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High-inclination WO_(3)Deposition Enabled Fast-response Aqueous Zinc-ion Electrochromism 被引量:1
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作者 CHEN Shuo XING Kaixiao +6 位作者 LYU Ying YAO Xinxin LI Pan GUO Xiaoyang WANG Tienan LI Xiaotian LIU Xingyuan 《发光学报》 北大核心 2025年第6期1082-1094,共13页
Aqueous zinc-ion electrochromic(EC)technology,boasting the capability to fulfill both safety and cost-ef⁃fectiveness requirements,is garnering extensive attention in various application areas including smart windows,t... Aqueous zinc-ion electrochromic(EC)technology,boasting the capability to fulfill both safety and cost-ef⁃fectiveness requirements,is garnering extensive attention in various application areas including smart windows,thermal management,displays,and camouflage.However,typical inorganic EC materials,such as tungsten oxides(WO_(3)),of⁃ten suffer from slow ion diffusion kinetics and limited optical contrast within the aqueous Zn^(2+)electrolyte because of the large size and strong Coulombic interactions of the Zn^(2+),which limits their wide applicability.Here,ordered WO_(3)nanowire films,constructed by a one-step grazing angle deposition method,is demonstrated to boost the response speed and optical contrast during EC phenomena.Compared with dense films,the ordered WO_(3)nanowire films with a porosity of 44.6%demonstrate anti-reflective property and excellent comprehensive EC performance,including fast response time(3.6 s and 1.2 s for coloring and bleaching,respectively),large optical contrast(66.6%at 700 nm)and high col⁃oration efficiency(64.3 cm^(2)·C^(-1)).A large-area prototype EC device(17 cm×12 cm)with fast color-switching is also successfully achieved.Mechanistic studies show that the improved performance is mainly due to the ordered porous nanowire structures,which provides direct electron transfer paths and sufficient interfacial contacts,thus simultaneously enhancing the electrochemical activity and fast redox kinetics.This study provides a simple and effective strategy to im⁃prove the performance of tungsten oxide-based aqueous zinc ion EC materials and devices. 展开更多
关键词 electrochromic WO_(3) aqueous Zn^(2+)electrolyte ordered nanowires glancing angle deposition
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The low-temperature deposition of a zincophilic carbon layer on the Zn foil for long-life zinc metal batteries
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作者 LI Chun-yu ZHANG Ming-hui +2 位作者 LANG Xin-yue CHEN Ye DONG Yan-feng 《新型炭材料(中英文)》 北大核心 2025年第1期178-187,共10页
Aqueous zinc metal batteries(ZMBs)which are environmentally benign and cheap can be used for grid-scale energy storage,but have a short cycling life mainly due to the poor reversibility of zinc metal anodes in mild aq... Aqueous zinc metal batteries(ZMBs)which are environmentally benign and cheap can be used for grid-scale energy storage,but have a short cycling life mainly due to the poor reversibility of zinc metal anodes in mild aqueous electrolytes.A zincophilic carbon(ZC)layer was deposited on a Zn metal foil at 450°C by the up-stream pyrolysis of a hydrogen-bonded supramolecular substance framework,as-sembled from melamine(ME)and cyanuric acid(CA).The zincophilic groups(C=O and C=N)in the ZC layer guide uniform zinc plating/stripping and eliminate dendrites and side reactions.so that assembled symmetrical batteries(ZC@Zn//ZC@Zn)have a long-term service life of 2500 h at 1 mA cm^(−2) and 1 mAh cm^(−2),which is much longer than that of bare Zn anodes(180 h).In addition,ZC@Zn//V2O5 full batteries have a higher capacity of 174 mAh g^(−1) after 1200 cycles at 2 A g^(−1) than a Zn//V_(2)O_(5) counterpart(100 mAh g^(−1)).The strategy developed for the low-temperat-ure deposition of the ZC layer is a new way to construct advanced zinc metal anodes for ZMBs. 展开更多
