The reaction of Mg^(2+)and 5-{1,3-dioxo-1H-benzo[de]isoquinolin-2(3H)-yl}terephthalic acid(H_(2)L)leads to two metal-organic frameworks,[Mg(L)(DMF)_(2)(H_(2)O)_(2)]_(2)·5DMF·2H_(2)O(1)with a 1D structure and...The reaction of Mg^(2+)and 5-{1,3-dioxo-1H-benzo[de]isoquinolin-2(3H)-yl}terephthalic acid(H_(2)L)leads to two metal-organic frameworks,[Mg(L)(DMF)_(2)(H_(2)O)_(2)]_(2)·5DMF·2H_(2)O(1)with a 1D structure and[Mg_(2)(L)_(2)(DMSO)_(3)(H_(2)O)](2)with a 2D(4,4)-net structure.Interestingly,the two compounds exhibit distinct luminescent responses to external mechanical stimuli.1 exhibited exceptional resistance mechanical chromic luminescence(RMCL),which can be attributed to the predominant hydrogen bonds and the presence of high-boiling-point solvent molecules within its structure.2 had a reversible MCL property,which can be attributed to the dominantπ-πweak interactions,coupled with the reversible destruction/restoration of its crystallinity under grinding/fumigation.CCDC:2410963,1;2410964,2.展开更多
Based on the working principle and the damping characteristic of hydraulic shock absorber, a fluid structure interaction method was presented, which was used to analyze the microcosmic and high-frequency processing me...Based on the working principle and the damping characteristic of hydraulic shock absorber, a fluid structure interaction method was presented, which was used to analyze the microcosmic and high-frequency processing mechanism of fluid structure interaction between circulation valve and liquid of hydraulic shock absorber. The fluid mesh distortion was controlled by the CEL language, and the fluid struc^tre interaction mathematical model was established. The finite element model was established by ANSYS CFX software and was analyzed by dynamic mesh technique. The local sensitive computational area was meshed by prismatic grid, which could reduce the negative volume problem during the simulation. The circulation valve and liquid of hydraulic shock absorber were simulated and analyzed under the condition of sinusoidal inlet velocity loads. Flow characteristic and dynamics characteristic were obtained. The pressure distribution and the displacement of circulation value were obtained, and the acceleration curve of circulation valve was simulated and analyzed. The conformity of the final simulation results with the experimental datum indicates that this method is accurate and reliable to analyze the dynamics characteristic between circulation valve and liquid of hydraulic shock absorber, which can provide a theoretical foundation for optimizing hydraulic shock absorber in the future.展开更多
Vascular diseases such as aneurysm,hemadostenosis,aortic dissection are the primary causes of people’s death around world.As a result,it is significant to improve our knowledge about them,which can help to treat the ...Vascular diseases such as aneurysm,hemadostenosis,aortic dissection are the primary causes of people’s death around world.As a result,it is significant to improve our knowledge about them,which can help to treat the disease.Measuring the hemodynamic factor like the blood pressure,the wall shear stress(WSS)and the oscillatory shear index(OSI)is,however,still beyond the capabilities of in-vivo measurement techniques.So the use of mathematical models and numerical simulations for the studies of the blood flow in arteries and,in general,of the cardiovascular system,both in physiological and pathological conditions,has received an increasing attention in the biomedical community during the last two decades.Indeed,such studies aims at enhancing the current knowledge of the physiology of the cardiovascular system,as well as providing reliable tools for the medical doctors to predict the natural course of pathologies and,possibly,the occurrence of cardiovascular accidents.The computational vascular fluid-structure interaction(FSI)methodology is a numerical simulation method which is used to explain the hemodynamic factors.The WSS on the luminal wall and the mechanical stress in the vascular wall are directly related to the location of the lesion,and the blood flow strongly interacts with the vascular wall motion.The arterial wall continually adapts to the charge of its mechanical environment(due to,for example,growth,atrophy,remodelling,repair,ageing,and disease)and consequently undergoes several irreversible processes.Primary acute mechanisms of vascularFSI numerical simulation seem to be associated with(1)the arterial histology and the patient-specific complex geometry,(2)the typical mechanical properties of the layer,(3)properties of the blood is assumed as Newtonian fluid or non-Newtonian fluid based on the scale ofthe diameter of a vessel,(4)residual stress in the zero-pressure configuration.The arterial system naturally function under permanent physiological loading conditions.Fung defined the residual stress and measured the opening angle which varies greatly along the aortic tree.Consequently,most of these systems never experience a stress-free state in their’service life’,so a stress and strain fields are present