Because of an unfortunate mistake by authors,the Project(5227010679)of Foundation item was wrong.The corrected Project is shown as follows:Project(52271073).
Transition metal sulfides are considered promising anode materials for sodium-ion batteries(SIBs)due to their high theoretical capacity and low synthesis cost.However,is-sues such as poor cyclic stability and rate per...Transition metal sulfides are considered promising anode materials for sodium-ion batteries(SIBs)due to their high theoretical capacity and low synthesis cost.However,is-sues such as poor cyclic stability and rate performance,arising from volume expansion and structural degradation,remain sig-nificant challenges.We report a novel FeS_(2)/CoS_(2) heterostruc-ture embedded in a 3D carbon aerogel matrix(FeS_(2)/CoS_(2)@C)synthesized by a cross-linking and vulcanization process.The resulting core-shell structure,with bimetallic FeS_(2)/CoS_(2) nano-particles encapsulated in a conductive carbon shell,effectively reduces the adverse effects of volume changes during sodiation/desodiation cycles.The 3D porous carbon network increases both ion and electron diffusion,while preventing agglomeration of the active material and maintaining interface integrity.The FeS_(2)/CoS_(2)@C composite has an outstanding electrochemical performance,including a high specific capacity of 725 mAh g^(-1)at 0.5 A g^(-1)and an exceptional rate capability of 572 mAh g^(-1)at 10 A g^(-1).It also has remarkable cycling stability with no signific-ant capacity decay over 1000 cycles at 5 A g^(-1).展开更多
Detonation performance is crucial for evaluating the power of high explosives(HEs),and the equation of state(EOS)that accurately describes the high-temperature,high-pressure,and high-temperature,medium-pressure states...Detonation performance is crucial for evaluating the power of high explosives(HEs),and the equation of state(EOS)that accurately describes the high-temperature,high-pressure,and high-temperature,medium-pressure states of detonation products is key to assessing the damage efficiency of these energetic materials.This article examines the limitations of the VLW EOS in representing the thermodynamic states of explosive detonation gas products under high-temperature and medium-to high-pressure conditions.A new gas EOS for detonation products,called VHL(Virial-Han-Long),is proposed.The accuracy of VHL in describing gas states under high-temperature and medium-to high-pressure conditions is verified,and its performance in evaluating explosive detonation and working capabilities is explored.The results demonstrate that VHL exhibits high precision in calculating detonation performance.Subsequently,the detonation performance of three new HEs(ICM-101,ONC,and TNAZ)was calculated and compared to traditional HEs(TATB,CL-20,and HMX).The results indicate that ONC has superior detonation performance compared to the other explosives,while ICM-101 shows a detonation velocity similar to CL-20 but with slightly lower detonation pressure.The detonation characteristics of TNAZ are comparable to those of the standard HE HMX.From the perspective of products,considering the comprehensive work performance(mechanical work and detonation heat),both ONC and ICM-101demonstrate relatively superior performance.展开更多
利用超高性能混凝土(ultra high performance concrete, UHPC)材料特性,提出一种针对预制拼装桥墩的重力灌浆构造,即采用UHPC灌浆并依靠立柱自身重力完成拼接的插槽式连接构造。为研究该形式桥墩的抗震性能,设计完成了三个桥墩的拟静力...利用超高性能混凝土(ultra high performance concrete, UHPC)材料特性,提出一种针对预制拼装桥墩的重力灌浆构造,即采用UHPC灌浆并依靠立柱自身重力完成拼接的插槽式连接构造。为研究该形式桥墩的抗震性能,设计完成了三个桥墩的拟静力试验,分别为整体现浇墩Z1、新型插槽式连接墩P1及现有“I型”连接墩P2,并采用OpenSees有限元软件做模拟分析,与试验结果对比分析。结果表明:三个桥墩的破坏形式一致,均为弯曲破坏;Z1墩与P1墩滞回曲线呈梭形,滞回环较为饱满,且相同位移加载循环下的滞回路径较为吻合,P2墩接口处钢筋与混凝土间黏结滑移影响较大,导致滞回环面积减小,桥墩整体滞回耗能能力降低;P1墩的耗能能力较Z1墩和P2墩分别提升7.0%、10.7%,呈现峰值荷载小、失效速率慢、极限位移大、滞回耗能多的骨架趋势。试验结果与有限元模拟结果较为吻合,抗震性能参数差幅在10.0%以内,新型插槽式连接墩可应用于实际工程。展开更多
The impact properties of normal concrete (NC) and reinforced concrete (RC) specimens,steel fibre reinforced concrete (SFRC) specimens and RC+SFRC specimens with different steel fibre dosages were investigated with the...The impact properties of normal concrete (NC) and reinforced concrete (RC) specimens,steel fibre reinforced concrete (SFRC) specimens and RC+SFRC specimens with different steel fibre dosages were investigated with the drop-weight impact test recommended by ACI Committee 544.The results indicate that the number of blows to final failure is greatly increased by addition of steel fibres.Moreover,the combination of steel fibres and steel rebars demonstrates a significant positive composite effect on the impact resistance,which results in the improvement in impact toughness of concrete specimens.In the view of variation of impact test results,the two-parameter Weibull distribution was adopted to analyze the experimental data.It is proved that the probabilistic distributions of the blows to first crack and to final failure of six types of samples approximately follow two-parameter Weibull distribution.展开更多
文摘Because of an unfortunate mistake by authors,the Project(5227010679)of Foundation item was wrong.The corrected Project is shown as follows:Project(52271073).
