Melt inclusions in primitive olivine phenocrysts,which has been thought to represent the primitive melts(Schiano,2003),have increasingly been applied to studies of igneous processes(Audétat and Lowenstern,2014;Ke...Melt inclusions in primitive olivine phenocrysts,which has been thought to represent the primitive melts(Schiano,2003),have increasingly been applied to studies of igneous processes(Audétat and Lowenstern,2014;Kent,2008),including lunar magmatism(Chen et al.,2015;Hauri et al.,2011;Saal et al.,2013).However,some melt inclusions in primitive olivine phenocrysts in various tectonic settings。展开更多
Two centuries ago,Asia delivered over 60 percent of world production;in the middle of the 20th century it was less than 20 percent.Currently,it is twice as large and this share is still increasing,above all but not on...Two centuries ago,Asia delivered over 60 percent of world production;in the middle of the 20th century it was less than 20 percent.Currently,it is twice as large and this share is still increasing,above all but not only,because of China whose production is still growing at a rate twice as fast as the world average.China is trying to maintain high economic dynamics,inter alia,through investment external expansion.This aim is to be served,among others,by the infrastructure project,drawn up with enormous verve,known as the New Silk Road,which the Middle Kingdom addresses to 65 countries on three continents.While some hope for accelerating their own economic growth,others warn against the risk of becoming dependent on China.The article analyzes these challenges,pointing to the desired directions of irreversible evolution globalization by giving it a more inclusive character,which is also strongly emphasized by the Chinese authorities in their official enunciations.展开更多
With China’s reform and development entering a critical period,the interweaving of various interest relations and the superimposing of the old and new contradictions have intensified social risks.Based on the concept...With China’s reform and development entering a critical period,the interweaving of various interest relations and the superimposing of the old and new contradictions have intensified social risks.Based on the concept of“pluralism,sharing,participation,cooperation and tolerance”,social stability can be maintained by the balanced protection of civil rights and the full realization of the development strategy.In addition,with the guidance of comprehensive legal thinking and core socialist values,the legal regulation of administrative behavior and rights-protection behavior is strengthened.In this way,the win-win of maintaining rights and stability can be realized in the positive-sum game that will help resolve social risks and achieve high-quality social stability.展开更多
The influence of concrete components on projectile penetration is significant.To study the relationship between the equivalent mechanical properties and components of concrete under a penetration load,concrete is simp...The influence of concrete components on projectile penetration is significant.To study the relationship between the equivalent mechanical properties and components of concrete under a penetration load,concrete is simplified as a two-phase composite of coarse aggregate and mortar,and a meso-mechanical model is established,including the equivalent equation of state model,the equivalent confining pressure strength model and the equivalent dynamic tensile strength model,considering shear stress,large deformation and pore compression.Tests of the mechanical properties of mortar,concrete and limestone were conducted;the results show that the equivalent mechanical properties of concrete calculated by the meso-mechanical model are consistent with the test results,and the equivalent mechanical properties of concrete with different volume fractions of coarse aggregate are obtained.Meso-scale and macro-scale numerical simulations of a projectile penetrating into concrete are carried out,the penetration depths obtained by meso-scale and macro-scale numerical simulations are consistent for different volume fractions of coarse aggregate and different velocities of the projectile,which verifies the rationality of the meso-mechanical model.展开更多
Chemical inclusions significantly alter shock responses of crystalline explosives in macroscale gap experiments but their microscale dynamics origin remains unclear.Herein shock-induced energy localization,overall phy...Chemical inclusions significantly alter shock responses of crystalline explosives in macroscale gap experiments but their microscale dynamics origin remains unclear.Herein shock-induced energy localization,overall physical responses,and reactions in a-1,3,5-trinitro-1,3,5-triazinane(a-RDX)crystal entrained various chemical inclusions were investigated by the multi-scale shock technique implemented in the reactive molecular dynamics method.Results indicated that energy localization and shock reaction were affected by the intrinsic factors within chemical inclusions,i.e.,phase states,chemical