The coupling reactions of methanol and long-chain alkanes(n-dodecane,n-tetradecane and n-hexadecane)over CHA-type molecular sieves were studied in a fixed bed reactor.Over SAPO-34 and SSZ-13,it was found that the indu...The coupling reactions of methanol and long-chain alkanes(n-dodecane,n-tetradecane and n-hexadecane)over CHA-type molecular sieves were studied in a fixed bed reactor.Over SAPO-34 and SSZ-13,it was found that the induction period of methanol conversion was shortened by the introduction of long-chain alkanes.However,the addition of long-chain alkanes had little influence on the product distribution.Polymethylbenzenes and the derivatives were the main retained species on spent SSZ-13 catalyst,while adamantanes were the main retained species on SAPO-34.This indicates that coking species formation was mainly related to the further transformation of long-chain alkane/methanol coupling products at acid sites of the molecular sieve.These findings provide valuable information of long chain alkanes conversion and methanol reaction behavior of induction period over small pore CHA molecular sieves.展开更多
Aiming at the problem of dynamic instability of hard-brittle jointed rock surrounding in deep tunnel/roadway engineering,combining with the support concepts of"coupling rigidity with flexibility"and"ove...Aiming at the problem of dynamic instability of hard-brittle jointed rock surrounding in deep tunnel/roadway engineering,combining with the support concepts of"coupling rigidity with flexibility"and"overcoming rigidity by flexibility",the prevention and control method with"rigid-flexible coupling(R-F-C)"was put forward.Through numerical simulation calculation,the impact damage process,acoustic emission(AE)evolution characteristics,and element stress/displacement evolution characteristics of unsupported surrounding rock structure model,rigid supporting surrounding rock structure model,and"R-F-C"supporting surrounding rock structure model under horizontal bidirectional impact loading were compared and analyzed.Based on the theory of stress wave propagation,the dynamic instability catastrophe mechanism of three kinds of supporting structure models induced by horizontal bidirectional impact loading was revealed.Based on the Mohr-Coulomb strength theory,the stress discrimination methods of dynamic catastrophe of surrounding rock induced by horizontal bidirectional impact loading under three kinds of supporting structures were proposed.Combined with the above numerical simulation study,the explosion impact physical and mechanical test of"R-F-C"surrounding rock supporting plate structure was further designed and carried out.Finally,combined with the"conceptual model of ball-cliff potential energy instability",the energy driving theory and energy transformation mechanism of impact-induced rockburst under three kinds of supporting structures were discussed deeply.The research results provided a scientific basis for further promoting the effective application of"R-F-C"supporting structure in the prevention and control of dynamic instability of deep tunnel/roadway surrounding rock.展开更多
To investigate the effects of water and cyclic loading on dolomite’s mechanical properties during deep mining,mechanical experiments on non-pressure water absorption and cyclic loading were conducted.The findings rev...To investigate the effects of water and cyclic loading on dolomite’s mechanical properties during deep mining,mechanical experiments on non-pressure water absorption and cyclic loading were conducted.The findings reveal that the elastic modulus and Poisson ratio of dolomite fluctuate with increasing water content.The mass of water absorption is positively correlated with time and the water absorption stage can be divided into three stages:accelerated,decelerated,and stabilized stages.During this process,the number of pores in dolomite increases,while the pore diameter initially decreases and then fluctuates.Microscopic analysis shows that the proportion of mesopores first increases and then decreases,while micropores exhibit the opposite trend,and the proportion of macropores fluctuates around 0%.A model diagram of structural evolution during water absorption has been developed.Additionally,the softening process of dolomite’s water absorption strength is categorized into three stages:a relatively stable stage,an accelerated softening stage dominated by mesopore water absorption,and a decelerated softening stage characterized by micropore water absorption.A uniaxial damage constitutive model for dolomite under water influence was established based on the Weibull distribution and Mohr-Coulomb strength criterion,and experimental validation indicates its strong applicability.展开更多
For space-borne gravitational wave detection missions based on the heterodyne interferometry principle,tilt-to-length(TTL)coupling noise is an important optical noise source,significantly influencing the accuracy of t...For space-borne gravitational wave detection missions based on the heterodyne interferometry principle,tilt-to-length(TTL)coupling noise is an important optical noise source,significantly influencing the accuracy of the measurement system.We present a method for analyzing TTL coupling noise under the joint influence of multiple factors.An equivalent simulated optical bench for the test mass interferometer was designed,and Gaussian beam tracing was adopted to simulate beam propagation.By simulating the interference signal,it can analyze the impact of various factors on the TTL coupling noise,including positional,beam parameters,detector parameters,and signal definition factors.On this basis,a random parameter space composed of multiple influential factors was constructed within a range satisfying the analysis requirement,and the corresponding simulation results from random sampling were evaluated via variance-based global sensitivity analysis.The calculated results of the main and total effect indexes show that the test mass rotation angle and the piston effect(lateral)significantly influence the TTL coupling noise in the test mass interferometer.The analysis provides a qualitative reference for designing and optimizing space-borne laser interferometry systems.展开更多
The Majorana zero modes in vortex cores are of extensive interest in the context of topological quantum computing.However,a zero-energy bound state may arise accidentally but is not necessarily a Majorana zero mode.Su...The Majorana zero modes in vortex cores are of extensive interest in the context of topological quantum computing.However,a zero-energy bound state may arise accidentally but is not necessarily a Majorana zero mode.Such accidental zero modes should be carefully ruled out in experiment in order to identify the genuine Majorana zero modes.We show that in a spin-orbital coupled multi-band superconductor,such as the iron-selenide superconductor,accidental zero modes indeed arise in the vortex core if the pairing symmetry is the so-called nodeless d-wave(defined in the absence of spin-orbital coupling).Instead,if the pairing sym-metry is s_(++)or s_(+−)with respect to the Fermi pockets split by the spin-orbital coupling,the accidental zero modes do not appear in the limit of weak spin-orbital coupling.Our results are not only important in the experimental identification of Majorana zero modes,but also provide an avenue to pinpoint the pairing symmetry of the iron-selenide superconductor.展开更多