关键词 Aqueous zinc metal batteries Zinc metal anodes Low-temperature deposition Zincophilic carbon layer High performance
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Improved microstructure and mechanical properties of A517Q steel fabricated via laser directed energy deposition assisted by ultrasonic vibration combined with tempering treatment
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作者 LI Jian-liang REN He +6 位作者 WANG Qi-chen CHEN Zu-bin JIANG Guo-rui SUN Wen-yao SU Ye-tong GUO Chun-huan JIANG Feng-chun 《Journal of Central South University》 2025年第3期760-775,共16页
In this work,ultrasonic energy field assistance combined with tempering treatment is proposed to improve the microstructure and mechanical properties of A517Q alloy steel fabricated by laser directed energy deposition... In this work,ultrasonic energy field assistance combined with tempering treatment is proposed to improve the microstructure and mechanical properties of A517Q alloy steel fabricated by laser directed energy deposition(LDED).The effects of ultrasonic vibration(UV)and tempering treatment on microstructure evolution,microhardness distribution and mechanical properties of deposition layer were studied in detail.The microstructure of UV assisted LDED sample after tempering is mainly composed of tempered sorbite(TS).Due to the improvement of microstructure inhomogeneity and grains refinement,UV assisted LDED sample with tempering treatment obtains excellent mechanical properties.The ultimate tensile strength(UTS),yield strength(YS)and elongation after breaking(EL)reach 765 MPa,657 MPa and 19.5%,the increase ratios of UTS and YS are 14.5%and 33.8%while maintaining plasticity compared to original LDED sample,respectively.It is obvious that ultrasonic vibration combined with tempering is a potential and effective method to obtain uniform microstructure and excellent mechanical properties in metal laser directed energy deposition field. 展开更多
关键词 laser directed energy deposition ultrasonic vibration TEMPERING microstructure mechanical property A517Q steel
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Sedimentary facies and depositional model of shallow water delta dominated by fluvial for Chang 8 oil-bearing group of Yanchang Formation in southwestern Ordos Basin,China 被引量:12
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作者 陈林 陆永潮 +5 位作者 吴吉元 邢凤存 刘璐 马义权 饶丹 彭丽 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第12期4749-4763,共15页
A systematic analysis of southwestern Ordos Basin's sedimentary characteristics,internal architectural element association styles and depositional model was illustrated through core statistics,well logging data an... A systematic analysis of southwestern Ordos Basin's sedimentary characteristics,internal architectural element association styles and depositional model was illustrated through core statistics,well logging data and outcrop observations in Chang 8 oil-bearing group.This analysis indicates that shallow water delta sediments dominated by a fluvial system is the primary sedimentary system of the Chang 8 oil-bearing group of the Yanchang Formation in southwestern Ordos Basin.Four microfacies with fine grain sizes are identified: distributary channels,sheet sandstone,mouth bar and interdistributary fines.According to the sandbody's spatial distribution and internal architecture,two types of sandbody architectural element associations are identified: amalgamated distributary channels and thin-layer lobate sandstone.In this sedimentary system,net-like distributary channels at the delta with a narrow ribbon shape compose the skeleton of the sandbody that extends further into the delta front and shades into contiguous lobate distribution sheet sandstone in the distal delta front.The mouth bar is largely absent in this system.By analyzing the palaeogeomorphology,the palaeostructure background,sedimentary characteristics,sedimentary facies types and spatial distribution of sedimentary facies during the Chang 8 period,a distinctive depositional model of the Chang 8 shallow water fluvial-dominated delta was established,which primarily consists of straight multi-phase amalgamated distributary channels in the delta plain,net-like distributary channels frequently diverting and converging in the proximal delta front,sheet sandstones with dispersing contiguous lobate shapes in the distal delta front,and prodelta or shallow lake mudstones. 展开更多
