Accurate insight into the heat generation rate(HGR) of lithium-ion batteries(LIBs) is one of key issues for battery management systems to formulate thermal safety warning strategies in advance.For this reason,this pap...Accurate insight into the heat generation rate(HGR) of lithium-ion batteries(LIBs) is one of key issues for battery management systems to formulate thermal safety warning strategies in advance.For this reason,this paper proposes a novel physics-informed neural network(PINN) approach for HGR estimation of LIBs under various driving conditions.Specifically,a single particle model with thermodynamics(SPMT) is first constructed for extracting the critical physical knowledge related with battery HGR.Subsequently,the surface concentrations of positive and negative electrodes in battery SPMT model are integrated into the bidirectional long short-term memory(BiLSTM) networks as physical information.And combined with other feature variables,a novel PINN approach to achieve HGR estimation of LIBs with higher accuracy is constituted.Additionally,some critical hyperparameters of BiLSTM used in PINN approach are determined through Bayesian optimization algorithm(BOA) and the results of BOA-based BiLSTM are compared with other traditional BiLSTM/LSTM networks.Eventually,combined with the HGR data generated from the validated virtual battery,it is proved that the proposed approach can well predict the battery HGR under the dynamic stress test(DST) and worldwide light vehicles test procedure(WLTP),the mean absolute error under DST is 0.542 kW/m^(3),and the root mean square error under WLTP is1.428 kW/m^(3)at 25℃.Lastly,the investigation results of this paper also show a new perspective in the application of the PINN approach in battery HGR estimation.展开更多
Heat generated by electric current in a quantum dot device contacting a phonon bath is studied using the non- equilibrium Green function technique. Spin-polarized current is generated owing to the Zeeman splitting of ...Heat generated by electric current in a quantum dot device contacting a phonon bath is studied using the non- equilibrium Green function technique. Spin-polarized current is generated owing to the Zeeman splitting of the dot level. The current＇s strength and the spin polarization are further manipulated by changing the frequency of an applied photon field and the ferromagnetism on the leads. We find that the associated heat by this spin- polarized current emerges even if the bias voltage is smaller than the phonon energy quanta and obvious negative differential of the heat generation develops when the photon frequency exceeds that of the phonon. It is also found that both the strength and the resonant peaks＇ position of the heat generation can be tuned by changing the value and the arrangement configurations of the magnetic moments of the two leads, and then provides an effective method to generate large spin-polarized current with weak heat. Such a result may be useful in designing low energy consumption spintronic devices.展开更多
1.Introduction With the superior performance of high energy density,lightweight and long life span,lithium-ion battery(LIB)are perceived as an attractive and reliable power source for modern-used portable electronics,...1.Introduction With the superior performance of high energy density,lightweight and long life span,lithium-ion battery(LIB)are perceived as an attractive and reliable power source for modern-used portable electronics,ecofriendly electric vehicles and power distribution,and thereby a remarkable solution to assuage energy dependence on fossil fuel and environmental concern.Nevertheless,the unexpected Li plating together with the Li dendrites growth on graphite anode surface has been a profound hindrance to the practical application of LIB,of which induces inferior Coulombic efficiency,poor lifespan and safety concern[1].展开更多
We study theoretically the heat originated from electron-phonon coupling in a spintronic device composed of a semi- conductor quantum dot attached to one spin battery and one ferromagnetic lead. It is found that the p...We study theoretically the heat originated from electron-phonon coupling in a spintronic device composed of a semi- conductor quantum dot attached to one spin battery and one ferromagnetic lead. It is found that the phenomenon of the negative differential of the heat current, which has previously been predicted in the charge-based device, disappears due to the Pauli exclusion principle resulted from the presence of the spin battery. Under some conditions, huge heat in the heat generation induced by resonant phonon emitting processes also disappears in this spin-based device. Furthermore, we find that the ferromagnetism of the lead can be used to effectively adjust the magnitude of the heat current in different dot level ranges. The proposed system is realizable by current technology and may be useful in designing high-efficiency spintronic components.展开更多
