(2E,6E)-4-methyl-2,6-bis(pyridin-3-ylmethylene)cyclohexan-1-one(L_(1))and 4-methyl-2,6-bis[(E)-4-(pyridin-4-yl)benzylidene]cyclohexan-1-one(L_(2))were synthesized and combined with isophthalic acid(H_(2)IP),then under...(2E,6E)-4-methyl-2,6-bis(pyridin-3-ylmethylene)cyclohexan-1-one(L_(1))and 4-methyl-2,6-bis[(E)-4-(pyridin-4-yl)benzylidene]cyclohexan-1-one(L_(2))were synthesized and combined with isophthalic acid(H_(2)IP),then under solvothermal conditions,to react with transition metals achieving four novel metal-organic frameworks(MOFs):[Zn(IP)(L_(1))]_(n)(1),{[Cd(IP)(L_(1))]·H_(2)O}_(n)(2),{[Co(IP)(L_(1))]·H_(2)O}_(n)(3),and[Zn(IP)(L_(2))(H_(2)O)]_(n)(4).MOFs 1-4 have been characterized by single-crystal X-ray diffraction,powder X-ray diffraction,thermogravimetry,and elemental analysis.Single-crystal X-ray diffraction shows that MOF 1 crystallizes in the monoclinic crystal system with space group P2_(1)/n,and MOFs 2-4 belong to the triclinic system with the P1 space group.1-3 are 2D sheet structures,2 and 3 have similar structural characters,whereas 4 is a 1D chain structure.Furthermore,1-3 exhibited certain photocatalytic capability in the degradation of rhodamine B(Rh B)and pararosaniline hydrochloride(PH).4could be used as a heterogeneous catalyst for the Knoevenagel reaction starting with benzaldehyde derivative and malononitrile.4 could promote the reaction to achieve corresponding products in moderate yields within 3 h.Moreover,the catalyst exhibited recyclability for up to three cycles without significantly dropping its activity.A mechanism for MOF 4 catalyzed Knoevenagel condensation reaction of aromatic aldehyde and malononitrile has been initially proposed.CCDC:2356488,1;2356497,2;2356499,3;2356498,4.展开更多
Metal-organic frameworks(MOFs)represent a class of multifunctional hybrid materials distinguished by their tunable structural architectures,adjustable pore dimensions,and tailorable surface chemical functionalities,wh...Metal-organic frameworks(MOFs)represent a class of multifunctional hybrid materials distinguished by their tunable structural architectures,adjustable pore dimensions,and tailorable surface chemical functionalities,which underpin their broad applicability across diverse domains.Within the cosmetics industry,MOFs exhibit significant application potential owing to their high thermal and chemical stability,substantial loading capacity,low biological toxicity,favorable luminescent characteristics,and robust catalytic activity,leading to their increasing deployment in various cosmetic-related applications.This article systematically outlines the structural features and functional properties of MOFs,emphasizing their suitability for integration into cosmetic systems.Furthermore,it provides a comprehensive review of recent advances in the utilization of MOFs in cosmetics,encompassing the detection of organic contaminants and metal ions,ultraviolet protection,encapsulation,and controlled release of volatile active ingredients,as well as targeted delivery of dermatological therapeutic agents.The structure-property-application relationships of MOFs are critically examined.Building upon the foundation of existing research,this study offers a comprehensive outlook on the future development of MOFs in the field of cosmetics.It presents several strategic perspectives,including an in-depth analysis of current application studies,the expansion of MOFs applications into additional cosmetic domains,the integration of multifunctional MOFs systems,the development of MOFs-based composite materials,and the scale-up of synthesis processes from laboratory-scale research to industrial production.It is expected that the present piece of paper can contribute valuable guidance for further exploration and practical implementation in this emerging field of cosmetics.展开更多
Herein,we report the synthesis and third-order nonlinear optical(NLO)properties of a novel cage-based 2D metal-organic framework constructed from Ti_(4)L_(6)(L4-=embonate)cage combined with Mg^(2+)and tris[4-(1H-imida...Herein,we report the synthesis and third-order nonlinear optical(NLO)properties of a novel cage-based 2D metal-organic framework constructed from Ti_(4)L_(6)(L4-=embonate)cage combined with Mg^(2+)and tris[4-(1H-imidazol-1-yl)phenyl]amine(tipa)ligand,whose molecular formula is(Me_(2)CH_(2))_(2)[Mg_(3)(Ti_(4)L_(6))(tipa)(H_(2)O)_(12)](PTC‑378).The Ti_(4)L_(6)tetrahedral cages serve as robust building units,while the Mg^(2+)ions and tipa ligands provide structural stability and tunable optical properties.The resulting PTC‑378 film exhibited intriguing third-order NLO property,which was systematically investigated using Z-scan techniques.Our results demonstrate that the synergistic interaction between Ti_(4)L_(6)cages andπ-conjugated ligands significantly enhances the NLO performance of the materials.CCDC:2453909.展开更多
Ultrafine,highly dispersed Pt clusters were immobilized onto the Co nanoparticle surfaces by one-step pyrolysis of the precursor Pt(Ⅱ)-encapsulating Co-MOF-74.Owing to the small size effects of Pt clusters as well as...Ultrafine,highly dispersed Pt clusters were immobilized onto the Co nanoparticle surfaces by one-step pyrolysis of the precursor Pt(Ⅱ)-encapsulating Co-MOF-74.Owing to the small size effects of Pt clusters as well as the strongly enhanced synergistic interactions between Pt and Co atoms,the obtained Pt-on-Co/C400 catalysts exhib-ited excellent catalytic activity toward the hydrolysis of ammonia borane with an extremely high turnover frequency(TOF)value of 3022 min^(-1)at 303 K.Durability test indicated that the obtained Pt-on-Co/C400 catalysts possessed high catalytic stability,and there were no changes in the catalyst structures and catalytic activities after 10 cycles.展开更多
