The treatment of contaminated soil is a crucial issue in geotechnical and environmental engineering.This study proposes to incorporate appropriate polypropylene fibers and cements as an effective method to treat heavy...The treatment of contaminated soil is a crucial issue in geotechnical and environmental engineering.This study proposes to incorporate appropriate polypropylene fibers and cements as an effective method to treat heavy metal contaminated soil(HMCS).The objective of this paper is to investigate the effects of fiber content,fiber length,cement content,curing time,heavy metal types and concentration on the mechanical properties of soils.To this end,a series of direct shear test,unconfined compression strength(UCS)test,dry-wet cycle and freeze-thaw cycle test are performed.The results confirm that the appropriate reinforcement of polypropylene fibers and cement is an effective way to recycle HMCS as substitutable fillers in roadbed,which exhibits benefits in environment and economy development.展开更多
39 soil samples surrounding a lead-zinc mining area in Guangxi were collected,and the contents of Pb,Hg,Cd,Cr,As,Cu,Zn,and Ni were determined to investigate the pollution characteristics and sources of heavy metals.Ar...39 soil samples surrounding a lead-zinc mining area in Guangxi were collected,and the contents of Pb,Hg,Cd,Cr,As,Cu,Zn,and Ni were determined to investigate the pollution characteristics and sources of heavy metals.ArcGIS inverse distance weight difference method was used to analyze the characteristics of pollution distribution,and single-factor pollution index,Nemerow comprehensive pollution index,ground accumulation index,and potential ecological risk index were selected to evaluate the characteristics of heavy metal pollution.Based on correlation analysis,the absolute principal component-multiple linear regression(APCS-MLR)and positive definite matrix factorization(PMF)models were used to analyze the sources of soil heavy metals.The results showed that the average concentrations of all eight heavy metals exceeded both national and Guangxi soil background values.Hg,Cd,and Zn exhibited high variation(greater than 0.5),indicating significant external disturbances,and their spatial distribution was closely related to mining activity locations.The single-factor pollution index evaluation indicated varying degrees of pollution risk for Cd,Zn,and As,with Cd and Zn being the most severe pollutants,as 69.23%and 30.77%of the samples fell into the moderate pollution or higher category.The geoaccumulation index analysis ranked the mean pollution levels of the eight elements as follows:Zn>Cd>Ni>Pb>Cu>Cr>Hg>As,with Cd and Zn showing the most severe contamination,and 51.28%of the samples exhibiting moderate or higher pollution levels.The Nemerow comprehensive pollution index evaluation showed that 74.35%of soil samples were classified as moderate to heavy pollution.The potential ecological risk index assessment indicated significant ecological risks posed by Cd and Zn,with 82.05%and 5.12%of the samples classified as causing strong to extreme ecological risks,respectively.The source apportionment analysis revealed minor differences between the two models.The APCS-MLR model identified three pollution sources and their contribution rates:anthropogenic mining sources(31.13%),parent material sources(40.38%),and unidentified sources(28.49%).The PMF model identified three pollution sources with contribution rates of anthropogenic mining sources(26.10%),parent material sources(46.96%),and a combined traffic and agricultural source(26.61%).Pb,Hg,Cd,and Zn mainly originated from mining activities;Cr,As,and Ni were primarily derived from the parent material,while Cu was predominantly attributed to traffic and agricultural sources.These findings provide a scientific basis for the prevention and control of heavy metal pollution in mining areas.展开更多
