The transverse shrinkage, mechanical and metallurgical properties of AISI: 310 S ASS weld joints prepared by P-GMAW and DP-GMAW processes were investigated. It was observed that the use of the DP-GMAW process improves...The transverse shrinkage, mechanical and metallurgical properties of AISI: 310 S ASS weld joints prepared by P-GMAW and DP-GMAW processes were investigated. It was observed that the use of the DP-GMAW process improves the aforementioned characteristics in comparison to that of the P-GMAW process. The enhanced quality of weld joints obtained with DP-GMAW process is primarily due to the combined effect of pulsed current and thermal pulsation(low frequency pulse). During the thermal pulsation period, there is a fluctuation of wire feed rate,which results in the further increase in welding current and the decrease in arc voltage. Because of this synchronization between welding current and arc voltage during the period of low frequency pulse, the DP-GMAW deposit introduces comparatively more thermal shock compared to the P-GMAW deposit, thereby reducing the heat input and improves the properties of weld joints.展开更多
25 mm thick micro-alloyed HSLA steel plate is welded by multi-pass GMAW and P-GMAW processes using conventional V-groove and suitably designed narrow gap with 20 mm(NG-20) and 13 mm(NG-13) groove openings.The variatio...25 mm thick micro-alloyed HSLA steel plate is welded by multi-pass GMAW and P-GMAW processes using conventional V-groove and suitably designed narrow gap with 20 mm(NG-20) and 13 mm(NG-13) groove openings.The variation of weld metal chemistry in the multi pass GMA and P-GMA weld depositions are studied by spark emission spectroscopy.It is observed that the narrow groove GMA weld joint shows significant variation of weld metal chemistry compared to the conventional V-groove GMA weld joint since the dilution of base metal extends from the deposit adjacent to groove wall to weld center through dissolution by fusion and solid state diffusion.Further,it is noticed that a high rate of metal deposition along with high velocity of droplet transfer in P-GMAW process enhances the dilution of weld deposit and accordingly varies the chemical composition in multi-pass P-GMA weld deposit.Lower angle of attack to the groove wall surface along with low heat input in NG-13 weld groove minimizes the effect of dissolution by fusion and solid state diffusion from the deposit adjacent to groove wall to weld center.This results in more uniform properties of NG-13 P-GMA weld in comparison to those of NG-20 and CG welds.展开更多
Ni/n-SiO2 composite coating was electrodeposited by brush-plating with pulse-reverse current（RC）. The morphology, hardness, and tribological properties of the coating were investigated and compared with those of Ni ...Ni/n-SiO2 composite coating was electrodeposited by brush-plating with pulse-reverse current（RC）. The morphology, hardness, and tribological properties of the coating were investigated and compared with those of Ni and composite coatings electrodeposited with direct current（DC）. The results indicate that Ni/n-SiO2 composite coating electrodeposited by RC, because of RC and the nano powders, has denser coating, finer crystal grains, higher hardness（HV650.0, nearly 1.5 times higher than that of Ni coating electrodeposited by DC） and lower friction coefficient（nearly 0.62）, as a result, in the wearing experiment, the Ni/n-SiO2 composite coating electrodeposited by RC has the least worn loss. So this kind of coating has better wear resistance. And RC electro brush-plating can be used as a new technology of brush-plating in the area of wear resistance.展开更多
An electromagnetic coupling mathematical model is established by finite element method and is verified by the contrastive experiments of copper matrix Ni-TiN cylindrical coating electrode,copper electrode and Cu50 W e...An electromagnetic coupling mathematical model is established by finite element method and is verified by the contrastive experiments of copper matrix Ni-TiN cylindrical coating electrode,copper electrode and Cu50 W electrode.The wear mechanism of Ni-TiN/Cu composite electrode in the case of high-frequency pulse current is studied,and the influence of the fluctuation frequency of discharge current on electrode wear in micro-EDM is found out.Compared with the electrode made from homogeneous material,the high frequency electromagnetic properties of Ni-TiN composite layer can be used effectively to inhibit the effect of high frequency pulse on the electrode and improve the distribution trend of current density.展开更多