[Objective]Under the combined impact of climate change and urbanization,urban rainstorm flood disasters occur frequently,seriously restricting urban safety and sustainable development.Relying on traditional grey infra...[Objective]Under the combined impact of climate change and urbanization,urban rainstorm flood disasters occur frequently,seriously restricting urban safety and sustainable development.Relying on traditional grey infrastructure such as pipe networks for urban stormwater management is not enough to deal with urban rainstorm flood disasters under extreme rainfall events.The integration of green,grey and blue systems(GGB-integrated system)is gradually gaining recognition in the field of global flood prevention.It is necessary to further clarify the connotation,technical and engineering implementation strategies of the GGB-integrated system,to provide support for the resilient city construction.[Methods]Through literature retrieval and analysis,the relevant research and progress related to the layout optimization and joint scheduling optimization of the GGBintegrated system were systematically reviewed.In response to existing limitations and future engineering application requirements,key supporting technologies including the utilization of overground emergency storage spaces,safety protection of underground important infrastructure and multi-departmental collaboration,were proposed.A layout optimization framework and a joint scheduling framework for the GGB-integrated system were also developed.[Results]Current research on layout optimization predominantly focuses on the integration of green system and grey system,with relatively fewer studies incorporating blue system infrastructure into the optimization process.Moreover,these studies tend to be on a smaller scale with simpler scenarios,which do not fully capture the complexity of real-world systems.Additionally,optimization objective tend to prioritize environmental and economic goals,while social and ecological factors are less frequently considered.Current research on joint scheduling optimization is often limited to small-scale plots,with insufficient attention paid to the entire system.There is a deficiency in method for real-time,automated determination of optimal control strategies for combinations of multiple system facilities based on actual rainfall-runoff processes.Additionally,the application of emergency facilities during extreme conditions is not sufficiently addressed.Furthermore,both layout optimization and joint scheduling optimization lack consideration of the mute feed effect of flood and waterlogging in urban,watershed and regional scales.[Conclusion]Future research needs to improve the theoretical framework for layout optimization and joint scheduling optimization of GGB-integrated system.Through the comprehensive application of the Internet of things,artificial intelligence,coupling model development,multi-scale analysis,multi-scenario simulation,and the establishment of multi-departmental collaboration mechanisms,it can enhance the flood resilience of urban areas in response to rainfall events of varying intensities,particularly extreme rainfall events.展开更多
In distribution systems,network reconfiguration and capacitor placement are commonly used to diminish power losses and keep voltage profiles within acceptable limits.Moreover,the problem of DG allocation and sizing is...In distribution systems,network reconfiguration and capacitor placement are commonly used to diminish power losses and keep voltage profiles within acceptable limits.Moreover,the problem of DG allocation and sizing is great important.In this work,a combination of a fuzzy multi-objective approach and bacterial foraging optimization(BFO) as a meta-heuristic algorithm is used to solve the simultaneous reconfiguration and optimal sizing of DGs and shunt capacitors in a distribution system.Each objective is transferred into fuzzy domain using its membership function.Then,the overall fuzzy satisfaction function is formed and considered a fitness function inasmuch as the value of this function has to be maximized to gain the optimal solution.The numerical results show that the presented algorithm improves the performance much more than other meta-heuristic algorithms.Simulation results found that simultaneous reconfiguration with DG and shunt capacitors allocation(case 5) has 77.41%,42.15%,and 56.14%improvements in power loss reduction,load balancing,and voltage profile indices,respectively in 33-bus test system.This result found 87.27%,35.82%,and 54.34%improvements of mentioned indices respectively for 69-bus system.展开更多
The reaction of Mg^(2+)and 5-{1,3-dioxo-1H-benzo[de]isoquinolin-2(3H)-yl}terephthalic acid(H_(2)L)leads to two metal-organic frameworks,[Mg(L)(DMF)_(2)(H_(2)O)_(2)]_(2)·5DMF·2H_(2)O(1)with a 1D structure and...The reaction of Mg^(2+)and 5-{1,3-dioxo-1H-benzo[de]isoquinolin-2(3H)-yl}terephthalic acid(H_(2)L)leads to two metal-organic frameworks,[Mg(L)(DMF)_(2)(H_(2)O)_(2)]_(2)·5DMF·2H_(2)O(1)with a 1D structure and[Mg_(2)(L)_(2)(DMSO)_(3)(H_(2)O)](2)with a 2D(4,4)-net structure.Interestingly,the two compounds exhibit distinct luminescent responses to external mechanical stimuli.1 exhibited exceptional resistance mechanical chromic luminescence(RMCL),which can be attributed to the predominant hydrogen bonds and the presence of high-boiling-point solvent molecules within its structure.2 had a reversible MCL property,which can be attributed to the dominantπ-πweak interactions,coupled with the reversible destruction/restoration of its crystallinity under grinding/fumigation.CCDC:2410963,1;2410964,2.展开更多
A cobalt-based metal-organic framework[Co_(3)(L)_(2)(1,4-bib)_(4)]·4H_(2)O(Co-MOF)was prepared using 5-[(4-carboxyphenoxy)methyl]isophthalic acid(H_(3)L)and 1,4-bis(1H-imidazol-1-yl)benzene(1,4-bib)as ligands.The...A cobalt-based metal-organic framework[Co_(3)(L)_(2)(1,4-bib)_(4)]·4H_(2)O(Co-MOF)was prepared using 5-[(4-carboxyphenoxy)methyl]isophthalic acid(H_(3)L)and 1,4-bis(1H-imidazol-1-yl)benzene(1,4-bib)as ligands.Then,an electrochemical sensor modified with Co-MOF on a glassy carbon electrode(Co-MOF@GCE)was constructed for detecting Cd^(2+)and Pb^(2+)in aqueous solutions.The sensor exhibited a linear range of 1.0-16.0µmol·L^(-1)with a detection limit(LOD)of 4.609 nmol·L^(-1)for Cd^(2+),and 0.5-10.0µmol·L^(-1)with an LOD of 1.307 nmol·L^(-1)for Pb^(2+).Simultaneous detection of both ions within 0.5-7.0µmol·L^(-1)achieved LOD values of 0.47 nmol·L^(-1)(Cd^(2+))and 0.008 nmol·L^(-1)(Pb^(2+)),respectively.Analysis of real water samples(tap water,mineral water,and river water)yielded recoveries of 95%-105%,validating practical applicability.Density functional theory(DFT)calculations reveal that synergistic interactions between cobalt centers and N/O atoms enhance adsorption and electron-transfer efficiency.CCDC:2160744.展开更多
