为了有效监测环境水体中的有机氯农药(OCPs)残留,本研究开发了一种低消耗、弱基质效应、经济便捷的固相微萃取技术测定水中13种OCPs残留的方法。应用具有强选择性的硅橡胶(SR)薄膜为固相吸附材料,制备了简便易操作的固相萃取瓶,通过优...为了有效监测环境水体中的有机氯农药(OCPs)残留,本研究开发了一种低消耗、弱基质效应、经济便捷的固相微萃取技术测定水中13种OCPs残留的方法。应用具有强选择性的硅橡胶(SR)薄膜为固相吸附材料,制备了简便易操作的固相萃取瓶,通过优化萃取方式、萃取时间、洗脱溶剂以及洗脱方式等条件,选择涡旋10 min进行SR薄膜对目标物的萃取,利用5 mL V_(正己烷):V_(乙酸乙酯)=1:1溶液洗脱SR薄膜上目标物,采用气相色谱仪进行检测。结果表明:方法检出限在0.001~0.132μg/L之间,定量限为0.2μg/L;决定系数(R^(2))>0.9973;在0.2、1、20μg/L 3个添加水平下,13种农药在水中OCPs的平均回收率在73%~109%之间,相对标准偏差在0.5%~13%之间(n=5)。利用该方法对巢湖、南淝河等合肥市内主要河流进行了13种OCPs残留的检测,结果发现13种OCPs的最高检出质量浓度为3.64μg/L。与已所报道的方法相比,该方法具有灵敏度高、操作简便、成本低等特点,在环境水体OCPs多残留痕量监测领域具有良好的应用前景。展开更多
In engineering application,there is only one adaptive weights estimated by most of traditional early warning radars for adaptive interference suppression in a pulse reputation interval(PRI).Therefore,if the training s...In engineering application,there is only one adaptive weights estimated by most of traditional early warning radars for adaptive interference suppression in a pulse reputation interval(PRI).Therefore,if the training samples used to calculate the weight vector does not contain the jamming,then the jamming cannot be removed by adaptive spatial filtering.If the weight vector is constantly updated in the range dimension,the training data may contain target echo signals,resulting in signal cancellation effect.To cope with the situation that the training samples are contaminated by target signal,an iterative training sample selection method based on non-homogeneous detector(NHD)is proposed in this paper for updating the weight vector in entire range dimension.The principle is presented,and the validity is proven by simulation results.展开更多
近年来应用于中高能核物理实验的先进前端读出专用集成电路(application specific integrated circuit,ASIC)芯片呈现出越来越强的数字化趋势,可提高系统的集成度并降低功耗。论文研制了一种高计数率多通道时间测量与串行读出电路(high-...近年来应用于中高能核物理实验的先进前端读出专用集成电路(application specific integrated circuit,ASIC)芯片呈现出越来越强的数字化趋势,可提高系统的集成度并降低功耗。论文研制了一种高计数率多通道时间测量与串行读出电路(high-count rate multi-channel time measurement and serial readout circuit,HMTRC),可实现核事件去稀疏化、去随机化的读出。该电路主要包括了基于时钟分相技术的时间数字转化器、控制器、先进先出存储器和基于令牌环逻辑的轮询读出模块。HMTRC已被集成到一款自研的16通道前端读出ASIC芯片中,可测量和储存时间信息,并利用数字驱动的前端读出架构实现时间与能量信息同步读出。测试表明,时间分辨率好于2 ns,功能符合预期。展开更多
文摘为了有效监测环境水体中的有机氯农药(OCPs)残留,本研究开发了一种低消耗、弱基质效应、经济便捷的固相微萃取技术测定水中13种OCPs残留的方法。应用具有强选择性的硅橡胶(SR)薄膜为固相吸附材料,制备了简便易操作的固相萃取瓶,通过优化萃取方式、萃取时间、洗脱溶剂以及洗脱方式等条件,选择涡旋10 min进行SR薄膜对目标物的萃取,利用5 mL V_(正己烷):V_(乙酸乙酯)=1:1溶液洗脱SR薄膜上目标物,采用气相色谱仪进行检测。结果表明:方法检出限在0.001~0.132μg/L之间,定量限为0.2μg/L;决定系数(R^(2))>0.9973;在0.2、1、20μg/L 3个添加水平下,13种农药在水中OCPs的平均回收率在73%~109%之间,相对标准偏差在0.5%~13%之间(n=5)。利用该方法对巢湖、南淝河等合肥市内主要河流进行了13种OCPs残留的检测,结果发现13种OCPs的最高检出质量浓度为3.64μg/L。与已所报道的方法相比,该方法具有灵敏度高、操作简便、成本低等特点,在环境水体OCPs多残留痕量监测领域具有良好的应用前景。
基金supported by the National Natural Science Foundation of China(62371049)。
文摘In engineering application,there is only one adaptive weights estimated by most of traditional early warning radars for adaptive interference suppression in a pulse reputation interval(PRI).Therefore,if the training samples used to calculate the weight vector does not contain the jamming,then the jamming cannot be removed by adaptive spatial filtering.If the weight vector is constantly updated in the range dimension,the training data may contain target echo signals,resulting in signal cancellation effect.To cope with the situation that the training samples are contaminated by target signal,an iterative training sample selection method based on non-homogeneous detector(NHD)is proposed in this paper for updating the weight vector in entire range dimension.The principle is presented,and the validity is proven by simulation results.
文摘近年来应用于中高能核物理实验的先进前端读出专用集成电路(application specific integrated circuit,ASIC)芯片呈现出越来越强的数字化趋势,可提高系统的集成度并降低功耗。论文研制了一种高计数率多通道时间测量与串行读出电路(high-count rate multi-channel time measurement and serial readout circuit,HMTRC),可实现核事件去稀疏化、去随机化的读出。该电路主要包括了基于时钟分相技术的时间数字转化器、控制器、先进先出存储器和基于令牌环逻辑的轮询读出模块。HMTRC已被集成到一款自研的16通道前端读出ASIC芯片中,可测量和储存时间信息,并利用数字驱动的前端读出架构实现时间与能量信息同步读出。测试表明,时间分辨率好于2 ns,功能符合预期。
