NiFe2O4-based cermet inert anodes with metallic phase compositions of Cu, Ni and 85Cu15Ni were prepared by cold pressing-sintering. Their corrosion resistance was also investigated in Na3 AIF6-Al2O3 melts. The resuits...NiFe2O4-based cermet inert anodes with metallic phase compositions of Cu, Ni and 85Cu15Ni were prepared by cold pressing-sintering. Their corrosion resistance was also investigated in Na3 AIF6-Al2O3 melts. The resuits show that the metallic phase species in cermets have no effect on the concentration of impurities in bath during electrolysis, the total steady-state concentration of impurities is almost the same, i.e. between 4.12 × 10^-4- 4.80 × 10^-4. There exists metal preferential corrosion for the cermet inert anode with metal Ni as metallic phase. For NiFe2 O4-based cermets, the cermet with metal Cu as metallic phase exhibits better corrosion resistance than the others.展开更多
5Cu/(10NiO-NiFe2O4) cermet inert anodes were prepared by cold-pressing and sintering process, and the effect of superheat degree of melting K3AlF6-Na3AlF6-AlF3 on their anticorrosion performance was studied under elec...5Cu/(10NiO-NiFe2O4) cermet inert anodes were prepared by cold-pressing and sintering process, and the effect of superheat degree of melting K3AlF6-Na3AlF6-AlF3 on their anticorrosion performance was studied under electrolysis conditions. The results show that, the fluctuation of cell becomes small with increasing of superheat degree, which is helpful to inhibit the formation of cathodic encrustation; the concentration of impurities from inert anode in bath goes up to certain degree, but it is far smaller than those in traditional high-temperature bath. Increasing the superheat degree of melting K3AlF6-Na3AlF6-AlF3 has unconspicuous effect on the contents of impurities in cathodic aluminum. The total mass fractions of Fe, Ni and Cu in aluminum are 15.38% and 15.09% respectively under superheat degree of 95 and 195 ℃. From micro-topography of anode used view, increasing the superheat degree can aggravate corrosion of metal Cu in inert anode, and has negative influence on electrical conductivity of electrode to some extent.展开更多
This paper presents the use of a computer method of the ventilation process simulation for the analysis of the flow distribution of air and gases in the area of wall mining work and the adjacent goaf.In workings and g...This paper presents the use of a computer method of the ventilation process simulation for the analysis of the flow distribution of air and gases in the area of wall mining work and the adjacent goaf.In workings and goaf,the complex issue of the formation of a gaseous atmosphere under variable ventilation conditions and an existing fire hazard level,with the possibility of feeding goaf with an additional carbon dioxide flux as the inertizing agent is considered.Some examples of the simulation of feeding goaf with carbon dioxide illustrating the different patterns of the distribution of the goaf atmosphere gases concentration,said distribution patterns being gas supply place dependent,have been presented.In addition,the impact of the additional sealing of goaf on the distribution level of the concentration of gases,the said sealing made from the wall side with chemical agents has also been considered.The capabilities of the VentGoaf computer simulation program,being the basis for our calculations,enable consideration of the use of the inert gases supplied to the goaf depending on: the location of the gas feeding the pipe outlet,tightness of the fire field,fire centre location,and spatial situation of the mined wall.It has been found that fire prevention elements,such as chemical sealing agents,are of great impact on the effectiveness of fire prevention.展开更多
The bubble behavior is one of the key factors for the design and the process of aluminum reduction cell using inert anode.A see-through cell is constructed to investigate the bubble flow behavior and the electrolyte f...The bubble behavior is one of the key factors for the design and the process of aluminum reduction cell using inert anode.A see-through cell is constructed to investigate the bubble flow behavior and the electrolyte flow pattern induced by bubbles.The test results show that the electrolyte is driven by the bubble to move around the cathode,and also some vortices occur in local areas.The bubble generated at the anode bottom undergoes the processes of formation,growth,sliding,detachment and coalescence.However,the bubble generated at the middle of anode detaches rapidly from the anode surface and moves upward and collides with other bubbles,which results in coalescence or break-up.Most bubbles are released into the atmosphere at the liquid surface,while some other bubbles taken by the electrolyte flush to the height higher than the mean horizontal level of the liquid and then drop down and move horizontally and they are released finally.Some bubbles are kept unbroken and are sliding on the electrolyte surface.The diameter of bubble generated at inert anode is smaller than that of bubble generated at graphite anode.Moreover,the bubbles on inert anode are spherical,which was different from those in tubular or disk form on graphite anode.展开更多
