In order to study the distribution of shale gas reservoir in the Babaoshan Basin of Eastern Kunlun,the wide-field electromagnetic(WFEM)survey was carried out to obtain the spatial distribution characteristics of the u...In order to study the distribution of shale gas reservoir in the Babaoshan Basin of Eastern Kunlun,the wide-field electromagnetic(WFEM)survey was carried out to obtain the spatial distribution characteristics of the underground electrical volume resistivity based on the delineation of the scope of the Babaoshan Basin by regional gravity data.The basic characteristics of the basement,basin framework,and extension,vertical change,burial depth of dark mud shale in this area were identified,and the electrical distribution of the Babaoshan mud shale horizon was revealed,which has been proved to be a good geological effect by drilling.The exploration results show that the WFEM has significant effects on the exploration of shale gas occurrence strata,which meets the needs of investigation and evaluation of multi-layered and large-scale shale gas,and plays a good demonstration role in the follow-up shale gas exploration.展开更多
The selection of refracturing candidate is one of the most important jobs faced by oilfield engineers. However, due to the complicated multi-parameter relationships and their comprehensive influence, the selection of ...The selection of refracturing candidate is one of the most important jobs faced by oilfield engineers. However, due to the complicated multi-parameter relationships and their comprehensive influence, the selection of refracturing candidate is often very difficult. In this paper, a novel approach combining data analysis techniques and fuzzy clustering was proposed to select refracturing candidate. First, the analysis techniques were used to quantitatively calculate the weight coefficient and determine the key factors. Then, the idealized refracturing well was established by considering the main factors. Fuzzy clustering was applied to evaluate refracturing potential. Finally, reservoirs numerical simulation was used to further evaluate reservoirs energy and material basis of the optimum refracturing candidates. The hybrid method has been successfully applied to a tight oil reservoir in China. The average steady production was 15.8 t/d after refracturing treatment, increasing significantly compared with previous status. The research results can guide the development of tight oil and gas reservoirs effectively.展开更多
Three dimensional geophysical models were abstracted and established according to characteristics of oil and gas reservoir.Then direct current fields for different models were simulated with finite element software(fi...Three dimensional geophysical models were abstracted and established according to characteristics of oil and gas reservoir.Then direct current fields for different models were simulated with finite element software(finite element program generator) by hole-to-surface resistivity method.Numerical solution was compared with analytical one for the homogeneity earth model.And a new parameter of deviation rate was proposed by analyzing different plot curves.The results show that the relative error of solution for homogeneity earth model may attain to 0.043%.And deviation rate decreases from 18% to 1% and its anomaly range becomes wide gradually when the depth of oil and gas reservoir increases from 200 to 1 500 m.If resistivity ratio of oil and gas reservoir to sur-rounding rock decreases from 100 to 10 for the resistive oil and gas reservoir,the amplitude attenuation of deviation rate nearly reaches 8%.When there exists stratum above oil and gas reservoir,and influence of resistive stratum may be eliminated or weakened and anomaly of oil and gas reservoir can be strengthened.展开更多
The volatile oil was extracted from Curcuma longa and Turmeric oleoresin by Soxhelt method with petroleum ether.All the volatile oil was analyzed of chemical component by the method of GC-MS,the relative contents of t...The volatile oil was extracted from Curcuma longa and Turmeric oleoresin by Soxhelt method with petroleum ether.All the volatile oil was analyzed of chemical component by the method of GC-MS,the relative contents of these compounds were calculated using square peaks to normalization.On the volatile oil of Curcuma longa 35 peaks were separated and 21 compounds were identified,which accounted for 89.10%,the main chemical constituents was (-)-Zingiberene(22.12%),β-Sesquiphellandrene(15.24%),α-Turmerone (11.30%),β-Turmerone (8.87%),Ar-turmerone(8.20%),but on the volatile oil of Turmeric oleoresin 32 peaks were separated,of which 21 compounds were identified,which accounted for 90.12% the main chemical constituents was (-)-Zingiberene(23.92%),β-Sesquiphellandrene(15.73%),Ar-turmerone(12.89%),β-Turmerone(10.85%).展开更多
The cellulase was used for extracting the volatile constituents of the Leonurus japonicus Houtt.The effects of the pH,the amounts and the fineness of cellulase were discussed.The average yield obtained was 4.05%.16 ch...The cellulase was used for extracting the volatile constituents of the Leonurus japonicus Houtt.The effects of the pH,the amounts and the fineness of cellulase were discussed.The average yield obtained was 4.05%.16 chemical components were identified by gas chromatography-mass spectrometry (GC-MS)method.The cellulase extraction (CE)method was made a camparison with distillation extraction (DSE)method.展开更多
