In the hydraulic transporting process of cutter-suction mining natural gas hydrate, when the temperature-pressure equilibrium of gas hydrate is broken, gas hydrates dissociate into gas. As a result, solid-liquid two-p...In the hydraulic transporting process of cutter-suction mining natural gas hydrate, when the temperature-pressure equilibrium of gas hydrate is broken, gas hydrates dissociate into gas. As a result, solid-liquid two-phase flow(hydrate and water) transforms into gas-solid-liquid three-phase flow(methane, hydrate and water) inside the pipeline. The Euler model and CFD-PBM model were used to simulate gas-solid-liquid three-phase flow. Numerical simulation results show that the gas and solid phase gradually accumulate to the center of the pipe. Flow velocity decreases from center to boundary of the pipe along the radial direction. Comparison of numerical simulation results of two models reveals that the flow state simulated by CFD-PBM model is more uniform than that simulated by Euler model, and the main behavior of the bubble is small bubbles coalescence to large one. Comparison of numerical simulation and experimental investigation shows that the values of flow velocity and gas fraction in CFD-PBM model agree with experimental data better than those in Euler model. The proposed PBM model provides a more accurate and effective way to estimate three-phase flow state of transporting gas hydrate within the submarine pipeline.展开更多
In order to design a kind of heat exchanger suitable to the indirect-touched gas hydrate cool storage vessel, a visual observation of HCFC141b gas hydrate formation/decomposition process was presented through a self-d...In order to design a kind of heat exchanger suitable to the indirect-touched gas hydrate cool storage vessel, a visual observation of HCFC141b gas hydrate formation/decomposition process was presented through a self-designed small-scale visualization apparatus of gas hydrate cool storage. Based on the shooted photos and recorded temperatures, the formation/decomposition process of HCFC141b are described, some characteristics are concluded, and some suggestions of designing heat exchanger are indicated according to the specific characteristics of HCFC141b gas hydrate formation/decomposition process.展开更多
The mathematical and simulation models of working head in the deep-sea working environment were built to analyze the effects of cutter-suction flow,cutter-head rotating speed,cutting depth and suction port position on...The mathematical and simulation models of working head in the deep-sea working environment were built to analyze the effects of cutter-suction flow,cutter-head rotating speed,cutting depth and suction port position on the cutter-suction capacity.The efficiency of the cutter-suction is analyzed based on the analysis of the variation law of the solid-phase volume fraction of the flow field,the variation law of the velocity distribution in the flow field and the distribution law of the solid-phase concentration.The results show that the increase of cutter-suction flow can significantly improve the cutter-suction efficiency when it is less than1000m3/h.However,when it is more than1000m3/h,it is helpless.When the cutter-head rotate speed is within the range of10–25r/min,the cutter-suction efficiency stabilizes at about95%.While the speed is greater than25r/min,the cutter-suction efficiency decreases sharply with the increase of cutter-head rotate speed.With the increase of cutting depth,the cutter-suction efficiency first increases and then remains stable and finally decreases.The cutter-suction efficiency remains at about94%when the suction port position deviation ranges from0°to30°,but it has a sharply reduction when the deviation angle is more than30°.展开更多
Elastic velocities(v_p and v_s)have been widely used in estimating gas hydrate saturation in void spaces of sediments.The commonly used models are empirical equations or some physically based models,such as Wyllie’s ...Elastic velocities(v_p and v_s)have been widely used in estimating gas hydrate saturation in void spaces of sediments.The commonly used models are empirical equations or some physically based models,such as Wyllie’s time average,Effective Medium Theory(EMT),Modified Biot-Gassmann Theory by Lee(BGTL),etc.These equations or models are selective to distinct conditions.展开更多
A new experimental equipment is developed to study the relationship between gas hydrate saturation and water permeability in sediments.Water with dissolved methane is injected circularly into the sediments to form gas...A new experimental equipment is developed to study the relationship between gas hydrate saturation and water permeability in sediments.Water with dissolved methane is injected circularly into the sediments to form gas hydrate,and the gas hydrate saturation in sediment pores is measured by Time Domain Reflectometry(TDR).The experimental result shows that water permeability is barely influenced by gas hydrate when the saturation is below 30%.展开更多