关键词 sedimentary facies architectural element depositional model shallow water delta CHANG 8 oil-bearing GROUP ORDOS Basin
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Depositional conditions and modeling of Triassic Oil shale in southern Ordos Basin using geochemical records 被引量:7
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作者 LI De-lu LI Rong-xi +3 位作者 TAN Cheng-qian ZHAO Di) LIU Fu-tian ZHAO Bang-sheng 《Journal of Central South University》 SCIE EI CAS CSCD 2019年第12期3436-3456,共21页
Based on the element geochemistry and biomarkers of the oil shale from the Chang 7 sub-unit in the southern Ordos Basin,the depositional conditions and organic source of the oil shale are discussed.Biomarkers analyses... Based on the element geochemistry and biomarkers of the oil shale from the Chang 7 sub-unit in the southern Ordos Basin,the depositional conditions and organic source of the oil shale are discussed.Biomarkers analyses show that the oil shale has a homologous organic matter source,with a mix of plankton and advanced plants.U/Th and V/Ni ratios suggest that the redox condition is dominated by a reducing condition,and the degree of anoxia in the Tongchuan area is higher than that of the Xunyi area.Sr/Ba ratios illustrate that the oil shale is deposited in fresh water and the paleosalinity in the Tongchuan area is slightly higher.Fe/Ti ratios imply that the Tongchuan area underwent obvious hydrothermal fluid activities.Sr/Cu ratios show warm and humid paleoclimate in both areas.As assessed by(La/Yb)NASC,the deposition rate in the Tongchuan area is relatively lower.Fe/Co and Th/U ratios suggest that the paleo-water-depth in the Tongchuan area is deeper.The source rock could have the advance plants source,which must have close relationship with the Qinling orogeny.Comparing the paleoenvironment,the Tongchuan area has better depositional conditions,and is the key oil shale exploration area in the southern Ordos Basin. 展开更多
关键词 oil shale geochemistry depositional model Chang 7 Ordos Basin
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Sedimentary system characteristics and depositional filling model of Upper Permian——Lower Triassic in South Yellow Sea Basin 被引量:7
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作者 YUAN Yong CHEN Jian-wen +3 位作者 ZHANG Yin-g ZHANG Yu-xi LIANG Jie ZHANG Peng-hui 《Journal of Central South University》 SCIE EI CAS CSCD 2018年第12期2910-2928,共19页
In the South Yellow Sea Basin,Mesozoic–Paleozoic marine strata are generally well developed with large thickness,and no substantial breakthroughs have been made in hydrocarbon exploration.Through research,it is belie... In the South Yellow Sea Basin,Mesozoic–Paleozoic marine strata are generally well developed with large thickness,and no substantial breakthroughs have been made in hydrocarbon exploration.Through research,it is believed that the Upper Permian–Lower Triassic can be regarded as a long-term base-level cycle.Based on drilling data,characteristics of the lithology–electric property combination cyclicity,and the special lithology,the long-term base-level cycle was divided into five medium-term base-level cycles(MC1–MC5).On this basis,the Permian–Triassic sedimentary systems and their filling model were analyzed in accordance with the change of base-level cycle and