In order to better understand the physical mechanism of sub-microsecond pulsed glow discharge with bare metal electrodes,using a one-dimensional self-consistent fluid model,the properties of the discharge at atmospher...In order to better understand the physical mechanism of sub-microsecond pulsed glow discharge with bare metal electrodes,using a one-dimensional self-consistent fluid model,the properties of the discharge at atmospheric pressure are numerically studied.The results show that,a discharge without dielectric layers,i.e.a barrier free discharge,is extinguished only with the decrease of the applied voltage.Only one positive discharge event occurs at the slope of the pulsed voltage.A stable glow of barrier free discharge can be achieved only in short durations of the pulsed voltage.The barrier free discharge always starts with a subnormal glow discharge and then evolves into a normal glow discharge.Moreover,to control the discharge stabilization better,the effects of pulse repetition frequency,pulse duration,rising(front) and falling(slope) times on the discharge characteristics are investigated systematically.It is found that the discharge is comparatively more sensitive to the repetition frequency and the pulse duration,while little affected by the rising and falling times.展开更多
针对现有污水样本快速检测技术存在的不足,以及传统实验室质谱技术无法应用于现场快速检测、检测耗时较长等问题,本文提出了一种基于脉冲直流电喷雾电离质谱(pulsed-DC-ESI-MS)测定生活污水中11种常见毒品(吗啡、甲基苯丙胺、去甲氯胺...针对现有污水样本快速检测技术存在的不足,以及传统实验室质谱技术无法应用于现场快速检测、检测耗时较长等问题,本文提出了一种基于脉冲直流电喷雾电离质谱(pulsed-DC-ESI-MS)测定生活污水中11种常见毒品(吗啡、甲基苯丙胺、去甲氯胺酮、苯丙胺、3,4-亚甲基双氧甲基苯丙胺、可卡因、6-单乙酰吗啡、3,4-亚甲基双氧苯丙胺、苯甲酰爱康宁、氯胺酮、可待因)的快速检测方法。污水样品经浓盐酸调节pH至2,用Oasis PRiME MCX固相萃取柱进行萃取,萃取液经氮吹至近干后用200μL甲醇复溶,涡旋0.5 min;复溶后的样品溶液经0.22μm有机相滤膜过滤后采用pulsed-DC-ESI-MS进行分析。方法学验证结果表明,11种毒品在各自的线性范围内具有良好的线性关系,相关系数(r2)均≥0.9986,检出限(LOD)为0.01~0.5μg/L,定量限(LOQ)为0.05~5μg/L。在低、中、高3个加标水平下,11种毒品的回收率为88.0%~107.6%,日内和日间精密度均≤8.5%。该方法检测速度快,大大提高了检测效率,适用于生活污水中常见毒品的快速检测分析。展开更多
文摘The transverse shrinkage, mechanical and metallurgical properties of AISI: 310 S ASS weld joints prepared by P-GMAW and DP-GMAW processes were investigated. It was observed that the use of the DP-GMAW process improves the aforementioned characteristics in comparison to that of the P-GMAW process. The enhanced quality of weld joints obtained with DP-GMAW process is primarily due to the combined effect of pulsed current and thermal pulsation(low frequency pulse). During the thermal pulsation period, there is a fluctuation of wire feed rate,which results in the further increase in welding current and the decrease in arc voltage. Because of this synchronization between welding current and arc voltage during the period of low frequency pulse, the DP-GMAW deposit introduces comparatively more thermal shock compared to the P-GMAW deposit, thereby reducing the heat input and improves the properties of weld joints.
基金the Indian Institute of Technology Roorkee (IITR), India for supporting to the research work
文摘25 mm thick micro-alloyed HSLA steel plate is welded by multi-pass GMAW and P-GMAW processes using conventional V-groove and suitably designed narrow gap with 20 mm(NG-20) and 13 mm(NG-13) groove openings.The variation of weld metal chemistry in the multi pass GMA and P-GMA weld depositions are studied by spark emission spectroscopy.It is observed that the narrow groove GMA weld joint shows significant variation of weld metal chemistry compared to the conventional V-groove GMA weld joint since the dilution of base metal extends from the deposit adjacent to groove wall to weld center through dissolution by fusion and solid state diffusion.Further,it is noticed that a high rate of metal deposition along with high velocity of droplet transfer in P-GMAW process enhances the dilution of weld deposit and accordingly varies the chemical composition in multi-pass P-GMA weld deposit.Lower angle of attack to the groove wall surface along with low heat input in NG-13 weld groove minimizes the effect of dissolution by fusion and solid state diffusion from the deposit adjacent to groove wall to weld center.This results in more uniform properties of NG-13 P-GMA weld in comparison to those of NG-20 and CG welds.