Photocatalytic ammonia(NH_(3))decomposition is a key strategy for green hydrogen production and renewable energy conversion.Although conventional plasmonic metal/TiO_(2) composites exhibit some activity,their applicat...Photocatalytic ammonia(NH_(3))decomposition is a key strategy for green hydrogen production and renewable energy conversion.Although conventional plasmonic metal/TiO_(2) composites exhibit some activity,their applications are constrained by high carrier recombination rates and narrow light harvesting ranges.To address these challenges,this study innovatively introduces the plasmonic semiconductor MoO_(3-x),which is characterized by broad-spectrum absorption and abundant oxygen vacancies,to construct a Cu-MoO_(3-x)/TiO_(2) plasmon resonance coupling nanostructure.The construction of the Cu-MoO_(3-x) composite stabilizes Cu via MoO_(3-x) coating and facilitates electron transfer from Cu to MoO_(3-x),generating more oxygen vacancies for NH_(3) activation.The visible localized surface plasmon resonance(LSPR)response of Cu,coupled with the visible to near-infrared LSPR resonance of MoO_(3-x),broadens the spectral response and optimizes carrier dynamics,thereby reducing the recombination of photogenerated carriers.The use of hot carriers and plasmonic photothermal effects synergistically accelerate surface reaction kinetics and enhance photocatalytic efficiency.In particular,the optimal Cu-MoO_(3-x)/TiO_(2) catalyst results in an enhanced NH_(3) decomposition rate of 103.2 mmol·g^(-1)·h^(-1) under fullspectrum light irradiation,representing 29-fold and 94-fold enhancements over those of Cu/TiO_(2) and MoO_(3-x)/TiO_(2),respectively.This innovative design strategy transcends traditional plasmonic metal/semiconductor catalyst designs and opens new avenues for developing efficient solar-driven plasmon resonance coupling catalysts.展开更多
A radical C−C-coupling reaction of acetonitrile into succinonitrile over hydrophobic TiO_(2) photocatalyst with enhanced catalytic activity was developed.In addition,the usage of a flow reactor further improved the ph...A radical C−C-coupling reaction of acetonitrile into succinonitrile over hydrophobic TiO_(2) photocatalyst with enhanced catalytic activity was developed.In addition,the usage of a flow reactor further improved the photon utilization efficiency for succinonitrile synthesis at room temperature.The space time yield of succinonitrile reached 55.59μmol/(g·h)over hydrophobic TiO_(2) catalyst,which was much higher than that of pristine TiO_(2)(4.23μmol/(g·h)).Mechanistic studies revealed that the hydrophobic modification of TiO_(2) promoted the separation and transfer of photogenerated carriers,as well as suppressed their recombination.Hydrophobic TiO_(2) also enhanced the adsorption of−CH3 of acetonitrile,thus facilitating the activation of C−H bond and the utilization efficiency of photocarriers.展开更多
In this study,a series of triaxial tests are conducted on sandstone specimens to investigate the evolution of their mechanics and permeability characteristics under the combined action of immersion corrosion and seepa...In this study,a series of triaxial tests are conducted on sandstone specimens to investigate the evolution of their mechanics and permeability characteristics under the combined action of immersion corrosion and seepage of different chemical solutions.It is observed that with the increase of confining pressure,the peak stress,dilatancy stress,dilatancy stress ratio,peak strain,and elastic modulus of the sandstone increase while the Poisson ratio decreases and less secondary cracks are produced when the samples are broken.The pore pressure and confining pressure have opposite influences on the mechanical properties.With the increase of the applied axial stress,three stages are clearly identified in the permeability evolution curves:initial compaction stage,linear elasticity stage and plastic deformation stage.The permeability reaches the maximum value when the highest volumetric dilatancy is obtained.In addition,the hydrochemical action of salt solution with pH=7 and 4 has an obvious deteriorating effect on the mechanical properties and induces the increase of permeability.The obtained results will be useful in engineering to understand the mechanical and seepage properties of sandstone under the coupled chemical-seepage-stress multiple fields.展开更多
Cutting off or controlling the enemy’s power supply at critical moments or strategic locations may result in a cascade failure,thus gaining an advantage in a war.However,the exist-ing cascading failure modeling analy...Cutting off or controlling the enemy’s power supply at critical moments or strategic locations may result in a cascade failure,thus gaining an advantage in a war.However,the exist-ing cascading failure modeling analysis of interdependent net-works is insufficient for describing the load characteristics and dependencies of subnetworks,and it is difficult to use for model-ing and failure analysis of power-combat(P-C)coupling net-works.This paper considers the physical characteristics of the two subnetworks and studies the mechanism of fault propaga-tion between subnetworks and across systems.Then the surviv-ability of the coupled network is evaluated.Firstly,an integrated modeling approach for the combat system and power system is predicted based on interdependent network theory.A heteroge-neous one-way interdependent network model based on proba-bility dependence is constructed.Secondly,using the operation loop theory,a load-capacity model based on combat-loop betweenness is proposed,and the cascade failure model of the P-C coupling system is investigated from three perspectives:ini-tial capacity,allocation strategy,and failure mechanism.Thirdly,survivability indexes based on load loss rate and network sur-vival rate are proposed.Finally,the P-C coupling system is con-structed based on the IEEE 118-bus system to demonstrate the proposed method.展开更多
The pantograph cavity coupling system(PCCS)of high-speed trains,as a representative region for aerodynamic noise generation,merits further investigation into its scale effects.In this paper,the large-eddy simulation(L...The pantograph cavity coupling system(PCCS)of high-speed trains,as a representative region for aerodynamic noise generation,merits further investigation into its scale effects.In this paper,the large-eddy simulation(LES)and the Ffowcs Williams-Hawkings(FW-H)integral equation are used to calculate and analyze the sound energy intensity distribution pattern and spectral characteristics of the PCCS at different scales(1/1,1/2,1/4,1/8,1/16,1/25,1/50).The research shows that as the scaled model decreases,the relative area of the pantograph submerged by the vehicle boundary layer increases,and its inflow velocity decreases,thereby reducing the overall radiated sound pressure level in this area.For the segments 1/1-1/2 and 1/4-1/16,the dominant scale of sound generation is typical pure tone noise,with distinct similar features in the spectral discrete scales.For the segments 1/25-1/50,the turbulent fluctuation characteristics of the vehicle boundary layer mask the peak features,and the spectrum is dominated by broadband characteristics.Combining the PCCS sound source energy scale correction model and the dimensionless spectrum correction function,a scale correction model for the sound power spectrum of the sound source is obtained,so that the noise results of the reduced-scale model can be corresponded to the full-scale model.This work advances the comprehension of high-speed train aerodynamic noise generation mechanisms and offers critical references for developing precision noise control technologies.展开更多