Molecular dynamics simulations are performed to observe the evolutions of 512 and 51262 cage-like water clusters filled with or without a methane molecule immersed in bulk liquid water at 250 K and 230 K. The lifetime...Molecular dynamics simulations are performed to observe the evolutions of 512 and 51262 cage-like water clusters filled with or without a methane molecule immersed in bulk liquid water at 250 K and 230 K. The lifetimes of these clusters are calculated according to their Lindemann index δ (t) using the criteria of δ≥0.07. For both the filled and empty clusters, we find the dynamics of bulk water determines the lifetimes of cage-like water clusters, and that the lifetime of 512 62 cage-like cluster is the same as that of 512 cage-like cluster. Although the methane molecule indeed makes the filled cage-like cluster more stable than the empty one, the empty cage-like cluster still has chance to be long-lived compared with the filled clusters. These observations support the labile cluster hypothesis on the formation mechanisms of gas hydrates.展开更多
Carbon and oxygen isotope and dating analyses of foraminiferan in sediment cores collected from three different areas of the northern slope of the South China Sea were conducted, in order to examine the records of the...Carbon and oxygen isotope and dating analyses of foraminiferan in sediment cores collected from three different areas of the northern slope of the South China Sea were conducted, in order to examine the records of the gas hydrate decomposition events since the late Quaternary under the conditions of methane seepage. The results show that： 1） the δ13C values of the benthic foraminiferan Uvigerina spp. （size range of 0.25-0.35 ram） are from -0.212% to -0.021% and the δ180 values of the planktonic foraminiferan Globigerinoides ruber （size range of 0.25-0.35 ram） are from -0.311% to -0.060%; 2） three cores （ZD2, ZD3 and ZS5） from the bottom of a hole are aged for 11 814, 26 616 and 64 090 a corresponding to the early oxygen isotope stage （MIS） Ⅰ, Ⅲ and Ⅳ final period, respectively; 3） a negative-skewed layer of carbon isotope corresponds to that of MIS II （cold period）, whose degree of negative bias is -0.2%0; and 4） the δ13C compositions of foraminiferans are similar to those of the Blake Ridge and the Gulf of Mexico sediments of the late Quaternary. According to the analysis, the reasons for these results are that the studied area is a typical area of methane seep environment in the area during MIS II due to the global sea-level fall and sea pressure decrease. Gas hydrate is decomposed and released, and a large number of light carbon isotopes of methane are released into the ocean, dissolved to inorganic carbon （DIC） pool and recorded in the foraminiferan shells. A pyrite layer developed in the negative bias layers of the foraminiferans confirms that the δ13C of foraminiferans is more affected by methane and less by the reduction of marine productivity and early diagenesis. The use of foraminiferan δ13C could accurately determine late Quaternary hydrate release events and provide evidence for both reconstructing the geological history of methane release events and exploring natural gas hydrate.展开更多
Through analyzing the needs of seismic data processing and interpretation,a system model based on CSCW is designed.Using the technology of CSCW to build the environment of cooperative work allows the field data acquis...Through analyzing the needs of seismic data processing and interpretation,a system model based on CSCW is designed.Using the technology of CSCW to build the environment of cooperative work allows the field data acquisition to possess the functions of remote real-time guidance by experts and remote real-time processing of the data.展开更多
基金Project(51375498) supported by the National Natural Science Foundation of China
文摘In the hydraulic transporting process of cutter-suction mining natural gas hydrate, when the temperature-pressure equilibrium of gas hydrate is broken, gas hydrates dissociate into gas. As a result, solid-liquid two-phase flow(hydrate and water) transforms into gas-solid-liquid three-phase flow(methane, hydrate and water) inside the pipeline. The Euler model and CFD-PBM model were used to simulate gas-solid-liquid three-phase flow. Numerical simulation results show that the gas and solid phase gradually accumulate to the center of the pipe. Flow velocity decreases from center to boundary of the pipe along the radial direction. Comparison of numerical simulation results of two models reveals that the flow state simulated by CFD-PBM model is more uniform than that simulated by Euler model, and the main behavior of the bubble is small bubbles coalescence to large one. Comparison of numerical simulation and experimental investigation shows that the values of flow velocity and gas fraction in CFD-PBM model agree with experimental data better than those in Euler model. The proposed PBM model provides a more accurate and effective way to estimate three-phase flow state of transporting gas hydrate within the submarine pipeline.
基金supported by the National Natural Science Foundation of China (No. 50176051, No. 59836230)the Satate Key Development Program for Basic Research of China (No. 2000026306).
文摘In order to design a kind of heat exchanger suitable to the indirect-touched gas hydrate cool storage vessel, a visual observation of HCFC141b gas hydrate formation/decomposition process was presented through a self-designed small-scale visualization apparatus of gas hydrate cool storage. Based on the shooted photos and recorded temperatures, the formation/decomposition process of HCFC141b are described, some characteristics are concluded, and some suggestions of designing heat exchanger are indicated according to the specific characteristics of HCFC141b gas hydrate formation/decomposition process.
