Low-electrode capacitive deionization(FCDI)is an emerging desalination technology with great potential for removal and/or recycling ions from a range of waters.However,it still suffers from inefficient charge transfer...Low-electrode capacitive deionization(FCDI)is an emerging desalination technology with great potential for removal and/or recycling ions from a range of waters.However,it still suffers from inefficient charge transfer and ion transport kinetics due to weak turbulence and low electric intensity in flow electrodes,both restricted by the current collectors.Herein,a new tip-array current collector(designated as T-CC)was developed to replace the conventional planar current collectors,which intensifies both the charge transfer and ion transport significantly.The effects of tip arrays on flow and electric fields were studied by both computational simulations and electrochemical impedance spectroscopy,which revealed the reduction of ion transport barrier,charge transport barrier and internal resistance.With the voltage increased from 1.0 to 1.5 and 2.0 V,the T-CC-based FCDI system(T-FCDI)exhibited average salt removal rates(ASRR)of 0.18,0.50,and 0.89μmol cm^(-2) min^(-1),respectively,which are 1.82,2.65,and 2.48 folds higher than that of the conventional serpentine current collectors,and 1.48,1.67,and 1.49 folds higher than that of the planar current collectors.Meanwhile,with the solid content in flow electrodes increased from 1 to 5 wt%,the ASRR for T-FCDI increased from 0.29 to 0.50μmol cm^(-2) min^(-1),which are 1.70 and 1.67 folds higher than that of the planar current collectors.Additionally,a salt removal efficiency of 99.89%was achieved with T-FCDI and the charge efficiency remained above 95%after 24 h of operation,thus showing its superior long-term stability.展开更多
van der Waals(vdW)heterostructures constructed by lowdimensional(0D,1D,and 2D)materials are emerging as one of the most appealing systems in next-generation flexible photodetection.Currently,hand-stacked vdW-type phot...van der Waals(vdW)heterostructures constructed by lowdimensional(0D,1D,and 2D)materials are emerging as one of the most appealing systems in next-generation flexible photodetection.Currently,hand-stacked vdW-type photodetectors are not compatible with large-areaarray fabrication and show unimpressive performance in self-powered mode.Herein,vertical 1D GaN nanorods arrays(NRAs)/2D MoS_(2)/PEDOT:PSS in wafer scale have been proposed for self-powered flexible photodetectors arrays firstly.The as-integrated device without external bias under weak UV illumination exhibits a competitive responsivity of 1.47 A W^(−1)and a high detectivity of 1.2×10^(11)Jones,as well as a fast response speed of 54/71μs,thanks to the strong light absorption of GaN NRAs and the efficient photogenerated carrier separation in type-II heterojunction.Notably,the strain-tunable photodetection performances of device have been demonstrated.Impressively,the device at−0.78%strain and zero bias reveals a significantly enhanced photoresponse with a responsivity of 2.47 A W^(−1),a detectivity of 2.6×10^(11)Jones,and response times of 40/45μs,which are superior to the state-of-the-art self-powered flexible photodetectors.This work presents a valuable avenue to prepare tunable vdWs heterostructures for self-powered flexible photodetection,which performs well in flexible sensors.展开更多
Thermally activated delayed fluorescence(TADF)molecules have outstanding potential for applications in organic light-emitting diodes(OLEDs).Due to the lack of systematic studies on the correlation between molecular st...Thermally activated delayed fluorescence(TADF)molecules have outstanding potential for applications in organic light-emitting diodes(OLEDs).Due to the lack of systematic studies on the correlation between molecular structure and luminescence properties,TADF molecules are far from meeting the needs of practical applications in terms of variety and number.In this paper,three twisted TADF molecules are studied and their photophysical properties are theoretically predicted based on the thermal vibrational correlation function method combined with multiscale calculations.The results show that all the molecules exhibit fast reverse intersystem crossing(RISC)rates(kRISC),predicting their TADF luminescence properties.In addition,the binding of DHPAzSi as the donor unit with different acceptors can change the dihedral angle between the ground and excited states,and the planarity of the acceptors is positively correlated with the reorganization energy,a property that has a strong influence on the non-radiative process.Furthermore,a decrease in the energy of the molecular charge transfer state and an increase in the kRISC were observed in the films.This study not only provides a reliable explanation for the observed experimental results,but also offers valuable insights that can guide the design of future TADF molecules.展开更多
Spin-orbit interaction(SOI)can be introduced by the proximity effect to modulate the electronic properties of graphene-based heterostructures.In this work,we stack trilayer WSe_(2) on Bernal tetralayer graphene to inv...Spin-orbit interaction(SOI)can be introduced by the proximity effect to modulate the electronic properties of graphene-based heterostructures.In this work,we stack trilayer WSe_(2) on Bernal tetralayer graphene to investigate the influence of SOI on the anomalous Hall effect(AHE).In this structurally asymmetric device,by comparing the magnitude of AHE at positive and negative displacement fields,we find that AHE is strongly enhanced by bringing electrons in proximity to the WSe_(2) layer.Meanwhile,the enhanced AHE signal persists up to 80 K,providing important routes for topological device applications at high temperatures.展开更多