The spin-exchange relaxation-free atomic gyroscope,with its exceptionally high theoretical precision,demonstrates immense potential to become the next-generation strategic-grade gyroscope.However,due to technological ...The spin-exchange relaxation-free atomic gyroscope,with its exceptionally high theoretical precision,demonstrates immense potential to become the next-generation strategic-grade gyroscope.However,due to technological noise,there is still a significant gap between its actual precision and theoretical precision.This study identifies the key factor limiting the precision of the SERF gyroscope as coupling noise.By optimizing the detection loop structure,a distinction between the dual-axis signals'response to optical and magnetic fields was achieved-where the optical errors responded similarly,while the response to magnetic noise was opposite.Based on the differences in the optical-magnetic response of the dual-axis signals,empirical mode decomposition was used to decompose the dual-axis gyroscope signals into multiple intrinsic mode functions,and Allan deviation analysis was applied to analyze the noise characteristics of the intrinsic mode functions over various periods.This study successfully reveals that optical errors caused by thermal-optical coupling and long-period magnetic noise induced by thermal-magnetic coupling are the dominant factors limiting the long-term stability of the SERF gyroscope.Based on these analyses,the study concludes that to achieve strategic-grade precision for the SERF gyroscope,it is essential to effectively address the noise issues caused by multi-physical field couplings.展开更多
Hypersonic morphing vehicle(HMV)can reconfigure aerodynamic geometries in real time,adapting to diverse needs like multi-mission profiles and wide-speed-range flight,spanwise morphing and sweep angle variation are rep...Hypersonic morphing vehicle(HMV)can reconfigure aerodynamic geometries in real time,adapting to diverse needs like multi-mission profiles and wide-speed-range flight,spanwise morphing and sweep angle variation are representative large-scale wing reconfiguration modes.To meet the HMV's need for an increased lift and a lift to drag ratio during hypersonic maneuverability and cruise or reentry equilibrium glide,this paper proposes an innovative single-DOF coupled morphing-wing system.We then systematically analyze its open-loop kinematics and closed-loop connectivity constraints,and the proposed system integrates three functional modules:the preset locking/release mechanism,the coupled morphing-wing mechanism,and the integrated wing locking with active stiffness control mechanism.Experimental validation confirms stable,continuous morphing under simulated aerodynamic loads.The experimental results indicate:(i)SMA actuators exhibit response times ranging from 18 s to 160 s,providing sufficient force output for wing unlocking;(ii)The integrated wing locking with active stiffness control mechanism effectively secures wing positions while eliminating airframe clearance via SMA actuation,improving the first-order natural frequency by more than 17%;(iii)The distributed aerodynamic loading system enables precise multi-stage follow-up loading during morphing,with the coupled morphing wing maintaining stable,continuous operation under 0-3500 N normal loads and 110-140 N axial force.The proposed single-DOF coupled morphing mechanism not only simplifies and improves structural efficiency but also demonstrates superior performance in locking control,stiffness enhancement,and aerodynamic responsiveness.This establishes a foundational framework for the design of future intelligent morphing configurations and the implementation of flight control systems.展开更多
This paper prepared a novel as-cast W-Zr-Ti metallic ESM using high-frequency vacuum induction melting technique.The above ESM performs a typical elastic-brittle material feature and strain rate strengthening behavior...This paper prepared a novel as-cast W-Zr-Ti metallic ESM using high-frequency vacuum induction melting technique.The above ESM performs a typical elastic-brittle material feature and strain rate strengthening behavior.The specimens exhibit violent chemical reaction during the fracture process under the impact loading,and the size distribution of their residual debris follows Rosin-Rammler model.The dynamic fracture toughness is obtained by the fitting of debris length scale,approximately 1.87 MPa·m~(1/2).Microstructure observation on residual debris indicates that the failure process is determined by primary crack propagation under quasi-static compression,while it is affected by multiple cracks propagation in both particle and matrix in the case of dynamic impact.Impact test demonstrates that the novel energetic fragment performs brilliant penetration and combustion effect behind the front target,leading to the effective ignition of fuel tank.For the brittleness of as-cast W-ZrTi ESM,further study conducted bond-based peridynamic(BB-PD)C++computational code to simulate its fracture behavior during penetration.The BB-PD method successfully captured the fracture process and debris cloud formation of the energetic fragment.This paper explores a novel as-cast metallic ESM,and provides an available numerical avenue to the simulation of brittle energetic fragment.展开更多
Based on the model which couples the projectile and gun barrel during an interior ballistic cycle,the uncertainty propagation analysis of the model is presented caused by the uncertainty of the input parameters.The Bo...Based on the model which couples the projectile and gun barrel during an interior ballistic cycle,the uncertainty propagation analysis of the model is presented caused by the uncertainty of the input parameters.The Bootstrap method is employed to calculate the statistical moments(i.e.the mean,variance,skewness coefficient and kurtosis coefficient)of the parameters of the projectile.Meanwhile,the maximum entropy method is used to estimate the probability density function(PDF)and the cumulative density function(CDF),the interval of the parameters of the projectile are also given.Moreover,the results obtained are compared to the results calculated by Monte Carlo(MC)method to verify the effectiveness of the presented method.Finally,the rule and the uncertainty propagation model of the projectile-barrel coupling system are given with the variation of the uncertainties of the input parameters.展开更多
Uplift\|related geological and geophysical data available from regional geological mapping , detailed structural, tectonic, granitic, volcanic, metamorphic , geochronological studies, deep seismic reflection, wide\|an...Uplift\|related geological and geophysical data available from regional geological mapping , detailed structural, tectonic, granitic, volcanic, metamorphic , geochronological studies, deep seismic reflection, wide\|angle seismic experiment, seismic tomography, broadband seismic network, and magnetotelluric sounding of key areas of the Qinghai—Tibet plateau are radically different from models of plate subduction or collision. Key geological features include: (1) obvio us time difference between plate collision and uplift of the plateau; (2) developments of intracrustal low\|velocity layers , low resistivity layers and discontinuous subhorizontal reflectors; (3) similar results between the rate and time of uplift of the Qinghai\|Tibet plateau and the time and rate of subsidence of its surrounding basins; (4) subhorizontal detachments and metamorphic core complexes occurred in Himalayan and Longmenshan; (5) weak deformation of late Cenozoic sediments and development of major steeply to gently dipping normal faults in the central part of the plateau; (6) discovery of high pressure and ultrahigh pressure metamorphic rocks in Nanbajiawa; (7) young volcanic rocks distributed from the northern plateau to the southern plateau; (8) nearly concordant processes among thrusting , mountain building, horizontal extension and intrusion of leucogranite in Himalayans.展开更多
