases of AgTi, AgTi2, AgZr and AgZr2 are found in Ag-Ti-Zr ternary system at 1 023 K. AgZr2 and AgTi2 form a continuous solid solution, namely Ag(Ti,Zr)2. Four three-phase regions: AgTi +AgZr + Ag, AgTi +AgZr + Ag (Ti, Zr)2, α-Zr +β(Ti, Zr) + Ag (Ti, Zr) 2 and α-Ti +β(Ti, Zr) + Ag (Ti, Zr)2 exist in the isothermal section. No ternary compound is observed.展开更多
The phase equilibriua in the Ni Re Hf ternary system at 1173K were investigated by means of diffusion triple technique and electron microprobe analysis(EMPA). The experimental results indicate that two ternary interme...The phase equilibriua in the Ni Re Hf ternary system at 1173K were investigated by means of diffusion triple technique and electron microprobe analysis(EMPA). The experimental results indicate that two ternary intermetallics (α and β) and five binary intermetallics (Ni 3Hf, Ni 10 Hf 7, Ni 11 Hf 9, NiHf and NiHf 2) exist in the Ni Re Hf system at 1?173 K. A tentative isothermal section of this system at 1?173 K was constructed on the basis of experimental results. The isothermal section consists of nine three phase regions, five of which are supported by the experimental data.展开更多
Rice bacterial leaf brown spot disease caused by Pseudomonas syringae pv.syringae(Pss)is a major disease on rice.In recent years,Pss has emerged worldwide,seriously affecting rice production.It is very important to es...Rice bacterial leaf brown spot disease caused by Pseudomonas syringae pv.syringae(Pss)is a major disease on rice.In recent years,Pss has emerged worldwide,seriously affecting rice production.It is very important to establish a rapid detection method of Pss for the diagnosis and prevention of this disease.In order to robust and accurately diagnose the rice bacterial leaf brown spot disease in the field and laboratory,an assay system for the Pss was developed in this study,and the specific sequence of hrcN was used as the target,based on loop-mediated isothermal amplification(LAMP).The best detection system was MgSO 48 mmol·L^(-1),Bst DNA polymerase 8 U,dNTP 1.4 mmol·L^(-1),the ratio of internal and outer primers was 2:1,the reaction temperature was 63℃,the reaction time was 45 min,and the lowest sensitivity was 104 CFU·mL^(-1).This results provided an accurate and robust method for laboratory and field diagnosis of bacterial leaf brown spot disease of rice.展开更多
Cold-rolling was conducted on AZ31 magnesium alloy with fine and coarse grains to produce plates with high density of shear bands and{101^(-)1}twins,respectively.Then,these two kinds of plates are subjected to isother...Cold-rolling was conducted on AZ31 magnesium alloy with fine and coarse grains to produce plates with high density of shear bands and{101^(-)1}twins,respectively.Then,these two kinds of plates are subjected to isothermal annealing to reveal the effect of shear bands and{101^(-)1}twins on recrystallization behavior.During annealing,static recrystallization occurs firstly in shear band zones and{101^(-)1}twin zones,which has different effect on texture and mechanical properties.With the increase of annealing temperature,strong basal texture remains in annealed SG-17%while the basal texture is weakened gradually in annealed LG-15%.Recrystallized grains from twin zones have a random orientation which is responsible for the weakened basal texture in annealed LG-15%.In addition,microhardness decreases gradually with the prolonged annealing time due to static recrystallization.LG-15%has a lower recrystallization activation energy because{101^(-)1}twins are in favor of the nucleation and growth of recrystallized grains.After 500℃annealing,the yield strength decreases significantly with a significant improvement in failure strain.The annealed LG-15%has a much higher compressive strain than the annealed SG-17%due to texture weakening effect.展开更多
In order to analyze the influences of storage aging on the safety of typical elemental explosives,the aged cyclotrimethylene trinitramine(RDX)and cyclotetramethylene tetranitramine(HMX)were prepared by isothermal agin...In order to analyze the influences of storage aging on the safety of typical elemental explosives,the aged cyclotrimethylene trinitramine(RDX)and cyclotetramethylene tetranitramine(HMX)were prepared by isothermal aging tests.The reaction thresholds of aged RDX and HMX under any ignition probability were studied by Langlie-Optimal D method.The thermal decomposition characteristics of RDX and HMX after aging were analyzed by DSC and ARC.Experimental results showed that compared with unaged RDX and HMX,on the one hand,the critical impact energy and critical friction of RDX and HMX aged for 14,28,and 56 days are significantly reduced at an explosion probability of 50%,0.01%,and 0.0001%,respectively.With the increase of aging time,the mechanical sensitivity of RDX and HMX increases obviously.On the other hand,the initial decomposition temperature of RDX and HMX after 56 days of aging decreases,the decomposition heat decreases,the activation energy increases,and the reaction difficulty increases.展开更多