The Monte Carlo simulation is performed to investigate the quantum mechanical （QM） effects on heat generation in nano-scale metal oxide semiconductor field effect transistors （MOSFETs） by solving the quantum Boltz...The Monte Carlo simulation is performed to investigate the quantum mechanical （QM） effects on heat generation in nano-scale metal oxide semiconductor field effect transistors （MOSFETs） by solving the quantum Boltzmann equation. The influence of QM effects both in real space and K space on the heat generation is investigated.展开更多
The methods and techniques commonly used in investigating the change of entropy and heat generation in Li cells/batteries are introduced, as are the measurements, calculations and purposes. The changes of entropy and ...The methods and techniques commonly used in investigating the change of entropy and heat generation in Li cells/batteries are introduced, as are the measurements, calculations and purposes. The changes of entropy and heat generation are concomitant with the use of Li ceUs/batteries. In order to improve the management and the application of Li cells/batteries, especially for large scale power batteries, the quantitative investigations of the change of entropy and heat generating are necessary.展开更多
The extra heat generation in spin transport is usually interpreted in terms of the spin relaxation. Reformulating the heat generation rate, we find alternative current-force pairs without cross effects, which enable u...The extra heat generation in spin transport is usually interpreted in terms of the spin relaxation. Reformulating the heat generation rate, we find alternative current-force pairs without cross effects, which enable us to interpret the product of each pair as a distinct mechanism of heat generation. The results show that the spin-dependent part of the heat generation includes two terms. One is proportional to the square of the spin accumulation and arises from the spin relaxation. However, the other is proportional to the square of the spin-accumulation gradient and should be attributed to another mechanism, the spin diffusion. We illustrate the characteristics of the two mechanisms in a typical spin valve with a finite nonmagnetic spacer layer.展开更多
To obtain intrinsic overcharge boundary and investigate overcharge mechanism,here we propose an innovative method,the step overcharge test,to reduce the thermal crossover and distinguish the overcharge thermal behavio...To obtain intrinsic overcharge boundary and investigate overcharge mechanism,here we propose an innovative method,the step overcharge test,to reduce the thermal crossover and distinguish the overcharge thermal behavior,including 5%state of charge(SOC)with small current overcharge and resting until the temperature equilibrium under adiabatic conditions.The intrinsic thermal response and the self-excitation behaviour are analysed through temperature and voltage changes during the step overcharge period.Experimental results show that the deintercalated state of the cathode is highly correlated to self-heating parasitic reactions.Before reaching the upper limit of Negative/Positive(N/P)ratio,the temperature changes little,the heat generation is significantly induced by the reversible heat(endothermic)and ohmic heat,which could balance each other.Following that the lithium metal is gradually deposited on the surface of the anode and reacts with electrolyte upon overcharge,inducing selfheating side reaction.However,this spontaneous thermal reaction could be“self-extinguished”.When the lithium in cathode is completely deintercalated,the boundary point of overcharge is about 4.7 V(~148%SOC,>40℃),and from this point,the self-heating behaviour could be continuously triggered until thermal runaway(TR)without additional overcharge.The whole static and spontaneous process lasts for 115 h and the side reaction heat is beyond 320,000 J.The continuous self-excitation behavior inside the battery is attributed to the interaction between the highly oxidized cathode and the solvent,which leads to the dissolution of metal ions.The dissolved metal ions destroy the SEI(solid electrolyte interphase)film on the surface of the deposited Li of anode,which induces the thermal reaction between lithium metal and the solvent.The interaction between cathode,the deposited Li of anode,and solvent promotes the temperature of the battery to rise slowly.When the temperature of the battery reaches more than 60℃,the reaction between lithium metal and solvent is accelerated.After the temperature rises rapidly to the melting point of the separator,it triggers the thermal runaway of the battery due to the short circuit of the battery.展开更多
