Aqueous zinc-ion electrochromic(EC)technology,boasting the capability to fulfill both safety and cost-ef⁃fectiveness requirements,is garnering extensive attention in various application areas including smart windows,t...Aqueous zinc-ion electrochromic(EC)technology,boasting the capability to fulfill both safety and cost-ef⁃fectiveness requirements,is garnering extensive attention in various application areas including smart windows,thermal management,displays,and camouflage.However,typical inorganic EC materials,such as tungsten oxides(WO_(3)),of⁃ten suffer from slow ion diffusion kinetics and limited optical contrast within the aqueous Zn^(2+)electrolyte because of the large size and strong Coulombic interactions of the Zn^(2+),which limits their wide applicability.Here,ordered WO_(3)nanowire films,constructed by a one-step grazing angle deposition method,is demonstrated to boost the response speed and optical contrast during EC phenomena.Compared with dense films,the ordered WO_(3)nanowire films with a porosity of 44.6%demonstrate anti-reflective property and excellent comprehensive EC performance,including fast response time(3.6 s and 1.2 s for coloring and bleaching,respectively),large optical contrast(66.6%at 700 nm)and high col⁃oration efficiency(64.3 cm^(2)·C^(-1)).A large-area prototype EC device(17 cm×12 cm)with fast color-switching is also successfully achieved.Mechanistic studies show that the improved performance is mainly due to the ordered porous nanowire structures,which provides direct electron transfer paths and sufficient interfacial contacts,thus simultaneously enhancing the electrochemical activity and fast redox kinetics.This study provides a simple and effective strategy to im⁃prove the performance of tungsten oxide-based aqueous zinc ion EC materials and devices.展开更多
Aqueous zinc metal batteries(ZMBs)which are environmentally benign and cheap can be used for grid-scale energy storage,but have a short cycling life mainly due to the poor reversibility of zinc metal anodes in mild aq...Aqueous zinc metal batteries(ZMBs)which are environmentally benign and cheap can be used for grid-scale energy storage,but have a short cycling life mainly due to the poor reversibility of zinc metal anodes in mild aqueous electrolytes.A zincophilic carbon(ZC)layer was deposited on a Zn metal foil at 450°C by the up-stream pyrolysis of a hydrogen-bonded supramolecular substance framework,as-sembled from melamine(ME)and cyanuric acid(CA).The zincophilic groups(C=O and C=N)in the ZC layer guide uniform zinc plating/stripping and eliminate dendrites and side reactions.so that assembled symmetrical batteries(ZC@Zn//ZC@Zn)have a long-term service life of 2500 h at 1 mA cm^(−2) and 1 mAh cm^(−2),which is much longer than that of bare Zn anodes(180 h).In addition,ZC@Zn//V2O5 full batteries have a higher capacity of 174 mAh g^(−1) after 1200 cycles at 2 A g^(−1) than a Zn//V_(2)O_(5) counterpart(100 mAh g^(−1)).The strategy developed for the low-temperat-ure deposition of the ZC layer is a new way to construct advanced zinc metal anodes for ZMBs.展开更多
In this work,ultrasonic energy field assistance combined with tempering treatment is proposed to improve the microstructure and mechanical properties of A517Q alloy steel fabricated by laser directed energy deposition...In this work,ultrasonic energy field assistance combined with tempering treatment is proposed to improve the microstructure and mechanical properties of A517Q alloy steel fabricated by laser directed energy deposition(LDED).The effects of ultrasonic vibration(UV)and tempering treatment on microstructure evolution,microhardness distribution and mechanical properties of deposition layer were studied in detail.The microstructure of UV assisted LDED sample after tempering is mainly composed of tempered sorbite(TS).Due to the improvement of microstructure inhomogeneity and grains refinement,UV assisted LDED sample with tempering treatment obtains excellent mechanical properties.The ultimate tensile strength(UTS),yield strength(YS)and elongation after breaking(EL)reach 765 MPa,657 MPa and 19.5%,the increase ratios of UTS and YS are 14.5%and 33.8%while maintaining plasticity compared to original LDED sample,respectively.It is obvious that ultrasonic vibration combined with tempering is a potential and effective method to obtain uniform microstructure and excellent mechanical properties in metal laser directed energy deposition field.展开更多