The selective hydrogenation ofα,β-unsaturated aldehydes/ketones enables precise control over product structures and properties by regulating hydrogen transport pathways and bond cleavage sequences to selectively red...The selective hydrogenation ofα,β-unsaturated aldehydes/ketones enables precise control over product structures and properties by regulating hydrogen transport pathways and bond cleavage sequences to selectively reduce C=C or C=O bonds while preserving other functional groups within the molecule.This approach serves as a critical strategy for the directional synthesis of high-value molecules.However,achieving such selectivity remains challenging due to the thermodynamic equilibrium and kinetic competition between C=O and C=C bonds inα,β-unsaturated systems.Consequently,constructing precisely targeted catalytic systems is essential to overcome these limitations,offering both fundamental scientific significance and industrial application potential.Metal-organic frameworks(MOFs)and their derivatives have emerged as innovative platforms for designing such systems,owing to their programmable topology,tunable pore microenvironments,spatially controllable active sites,and modifiable electronic structures.This review systematically summarizes the research progress of MOF-based catalysts for selec-tive hydrogenation ofα,β-unsaturated aldehydes/ketones in the last decade,with emphasis on the design strategy,conformational relationship,and catalytic mechanism,aiming to provide new ideas for the design of targeted catalyt-ic systems for the selective hydrogenation ofα,β-unsaturated aldehydes/ketones.展开更多
Preparing multifunctional coatings with both anti-corrosion and anti-biofouling properties is crucial.Copper has been in the spotlight as an effective biocide,especially in the recent past concerning its impact on cau...Preparing multifunctional coatings with both anti-corrosion and anti-biofouling properties is crucial.Copper has been in the spotlight as an effective biocide,especially in the recent past concerning its impact on causing environmental hazards.Reducing the amount used and increasing its efficiency have become the focus of researchers.The hybridization of titanium dioxide nanoparticles(NPs)with copper metal-organic frameworks(MOFs)can significantly improve antimicrobial performance due to its photocatalytic properties.Composites(TiO_(2)-Cu-BTC)of titanium dioxide nanoparticles and copper 1,3,5-benzenetricarboxylate acid(Cu-BTC),obtained by three up-sampling methods,namely hydrothermal,mechanical stirring,and in-situ growth,were doped into epoxy resin(TiO_(2)-Cu-BTC/EP)to enhance its anticorrosion and antifouling properties.The loaded forms were determined by field emission scanning electron microscopy and confirmed using Fourier infrared spectroscopy and X-ray diffraction spectroscopy.The lethality of the composite coating against Escherichia coli(E.coli)increased by 12%after 3 h of exposure to light,and the impedance value increased by 1×1010Ω.The efficiency of the coating was greatly improved.展开更多
Model-based system-of-systems(SOS)engineering(MBSoSE)is becoming a promising solution for the design of SoS with increasing complexity.However,bridging the models from the design phase to the simulation phase poses si...Model-based system-of-systems(SOS)engineering(MBSoSE)is becoming a promising solution for the design of SoS with increasing complexity.However,bridging the models from the design phase to the simulation phase poses significant challenges and requires an integrated approach.In this study,a unified requirement modeling approach is proposed based on unified architecture framework(UAF).Theoretical models are proposed which compose formalized descriptions from both topdown and bottom-up perspectives.Based on the description,the UAF profile is proposed to represent the SoS mission and constituent systems(CS)goal.Moreover,the agent-based simulation information is also described based on the overview,design concepts,and details(ODD)protocol as the complement part of the SoS profile,which can be transformed into different simulation platforms based on the eXtensible markup language(XML)technology and model-to-text method.In this way,the design of the SoS is simulated automatically in the early design stage.Finally,the method is implemented and an example is given to illustrate the whole process.展开更多
Drone swarm systems,equipped with photoelectric imaging and intelligent target perception,are essential for reconnaissance and strike missions in complex and high-risk environments.They excel in information sharing,an...Drone swarm systems,equipped with photoelectric imaging and intelligent target perception,are essential for reconnaissance and strike missions in complex and high-risk environments.They excel in information sharing,anti-jamming capabilities,and combat performance,making them critical for future warfare.However,varied perspectives in collaborative combat scenarios pose challenges to object detection,hindering traditional detection algorithms and reducing accuracy.Limited angle-prior data and sparse samples further complicate detection.This paper presents the Multi-View Collaborative Detection System,which tackles the challenges of multi-view object detection in collaborative combat scenarios.The system is designed to enhance multi-view image generation and detection algorithms,thereby improving the accuracy and efficiency of object detection across varying perspectives.First,an observation model for three-dimensional targets through line-of-sight angle transformation is constructed,and a multi-view image generation algorithm based on the Pix2Pix network is designed.For object detection,YOLOX is utilized,and a deep feature extraction network,BA-RepCSPDarknet,is developed to address challenges related to small target scale and feature extraction challenges.Additionally,a feature fusion network NS-PAFPN is developed to mitigate the issue of deep feature map information loss in UAV images.A visual attention module(BAM)is employed to manage appearance differences under varying angles,while a feature mapping module(DFM)prevents fine-grained feature loss.These advancements lead to the development of BA-YOLOX,a multi-view object detection network model suitable for drone platforms,enhancing accuracy and effectively targeting small objects.展开更多
The view that the traditional method of DSS development is outdated, which results to the diversiform disadvantages of DSS product. Therefore the ideas of application software framework based development to the genera...The view that the traditional method of DSS development is outdated, which results to the diversiform disadvantages of DSS product. Therefore the ideas of application software framework based development to the generation process of DSS is introduced and a modified flow chat of DSS development is proposed. Moreover, a formal description of the DSS software framework and its development is given. The analysis results indicates that not only does the new development flow ensure the DSS development global stability but also improves the software reusability level of the development process.展开更多