Roasting bastnaesite concentrates is a crucial process in extracting rare earths.This study explored an efficient suspension roasting technology and investigated the bastnaesite pyrolysis and cerium(Ce)oxidation.Relev...Roasting bastnaesite concentrates is a crucial process in extracting rare earths.This study explored an efficient suspension roasting technology and investigated the bastnaesite pyrolysis and cerium(Ce)oxidation.Relevant analytical tests were applied to evaluate the phase and surface property variations of bastnaesite,and isothermal kinetic analysis of bastnaesite pyrolysis and Ce oxidation was performed.The results revealed that bastnaesite decomposed rapidly and accompanied by Ce oxidation,and the gas-solid products were identified as CO_(2),Ce_(7)O_(12),La_(2)O_(3),CeF_(3) and LaF_(3),with Ce oxidation restricted by bastnaesite pyrolysis.As roasting time prolonged,cracks and pores appeared on bastnaesite surface;the BET specific surface and pore diameter increased.In later roasting period,the pore diameter continued to increase but the specific surface decreased,assigned to particle fusion agglomeration and pore consolidation.Additionally,the surface C content reduced and Ce(Ⅳ)content increased gradually as roasting progressed.The reaction kinetics all followed Avrami-Erofeev equations,the reaction orders of bastnaesite pyrolysis and Ce oxidation decreased with decreasing reaction temperature.The calculated activation energies at lower temperatures were higher than those calculated at higher temperatures.This study analyzed the bastnaesite reaction mechanism to supply a reference for the application of suspension roasting technology in bastnaesite smelting.展开更多
Constitutive model plays an important role in the numerical simulations of metal forming. However, th~ influence of the models on the calculation is vague. Based on the stress-strain data of A1 7050 and Ti-6A1-4V allo...Constitutive model plays an important role in the numerical simulations of metal forming. However, th~ influence of the models on the calculation is vague. Based on the stress-strain data of A1 7050 and Ti-6A1-4V alloy generated by isothermal compressive tests, the Johnson-Cook （JC） and Arrhenius-type （A-type） hyperbolic sine model were fitted to obtain the constants. Flow stresses directly calculated by the equations were compared with th~ experiment results, and rigid-plastic finite element analyses （FEA） utilizing these models were employed to simulate th~ same compression processes. The results show that A-type model has higher accuracy in the direct prediction of roy stress, even outside of the fit domain. The simulation results using A-type model also have higher agreement with th~ experiment; however, the suitability is affected by the referential parameters employed in the regression process, h terms of the overall deformation and strain distributions, there are slight differences among the simulation results usint these two models.展开更多
Based on heat and mass transfer characteristics of spontaneous combustion of coal,Arrhenius equation and the Ranz-Marshall correlation,a novel approach was proposed in this paper to estimate oxygen consumption rate of...Based on heat and mass transfer characteristics of spontaneous combustion of coal,Arrhenius equation and the Ranz-Marshall correlation,a novel approach was proposed in this paper to estimate oxygen consumption rate of self-ignition of coal at high temperature.Compared with the conventional methods,this approach involves not only kinetic properties of self-ignition of coal and temperature,but also the ambient air flow characteristics and diameter of coal particle.To testify the proposed approach,oxygen consumption rates at high temperature were measured by the programmable isothermal oven experiments.Comparisons between experimental and theoretical results indicate that the rates of oxygen depletion calculated by the proposed approach agree well with those measured from laboratory-scale experiments,which further validates the proposed approach.展开更多