Fertilization or atmospheric deposition of nitrogen(N)and phosphorus(P)to terrestrial ecosystems can alter soil N(P)availability and the nature of nutrient limitation for plant growth.Changing the allocation of leaf P...Fertilization or atmospheric deposition of nitrogen(N)and phosphorus(P)to terrestrial ecosystems can alter soil N(P)availability and the nature of nutrient limitation for plant growth.Changing the allocation of leaf P fractions is potentially an adaptive strategy for plants to cope with soil N(P)availability and nutrient-limiting conditions.However,the impact of the interactions between imbalanced anthropogenic N and P inputs on the concentrations and allocation proportions of leaf P fractions in forest woody plants remains elusive.We conducted a metaanalysis of data about the concentrations and allocation proportions of leaf P fractions,specifically associated with individual and combined additions of N and P in evergreen forests,the dominant vegetation type in southern China where the primary productivity is usually considered limited by P.This assessment allowed us to quantitatively evaluate the effects of N and P additions alone and interactively on leaf P allocation and use strategies.Nitrogen addition(exacerbating P limitation)reduced the concentrations of leaf total P and different leaf P fractions.Nitrogen addition reduced the allocation to leaf metabolic P but increased the allocation to other fractions,while P addition showed opposite trends.The simultaneous additions of N and P showed an antagonistic(mutual suppression)effect on the concentrations of leaf P fractions,but an additive(summary)effect on the allocation proportions of leaf P fractions.These results highlight the importance of strategies of leaf P fraction allocation in forest plants under changes in environmental nutrient availability.Importantly,our study identified critical interactions associated with combined N and P inputs that affect leaf P fractions,thus aiding in predicting plant acclimation strategies in the context of intensifying and imbalanced anthropogenic nutrient inputs.展开更多
The barocaloric effect is considered as one of the most promising refrigeration with the potential to replace traditional gas compression refrigeration.One of the main obstacles to the application of barocaloric mater...The barocaloric effect is considered as one of the most promising refrigeration with the potential to replace traditional gas compression refrigeration.One of the main obstacles to the application of barocaloric materials lies in the requirement for high driving pressures.In this paper,we report on the barocaloric effect of Pb_(3)(VO_(4))_(2),which exhibits a ferroelastic transition from a high-temperature trigonal structure to a low-temperature monoclinic structure at 357 K,accompanied by a substantial volume change.The entropy change induced by hydrostatic pressure can reach up 14 J·kg^(-1)·K^(-1)under a relatively low pressure of 80 MPa.This work is expected to expand the selection range of barocaloric materials.展开更多
The pressure and temperature increase resulting from the impact of different threats onto target materials is analyzed with a unified laboratory-scale setup.This allows deriving qualitative information on the occurrin...The pressure and temperature increase resulting from the impact of different threats onto target materials is analyzed with a unified laboratory-scale setup.This allows deriving qualitative information on the occurring phenomenology as well as quantitative statements about the relative effects sizes as a function of target material and threat.The considered target materials are steel,aluminum,and magnesium.As threats,kinetic energy penetrator,explosively formed projectile,and shaped charge jet are used.For the investigated combinations,the measured overpressures vary by a factor of up to 5 for a variation of the material,by a factor of up to 7 for a variation of the threat,and by a factor larger than 15for a simultaneous variation of both.The obtained results as well as the experimental approach are relevant for the basic understanding of impact effects and risks due to material reactivity.The paper combines two main aims.Firstly,to provide a summary of own prior work in a coherent journal article and,secondly,to review and discuss these earlier results with a new perspective.展开更多
The Hydrodynamic Ram(HRAM)effect occurs when a high kinetic energy projectile penetrates a fluid filled area,e.g.,a liquid filled tank.The projectile transfers its momentum and kinetic energy to the fluid,what causes ...The Hydrodynamic Ram(HRAM)effect occurs when a high kinetic energy projectile penetrates a fluid filled area,e.g.,a liquid filled tank.The projectile transfers its momentum and kinetic energy to the fluid,what causes a sudden,local pressure rise,further expanding as primary shock wave in the fluid and developing a cavity.It is possible that the entire tank ruptures due to the loads transferred through the fluid to its surrounding structure.In the past decades,additionally to experimental investigations,HRAM has been studied using various computational approaches particularly focusing on the description of the Fluid-Structure Interaction(FSI).This article reviews the published experimental,analytical and numerical results and delivers a chronological overview since the end of World War II.Furthermore,HRAM mitigation measures are highlighted,which have been developed with the experimental,analytical and numerical toolboxes matured over the past 80 years.展开更多