To study the detection method of trimethyltin chloride in urine.Extraction trimethyltin chloride in urine by ethyl acetate,and detection by capillary gas chromatography and mass spectrometry method (GC-MS).The linear ...To study the detection method of trimethyltin chloride in urine.Extraction trimethyltin chloride in urine by ethyl acetate,and detection by capillary gas chromatography and mass spectrometry method (GC-MS).The linear range of trimethyltin chloride in the method was 0.776-19.4 μg/mL,the correlation coefficient was 0.999 9,the lowest detection concentration was 0.01 mg/L.Relative standard deviation(RSD) was 4.4%-8.6%,the recovery rates were 99.0%-110.0%,sample could be save in -20℃ at least one half year.The method was applicable to detect trimethyltin chloride in urine.展开更多
Active volatile components in drug pair(DP)Herba Ephedrae-Ramulus Cinnamomi(HE-RC),single drug HE and RC were analyzed by gas chromatography/mass spectrometry(GC/MS),chemometric resolution method(CRM)and overall volum...Active volatile components in drug pair(DP)Herba Ephedrae-Ramulus Cinnamomi(HE-RC),single drug HE and RC were analyzed by gas chromatography/mass spectrometry(GC/MS),chemometric resolution method(CRM)and overall volume integration.By means of CRM,the two-dimensional data obtained from GC-MS instruments were resolved into a pure chromatogram and a mass spectrum of each chemical compound.In total,97,62,and 78 volatile chemical components in volatile oil of HE,RC,and DP HE-RC,were respectively determined qualitatively and quantitatively,accounting for 90.08%,91.62%,and 89.76% total contents of volatile oil of HE,RC,and DP HE-RC respectively.It is further demonstrated that the numbers of volatile components of DP HE-RC are almost the sum of those of two single drugs,but some relative contents of them are changed.Some new components,such as 1,6-dimethylhepta-1,3,5-triene,tetracyclo[4.2.1.1(2,5).0(9,10)]deca-3,7-diene,globulol and(E,E)-6,10,14-trimethyl-5,9,13-pentadecatrien-2-one are found in DP HE-RC because of chemical reactions and physical changes during decoction.展开更多
Analysis of volatile components in herbal pair (HP) herba schizonepetae-ramulus cinnamomi (HS-RC), single herb HS and RC was carried out by gas chromatography-mass spectrometry (GC-MS) data and chemometric resolution ...Analysis of volatile components in herbal pair (HP) herba schizonepetae-ramulus cinnamomi (HS-RC), single herb HS and RC was carried out by gas chromatography-mass spectrometry (GC-MS) data and chemometric resolution method (CRM). The two-dimensional data obtained from GC-MS instruments were resolved into a pure chromatogram and a mass spectrum of each chemical compound by CRM. In total, 47, 61 and 51 chemical components in volatile oil of HS, RC, and HP HS-RC were respectively determined qualitatively and quantitatively, accounting for 90.52%, 88.37%, and 88.72% total contents of volatile oil of HS, RC, and HP HS-RC, respectively. The number of the volatile components of HP HS-RC is almost the addition of that of two single herbs, but their relative contents are changed.展开更多
基金Project(2019-SF-141)supported by Science and Technology Program of Qinghai Province,ChinaProjects(2017042105kc055,2017042014ky014)supported by Geological Exploration Foundation of Qinghai Province,China。
文摘In order to study the distribution of shale gas reservoir in the Babaoshan Basin of Eastern Kunlun,the wide-field electromagnetic(WFEM)survey was carried out to obtain the spatial distribution characteristics of the underground electrical volume resistivity based on the delineation of the scope of the Babaoshan Basin by regional gravity data.The basic characteristics of the basement,basin framework,and extension,vertical change,burial depth of dark mud shale in this area were identified,and the electrical distribution of the Babaoshan mud shale horizon was revealed,which has been proved to be a good geological effect by drilling.The exploration results show that the WFEM has significant effects on the exploration of shale gas occurrence strata,which meets the needs of investigation and evaluation of multi-layered and large-scale shale gas,and plays a good demonstration role in the follow-up shale gas exploration.
基金Projects(51204054,51504203)supported by the National Natural Science Foundation of ChinaProject(2016ZX05023-001)supported by the National Science and Technology Major Project of China
文摘The selection of refracturing candidate is one of the most important jobs faced by oilfield engineers. However, due to the complicated multi-parameter relationships and their comprehensive influence, the selection of refracturing candidate is often very difficult. In this paper, a novel approach combining data analysis techniques and fuzzy clustering was proposed to select refracturing candidate. First, the analysis techniques were used to quantitatively calculate the weight coefficient and determine the key factors. Then, the idealized refracturing well was established by considering the main factors. Fuzzy clustering was applied to evaluate refracturing potential. Finally, reservoirs numerical simulation was used to further evaluate reservoirs energy and material basis of the optimum refracturing candidates. The hybrid method has been successfully applied to a tight oil reservoir in China. The average steady production was 15.8 t/d after refracturing treatment, increasing significantly compared with previous status. The research results can guide the development of tight oil and gas reservoirs effectively.