The experimental observations about remarkable influence of the substrates on the isothermal crystallization rate of a high density polyethylene(HDPE) were presented.Two methods were used to characterize the crystalli...The experimental observations about remarkable influence of the substrates on the isothermal crystallization rate of a high density polyethylene(HDPE) were presented.Two methods were used to characterize the crystallization rate:the change of turbidity of the HDPE specimen and the changes of the complex viscosity and storage modulus measured by a rotational rheometer,which gave consistent results showing that the isothermal crystallization rate decreased in sequence as the specimen contacted with aluminum,brass and stainless steel plates,respectively.As to the dominant influence factor,the chemical composition of the substrates can be excluded via insulating the plate by an aluminum foil.Instead,we propose the plate's ability of removing the latent heat of crystallization from the specimen.Rheological measurement is sensitive to the crystallization process.The colloid like model proposed by BOUTAHAR et al for the crystallization of HDPE gives reasonable predictions of the crystallized fraction from the measured storage modulus.展开更多
In order to study the effect of Zr on the microstructure and isothermal annealing performance of Cu–Cr in situ composites, Cu–15 Cr and Cu–15 Cr–0.24 Zr alloys were prepared by means of vacuum medium frequency ind...In order to study the effect of Zr on the microstructure and isothermal annealing performance of Cu–Cr in situ composites, Cu–15 Cr and Cu–15 Cr–0.24 Zr alloys were prepared by means of vacuum medium frequency induction melting technology. The two kinds of test alloys with deformation of 3.79 were subjected to isothermal annealing test. The effects of Zr on the as-cast microstructure, the isothermal annealing structure and the tensile fracture morphology of Cu–15 Cr alloy were studied by means of scanning electron microscopy(SEM), energy dispersive spectroscopy(EDS) and transmission electron microscopy(TEM). The results show that the addition of Zr leads to the formation of homogeneous and fine Cu Zr intermetallic compounds, which suppresses the formation electron microscopy of eutectic Cr phase and makes the eutectic Cr content much lower than that of Cu–15 Cr alloy. The recrystallization temperature of the Cu matrix is increased, and it is maintained at a fine equiaxed crystal at 400 °C. After isothermal annealing at 400 °C for 220 h, the tensile strength, electrical conductivity and elongation of the test alloy containing Zr were 720 MPa, 68% IACS and 6.7%, respectively; while the tensile strength, electrical conductivity and elongation of the test alloys without Zr were 488 MPa, 70% IACS and 12.4%, respectively.展开更多
基金Project(cstb2022nscq-msx0801)supported by the Natural Science Foundation of Chongqing,ChinaProject(52004044)supported by the National Natural Science Foundation of China+2 种基金Project(ckrc2022030)supported by the Foundation of Chongqing University of Science and Technology,ChinaProject(YKJCX2220216)supported by the Graduate Research Innovation Project of Chongqing University of Science and Technology,ChinaProject(202311551007)supported by the National Undergraduate Training Program for Innovation and Entrepreneurship,China。
文摘The oxidation behavior of ferrovanadium spinel(FeV_(2)O_(4)),synthesized via high-temperature solid-state reaction,was investigated using thermogravimetry,X-ray diffractometry,and X-ray photoelectron spectroscopy over the temperature range of 450–700℃.The results revealed that the oxidation process of FeV_(2)O_(4)can be divided into three stages with the second stage being responsible for maximum weight gain due to oxidation.Three classical methods were employed to analyze the reaction mechanisms and model functions for distinct oxidation stages.The random nucleation and subsequent growth(A_(3))kinetic model was found to be applicable to both initial and secondary stage.The third stage of oxidation was consistent with the three-dimensional diffusion,spherical symmetry(D_(3))kinetic mode.Both the model-function method and the model-free method were utilized to investigate the apparent activation energy of the oxidation reaction at each stage.It was found that the intermediates including Fe_(3)O_(4),VO_(2),V_(2)O_(3),and Fe_(2.5)V_(7.11)O_(16),played significant roles in the oxidation process prior to the final formation of FeVO_(4)and V_(2)O_(5)through oxidation of FeV_(2)O_(4).