The customarily discarded exhaust from the fossil fuel-based power plants of the off-grid mines holds the thermal potential to fulfill the heating requirement of the underground operation.This present research fills i...The customarily discarded exhaust from the fossil fuel-based power plants of the off-grid mines holds the thermal potential to fulfill the heating requirement of the underground operation.This present research fills in an important research gap by investigating the coupling effect between a diesel exhaust heat recovery and an intake air heating system employed in a remote mine.An integrative approach comprising analytical,numerical,and experimental assessment has been adapted.The novel analytical model developed here establishes the reliability of the proposed mine heating system by providing comparative analysis between a coupled and a decoupled system.The effect of working fluid variation has been examined by the numerical analysis and the possible improvement has been identified.Experimental investigations present a demonstration of the successful lab-scale implementation of the concept and validate the numerical and analytical models developed.Successful deployment of the fully coupled mine heating system proposed here will assist the mining industry on its journey towards energy-efficient,and sustainable mining practices through nearly 70%reduction in fossil fuel consumption for heating intentions.展开更多
With the increasing attention paid to battery technology,the microscopic reaction mechanism and macroscopic heat transfer process of lithium-ion batteries have been further studied and understood from both academic an...With the increasing attention paid to battery technology,the microscopic reaction mechanism and macroscopic heat transfer process of lithium-ion batteries have been further studied and understood from both academic and industrial perspectives.Temperature,as one of the key parameters in the physical fra mework of batteries,affects the performa nce of the multi-physical fields within the battery,a nd its effective control is crucial.Since the heat generation in the battery is determined by the real-time operating conditions,the battery temperature is essentially controlled by the real-time heat dissipation conditions provided by the battery thermal management system.Conventional battery thermal management systems have basic temperature control capabilities for most conventional application scenarios.However,with the current development of la rge-scale,integrated,and intelligent battery technology,the adva ncement of battery thermal management technology will pay more attention to the effective control of battery temperature under sophisticated situations,such as high power and widely varied operating conditions.In this context,this paper presents the latest advances and representative research related to battery thermal management system.Firstly,starting from battery thermal profile,the mechanism of battery heat generation is discussed in detail.Secondly,the static characteristics of the traditional battery thermal management system are summarized.Then,considering the dynamic requirements of battery heat dissipation under complex operating conditions,the concept of adaptive battery thermal management system is proposed based on specific research cases.Finally,the main challenges for battery thermal management system in practice are identified,and potential future developments to overcome these challenges are presented and discussed.展开更多
In the last decades the interest in the biomass gasification process has increased due to the growing attention to the use of sustainable energy. Biomass is a renewable energy source and represents a valid alternative...In the last decades the interest in the biomass gasification process has increased due to the growing attention to the use of sustainable energy. Biomass is a renewable energy source and represents a valid alternative to fossil fuels. Gasification is the thermochemical conversion of an organic material into a valuable gaseous product, called syngas, and a solid product, called char. The biomass gasification represents an efficient process for the production of power and heat and the production of hydrogen and second-generation biofuels.This paper deals with the state of the art biomass gasification technologies, evaluating advantages and disadvantages, the potential use of the syngas and the application of the biomass gasification. Syngas cleaning though fundamental to evaluate any gasification technology is not included in this paper since; in the authors＇ opinion, a dedicated review is necessary.展开更多
Multiple mode calorimetry and C80 micro-calorimeter are used to investigate the impact of cathode and anode on heat generation of lithium ion battery.The thermal behaviors of LiNi_(x)Co_(y)Mn_(z)O_(2)/graphite full ce...Multiple mode calorimetry and C80 micro-calorimeter are used to investigate the impact of cathode and anode on heat generation of lithium ion battery.The thermal behaviors of LiNi_(x)Co_(y)Mn_(z)O_(2)/graphite full cell are discussed under normal operating and elevating temperature.Affected by negative entropy change,lithium intercalation presents more exotherms than deintercalation for both electrode materials.The contributions of irreversible and reversible heat to the total heat generation of graphite are evaluated.The phase transitions correlated with voltages and lithium contents are determined.Based on the analysis of half-cell,the effect of two electrodes(with the same capacity)on overall heat generation is nearly the same and anode of full cell plays a key role in charging while cathode dominates in discharging.Thermal behaviors of lithiated graphite and delithiated LiNi_(x)Co_(y)Mn_(z)O_(2) electrolyte and their coexisting system are identified to further explore their influence on battery safety.The breakdown of solid electrolyte interface(SEI)at around 82℃ is considered as a crucial factor affecting the thermal stability of full cell.The oxidation of electrolyte induced by oxygen released from cathode material turns out to be one of the main heat sources.These accurate results are of great significance to improve the existing thermal management system and provide basic data for the prediction of battery performance.展开更多