compositions,and concentrations.The atomic origin of chemical-inclusions effects on energy localization is dependent on the dynamics mechanism of interfacial molecules with free space volume,which includes homogeneous intermolecular compression,interfacial impact and shear,and void collapse and jet.As introducing various chemical inclusions,the initiation of those dynamics mechanisms triggers diverse decay rates of bulk RDX molecules and hereby impacts on growth speeds of final reactions.Adding chemical inclusions can reduce the effectiveness of the void during the shock impacting.Under the shockwave velocity of 9 km/s,the parent RDX decay rate in RDX entrained amorphous carbon decreases the most and is about one fourth of that in RDX with a vacuum void,and solid HMX and TATB inclusions are more reactive than amorphous carbon but less reactive than dry air or acetone inclusions.The lessdense shocking system denotes the greater increases in local temperature and stress,the faster energy liberation,and the earlier final reaction into equilibrium,revealing more pronounced responses to the present intense shockwave.The quantitative models associated with the relative system density(RD_(sys))were proposed for indicating energy-localization mechanisms and evaluating initiation safety in the shocked crystalline explosive.RD_(sys)is defined by the density ratio of defective RDX to perfect crystal after dynamics relaxation and reveals the global density characteristic in shocked systems filled with chemical inclusions.When RD_(sys)is below 0.9,local hydrodynamic jet initiated by void collapse dominates upon energy localization instead of interfacial impact.This study sheds light on novel insights for understanding the shock chemistry and physical-based atomic origin in crystalline explosives considering chemical-inclusions effects.展开更多
The high cycle fatigue response of a high V-alloyed powder metallurgy tool steel （AISI 11） with different inclusion sizes was studied. Two materials of this grade at a similar hardness of about HRC 60 were subjected...The high cycle fatigue response of a high V-alloyed powder metallurgy tool steel （AISI 11） with different inclusion sizes was studied. Two materials of this grade at a similar hardness of about HRC 60 were subjected to axial loading fatigue tests, tensile tests and fracture toughness measurements to investigate their mechanical properties. Large inclusion above 70 ~rn is indicated to be responsible for the tensile fracture which happens before yielding. The fatigue strength obtained up to 107 cycles is found to decrease from approximately 1 538 MPa to 1000 MPa with the inclusion size increasing above 30 Izm. The internally induced crack initiation is mainly attributed to the surface compressive residual stress of 300-450 MPa. Fractographic evaluation demonstrates that the crack initiation and propagation controlling factors of the two materials are almost the same, indicating that the two factors would be insignificantly affected by the inclusion size level. Paris sizes of the two materials both show a tendency to decrease as the ratio of stress intensity factor of crack origin to factor of fish-eye increases. The investigation into the relationship between stress intensity factors and fatigue life of the two materials further indicates that the high cycle fatigue behavior of AISI 11 is controlled by crack propagation.展开更多
The types, composition and physico-chemical conditions of primary fluid inclusions were researched. The results show that the primary fluid inclusions contain vapor and liquid phase type （Type I）, daughter mineral-b...The types, composition and physico-chemical conditions of primary fluid inclusions were researched. The results show that the primary fluid inclusions contain vapor and liquid phase type （Type I）, daughter mineral-bearing type （Type II） and pure liquid phase type （Type III）. The compositions of vapor are mainly H20 and CO2 with a tiny amounts of CH4 and H2; the liquid phase mainly contains Mg2＋, Ca2＋, Na＋, K＋, CI- and SO]-, and w（Na＋）/w（K＋）〉l; the homogenization temperatures of the primary fluid inclusions can be divided into 190-250 ℃, 250-340 ℃ and 360-420 ℃, corresponding to the salinities of 4%-9%, 9%-14%, and 14%-20.43% （NaC1 equivalent mass fraction）, respectively. The mineralization process can be divided into three episodes： the silicatization stage, the quartz-sulfide stage, and the carbonatization stage, and all of them are associated with the ore-forming hydrothermal fluid activity. The origin of the hydrothermal fluid is from magrnatic water mainly, and later it mixes with the groundwater and meteoric water, which lead to the decrease of temperature and salinity. The decrease of salinity, temperature and pressure are the main causes of the metallogenic elements unloading and enriching in the favorable position.展开更多