本文论述了图书馆期刊发布系统的计算机软件结构,介绍了在Microsof.tNET Framework2.0技术下图书馆期刊发布系统的优点与缺点,并结合本馆自身实例介绍了如何利用Microsoft公司最新的开发工具Visual Studio 2005来实现图书馆期刊发布系...本文论述了图书馆期刊发布系统的计算机软件结构,介绍了在Microsof.tNET Framework2.0技术下图书馆期刊发布系统的优点与缺点,并结合本馆自身实例介绍了如何利用Microsoft公司最新的开发工具Visual Studio 2005来实现图书馆期刊发布系统的计算机软件。展开更多
The effect of the information delay, which was caused by thc naturc of the distance sensors and wireless communication systems, on the string stability of platoon of automated vehicles was studied. The longitudinal ve...The effect of the information delay, which was caused by thc naturc of the distance sensors and wireless communication systems, on the string stability of platoon of automated vehicles was studied. The longitudinal vehicle dynamics model was built by taking the information delay into consideration, and three typical information frameworks, i.e., leader-predecessor framework （LPF）, multiple-predecessors framework （MPF） and predecessor-successor framework （PSF）, were defined and their related spacing error dynamics models in frequency domain were proposed. The string stability of platoon of automated vehicles was analyzed for the LPF, MPF and PSF, respectively. Meanwhile, the related sufficient string stable conditions were also obtained. The results demonstrate that the string stability can be guaranteed tbr the LPF and PSF with considering the information delay, but the ranges of the control gains of the control laws are smaller than those without considering the information delay. For the MPF, the ＂weak＂ string stability, which can be guaranteed without considering the information delay, cannot be obtained with considering the information delay. The comparative simulations further demonstrate that the LPF shows better string stability, but the PSF shows better string scalable performance.展开更多
The command and control（C2） is a decision-making process based on human cognition,which contains operational,physical,and human characteristics,so it takes on uncertainty and complexity.As a decision support approac...The command and control（C2） is a decision-making process based on human cognition,which contains operational,physical,and human characteristics,so it takes on uncertainty and complexity.As a decision support approach,Bayesian networks（BNs） provide a framework in which a decision is made by combining the experts＇ knowledge and the specific data.In addition,an expert system represented by human cognitive framework is adopted to express the real-time decision-making process of the decision maker.The combination of the Bayesian decision support and human cognitive framework in the C2 of a specific application field is modeled and executed by colored Petri nets（CPNs）,and the consequences of execution manifest such combination can perfectly present the decision-making process in C2.展开更多
At present,depression is treated with antidepressant drugs and assisted with psychotherapy and physical therapy,and these expensive and time-consuming treatment methods often end prematurely and result in a prolonged ...At present,depression is treated with antidepressant drugs and assisted with psychotherapy and physical therapy,and these expensive and time-consuming treatment methods often end prematurely and result in a prolonged course w ithout effective symptom relief. Therefore,based on the neurofeedback therapy,a novel depression rehabilitation method using a Virtual-Reality(VR) game framew ork is proposed. In this VR game framew ork,an innovative threeelectrode Electroencephalography(EEG) collector is used to record patients' EEG data. The data are processed and converted into feedback features,and the feedback w ill be displayed to patients in real time through a VR headset. Patients can adjust their psychological activity based on the feedback,and relieve their physiological dysfunction effectively. The framew ork also provides a data storage module,w hich may offer therapists w ays to assess patients' rehabilitation results in a long term,as w ell as provide possibility to continue tow ards better algorithm of feedback features w ith data-mining.The prototype system is tested in the framew ork,and the experimental results prove the effectiveness of the framew ork in depression rehabilitation.展开更多
Efficiently converting CO_(2)and H_(2)O into value-added chemicals using solar energy is a viable approach to address global warming and the energy crisis.However,achieving artificial photocatalytic CO_(2)reduction us...Efficiently converting CO_(2)and H_(2)O into value-added chemicals using solar energy is a viable approach to address global warming and the energy crisis.However,achieving artificial photocatalytic CO_(2)reduction using H_(2)O as the reductant poses challenges is due to the difficulty in efficient cooperation among multiple functional moieties.Metal-organic frameworks(MOFs)are promising candidates for overall CO_(2)photoreduction due to their large surface area,diverse active sites,and excellent tailorability.In this study,we designed a metal-organic framework photocatalyst,named PCN-224(Zn)-Bpy(Ru),by integrating photoactive Zn(Ⅱ)-porphyrin and Ru(Ⅱ)-bipyridyl moieties.In comparison,two isostructural MOFs just with either Zn(Ⅱ)-porphyrin or Ru(Ⅱ)-bipyridyl moiety,namely PCN-224-Bpy(Ru)and PCN-224(Zn)-Bpy were also synthesized.As a result,PCN-224(Zn)-Bpy(Ru)exhibited the highest photocatalytic conversion rate of CO_(2)to CO,with a production rate of 7.6μmol·g^(-1)·h^(-1)in a mixed solvent of CH_(3)CN and H_(2)O,without the need for co-catalysts,photosensitizers,or sacrificial agents.Mass spectrometer analysis detected the signals of^(13)CO(m/z=29),^(13)C^(18)O(m/z=31),^(16)O^(18)O(m/z=34),and^(18)O_(2)(m/z=36),confirming that CO_(2)and H_(2)O acted as the carbon and oxygen sources for CO and O_(2),respectively,thereby confirming the coupling of photocatalytic CO_(2)reduction with H_(2)O oxidation.In contrast,using PCN-224-Bpy(Ru)or PCN-224(Zn)-Bpy as catalysts under the same conditions resulted in significantly lower CO production rates of only 1.5 and 0μmol·g^(-1)·h^(-1),respectively.Mechanistic studies revealed that the lowest unoccupied molecular orbital(LUMO)potential of PCN-224(Zn)-Bpy(Ru)is more negative than the redox potentials of CO_(2)/CO,and the highest occupied molecular orbital(HOMO)potential is more positive than that of H_(2)O/O_(2),satisfying the thermodynamic requirements for overall photocatalytic CO_(2)reduction.In comparison,the HOMO potential of PCN-224(Zn)-Bpy without Ru(II)-bipyridyl moieties is less positive than that of H_(2)O/O_(2),indicating that the Ru(II)-bipyridyl moiety is thermodynamically necessary for CO_(2)reduction coupled with H_(2)O oxidation.Additionally,photoluminescence spectroscopy revealed that the fluorescence of PCN-224(Zn)-Bpy(Ru)was almost completely quenched,and a longer average photoluminescence lifetime compared to PCN-224(Zn)-Bpy and PCN-224-Bpy(Ru)was observed.These suggest a low recombination rate of photogenerated carriers in PCN-224(Zn)-Bpy(Ru),which also supported by the higher photocurrent observed in PCN-224(Zn)-Bpy(Ru)compared to PCN-224(Zn)-Bpy and PCN-224-Bpy(Ru).In summary,the integrated Zn(II)-porphyrin and Ru(II)-bipyridyl moieties in PCN-224(Zn)-Bpy(Ru)play important roles of a photosensitizer and CO_(2)reduction as well as H_(2)O oxidation sites,and their efficient cooperation optimizes the band structure,thereby facilitating the coupling of CO_(2)reduction with H_(2)O oxidation and resulting in highperformance artificial photocatalytic CO_(2)reduction.展开更多