in any in vivo obtained patientspecific cardiovascular geometry.The residual stress always be ignored in FSI simulation or be assumed to equal zero,and the vivo patient-specific artery geometry is assumed as zero-pressure configuration.To define the in vivo stress state of artery,an inverse problem needs to be solved:the undeformed shape of a body or its stress state in its deformed state needs to be determined given the deformed configuration and the loads causing this deformation.The modular inverse elastostatics method is used to resolve the pressure-induced stress state for in vivo imaging based on cardiovascular modeling proposed by Peirlinck.Here,we build a living vessel FSI model based on 4 key factors.In order to get the universal simulation results,we focus on idealized geometries of the vessel that represent healthy(physiological)conditions of the cerebral vasculature.Blood can be assumed as the Newtonian fluid at this scale.The anisotropic hyperelastic constitutive law(Gasser-Holzapfel-Ogden)is used in zero-pressure configuration.Afterwards,we propose the material parameters for the different constitutive models and the computational configurations.We demonstrate the importance of introducing the residual stress into vascular blood flow modeling by performing a comparing zero-pressure configuration and no-resistance configuration.We get the conclusion that the zero-pressure status model has smaller displacement and larger stress distribution compared with no-resistance stress model.Hence,the methodology presented here will be particularly useful to study the mechanobiological processes in the healthy and diseased vascular wall.展开更多
In consideration of the problem that the effect of conduit structure on water hammer has been ignored in the classical theory,the Poisson coupling between the fluid and the pipeline was studied and a fourteen-equation...In consideration of the problem that the effect of conduit structure on water hammer has been ignored in the classical theory,the Poisson coupling between the fluid and the pipeline was studied and a fourteen-equation mathematical model of fluid-structure interaction(FSI)was developed.Then,the transfer matrix method(TMM)was used to calculate the modal frequency,modal shape and frequency response.The results were compared with that in experiment to verify the correctness of the TMM and the results show that the fluid-structure coupling has a greater impact on the modal frequencies than the modal shape.Finally,the influence on the response spectrum of different damping ratios was studied and the results show that the natural frequency under different damping ratios has changed little but there is a big difference for the pressure spectrum.With the decreasing of damping ratio,the damping of the system on frequency spectrum is more and more significant and the dispersion and dissipation is more and more apparent.Therefore the appropriate damping ratio should be selected to minimize the effects of the vibration of the FSI.The results provide references for the theory research of FSI in the transient process.展开更多
Single-layer reticulated dome structure are commonly high-profile building in the public and can be attractive targets for terrorist bombings,so the public can benefit from enhanced safety with a stronger understandin...Single-layer reticulated dome structure are commonly high-profile building in the public and can be attractive targets for terrorist bombings,so the public can benefit from enhanced safety with a stronger understanding of the behavior of single-layer reticulated dome structure under explosion.This paper investigates the fluid-structure interaction process and the dynamic response performance of the singlelayer reticulated dome under external blast load.Both experimental and numerical results shown that structural deformation is remarkably delayed compared with the velocity of blast wave,which advises the dynamic response of large-span reticulated dome structure has a negligible effect on the blast wave propagation under explosion.Four failure modes are identified by comparing the plastic development of each ring and the residual spatial geometric of the structure,i.e.,minor vibration,local depression,severe damage,and overall collapse.The plastic deformation energy and the displacement potential energy of the structure are the main consumers of the blast energy.In addition,the stress performance of the vertex member and the deep plastic ratio of the whole structure can serve as qualitative indicators to distinguish different failure modes.展开更多