Cu/(10NiO-NiFe2O4) cermets containing mass fractions of Cu of 5%, 10%, 15% and 20% were prepared, and their electrical conductivities were measured at different temperatures. The effects of temperature and content of ...Cu/(10NiO-NiFe2O4) cermets containing mass fractions of Cu of 5%, 10%, 15% and 20% were prepared, and their electrical conductivities were measured at different temperatures. The effects of temperature and content of metal Cu on the electrical conductivity were investigated especially. The results indicate that the metallic phase Cu distributes evenly in 10NiO-NiFe2O4 ceramic matrix. The mechanism of electrical conductivity of Cu/(10NiO-NiFe2O4) cermets obeys the rule of electrical mechanism of semiconductor, the electrical conductivity for cermet containing 5% Cu increases from 2.70 to 20.41 S/cm with temperature increasing from 200 to 900 ℃. The change trend of electrical conductivity with temperature is similar with each other and it increases with increasing temperature and content of metal Cu. At 960 ℃, the electrical conductivity of cermet increases from 2.88 to 82.65 S/cm with the content of metal Cu increasing from 0 to 20%.展开更多
The CaO-doped Cu/（NiFe2O4-10NiO） cermet inert anodes were prepared by the cold isostatie pressing-sintering process, and their corrosion resistance to Na3AlF6-K3AlF6-Al203 melt was studied. The results show that the...The CaO-doped Cu/（NiFe2O4-10NiO） cermet inert anodes were prepared by the cold isostatie pressing-sintering process, and their corrosion resistance to Na3AlF6-K3AlF6-Al203 melt was studied. The results show that the relative density of 5Cu/（NiFe2O4-10NiO） cermet sintered at 1 200 ℃ increases from 82.83% to 97.63% when 2% CaO （mass fraction） is added. During the electrolysis, the relative density of cermet inert anode descends owing to the chemical dissolution of additive CaO at ceramic grain boundary, which accelerates the penetration of electrolyte. Thus, the corrosion resistance to melts of Cu/（NiFe2O4-10NiO） cermet inert anode is reduced. To improve the corrosion resistance of the cermet inert anode, the content of CaO doped should be decreased and the technology of cleaning the ceramic grain boundary should be applied.展开更多
Based on the FEA software ANSYS,a model was developed to simulate the thermal stress distribution of inert anode.In order to reduce its thermal stress,the effect of some parameters on thermal stress distribution was i...Based on the FEA software ANSYS,a model was developed to simulate the thermal stress distribution of inert anode.In order to reduce its thermal stress,the effect of some parameters on thermal stress distribution was investigated,including the temperature of electrolyte,the current,the anode cathode distance,the anode immersion depth,the surrounding temperature and the convection coefficient between anode and circumstance.The results show that there exists a large axial tensile stress near the tangent interface between the anode and bath,which is the major cause of anode breaking.Increasing the temperature of electrolyte or the anode immersion depth will deteriorate the stress distribution of inert anode.When the bath temperature increases from 750 to 970 ℃,the maximal value and absolute minimal value of the 1st principal stress increase by 29.7% and 29.6%,respectively.When the anode immersion depth is changed from 1 to 10 cm,the maximal value and absolute minimal value of the 1st principal stress increase by 52.1% and 65.0%,respectively.The effects of other parameters on stress distribution are not significant.展开更多
惯容器是一种两端点加速度相关型控制元件,具有表观质量放大、耗能增效等特性,可更加高效、经济地进行结构振动控制,将惯容器表观质量增大的特性拓展到调谐减震装置中可实现轻量化振动控制。为研究高层结构上附加旋转惯质双调谐质量阻尼...惯容器是一种两端点加速度相关型控制元件,具有表观质量放大、耗能增效等特性,可更加高效、经济地进行结构振动控制,将惯容器表观质量增大的特性拓展到调谐减震装置中可实现轻量化振动控制。为研究高层结构上附加旋转惯质双调谐质量阻尼器(rotating inertia dual-tuned mass damper,RIDTMD)的轻量化振动控制效果,采用柔度法求逆的方法获得等效简化模型;通过结构模态分析、时程分析验证了等效模型的可靠性;建立附加RIDTMD多自由度结构的力学模型与运动方程;采取H_(2)优化和给定质量、阻尼参数的取值区间来确定RIDTMD的参数。在一个51层的框架核心筒结构上设计了RIDTMD,分析其在地震激励下的楼层位移、加速度和层间位移角等结构响应,频域与时程分析结果看,以调谐质量阻尼器(tuned mass damper,TMD)控制效果为目标的H_(2)优化设计可以使RIDTMD有着与TMD类似的振动控制效果,与无控结构相比,顶层峰值位移、均方根位移最大可分别降低18.0、32.9%,且RIDTMD的调谐质量比TMD减少30.0%。展开更多
基金Project(2005CB623703) supported by the National Basic Research Programof China project(03JJY3080) supported bythe Hunan Provincial Natural Science Foundation
文摘NiFe2O4-based cermet inert anodes with metallic phase compositions of Cu, Ni and 85Cu15Ni were prepared by cold pressing-sintering. Their corrosion resistance was also investigated in Na3 AIF6-Al2O3 melts. The resuits show that the metallic phase species in cermets have no effect on the concentration of impurities in bath during electrolysis, the total steady-state concentration of impurities is almost the same, i.e. between 4.12 × 10^-4- 4.80 × 10^-4. There exists metal preferential corrosion for the cermet inert anode with metal Ni as metallic phase. For NiFe2 O4-based cermets, the cermet with metal Cu as metallic phase exhibits better corrosion resistance than the others.