The past decade has witnessed the rapid increasement in power conversion efficiency of perovskite solar cells(PSCs).However,serious ion migration hampers their operational stability.Although dopants composed of varied...The past decade has witnessed the rapid increasement in power conversion efficiency of perovskite solar cells(PSCs).However,serious ion migration hampers their operational stability.Although dopants composed of varied cations and anions are introduced into perovskite to suppress ion migration,the impact of cations or anions is not individually explored,which hinders the evaluation of different cations and further application of doping strategy.Here we report that a special group of sulfonic anions(like CF_(3)SO_(3)^(-))successfully introduce alkaline earth ions(like Ca^(2+))into perovskite lattice compared to its halide counterparts.Furthermore,with effective crystallization regulation and defect passivation of sulfonic anions,perovskite with Ca(CF_(3)SO_(3))_(2)shows reduced PbI2 residue and metallic Pb0 defects;thereby,corresponding PSCs show an enhanced PCE of 24.95%.Finally by comparing the properties of perovskite with Ca(CF_(3)SO_(3))_(2)and FACF_(3)SO_(3),we found that doped Ca^(2+)significantly suppressed halide migration with an activation energy of 1.246 eV which accounts for the improved operational stability of Ca(CF_(3)SO_(3))_(2-)doped PSCs,while no obvious impact of Ca^(2+)on trap density is observed.Combining the benefits of cations and anions,this study presents an effective method to decouple the effects of cations and anions and fabricate efficient and stable PSCs.展开更多
Organic additives with multiple functional groups have shown great promise in improving the performance and stability of perovskite solar cells.The functional groups can passivate undercoordinated ions to reduce nonra...Organic additives with multiple functional groups have shown great promise in improving the performance and stability of perovskite solar cells.The functional groups can passivate undercoordinated ions to reduce nonradiative recombination losses.However,how these groups synergistically affect the enhancement beyond passivation is still unclear.Specifically,isomeric molecules with different substitution patterns or molecular shapes remain elusive in designing new organic additives.Here,we report two isomeric carbazolyl bisphosphonate additives,2,7-Cz BP and 3,6-Cz BP.The isomerism effect on passivation and charge transport process was studied.The two molecules have similar passivation effects through multiple interactions,e.g.,P=O···Pb,P=O···H–N and N–H···I.2,7-CzBP can further bridge the perovskite crystallites to facilitates charge transport.Power conversion efficiencies(PCEs)of 25.88%and 21.04%were achieved for 0.09 cm^(2)devices and 14 cm^(2)modules after 2,7-Cz BP treatment,respectively.The devices exhibited enhanced operational stability maintaining 95%of initial PCE after 1000 h of continuous maximum power point tracking.This study of isomerism effect hints at the importance of tuning substitution positions and molecular shapes for organic additives,which paves the way for innovation of next-generation multifunctional aromatic additives.展开更多
Recent theoretical verification of self-similar and dissipative pure-quartic solitons(PQSs)emphasized the similarity between PQS lasers and conventional fiber lasers,but the unique equilibrium mechanism hinders the fo...Recent theoretical verification of self-similar and dissipative pure-quartic solitons(PQSs)emphasized the similarity between PQS lasers and conventional fiber lasers,but the unique equilibrium mechanism hinders the formation of PQS molecules in normal fourth-order dispersion(FOD)regimes.In this paper,we investigated the effect of filters on shaping PQSs in normal FOD based on a passively mode-locked fiber laser model.A bandpass filter eliminates the time pedestal of dissipative PQSs,thus realizing a multi-pulsing state.When the filter bandwidth is appropriate,the effective spectral filtering effect can lower the pulse splitting threshold and enable the coherent restoration from chaotic PQSs to PQS molecules.Additionally,changing the central wavelength of the filter can generate PQSs and PQS molecules with asymmetric intensity distributions.These results are important guides for the manipulation of PQSs and the construction of high repetition-frequency fiber lasers.展开更多
Mn-based layered oxides(KMO)have emerged as one of the promising low-cost cathodes for potassiumion batteries(PIBs).However,due to the multiple-phase transitions and the distortion in the MnO6structure induced by the ...Mn-based layered oxides(KMO)have emerged as one of the promising low-cost cathodes for potassiumion batteries(PIBs).However,due to the multiple-phase transitions and the distortion in the MnO6structure induced by the Jahn-Teller(JT)effect associated with Mn-ion,the cathode exhibits poor structural stability.Herein,we propose a strategy to enhance structural stability by introducing robust metal-oxygen(M-O)bonds,which can realize the pinning effect to constrain the distortion in the transition metal(TM)layer.Concurrently,all the elements employed have exceptionally high crustal abundance.As a proof of concept,the designed K_(0.5)Mn_(0.9)Mg_(0.025)Ti_(0.025)Al_(0.05)O_(2)cathode exhibited a discharge capacity of approximately 100 mA h g^(-1)at 20 mA g^(-1)with 79%capacity retention over 50 cycles,and 73%capacity retention over 200 cycles at 200 mA g^(-1),showcased much better battery performance than the designed cathode with less robust M-O bonds.The properties of the formed M-O bonds were investigated using theoretical calculations.The enhanced dynamics,mitigated JT effect,and improved structural stability were elucidated through the in-situ X-ray diffractometer(XRD),in-situ electrochemical impedance spectroscopy(EIS)(and distribution of relaxation times(DRT)method),and ex-situ X-ray absorption fine structure(XAFS)tests.This study holds substantial reference value for the future design of costeffective Mn-based layered cathodes for PIBs.展开更多