In order to analyze the seismic response characteristics of pile-supported structure,a computational model considering pile-soil-structure interaction effect was established by finite element method.Then,numerical imp...In order to analyze the seismic response characteristics of pile-supported structure,a computational model considering pile-soil-structure interaction effect was established by finite element method.Then,numerical implementation was made in time domain.At the same time,a simplified approximation for seismic response analysis of pile-soil-structure system was briefly presented.Furthermore,comparative study was performed for an engineering example.Through comparative analysis,it is shown that the results obtained by the simplified method well agree with those achieved by the finite element method.These results show that spectrum characteristics and intensity of input earthquakes are two important factors that can notablely influence the seismic response characteristics of superstructure.When the input ground motion acceleration amplitude gradually increases from 1 to 4 m/s2,the acceleration of pier top will increase,but it will not be simply proportional to the increase of input acceleration amplitude.展开更多
By virtue of a 3∶1 complementary coordination strategy,a chiral heteroleptic metal-organic cage that con-tains divergent functional units,Pd‑R(Zn),was precisely constructed via self-assembly of monodentate variationa...By virtue of a 3∶1 complementary coordination strategy,a chiral heteroleptic metal-organic cage that con-tains divergent functional units,Pd‑R(Zn),was precisely constructed via self-assembly of monodentate variational Zn-salen ligands RZn and NADH(reduced nicotinamide adenine dinucleotide)mimic modified tridentate ligands with square-planar Pd ions.UV-Vis and luminescence spectra experiments reveal that different anions could selec-tively interact with different sites of Zn-salen modified metal-organic cages to achieve the structural regulation of cage compound,by using the differentiated host-guest electrostatic interactions of counter ions with metal-organic hosts.Compared to other anions,the presence of chloride ions caused the most significant fluorescence emission enhancement of Pd‑R(Zn),meanwhile,the UV-Vis absorption band attributed to the salen aromatic backbone showed an absorption decrease,and the metal-to-ligand induced peak displayed a blue shift effect.Circular dichro-ism and ^(1)H NMR spectra further demonstrate that the introduction of chloride anions is beneficial to keeping a more rigid scaffold.展开更多
生物质和化石燃料经不完全燃烧产生的固相富碳残留物统称为黑炭.溶解性炭黑(dissolved black carbon,DBC)是黑炭的水溶性组分(其粒径尺度小于0.45μm),被视为全球溶解有机碳库的重要组成部分.尽管针对它的结构与功能、行为与归宿已有研...生物质和化石燃料经不完全燃烧产生的固相富碳残留物统称为黑炭.溶解性炭黑(dissolved black carbon,DBC)是黑炭的水溶性组分(其粒径尺度小于0.45μm),被视为全球溶解有机碳库的重要组成部分.尽管针对它的结构与功能、行为与归宿已有研究,但DBC在环境中的产生、迁移、转化等过程对有机污染物环境行为的影响关注仍显不足.因此,综述了DBC的分布特征,从元素组成、碳质结构、基团性质和技术检测上深度认识DBC的分子结构与性质变化;归纳了DBC与环境新污染物的相互作用,梳理了DBC与新污染物的作用机制和转化效果;概述了DBC的环境过程对有机污染物行为的影响(如结合、去除、转化等).着重就DBC通过氢键、π-π电子供受体、疏水分配、静电作用等与有机污染物发生结合过程、在阳离子条件下DBC通过压缩双电层机制发生团聚并吸附去除污染物过程、以及DBC介导有机污染物光降解过程进行了系统地阐述.未来研究重点应结合跨学科的技术手段认识DBC分子结构的复杂性,深入理解DBC在环境过程中对新污染物行为的影响机制.这为准确评估DBC环境行为与效应,有效构建DBC与新污染物的命运关系起到重要作用.展开更多
文摘The reaction of Mg^(2+)and 5-{1,3-dioxo-1H-benzo[de]isoquinolin-2(3H)-yl}terephthalic acid(H_(2)L)leads to two metal-organic frameworks,[Mg(L)(DMF)_(2)(H_(2)O)_(2)]_(2)·5DMF·2H_(2)O(1)with a 1D structure and[Mg_(2)(L)_(2)(DMSO)_(3)(H_(2)O)](2)with a 2D(4,4)-net structure.Interestingly,the two compounds exhibit distinct luminescent responses to external mechanical stimuli.1 exhibited exceptional resistance mechanical chromic luminescence(RMCL),which can be attributed to the predominant hydrogen bonds and the presence of high-boiling-point solvent molecules within its structure.2 had a reversible MCL property,which can be attributed to the dominantπ-πweak interactions,coupled with the reversible destruction/restoration of its crystallinity under grinding/fumigation.CCDC:2410963,1;2410964,2.
基金Project(51275542) supported by the National Natural Science Foundation of Chinaproject(CDJXS12110010) supported by the Fundamental Research Funds for the Central Universities of China
文摘Based on the working principle and the damping characteristic of hydraulic shock absorber, a fluid structure interaction method was presented, which was used to analyze the microcosmic and high-frequency processing mechanism of fluid structure interaction between circulation valve and liquid of hydraulic shock absorber. The fluid mesh distortion was controlled by the CEL language, and the fluid struc^tre interaction mathematical model was established. The finite element model was established by ANSYS CFX software and was analyzed by dynamic mesh technique. The local sensitive computational area was meshed by prismatic grid, which could reduce the negative volume problem during the simulation. The circulation valve and liquid of hydraulic shock absorber were simulated and analyzed under the condition of sinusoidal inlet velocity loads. Flow characteristic and dynamics characteristic were obtained. The pressure distribution and the displacement of circulation value were obtained, and the acceleration curve of circulation valve was simulated and analyzed. The conformity of the final simulation results with the experimental datum indicates that this method is accurate and reliable to analyze the dynamics characteristic between circulation valve and liquid of hydraulic shock absorber, which can provide a theoretical foundation for optimizing hydraulic shock absorber in the future.