基金funded by the Artificial Intelligence Technology Project of Xi’an Science and Technology Bureau in China(No.21RGZN0014)。
文摘Accurate insight into the heat generation rate(HGR) of lithium-ion batteries(LIBs) is one of key issues for battery management systems to formulate thermal safety warning strategies in advance.For this reason,this paper proposes a novel physics-informed neural network(PINN) approach for HGR estimation of LIBs under various driving conditions.Specifically,a single particle model with thermodynamics(SPMT) is first constructed for extracting the critical physical knowledge related with battery HGR.Subsequently,the surface concentrations of positive and negative electrodes in battery SPMT model are integrated into the bidirectional long short-term memory(BiLSTM) networks as physical information.And combined with other feature variables,a novel PINN approach to achieve HGR estimation of LIBs with higher accuracy is constituted.Additionally,some critical hyperparameters of BiLSTM used in PINN approach are determined through Bayesian optimization algorithm(BOA) and the results of BOA-based BiLSTM are compared with other traditional BiLSTM/LSTM networks.Eventually,combined with the HGR data generated from the validated virtual battery,it is proved that the proposed approach can well predict the battery HGR under the dynamic stress test(DST) and worldwide light vehicles test procedure(WLTP),the mean absolute error under DST is 0.542 kW/m^(3),and the root mean square error under WLTP is1.428 kW/m^(3)at 25℃.Lastly,the investigation results of this paper also show a new perspective in the application of the PINN approach in battery HGR estimation.
基金Supported by the National Natural Science Foundation of China under Grant No 61274101
文摘Heat generated by electric current in a quantum dot device contacting a phonon bath is studied using the non- equilibrium Green function technique. Spin-polarized current is generated owing to the Zeeman splitting of the dot level. The current＇s strength and the spin polarization are further manipulated by changing the frequency of an applied photon field and the ferromagnetism on the leads. We find that the associated heat by this spin- polarized current emerges even if the bias voltage is smaller than the phonon energy quanta and obvious negative differential of the heat generation develops when the photon frequency exceeds that of the phonon. It is also found that both the strength and the resonant peaks＇ position of the heat generation can be tuned by changing the value and the arrangement configurations of the magnetic moments of the two leads, and then provides an effective method to generate large spin-polarized current with weak heat. Such a result may be useful in designing low energy consumption spintronic devices.
基金supported by the National Natural Science Foundation of China (U2033204)the China Postdoctoral Science Foundation (2021M703053)+1 种基金supported by the China National Postdoctoral Program for Innovative Talents(BX20220286)supported by Youth Innovative Promotion Association CAS (Y201768)
文摘1.Introduction With the superior performance of high energy density,lightweight and long life span,lithium-ion battery(LIB)are perceived as an attractive and reliable power source for modern-used portable electronics,ecofriendly electric vehicles and power distribution,and thereby a remarkable solution to assuage energy dependence on fossil fuel and environmental concern.Nevertheless,the unexpected Li plating together with the Li dendrites growth on graphite anode surface has been a profound hindrance to the practical application of LIB,of which induces inferior Coulombic efficiency,poor lifespan and safety concern[1].
基金supported by the National Natural Science Foundation of China(Grant No.61274101)
文摘We study theoretically the heat originated from electron-phonon coupling in a spintronic device composed of a semi- conductor quantum dot attached to one spin battery and one ferromagnetic lead. It is found that the phenomenon of the negative differential of the heat current, which has previously been predicted in the charge-based device, disappears due to the Pauli exclusion principle resulted from the presence of the spin battery. Under some conditions, huge heat in the heat generation induced by resonant phonon emitting processes also disappears in this spin-based device. Furthermore, we find that the ferromagnetism of the lead can be used to effectively adjust the magnitude of the heat current in different dot level ranges. The proposed system is realizable by current technology and may be useful in designing high-efficiency spintronic components.