An approach for modeling a human cognitive framework in time-stressed decision making is presented. The recognitive and metacognitive processes that represent the cognitive framework are modeled by the colored Petri n...An approach for modeling a human cognitive framework in time-stressed decision making is presented. The recognitive and metacognitive processes that represent the cognitive framework are modeled by the colored Petri nets （CPNs）. A structural and behavioral analysis method is adopted to obtain the static and dynamic property used to verify the CPNs model of the cognitive framework. Finally, an example from the command and control radar recognition system is used to evaluate the feasibility and availability of the CPNs model adopted in practical systems.展开更多
文摘(2E,6E)-4-methyl-2,6-bis(pyridin-3-ylmethylene)cyclohexan-1-one(L_(1))and 4-methyl-2,6-bis[(E)-4-(pyridin-4-yl)benzylidene]cyclohexan-1-one(L_(2))were synthesized and combined with isophthalic acid(H_(2)IP),then under solvothermal conditions,to react with transition metals achieving four novel metal-organic frameworks(MOFs):[Zn(IP)(L_(1))]_(n)(1),{[Cd(IP)(L_(1))]·H_(2)O}_(n)(2),{[Co(IP)(L_(1))]·H_(2)O}_(n)(3),and[Zn(IP)(L_(2))(H_(2)O)]_(n)(4).MOFs 1-4 have been characterized by single-crystal X-ray diffraction,powder X-ray diffraction,thermogravimetry,and elemental analysis.Single-crystal X-ray diffraction shows that MOF 1 crystallizes in the monoclinic crystal system with space group P2_(1)/n,and MOFs 2-4 belong to the triclinic system with the P1 space group.1-3 are 2D sheet structures,2 and 3 have similar structural characters,whereas 4 is a 1D chain structure.Furthermore,1-3 exhibited certain photocatalytic capability in the degradation of rhodamine B(Rh B)and pararosaniline hydrochloride(PH).4could be used as a heterogeneous catalyst for the Knoevenagel reaction starting with benzaldehyde derivative and malononitrile.4 could promote the reaction to achieve corresponding products in moderate yields within 3 h.Moreover,the catalyst exhibited recyclability for up to three cycles without significantly dropping its activity.A mechanism for MOF 4 catalyzed Knoevenagel condensation reaction of aromatic aldehyde and malononitrile has been initially proposed.CCDC:2356488,1;2356497,2;2356499,3;2356498,4.
文摘Metal-organic frameworks(MOFs)represent a class of multifunctional hybrid materials distinguished by their tunable structural architectures,adjustable pore dimensions,and tailorable surface chemical functionalities,which underpin their broad applicability across diverse domains.Within the cosmetics industry,MOFs exhibit significant application potential owing to their high thermal and chemical stability,substantial loading capacity,low biological toxicity,favorable luminescent characteristics,and robust catalytic activity,leading to their increasing deployment in various cosmetic-related applications.This article systematically outlines the structural features and functional properties of MOFs,emphasizing their suitability for integration into cosmetic systems.Furthermore,it provides a comprehensive review of recent advances in the utilization of MOFs in cosmetics,encompassing the detection of organic contaminants and metal ions,ultraviolet protection,encapsulation,and controlled release of volatile active ingredients,as well as targeted delivery of dermatological therapeutic agents.The structure-property-application relationships of MOFs are critically examined.Building upon the foundation of existing research,this study offers a comprehensive outlook on the future development of MOFs in the field of cosmetics.It presents several strategic perspectives,including an in-depth analysis of current application studies,the expansion of MOFs applications into additional cosmetic domains,the integration of multifunctional MOFs systems,the development of MOFs-based composite materials,and the scale-up of synthesis processes from laboratory-scale research to industrial production.It is expected that the present piece of paper can contribute valuable guidance for further exploration and practical implementation in this emerging field of cosmetics.
文摘Herein,we report the synthesis and third-order nonlinear optical(NLO)properties of a novel cage-based 2D metal-organic framework constructed from Ti_(4)L_(6)(L4-=embonate)cage combined with Mg^(2+)and tris[4-(1H-imidazol-1-yl)phenyl]amine(tipa)ligand,whose molecular formula is(Me_(2)CH_(2))_(2)[Mg_(3)(Ti_(4)L_(6))(tipa)(H_(2)O)_(12)](PTC‑378).The Ti_(4)L_(6)tetrahedral cages serve as robust building units,while the Mg^(2+)ions and tipa ligands provide structural stability and tunable optical properties.The resulting PTC‑378 film exhibited intriguing third-order NLO property,which was systematically investigated using Z-scan techniques.Our results demonstrate that the synergistic interaction between Ti_(4)L_(6)cages andπ-conjugated ligands significantly enhances the NLO performance of the materials.CCDC:2453909.
文摘Ultrafine,highly dispersed Pt clusters were immobilized onto the Co nanoparticle surfaces by one-step pyrolysis of the precursor Pt(Ⅱ)-encapsulating Co-MOF-74.Owing to the small size effects of Pt clusters as well as the strongly enhanced synergistic interactions between Pt and Co atoms,the obtained Pt-on-Co/C400 catalysts exhib-ited excellent catalytic activity toward the hydrolysis of ammonia borane with an extremely high turnover frequency(TOF)value of 3022 min^(-1)at 303 K.Durability test indicated that the obtained Pt-on-Co/C400 catalysts possessed high catalytic stability,and there were no changes in the catalyst structures and catalytic activities after 10 cycles.