A systematic analysis of southwestern Ordos Basin's sedimentary characteristics,internal architectural element association styles and depositional model was illustrated through core statistics,well logging data an...A systematic analysis of southwestern Ordos Basin's sedimentary characteristics,internal architectural element association styles and depositional model was illustrated through core statistics,well logging data and outcrop observations in Chang 8 oil-bearing group.This analysis indicates that shallow water delta sediments dominated by a fluvial system is the primary sedimentary system of the Chang 8 oil-bearing group of the Yanchang Formation in southwestern Ordos Basin.Four microfacies with fine grain sizes are identified: distributary channels,sheet sandstone,mouth bar and interdistributary fines.According to the sandbody's spatial distribution and internal architecture,two types of sandbody architectural element associations are identified: amalgamated distributary channels and thin-layer lobate sandstone.In this sedimentary system,net-like distributary channels at the delta with a narrow ribbon shape compose the skeleton of the sandbody that extends further into the delta front and shades into contiguous lobate distribution sheet sandstone in the distal delta front.The mouth bar is largely absent in this system.By analyzing the palaeogeomorphology,the palaeostructure background,sedimentary characteristics,sedimentary facies types and spatial distribution of sedimentary facies during the Chang 8 period,a distinctive depositional model of the Chang 8 shallow water fluvial-dominated delta was established,which primarily consists of straight multi-phase amalgamated distributary channels in the delta plain,net-like distributary channels frequently diverting and converging in the proximal delta front,sheet sandstones with dispersing contiguous lobate shapes in the distal delta front,and prodelta or shallow lake mudstones.展开更多
Based on the element geochemistry and biomarkers of the oil shale from the Chang 7 sub-unit in the southern Ordos Basin,the depositional conditions and organic source of the oil shale are discussed.Biomarkers analyses...Based on the element geochemistry and biomarkers of the oil shale from the Chang 7 sub-unit in the southern Ordos Basin,the depositional conditions and organic source of the oil shale are discussed.Biomarkers analyses show that the oil shale has a homologous organic matter source,with a mix of plankton and advanced plants.U/Th and V/Ni ratios suggest that the redox condition is dominated by a reducing condition,and the degree of anoxia in the Tongchuan area is higher than that of the Xunyi area.Sr/Ba ratios illustrate that the oil shale is deposited in fresh water and the paleosalinity in the Tongchuan area is slightly higher.Fe/Ti ratios imply that the Tongchuan area underwent obvious hydrothermal fluid activities.Sr/Cu ratios show warm and humid paleoclimate in both areas.As assessed by(La/Yb)NASC,the deposition rate in the Tongchuan area is relatively lower.Fe/Co and Th/U ratios suggest that the paleo-water-depth in the Tongchuan area is deeper.The source rock could have the advance plants source,which must have close relationship with the Qinling orogeny.Comparing the paleoenvironment,the Tongchuan area has better depositional conditions,and is the key oil shale exploration area in the southern Ordos Basin.展开更多
In the South Yellow Sea Basin,Mesozoic–Paleozoic marine strata are generally well developed with large thickness,and no substantial breakthroughs have been made in hydrocarbon exploration.Through research,it is belie...In the South Yellow Sea Basin,Mesozoic–Paleozoic marine strata are generally well developed with large thickness,and no substantial breakthroughs have been made in hydrocarbon exploration.Through research,it is believed that the Upper Permian–Lower Triassic can be regarded as a long-term base-level cycle.Based on drilling data,characteristics of the lithology–electric property combination cyclicity,and the special lithology,the long-term base-level cycle was divided into five medium-term base-level cycles(MC1–MC5).On this basis,the Permian–Triassic sedimentary systems and their filling model were analyzed in accordance with the change of base-level cycle and transition of sedimentary environment,as well as characteristics of the drilling sedimentary facies and seismic facies.The results show that there were six sedimentary systems(fluvial,delta,tidal flat,open platform,restricted platform,and continental shelf)developed in the Upper Permian–Lower Triassic,the sedimentary systems were distributed such that the water was deep in the northwest and shallow in the southeast,and there were two base-level cycle filling models(a relatively stable tidal flat facies and a rapidly transgressive continental shelf facies to stable platform facies)developed in the Upper Permian–Lower Triassic.These models can provide a basis for evaluation of the Mesozoic–Paleozoic hydrocarbon geology in the South Yellow Sea Basin.展开更多