The paper probes into a probable condition that causes temper mill chatter from aspect of electromechanical coupling of complex electromechanical system, and mainly studies the effect of temper mill electrical driving...The paper probes into a probable condition that causes temper mill chatter from aspect of electromechanical coupling of complex electromechanical system, and mainly studies the effect of temper mill electrical driving system harmonic current on the main motion of temper mill set. Aiming at the electrical driving system of CM04 temper mill, the effect of harmonic current is analyzed and evaluated according to different load. Combining the features of CM04 temper mill′s structure and its working state, the paper discusses in every detail how the harmonic current in main circuit, which can be regarded as a disturbance via feedback control circuit , influences main motion of temper mill set.展开更多
Long distance buried liquid-conveying pipeline is inevitable to cross faults and under earthquake action,it is necessary to calculate fluid-structure interaction(FSI) in finite element analysis under pipe-soil interac...Long distance buried liquid-conveying pipeline is inevitable to cross faults and under earthquake action,it is necessary to calculate fluid-structure interaction(FSI) in finite element analysis under pipe-soil interaction.Under multi-action of site,fault movement and earthquake,finite element model of buried liquid-conveying pipeline for the calculation of fluid structure interaction was constructed through combinative application of ADINA-parasolid and ADINA-native modeling methods,and the direct computing method of two-way fluid-structure coupling was introduced.The methods of solid and fluid modeling were analyzed,pipe-soil friction was defined in solid model,and special flow assumption and fluid structure interface condition were defined in fluid model.Earthquake load,gravity and displacement of fault movement were applied,also model preferences.Finite element research on the damage of buried liquid-conveying pipeline was carried out through computing fluid-structure coupling.The influences of pipe-soil friction coefficient,fault-pipe angle,and liquid density on axial stress of pipeline were analyzed,and optimum parameters were proposed for the protection of buried liquid-conveying pipeline.展开更多
The dynamics of spatial parallel manipulator with rigid and flexible links is explored. Firstly, a spatial beam element model for finite element analysis is established. Then, the differential equation of motion of be...The dynamics of spatial parallel manipulator with rigid and flexible links is explored. Firstly, a spatial beam element model for finite element analysis is established. Then, the differential equation of motion of beam element is derived based on finite element method. The kinematic constraints of parallel manipulator with rigid and flexible links are obtained by analyzing the motive parameters of moving platform and the relationships of movements of kinematic chains, and the overall kinetic equation of the parallel mechanism with rigid and flexible links is derived by assembling the differential equations of motion of components. On the basis of abovementioned analyses, the dynamic mechanical analysis of the spatial parallel manipulator with rigid and flexible links is conducted. After obtaining the method for force analysis and expressions for the calculation of dynamic stress of flexible components, the dynamic analysis and simulation of spatial parallel manipulator with rigid and flexible links is performed. The result shows that because of the elastic deformation of flexible components in the parallel mechanism with rigid and flexible links, the force on each component in the mechanism fluctuates sharply, and the change of normal stress at the root of drive components is also remarkable. This study provides references for further studies on the dynamic characteristics of parallel mechanisms with rigid and flexible links and for the optimization of the design of the mechanism.展开更多
Soybean cultivar Bei 92-28 was tested in this experiment in 2000 to study the coupling effect of water and ferilizer on soybean yield.The results showed that the effect of irrigation varied among the levels of fertili...Soybean cultivar Bei 92-28 was tested in this experiment in 2000 to study the coupling effect of water and ferilizer on soybean yield.The results showed that the effect of irrigation varied among the levels of fertilizer application,and vice versa;pods per plant,seeds per pod.and 100-seed weight had positive correlations with soybean yield,but the degrees of correlations of different treatments were various;LAI and dry matter accumulation could be significantly increased when watered and applied fertilizer with different levels,but high fertilizer application treatment didn't obtain the highest yield;watering could increase the absolute absorption amount of N,P,K in seeds,but the accumulation rates were various.展开更多
In this paper, numerical simulations of FPSO ship motion coupled with LNG tank sloshing with low-filling ratios are conducted. The fully coupled problem is addressed with our own unsteady RANS solver: naoe-FOAM-SJTU d...In this paper, numerical simulations of FPSO ship motion coupled with LNG tank sloshing with low-filling ratios are conducted. The fully coupled problem is addressed with our own unsteady RANS solver: naoe-FOAM-SJTU developed based on the open source tool librar- ies of OpenFOAM. The internal tank sloshing and external wave flow are solved simultaneously. The FPSO model includes 2 LNG tanks. For the ship 3-DOFs are released in the regular beam waves. The filling ratios of the 2 tanks are 20% - 20%, lower than the external free surface. This kind of low-filling condition reduces ship roll motion significantly, and produces complex free surface shapes in tanks. 4 different incident wave frequencies are considered in the simulation in comparison with the existing experimental data. The comparison shows that the numerical re- sults are in good agreement with the experimental data, proving the reliability of the proposed method. The filling conditions with large wave amplitudes are studied further, and due to the coupling effect, violent sloshing occurs in tanks and impulsive pressure forms on bulkhead.展开更多
基金Supported by National Natural Science Foundation of China(21991093)。
文摘The coupling reactions of methanol and long-chain alkanes(n-dodecane,n-tetradecane and n-hexadecane)over CHA-type molecular sieves were studied in a fixed bed reactor.Over SAPO-34 and SSZ-13,it was found that the induction period of methanol conversion was shortened by the introduction of long-chain alkanes.However,the addition of long-chain alkanes had little influence on the product distribution.Polymethylbenzenes and the derivatives were the main retained species on spent SSZ-13 catalyst,while adamantanes were the main retained species on SAPO-34.This indicates that coking species formation was mainly related to the further transformation of long-chain alkane/methanol coupling products at acid sites of the molecular sieve.These findings provide valuable information of long chain alkanes conversion and methanol reaction behavior of induction period over small pore CHA molecular sieves.