基金the research committee of Malek-ashtar University of Technology(MUT)
文摘The kintic and activation energy of mass loss of two grades of melted TNT explosive, grade A and grade B, with freezing points of 80.57 and 78.15 ℃, respectively, were studied by isothermal and nonisothermal gravimetric methods. In isothermal method, the mass loss of samples in containers of glass and aluminum was followed in temperatures of 80, 90 and 100 ℃. The kinetic of the mass loss of the samples in the aluminum container was higher than the kinetic of it in the glass container that can be related to the effects of heat transfer and catalytic of aluminm metal. Also, the presence of impurities in grade B was due to increasing of kinetic of mass loss of it versus grade A. The non-isothermal curves were obtained in range of 30-330 ℃ at heating rates of 10,15 and 20 ℃·min^(-1).The TG/DTG data were used for determination of activation energy(E_a) of mass loss of TNT samples upon degradation by using Ozawa, Kissinger, Ozawa-Flynn-Wall(OFW) and Kissinger-Akahira-Sunose(KAS) methods as model free methods. The activation energies of grades of A and B of TNT was obtained 99-120 and 66-70 kJ mol^(-1)respectively. The lower values of activation energy of the degradation reaction of grade B confirm the effect of impurities in the kinetics of mass loss of this grade.
基金Project(20171BAB206005)supported by the Natural Science Foundation of Jiangxi Province,ChinaProject(20153BCB23023)supported by the Training Program Foundation for Young Scientists of Jiangxi Province,ChinaProject(51961026)supported by the National Natural Science Foundation of China。
文摘The microstructure and Gd-rich phase evolution of as-cast AZ31-xGd(x=0,1.5 wt.%,2.0 wt.%and 2.5 wt.%)magnesium alloys during semi-solid isothermal heat treatment were investigated deeply in the present work.Results showed that the lamellar(Mg,Al)3Gd phases transformed into the particle-like Al2Gd phases in AZ31 magnesium alloys with Gd addition during semi-solid isothermal heat treatment,leading to yielding more sphericalα-Mg grains.When Gd content is 2.0 wt.%,the size of semi-solid spherical grains reaches the minimum.The main mechanism of grain refinement lies in the remelting of dendritic branches as well as the auxiliary effect of a small number of Al2Gd particles as grain refining inoculants.Meanwhile,Al2Gd particles enriched at the solid-liquid interfaces can remarkably retard the growth rate ofα-Mg grains.A reduction of deformation resistance has been successfully achieved in AZ31-2.0Gd magnesium alloy after semi-solid isothermal heat treatment,which shows a moderate compressive deformation resistance(230 MPa),comparing to the as-cast AZ31 magnesium alloy(280 MPa)and semi-solid AZ31 magnesium alloy(209 MPa).
基金Project(200202AA305207) supported by the National High Technology Research and Development Program of China
文摘The ablation properties of C/C composites with four different needled preforms prepared by isothermal chemical vapor infiltration （ICVI）, which are super-thin mat lay-up, 0°/90° weftless fabric lay-up, 0°/45° weftless fabric lay-up and 0°/45° twill fabric lay-up, were quantitatively evaluated by performing the ablation tests with an engine torch. And their ablation discrepancies were analyzed according to the surface characteristic, porosity and thermal diffusivity. The results show that the 0°/45° weftless composite has a fiat eroded surface with no obvious macroscopic pits. Its thickness and mass erosion rates are decreased by about 46.8% and 34.8%, 25.0% and 27.5%, and 17.5% and 19.4% compared with those of the mat, the 0°/90° weftless and the 0°/45° twill composites, respectively. The ablation properties are mainly controlled by the thermo-chemical effect （oxidation）, and a little by the thermo-mechanical effect （mechanical denudation）. The needling fiber bundles play an important role in accelerating the ablation process and resulting in the heterogeneous ablation.