The uppermost Jurassic to Lower Cretaceous in the Qomolongma (Mt. Everest) area were deposited in a strong subsiding setting on passive continental margin. From Tithonian to Valanginian, the area experienced an enviro...The uppermost Jurassic to Lower Cretaceous in the Qomolongma (Mt. Everest) area were deposited in a strong subsiding setting on passive continental margin. From Tithonian to Valanginian, the area experienced an environment shift from circum\|shelf margin carbonate platform to foreslope, then to deep continental slope [1] . Correspondingly, the sediments change in vertical succession from quartz sandstone, via carbonate grainstone to dark shale intercalated with lithic sandstone of gravity flow. From the Tithonian to Valanginian, eight 3rd\|order sequences have been recognized [1] with clearly delineated sequence boundaries and reasonable biostratigraphic controls of ammonites. From the angle of sequence stratigraphy and sedimentary cycles, the important change happened at ca. 138Ma [2] of the Lower Tithonian (about 120m above Aulacosphinctoides hybonotum zone), where a waved subaerial erosion surface occurs in massive bioclastic grainstone. The boundary at ca. 134 5Ma (latest Tithonian, about 60m below the FAD of \%Berriasella cf. jacobi [3] ) comes to the next. The third one is at ca 132Ma (some 170m above the FAD of Berriasella cf. jacobi [3] , but about 60m below the FAD of Berriasella cf. grandis [3] ). In terms of sea\|level change, the sequence boundary at 134 5Ma is probably the most distinctive one, above which some 60m gravel\|bearing massive medium\|grained quartz sandstone was laid down and obviously truncates the underlying strata. In the dark shale below the sandstone, abundant in ammonites, such as Virgatosphinctes, Aulacosphinctes, Haplophylloceras and Gymnosphinctes are recorded [3] . The quartz sandstone itself does not bear identifiable fossils. Above the quartz sandstone, the strata mainly consists of dark silty shale up to 180m thick, with an prominent marine transgression at the base. Just above the first flooding surface (FFS), quite a number of ammonites such as \%Berriasella\% cf. \%jacobi, Blanofordiceras, Hymalayaites\% and \%Pseudosubplanites \%are documented [3] . The third sequence, which is delineated by submarine truncation of slope fan complexes at bottom, is also characterized by dark shale and silts, yielding ammonites \%Berriasella \%cf. \%grandis\% and B. cf. \%berthei.\%>From the viewpoint of sequence stratigraphy, we herein suggest to take the FFS in the second sequence as the J/K boundary. The sequence boundary below it can be used as a nice auxiliary marker, which represents a large sea\|level fall, and can be correlated widely in the world. From the angle of paleontology, the FFS is also ideal for the boundary, where the most important faunal turnover happened. Theoretically, taking FFS as a chronostratigraphic boundary has more advantages than using sequence boundary.展开更多
On the basis of history study and the depositional study the systematic investigation of late Mesozoic sedimentary features and basin evolution are conducted.The architectural elements analysis of sedimentary environm...On the basis of history study and the depositional study the systematic investigation of late Mesozoic sedimentary features and basin evolution are conducted.The architectural elements analysis of sedimentary environment shows that the depositional environment of the early Jurassic in late Mesozoic basin(Gahai basin) in the study area is lacustrine environment,and is further展开更多