The single event effects(SEEs)evaluations caused by atmospheric neutrons were conducted on three different convolutional neural network(CNN)models(Yolov3,MNIST,and ResNet50)in the atmospheric neutron irradiation spect...The single event effects(SEEs)evaluations caused by atmospheric neutrons were conducted on three different convolutional neural network(CNN)models(Yolov3,MNIST,and ResNet50)in the atmospheric neutron irradiation spectrometer(ANIS)at the China Spallation Neutron Source(CSNS).The Yolov3 and MNIST models were implemented on the XILINX28-nm system-on-chip(So C).Meanwhile,the Yolov3 and ResNet50 models were deployed on the XILINX 16-nm Fin FET Ultra Scale+MPSoC.The atmospheric neutron SEEs on the tested CNN systems were comprehensively evaluated from six aspects,including chip type,network architecture,deployment methods,inference time,datasets,and the position of the anchor boxes.The various types of SEE soft errors,SEE cross-sections,and their distribution were analyzed to explore the radiation sensitivities and rules of 28-nm and 16-nm SoC.The current research can provide the technology support of radiation-resistant design of CNN system for developing and applying high-reliability,long-lifespan domestic artificial intelligence chips.展开更多
The coupling of fast redox kinetics,high-energy density,and prolonged lifespan is a permanent aspiration for aqueous rechargeable zinc batteries,but which has been severely hampered by a narrow voltage range and subop...The coupling of fast redox kinetics,high-energy density,and prolonged lifespan is a permanent aspiration for aqueous rechargeable zinc batteries,but which has been severely hampered by a narrow voltage range and suboptimal compatibility between the electrolytes and electrodes.Here,we unprecedentedly introduced an electric ambipolar effect for synergistic manipulation on Zn^(2+)ternary-hydrated eutectic electrolyte(ZTE)enabling high-performance Zn-Br_(2)batteries.The electric ambipolar effect motivates strong dipole interactions among hydrated perchlorates and bipolar ligands of L-carnitine(L-CN)and sulfamide,which reorganized primary cations solvation sheath in a manner of forming Zn[(L-CN)(SA)(H_(2)O)_(4)]^(2+)configuration and dynamically restricting desolvated H2O molecules,thus ensuring a broadened electrochemical window of 2.9 V coupled with high ionic conductivity.Noticeably,L-CN affords an electrostatic shielding effect and an in situ construction of organic-inorganic interphase,endowing oriented Zn anode plating/stripping reversibly for over 2400 h.Therefore,with the synergy of electro/nucleophilicity and exceptional compatibility,the ZTE electrolyte dynamically boosts the conversion redox of Zn-Br_(2)batteries in terms of high specific capacity and stable cycling performance.These findings open a window for designing electrolytes with synergetic chemical stability and compatibility toward advanced zinc-ion batteries.展开更多
Semiconductor moirésuperlattices provide great platforms for exploring exotic collective excitations.Optical Stark effect,a shift of the electronic transition in the presence of a light field,provides an ultrafas...Semiconductor moirésuperlattices provide great platforms for exploring exotic collective excitations.Optical Stark effect,a shift of the electronic transition in the presence of a light field,provides an ultrafast and coherent method of manipulating matter states,which,however,has not been demonstrated in moirématerials.Here,we report the valleyselective optical Stark effect of moiréexcitons in the WSe_(2)/WS_(2)superlattice by using transient reflection spectroscopy.Prominent valley-selective energy shifts up to 7.8 meV have been observed for moiréexcitons,corresponding to pseudomagnetic fields as large as 34 T.Our results provide a route to coherently manipulate exotic states in moirésuperlattices.展开更多
The Bessel-like vector vortex beam(BlVVB)has gained increasing significance across numerous applications.However,its practical application is restricted by manufacturing difficulties and polarization manipulation.Thus...The Bessel-like vector vortex beam(BlVVB)has gained increasing significance across numerous applications.However,its practical application is restricted by manufacturing difficulties and polarization manipulation.Thus,the ability to manipulate its degrees of freedom is highly desirable.In this paper,the full-domain polarization modulation of BlVVB within a hot atomic ensemble has been investigated.We begin with the theoretical analysis of the resonant magneto-optical effect of atoms with a horizontal linear-polarized beam and experimentally demonstrate precise manipulation of the polarization state across the entire domain of the BlVVB,achieving an error margin of less than 3°at various cross-sectional points.Our study provides a novel approach for the modulation of BlVVB based on atomic media,which holds potential applications in sensitive vector magnetometers,optical communications,and signal processing.展开更多