文摘Transition metal sulfides are considered promising anode materials for sodium-ion batteries(SIBs)due to their high theoretical capacity and low synthesis cost.However,is-sues such as poor cyclic stability and rate performance,arising from volume expansion and structural degradation,remain sig-nificant challenges.We report a novel FeS_(2)/CoS_(2) heterostruc-ture embedded in a 3D carbon aerogel matrix(FeS_(2)/CoS_(2)@C)synthesized by a cross-linking and vulcanization process.The resulting core-shell structure,with bimetallic FeS_(2)/CoS_(2) nano-particles encapsulated in a conductive carbon shell,effectively reduces the adverse effects of volume changes during sodiation/desodiation cycles.The 3D porous carbon network increases both ion and electron diffusion,while preventing agglomeration of the active material and maintaining interface integrity.The FeS_(2)/CoS_(2)@C composite has an outstanding electrochemical performance,including a high specific capacity of 725 mAh g^(-1)at 0.5 A g^(-1)and an exceptional rate capability of 572 mAh g^(-1)at 10 A g^(-1).It also has remarkable cycling stability with no signific-ant capacity decay over 1000 cycles at 5 A g^(-1).
基金supported by the National Natural Science Foundation of China(Gant Nos.11372291 and 11902298)。
文摘Detonation performance is crucial for evaluating the power of high explosives(HEs),and the equation of state(EOS)that accurately describes the high-temperature,high-pressure,and high-temperature,medium-pressure states of detonation products is key to assessing the damage efficiency of these energetic materials.This article examines the limitations of the VLW EOS in representing the thermodynamic states of explosive detonation gas products under high-temperature and medium-to high-pressure conditions.A new gas EOS for detonation products,called VHL(Virial-Han-Long),is proposed.The accuracy of VHL in describing gas states under high-temperature and medium-to high-pressure conditions is verified,and its performance in evaluating explosive detonation and working capabilities is explored.The results demonstrate that VHL exhibits high precision in calculating detonation performance.Subsequently,the detonation performance of three new HEs(ICM-101,ONC,and TNAZ)was calculated and compared to traditional HEs(TATB,CL-20,and HMX).The results indicate that ONC has superior detonation performance compared to the other explosives,while ICM-101 shows a detonation velocity similar to CL-20 but with slightly lower detonation pressure.The detonation characteristics of TNAZ are comparable to those of the standard HE HMX.From the perspective of products,considering the comprehensive work performance(mechanical work and detonation heat),both ONC and ICM-101demonstrate relatively superior performance.
文摘利用超高性能混凝土(ultra high performance concrete, UHPC)材料特性,提出一种针对预制拼装桥墩的重力灌浆构造,即采用UHPC灌浆并依靠立柱自身重力完成拼接的插槽式连接构造。为研究该形式桥墩的抗震性能,设计完成了三个桥墩的拟静力试验,分别为整体现浇墩Z1、新型插槽式连接墩P1及现有“I型”连接墩P2,并采用OpenSees有限元软件做模拟分析,与试验结果对比分析。结果表明:三个桥墩的破坏形式一致,均为弯曲破坏;Z1墩与P1墩滞回曲线呈梭形,滞回环较为饱满,且相同位移加载循环下的滞回路径较为吻合,P2墩接口处钢筋与混凝土间黏结滑移影响较大,导致滞回环面积减小,桥墩整体滞回耗能能力降低;P1墩的耗能能力较Z1墩和P2墩分别提升7.0%、10.7%,呈现峰值荷载小、失效速率慢、极限位移大、滞回耗能多的骨架趋势。试验结果与有限元模拟结果较为吻合,抗震性能参数差幅在10.0%以内,新型插槽式连接墩可应用于实际工程。
基金Project(50578026) supported by the National Natural Science Foundation of ChinaProject supported by FCT (SFRH/BPD/22680/2005)and Research Center of Mathematics of the University of Minho through the FCT Pluriannual Funding Program
文摘The impact properties of normal concrete (NC) and reinforced concrete (RC) specimens,steel fibre reinforced concrete (SFRC) specimens and RC+SFRC specimens with different steel fibre dosages were investigated with the drop-weight impact test recommended by ACI Committee 544.The results indicate that the number of blows to final failure is greatly increased by addition of steel fibres.Moreover,the combination of steel fibres and steel rebars demonstrates a significant positive composite effect on the impact resistance,which results in the improvement in impact toughness of concrete specimens.In the view of variation of impact test results,the two-parameter Weibull distribution was adopted to analyze the experimental data.It is proved that the probabilistic distributions of the blows to first crack and to final failure of six types of samples approximately follow two-parameter Weibull distribution.