文摘[Objective]Under the combined impact of climate change and urbanization,urban rainstorm flood disasters occur frequently,seriously restricting urban safety and sustainable development.Relying on traditional grey infrastructure such as pipe networks for urban stormwater management is not enough to deal with urban rainstorm flood disasters under extreme rainfall events.The integration of green,grey and blue systems(GGB-integrated system)is gradually gaining recognition in the field of global flood prevention.It is necessary to further clarify the connotation,technical and engineering implementation strategies of the GGB-integrated system,to provide support for the resilient city construction.[Methods]Through literature retrieval and analysis,the relevant research and progress related to the layout optimization and joint scheduling optimization of the GGBintegrated system were systematically reviewed.In response to existing limitations and future engineering application requirements,key supporting technologies including the utilization of overground emergency storage spaces,safety protection of underground important infrastructure and multi-departmental collaboration,were proposed.A layout optimization framework and a joint scheduling framework for the GGB-integrated system were also developed.[Results]Current research on layout optimization predominantly focuses on the integration of green system and grey system,with relatively fewer studies incorporating blue system infrastructure into the optimization process.Moreover,these studies tend to be on a smaller scale with simpler scenarios,which do not fully capture the complexity of real-world systems.Additionally,optimization objective tend to prioritize environmental and economic goals,while social and ecological factors are less frequently considered.Current research on joint scheduling optimization is often limited to small-scale plots,with insufficient attention paid to the entire system.There is a deficiency in method for real-time,automated determination of optimal control strategies for combinations of multiple system facilities based on actual rainfall-runoff processes.Additionally,the application of emergency facilities during extreme conditions is not sufficiently addressed.Furthermore,both layout optimization and joint scheduling optimization lack consideration of the mute feed effect of flood and waterlogging in urban,watershed and regional scales.[Conclusion]Future research needs to improve the theoretical framework for layout optimization and joint scheduling optimization of GGB-integrated system.Through the comprehensive application of the Internet of things,artificial intelligence,coupling model development,multi-scale analysis,multi-scenario simulation,and the establishment of multi-departmental collaboration mechanisms,it can enhance the flood resilience of urban areas in response to rainfall events of varying intensities,particularly extreme rainfall events.
文摘In distribution systems,network reconfiguration and capacitor placement are commonly used to diminish power losses and keep voltage profiles within acceptable limits.Moreover,the problem of DG allocation and sizing is great important.In this work,a combination of a fuzzy multi-objective approach and bacterial foraging optimization(BFO) as a meta-heuristic algorithm is used to solve the simultaneous reconfiguration and optimal sizing of DGs and shunt capacitors in a distribution system.Each objective is transferred into fuzzy domain using its membership function.Then,the overall fuzzy satisfaction function is formed and considered a fitness function inasmuch as the value of this function has to be maximized to gain the optimal solution.The numerical results show that the presented algorithm improves the performance much more than other meta-heuristic algorithms.Simulation results found that simultaneous reconfiguration with DG and shunt capacitors allocation(case 5) has 77.41%,42.15%,and 56.14%improvements in power loss reduction,load balancing,and voltage profile indices,respectively in 33-bus test system.This result found 87.27%,35.82%,and 54.34%improvements of mentioned indices respectively for 69-bus system.
文摘The reaction of Mg^(2+)and 5-{1,3-dioxo-1H-benzo[de]isoquinolin-2(3H)-yl}terephthalic acid(H_(2)L)leads to two metal-organic frameworks,[Mg(L)(DMF)_(2)(H_(2)O)_(2)]_(2)·5DMF·2H_(2)O(1)with a 1D structure and[Mg_(2)(L)_(2)(DMSO)_(3)(H_(2)O)](2)with a 2D(4,4)-net structure.Interestingly,the two compounds exhibit distinct luminescent responses to external mechanical stimuli.1 exhibited exceptional resistance mechanical chromic luminescence(RMCL),which can be attributed to the predominant hydrogen bonds and the presence of high-boiling-point solvent molecules within its structure.2 had a reversible MCL property,which can be attributed to the dominantπ-πweak interactions,coupled with the reversible destruction/restoration of its crystallinity under grinding/fumigation.CCDC:2410963,1;2410964,2.
文摘A cobalt-based metal-organic framework[Co_(3)(L)_(2)(1,4-bib)_(4)]·4H_(2)O(Co-MOF)was prepared using 5-[(4-carboxyphenoxy)methyl]isophthalic acid(H_(3)L)and 1,4-bis(1H-imidazol-1-yl)benzene(1,4-bib)as ligands.Then,an electrochemical sensor modified with Co-MOF on a glassy carbon electrode(Co-MOF@GCE)was constructed for detecting Cd^(2+)and Pb^(2+)in aqueous solutions.The sensor exhibited a linear range of 1.0-16.0µmol·L^(-1)with a detection limit(LOD)of 4.609 nmol·L^(-1)for Cd^(2+),and 0.5-10.0µmol·L^(-1)with an LOD of 1.307 nmol·L^(-1)for Pb^(2+).Simultaneous detection of both ions within 0.5-7.0µmol·L^(-1)achieved LOD values of 0.47 nmol·L^(-1)(Cd^(2+))and 0.008 nmol·L^(-1)(Pb^(2+)),respectively.Analysis of real water samples(tap water,mineral water,and river water)yielded recoveries of 95%-105%,validating practical applicability.Density functional theory(DFT)calculations reveal that synergistic interactions between cobalt centers and N/O atoms enhance adsorption and electron-transfer efficiency.CCDC:2160744.