Some key factors on the heavy metals removal efficiencies were studied when soil washing technology was used in the remediation of soils contaminated by multiple heavy metals. The results show that the dissolubilities...Some key factors on the heavy metals removal efficiencies were studied when soil washing technology was used in the remediation of soils contaminated by multiple heavy metals. The results show that the dissolubilities of Cu and Zn are promoted by humic acids, but Pb and Cd are inhibited by humic acids; heavy metals in the clay are more difficult to be extracted than silt; the strong acidic soils can cause the protonation of EDTA and weaken its extracting ability; EDTA is effective for extracting Pb and Cd, while oxalate (OX) is effective for extracting Cu and Zn; and biosurfactant can be used as additive to improve the removal of some particular heavy metals.展开更多
Total concentrations of arsenic, lead, cadmium, mercury, nickel, chromium, and copper in the soils from near a coal mine area in southwest Guizhou, China, were measured to evaluate the level of contamination, and the ...Total concentrations of arsenic, lead, cadmium, mercury, nickel, chromium, and copper in the soils from near a coal mine area in southwest Guizhou, China, were measured to evaluate the level of contamination, and the potential ecological risks posed by the heavy metals were quantitatively estimated. Results reveal that all heavy metals/metalloid exceeded the background values for soil environmental quality of heavy metals in Guizhou area. Geo-accumulation index(I_(geo)) showed that arsenic had the highest contamination level(I_(geo)=4) among the seven heavy metals/metalloid, and the contamination levels of mercury and lead were also relatively high(I_(geo)=3). Pearson correlation and cluster analysis identified that mercury, copper and arsenic had a relationship, and their presence might be mainly related to mining activity, coal and oil combustion, and vehicle emissions. Improved Nemerow index indicated that the overall level of heavy metal contamination in the studied area ranged from moderately–heavily contaminated to heavily contaminated level. Potential ecological risk index(R_I) analysis manifested that the whole ecological risk level ranged from high degree to very high degree(325.30≤R_I≤801.02) in the studied soil samples, and the potential ecological risk factors (E_r^i) of heavy metals/metalloid were as follows: Hg > As > Cd > Pb > Cu > Ni > Cr, and the E_r^i of Hg and As reached very high risk grade.展开更多
A land use- and geographical information system-based framework was presented for potential human health risk analysis using soil sampling data obtained in Zhuzhou City, Hunan Province, China. The results show that he...A land use- and geographical information system-based framework was presented for potential human health risk analysis using soil sampling data obtained in Zhuzhou City, Hunan Province, China. The results show that heavy metal content in soil significantly differs among different land use types. In total, 8.3% of the study area has a hazard index(HI) above the threshold of 1.0. High HIs are recorded mainly for industrial areas. Arsenic((29)87%) and the soil ingestion pathway(about 76%) contribute most to the HI. The mean standardized error and root-mean-square standardized error data indicate that the land use-based simulation method provides more accurate estimates than the classic method, which applies only geostatistical analysis to entire study area and disregards land use information. The findings not only highlight the significance of industrial land use, arsenic and the soil ingestion exposure pathway, but also indicate that evaluating different land use-types can spatially identify areas of greater concern for human health and better identify health risks.展开更多
Solidification/stabilization （S/S） is one of the most effective methods of dealing with heavy metal contaminated soils. The effects of cyclic wetting and drying on solidified/stabilized contaminated soils were inves...Solidification/stabilization （S/S） is one of the most effective methods of dealing with heavy metal contaminated soils. The effects of cyclic wetting and drying on solidified/stabilized contaminated soils were investigated. A series of test program, unconfined compressive strength （UCS） test, TCLP leaching test and scanning electron microscopy （SEM） test, were performed on lead and zinc contaminated soils solidified/stabilized by fly ash. Test results show that UCS and the leaching characteristics of heavy metal ions of S/S contaminated soils are significantly improved with the increase of fly ash content. UCS of S/S soils firstly increases with the increase of the times of drying and wetting cycles, after reaching the peak, it decreases with it. When the pollutant content is lower （1 000 mg/kg）, the TCLP concentration first slightly decreases under cyclic drying and wetting, then increases, but the change is minor. The TCLP concentration is higher under a high pollutant content of 5 000 mg/kg, and increases with the increase of the times of drying and wetting cycles. The results of scanning electron microscopy （SEM） test are consistent with UCS tests and TCLP leaching tests, which reveals the micro-mechanism of the variations of engineering properties of stabilized contaminated soils after drying and wetting cycles.