transition of sedimentary environment,as well as characteristics of the drilling sedimentary facies and seismic facies.The results show that there were six sedimentary systems(fluvial,delta,tidal flat,open platform,restricted platform,and continental shelf)developed in the Upper Permian–Lower Triassic,the sedimentary systems were distributed such that the water was deep in the northwest and shallow in the southeast,and there were two base-level cycle filling models(a relatively stable tidal flat facies and a rapidly transgressive continental shelf facies to stable platform facies)developed in the Upper Permian–Lower Triassic.These models can provide a basis for evaluation of the Mesozoic–Paleozoic hydrocarbon geology in the South Yellow Sea Basin. 展开更多
关键词 sequence base-level cycle sedimentary system depositional filling model Upper Permian–Lower Triassic South Yellow Sea Basin
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DEPOSITIONAL SEQUENCES AROUND J/K BOUNDARY IN THE QOMOLONGMA AREA, SOUTH TIBET
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作者 Shi Xiaoying 1, Nicol Morton 2(1 China University of Geosciences, Beijing 100083,China 2.University of London, London WC1E 7HX,UK) 《地学前缘》 EI CAS CSCD 2000年第S1期21-22,共2页
The uppermost Jurassic to Lower Cretaceous in the Qomolongma (Mt. Everest) area were deposited in a strong subsiding setting on passive continental margin. From Tithonian to Valanginian, the area experienced an enviro... The uppermost Jurassic to Lower Cretaceous in the Qomolongma (Mt. Everest) area were deposited in a strong subsiding setting on passive continental margin. From Tithonian to Valanginian, the area experienced an environment shift from circum\|shelf margin carbonate platform to foreslope, then to deep continental slope [1] . Correspondingly, the sediments change in vertical succession from quartz sandstone, via carbonate grainstone to dark shale intercalated with lithic sandstone of gravity flow. From the Tithonian to Valanginian, eight 3rd\|order sequences have been recognized [1] with clearly delineated sequence boundaries and reasonable biostratigraphic controls of ammonites. From the angle of sequence stratigraphy and sedimentary cycles, the important change happened at ca. 138Ma [2] of the Lower Tithonian (about 120m above Aulacosphinctoides hybonotum zone), where a waved subaerial erosion surface occurs in massive bioclastic grainstone. The boundary at ca. 134 5Ma (latest Tithonian, about 60m below the FAD of \%Berriasella cf. jacobi [3] ) comes to the next. The third one is at ca 132Ma (some 170m above the FAD of Berriasella cf. jacobi [3] , but about 60m below the FAD of Berriasella cf. grandis [3] ). In terms of sea\|level change, the sequence boundary at 134 5Ma is probably the most distinctive one, above which some 60m gravel\|bearing massive medium\|grained quartz sandstone was laid down and obviously truncates the underlying strata. In the dark shale below the sandstone, abundant in ammonites, such as Virgatosphinctes, Aulacosphinctes, Haplophylloceras and Gymnosphinctes are recorded [3] . The quartz sandstone itself does not bear identifiable fossils. Above the quartz sandstone, the strata mainly consists of dark silty shale up to 180m thick, with an prominent marine transgression at the base. Just above the first flooding surface (FFS), quite a number of ammonites such as \%Berriasella\% cf. \%jacobi, Blanofordiceras, Hymalayaites\% and \%Pseudosubplanites \%are documented [3] . The third sequence, which is delineated by submarine truncation of slope fan complexes at bottom, is also characterized by dark shale and silts, yielding ammonites \%Berriasella \%cf. \%grandis\% and B. cf. \%berthei.\%>From the viewpoint of sequence stratigraphy, we herein suggest to take the FFS in the second sequence as the J/K boundary. The sequence boundary below it can be used as a nice auxiliary marker, which represents a large sea\|level fall, and can be correlated widely in the world. From the angle of paleontology, the FFS is also ideal for the boundary, where the most important faunal turnover happened. Theoretically, taking FFS as a chronostratigraphic boundary has more advantages than using sequence boundary. 展开更多