The Gamba—Tingri basin lies in south Tethys Himalaya subzone. It is 400km in length from east to west, and 30~50km in width from north to south. The basin is mainly made up of marine Mesozoic and Lower Cenozoic, i.e...The Gamba—Tingri basin lies in south Tethys Himalaya subzone. It is 400km in length from east to west, and 30~50km in width from north to south. The basin is mainly made up of marine Mesozoic and Lower Cenozoic, i.e., Jurassic, Cretaceous, and Lower Tertiary. Its total strata are more than 3100m in thickness. The passive continental margin of the India plate developed during Jurassic—Cretaceous after a Triassic rifting stage. Collision took place between the India and the Eurasian plate during the latest Cretaceous and earliest Tertiary (Liu and Einsele, 1994), which resulted in a Tertiary residual basin.The Jurassic stratigraphic system in the Gamba—Tingri basin were not carried out until recently (Wan et al., 1999), which is divided into three formations, i.e.., Pupuga Fm., Nieniexiongla Fm., and Menkadun Fm.. The Cretaceous and Tertiary stratigraphic system is after Wan (1985) and Xu et al.(1990), which the Cretaceous is divided into six formations: Dongsan Fm., Chaqiela Fm., Lengqingle Fm., Xiawuchubo Fm., Jiubao Fm., and Zongshan Fm, whereas the Tertiary is divided into Jiabula Fm. Zongpu Fm., and Zhepure Fm.展开更多
This paper proposes a type of double-layer charge liner fabricated using chemical vapor deposition(CVD)that has tungsten as its inner liner.The feasibility of this design was evaluated through penetration tests.Double...This paper proposes a type of double-layer charge liner fabricated using chemical vapor deposition(CVD)that has tungsten as its inner liner.The feasibility of this design was evaluated through penetration tests.Double-layer charge liners were fabricated by using CVD to deposit tungsten layers on the inner surfaces of pure T2 copper liners.The microstructures of the tungsten layers were analyzed using a scanning electron microscope(SEM).The feasibility analysis was carried out by pulsed X-rays,slug-retrieval test and static penetration tests.The shaped charge jet forming and penetration law of inner tungsten-coated double-layer liner were studied by numerical simulation method.The results showed that the double-layer liners could form well-shaped jets.The errors between the X-ray test results and the numerical results were within 11.07%.A slug-retrieval test was found that the retrieved slug was similar to a numerically simulated slug.Compared with the traditional pure copper shaped charge jet,the penetration depth of the double-layer shaped charge liner increased by 11.4% and>10.8% respectively.In summary,the test results are good,and the numerical simulation is in good agreement with the test,which verified the feasibility of using the CVD method to fabricate double-layer charge liners with a high-density and high-strength refractory metal as the inner liner.展开更多
Infrared microthermometry allows direct measurement of fluid inclusions hosted in opaque ore minerals and can provide direct constraints on the evolution of ore-forming fluids.This study presents infrared microthermom...Infrared microthermometry allows direct measurement of fluid inclusions hosted in opaque ore minerals and can provide direct constraints on the evolution of ore-forming fluids.This study presents infrared microthermometry of spherite-hosted fluid inclusions from the Xinqiao deposit in the Middle-Lower Yangtze Metallogenic Belt and sheds new light on the ore genesis of the deposit.Considering that infrared light may lead to non-negligible temperature deviations during microthermometry,some tests were first conducted to ensure the accuracy of the microthermometric measurements.The measurement results indicated that using the lowest light intensity of the microscope and inserting an optical filter were effective in minimizing the possible temperature deviations of infrared microthermometry.All sphalerite-hosted fluid inclusions from the Xinqiao deposit were aqueous.They show homogenization temperature ranging from~200 to 350℃,but have two separate salinity groups(1.0 wt%-10 wt%and 15.1 wt%-19.2 wt%NaCl equivalent).The low-salinity group represents sedimentary exhalative(SEDEX)-associated fluids,whereas the high-salinity group results from modification by later magmatic hydrothermal fluids.Combined with published fluid inclusion data,the four-stage fluid evolution of the Xinqiao deposit was depicted.Furthermore,our data suggest that the Xinqiao deposit was formed by twostage metallogenic events including SEDEX and magmatic-hydrothermal mineralization.展开更多
基金Supported by Jilin Provincial Scientific and Technological Development Program(20230508109RC,20230201051GX,20220201091GX)National Natural Science Foundation of China(62035013,61275235)。