基金Project(2023AH051167)supported by the Natural Science Research Project of Anhui Educational Committee,ChinaProject(AHBP2024B-04)supported by the Foundation of Anhui Engineering Research Center of New Explosive Materials and Blasting Technology,China+1 种基金Project(GXZDSYS2023103)supported by the Open Fund for Anhui Key Laboratory of Mining Construction Engineering,ChinaProjects(52274071,52404155)supported by the National Natural Science Foundation of China。
文摘Aiming at the problem of dynamic instability of hard-brittle jointed rock surrounding in deep tunnel/roadway engineering,combining with the support concepts of"coupling rigidity with flexibility"and"overcoming rigidity by flexibility",the prevention and control method with"rigid-flexible coupling(R-F-C)"was put forward.Through numerical simulation calculation,the impact damage process,acoustic emission(AE)evolution characteristics,and element stress/displacement evolution characteristics of unsupported surrounding rock structure model,rigid supporting surrounding rock structure model,and"R-F-C"supporting surrounding rock structure model under horizontal bidirectional impact loading were compared and analyzed.Based on the theory of stress wave propagation,the dynamic instability catastrophe mechanism of three kinds of supporting structure models induced by horizontal bidirectional impact loading was revealed.Based on the Mohr-Coulomb strength theory,the stress discrimination methods of dynamic catastrophe of surrounding rock induced by horizontal bidirectional impact loading under three kinds of supporting structures were proposed.Combined with the above numerical simulation study,the explosion impact physical and mechanical test of"R-F-C"surrounding rock supporting plate structure was further designed and carried out.Finally,combined with the"conceptual model of ball-cliff potential energy instability",the energy driving theory and energy transformation mechanism of impact-induced rockburst under three kinds of supporting structures were discussed deeply.The research results provided a scientific basis for further promoting the effective application of"R-F-C"supporting structure in the prevention and control of dynamic instability of deep tunnel/roadway surrounding rock.
基金Project(IMRI23005)supported by Ordos Science and Technology Bureau,ChinaProjects(52174096,52304110)supported by the National Natural Science Foundation of China。
文摘To investigate the effects of water and cyclic loading on dolomite’s mechanical properties during deep mining,mechanical experiments on non-pressure water absorption and cyclic loading were conducted.The findings reveal that the elastic modulus and Poisson ratio of dolomite fluctuate with increasing water content.The mass of water absorption is positively correlated with time and the water absorption stage can be divided into three stages:accelerated,decelerated,and stabilized stages.During this process,the number of pores in dolomite increases,while the pore diameter initially decreases and then fluctuates.Microscopic analysis shows that the proportion of mesopores first increases and then decreases,while micropores exhibit the opposite trend,and the proportion of macropores fluctuates around 0%.A model diagram of structural evolution during water absorption has been developed.Additionally,the softening process of dolomite’s water absorption strength is categorized into three stages:a relatively stable stage,an accelerated softening stage dominated by mesopore water absorption,and a decelerated softening stage characterized by micropore water absorption.A uniaxial damage constitutive model for dolomite under water influence was established based on the Weibull distribution and Mohr-Coulomb strength criterion,and experimental validation indicates its strong applicability.
文摘For space-borne gravitational wave detection missions based on the heterodyne interferometry principle,tilt-to-length(TTL)coupling noise is an important optical noise source,significantly influencing the accuracy of the measurement system.We present a method for analyzing TTL coupling noise under the joint influence of multiple factors.An equivalent simulated optical bench for the test mass interferometer was designed,and Gaussian beam tracing was adopted to simulate beam propagation.By simulating the interference signal,it can analyze the impact of various factors on the TTL coupling noise,including positional,beam parameters,detector parameters,and signal definition factors.On this basis,a random parameter space composed of multiple influential factors was constructed within a range satisfying the analysis requirement,and the corresponding simulation results from random sampling were evaluated via variance-based global sensitivity analysis.The calculated results of the main and total effect indexes show that the test mass rotation angle and the piston effect(lateral)significantly influence the TTL coupling noise in the test mass interferometer.The analysis provides a qualitative reference for designing and optimizing space-borne laser interferometry systems.
基金supported by National Key R&D Program of China(Grant No.2022YFA1403201)and National Natural Science Foundation of China(Grant No.12374147,12274205 and 92365203).
文摘The Majorana zero modes in vortex cores are of extensive interest in the context of topological quantum computing.However,a zero-energy bound state may arise accidentally but is not necessarily a Majorana zero mode.Such accidental zero modes should be carefully ruled out in experiment in order to identify the genuine Majorana zero modes.We show that in a spin-orbital coupled multi-band superconductor,such as the iron-selenide superconductor,accidental zero modes indeed arise in the vortex core if the pairing symmetry is the so-called nodeless d-wave(defined in the absence of spin-orbital coupling).Instead,if the pairing sym-metry is s_(++)or s_(+−)with respect to the Fermi pockets split by the spin-orbital coupling,the accidental zero modes do not appear in the limit of weak spin-orbital coupling.Our results are not only important in the experimental identification of Majorana zero modes,but also provide an avenue to pinpoint the pairing symmetry of the iron-selenide superconductor.