基金Project (2005CB623703) supported by the Major State Basic Research and Development Program of China
文摘5Cu/(10NiO-NiFe2O4) cermet inert anodes were prepared by cold-pressing and sintering process, and the effect of superheat degree of melting K3AlF6-Na3AlF6-AlF3 on their anticorrosion performance was studied under electrolysis conditions. The results show that, the fluctuation of cell becomes small with increasing of superheat degree, which is helpful to inhibit the formation of cathodic encrustation; the concentration of impurities from inert anode in bath goes up to certain degree, but it is far smaller than those in traditional high-temperature bath. Increasing the superheat degree of melting K3AlF6-Na3AlF6-AlF3 has unconspicuous effect on the contents of impurities in cathodic aluminum. The total mass fractions of Fe, Ni and Cu in aluminum are 15.38% and 15.09% respectively under superheat degree of 95 and 195 ℃. From micro-topography of anode used view, increasing the superheat degree can aggravate corrosion of metal Cu in inert anode, and has negative influence on electrical conductivity of electrode to some extent.
基金a part of research projects(NN524 368237)Financed by the Ministry of Science and Higher Education
文摘This paper presents the use of a computer method of the ventilation process simulation for the analysis of the flow distribution of air and gases in the area of wall mining work and the adjacent goaf.In workings and goaf,the complex issue of the formation of a gaseous atmosphere under variable ventilation conditions and an existing fire hazard level,with the possibility of feeding goaf with an additional carbon dioxide flux as the inertizing agent is considered.Some examples of the simulation of feeding goaf with carbon dioxide illustrating the different patterns of the distribution of the goaf atmosphere gases concentration,said distribution patterns being gas supply place dependent,have been presented.In addition,the impact of the additional sealing of goaf on the distribution level of the concentration of gases,the said sealing made from the wall side with chemical agents has also been considered.The capabilities of the VentGoaf computer simulation program,being the basis for our calculations,enable consideration of the use of the inert gases supplied to the goaf depending on: the location of the gas feeding the pipe outlet,tightness of the fire field,fire centre location,and spatial situation of the mined wall.It has been found that fire prevention elements,such as chemical sealing agents,are of great impact on the effectiveness of fire prevention.
基金Projects(51304216,51371161)supported by the National Natural Science Foundation of China
文摘The bubble behavior is one of the key factors for the design and the process of aluminum reduction cell using inert anode.A see-through cell is constructed to investigate the bubble flow behavior and the electrolyte flow pattern induced by bubbles.The test results show that the electrolyte is driven by the bubble to move around the cathode,and also some vortices occur in local areas.The bubble generated at the anode bottom undergoes the processes of formation,growth,sliding,detachment and coalescence.However,the bubble generated at the middle of anode detaches rapidly from the anode surface and moves upward and collides with other bubbles,which results in coalescence or break-up.Most bubbles are released into the atmosphere at the liquid surface,while some other bubbles taken by the electrolyte flush to the height higher than the mean horizontal level of the liquid and then drop down and move horizontally and they are released finally.Some bubbles are kept unbroken and are sliding on the electrolyte surface.The diameter of bubble generated at inert anode is smaller than that of bubble generated at graphite anode.Moreover,the bubbles on inert anode are spherical,which was different from those in tubular or disk form on graphite anode.