文摘The selective hydrogenation ofα,β-unsaturated aldehydes/ketones enables precise control over product structures and properties by regulating hydrogen transport pathways and bond cleavage sequences to selectively reduce C=C or C=O bonds while preserving other functional groups within the molecule.This approach serves as a critical strategy for the directional synthesis of high-value molecules.However,achieving such selectivity remains challenging due to the thermodynamic equilibrium and kinetic competition between C=O and C=C bonds inα,β-unsaturated systems.Consequently,constructing precisely targeted catalytic systems is essential to overcome these limitations,offering both fundamental scientific significance and industrial application potential.Metal-organic frameworks(MOFs)and their derivatives have emerged as innovative platforms for designing such systems,owing to their programmable topology,tunable pore microenvironments,spatially controllable active sites,and modifiable electronic structures.This review systematically summarizes the research progress of MOF-based catalysts for selec-tive hydrogenation ofα,β-unsaturated aldehydes/ketones in the last decade,with emphasis on the design strategy,conformational relationship,and catalytic mechanism,aiming to provide new ideas for the design of targeted catalyt-ic systems for the selective hydrogenation ofα,β-unsaturated aldehydes/ketones.
基金Project(52073311) supported by the National Natural Science Foundation of ChinaProject(2023A0505010011) supported by the Guangdong-Hong Kong-Macao Joint Innovation Field Research Foundation,ChinaProject(2021A1515012281) supported by the Guangdong Basic and Applied Basic Research Foundation,China。
文摘Preparing multifunctional coatings with both anti-corrosion and anti-biofouling properties is crucial.Copper has been in the spotlight as an effective biocide,especially in the recent past concerning its impact on causing environmental hazards.Reducing the amount used and increasing its efficiency have become the focus of researchers.The hybridization of titanium dioxide nanoparticles(NPs)with copper metal-organic frameworks(MOFs)can significantly improve antimicrobial performance due to its photocatalytic properties.Composites(TiO_(2)-Cu-BTC)of titanium dioxide nanoparticles and copper 1,3,5-benzenetricarboxylate acid(Cu-BTC),obtained by three up-sampling methods,namely hydrothermal,mechanical stirring,and in-situ growth,were doped into epoxy resin(TiO_(2)-Cu-BTC/EP)to enhance its anticorrosion and antifouling properties.The loaded forms were determined by field emission scanning electron microscopy and confirmed using Fourier infrared spectroscopy and X-ray diffraction spectroscopy.The lethality of the composite coating against Escherichia coli(E.coli)increased by 12%after 3 h of exposure to light,and the impedance value increased by 1×1010Ω.The efficiency of the coating was greatly improved.
基金Fifth Electronic Research Institute of the Ministry of Industry and Information Technology(HK07202200877)Pre-research Project on Civil Aerospace Technologies of CNSA(D020101)+2 种基金Zhejiang Provincial Science and Technology Plan Project(2022C01052)Frontier Scientific Research Program of Deep Space Exploration Laboratory(2022-QYKYJHHXYF-018,2022-QYKYJH-GCXD-001)Zhiyuan Laboratory(ZYL2024001)。
文摘Model-based system-of-systems(SOS)engineering(MBSoSE)is becoming a promising solution for the design of SoS with increasing complexity.However,bridging the models from the design phase to the simulation phase poses significant challenges and requires an integrated approach.In this study,a unified requirement modeling approach is proposed based on unified architecture framework(UAF).Theoretical models are proposed which compose formalized descriptions from both topdown and bottom-up perspectives.Based on the description,the UAF profile is proposed to represent the SoS mission and constituent systems(CS)goal.Moreover,the agent-based simulation information is also described based on the overview,design concepts,and details(ODD)protocol as the complement part of the SoS profile,which can be transformed into different simulation platforms based on the eXtensible markup language(XML)technology and model-to-text method.In this way,the design of the SoS is simulated automatically in the early design stage.Finally,the method is implemented and an example is given to illustrate the whole process.
基金supported by the Natural Science Foundation of China,Grant No.62103052.
文摘Drone swarm systems,equipped with photoelectric imaging and intelligent target perception,are essential for reconnaissance and strike missions in complex and high-risk environments.They excel in information sharing,anti-jamming capabilities,and combat performance,making them critical for future warfare.However,varied perspectives in collaborative combat scenarios pose challenges to object detection,hindering traditional detection algorithms and reducing accuracy.Limited angle-prior data and sparse samples further complicate detection.This paper presents the Multi-View Collaborative Detection System,which tackles the challenges of multi-view object detection in collaborative combat scenarios.The system is designed to enhance multi-view image generation and detection algorithms,thereby improving the accuracy and efficiency of object detection across varying perspectives.First,an observation model for three-dimensional targets through line-of-sight angle transformation is constructed,and a multi-view image generation algorithm based on the Pix2Pix network is designed.For object detection,YOLOX is utilized,and a deep feature extraction network,BA-RepCSPDarknet,is developed to address challenges related to small target scale and feature extraction challenges.Additionally,a feature fusion network NS-PAFPN is developed to mitigate the issue of deep feature map information loss in UAV images.A visual attention module(BAM)is employed to manage appearance differences under varying angles,while a feature mapping module(DFM)prevents fine-grained feature loss.These advancements lead to the development of BA-YOLOX,a multi-view object detection network model suitable for drone platforms,enhancing accuracy and effectively targeting small objects.
文摘The view that the traditional method of DSS development is outdated, which results to the diversiform disadvantages of DSS product. Therefore the ideas of application software framework based development to the generation process of DSS is introduced and a modified flow chat of DSS development is proposed. Moreover, a formal description of the DSS software framework and its development is given. The analysis results indicates that not only does the new development flow ensure the DSS development global stability but also improves the software reusability level of the development process.
基金Project(20070006011) supported by the Doctoral Foundation of Ministry of Education of China
文摘The effect of the information delay, which was caused by thc naturc of the distance sensors and wireless communication systems, on the string stability of platoon of automated vehicles was studied. The longitudinal vehicle dynamics model was built by taking the information delay into consideration, and three typical information frameworks, i.e., leader-predecessor framework （LPF）, multiple-predecessors framework （MPF） and predecessor-successor framework （PSF）, were defined and their related spacing error dynamics models in frequency domain were proposed. The string stability of platoon of automated vehicles was analyzed for the LPF, MPF and PSF, respectively. Meanwhile, the related sufficient string stable conditions were also obtained. The results demonstrate that the string stability can be guaranteed tbr the LPF and PSF with considering the information delay, but the ranges of the control gains of the control laws are smaller than those without considering the information delay. For the MPF, the ＂weak＂ string stability, which can be guaranteed without considering the information delay, cannot be obtained with considering the information delay. The comparative simulations further demonstrate that the LPF shows better string stability, but the PSF shows better string scalable performance.