基金supported by the National Key Basic Research Program of China (Grant No 2006CB302705)the National Natural Science Foundation of China (Grant No 60776068)
文摘The Monte Carlo simulation is performed to investigate the quantum mechanical （QM） effects on heat generation in nano-scale metal oxide semiconductor field effect transistors （MOSFETs） by solving the quantum Boltzmann equation. The influence of QM effects both in real space and K space on the heat generation is investigated.
文摘The methods and techniques commonly used in investigating the change of entropy and heat generation in Li cells/batteries are introduced, as are the measurements, calculations and purposes. The changes of entropy and heat generation are concomitant with the use of Li ceUs/batteries. In order to improve the management and the application of Li cells/batteries, especially for large scale power batteries, the quantitative investigations of the change of entropy and heat generating are necessary.
基金Supported by the National Natural Science Foundation of China under Grant Nos 11404013,11605003,61405003,11174020 and 11474012the Scientific Research Project of Beijing Educational Committee under Grant No KM201510011002the 2016 Graduate Research Program of Beijing Technology and Business University
文摘The extra heat generation in spin transport is usually interpreted in terms of the spin relaxation. Reformulating the heat generation rate, we find alternative current-force pairs without cross effects, which enable us to interpret the product of each pair as a distinct mechanism of heat generation. The results show that the spin-dependent part of the heat generation includes two terms. One is proportional to the square of the spin accumulation and arises from the spin relaxation. However, the other is proportional to the square of the spin-accumulation gradient and should be attributed to another mechanism, the spin diffusion. We illustrate the characteristics of the two mechanisms in a typical spin valve with a finite nonmagnetic spacer layer.
基金funded by the National Key Research and Development Program of China(2018YFB0104400)supported by the Beijing Natural Science Foundation(2214066)。
文摘To obtain intrinsic overcharge boundary and investigate overcharge mechanism,here we propose an innovative method,the step overcharge test,to reduce the thermal crossover and distinguish the overcharge thermal behavior,including 5%state of charge(SOC)with small current overcharge and resting until the temperature equilibrium under adiabatic conditions.The intrinsic thermal response and the self-excitation behaviour are analysed through temperature and voltage changes during the step overcharge period.Experimental results show that the deintercalated state of the cathode is highly correlated to self-heating parasitic reactions.Before reaching the upper limit of Negative/Positive(N/P)ratio,the temperature changes little,the heat generation is significantly induced by the reversible heat(endothermic)and ohmic heat,which could balance each other.Following that the lithium metal is gradually deposited on the surface of the anode and reacts with electrolyte upon overcharge,inducing selfheating side reaction.However,this spontaneous thermal reaction could be“self-extinguished”.When the lithium in cathode is completely deintercalated,the boundary point of overcharge is about 4.7 V(~148%SOC,>40℃),and from this point,the self-heating behaviour could be continuously triggered until thermal runaway(TR)without additional overcharge.The whole static and spontaneous process lasts for 115 h and the side reaction heat is beyond 320,000 J.The continuous self-excitation behavior inside the battery is attributed to the interaction between the highly oxidized cathode and the solvent,which leads to the dissolution of metal ions.The dissolved metal ions destroy the SEI(solid electrolyte interphase)film on the surface of the deposited Li of anode,which induces the thermal reaction between lithium metal and the solvent.The interaction between cathode,the deposited Li of anode,and solvent promotes the temperature of the battery to rise slowly.When the temperature of the battery reaches more than 60℃,the reaction between lithium metal and solvent is accelerated.After the temperature rises rapidly to the melting point of the separator,it triggers the thermal runaway of the battery due to the short circuit of the battery.