展开更多
The present study demonstrates the distribution of heavy metals in soils of Almalyk mining and smelting industrial area along the 5 transects.The study area is located in Almalyk,Uzbekistan,where the intensification o...The present study demonstrates the distribution of heavy metals in soils of Almalyk mining and smelting industrial area along the 5 transects.The study area is located in Almalyk,Uzbekistan,where the intensification of industrial enterprises negatively impact on the environment.The distribution of 17 heavy metals (Cu,Zn,Pb,Sc,V,Cr,Co,Ni,Ga,Rb,Sr,Y,Zr,Nb, Ba,Th,and U)were studied in 21 sampling locations (21×3=63 soil samples)along the 5 radial transects with the total length of 60 km downwind展开更多
Biochar-derived dissolved organic matter(BCDOM),an essential component of biochar,plays a vital role in regulating the physicochemical and biological properties of soils during biochar application.However,the influenc...Biochar-derived dissolved organic matter(BCDOM),an essential component of biochar,plays a vital role in regulating the physicochemical and biological properties of soils during biochar application.However,the influence of BCDOM on soil organisms has not been clearly explained.Hence,this review aims to discuss the factors affecting BCDOM and its interaction with soil substances including organic pollutants,heavy metals,and microorganisms.Results displayed that the quantity of BCDOM ranges from 0.17 to 37.03 mg/g,which was influenced by feedstock,preparation methods of biochar,and extraction methods.With the decrease in lignin content of feedstocks,carbonization temperature,and acidity of extraction solution,the content of BCDOM increased.Through complexation and adsorption,protein-like components in BCDOM interact with heavy metals,promoting the adsorption and immobilization of heavy metals onto biochar.Furthermore,BCDOM enhances the adsorption of organic pollutants by biochar throughπ−πinteractions,hydrogen bonding,and redox processes.More importantly,BCDOM promotes plant growth by enhancing microbial activities,providing nutrients,and improving soil properties.However,the transport and fate of BCDOM in soil have not been well studied,and more researches are needed to explore the interaction mechanisms between BCDOM and soil organisms.展开更多
基金Projects(51778386,51708377,51608059)supported by the National Natural Science Foundation of ChinaProject(BK20170339)supported by Natural Science Foundation of Jiangsu Province,China+2 种基金Project(17KJB560008)supported by Natural Science Fund for Colleges and Universities in Jiangsu Province,ChinaProjects(KFJ170106,KFJ180105)supported by Open Fund of National Engineering Laboratory of Highway Maintenance Technology(Changsha University of Science&Technology),ChinaProjects(2016ZD18,2017ZD002)supported by Jiangsu Provincial Department of Housing,Urban-Rural Development,China。
文摘The treatment of contaminated soil is a crucial issue in geotechnical and environmental engineering.This study proposes to incorporate appropriate polypropylene fibers and cements as an effective method to treat heavy metal contaminated soil(HMCS).The objective of this paper is to investigate the effects of fiber content,fiber length,cement content,curing time,heavy metal types and concentration on the mechanical properties of soils.To this end,a series of direct shear test,unconfined compression strength(UCS)test,dry-wet cycle and freeze-thaw cycle test are performed.The results confirm that the appropriate reinforcement of polypropylene fibers and cement is an effective way to recycle HMCS as substitutable fillers in roadbed,which exhibits benefits in environment and economy development.