基金Project(2010CB731701) supported by the National Basic Research Program of ChinaProject(2012ZX04010-081) supported by National Science and Technology Major Program of China
文摘Large complex 7A85 aluminum wing-body joint was forged employing isothermal forging process and its mechanical properties were studied.The tensile strength after forging is up to 587.5 MPa in longitudinal direction,15% higher than that using free forging.Moreover,the tensile strength of the forging is almost the same in three directions.Isothermal forging also performs well on overall fracture toughness,with a maximum value of 39.8 MPa·m1/2,and that of short transverse direction all reaches 36 MPa·m1/2 and above,with a maximum relative error of only 3.6%.The results indicate that the isothermal forging leads to better performance as well as higher uniformity in mechanical properties.
基金Project(2018BSHQYXMZZ32)supported by the Postdoctoral Science Foundation of Shaanxi Province of ChinaProject(20192109)supported by the State Key Laboratory for Mechanical Behavior of Materials,ChinaProjects(2017M623213,2018M633487)supported by the Postdoctoral Science Foundation of China
文摘After a standard heat treatment,the microstructural evolution with time during isothermal aging at 850°C and its effect on the creep rupture properties of the Ni-base superalloy M4706 at 870°C and 370 MPa are investigated.It is found that as the aging time increases from 0 to 5000 h,the average diameter of coarseγ′increases from 241 to 484 nm,and the distribution of the carbides at grain boundaries changes from discontinuous to continuous.Moreover,experimental observations on the microstructures of all the crept specimens reveal that dislocation bypassing controls the creep deformation.Thus,it is concluded that the transitions in the microstructures result in the degeneration of the creep rupture properties of the experimental alloy with aging time.
基金Project(2011CB605805) supported by the National Basic Research Program of ChinaProject(51021063) supported by the Creative Research Group of National Natural Science Foundation of China
文摘Carbon-carbon composite （C/C） materials are prone to severe oxidation and volatilization problems. To address these issues, mullite （3Al2O3.2SiO2）/silicon carbide （SIC） coatings were deposited on C/C composite substrates characterized into high and low densities. The coatings were applied by a two-step approach： pack cementation and silica sol based slurry coating processes. The relationship between the microstructure of 3Al2O3·2SiO2/SiC coatings and C/C substrates during isothermal oxidation cycle at 1 500 ℃ was investigated using X-ray diffractometer （XRD） and scanning electron microscope （SEM） mounted with energy dispersive spectrometer （EDS）. The results indicate that the density of the substrates has a marked effect on the coatings. Dense, thick and well-bonded coatings are obtained in the high density substrate. After 106 h of isothermal oxidation, the high density substrate with 3Al2O3-2SiO2/SiC coating offers effective protection as compared to low density substrate suffering recession.
文摘Martensitic transformation behavior was studied for zirconia containing 4%～10% CeO2 (in mole fraction) by using a dilatometric method. The Ms (Martensite start temperature) decreased near linearly with increasing CeO2. Different transformation modes were observed depending on the composition and cooling rate. ZrO2 containing 6% CeO2 showed isothermal transformation behavior, whereas ZrO2 containing 9% and 10% CeO2 showed athermal transformation behavior. However, ZrO2 containing 8% CeO2 showed either isothermal or athermal transformations behavior depending on the cooling rate. A TTT (Time-Temperature-Transformation) diagram was proposed for ZrO2 containing 8% CeO2.