关键词 J/K BOUNDARY depositional SEQUENCES SOUTH TIBET
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Late Mesozoic Depositional Features and Basin Evolution of the Western Segment of Bailongjiang Uplift Zone in the Songpan Area
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作者 Meng He,Chengshan Wang,Yuxiu Zhang,Chao Ma,Meng Wang 1.Liaoning Non-ferrous Geological Exploration Institute,Shenyang 110013,China. 2.Research Center for Tibetan Plateau Geology,China University of Geosciences(Beijing),Beijing 100083,China 《地学前缘》 EI CAS CSCD 北大核心 2009年第S1期271-271,共1页
On the basis of history study and the depositional study the systematic investigation of late Mesozoic sedimentary features and basin evolution are conducted.The architectural elements analysis of sedimentary environm... On the basis of history study and the depositional study the systematic investigation of late Mesozoic sedimentary features and basin evolution are conducted.The architectural elements analysis of sedimentary environment shows that the depositional environment of the early Jurassic in late Mesozoic basin(Gahai basin) in the study area is lacustrine environment,and is further 展开更多
关键词 Bailongjiang UPLIFT depositional feature BASIN evolution STRIKE-SLIP RIFTING BASIN late MESOZOIC
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MARINE SOURCE ROCKS AND THEIR DEPOSITIONAL CONDITIONS OF MESOZOIC—CENOZOIC IN THE GAMBA—TINGRE BASIN,SOUTH TIBET:ORGANIC GEOCHEMICAL STUDY
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作者 Hu Xiumian,Wang Chengshan,Li Xianghui 《地学前缘》 EI CAS CSCD 2000年第S1期423-425,共3页
The Gamba—Tingri basin lies in south Tethys Himalaya subzone. It is 400km in length from east to west, and 30~50km in width from north to south. The basin is mainly made up of marine Mesozoic and Lower Cenozoic, i.e... The Gamba—Tingri basin lies in south Tethys Himalaya subzone. It is 400km in length from east to west, and 30~50km in width from north to south. The basin is mainly made up of marine Mesozoic and Lower Cenozoic, i.e., Jurassic, Cretaceous, and Lower Tertiary. Its total strata are more than 3100m in thickness. The passive continental margin of the India plate developed during Jurassic—Cretaceous after a Triassic rifting stage. Collision took place between the India and the Eurasian plate during the latest Cretaceous and earliest Tertiary (Liu and Einsele, 1994), which resulted in a Tertiary residual basin.The Jurassic stratigraphic system in the Gamba—Tingri basin were not carried out until recently (Wan et al., 1999), which is divided into three formations, i.e.., Pupuga Fm., Nieniexiongla Fm., and Menkadun Fm.. The Cretaceous and Tertiary stratigraphic system is after Wan (1985) and Xu et al.(1990), which the Cretaceous is divided into six formations: Dongsan Fm., Chaqiela Fm., Lengqingle Fm., Xiawuchubo Fm., Jiubao Fm., and Zongshan Fm, whereas the Tertiary is divided into Jiabula Fm. Zongpu Fm., and Zhepure Fm. 展开更多
关键词 marine source rocks depositional conditions MESOZOIC CENOZOIC organic GEOCHEMICAL study SOUTH TIBET
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Jet formation and penetration performance of a double-layer charge liner with chemically-deposited tungsten as the inner liner 被引量:3
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作者 Bihui Hong Wenbin Li +2 位作者 Yiming Li Zhiwei Guo Binyou Yan 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第3期374-385,共12页