文摘39 soil samples surrounding a lead-zinc mining area in Guangxi were collected,and the contents of Pb,Hg,Cd,Cr,As,Cu,Zn,and Ni were determined to investigate the pollution characteristics and sources of heavy metals.ArcGIS inverse distance weight difference method was used to analyze the characteristics of pollution distribution,and single-factor pollution index,Nemerow comprehensive pollution index,ground accumulation index,and potential ecological risk index were selected to evaluate the characteristics of heavy metal pollution.Based on correlation analysis,the absolute principal component-multiple linear regression(APCS-MLR)and positive definite matrix factorization(PMF)models were used to analyze the sources of soil heavy metals.The results showed that the average concentrations of all eight heavy metals exceeded both national and Guangxi soil background values.Hg,Cd,and Zn exhibited high variation(greater than 0.5),indicating significant external disturbances,and their spatial distribution was closely related to mining activity locations.The single-factor pollution index evaluation indicated varying degrees of pollution risk for Cd,Zn,and As,with Cd and Zn being the most severe pollutants,as 69.23%and 30.77%of the samples fell into the moderate pollution or higher category.The geoaccumulation index analysis ranked the mean pollution levels of the eight elements as follows:Zn>Cd>Ni>Pb>Cu>Cr>Hg>As,with Cd and Zn showing the most severe contamination,and 51.28%of the samples exhibiting moderate or higher pollution levels.The Nemerow comprehensive pollution index evaluation showed that 74.35%of soil samples were classified as moderate to heavy pollution.The potential ecological risk index assessment indicated significant ecological risks posed by Cd and Zn,with 82.05%and 5.12%of the samples classified as causing strong to extreme ecological risks,respectively.The source apportionment analysis revealed minor differences between the two models.The APCS-MLR model identified three pollution sources and their contribution rates:anthropogenic mining sources(31.13%),parent material sources(40.38%),and unidentified sources(28.49%).The PMF model identified three pollution sources with contribution rates of anthropogenic mining sources(26.10%),parent material sources(46.96%),and a combined traffic and agricultural source(26.61%).Pb,Hg,Cd,and Zn mainly originated from mining activities;Cr,As,and Ni were primarily derived from the parent material,while Cu was predominantly attributed to traffic and agricultural sources.These findings provide a scientific basis for the prevention and control of heavy metal pollution in mining areas.
基金Project(20050532009) supported by the Doctoral Foundation of Ministry of Education of ChinaProjects(2006BAD03A1704, 2006BAD03A1706) supported by the National 11th-Five Technology Supporting Project
文摘Some key factors on the heavy metals removal efficiencies were studied when soil washing technology was used in the remediation of soils contaminated by multiple heavy metals. The results show that the dissolubilities of Cu and Zn are promoted by humic acids, but Pb and Cd are inhibited by humic acids; heavy metals in the clay are more difficult to be extracted than silt; the strong acidic soils can cause the protonation of EDTA and weaken its extracting ability; EDTA is effective for extracting Pb and Cd, while oxalate (OX) is effective for extracting Cu and Zn; and biosurfactant can be used as additive to improve the removal of some particular heavy metals.
基金Project(21467005)supported by the National Natural Science Foundation of China
文摘Total concentrations of arsenic, lead, cadmium, mercury, nickel, chromium, and copper in the soils from near a coal mine area in southwest Guizhou, China, were measured to evaluate the level of contamination, and the potential ecological risks posed by the heavy metals were quantitatively estimated. Results reveal that all heavy metals/metalloid exceeded the background values for soil environmental quality of heavy metals in Guizhou area. Geo-accumulation index(I_(geo)) showed that arsenic had the highest contamination level(I_(geo)=4) among the seven heavy metals/metalloid, and the contamination levels of mercury and lead were also relatively high(I_(geo)=3). Pearson correlation and cluster analysis identified that mercury, copper and arsenic had a relationship, and their presence might be mainly related to mining activity, coal and oil combustion, and vehicle emissions. Improved Nemerow index indicated that the overall level of heavy metal contamination in the studied area ranged from moderately–heavily contaminated to heavily contaminated level. Potential ecological risk index(R_I) analysis manifested that the whole ecological risk level ranged from high degree to very high degree(325.30≤R_I≤801.02) in the studied soil samples, and the potential ecological risk factors (E_r^i) of heavy metals/metalloid were as follows: Hg > As > Cd > Pb > Cu > Ni > Cr, and the E_r^i of Hg and As reached very high risk grade.