Traffic engineering such as tunnels in various altitudinal gradient zone are at risk of accidental explosion,which can damage personnel and equipment.Accurate prediction of the distribution pattern of explosive loads ...Traffic engineering such as tunnels in various altitudinal gradient zone are at risk of accidental explosion,which can damage personnel and equipment.Accurate prediction of the distribution pattern of explosive loads and shock wave propagation process in semi-enclosed structures at various altitude environment is key research focus in the fields of explosion shock and fluid dynamics.The effect of altitude on the propagation of shock waves in tunnels was investigated by conducting explosion test and numerical simulation.Based on the experimental and numerical simulation results,a prediction model for the attenuation of the peak overpressure of tunnel shock waves at different altitudes was established.The results showed that the peak overpressure decreased at the same measurement points in the tunnel entrance under the high altitude condition.In contrast,an increase in altitude accelerated the propagation speed of the shock wave in the tunnel.The average error between the peak shock wave overpressure obtained using the overpressure prediction formula and the measured test data was less than15%,the average error between the propagation velocity of shock waves predicted values and the test data is less than 10%.The method can effectively predict the overpressure attenuation of blast wave in tunnel at various altitudes.展开更多
To elucidate the yielding performance of compact yielding anchor cables in working state,a yielding mechanical model incorporating extrusion friction and fastening rotation under confining pressure is constructed.The ...To elucidate the yielding performance of compact yielding anchor cables in working state,a yielding mechanical model incorporating extrusion friction and fastening rotation under confining pressure is constructed.The yielding resistance enhancement effect(ω)caused by working environment constraints is evaluated through multi-layer composite sleeve hole expansion analysis,forming a theoretical framework for calculating the working yielding force.Laboratory and in-situ pull-out tests are conducted to determine the yielding performance and validate the analytical theory.The main conclusions are:(1)Yielding force and energy-release capacity increase withω,significantly outperforming the unconfined state.(2)In-situ tests under varying rockmass and geostress conditions(F1–F3)determine the yielding force increases to 183.4–290.1,204.0–290.8,and 235.0–327.1 kN.(3)The slight deviation(–12.5%to 6.2%)between the theoretical and measured yielding force confirms that the analytical theory effectively describes the working yielding performance.(4)ωincreases with higher geostress and improved rock mechanical properties,with initial geostress(σ_(0))and elastic modulus of surrounding rock(E_(3))identified as critical parameters.展开更多
Under investigation is the n-component nonlinear Schrödinger equation with higher-order effects,which describes the ultrashort pulses in the birefringent fiber.Based on the Lax pair,the eigenfunction and generali...Under investigation is the n-component nonlinear Schrödinger equation with higher-order effects,which describes the ultrashort pulses in the birefringent fiber.Based on the Lax pair,the eigenfunction and generalized Darboux transformation are derived.Next,we construct several novel higher-order localized waves and classified them into three categories:(i)higher-order rogue waves interacting with bright/antidark breathers,(ii)higher-order breather fission/fusion,(iii)higherorder breather interacting with soliton.Moreover,we explore the effects of parameters on the structure,collision process and energy distribution of localized waves and these characteristics are significantly different from previous ones.Finally,the dynamical properties of these solutions are discussed in detail.展开更多
Under complex flight conditions,such as obstacle avoidance and extreme sea state,wing-in-ground(WIG)effect aircraft need to ascend to higher altitudes,resulting in the disappearance of the ground effect.A design of hi...Under complex flight conditions,such as obstacle avoidance and extreme sea state,wing-in-ground(WIG)effect aircraft need to ascend to higher altitudes,resulting in the disappearance of the ground effect.A design of high-speed WIG airfoil considering non-ground effect is carried out by a novel two-step inverse airfoil design method that combines conditional generative adversarial network(CGAN)and artificial neural network(ANN).The CGAN model is employed to generate a variety of airfoil designs that satisfy the desired lift-drag ratios in both ground effect and non-ground effect conditions.Subsequently,the ANN model is utilized to forecast aerodynamic parameters of the generated airfoils.The results indicate that the CGAN model contributes to a high accuracy rate for airfoil design and enables the creation of novel airfoil designs.Furthermore,it demonstrates high accuracy in predicting aerodynamic parameters of these airfoils due to the ANN model.This method eliminates the necessity for numerical simulations and experimental testing through the design procedure,showcasing notable efficiency.The analysis of airfoils generated by the CGAN model shows that airfoils exhibiting high lift-drag ratios under both flight conditions typically have cambers of among[0.08c,0.105c],with the positions of maximum camber occurring among[0.35c,0.5c]of the chord length,and the leading-edge radiuses of these airfoils primarily cluster among[0.008c,0.025c]展开更多
基金supported by the Shenzhen Science and Technology Program(JCYJ20230808105111022,JCYJ20220818095806013)Natural Science Foundation of Guangdong(2023A1515012267)+1 种基金the National Natural Science Foundation of China(22178223)the Royal Society/NSFC cost share program(IEC\NSFC\223372).