基金Project(51305317)supported by the National Natural Science Foundation of ChinaProjects(WUT:2013-IV-092,WUT:2014-VII-002)supported by the Fundamental Research Funds for the Central Universities,ChinaProject(IRT13087)supported by Innovative Research Team Development Program of Ministry of Education of China
文摘The fracture behaviour and morphologies of high-strength boron steel were investigated at different temperatures at a constant strain rate of 0.1 s-1 based on isothermal tensile tests. Fracture mechanisms were also analyzed based on the relationship between microstructure transformation and continuous cooling transformation(CCT) curves. It is found that 1) fractures of the investigated steel at high temperatures are dimple fractures; 2) the deformation of high-strength boron steel at high temperatures accelerates diffusion transformations; thus, to obtain full martensite, a higher cooling rate is needed; and 3) the investigated steel has the best plasticity when the deformation temperature is 750 °C.
文摘When the loop-mediated isothermal amplification(LAMP)assay is used for detecting target genes,DNA extraction is unnecessary in many cases.Simple pretreatment(e.g.heating)is enough to obtain rather sensitive responses.Even test samples without any pretreatment can be used as template.This feature suggests that LAMP is superior to PCR in developing point-of-care test strategies.In this study,using Stx1 gene from E.coli as model,we verified that viable cells,dead cells and extracellular DNA could function as template in the LAMP assay.In the incubation at 63℃,viable bacteria in the LAMP reaction mixture lysed completely within 2 min,providing DNA template for nucleic acid amplification.The Stx1 gene in diluted culture medium,spiked tap water,spiked seawater and real seawater all could be detected,with or without the step of DNA extraction.We found that the complex substances in real sample(e.g.natural seawater)exhibited considerable inhibitory effect on the sensitivity of the LAMP assay.These outcomes are meaningful for building a point-of-care strategy by employing the LAMP assay for environmental monitoring,bio-resource surveys,food safety,etc.in particular those based on environmental DNA.
基金Projects(50371104 50401011) supported by the National Natural Science Foundation of China
文摘The isothermal section of Ag-Ti-Zr ternary system at 1023 K was determined by diffusion triple and electron probe microanalysis. The results indicate that four binary intermetallic phases of AgTi, AgTi2, AgZr and AgZr2 are found in Ag-Ti-Zr ternary system at 1 023 K. AgZr2 and AgTi2 form a continuous solid solution, namely Ag(Ti,Zr)2. Four three-phase regions: AgTi +AgZr + Ag, AgTi +AgZr + Ag (Ti, Zr)2, α-Zr +β(Ti, Zr) + Ag (Ti, Zr) 2 and α-Ti +β(Ti, Zr) + Ag (Ti, Zr)2 exist in the isothermal section. No ternary compound is observed.
文摘The phase equilibriua in the Ni Re Hf ternary system at 1173K were investigated by means of diffusion triple technique and electron microprobe analysis(EMPA). The experimental results indicate that two ternary intermetallics (α and β) and five binary intermetallics (Ni 3Hf, Ni 10 Hf 7, Ni 11 Hf 9, NiHf and NiHf 2) exist in the Ni Re Hf system at 1?173 K. A tentative isothermal section of this system at 1?173 K was constructed on the basis of experimental results. The isothermal section consists of nine three phase regions, five of which are supported by the experimental data.
基金Supported by the Natural Science Foundation of Heilongjiang Province(Topic C2017032)Heilongjiang Province Applied Technology Research and Development Program(Topic GA19B104)the National Key Research and Development Program(Topic 2018YFD0300105)。
文摘Rice bacterial leaf brown spot disease caused by Pseudomonas syringae pv.syringae(Pss)is a major disease on rice.In recent years,Pss has emerged worldwide,seriously affecting rice production.It is very important to establish a rapid detection method of Pss for the diagnosis and prevention of this disease.In order to robust and accurately diagnose the rice bacterial leaf brown spot disease in the field and laboratory,an assay system for the Pss was developed in this study,and the specific sequence of hrcN was used as the target,based on loop-mediated isothermal amplification(LAMP).The best detection system was MgSO 48 mmol·L^(-1),Bst DNA polymerase 8 U,dNTP 1.4 mmol·L^(-1),the ratio of internal and outer primers was 2:1,the reaction temperature was 63℃,the reaction time was 45 min,and the lowest sensitivity was 104 CFU·mL^(-1).This results provided an accurate and robust method for laboratory and field diagnosis of bacterial leaf brown spot disease of rice.