基金supported by the National Natural Science Foundation of China (60874068)
文摘The command and control（C2） is a decision-making process based on human cognition,which contains operational,physical,and human characteristics,so it takes on uncertainty and complexity.As a decision support approach,Bayesian networks（BNs） provide a framework in which a decision is made by combining the experts＇ knowledge and the specific data.In addition,an expert system represented by human cognitive framework is adopted to express the real-time decision-making process of the decision maker.The combination of the Bayesian decision support and human cognitive framework in the C2 of a specific application field is modeled and executed by colored Petri nets（CPNs）,and the consequences of execution manifest such combination can perfectly present the decision-making process in C2.
基金National Basic Research Program of China(2014CB744600)National Natural Science Foundation of China(61632014,61210010)+2 种基金Program of Beijing M unicipal Science&Technology Commission(Z171100000117005)Program of International S&T Cooperation of M OST(2013DFA11140)National Key Research and Development Program of China(2016YFC1307203)
文摘At present,depression is treated with antidepressant drugs and assisted with psychotherapy and physical therapy,and these expensive and time-consuming treatment methods often end prematurely and result in a prolonged course w ithout effective symptom relief. Therefore,based on the neurofeedback therapy,a novel depression rehabilitation method using a Virtual-Reality(VR) game framew ork is proposed. In this VR game framew ork,an innovative threeelectrode Electroencephalography(EEG) collector is used to record patients' EEG data. The data are processed and converted into feedback features,and the feedback w ill be displayed to patients in real time through a VR headset. Patients can adjust their psychological activity based on the feedback,and relieve their physiological dysfunction effectively. The framew ork also provides a data storage module,w hich may offer therapists w ays to assess patients' rehabilitation results in a long term,as w ell as provide possibility to continue tow ards better algorithm of feedback features w ith data-mining.The prototype system is tested in the framew ork,and the experimental results prove the effectiveness of the framew ork in depression rehabilitation.
文摘Efficiently converting CO_(2)and H_(2)O into value-added chemicals using solar energy is a viable approach to address global warming and the energy crisis.However,achieving artificial photocatalytic CO_(2)reduction using H_(2)O as the reductant poses challenges is due to the difficulty in efficient cooperation among multiple functional moieties.Metal-organic frameworks(MOFs)are promising candidates for overall CO_(2)photoreduction due to their large surface area,diverse active sites,and excellent tailorability.In this study,we designed a metal-organic framework photocatalyst,named PCN-224(Zn)-Bpy(Ru),by integrating photoactive Zn(Ⅱ)-porphyrin and Ru(Ⅱ)-bipyridyl moieties.In comparison,two isostructural MOFs just with either Zn(Ⅱ)-porphyrin or Ru(Ⅱ)-bipyridyl moiety,namely PCN-224-Bpy(Ru)and PCN-224(Zn)-Bpy were also synthesized.As a result,PCN-224(Zn)-Bpy(Ru)exhibited the highest photocatalytic conversion rate of CO_(2)to CO,with a production rate of 7.6μmol·g^(-1)·h^(-1)in a mixed solvent of CH_(3)CN and H_(2)O,without the need for co-catalysts,photosensitizers,or sacrificial agents.Mass spectrometer analysis detected the signals of^(13)CO(m/z=29),^(13)C^(18)O(m/z=31),^(16)O^(18)O(m/z=34),and^(18)O_(2)(m/z=36),confirming that CO_(2)and H_(2)O acted as the carbon and oxygen sources for CO and O_(2),respectively,thereby confirming the coupling of photocatalytic CO_(2)reduction with H_(2)O oxidation.In contrast,using PCN-224-Bpy(Ru)or PCN-224(Zn)-Bpy as catalysts under the same conditions resulted in significantly lower CO production rates of only 1.5 and 0μmol·g^(-1)·h^(-1),respectively.Mechanistic studies revealed that the lowest unoccupied molecular orbital(LUMO)potential of PCN-224(Zn)-Bpy(Ru)is more negative than the redox potentials of CO_(2)/CO,and the highest occupied molecular orbital(HOMO)potential is more positive than that of H_(2)O/O_(2),satisfying the thermodynamic requirements for overall photocatalytic CO_(2)reduction.In comparison,the HOMO potential of PCN-224(Zn)-Bpy without Ru(II)-bipyridyl moieties is less positive than that of H_(2)O/O_(2),indicating that the Ru(II)-bipyridyl moiety is thermodynamically necessary for CO_(2)reduction coupled with H_(2)O oxidation.Additionally,photoluminescence spectroscopy revealed that the fluorescence of PCN-224(Zn)-Bpy(Ru)was almost completely quenched,and a longer average photoluminescence lifetime compared to PCN-224(Zn)-Bpy and PCN-224-Bpy(Ru)was observed.These suggest a low recombination rate of photogenerated carriers in PCN-224(Zn)-Bpy(Ru),which also supported by the higher photocurrent observed in PCN-224(Zn)-Bpy(Ru)compared to PCN-224(Zn)-Bpy and PCN-224-Bpy(Ru).In summary,the integrated Zn(II)-porphyrin and Ru(II)-bipyridyl moieties in PCN-224(Zn)-Bpy(Ru)play important roles of a photosensitizer and CO_(2)reduction as well as H_(2)O oxidation sites,and their efficient cooperation optimizes the band structure,thereby facilitating the coupling of CO_(2)reduction with H_(2)O oxidation and resulting in highperformance artificial photocatalytic CO_(2)reduction.
基金supported by the National Natural Science Foundation of China(60874068).
文摘An approach for modeling a human cognitive framework in time-stressed decision making is presented. The recognitive and metacognitive processes that represent the cognitive framework are modeled by the colored Petri nets （CPNs）. A structural and behavioral analysis method is adopted to obtain the static and dynamic property used to verify the CPNs model of the cognitive framework. Finally, an example from the command and control radar recognition system is used to evaluate the feasibility and availability of the CPNs model adopted in practical systems.