基金Project(51204074)supported by the National Natural Science Foundation of ChinaProjects(201309051,PM-zx021-201212-003,PM-zx021-201106-031)supported by the National Environmental Protection Public Welfare Industry Targeted Research Fund,China
文摘A land use- and geographical information system-based framework was presented for potential human health risk analysis using soil sampling data obtained in Zhuzhou City, Hunan Province, China. The results show that heavy metal content in soil significantly differs among different land use types. In total, 8.3% of the study area has a hazard index(HI) above the threshold of 1.0. High HIs are recorded mainly for industrial areas. Arsenic((29)87%) and the soil ingestion pathway(about 76%) contribute most to the HI. The mean standardized error and root-mean-square standardized error data indicate that the land use-based simulation method provides more accurate estimates than the classic method, which applies only geostatistical analysis to entire study area and disregards land use information. The findings not only highlight the significance of industrial land use, arsenic and the soil ingestion exposure pathway, but also indicate that evaluating different land use-types can spatially identify areas of greater concern for human health and better identify health risks.
基金Foundation item： Projects（41172273, 40802079, 51108288） supported by the National Natural Science Foundation of China Project（KLE-TJGE-B1106） supported by the Opening Fund of Key Laboratory of Geotechnical and Underground Engineering of Ministry of Education （Tongji University）, China
文摘Solidification/stabilization （S/S） is one of the most effective methods of dealing with heavy metal contaminated soils. The effects of cyclic wetting and drying on solidified/stabilized contaminated soils were investigated. A series of test program, unconfined compressive strength （UCS） test, TCLP leaching test and scanning electron microscopy （SEM） test, were performed on lead and zinc contaminated soils solidified/stabilized by fly ash. Test results show that UCS and the leaching characteristics of heavy metal ions of S/S contaminated soils are significantly improved with the increase of fly ash content. UCS of S/S soils firstly increases with the increase of the times of drying and wetting cycles, after reaching the peak, it decreases with it. When the pollutant content is lower （1 000 mg/kg）, the TCLP concentration first slightly decreases under cyclic drying and wetting, then increases, but the change is minor. The TCLP concentration is higher under a high pollutant content of 5 000 mg/kg, and increases with the increase of the times of drying and wetting cycles. The results of scanning electron microscopy （SEM） test are consistent with UCS tests and TCLP leaching tests, which reveals the micro-mechanism of the variations of engineering properties of stabilized contaminated soils after drying and wetting cycles.
文摘The present study demonstrates the distribution of heavy metals in soils of Almalyk mining and smelting industrial area along the 5 transects.The study area is located in Almalyk,Uzbekistan,where the intensification of industrial enterprises negatively impact on the environment.The distribution of 17 heavy metals (Cu,Zn,Pb,Sc,V,Cr,Co,Ni,Ga,Rb,Sr,Y,Zr,Nb, Ba,Th,and U)were studied in 21 sampling locations (21×3=63 soil samples)along the 5 radial transects with the total length of 60 km downwind
基金Project(2020YFC1908802)supported by the National Key Research and Development Project of China。
文摘Biochar-derived dissolved organic matter(BCDOM),an essential component of biochar,plays a vital role in regulating the physicochemical and biological properties of soils during biochar application.However,the influence of BCDOM on soil organisms has not been clearly explained.Hence,this review aims to discuss the factors affecting BCDOM and its interaction with soil substances including organic pollutants,heavy metals,and microorganisms.Results displayed that the quantity of BCDOM ranges from 0.17 to 37.03 mg/g,which was influenced by feedstock,preparation methods of biochar,and extraction methods.With the decrease in lignin content of feedstocks,carbonization temperature,and acidity of extraction solution,the content of BCDOM increased.Through complexation and adsorption,protein-like components in BCDOM interact with heavy metals,promoting the adsorption and immobilization of heavy metals onto biochar.Furthermore,BCDOM enhances the adsorption of organic pollutants by biochar throughπ−πinteractions,hydrogen bonding,and redox processes.More importantly,BCDOM promotes plant growth by enhancing microbial activities,providing nutrients,and improving soil properties.However,the transport and fate of BCDOM in soil have not been well studied,and more researches are needed to explore the interaction mechanisms between BCDOM and soil organisms.