基金Project(52405369) supported by National Natural Science Foundation of ChinaProject(BK20210891) supported by the Natural Science Foundation of Jiangsu Province,ChinaProject(BX2022030) supported by the Special Project of Introducing Foreign Talents of Jiangsu Province,China。
文摘Cold-rolling was conducted on AZ31 magnesium alloy with fine and coarse grains to produce plates with high density of shear bands and{101^(-)1}twins,respectively.Then,these two kinds of plates are subjected to isothermal annealing to reveal the effect of shear bands and{101^(-)1}twins on recrystallization behavior.During annealing,static recrystallization occurs firstly in shear band zones and{101^(-)1}twin zones,which has different effect on texture and mechanical properties.With the increase of annealing temperature,strong basal texture remains in annealed SG-17%while the basal texture is weakened gradually in annealed LG-15%.Recrystallized grains from twin zones have a random orientation which is responsible for the weakened basal texture in annealed LG-15%.In addition,microhardness decreases gradually with the prolonged annealing time due to static recrystallization.LG-15%has a lower recrystallization activation energy because{101^(-)1}twins are in favor of the nucleation and growth of recrystallized grains.After 500℃annealing,the yield strength decreases significantly with a significant improvement in failure strain.The annealed LG-15%has a much higher compressive strain than the annealed SG-17%due to texture weakening effect.
基金supported by the National Key Laboratory of Energetic Materials, China (Grant No. 2023-LB-036-09).
文摘In order to analyze the influences of storage aging on the safety of typical elemental explosives,the aged cyclotrimethylene trinitramine(RDX)and cyclotetramethylene tetranitramine(HMX)were prepared by isothermal aging tests.The reaction thresholds of aged RDX and HMX under any ignition probability were studied by Langlie-Optimal D method.The thermal decomposition characteristics of RDX and HMX after aging were analyzed by DSC and ARC.Experimental results showed that compared with unaged RDX and HMX,on the one hand,the critical impact energy and critical friction of RDX and HMX aged for 14,28,and 56 days are significantly reduced at an explosion probability of 50%,0.01%,and 0.0001%,respectively.With the increase of aging time,the mechanical sensitivity of RDX and HMX increases obviously.On the other hand,the initial decomposition temperature of RDX and HMX after 56 days of aging decreases,the decomposition heat decreases,the activation energy increases,and the reaction difficulty increases.
基金Projects(2022YFC2905800,2021YFC2901000)supported by the National Key R&D Program of ChinaProject(52174242)supported by the National Science and Technology of ChinaProject(52130406)supported by the National Science and Technology Major Project of China。
文摘Roasting bastnaesite concentrates is a crucial process in extracting rare earths.This study explored an efficient suspension roasting technology and investigated the bastnaesite pyrolysis and cerium(Ce)oxidation.Relevant analytical tests were applied to evaluate the phase and surface property variations of bastnaesite,and isothermal kinetic analysis of bastnaesite pyrolysis and Ce oxidation was performed.The results revealed that bastnaesite decomposed rapidly and accompanied by Ce oxidation,and the gas-solid products were identified as CO_(2),Ce_(7)O_(12),La_(2)O_(3),CeF_(3) and LaF_(3),with Ce oxidation restricted by bastnaesite pyrolysis.As roasting time prolonged,cracks and pores appeared on bastnaesite surface;the BET specific surface and pore diameter increased.In later roasting period,the pore diameter continued to increase but the specific surface decreased,assigned to particle fusion agglomeration and pore consolidation.Additionally,the surface C content reduced and Ce(Ⅳ)content increased gradually as roasting progressed.The reaction kinetics all followed Avrami-Erofeev equations,the reaction orders of bastnaesite pyrolysis and Ce oxidation decreased with decreasing reaction temperature.The calculated activation energies at lower temperatures were higher than those calculated at higher temperatures.This study analyzed the bastnaesite reaction mechanism to supply a reference for the application of suspension roasting technology in bastnaesite smelting.