This paper proposes a type of double-layer charge liner fabricated using chemical vapor deposition(CVD)that has tungsten as its inner liner.The feasibility of this design was evaluated through penetration tests.Double... This paper proposes a type of double-layer charge liner fabricated using chemical vapor deposition(CVD)that has tungsten as its inner liner.The feasibility of this design was evaluated through penetration tests.Double-layer charge liners were fabricated by using CVD to deposit tungsten layers on the inner surfaces of pure T2 copper liners.The microstructures of the tungsten layers were analyzed using a scanning electron microscope(SEM).The feasibility analysis was carried out by pulsed X-rays,slug-retrieval test and static penetration tests.The shaped charge jet forming and penetration law of inner tungsten-coated double-layer liner were studied by numerical simulation method.The results showed that the double-layer liners could form well-shaped jets.The errors between the X-ray test results and the numerical results were within 11.07%.A slug-retrieval test was found that the retrieved slug was similar to a numerically simulated slug.Compared with the traditional pure copper shaped charge jet,the penetration depth of the double-layer shaped charge liner increased by 11.4% and>10.8% respectively.In summary,the test results are good,and the numerical simulation is in good agreement with the test,which verified the feasibility of using the CVD method to fabricate double-layer charge liners with a high-density and high-strength refractory metal as the inner liner. 展开更多
关键词 Shaped charge Chemical vapor deposition TUNGSTEN Double-layer charge liner X-ray PENETRATION
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Infrared microthermometry of fluid inclusion in sphalerite:A case study of the Xinqiao deposit in the Middle-Lower Yangtze metallogenic belt
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作者 Yangyang Wang Yilin Xiao 《中国科学技术大学学报》 CAS CSCD 北大核心 2024年第5期10-21,I0006,共13页
Infrared microthermometry allows direct measurement of fluid inclusions hosted in opaque ore minerals and can provide direct constraints on the evolution of ore-forming fluids.This study presents infrared microthermom... Infrared microthermometry allows direct measurement of fluid inclusions hosted in opaque ore minerals and can provide direct constraints on the evolution of ore-forming fluids.This study presents infrared microthermometry of spherite-hosted fluid inclusions from the Xinqiao deposit in the Middle-Lower Yangtze Metallogenic Belt and sheds new light on the ore genesis of the deposit.Considering that infrared light may lead to non-negligible temperature deviations during microthermometry,some tests were first conducted to ensure the accuracy of the microthermometric measurements.The measurement results indicated that using the lowest light intensity of the microscope and inserting an optical filter were effective in minimizing the possible temperature deviations of infrared microthermometry.All sphalerite-hosted fluid inclusions from the Xinqiao deposit were aqueous.They show homogenization temperature ranging from~200 to 350℃,but have two separate salinity groups(1.0 wt%-10 wt%and 15.1 wt%-19.2 wt%NaCl equivalent).The low-salinity group represents sedimentary exhalative(SEDEX)-associated fluids,whereas the high-salinity group results from modification by later magmatic hydrothermal fluids.Combined with published fluid inclusion data,the four-stage fluid evolution of the Xinqiao deposit was depicted.Furthermore,our data suggest that the Xinqiao deposit was formed by twostage metallogenic events including SEDEX and magmatic-hydrothermal mineralization. 展开更多
关键词 infrared microthermometry fluid inclusion SPHALERITE Xinqiao deposit
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辽宁大东沟超大型低品位金矿的发现及地质意义 被引量:1
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作者 李勇 王东波 +4 位作者 樊金虎 李浩 刘显高 梁维天 王鹏 《中国矿业》 北大核心 2025年第1期233-238,共6页