Marmarosh massif is an important structural element of the Eastern Carpathians,which differs by the geological features from the other structural-facial zones of Carpathian fold belt.Metamorphic rocks of the massif ha...Marmarosh massif is an important structural element of the Eastern Carpathians,which differs by the geological features from the other structural-facial zones of Carpathian fold belt.Metamorphic rocks of the massif have been formed under the influence of the processes of medium-and low-temperature meta-morphism and metasomatism.Within the Marmarosh massif the stratiform gold ore has展开更多
The density of CO_(2)inclusions in minerals is commonly used to determine the crystallizing conditions of the host minerals.However,the conventional microthermometry method is difficult to apply for inclusions that ar...The density of CO_(2)inclusions in minerals is commonly used to determine the crystallizing conditions of the host minerals.However,the conventional microthermometry method is difficult to apply for inclusions that are small in size(【5-10μm)or low in density.展开更多
Located at the boundary of Chongli county, Chicheng county and Xuanhua county of Heibei province, the Dongping gold deposit is genetically affiliated to the late Jurassic- early Cretaceous volcanics and intrusives. Th...Located at the boundary of Chongli county, Chicheng county and Xuanhua county of Heibei province, the Dongping gold deposit is genetically affiliated to the late Jurassic- early Cretaceous volcanics and intrusives. The ore body is quartz vein- and alteration-type and pyrite and quartz are the dominant gold-bearing minerals.展开更多
Samples in the two oil fields with reported gas-washing and water-washing were collected for fluid inclusion analysis.Micro-fluorescence and Fourier infrared spectra of single oil inclusions were measured to study the...Samples in the two oil fields with reported gas-washing and water-washing were collected for fluid inclusion analysis.Micro-fluorescence and Fourier infrared spectra of single oil inclusions were measured to study the different effects of gas-washing and water-washing on oil compositions.The results show that spectral parameter QF_(535)values of the oils altered by gas-washing were expanded toward decreasing and increasing,respectively.The CH_(2)/CH_(3)distribution range ratio does not expand significantly,but the peak values are averaged.And the distribution of H_(2)O/Alkanes has no change.The QF_(535)values of the oils affected by water-washing increased towards the increase direction,and the distribution ranges of both CH_(2)/CH_(3)and H_(2)O/Alkanes increase significantly.The changes of QF_(535)in light oil reservoirs altered by gas-washing and CH_(2)/CH_(3)in heavy oil reservoirs by water-washing are not obvious.Therefore,two spectral parameter distribution trend charts of light and heavy oil reservoirs are summarized to discriminate the gas-washing and water-washing processes.This study is of great practical significance to utilize fluid inclusion analysis to restructure stages and processes of petroleum accumulation.展开更多
The chemical nature of the interaction of starch and dodecylamine （DDA）, which generally act as depressant and collector, respectively, in the reverse flotation of bauxite, was investigated using starch-iodine tests...The chemical nature of the interaction of starch and dodecylamine （DDA）, which generally act as depressant and collector, respectively, in the reverse flotation of bauxite, was investigated using starch-iodine tests. The results obtained from the blue-value measurements for starch＋DDA＋iodine system indicate the formation of the inclusion complex for amylose-DDA system at low DDA concentration （〈2 retool/L）. However, it is less likely for amylopectin-DDA system with short helix. UV-Vis spectra of starch-iodine complexes show that each helix of amylose can accommodate two DDA molecules locating separately at its two ends, and in the helical cavity there is room available for the upcoming iodine. When concentrated DDA is tested, amylose-DDA system exhibits no characteristic starch-iodine color, owing to the presence of a compact coating of DDA molecules on starch via hydroxyl/amine hydrogen bonding. ^1H NMR spectroscopy and surface tension determination help to clarify the interaction mechanism of amylose with DDA.展开更多
Infrared microthermometry allows direct measurement of fluid inclusions hosted in opaque ore minerals and can provide direct constraints on the evolution of ore-forming fluids.This study presents infrared microthermom...Infrared microthermometry allows direct measurement of fluid inclusions hosted in opaque ore minerals and can provide direct constraints on the evolution of ore-forming fluids.This study presents infrared microthermometry of spherite-hosted fluid inclusions from the Xinqiao deposit in the Middle-Lower Yangtze Metallogenic Belt and sheds new light on the ore genesis of the deposit.Considering that infrared light may lead to non-negligible temperature deviations during microthermometry,some tests were first conducted to ensure the accuracy of the microthermometric measurements.The measurement results indicated that using the lowest light intensity of the microscope and inserting an optical filter were effective in minimizing the possible temperature deviations of infrared microthermometry.All sphalerite-hosted fluid inclusions from the Xinqiao deposit were aqueous.They show homogenization temperature ranging from~200 to 350℃,but have two separate salinity groups(1.0 wt%-10 wt%and 15.1 wt%-19.2 wt%NaCl equivalent).The low-salinity group represents sedimentary exhalative(SEDEX)-associated fluids,whereas the high-salinity group results from modification by later magmatic hydrothermal fluids.Combined with published fluid inclusion data,the four-stage fluid evolution of the Xinqiao deposit was depicted.Furthermore,our data suggest that the Xinqiao deposit was formed by twostage metallogenic events including SEDEX and magmatic-hydrothermal mineralization.展开更多