基金Project（2012ZX04010-81） supported by the National Key Technology R＆D Program of China Project （51575066） supported by the National Natural Science Foundation of China
文摘Constitutive model plays an important role in the numerical simulations of metal forming. However, th~ influence of the models on the calculation is vague. Based on the stress-strain data of A1 7050 and Ti-6A1-4V alloy generated by isothermal compressive tests, the Johnson-Cook （JC） and Arrhenius-type （A-type） hyperbolic sine model were fitted to obtain the constants. Flow stresses directly calculated by the equations were compared with th~ experiment results, and rigid-plastic finite element analyses （FEA） utilizing these models were employed to simulate th~ same compression processes. The results show that A-type model has higher accuracy in the direct prediction of roy stress, even outside of the fit domain. The simulation results using A-type model also have higher agreement with th~ experiment; however, the suitability is affected by the referential parameters employed in the regression process, h terms of the overall deformation and strain distributions, there are slight differences among the simulation results usint these two models.
基金Project(51534008) supported by the National Natural Science Foundation of China
文摘Based on heat and mass transfer characteristics of spontaneous combustion of coal,Arrhenius equation and the Ranz-Marshall correlation,a novel approach was proposed in this paper to estimate oxygen consumption rate of self-ignition of coal at high temperature.Compared with the conventional methods,this approach involves not only kinetic properties of self-ignition of coal and temperature,but also the ambient air flow characteristics and diameter of coal particle.To testify the proposed approach,oxygen consumption rates at high temperature were measured by the programmable isothermal oven experiments.Comparisons between experimental and theoretical results indicate that the rates of oxygen depletion calculated by the proposed approach agree well with those measured from laboratory-scale experiments,which further validates the proposed approach.
基金Project(20050335050) supported by the Special Foundation of Education Ministry of ChinaProject(10472105) supported by the National Natural Science Foundation of China
文摘The experimental observations about remarkable influence of the substrates on the isothermal crystallization rate of a high density polyethylene(HDPE) were presented.Two methods were used to characterize the crystallization rate:the change of turbidity of the HDPE specimen and the changes of the complex viscosity and storage modulus measured by a rotational rheometer,which gave consistent results showing that the isothermal crystallization rate decreased in sequence as the specimen contacted with aluminum,brass and stainless steel plates,respectively.As to the dominant influence factor,the chemical composition of the substrates can be excluded via insulating the plate by an aluminum foil.Instead,we propose the plate's ability of removing the latent heat of crystallization from the specimen.Rheological measurement is sensitive to the crystallization process.The colloid like model proposed by BOUTAHAR et al for the crystallization of HDPE gives reasonable predictions of the crystallized fraction from the measured storage modulus.
基金Project(10874118) supported by the National Natural Science Foundation of ChinaProject(109061) supported by the key Project of the Ministry of Education of China
文摘In order to study the effect of Zr on the microstructure and isothermal annealing performance of Cu–Cr in situ composites, Cu–15 Cr and Cu–15 Cr–0.24 Zr alloys were prepared by means of vacuum medium frequency induction melting technology. The two kinds of test alloys with deformation of 3.79 were subjected to isothermal annealing test. The effects of Zr on the as-cast microstructure, the isothermal annealing structure and the tensile fracture morphology of Cu–15 Cr alloy were studied by means of scanning electron microscopy(SEM), energy dispersive spectroscopy(EDS) and transmission electron microscopy(TEM). The results show that the addition of Zr leads to the formation of homogeneous and fine Cu Zr intermetallic compounds, which suppresses the formation electron microscopy of eutectic Cr phase and makes the eutectic Cr content much lower than that of Cu–15 Cr alloy. The recrystallization temperature of the Cu matrix is increased, and it is maintained at a fine equiaxed crystal at 400 °C. After isothermal annealing at 400 °C for 220 h, the tensile strength, electrical conductivity and elongation of the test alloy containing Zr were 720 MPa, 68% IACS and 6.7%, respectively; while the tensile strength, electrical conductivity and elongation of the test alloys without Zr were 488 MPa, 70% IACS and 12.4%, respectively.