文摘The customarily discarded exhaust from the fossil fuel-based power plants of the off-grid mines holds the thermal potential to fulfill the heating requirement of the underground operation.This present research fills in an important research gap by investigating the coupling effect between a diesel exhaust heat recovery and an intake air heating system employed in a remote mine.An integrative approach comprising analytical,numerical,and experimental assessment has been adapted.The novel analytical model developed here establishes the reliability of the proposed mine heating system by providing comparative analysis between a coupled and a decoupled system.The effect of working fluid variation has been examined by the numerical analysis and the possible improvement has been identified.Experimental investigations present a demonstration of the successful lab-scale implementation of the concept and validate the numerical and analytical models developed.Successful deployment of the fully coupled mine heating system proposed here will assist the mining industry on its journey towards energy-efficient,and sustainable mining practices through nearly 70%reduction in fossil fuel consumption for heating intentions.
基金supported by the National Natural Science Foundation of China (No.62373224,62333013,and U23A20327)。
文摘With the increasing attention paid to battery technology,the microscopic reaction mechanism and macroscopic heat transfer process of lithium-ion batteries have been further studied and understood from both academic and industrial perspectives.Temperature,as one of the key parameters in the physical fra mework of batteries,affects the performa nce of the multi-physical fields within the battery,a nd its effective control is crucial.Since the heat generation in the battery is determined by the real-time operating conditions,the battery temperature is essentially controlled by the real-time heat dissipation conditions provided by the battery thermal management system.Conventional battery thermal management systems have basic temperature control capabilities for most conventional application scenarios.However,with the current development of la rge-scale,integrated,and intelligent battery technology,the adva ncement of battery thermal management technology will pay more attention to the effective control of battery temperature under sophisticated situations,such as high power and widely varied operating conditions.In this context,this paper presents the latest advances and representative research related to battery thermal management system.Firstly,starting from battery thermal profile,the mechanism of battery heat generation is discussed in detail.Secondly,the static characteristics of the traditional battery thermal management system are summarized.Then,considering the dynamic requirements of battery heat dissipation under complex operating conditions,the concept of adaptive battery thermal management system is proposed based on specific research cases.Finally,the main challenges for battery thermal management system in practice are identified,and potential future developments to overcome these challenges are presented and discussed.
文摘In the last decades the interest in the biomass gasification process has increased due to the growing attention to the use of sustainable energy. Biomass is a renewable energy source and represents a valid alternative to fossil fuels. Gasification is the thermochemical conversion of an organic material into a valuable gaseous product, called syngas, and a solid product, called char. The biomass gasification represents an efficient process for the production of power and heat and the production of hydrogen and second-generation biofuels.This paper deals with the state of the art biomass gasification technologies, evaluating advantages and disadvantages, the potential use of the syngas and the application of the biomass gasification. Syngas cleaning though fundamental to evaluate any gasification technology is not included in this paper since; in the authors＇ opinion, a dedicated review is necessary.
基金supported by the National Natural Science Foundation of China(No.51976209)the Fundamental Research Funds for the Central Universities(No.WK2320000040)supported by Youth Innovation Promotion Association CAS(No.Y201768)。
文摘Multiple mode calorimetry and C80 micro-calorimeter are used to investigate the impact of cathode and anode on heat generation of lithium ion battery.The thermal behaviors of LiNi_(x)Co_(y)Mn_(z)O_(2)/graphite full cell are discussed under normal operating and elevating temperature.Affected by negative entropy change,lithium intercalation presents more exotherms than deintercalation for both electrode materials.The contributions of irreversible and reversible heat to the total heat generation of graphite are evaluated.The phase transitions correlated with voltages and lithium contents are determined.Based on the analysis of half-cell,the effect of two electrodes(with the same capacity)on overall heat generation is nearly the same and anode of full cell plays a key role in charging while cathode dominates in discharging.Thermal behaviors of lithiated graphite and delithiated LiNi_(x)Co_(y)Mn_(z)O_(2) electrolyte and their coexisting system are identified to further explore their influence on battery safety.The breakdown of solid electrolyte interface(SEI)at around 82℃ is considered as a crucial factor affecting the thermal stability of full cell.The oxidation of electrolyte induced by oxygen released from cathode material turns out to be one of the main heat sources.These accurate results are of great significance to improve the existing thermal management system and provide basic data for the prediction of battery performance.