大东沟金矿是辽宁省第五地质大队有限责任公司近年发现的超大型低品位金矿床。矿区大地构造位于胶-辽-吉古元古代造山/活动带辽东段西端,赋矿地层及岩性为辽河群盖县岩组二段含碳质绢云千枚岩,大规模含金构造蚀变岩带受水平(或缓倾斜)... 大东沟金矿是辽宁省第五地质大队有限责任公司近年发现的超大型低品位金矿床。矿区大地构造位于胶-辽-吉古元古代造山/活动带辽东段西端,赋矿地层及岩性为辽河群盖县岩组二段含碳质绢云千枚岩,大规模含金构造蚀变岩带受水平(或缓倾斜)剪切构造控制,带内金矿化广泛分布,含金相对均匀,含金一般为0.3×10^(-6)~1.0×10^(-6),少数样品可达1.0×10^(-6)~3.0×10^(-6),按低品位指标圈连矿体,矿区金资源量可达1000 t以上;矿体金矿物赋存状态简单,选冶技术指标较好,矿床埋藏浅,经济潜力巨大。大东沟矿床地质特征独特,以含金品位低、规模大、具有明显的层控属性和后期热液叠加改造特征,可称之为“大东沟式”金矿,其矿床学意义深远,深入研究可为辽东金矿矿集区同类型金矿找矿实现更大的突破提供参考。 展开更多
关键词 辽宁省 大东沟金矿 千吨级金矿床 超大型金矿 低品位金矿 地质意义
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中低温岩浆热液型金矿床找矿预测地质模型 被引量:2
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作者 薛建玲 庞振山 +5 位作者 程志中 陈辉 张晓飞 贾儒雅 俞炳 牟妮妮 《岩石学报》 SCIE EI CAS 北大核心 2025年第1期4-30,共27页
我国金矿资源对外依存度长期居高不下,立足国内,寻找并探明一批大型金矿床是一项迫在眉睫的重大任务。中低温岩浆热液型金矿床是我国金的最主要来源,如何寻找其隐伏矿和深部矿成为当前矿产勘查研究的热点。本文以勘查区找矿预测理论为指... 我国金矿资源对外依存度长期居高不下,立足国内,寻找并探明一批大型金矿床是一项迫在眉睫的重大任务。中低温岩浆热液型金矿床是我国金的最主要来源,如何寻找其隐伏矿和深部矿成为当前矿产勘查研究的热点。本文以勘查区找矿预测理论为指导,以中低温岩浆热液型金矿床为研究对象,总结了中低温岩浆热液型金矿床地质特征,构建了以成矿地质体、成矿构造和成矿结构面特征和成矿作用特征标志为核心内容的找矿预测地质模型,为该类型金矿床找矿预测提供了新的思路,指导隐伏矿和深部矿金资源勘查取得突破。中低温岩浆热液型金矿床分为中温岩浆热液型金矿床和低温岩浆热液型金矿床两个亚类,广泛发育于陆块区和造山带中,赋矿围岩多种多样,成矿时代广泛,主要集中在中生代。本文厘定了中低温岩浆热液型金矿床成矿地质体为中酸性侵入体,与矿床(体)呈现出空间上相依(1~5km)、时间上相近(10Myr)、成因上相关的内在成生联系和时空配置关系。成矿构造属褶皱、断裂、岩浆侵入复合构造系统;成矿结构面主要有断裂、硅钙面、岩溶构造及岩体侵入接触带、爆破角砾岩体及水压裂隙等;矿化样式受成矿结构面控制,大致可分为四个类型:层状、脉状、块状及其组合而成的复合型。中温岩浆热液型金矿床成矿作用早阶段温度可达450℃左右,形成强度不等的钾长石化、钠长石化或铁白云石化;主成矿阶段成矿温度250℃左右,蚀变主要为硅化、绢云母化、伊利石化,Au和Ag共伴生,同时伴生少量Pb、Zn、Cu等,主要金属矿物为黄铁矿,次为黄铜矿、磁黄铁矿、方铅矿和闪锌矿;而低温岩浆热液型金矿床成矿作用主阶段温度低于250℃,Au和As、Sb共伴生,Ag含量低,常见毒砂和辉锑矿等矿物,成矿作用早阶段蚀变则主要为硅化,有的为次生石英岩化。金的沉淀富集机制包括流体的沸腾、混合和交代等机制。成矿作用中心位于岩体外接触带2~3km和接触带之内,由浅部到深部形成“上脉下层”的二元结构模式,脉状矿体具有侧伏延深规律,在此基础上构建了找矿预测地质模型。在该模型指导下,我们重新厘定了我国重要成矿区带金矿床类型,在深部发现新的矿体样式,拓宽了深部找矿空间,提升了我国重要成矿区带成矿规律的认识水平,带动了我国重要成矿区带金矿找矿新突破。 展开更多
关键词 中温岩浆热液型金矿床 低温岩浆热液型金矿床 成矿地质体 成矿构造与成矿结构面 成矿作用特征标志 找矿预测模型
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矽卡岩矿床模型研究 被引量:2
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作者 谢桂青 纪云昊 +3 位作者 吴晓林 李伟 朱乔乔 张志远 《地质通报》 北大核心 2025年第2期201-219,共19页
【研究目的】矽卡岩矿床是地壳中最丰富的矿床类型之一,是中国多数成矿区带的主攻找矿类型之一。矿床模型不仅用于刻画成矿理论,而且可以用于指导找矿勘查,是评价未发现矿床的重要技术方法,因此,矽卡岩矿床的矿床模型一直受到高度关注,... 【研究目的】矽卡岩矿床是地壳中最丰富的矿床类型之一,是中国多数成矿区带的主攻找矿类型之一。矿床模型不仅用于刻画成矿理论,而且可以用于指导找矿勘查,是评价未发现矿床的重要技术方法,因此,矽卡岩矿床的矿床模型一直受到高度关注,但系统总结近年研究进展相对薄弱。【研究方法】全面收集国内外矽卡岩矿床的资料,结合笔者长达20余年的研究成.果,综合分析矽卡岩矿床模型的研究进展。【研究结果】叙述全球矽卡岩矿床的研究历史和主要类型,总结矽卡岩矿床的矿物组合和分带模式及其控制因素,综述与斑岩有关的矽卡岩铜多金属矿床、远成矽卡岩矿床和交代火成岩矽卡岩矿床的研究现状。以中国长江中下游和江南造山带中段湘中地区矽卡岩矿床为对象,从成矿系统角度,构建氧化性矽卡岩铜铁金矿床组合模型和还原性矽卡岩钨金锑矿床组合模型。【结论】两组成矿系统矿床模型拓宽了找矿方向,展望了矽卡岩矿床模型未来研究方向,为新一轮找矿突破战略行动提供借鉴和参考。 展开更多
关键词 矽卡岩矿床 矿物组合 分带模式 矿床模型 成矿系统
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冈底斯:东西超过一千千米的中新世斑岩-矽卡岩-浅成低温热液型铜矿带 被引量:4
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作者 宋扬 唐菊兴 +5 位作者 刘治博 王楠 闫徐坤 谢富伟 马旭东 孙豪 《地球学报》 北大核心 2025年第1期15-19,共5页
冈底斯岩浆弧的中东段发育众多铜多金属矿,而在东经88°以西的冈底斯西段,铜矿的成矿潜力、找矿方向等问题一直是国内外矿床界和企业界关注的焦点。在陆相火山岩区斑岩-矽卡岩-浅成低温热液成矿作用和矿床成矿系列理论的指导下,通... 冈底斯岩浆弧的中东段发育众多铜多金属矿,而在东经88°以西的冈底斯西段,铜矿的成矿潜力、找矿方向等问题一直是国内外矿床界和企业界关注的焦点。在陆相火山岩区斑岩-矽卡岩-浅成低温热液成矿作用和矿床成矿系列理论的指导下,通过对藏西北革吉陆相火山岩区开展矿产地质调查,圈定短波红外光谱、水系、重砂、土壤地球化学-高精度大功率激电探测-矿物化学异常,经钻探验证,揭露了中新世嘎扎村组蚀变火山碎屑岩中巨厚的(>550 m)高级泥化蚀变带,发现了累计厚度137 m,平均品位0.46%铜(金银)矿体,实现了冈底斯西段铜矿找矿重大突破。赋矿火山岩中发育典型的高硫化浅成低温热液矿化蚀变矿物组合,成岩成矿年龄为17Ma左右,是青藏高原找矿新区新发现的高硫化浅成低温热液型铜(金银)矿,深部寻找斑岩铜矿的潜力大。珠勒—芒拉地区火山岩与冈底斯中—东段中新世岩浆岩具有相对一致的结晶年龄和岩石地球化学特点,显示与印度—欧亚大陆碰撞后伸展环境有关。因此,芒拉高硫化浅成低温热液型铜(金银)矿的发现,不仅将冈底斯中新世斑岩-矽卡岩-浅成低温热液铜矿带向西延伸了近千km,而且开辟了陆相火山岩区寻找碰撞型斑岩-浅成低温热液型铜矿的新方向。 展开更多
关键词 青藏高原 冈底斯 浅成低温热液 斑岩 铜矿
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中国银矿成矿规律与百年勘查成果及新一轮找矿突破行动建议--《中国矿产地质志·银矿卷》研编 被引量:3
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作者 江彪 王登红 +13 位作者 王岩 刘榆 黄凡 王成辉 李楠 武利文 张彤 唐增才 叶泽富 秦海燕 靳皇玉 冯德臣 缪仁谷 张荣臻 《地球学报》 北大核心 2025年第1期35-51,共17页