The large-range uncertainties of specific impulse,mass flow per second,aerodynamic coefficients and atmospheric density during rapid turning in solid launch vehicles(SLVs) ascending leads to the deviation of the actua...The large-range uncertainties of specific impulse,mass flow per second,aerodynamic coefficients and atmospheric density during rapid turning in solid launch vehicles(SLVs) ascending leads to the deviation of the actual trajectory from the reference one.One of the traditional trajectory tracking methods is to observe the uncertainties by Extended State Observer(ESO) and then modify the control commands.However,ESO cannot accurately estimate the uncertainties when the uncertainty ranges are large,which reduces the guidance accuracy.This paper introduces differential inclusion(DI) and designs a controller to solve the large-range parameter uncertainties problem.When above uncertainties have large ranges,it can be combined with the ascent dynamic equation and described as a DI system in the mathematical form of a set.If the DI system is stabilized,all the subsets are stabilized.Different from the traditional controllers,the parameters of the designed controller are calculated by the uncertain boundaries.Therefore,the controller can solve the problem of large-range parameter uncertainties of in ascending.Firstly,the ascent deviation system is obtained by linearization along the reference trajectory.The trajectory tracking system with engine parameters and aerodynamic uncertainties is described as an ascent DI system with respect to state deviation,which is called DI system.A DI adaptive saturation tracking controller(DIAST) is proposed to stabilize the DI system.Secondly,an improved barrier Lyapunov function(named time-varying tangent-log barrier Lyapunov function) is proposed to constrain the state deviations.Compared with traditional barrier Lyapunov function,it can dynamically adjust the boundary of deviation convergence,which improve the convergence rate and accuracy of altitude,velocity and LTIA deviation.In addition,the correction amplitudes of angle of attack(AOA) and angle of sideslip(AOS) need to be limited in order to guarantee that the overload constraint is not violated during actual flight.In this paper,a fixed time adaptive saturation compensation auxiliary system is designed to shorten the saturation time and accelerate the convergence rate,which eliminates the adverse effects caused by the saturation.Finally,it is proved that the state deviations are ultimately uniformly bounded under the action of DIAST controller.Simulation results show that the DI ascent tracking system is stabilized within the given uncertainty boundary values.The feasible bounds of uncertainty is broadened compared with Integrated Guidance and Control algorithm.Compared with Robust Gain-Scheduling Control method,the robustness to the engine parameters are greatly improved and the control variable is smoother.展开更多
文摘Melt inclusions in primitive olivine phenocrysts,which has been thought to represent the primitive melts(Schiano,2003),have increasingly been applied to studies of igneous processes(Audétat and Lowenstern,2014;Kent,2008),including lunar magmatism(Chen et al.,2015;Hauri et al.,2011;Saal et al.,2013).However,some melt inclusions in primitive olivine phenocrysts in various tectonic settings。
文摘Two centuries ago,Asia delivered over 60 percent of world production;in the middle of the 20th century it was less than 20 percent.Currently,it is twice as large and this share is still increasing,above all but not only,because of China whose production is still growing at a rate twice as fast as the world average.China is trying to maintain high economic dynamics,inter alia,through investment external expansion.This aim is to be served,among others,by the infrastructure project,drawn up with enormous verve,known as the New Silk Road,which the Middle Kingdom addresses to 65 countries on three continents.While some hope for accelerating their own economic growth,others warn against the risk of becoming dependent on China.The article analyzes these challenges,pointing to the desired directions of irreversible evolution globalization by giving it a more inclusive character,which is also strongly emphasized by the Chinese authorities in their official enunciations.