基金financially supported in part by the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB0450401)the National Natural Science Foundation of China(U23A2091,22122506,22479140,22479139,22232003,22075267,22109152)+3 种基金Anhui Provincial Natural Science Foundation(2408085JX001)Youth Innovation Promotion Association of CAS(Y2023129)Fundamental Research Funds for the Central Universities(20720220007,WK2060000039,KY2140000031)West Light Foundation of the Chinese Academy of Sciences(xbzg-zdsys-202209).
文摘Photocatalytic ammonia(NH_(3))decomposition is a key strategy for green hydrogen production and renewable energy conversion.Although conventional plasmonic metal/TiO_(2) composites exhibit some activity,their applications are constrained by high carrier recombination rates and narrow light harvesting ranges.To address these challenges,this study innovatively introduces the plasmonic semiconductor MoO_(3-x),which is characterized by broad-spectrum absorption and abundant oxygen vacancies,to construct a Cu-MoO_(3-x)/TiO_(2) plasmon resonance coupling nanostructure.The construction of the Cu-MoO_(3-x) composite stabilizes Cu via MoO_(3-x) coating and facilitates electron transfer from Cu to MoO_(3-x),generating more oxygen vacancies for NH_(3) activation.The visible localized surface plasmon resonance(LSPR)response of Cu,coupled with the visible to near-infrared LSPR resonance of MoO_(3-x),broadens the spectral response and optimizes carrier dynamics,thereby reducing the recombination of photogenerated carriers.The use of hot carriers and plasmonic photothermal effects synergistically accelerate surface reaction kinetics and enhance photocatalytic efficiency.In particular,the optimal Cu-MoO_(3-x)/TiO_(2) catalyst results in an enhanced NH_(3) decomposition rate of 103.2 mmol·g^(-1)·h^(-1) under fullspectrum light irradiation,representing 29-fold and 94-fold enhancements over those of Cu/TiO_(2) and MoO_(3-x)/TiO_(2),respectively.This innovative design strategy transcends traditional plasmonic metal/semiconductor catalyst designs and opens new avenues for developing efficient solar-driven plasmon resonance coupling catalysts.
基金supported by the National Key R&D Program of China(2021YFF0500703)Natural Science Foundation of Shanghai(22JC1404200)+3 种基金Program of Shanghai Academic/Technology Research Leader(20XD1404000)Natural Science Foundation of China(U22B20136,22293023)Science and Technology Major Project of Inner Mongolia(2021ZD0042)the Youth Innovation Promotion Association of CAS。
文摘A radical C−C-coupling reaction of acetonitrile into succinonitrile over hydrophobic TiO_(2) photocatalyst with enhanced catalytic activity was developed.In addition,the usage of a flow reactor further improved the photon utilization efficiency for succinonitrile synthesis at room temperature.The space time yield of succinonitrile reached 55.59μmol/(g·h)over hydrophobic TiO_(2) catalyst,which was much higher than that of pristine TiO_(2)(4.23μmol/(g·h)).Mechanistic studies revealed that the hydrophobic modification of TiO_(2) promoted the separation and transfer of photogenerated carriers,as well as suppressed their recombination.Hydrophobic TiO_(2) also enhanced the adsorption of−CH3 of acetonitrile,thus facilitating the activation of C−H bond and the utilization efficiency of photocarriers.
基金Projects(12072102,12102129)supported by the National Natural Science Foundation of ChinaProject(DM2022B01)supported by the Key Laboratory of Safe Mining of Deep Metal Mines,Ministry of Education,ChinaProject(JZ-008)supported by the Six Talent Peaks Project in Jiangsu Province,China。
文摘In this study,a series of triaxial tests are conducted on sandstone specimens to investigate the evolution of their mechanics and permeability characteristics under the combined action of immersion corrosion and seepage of different chemical solutions.It is observed that with the increase of confining pressure,the peak stress,dilatancy stress,dilatancy stress ratio,peak strain,and elastic modulus of the sandstone increase while the Poisson ratio decreases and less secondary cracks are produced when the samples are broken.The pore pressure and confining pressure have opposite influences on the mechanical properties.With the increase of the applied axial stress,three stages are clearly identified in the permeability evolution curves:initial compaction stage,linear elasticity stage and plastic deformation stage.The permeability reaches the maximum value when the highest volumetric dilatancy is obtained.In addition,the hydrochemical action of salt solution with pH=7 and 4 has an obvious deteriorating effect on the mechanical properties and induces the increase of permeability.The obtained results will be useful in engineering to understand the mechanical and seepage properties of sandstone under the coupled chemical-seepage-stress multiple fields.
基金supported by the National Natural Science Foundation of China(72271242)Hunan Provincial Natural Science Foundation of China for Excellent Young Scholars(2022JJ20046).
文摘Cutting off or controlling the enemy’s power supply at critical moments or strategic locations may result in a cascade failure,thus gaining an advantage in a war.However,the exist-ing cascading failure modeling analysis of interdependent net-works is insufficient for describing the load characteristics and dependencies of subnetworks,and it is difficult to use for model-ing and failure analysis of power-combat(P-C)coupling net-works.This paper considers the physical characteristics of the two subnetworks and studies the mechanism of fault propaga-tion between subnetworks and across systems.Then the surviv-ability of the coupled network is evaluated.Firstly,an integrated modeling approach for the combat system and power system is predicted based on interdependent network theory.A heteroge-neous one-way interdependent network model based on proba-bility dependence is constructed.Secondly,using the operation loop theory,a load-capacity model based on combat-loop betweenness is proposed,and the cascade failure model of the P-C coupling system is investigated from three perspectives:ini-tial capacity,allocation strategy,and failure mechanism.Thirdly,survivability indexes based on load loss rate and network sur-vival rate are proposed.Finally,the P-C coupling system is con-structed based on the IEEE 118-bus system to demonstrate the proposed method.