银是人类最早开发利用的元素之一,随着社会的发展和科技的进步,银的新材料属性日益突出。中国是银矿资源相对丰富的国家之一,自1990年以来,尤其是自2010年以来,中国银矿找矿勘查取得较大突破,新增银资源储量超过55000 t,新发现银矿产地... 银是人类最早开发利用的元素之一,随着社会的发展和科技的进步,银的新材料属性日益突出。中国是银矿资源相对丰富的国家之一,自1990年以来,尤其是自2010年以来,中国银矿找矿勘查取得较大突破,新增银资源储量超过55000 t,新发现银矿产地超过53处,探获了包括双尖子山超大型银矿在内的大量银矿。中国银矿有7个主要矿床类型,以热液型和陆相火山-次火山型最为重要,资源储量分别为161271 t和48870 t,分别占总量的49.5%和15%。中国银矿主要产于中生代,查明银资源储量为266476 t,占比达74.25%;空间上呈“东多西少”的分布格局。大兴安岭成矿带及其邻区查明银资源储量超过86000 t,是中国最重要的银矿产区和找矿潜力区。运用成矿系列理论,寻找新矿区或新类型银矿、老银矿区外围和深部以及在成银带内找银矿等是中国银矿找矿勘查的重要方向。 展开更多
关键词 银矿 成矿规律 勘查成果 找矿方向
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沉积锰矿成矿过程中铁锰分离与富锰矿形成机制 被引量:1
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作者 张连昌 李文君 +5 位作者 董志国 李文 徐一帆 高炳宇 王长乐 朱明田 《矿床地质》 北大核心 2025年第1期85-100,共16页
沉积型锰矿和沉积(变质)型铁矿在地球历史上具有明显的时控特征,前者集中形成于古元古代、新元古代和显生宙,后者主要形成于古元古代大氧化事件之前和新元古代;在空间上可表现为数百公里至上千公里的铁、锰分离。铁、锰分离的控制因素... 沉积型锰矿和沉积(变质)型铁矿在地球历史上具有明显的时控特征,前者集中形成于古元古代、新元古代和显生宙,后者主要形成于古元古代大氧化事件之前和新元古代;在空间上可表现为数百公里至上千公里的铁、锰分离。铁、锰分离的控制因素主要包括:①锰与铁元素的地球化学行为不同,如在pH>7.78时锰单独沉积,pH值在6.5~8.0之间铁、锰可同时沉淀,pH<7.78铁则单独沉淀;②原始含铁、锰物质溶解度的差异引起铁、锰浸出率的不同;③海洋氧化还原环境的变化;④早期黄铁矿在缺氧还原条件下的优先沉淀;⑤来自陆源的可溶性Fe2+和Mn2+在海水介质中,由于胶体或有机颗粒吸附和自身氧化作用能力的不同。综合研究表明铁锰分离是锰沉积成矿的必经过程,不同沉积锰矿床的铁、锰分离程度(Mn/Fe值)差异较大,海洋环境中的铁、锰分离和富锰成矿过程主要受控于次氧化条件下铁的优先氧化或缺氧硫化条件下黄铁矿的大量沉淀。 展开更多
关键词 Mn/Fe比值 铁锰分离 富锰矿床 沉积成矿机制 沉积锰矿床
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大冶式铁矿的矿床模型探讨 被引量:2
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作者 谢桂青 朱乔乔 +5 位作者 高宝龙 吴昌雄 吴晓林 李伟 毛景文 梅燕雄 《矿床地质》 北大核心 2025年第1期67-84,共18页
富铁矿是中国大宗紧缺的战略性矿产,鄂东南矿集区“大冶式”铁矿是中国富铁矿的主要类型之一,前人对其成矿规律和找矿勘查技术做过大量的研究,取得了重要进展,提出“大冶式”铁矿为广义矽卡岩型矿床,但成岩成矿事件格架、矽卡岩铜矿与... 富铁矿是中国大宗紧缺的战略性矿产,鄂东南矿集区“大冶式”铁矿是中国富铁矿的主要类型之一,前人对其成矿规律和找矿勘查技术做过大量的研究,取得了重要进展,提出“大冶式”铁矿为广义矽卡岩型矿床,但成岩成矿事件格架、矽卡岩铜矿与铁矿成矿差异、矿床组合模型和隐伏矿找矿有效技术方面的研究相对薄弱。笔者全面整理分析20余年的地质和物探等资料,确定大冶式铁矿存在两期成岩成矿事件:早期矽卡岩铜铁矿床和成铜岩体,晚期矽卡岩铁矿和成铁岩体。早期成铜岩体和晚期成铁岩体在岩石组合、源区性质、地幔贡献比例方面存在明显不同,矽卡岩铜铁矿床含矿岩浆的地幔物质所占比例明显高于矽卡岩铁矿床。大型矽卡岩铁矿所需的硫主要来源于膏盐层,膏盐矿物中的硫在岩浆-热液过渡阶段参与成矿作用,膏盐层参与矽卡岩铁矿床成矿作用的比例大于矽卡岩铜铁矿床。在此基础上,文章建立了“大冶式”铁矿的矿床组合模型,提出幔源组分和膏盐层参与成矿比例的不同,是造成矽卡岩铜铁矿与铁矿成矿差异的主要原因。创建两套隐伏“大冶式”铁矿的有效找矿技术组合,分别为1∶5万~1∶1万高精度航磁+1∶2000地面高磁+井中磁测+可控音频大地电磁、可控音频大地电磁+广域电磁法+微动探测+多元素原生晕,建立了找矿模型,拓宽了鄂东南地区“大冶式”铁矿的找矿方向。 展开更多
关键词 “大冶式”铁矿 铜铁共生分离机制 膏盐成矿 矿床模型 找矿技术
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造山带岩浆铜镍硫化物矿床深部动力学机制探讨 被引量:6
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作者 高晓峰 隋清霖 +6 位作者 尤敏鑫 胡朝斌 查显锋 李猛 任广利 李婷 杨敏 《西北地质》 北大核心 2025年第3期206-220,共15页
针对造山带岩浆铜镍硫化物矿床成矿岩浆具有富水、源区不均一、弧岩浆元素特征以及矿床中的硫来源多样的特征,前人提出其成矿动力学模式主要包括地幔柱叠加造山带、板块俯冲和地幔柱相互作用、俯冲交代改造的岩石圈地幔部分熔融、后碰... 针对造山带岩浆铜镍硫化物矿床成矿岩浆具有富水、源区不均一、弧岩浆元素特征以及矿床中的硫来源多样的特征,前人提出其成矿动力学模式主要包括地幔柱叠加造山带、板块俯冲和地幔柱相互作用、俯冲交代改造的岩石圈地幔部分熔融、后碰撞伸展阶段软流圈地幔和岩石圈地幔共同作用以及板块断裂引起软流圈地幔上涌减压熔融等多种观点。纵观地球演化历史,经历多期次造山作用,但并不是所有造山带均形成了岩浆铜镍硫化物矿床。因此,造山带中能够形成岩浆铜镍硫化物矿床成矿的关键因素有待进一步明晰。基于上述模式均指向造山带岩浆铜镍硫化物矿床均来源于俯冲交代地幔源区,形成时限滞后于俯冲峰期的研究结果和地质事实,笔者提出了造山带岩浆铜镍硫化物矿床两阶段成矿动力学模式。第一阶段:俯冲期内地幔橄榄岩被俯冲板片形成的硅质熔体交代,交代过程中,俯冲熔体导致Ni等元素从橄榄石中释放以及自身携带硫的释放,从而形成含有斜方辉石和镍硫化物的辉石岩为主地幔源区。第二阶段:俯冲碰撞期结束后,富集辉石和镍硫化物地幔通过拆沉方式进入软流圈地幔发生再次熔融,熔融条件转变成近似无水条件,镁铁质岩浆会分异形成富集亲铜元素形成的硫化物堆晶或岩浆硫化物矿床。区域上深大断裂、韧性剪切带和缝合带作为岩浆通道,是母岩浆脱离熔融源区后岩浆过程的富集通道,源区和岩浆过程共同作用形成造山带岩浆铜镍硫化物矿床。 展开更多
关键词 岩浆铜镍硫化物矿床 熔体交代 岩石圈拆沉 造山带
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中国金矿成矿规律与百年勘查成果及新一轮找矿突破行动建议--《中国矿产地质志·金矿卷》研编 被引量:2
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作者 王登红 秦锦华 +2 位作者 王成辉 刘善宝 江彪 《地球学报》 北大核心 2025年第1期20-34,共15页
中国金矿成矿地质条件优越,成矿期次、分布和矿床类型极其复杂。中国金矿矿床类型包括2个一级类型,6个二级类型和13个三级类型;时间分布上,包括以燕山期为主的7个主要成矿期,并记录了复杂的多期复合叠加成矿作用;在空间上,金矿在不同构... 中国金矿成矿地质条件优越,成矿期次、分布和矿床类型极其复杂。中国金矿矿床类型包括2个一级类型,6个二级类型和13个三级类型;时间分布上,包括以燕山期为主的7个主要成矿期,并记录了复杂的多期复合叠加成矿作用;在空间上,金矿在不同构造单元具有显著的空间差异,以与岩浆作用有关的金矿分布最为广泛,花岗-绿岩型金矿主要分布于太古宙克拉通-元古宙变质岩分布区(华北克拉通、滨太平洋域),产于沉积建造中的金矿床局限于黔桂滇交界、粤中地区、川西地区和秦岭地区。近年来,随着采选冶技术的进步、市场价格的变化和深部找矿的新发现,中国金矿勘查取得了一些突破性进展,一方面是一些低于1 g/t的低品位金矿也能得以开发,另一方面是1000 m深度以下的金矿也能被陆续探明,再一方面是斑岩型、矽卡岩型、浅成低温热液型铜多金属矿床中金的规模越来越大并得以开发利用,形成了多个千吨级金资源基地。这些新进展新趋势,也指明了新一轮找矿行动的方向,既要继续寻找大型-超大型金矿床,加强矿集区勘查与产业基地建设,也要加强共伴生矿床中低品位金的综合回收和尾矿的综合利用。其中,最为关键的是要突破现有思维格架,重点聚焦非传统矿床类型、成矿期次、找矿空间。 展开更多
关键词 金矿 成矿规律 成矿类型 找矿思路 勘查成果
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