文摘Low-electrode capacitive deionization(FCDI)is an emerging desalination technology with great potential for removal and/or recycling ions from a range of waters.However,it still suffers from inefficient charge transfer and ion transport kinetics due to weak turbulence and low electric intensity in flow electrodes,both restricted by the current collectors.Herein,a new tip-array current collector(designated as T-CC)was developed to replace the conventional planar current collectors,which intensifies both the charge transfer and ion transport significantly.The effects of tip arrays on flow and electric fields were studied by both computational simulations and electrochemical impedance spectroscopy,which revealed the reduction of ion transport barrier,charge transport barrier and internal resistance.With the voltage increased from 1.0 to 1.5 and 2.0 V,the T-CC-based FCDI system(T-FCDI)exhibited average salt removal rates(ASRR)of 0.18,0.50,and 0.89μmol cm^(-2) min^(-1),respectively,which are 1.82,2.65,and 2.48 folds higher than that of the conventional serpentine current collectors,and 1.48,1.67,and 1.49 folds higher than that of the planar current collectors.Meanwhile,with the solid content in flow electrodes increased from 1 to 5 wt%,the ASRR for T-FCDI increased from 0.29 to 0.50μmol cm^(-2) min^(-1),which are 1.70 and 1.67 folds higher than that of the planar current collectors.Additionally,a salt removal efficiency of 99.89%was achieved with T-FCDI and the charge efficiency remained above 95%after 24 h of operation,thus showing its superior long-term stability.
基金supported by the National Key Research and Development Program of China(No.2022YFB3604500,No.2022YFB3604501)the National Natural Science Foundation of China(No.52172141)the Technology Development Project of Shanxi-Zheda Institude of Advanced Materials and Chemical Engineering(No.2022SX-TD017).
文摘van der Waals(vdW)heterostructures constructed by lowdimensional(0D,1D,and 2D)materials are emerging as one of the most appealing systems in next-generation flexible photodetection.Currently,hand-stacked vdW-type photodetectors are not compatible with large-areaarray fabrication and show unimpressive performance in self-powered mode.Herein,vertical 1D GaN nanorods arrays(NRAs)/2D MoS_(2)/PEDOT:PSS in wafer scale have been proposed for self-powered flexible photodetectors arrays firstly.The as-integrated device without external bias under weak UV illumination exhibits a competitive responsivity of 1.47 A W^(−1)and a high detectivity of 1.2×10^(11)Jones,as well as a fast response speed of 54/71μs,thanks to the strong light absorption of GaN NRAs and the efficient photogenerated carrier separation in type-II heterojunction.Notably,the strain-tunable photodetection performances of device have been demonstrated.Impressively,the device at−0.78%strain and zero bias reveals a significantly enhanced photoresponse with a responsivity of 2.47 A W^(−1),a detectivity of 2.6×10^(11)Jones,and response times of 40/45μs,which are superior to the state-of-the-art self-powered flexible photodetectors.This work presents a valuable avenue to prepare tunable vdWs heterostructures for self-powered flexible photodetection,which performs well in flexible sensors.
文摘Thermally activated delayed fluorescence(TADF)molecules have outstanding potential for applications in organic light-emitting diodes(OLEDs).Due to the lack of systematic studies on the correlation between molecular structure and luminescence properties,TADF molecules are far from meeting the needs of practical applications in terms of variety and number.In this paper,three twisted TADF molecules are studied and their photophysical properties are theoretically predicted based on the thermal vibrational correlation function method combined with multiscale calculations.The results show that all the molecules exhibit fast reverse intersystem crossing(RISC)rates(kRISC),predicting their TADF luminescence properties.In addition,the binding of DHPAzSi as the donor unit with different acceptors can change the dihedral angle between the ground and excited states,and the planarity of the acceptors is positively correlated with the reorganization energy,a property that has a strong influence on the non-radiative process.Furthermore,a decrease in the energy of the molecular charge transfer state and an increase in the kRISC were observed in the films.This study not only provides a reliable explanation for the observed experimental results,but also offers valuable insights that can guide the design of future TADF molecules.