基金supported by the National Natural Science Foundation of China ( 11732001)
文摘Vascular diseases such as aneurysm,hemadostenosis,aortic dissection are the primary causes of people’s death around world.As a result,it is significant to improve our knowledge about them,which can help to treat the disease.Measuring the hemodynamic factor like the blood pressure,the wall shear stress(WSS)and the oscillatory shear index(OSI)is,however,still beyond the capabilities of in-vivo measurement techniques.So the use of mathematical models and numerical simulations for the studies of the blood flow in arteries and,in general,of the cardiovascular system,both in physiological and pathological conditions,has received an increasing attention in the biomedical community during the last two decades.Indeed,such studies aims at enhancing the current knowledge of the physiology of the cardiovascular system,as well as providing reliable tools for the medical doctors to predict the natural course of pathologies and,possibly,the occurrence of cardiovascular accidents.The computational vascular fluid-structure interaction(FSI)methodology is a numerical simulation method which is used to explain the hemodynamic factors.The WSS on the luminal wall and the mechanical stress in the vascular wall are directly related to the location of the lesion,and the blood flow strongly interacts with the vascular wall motion.The arterial wall continually adapts to the charge of its mechanical environment(due to,for example,growth,atrophy,remodelling,repair,ageing,and disease)and consequently undergoes several irreversible processes.Primary acute mechanisms of vascularFSI numerical simulation seem to be associated with(1)the arterial histology and the patient-specific complex geometry,(2)the typical mechanical properties of the layer,(3)properties of the blood is assumed as Newtonian fluid or non-Newtonian fluid based on the scale ofthe diameter of a vessel,(4)residual stress in the zero-pressure configuration.The arterial system naturally function under permanent physiological loading conditions.Fung defined the residual stress and measured the opening angle which varies greatly along the aortic tree.Consequently,most of these systems never experience a stress-free state in their’service life’,so a stress and strain fields are present in any in vivo obtained patientspecific cardiovascular geometry.The residual stress always be ignored in FSI simulation or be assumed to equal zero,and the vivo patient-specific artery geometry is assumed as zero-pressure configuration.To define the in vivo stress state of artery,an inverse problem needs to be solved:the undeformed shape of a body or its stress state in its deformed state needs to be determined given the deformed configuration and the loads causing this deformation.The modular inverse elastostatics method is used to resolve the pressure-induced stress state for in vivo imaging based on cardiovascular modeling proposed by Peirlinck.Here,we build a living vessel FSI model based on 4 key factors.In order to get the universal simulation results,we focus on idealized geometries of the vessel that represent healthy(physiological)conditions of the cerebral vasculature.Blood can be assumed as the Newtonian fluid at this scale.The anisotropic hyperelastic constitutive law(Gasser-Holzapfel-Ogden)is used in zero-pressure configuration.Afterwards,we propose the material parameters for the different constitutive models and the computational configurations.We demonstrate the importance of introducing the residual stress into vascular blood flow modeling by performing a comparing zero-pressure configuration and no-resistance configuration.We get the conclusion that the zero-pressure status model has smaller displacement and larger stress distribution compared with no-resistance stress model.Hence,the methodology presented here will be particularly useful to study the mechanobiological processes in the healthy and diseased vascular wall.
文摘In consideration of the problem that the effect of conduit structure on water hammer has been ignored in the classical theory,the Poisson coupling between the fluid and the pipeline was studied and a fourteen-equation mathematical model of fluid-structure interaction(FSI)was developed.Then,the transfer matrix method(TMM)was used to calculate the modal frequency,modal shape and frequency response.The results were compared with that in experiment to verify the correctness of the TMM and the results show that the fluid-structure coupling has a greater impact on the modal frequencies than the modal shape.Finally,the influence on the response spectrum of different damping ratios was studied and the results show that the natural frequency under different damping ratios has changed little but there is a big difference for the pressure spectrum.With the decreasing of damping ratio,the damping of the system on frequency spectrum is more and more significant and the dispersion and dissipation is more and more apparent.Therefore the appropriate damping ratio should be selected to minimize the effects of the vibration of the FSI.The results provide references for the theory research of FSI in the transient process.