文摘With China’s reform and development entering a critical period,the interweaving of various interest relations and the superimposing of the old and new contradictions have intensified social risks.Based on the concept of“pluralism,sharing,participation,cooperation and tolerance”,social stability can be maintained by the balanced protection of civil rights and the full realization of the development strategy.In addition,with the guidance of comprehensive legal thinking and core socialist values,the legal regulation of administrative behavior and rights-protection behavior is strengthened.In this way,the win-win of maintaining rights and stability can be realized in the positive-sum game that will help resolve social risks and achieve high-quality social stability.
基金supported by the National Natural Science Foundation of China [grant number 51278250]
文摘The influence of concrete components on projectile penetration is significant.To study the relationship between the equivalent mechanical properties and components of concrete under a penetration load,concrete is simplified as a two-phase composite of coarse aggregate and mortar,and a meso-mechanical model is established,including the equivalent equation of state model,the equivalent confining pressure strength model and the equivalent dynamic tensile strength model,considering shear stress,large deformation and pore compression.Tests of the mechanical properties of mortar,concrete and limestone were conducted;the results show that the equivalent mechanical properties of concrete calculated by the meso-mechanical model are consistent with the test results,and the equivalent mechanical properties of concrete with different volume fractions of coarse aggregate are obtained.Meso-scale and macro-scale numerical simulations of a projectile penetrating into concrete are carried out,the penetration depths obtained by meso-scale and macro-scale numerical simulations are consistent for different volume fractions of coarse aggregate and different velocities of the projectile,which verifies the rationality of the meso-mechanical model.
基金the financial support from National Natural Science Foundation of China(Grant Nos.11872119,12172051,and 11972329)Natural Science Foundation of Hubei Province(Grant No.2021CFB120)。
文摘Chemical inclusions significantly alter shock responses of crystalline explosives in macroscale gap experiments but their microscale dynamics origin remains unclear.Herein shock-induced energy localization,overall physical responses,and reactions in a-1,3,5-trinitro-1,3,5-triazinane(a-RDX)crystal entrained various chemical inclusions were investigated by the multi-scale shock technique implemented in the reactive molecular dynamics method.Results indicated that energy localization and shock reaction were affected by the intrinsic factors within chemical inclusions,i.e.,phase states,chemical compositions,and concentrations.The atomic origin of chemical-inclusions effects on energy localization is dependent on the dynamics mechanism of interfacial molecules with free space volume,which includes homogeneous intermolecular compression,interfacial impact and shear,and void collapse and jet.As introducing various chemical inclusions,the initiation of those dynamics mechanisms triggers diverse decay rates of bulk RDX molecules and hereby impacts on growth speeds of final reactions.Adding chemical inclusions can reduce the effectiveness of the void during the shock impacting.Under the shockwave velocity of 9 km/s,the parent RDX decay rate in RDX entrained amorphous carbon decreases the most and is about one fourth of that in RDX with a vacuum void,and solid HMX and TATB inclusions are more reactive than amorphous carbon but less reactive than dry air or acetone inclusions.The lessdense shocking system denotes the greater increases in local temperature and stress,the faster energy liberation,and the earlier final reaction into equilibrium,revealing more pronounced responses to the present intense shockwave.The quantitative models associated with the relative system density(RD_(sys))were proposed for indicating energy-localization mechanisms and evaluating initiation safety in the shocked crystalline explosive.RD_(sys)is defined by the density ratio of defective RDX to perfect crystal after dynamics relaxation and reveals the global density characteristic in shocked systems filled with chemical inclusions.When RD_(sys)is below 0.9,local hydrodynamic jet initiated by void collapse dominates upon energy localization instead of interfacial impact.This study sheds light on novel insights for understanding the shock chemistry and physical-based atomic origin in crystalline explosives considering chemical-inclusions effects.
基金Project(2007BAE51B05)supported by the National Key Technologies Research and Development Program of China
文摘The high cycle fatigue response of a high V-alloyed powder metallurgy tool steel （AISI 11） with different inclusion sizes was studied. Two materials of this grade at a similar hardness of about HRC 60 were subjected to axial loading fatigue tests, tensile tests and fracture toughness measurements to investigate their mechanical properties. Large inclusion above 70 ~rn is indicated to be responsible for the tensile fracture which happens before yielding. The fatigue strength obtained up to 107 cycles is found to decrease from approximately 1 538 MPa to 1000 MPa with the inclusion size increasing above 30 Izm. The internally induced crack initiation is mainly attributed to the surface compressive residual stress of 300-450 MPa. Fractographic evaluation demonstrates that the crack initiation and propagation controlling factors of the two materials are almost the same, indicating that the two factors would be insignificantly affected by the inclusion size level. Paris sizes of the two materials both show a tendency to decrease as the ratio of stress intensity factor of crack origin to factor of fish-eye increases. The investigation into the relationship between stress intensity factors and fatigue life of the two materials further indicates that the high cycle fatigue behavior of AISI 11 is controlled by crack propagation.