基金Project(52272363)supported by the National Natural Science Foundation of ChinaProject(2025JJ50308)supported by the Natural Science Foundation of Hunan Province,China+2 种基金Project(K-BBY1)supported by the Smart Railway Technology and Application,ChinaProject(1-W32Z)supported by the Postdoc Matching Fund Scheme,ChinaProject(ANCL20200302)supported by the Key Laboratory of Aerodynamic Noise Control,China。
文摘The pantograph cavity coupling system(PCCS)of high-speed trains,as a representative region for aerodynamic noise generation,merits further investigation into its scale effects.In this paper,the large-eddy simulation(LES)and the Ffowcs Williams-Hawkings(FW-H)integral equation are used to calculate and analyze the sound energy intensity distribution pattern and spectral characteristics of the PCCS at different scales(1/1,1/2,1/4,1/8,1/16,1/25,1/50).The research shows that as the scaled model decreases,the relative area of the pantograph submerged by the vehicle boundary layer increases,and its inflow velocity decreases,thereby reducing the overall radiated sound pressure level in this area.For the segments 1/1-1/2 and 1/4-1/16,the dominant scale of sound generation is typical pure tone noise,with distinct similar features in the spectral discrete scales.For the segments 1/25-1/50,the turbulent fluctuation characteristics of the vehicle boundary layer mask the peak features,and the spectrum is dominated by broadband characteristics.Combining the PCCS sound source energy scale correction model and the dimensionless spectrum correction function,a scale correction model for the sound power spectrum of the sound source is obtained,so that the noise results of the reduced-scale model can be corresponded to the full-scale model.This work advances the comprehension of high-speed train aerodynamic noise generation mechanisms and offers critical references for developing precision noise control technologies.
基金supported by Hefei National Laboratory,Innovation Program for Quantum Science and Technology(2021ZD0300400/2021ZD0300402)the Beijing Natural Science Foundation(3252013)the China Postdoctoral Science Foundation(2024T171116).
文摘The spin-exchange relaxation-free atomic gyroscope,with its exceptionally high theoretical precision,demonstrates immense potential to become the next-generation strategic-grade gyroscope.However,due to technological noise,there is still a significant gap between its actual precision and theoretical precision.This study identifies the key factor limiting the precision of the SERF gyroscope as coupling noise.By optimizing the detection loop structure,a distinction between the dual-axis signals'response to optical and magnetic fields was achieved-where the optical errors responded similarly,while the response to magnetic noise was opposite.Based on the differences in the optical-magnetic response of the dual-axis signals,empirical mode decomposition was used to decompose the dual-axis gyroscope signals into multiple intrinsic mode functions,and Allan deviation analysis was applied to analyze the noise characteristics of the intrinsic mode functions over various periods.This study successfully reveals that optical errors caused by thermal-optical coupling and long-period magnetic noise induced by thermal-magnetic coupling are the dominant factors limiting the long-term stability of the SERF gyroscope.Based on these analyses,the study concludes that to achieve strategic-grade precision for the SERF gyroscope,it is essential to effectively address the noise issues caused by multi-physical field couplings.
基金supported by the National Natural Science Foundation of China(Grant No.52405257)the China Postdoctoral Science Foundation(Grant No.2024M764201).
文摘Hypersonic morphing vehicle(HMV)can reconfigure aerodynamic geometries in real time,adapting to diverse needs like multi-mission profiles and wide-speed-range flight,spanwise morphing and sweep angle variation are representative large-scale wing reconfiguration modes.To meet the HMV's need for an increased lift and a lift to drag ratio during hypersonic maneuverability and cruise or reentry equilibrium glide,this paper proposes an innovative single-DOF coupled morphing-wing system.We then systematically analyze its open-loop kinematics and closed-loop connectivity constraints,and the proposed system integrates three functional modules:the preset locking/release mechanism,the coupled morphing-wing mechanism,and the integrated wing locking with active stiffness control mechanism.Experimental validation confirms stable,continuous morphing under simulated aerodynamic loads.The experimental results indicate:(i)SMA actuators exhibit response times ranging from 18 s to 160 s,providing sufficient force output for wing unlocking;(ii)The integrated wing locking with active stiffness control mechanism effectively secures wing positions while eliminating airframe clearance via SMA actuation,improving the first-order natural frequency by more than 17%;(iii)The distributed aerodynamic loading system enables precise multi-stage follow-up loading during morphing,with the coupled morphing wing maintaining stable,continuous operation under 0-3500 N normal loads and 110-140 N axial force.The proposed single-DOF coupled morphing mechanism not only simplifies and improves structural efficiency but also demonstrates superior performance in locking control,stiffness enhancement,and aerodynamic responsiveness.This establishes a foundational framework for the design of future intelligent morphing configurations and the implementation of flight control systems.
文摘This paper prepared a novel as-cast W-Zr-Ti metallic ESM using high-frequency vacuum induction melting technique.The above ESM performs a typical elastic-brittle material feature and strain rate strengthening behavior.The specimens exhibit violent chemical reaction during the fracture process under the impact loading,and the size distribution of their residual debris follows Rosin-Rammler model.The dynamic fracture toughness is obtained by the fitting of debris length scale,approximately 1.87 MPa·m~(1/2).Microstructure observation on residual debris indicates that the failure process is determined by primary crack propagation under quasi-static compression,while it is affected by multiple cracks propagation in both particle and matrix in the case of dynamic impact.Impact test demonstrates that the novel energetic fragment performs brilliant penetration and combustion effect behind the front target,leading to the effective ignition of fuel tank.For the brittleness of as-cast W-ZrTi ESM,further study conducted bond-based peridynamic(BB-PD)C++computational code to simulate its fracture behavior during penetration.The BB-PD method successfully captured the fracture process and debris cloud formation of the energetic fragment.This paper explores a novel as-cast metallic ESM,and provides an available numerical avenue to the simulation of brittle energetic fragment.
文摘Based on the model which couples the projectile and gun barrel during an interior ballistic cycle,the uncertainty propagation analysis of the model is presented caused by the uncertainty of the input parameters.The Bootstrap method is employed to calculate the statistical moments(i.e.the mean,variance,skewness coefficient and kurtosis coefficient)of the parameters of the projectile.Meanwhile,the maximum entropy method is used to estimate the probability density function(PDF)and the cumulative density function(CDF),the interval of the parameters of the projectile are also given.Moreover,the results obtained are compared to the results calculated by Monte Carlo(MC)method to verify the effectiveness of the presented method.Finally,the rule and the uncertainty propagation model of the projectile-barrel coupling system are given with the variation of the uncertainties of the input parameters.