基金financial support from the China Postdoctora Science Foundation(project No.2021M690406)financial supports from the National Natural Science Foundation of China(project No.51708521,51778183)。
文摘Single-layer reticulated dome structure are commonly high-profile building in the public and can be attractive targets for terrorist bombings,so the public can benefit from enhanced safety with a stronger understanding of the behavior of single-layer reticulated dome structure under explosion.This paper investigates the fluid-structure interaction process and the dynamic response performance of the singlelayer reticulated dome under external blast load.Both experimental and numerical results shown that structural deformation is remarkably delayed compared with the velocity of blast wave,which advises the dynamic response of large-span reticulated dome structure has a negligible effect on the blast wave propagation under explosion.Four failure modes are identified by comparing the plastic development of each ring and the residual spatial geometric of the structure,i.e.,minor vibration,local depression,severe damage,and overall collapse.The plastic deformation energy and the displacement potential energy of the structure are the main consumers of the blast energy.In addition,the stress performance of the vertex member and the deep plastic ratio of the whole structure can serve as qualitative indicators to distinguish different failure modes.
基金Project(Y2007F48) supported by the Natural Science Foundation of Shandong Province,ChinaProject(SDTS20080422) supported by the Specialized Development Foundation for Taishan Scholars of Shandong Province, China Project(SDVS20090525) supported by the Specialized Foundation for Domestic Visiting Scholars of Shandong Province,China
文摘In order to analyze the seismic response characteristics of pile-supported structure,a computational model considering pile-soil-structure interaction effect was established by finite element method.Then,numerical implementation was made in time domain.At the same time,a simplified approximation for seismic response analysis of pile-soil-structure system was briefly presented.Furthermore,comparative study was performed for an engineering example.Through comparative analysis,it is shown that the results obtained by the simplified method well agree with those achieved by the finite element method.These results show that spectrum characteristics and intensity of input earthquakes are two important factors that can notablely influence the seismic response characteristics of superstructure.When the input ground motion acceleration amplitude gradually increases from 1 to 4 m/s2,the acceleration of pier top will increase,but it will not be simply proportional to the increase of input acceleration amplitude.
文摘By virtue of a 3∶1 complementary coordination strategy,a chiral heteroleptic metal-organic cage that con-tains divergent functional units,Pd‑R(Zn),was precisely constructed via self-assembly of monodentate variational Zn-salen ligands RZn and NADH(reduced nicotinamide adenine dinucleotide)mimic modified tridentate ligands with square-planar Pd ions.UV-Vis and luminescence spectra experiments reveal that different anions could selec-tively interact with different sites of Zn-salen modified metal-organic cages to achieve the structural regulation of cage compound,by using the differentiated host-guest electrostatic interactions of counter ions with metal-organic hosts.Compared to other anions,the presence of chloride ions caused the most significant fluorescence emission enhancement of Pd‑R(Zn),meanwhile,the UV-Vis absorption band attributed to the salen aromatic backbone showed an absorption decrease,and the metal-to-ligand induced peak displayed a blue shift effect.Circular dichro-ism and ^(1)H NMR spectra further demonstrate that the introduction of chloride anions is beneficial to keeping a more rigid scaffold.
文摘生物质和化石燃料经不完全燃烧产生的固相富碳残留物统称为黑炭.溶解性炭黑(dissolved black carbon,DBC)是黑炭的水溶性组分(其粒径尺度小于0.45μm),被视为全球溶解有机碳库的重要组成部分.尽管针对它的结构与功能、行为与归宿已有研究,但DBC在环境中的产生、迁移、转化等过程对有机污染物环境行为的影响关注仍显不足.因此,综述了DBC的分布特征,从元素组成、碳质结构、基团性质和技术检测上深度认识DBC的分子结构与性质变化;归纳了DBC与环境新污染物的相互作用,梳理了DBC与新污染物的作用机制和转化效果;概述了DBC的环境过程对有机污染物行为的影响(如结合、去除、转化等).着重就DBC通过氢键、π-π电子供受体、疏水分配、静电作用等与有机污染物发生结合过程、在阳离子条件下DBC通过压缩双电层机制发生团聚并吸附去除污染物过程、以及DBC介导有机污染物光降解过程进行了系统地阐述.未来研究重点应结合跨学科的技术手段认识DBC分子结构的复杂性,深入理解DBC在环境过程中对新污染物行为的影响机制.这为准确评估DBC环境行为与效应,有效构建DBC与新污染物的命运关系起到重要作用.