文摘Aqueous zinc-ion electrochromic(EC)technology,boasting the capability to fulfill both safety and cost-ef⁃fectiveness requirements,is garnering extensive attention in various application areas including smart windows,thermal management,displays,and camouflage.However,typical inorganic EC materials,such as tungsten oxides(WO_(3)),of⁃ten suffer from slow ion diffusion kinetics and limited optical contrast within the aqueous Zn^(2+)electrolyte because of the large size and strong Coulombic interactions of the Zn^(2+),which limits their wide applicability.Here,ordered WO_(3)nanowire films,constructed by a one-step grazing angle deposition method,is demonstrated to boost the response speed and optical contrast during EC phenomena.Compared with dense films,the ordered WO_(3)nanowire films with a porosity of 44.6%demonstrate anti-reflective property and excellent comprehensive EC performance,including fast response time(3.6 s and 1.2 s for coloring and bleaching,respectively),large optical contrast(66.6%at 700 nm)and high col⁃oration efficiency(64.3 cm^(2)·C^(-1)).A large-area prototype EC device(17 cm×12 cm)with fast color-switching is also successfully achieved.Mechanistic studies show that the improved performance is mainly due to the ordered porous nanowire structures,which provides direct electron transfer paths and sufficient interfacial contacts,thus simultaneously enhancing the electrochemical activity and fast redox kinetics.This study provides a simple and effective strategy to im⁃prove the performance of tungsten oxide-based aqueous zinc ion EC materials and devices.
基金partially supported by the National Natural Science Foundation of China(22479022)Liaoning Revitalization Talents Program(XLYC2007129)。
文摘Aqueous zinc metal batteries(ZMBs)which are environmentally benign and cheap can be used for grid-scale energy storage,but have a short cycling life mainly due to the poor reversibility of zinc metal anodes in mild aqueous electrolytes.A zincophilic carbon(ZC)layer was deposited on a Zn metal foil at 450°C by the up-stream pyrolysis of a hydrogen-bonded supramolecular substance framework,as-sembled from melamine(ME)and cyanuric acid(CA).The zincophilic groups(C=O and C=N)in the ZC layer guide uniform zinc plating/stripping and eliminate dendrites and side reactions.so that assembled symmetrical batteries(ZC@Zn//ZC@Zn)have a long-term service life of 2500 h at 1 mA cm^(−2) and 1 mAh cm^(−2),which is much longer than that of bare Zn anodes(180 h).In addition,ZC@Zn//V2O5 full batteries have a higher capacity of 174 mAh g^(−1) after 1200 cycles at 2 A g^(−1) than a Zn//V_(2)O_(5) counterpart(100 mAh g^(−1)).The strategy developed for the low-temperat-ure deposition of the ZC layer is a new way to construct advanced zinc metal anodes for ZMBs.
基金Project(2021YFC2801904) supported by the National Key R&D Program of ChinaProject(KY10100230067) supported by the Basic Product Innovation Research Project,China+3 种基金Projects(52271130,52305344) supported by the National Natural Science Foundation of ChinaProject(ZR2022QE073) supported by the Natural Science Foundation of Shandong Province,ChinaProject(AMGM2021F01) supported by the Science Fund of Shandong Laboratory of Advanced Materials and Green Manufacturing at Yantai,ChinaProject(KY90200210015) supported by Leading Scientific Research Project of CNNC,China。
文摘In this work,ultrasonic energy field assistance combined with tempering treatment is proposed to improve the microstructure and mechanical properties of A517Q alloy steel fabricated by laser directed energy deposition(LDED).The effects of ultrasonic vibration(UV)and tempering treatment on microstructure evolution,microhardness distribution and mechanical properties of deposition layer were studied in detail.The microstructure of UV assisted LDED sample after tempering is mainly composed of tempered sorbite(TS).Due to the improvement of microstructure inhomogeneity and grains refinement,UV assisted LDED sample with tempering treatment obtains excellent mechanical properties.The ultimate tensile strength(UTS),yield strength(YS)and elongation after breaking(EL)reach 765 MPa,657 MPa and 19.5%,the increase ratios of UTS and YS are 14.5%and 33.8%while maintaining plasticity compared to original LDED sample,respectively.It is obvious that ultrasonic vibration combined with tempering is a potential and effective method to obtain uniform microstructure and excellent mechanical properties in metal laser directed energy deposition field.