文摘Uplift\|related geological and geophysical data available from regional geological mapping , detailed structural, tectonic, granitic, volcanic, metamorphic , geochronological studies, deep seismic reflection, wide\|angle seismic experiment, seismic tomography, broadband seismic network, and magnetotelluric sounding of key areas of the Qinghai—Tibet plateau are radically different from models of plate subduction or collision. Key geological features include: (1) obvio us time difference between plate collision and uplift of the plateau; (2) developments of intracrustal low\|velocity layers , low resistivity layers and discontinuous subhorizontal reflectors; (3) similar results between the rate and time of uplift of the Qinghai\|Tibet plateau and the time and rate of subsidence of its surrounding basins; (4) subhorizontal detachments and metamorphic core complexes occurred in Himalayan and Longmenshan; (5) weak deformation of late Cenozoic sediments and development of major steeply to gently dipping normal faults in the central part of the plateau; (6) discovery of high pressure and ultrahigh pressure metamorphic rocks in Nanbajiawa; (7) young volcanic rocks distributed from the northern plateau to the southern plateau; (8) nearly concordant processes among thrusting , mountain building, horizontal extension and intrusion of leucogranite in Himalayans.
文摘The paper probes into a probable condition that causes temper mill chatter from aspect of electromechanical coupling of complex electromechanical system, and mainly studies the effect of temper mill electrical driving system harmonic current on the main motion of temper mill set. Aiming at the electrical driving system of CM04 temper mill, the effect of harmonic current is analyzed and evaluated according to different load. Combining the features of CM04 temper mill′s structure and its working state, the paper discusses in every detail how the harmonic current in main circuit, which can be regarded as a disturbance via feedback control circuit , influences main motion of temper mill set.
基金Project(50678059) supported by the National Natural Science Foundation of China
文摘Long distance buried liquid-conveying pipeline is inevitable to cross faults and under earthquake action,it is necessary to calculate fluid-structure interaction(FSI) in finite element analysis under pipe-soil interaction.Under multi-action of site,fault movement and earthquake,finite element model of buried liquid-conveying pipeline for the calculation of fluid structure interaction was constructed through combinative application of ADINA-parasolid and ADINA-native modeling methods,and the direct computing method of two-way fluid-structure coupling was introduced.The methods of solid and fluid modeling were analyzed,pipe-soil friction was defined in solid model,and special flow assumption and fluid structure interface condition were defined in fluid model.Earthquake load,gravity and displacement of fault movement were applied,also model preferences.Finite element research on the damage of buried liquid-conveying pipeline was carried out through computing fluid-structure coupling.The influences of pipe-soil friction coefficient,fault-pipe angle,and liquid density on axial stress of pipeline were analyzed,and optimum parameters were proposed for the protection of buried liquid-conveying pipeline.
基金Projects(2014QNB18,2015XKMS022)supported by the Fundamental Research Funds for the Central Universities of ChinaProjects(51475456,51575511)supported by the National Natural Science Foundation of China+1 种基金Project supported by the Priority Academic Programme Development of Jiangsu Higher Education InstitutionsProject supported by the Visiting Scholar Foundation of China Scholarship Council
文摘The dynamics of spatial parallel manipulator with rigid and flexible links is explored. Firstly, a spatial beam element model for finite element analysis is established. Then, the differential equation of motion of beam element is derived based on finite element method. The kinematic constraints of parallel manipulator with rigid and flexible links are obtained by analyzing the motive parameters of moving platform and the relationships of movements of kinematic chains, and the overall kinetic equation of the parallel mechanism with rigid and flexible links is derived by assembling the differential equations of motion of components. On the basis of abovementioned analyses, the dynamic mechanical analysis of the spatial parallel manipulator with rigid and flexible links is conducted. After obtaining the method for force analysis and expressions for the calculation of dynamic stress of flexible components, the dynamic analysis and simulation of spatial parallel manipulator with rigid and flexible links is performed. The result shows that because of the elastic deformation of flexible components in the parallel mechanism with rigid and flexible links, the force on each component in the mechanism fluctuates sharply, and the change of normal stress at the root of drive components is also remarkable. This study provides references for further studies on the dynamic characteristics of parallel mechanisms with rigid and flexible links and for the optimization of the design of the mechanism.
文摘Soybean cultivar Bei 92-28 was tested in this experiment in 2000 to study the coupling effect of water and ferilizer on soybean yield.The results showed that the effect of irrigation varied among the levels of fertilizer application,and vice versa;pods per plant,seeds per pod.and 100-seed weight had positive correlations with soybean yield,but the degrees of correlations of different treatments were various;LAI and dry matter accumulation could be significantly increased when watered and applied fertilizer with different levels,but high fertilizer application treatment didn't obtain the highest yield;watering could increase the absolute absorption amount of N,P,K in seeds,but the accumulation rates were various.
文摘In this paper, numerical simulations of FPSO ship motion coupled with LNG tank sloshing with low-filling ratios are conducted. The fully coupled problem is addressed with our own unsteady RANS solver: naoe-FOAM-SJTU developed based on the open source tool librar- ies of OpenFOAM. The internal tank sloshing and external wave flow are solved simultaneously. The FPSO model includes 2 LNG tanks. For the ship 3-DOFs are released in the regular beam waves. The filling ratios of the 2 tanks are 20% - 20%, lower than the external free surface. This kind of low-filling condition reduces ship roll motion significantly, and produces complex free surface shapes in tanks. 4 different incident wave frequencies are considered in the simulation in comparison with the existing experimental data. The comparison shows that the numerical re- sults are in good agreement with the experimental data, proving the reliability of the proposed method. The filling conditions with large wave amplitudes are studied further, and due to the coupling effect, violent sloshing occurs in tanks and impulsive pressure forms on bulkhead.