基金Project(51775561)supported by the National Natural Science Foundation of ChinaProject(20130162110004)supported by the National Doctoral Foundation of China
文摘The mathematical and simulation models of working head in the deep-sea working environment were built to analyze the effects of cutter-suction flow,cutter-head rotating speed,cutting depth and suction port position on the cutter-suction capacity.The efficiency of the cutter-suction is analyzed based on the analysis of the variation law of the solid-phase volume fraction of the flow field,the variation law of the velocity distribution in the flow field and the distribution law of the solid-phase concentration.The results show that the increase of cutter-suction flow can significantly improve the cutter-suction efficiency when it is less than1000m3/h.However,when it is more than1000m3/h,it is helpless.When the cutter-head rotate speed is within the range of10–25r/min,the cutter-suction efficiency stabilizes at about95%.While the speed is greater than25r/min,the cutter-suction efficiency decreases sharply with the increase of cutter-head rotate speed.With the increase of cutting depth,the cutter-suction efficiency first increases and then remains stable and finally decreases.The cutter-suction efficiency remains at about94%when the suction port position deviation ranges from0°to30°,but it has a sharply reduction when the deviation angle is more than30°.
文摘Elastic velocities(v_p and v_s)have been widely used in estimating gas hydrate saturation in void spaces of sediments.The commonly used models are empirical equations or some physically based models,such as Wyllie’s time average,Effective Medium Theory(EMT),Modified Biot-Gassmann Theory by Lee(BGTL),etc.These equations or models are selective to distinct conditions.
文摘A new experimental equipment is developed to study the relationship between gas hydrate saturation and water permeability in sediments.Water with dissolved methane is injected circularly into the sediments to form gas hydrate,and the gas hydrate saturation in sediment pores is measured by Time Domain Reflectometry(TDR).The experimental result shows that water permeability is barely influenced by gas hydrate when the saturation is below 30%.
基金supported by the National Natural Science Foundation of China(Grant No.40102005 and No.49725205).
文摘Molecular dynamics simulations are performed to observe the evolutions of 512 and 51262 cage-like water clusters filled with or without a methane molecule immersed in bulk liquid water at 250 K and 230 K. The lifetimes of these clusters are calculated according to their Lindemann index δ (t) using the criteria of δ≥0.07. For both the filled and empty clusters, we find the dynamics of bulk water determines the lifetimes of cage-like water clusters, and that the lifetime of 512 62 cage-like cluster is the same as that of 512 cage-like cluster. Although the methane molecule indeed makes the filled cage-like cluster more stable than the empty one, the empty cage-like cluster still has chance to be long-lived compared with the filled clusters. These observations support the labile cluster hypothesis on the formation mechanisms of gas hydrates.
基金Project(40976035) supported by the National Natural Science Foundation of ChinaProject(2009CB219501) supported by the National Basic Research Program of ChinaProject(908-ZC-I-07) supported by the Special Program of Comprehensive Survey and Assessment Offshore China Sea
文摘Carbon and oxygen isotope and dating analyses of foraminiferan in sediment cores collected from three different areas of the northern slope of the South China Sea were conducted, in order to examine the records of the gas hydrate decomposition events since the late Quaternary under the conditions of methane seepage. The results show that： 1） the δ13C values of the benthic foraminiferan Uvigerina spp. （size range of 0.25-0.35 ram） are from -0.212% to -0.021% and the δ180 values of the planktonic foraminiferan Globigerinoides ruber （size range of 0.25-0.35 ram） are from -0.311% to -0.060%; 2） three cores （ZD2, ZD3 and ZS5） from the bottom of a hole are aged for 11 814, 26 616 and 64 090 a corresponding to the early oxygen isotope stage （MIS） Ⅰ, Ⅲ and Ⅳ final period, respectively; 3） a negative-skewed layer of carbon isotope corresponds to that of MIS II （cold period）, whose degree of negative bias is -0.2%0; and 4） the δ13C compositions of foraminiferans are similar to those of the Blake Ridge and the Gulf of Mexico sediments of the late Quaternary. According to the analysis, the reasons for these results are that the studied area is a typical area of methane seep environment in the area during MIS II due to the global sea-level fall and sea pressure decrease. Gas hydrate is decomposed and released, and a large number of light carbon isotopes of methane are released into the ocean, dissolved to inorganic carbon （DIC） pool and recorded in the foraminiferan shells. A pyrite layer developed in the negative bias layers of the foraminiferans confirms that the δ13C of foraminiferans is more affected by methane and less by the reduction of marine productivity and early diagenesis. The use of foraminiferan δ13C could accurately determine late Quaternary hydrate release events and provide evidence for both reconstructing the geological history of methane release events and exploring natural gas hydrate.
文摘Through analyzing the needs of seismic data processing and interpretation,a system model based on CSCW is designed.Using the technology of CSCW to build the environment of cooperative work allows the field data acquisition to possess the functions of remote real-time guidance by experts and remote real-time processing of the data.