基金Project(SQ2013CB021013)supported by the National Key Basic Research Program of ChinaProject(41002045)supported by the National Natural Science Foundation of China
文摘A systematic analysis of southwestern Ordos Basin's sedimentary characteristics,internal architectural element association styles and depositional model was illustrated through core statistics,well logging data and outcrop observations in Chang 8 oil-bearing group.This analysis indicates that shallow water delta sediments dominated by a fluvial system is the primary sedimentary system of the Chang 8 oil-bearing group of the Yanchang Formation in southwestern Ordos Basin.Four microfacies with fine grain sizes are identified: distributary channels,sheet sandstone,mouth bar and interdistributary fines.According to the sandbody's spatial distribution and internal architecture,two types of sandbody architectural element associations are identified: amalgamated distributary channels and thin-layer lobate sandstone.In this sedimentary system,net-like distributary channels at the delta with a narrow ribbon shape compose the skeleton of the sandbody that extends further into the delta front and shades into contiguous lobate distribution sheet sandstone in the distal delta front.The mouth bar is largely absent in this system.By analyzing the palaeogeomorphology,the palaeostructure background,sedimentary characteristics,sedimentary facies types and spatial distribution of sedimentary facies during the Chang 8 period,a distinctive depositional model of the Chang 8 shallow water fluvial-dominated delta was established,which primarily consists of straight multi-phase amalgamated distributary channels in the delta plain,net-like distributary channels frequently diverting and converging in the proximal delta front,sheet sandstones with dispersing contiguous lobate shapes in the distal delta front,and prodelta or shallow lake mudstones.
基金Projects(41173055,41772118)supported by the National Natural Science Foundation of China
文摘Based on the element geochemistry and biomarkers of the oil shale from the Chang 7 sub-unit in the southern Ordos Basin,the depositional conditions and organic source of the oil shale are discussed.Biomarkers analyses show that the oil shale has a homologous organic matter source,with a mix of plankton and advanced plants.U/Th and V/Ni ratios suggest that the redox condition is dominated by a reducing condition,and the degree of anoxia in the Tongchuan area is higher than that of the Xunyi area.Sr/Ba ratios illustrate that the oil shale is deposited in fresh water and the paleosalinity in the Tongchuan area is slightly higher.Fe/Ti ratios imply that the Tongchuan area underwent obvious hydrothermal fluid activities.Sr/Cu ratios show warm and humid paleoclimate in both areas.As assessed by(La/Yb)NASC,the deposition rate in the Tongchuan area is relatively lower.Fe/Co and Th/U ratios suggest that the paleo-water-depth in the Tongchuan area is deeper.The source rock could have the advance plants source,which must have close relationship with the Qinling orogeny.Comparing the paleoenvironment,the Tongchuan area has better depositional conditions,and is the key oil shale exploration area in the southern Ordos Basin.