文摘Ni/n-SiO2 composite coating was electrodeposited by brush-plating with pulse-reverse current（RC）. The morphology, hardness, and tribological properties of the coating were investigated and compared with those of Ni and composite coatings electrodeposited with direct current（DC）. The results indicate that Ni/n-SiO2 composite coating electrodeposited by RC, because of RC and the nano powders, has denser coating, finer crystal grains, higher hardness（HV650.0, nearly 1.5 times higher than that of Ni coating electrodeposited by DC） and lower friction coefficient（nearly 0.62）, as a result, in the wearing experiment, the Ni/n-SiO2 composite coating electrodeposited by RC has the least worn loss. So this kind of coating has better wear resistance. And RC electro brush-plating can be used as a new technology of brush-plating in the area of wear resistance.
基金the National Natural Science Foundation of China for financially supporting this research through project No.51005027
文摘An electromagnetic coupling mathematical model is established by finite element method and is verified by the contrastive experiments of copper matrix Ni-TiN cylindrical coating electrode,copper electrode and Cu50 W electrode.The wear mechanism of Ni-TiN/Cu composite electrode in the case of high-frequency pulse current is studied,and the influence of the fluctuation frequency of discharge current on electrode wear in micro-EDM is found out.Compared with the electrode made from homogeneous material,the high frequency electromagnetic properties of Ni-TiN composite layer can be used effectively to inhibit the effect of high frequency pulse on the electrode and improve the distribution trend of current density.
文摘In order to better understand the physical mechanism of sub-microsecond pulsed glow discharge with bare metal electrodes,using a one-dimensional self-consistent fluid model,the properties of the discharge at atmospheric pressure are numerically studied.The results show that,a discharge without dielectric layers,i.e.a barrier free discharge,is extinguished only with the decrease of the applied voltage.Only one positive discharge event occurs at the slope of the pulsed voltage.A stable glow of barrier free discharge can be achieved only in short durations of the pulsed voltage.The barrier free discharge always starts with a subnormal glow discharge and then evolves into a normal glow discharge.Moreover,to control the discharge stabilization better,the effects of pulse repetition frequency,pulse duration,rising(front) and falling(slope) times on the discharge characteristics are investigated systematically.It is found that the discharge is comparatively more sensitive to the repetition frequency and the pulse duration,while little affected by the rising and falling times.
文摘针对现有污水样本快速检测技术存在的不足,以及传统实验室质谱技术无法应用于现场快速检测、检测耗时较长等问题,本文提出了一种基于脉冲直流电喷雾电离质谱(pulsed-DC-ESI-MS)测定生活污水中11种常见毒品(吗啡、甲基苯丙胺、去甲氯胺酮、苯丙胺、3,4-亚甲基双氧甲基苯丙胺、可卡因、6-单乙酰吗啡、3,4-亚甲基双氧苯丙胺、苯甲酰爱康宁、氯胺酮、可待因)的快速检测方法。污水样品经浓盐酸调节pH至2,用Oasis PRiME MCX固相萃取柱进行萃取,萃取液经氮吹至近干后用200μL甲醇复溶,涡旋0.5 min;复溶后的样品溶液经0.22μm有机相滤膜过滤后采用pulsed-DC-ESI-MS进行分析。方法学验证结果表明,11种毒品在各自的线性范围内具有良好的线性关系,相关系数(r2)均≥0.9986,检出限(LOD)为0.01~0.5μg/L,定量限(LOQ)为0.05~5μg/L。在低、中、高3个加标水平下,11种毒品的回收率为88.0%~107.6%,日内和日间精密度均≤8.5%。该方法检测速度快,大大提高了检测效率,适用于生活污水中常见毒品的快速检测分析。