基金Projects(2006AA06Z105,2007AA06Z134) supported by the National High-Tech Research and Development Program of China
文摘Three dimensional geophysical models were abstracted and established according to characteristics of oil and gas reservoir.Then direct current fields for different models were simulated with finite element software(finite element program generator) by hole-to-surface resistivity method.Numerical solution was compared with analytical one for the homogeneity earth model.And a new parameter of deviation rate was proposed by analyzing different plot curves.The results show that the relative error of solution for homogeneity earth model may attain to 0.043%.And deviation rate decreases from 18% to 1% and its anomaly range becomes wide gradually when the depth of oil and gas reservoir increases from 200 to 1 500 m.If resistivity ratio of oil and gas reservoir to sur-rounding rock decreases from 100 to 10 for the resistive oil and gas reservoir,the amplitude attenuation of deviation rate nearly reaches 8%.When there exists stratum above oil and gas reservoir,and influence of resistive stratum may be eliminated or weakened and anomaly of oil and gas reservoir can be strengthened.
文摘The volatile oil was extracted from Curcuma longa and Turmeric oleoresin by Soxhelt method with petroleum ether.All the volatile oil was analyzed of chemical component by the method of GC-MS,the relative contents of these compounds were calculated using square peaks to normalization.On the volatile oil of Curcuma longa 35 peaks were separated and 21 compounds were identified,which accounted for 89.10%,the main chemical constituents was (-)-Zingiberene(22.12%),β-Sesquiphellandrene(15.24%),α-Turmerone (11.30%),β-Turmerone (8.87%),Ar-turmerone(8.20%),but on the volatile oil of Turmeric oleoresin 32 peaks were separated,of which 21 compounds were identified,which accounted for 90.12% the main chemical constituents was (-)-Zingiberene(23.92%),β-Sesquiphellandrene(15.73%),Ar-turmerone(12.89%),β-Turmerone(10.85%).
文摘The cellulase was used for extracting the volatile constituents of the Leonurus japonicus Houtt.The effects of the pH,the amounts and the fineness of cellulase were discussed.The average yield obtained was 4.05%.16 chemical components were identified by gas chromatography-mass spectrometry (GC-MS)method.The cellulase extraction (CE)method was made a camparison with distillation extraction (DSE)method.
文摘To study the detection method of trimethyltin chloride in urine.Extraction trimethyltin chloride in urine by ethyl acetate,and detection by capillary gas chromatography and mass spectrometry method (GC-MS).The linear range of trimethyltin chloride in the method was 0.776-19.4 μg/mL,the correlation coefficient was 0.999 9,the lowest detection concentration was 0.01 mg/L.Relative standard deviation(RSD) was 4.4%-8.6%,the recovery rates were 99.0%-110.0%,sample could be save in -20℃ at least one half year.The method was applicable to detect trimethyltin chloride in urine.
基金Project (01962502) supported by the Natural Science Foundation of Hunan Province, China
文摘Active volatile components in drug pair(DP)Herba Ephedrae-Ramulus Cinnamomi(HE-RC),single drug HE and RC were analyzed by gas chromatography/mass spectrometry(GC/MS),chemometric resolution method(CRM)and overall volume integration.By means of CRM,the two-dimensional data obtained from GC-MS instruments were resolved into a pure chromatogram and a mass spectrum of each chemical compound.In total,97,62,and 78 volatile chemical components in volatile oil of HE,RC,and DP HE-RC,were respectively determined qualitatively and quantitatively,accounting for 90.08%,91.62%,and 89.76% total contents of volatile oil of HE,RC,and DP HE-RC respectively.It is further demonstrated that the numbers of volatile components of DP HE-RC are almost the sum of those of two single drugs,but some relative contents of them are changed.Some new components,such as 1,6-dimethylhepta-1,3,5-triene,tetracyclo[4.2.1.1(2,5).0(9,10)]deca-3,7-diene,globulol and(E,E)-6,10,14-trimethyl-5,9,13-pentadecatrien-2-one are found in DP HE-RC because of chemical reactions and physical changes during decoction.
基金Project(20235020) supported by the National Natural Science Foundation of China
文摘Analysis of volatile components in herbal pair (HP) herba schizonepetae-ramulus cinnamomi (HS-RC), single herb HS and RC was carried out by gas chromatography-mass spectrometry (GC-MS) data and chemometric resolution method (CRM). The two-dimensional data obtained from GC-MS instruments were resolved into a pure chromatogram and a mass spectrum of each chemical compound by CRM. In total, 47, 61 and 51 chemical components in volatile oil of HS, RC, and HP HS-RC were respectively determined qualitatively and quantitatively, accounting for 90.52%, 88.37%, and 88.72% total contents of volatile oil of HS, RC, and HP HS-RC, respectively. The number of the volatile components of HP HS-RC is almost the addition of that of two single herbs, but their relative contents are changed.