基金Projects(41506080,41702162)supported by the National Natural Science Foundation of ChinaProjects(DD20160152,DD20160147,GZH200800503)supported by China Geological Survey+1 种基金Projects(XQ-2005-01,2009GYXQ10)supported by China Ministry of Land and ResourcesProject(201602004)supported by the Postdoctoral Innovation Foundation of Shandong Province,China
文摘In the South Yellow Sea Basin,Mesozoic–Paleozoic marine strata are generally well developed with large thickness,and no substantial breakthroughs have been made in hydrocarbon exploration.Through research,it is believed that the Upper Permian–Lower Triassic can be regarded as a long-term base-level cycle.Based on drilling data,characteristics of the lithology–electric property combination cyclicity,and the special lithology,the long-term base-level cycle was divided into five medium-term base-level cycles(MC1–MC5).On this basis,the Permian–Triassic sedimentary systems and their filling model were analyzed in accordance with the change of base-level cycle and transition of sedimentary environment,as well as characteristics of the drilling sedimentary facies and seismic facies.The results show that there were six sedimentary systems(fluvial,delta,tidal flat,open platform,restricted platform,and continental shelf)developed in the Upper Permian–Lower Triassic,the sedimentary systems were distributed such that the water was deep in the northwest and shallow in the southeast,and there were two base-level cycle filling models(a relatively stable tidal flat facies and a rapidly transgressive continental shelf facies to stable platform facies)developed in the Upper Permian–Lower Triassic.These models can provide a basis for evaluation of the Mesozoic–Paleozoic hydrocarbon geology in the South Yellow Sea Basin.
基金theNationalNaturalScienceFoundationofChina (No ..4982 5 10 2 )
文摘The uppermost Jurassic to Lower Cretaceous in the Qomolongma (Mt. Everest) area were deposited in a strong subsiding setting on passive continental margin. From Tithonian to Valanginian, the area experienced an environment shift from circum\|shelf margin carbonate platform to foreslope, then to deep continental slope [1] . Correspondingly, the sediments change in vertical succession from quartz sandstone, via carbonate grainstone to dark shale intercalated with lithic sandstone of gravity flow. From the Tithonian to Valanginian, eight 3rd\|order sequences have been recognized [1] with clearly delineated sequence boundaries and reasonable biostratigraphic controls of ammonites. From the angle of sequence stratigraphy and sedimentary cycles, the important change happened at ca. 138Ma [2] of the Lower Tithonian (about 120m above Aulacosphinctoides hybonotum zone), where a waved subaerial erosion surface occurs in massive bioclastic grainstone. The boundary at ca. 134 5Ma (latest Tithonian, about 60m below the FAD of \%Berriasella cf. jacobi [3] ) comes to the next. The third one is at ca 132Ma (some 170m above the FAD of Berriasella cf. jacobi [3] , but about 60m below the FAD of Berriasella cf. grandis [3] ). In terms of sea\|level change, the sequence boundary at 134 5Ma is probably the most distinctive one, above which some 60m gravel\|bearing massive medium\|grained quartz sandstone was laid down and obviously truncates the underlying strata. In the dark shale below the sandstone, abundant in ammonites, such as Virgatosphinctes, Aulacosphinctes, Haplophylloceras and Gymnosphinctes are recorded [3] . The quartz sandstone itself does not bear identifiable fossils. Above the quartz sandstone, the strata mainly consists of dark silty shale up to 180m thick, with an prominent marine transgression at the base. Just above the first flooding surface (FFS), quite a number of ammonites such as \%Berriasella\% cf. \%jacobi, Blanofordiceras, Hymalayaites\% and \%Pseudosubplanites \%are documented [3] . The third sequence, which is delineated by submarine truncation of slope fan complexes at bottom, is also characterized by dark shale and silts, yielding ammonites \%Berriasella \%cf. \%grandis\% and B. cf. \%berthei.\%>From the viewpoint of sequence stratigraphy, we herein suggest to take the FFS in the second sequence as the J/K boundary. The sequence boundary below it can be used as a nice auxiliary marker, which represents a large sea\|level fall, and can be correlated widely in the world. From the angle of paleontology, the FFS is also ideal for the boundary, where the most important faunal turnover happened. Theoretically, taking FFS as a chronostratigraphic boundary has more advantages than using sequence boundary.