基金Project(200911007-04) supported by the Special Funds for Scientific Research of Land and Natural Resources, ChinaProject (2007CB411405) supported by the National Basic Research Program of ChinaProject(20109901) supported by the National Crisis Office of China
文摘The types, composition and physico-chemical conditions of primary fluid inclusions were researched. The results show that the primary fluid inclusions contain vapor and liquid phase type （Type I）, daughter mineral-bearing type （Type II） and pure liquid phase type （Type III）. The compositions of vapor are mainly H20 and CO2 with a tiny amounts of CH4 and H2; the liquid phase mainly contains Mg2＋, Ca2＋, Na＋, K＋, CI- and SO]-, and w（Na＋）/w（K＋）〉l; the homogenization temperatures of the primary fluid inclusions can be divided into 190-250 ℃, 250-340 ℃ and 360-420 ℃, corresponding to the salinities of 4%-9%, 9%-14%, and 14%-20.43% （NaC1 equivalent mass fraction）, respectively. The mineralization process can be divided into three episodes： the silicatization stage, the quartz-sulfide stage, and the carbonatization stage, and all of them are associated with the ore-forming hydrothermal fluid activity. The origin of the hydrothermal fluid is from magrnatic water mainly, and later it mixes with the groundwater and meteoric water, which lead to the decrease of temperature and salinity. The decrease of salinity, temperature and pressure are the main causes of the metallogenic elements unloading and enriching in the favorable position.
文摘Marmarosh massif is an important structural element of the Eastern Carpathians,which differs by the geological features from the other structural-facial zones of Carpathian fold belt.Metamorphic rocks of the massif have been formed under the influence of the processes of medium-and low-temperature meta-morphism and metasomatism.Within the Marmarosh massif the stratiform gold ore has
文摘The density of CO_(2)inclusions in minerals is commonly used to determine the crystallizing conditions of the host minerals.However,the conventional microthermometry method is difficult to apply for inclusions that are small in size(【5-10μm)or low in density.
文摘Located at the boundary of Chongli county, Chicheng county and Xuanhua county of Heibei province, the Dongping gold deposit is genetically affiliated to the late Jurassic- early Cretaceous volcanics and intrusives. The ore body is quartz vein- and alteration-type and pyrite and quartz are the dominant gold-bearing minerals.
基金National Science and Technology Projects(2011ZX05023-004-010)National Science Foundation of Hubei Province(2020CFB372)。
文摘Samples in the two oil fields with reported gas-washing and water-washing were collected for fluid inclusion analysis.Micro-fluorescence and Fourier infrared spectra of single oil inclusions were measured to study the different effects of gas-washing and water-washing on oil compositions.The results show that spectral parameter QF_(535)values of the oils altered by gas-washing were expanded toward decreasing and increasing,respectively.The CH_(2)/CH_(3)distribution range ratio does not expand significantly,but the peak values are averaged.And the distribution of H_(2)O/Alkanes has no change.The QF_(535)values of the oils affected by water-washing increased towards the increase direction,and the distribution ranges of both CH_(2)/CH_(3)and H_(2)O/Alkanes increase significantly.The changes of QF_(535)in light oil reservoirs altered by gas-washing and CH_(2)/CH_(3)in heavy oil reservoirs by water-washing are not obvious.Therefore,two spectral parameter distribution trend charts of light and heavy oil reservoirs are summarized to discriminate the gas-washing and water-washing processes.This study is of great practical significance to utilize fluid inclusion analysis to restructure stages and processes of petroleum accumulation.