基金Project(2005CB623703) supported by the National Basic Research and Development Program of China
文摘Cu/(10NiO-NiFe2O4) cermets containing mass fractions of Cu of 5%, 10%, 15% and 20% were prepared, and their electrical conductivities were measured at different temperatures. The effects of temperature and content of metal Cu on the electrical conductivity were investigated especially. The results indicate that the metallic phase Cu distributes evenly in 10NiO-NiFe2O4 ceramic matrix. The mechanism of electrical conductivity of Cu/(10NiO-NiFe2O4) cermets obeys the rule of electrical mechanism of semiconductor, the electrical conductivity for cermet containing 5% Cu increases from 2.70 to 20.41 S/cm with temperature increasing from 200 to 900 ℃. The change trend of electrical conductivity with temperature is similar with each other and it increases with increasing temperature and content of metal Cu. At 960 ℃, the electrical conductivity of cermet increases from 2.88 to 82.65 S/cm with the content of metal Cu increasing from 0 to 20%.
基金Project(2005CB623703) supported by the Major State Basic Research and Development Program of ChinaProject(2008AA030503) supported by Hi-Tech Research and Development Program of China
文摘The CaO-doped Cu/（NiFe2O4-10NiO） cermet inert anodes were prepared by the cold isostatie pressing-sintering process, and their corrosion resistance to Na3AlF6-K3AlF6-Al203 melt was studied. The results show that the relative density of 5Cu/（NiFe2O4-10NiO） cermet sintered at 1 200 ℃ increases from 82.83% to 97.63% when 2% CaO （mass fraction） is added. During the electrolysis, the relative density of cermet inert anode descends owing to the chemical dissolution of additive CaO at ceramic grain boundary, which accelerates the penetration of electrolyte. Thus, the corrosion resistance to melts of Cu/（NiFe2O4-10NiO） cermet inert anode is reduced. To improve the corrosion resistance of the cermet inert anode, the content of CaO doped should be decreased and the technology of cleaning the ceramic grain boundary should be applied.
基金Project (2005CB623703) supported by the National Basic Research and Development Program of ChinaProject (50474051) supported by the National Natural Science Foundation of China
文摘Based on the FEA software ANSYS,a model was developed to simulate the thermal stress distribution of inert anode.In order to reduce its thermal stress,the effect of some parameters on thermal stress distribution was investigated,including the temperature of electrolyte,the current,the anode cathode distance,the anode immersion depth,the surrounding temperature and the convection coefficient between anode and circumstance.The results show that there exists a large axial tensile stress near the tangent interface between the anode and bath,which is the major cause of anode breaking.Increasing the temperature of electrolyte or the anode immersion depth will deteriorate the stress distribution of inert anode.When the bath temperature increases from 750 to 970 ℃,the maximal value and absolute minimal value of the 1st principal stress increase by 29.7% and 29.6%,respectively.When the anode immersion depth is changed from 1 to 10 cm,the maximal value and absolute minimal value of the 1st principal stress increase by 52.1% and 65.0%,respectively.The effects of other parameters on stress distribution are not significant.
基金Project Supported by National Natural Science Foundation of China （ 11105067 ）, Science Technology Pillar Program of Jiangxi Province, China （2009AE00100）.
文摘惯容器是一种两端点加速度相关型控制元件,具有表观质量放大、耗能增效等特性,可更加高效、经济地进行结构振动控制,将惯容器表观质量增大的特性拓展到调谐减震装置中可实现轻量化振动控制。为研究高层结构上附加旋转惯质双调谐质量阻尼器(rotating inertia dual-tuned mass damper,RIDTMD)的轻量化振动控制效果,采用柔度法求逆的方法获得等效简化模型;通过结构模态分析、时程分析验证了等效模型的可靠性;建立附加RIDTMD多自由度结构的力学模型与运动方程;采取H_(2)优化和给定质量、阻尼参数的取值区间来确定RIDTMD的参数。在一个51层的框架核心筒结构上设计了RIDTMD,分析其在地震激励下的楼层位移、加速度和层间位移角等结构响应,频域与时程分析结果看,以调谐质量阻尼器(tuned mass damper,TMD)控制效果为目标的H_(2)优化设计可以使RIDTMD有着与TMD类似的振动控制效果,与无控结构相比,顶层峰值位移、均方根位移最大可分别降低18.0、32.9%,且RIDTMD的调谐质量比TMD减少30.0%。