基金Supported by the project of China Petroleum & Chemical Corporation,the present paper is aimed at the late Mesozoic sedimentary features and basin evolution of the western segment of Bailongjiang Uplift Zone in the Songpan area
文摘On the basis of history study and the depositional study the systematic investigation of late Mesozoic sedimentary features and basin evolution are conducted.The architectural elements analysis of sedimentary environment shows that the depositional environment of the early Jurassic in late Mesozoic basin(Gahai basin) in the study area is lacustrine environment,and is further
文摘The Gamba—Tingri basin lies in south Tethys Himalaya subzone. It is 400km in length from east to west, and 30~50km in width from north to south. The basin is mainly made up of marine Mesozoic and Lower Cenozoic, i.e., Jurassic, Cretaceous, and Lower Tertiary. Its total strata are more than 3100m in thickness. The passive continental margin of the India plate developed during Jurassic—Cretaceous after a Triassic rifting stage. Collision took place between the India and the Eurasian plate during the latest Cretaceous and earliest Tertiary (Liu and Einsele, 1994), which resulted in a Tertiary residual basin.The Jurassic stratigraphic system in the Gamba—Tingri basin were not carried out until recently (Wan et al., 1999), which is divided into three formations, i.e.., Pupuga Fm., Nieniexiongla Fm., and Menkadun Fm.. The Cretaceous and Tertiary stratigraphic system is after Wan (1985) and Xu et al.(1990), which the Cretaceous is divided into six formations: Dongsan Fm., Chaqiela Fm., Lengqingle Fm., Xiawuchubo Fm., Jiubao Fm., and Zongshan Fm, whereas the Tertiary is divided into Jiabula Fm. Zongpu Fm., and Zhepure Fm.
基金funded by the China Postdoctoral Science Foundation(Grant No.2022M721614)the opening project of State Key Laboratory of Explosion Science and Technology,Beijing Institute of Technology(Grant No.KFJJ23-07M)。
文摘This paper proposes a type of double-layer charge liner fabricated using chemical vapor deposition(CVD)that has tungsten as its inner liner.The feasibility of this design was evaluated through penetration tests.Double-layer charge liners were fabricated by using CVD to deposit tungsten layers on the inner surfaces of pure T2 copper liners.The microstructures of the tungsten layers were analyzed using a scanning electron microscope(SEM).The feasibility analysis was carried out by pulsed X-rays,slug-retrieval test and static penetration tests.The shaped charge jet forming and penetration law of inner tungsten-coated double-layer liner were studied by numerical simulation method.The results showed that the double-layer liners could form well-shaped jets.The errors between the X-ray test results and the numerical results were within 11.07%.A slug-retrieval test was found that the retrieved slug was similar to a numerically simulated slug.Compared with the traditional pure copper shaped charge jet,the penetration depth of the double-layer shaped charge liner increased by 11.4% and>10.8% respectively.In summary,the test results are good,and the numerical simulation is in good agreement with the test,which verified the feasibility of using the CVD method to fabricate double-layer charge liners with a high-density and high-strength refractory metal as the inner liner.
基金supported by the National Key R&D Program of China(2018YFA0702701)the Fundamental Research Funds for the Central Universities(WK3410000015).
文摘Infrared microthermometry allows direct measurement of fluid inclusions hosted in opaque ore minerals and can provide direct constraints on the evolution of ore-forming fluids.This study presents infrared microthermometry of spherite-hosted fluid inclusions from the Xinqiao deposit in the Middle-Lower Yangtze Metallogenic Belt and sheds new light on the ore genesis of the deposit.Considering that infrared light may lead to non-negligible temperature deviations during microthermometry,some tests were first conducted to ensure the accuracy of the microthermometric measurements.The measurement results indicated that using the lowest light intensity of the microscope and inserting an optical filter were effective in minimizing the possible temperature deviations of infrared microthermometry.All sphalerite-hosted fluid inclusions from the Xinqiao deposit were aqueous.They show homogenization temperature ranging from~200 to 350℃,but have two separate salinity groups(1.0 wt%-10 wt%and 15.1 wt%-19.2 wt%NaCl equivalent).The low-salinity group represents sedimentary exhalative(SEDEX)-associated fluids,whereas the high-salinity group results from modification by later magmatic hydrothermal fluids.Combined with published fluid inclusion data,the four-stage fluid evolution of the Xinqiao deposit was depicted.Furthermore,our data suggest that the Xinqiao deposit was formed by twostage metallogenic events including SEDEX and magmatic-hydrothermal mineralization.