基金Project supported by the National Key R&D Program of China(Grant Nos.2021YFA1400100 and 2024YFA1409700)the National Natural Science Foudation of China(Grant Nos.12374168 and T2325026)。
文摘Spin-orbit interaction(SOI)can be introduced by the proximity effect to modulate the electronic properties of graphene-based heterostructures.In this work,we stack trilayer WSe_(2) on Bernal tetralayer graphene to investigate the influence of SOI on the anomalous Hall effect(AHE).In this structurally asymmetric device,by comparing the magnitude of AHE at positive and negative displacement fields,we find that AHE is strongly enhanced by bringing electrons in proximity to the WSe_(2) layer.Meanwhile,the enhanced AHE signal persists up to 80 K,providing important routes for topological device applications at high temperatures.
基金supported by the National Natural Science Foundation of China(No.41473068)supported by China Postdoctoral Science Foundation(No.2022M722667)。
文摘Fertilization or atmospheric deposition of nitrogen(N)and phosphorus(P)to terrestrial ecosystems can alter soil N(P)availability and the nature of nutrient limitation for plant growth.Changing the allocation of leaf P fractions is potentially an adaptive strategy for plants to cope with soil N(P)availability and nutrient-limiting conditions.However,the impact of the interactions between imbalanced anthropogenic N and P inputs on the concentrations and allocation proportions of leaf P fractions in forest woody plants remains elusive.We conducted a metaanalysis of data about the concentrations and allocation proportions of leaf P fractions,specifically associated with individual and combined additions of N and P in evergreen forests,the dominant vegetation type in southern China where the primary productivity is usually considered limited by P.This assessment allowed us to quantitatively evaluate the effects of N and P additions alone and interactively on leaf P allocation and use strategies.Nitrogen addition(exacerbating P limitation)reduced the concentrations of leaf total P and different leaf P fractions.Nitrogen addition reduced the allocation to leaf metabolic P but increased the allocation to other fractions,while P addition showed opposite trends.The simultaneous additions of N and P showed an antagonistic(mutual suppression)effect on the concentrations of leaf P fractions,but an additive(summary)effect on the allocation proportions of leaf P fractions.These results highlight the importance of strategies of leaf P fraction allocation in forest plants under changes in environmental nutrient availability.Importantly,our study identified critical interactions associated with combined N and P inputs that affect leaf P fractions,thus aiding in predicting plant acclimation strategies in the context of intensifying and imbalanced anthropogenic nutrient inputs.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.52301241 and 52271175)。
文摘The barocaloric effect is considered as one of the most promising refrigeration with the potential to replace traditional gas compression refrigeration.One of the main obstacles to the application of barocaloric materials lies in the requirement for high driving pressures.In this paper,we report on the barocaloric effect of Pb_(3)(VO_(4))_(2),which exhibits a ferroelastic transition from a high-temperature trigonal structure to a low-temperature monoclinic structure at 357 K,accompanied by a substantial volume change.The entropy change induced by hydrostatic pressure can reach up 14 J·kg^(-1)·K^(-1)under a relatively low pressure of 80 MPa.This work is expected to expand the selection range of barocaloric materials.
文摘The pressure and temperature increase resulting from the impact of different threats onto target materials is analyzed with a unified laboratory-scale setup.This allows deriving qualitative information on the occurring phenomenology as well as quantitative statements about the relative effects sizes as a function of target material and threat.The considered target materials are steel,aluminum,and magnesium.As threats,kinetic energy penetrator,explosively formed projectile,and shaped charge jet are used.For the investigated combinations,the measured overpressures vary by a factor of up to 5 for a variation of the material,by a factor of up to 7 for a variation of the threat,and by a factor larger than 15for a simultaneous variation of both.The obtained results as well as the experimental approach are relevant for the basic understanding of impact effects and risks due to material reactivity.The paper combines two main aims.Firstly,to provide a summary of own prior work in a coherent journal article and,secondly,to review and discuss these earlier results with a new perspective.
文摘The Hydrodynamic Ram(HRAM)effect occurs when a high kinetic energy projectile penetrates a fluid filled area,e.g.,a liquid filled tank.The projectile transfers its momentum and kinetic energy to the fluid,what causes a sudden,local pressure rise,further expanding as primary shock wave in the fluid and developing a cavity.It is possible that the entire tank ruptures due to the loads transferred through the fluid to its surrounding structure.In the past decades,additionally to experimental investigations,HRAM has been studied using various computational approaches particularly focusing on the description of the Fluid-Structure Interaction(FSI).This article reviews the published experimental,analytical and numerical results and delivers a chronological overview since the end of World War II.Furthermore,HRAM mitigation measures are highlighted,which have been developed with the experimental,analytical and numerical toolboxes matured over the past 80 years.
基金support from the National Key Research and Development Program of China(No.2022YFE0137400)the National Natural Science Foundation of China(Grant No.62274040).