基金Project(50804055) supported by the National Natural Science Foundation of China
文摘The chemical nature of the interaction of starch and dodecylamine （DDA）, which generally act as depressant and collector, respectively, in the reverse flotation of bauxite, was investigated using starch-iodine tests. The results obtained from the blue-value measurements for starch＋DDA＋iodine system indicate the formation of the inclusion complex for amylose-DDA system at low DDA concentration （〈2 retool/L）. However, it is less likely for amylopectin-DDA system with short helix. UV-Vis spectra of starch-iodine complexes show that each helix of amylose can accommodate two DDA molecules locating separately at its two ends, and in the helical cavity there is room available for the upcoming iodine. When concentrated DDA is tested, amylose-DDA system exhibits no characteristic starch-iodine color, owing to the presence of a compact coating of DDA molecules on starch via hydroxyl/amine hydrogen bonding. ^1H NMR spectroscopy and surface tension determination help to clarify the interaction mechanism of amylose with DDA.
基金supported by the National Key R&D Program of China(2018YFA0702701)the Fundamental Research Funds for the Central Universities(WK3410000015).
文摘Infrared microthermometry allows direct measurement of fluid inclusions hosted in opaque ore minerals and can provide direct constraints on the evolution of ore-forming fluids.This study presents infrared microthermometry of spherite-hosted fluid inclusions from the Xinqiao deposit in the Middle-Lower Yangtze Metallogenic Belt and sheds new light on the ore genesis of the deposit.Considering that infrared light may lead to non-negligible temperature deviations during microthermometry,some tests were first conducted to ensure the accuracy of the microthermometric measurements.The measurement results indicated that using the lowest light intensity of the microscope and inserting an optical filter were effective in minimizing the possible temperature deviations of infrared microthermometry.All sphalerite-hosted fluid inclusions from the Xinqiao deposit were aqueous.They show homogenization temperature ranging from~200 to 350℃,but have two separate salinity groups(1.0 wt%-10 wt%and 15.1 wt%-19.2 wt%NaCl equivalent).The low-salinity group represents sedimentary exhalative(SEDEX)-associated fluids,whereas the high-salinity group results from modification by later magmatic hydrothermal fluids.Combined with published fluid inclusion data,the four-stage fluid evolution of the Xinqiao deposit was depicted.Furthermore,our data suggest that the Xinqiao deposit was formed by twostage metallogenic events including SEDEX and magmatic-hydrothermal mineralization.
基金supported by the National Natural Science Foundation of China (Grant Nos.61627810, 61790562 and 61403096)。
文摘The large-range uncertainties of specific impulse,mass flow per second,aerodynamic coefficients and atmospheric density during rapid turning in solid launch vehicles(SLVs) ascending leads to the deviation of the actual trajectory from the reference one.One of the traditional trajectory tracking methods is to observe the uncertainties by Extended State Observer(ESO) and then modify the control commands.However,ESO cannot accurately estimate the uncertainties when the uncertainty ranges are large,which reduces the guidance accuracy.This paper introduces differential inclusion(DI) and designs a controller to solve the large-range parameter uncertainties problem.When above uncertainties have large ranges,it can be combined with the ascent dynamic equation and described as a DI system in the mathematical form of a set.If the DI system is stabilized,all the subsets are stabilized.Different from the traditional controllers,the parameters of the designed controller are calculated by the uncertain boundaries.Therefore,the controller can solve the problem of large-range parameter uncertainties of in ascending.Firstly,the ascent deviation system is obtained by linearization along the reference trajectory.The trajectory tracking system with engine parameters and aerodynamic uncertainties is described as an ascent DI system with respect to state deviation,which is called DI system.A DI adaptive saturation tracking controller(DIAST) is proposed to stabilize the DI system.Secondly,an improved barrier Lyapunov function(named time-varying tangent-log barrier Lyapunov function) is proposed to constrain the state deviations.Compared with traditional barrier Lyapunov function,it can dynamically adjust the boundary of deviation convergence,which improve the convergence rate and accuracy of altitude,velocity and LTIA deviation.In addition,the correction amplitudes of angle of attack(AOA) and angle of sideslip(AOS) need to be limited in order to guarantee that the overload constraint is not violated during actual flight.In this paper,a fixed time adaptive saturation compensation auxiliary system is designed to shorten the saturation time and accelerate the convergence rate,which eliminates the adverse effects caused by the saturation.Finally,it is proved that the state deviations are ultimately uniformly bounded under the action of DIAST controller.Simulation results show that the DI ascent tracking system is stabilized within the given uncertainty boundary values.The feasible bounds of uncertainty is broadened compared with Integrated Guidance and Control algorithm.Compared with Robust Gain-Scheduling Control method,the robustness to the engine parameters are greatly improved and the control variable is smoother.