文摘The past decade has witnessed the rapid increasement in power conversion efficiency of perovskite solar cells(PSCs).However,serious ion migration hampers their operational stability.Although dopants composed of varied cations and anions are introduced into perovskite to suppress ion migration,the impact of cations or anions is not individually explored,which hinders the evaluation of different cations and further application of doping strategy.Here we report that a special group of sulfonic anions(like CF_(3)SO_(3)^(-))successfully introduce alkaline earth ions(like Ca^(2+))into perovskite lattice compared to its halide counterparts.Furthermore,with effective crystallization regulation and defect passivation of sulfonic anions,perovskite with Ca(CF_(3)SO_(3))_(2)shows reduced PbI2 residue and metallic Pb0 defects;thereby,corresponding PSCs show an enhanced PCE of 24.95%.Finally by comparing the properties of perovskite with Ca(CF_(3)SO_(3))_(2)and FACF_(3)SO_(3),we found that doped Ca^(2+)significantly suppressed halide migration with an activation energy of 1.246 eV which accounts for the improved operational stability of Ca(CF_(3)SO_(3))_(2-)doped PSCs,while no obvious impact of Ca^(2+)on trap density is observed.Combining the benefits of cations and anions,this study presents an effective method to decouple the effects of cations and anions and fabricate efficient and stable PSCs.
基金financially supported by the National Science Foundation of China(62474142)Natural Science Foundation of Shandong Province(No.ZR2024YQ070)。
文摘Organic additives with multiple functional groups have shown great promise in improving the performance and stability of perovskite solar cells.The functional groups can passivate undercoordinated ions to reduce nonradiative recombination losses.However,how these groups synergistically affect the enhancement beyond passivation is still unclear.Specifically,isomeric molecules with different substitution patterns or molecular shapes remain elusive in designing new organic additives.Here,we report two isomeric carbazolyl bisphosphonate additives,2,7-Cz BP and 3,6-Cz BP.The isomerism effect on passivation and charge transport process was studied.The two molecules have similar passivation effects through multiple interactions,e.g.,P=O···Pb,P=O···H–N and N–H···I.2,7-CzBP can further bridge the perovskite crystallites to facilitates charge transport.Power conversion efficiencies(PCEs)of 25.88%and 21.04%were achieved for 0.09 cm^(2)devices and 14 cm^(2)modules after 2,7-Cz BP treatment,respectively.The devices exhibited enhanced operational stability maintaining 95%of initial PCE after 1000 h of continuous maximum power point tracking.This study of isomerism effect hints at the importance of tuning substitution positions and molecular shapes for organic additives,which paves the way for innovation of next-generation multifunctional aromatic additives.
基金Project supported by the National Natural Science Foundation of China(Grant No.62175116)。
文摘Recent theoretical verification of self-similar and dissipative pure-quartic solitons(PQSs)emphasized the similarity between PQS lasers and conventional fiber lasers,but the unique equilibrium mechanism hinders the formation of PQS molecules in normal fourth-order dispersion(FOD)regimes.In this paper,we investigated the effect of filters on shaping PQSs in normal FOD based on a passively mode-locked fiber laser model.A bandpass filter eliminates the time pedestal of dissipative PQSs,thus realizing a multi-pulsing state.When the filter bandwidth is appropriate,the effective spectral filtering effect can lower the pulse splitting threshold and enable the coherent restoration from chaotic PQSs to PQS molecules.Additionally,changing the central wavelength of the filter can generate PQSs and PQS molecules with asymmetric intensity distributions.These results are important guides for the manipulation of PQSs and the construction of high repetition-frequency fiber lasers.
基金financially supported by the National Natural Science Foundation of China(NSFC)(52274295)the Natural Science Foundation of Hebei Province(E2021501029)+3 种基金the Fundamental Research Funds for the Central Universities(N2423051,N2423053,N2302016,N2423019,N2323013,N2423005)the Science and Technology Project of Hebei Education Department(QN2024238)the Basic Research Program Project of Shijiazhuang City for Universities Stationed in Hebei Province(241790937A)the Science and Technology Project of Qinhuangdao City in 2023.
文摘Mn-based layered oxides(KMO)have emerged as one of the promising low-cost cathodes for potassiumion batteries(PIBs).However,due to the multiple-phase transitions and the distortion in the MnO6structure induced by the Jahn-Teller(JT)effect associated with Mn-ion,the cathode exhibits poor structural stability.Herein,we propose a strategy to enhance structural stability by introducing robust metal-oxygen(M-O)bonds,which can realize the pinning effect to constrain the distortion in the transition metal(TM)layer.Concurrently,all the elements employed have exceptionally high crustal abundance.As a proof of concept,the designed K_(0.5)Mn_(0.9)Mg_(0.025)Ti_(0.025)Al_(0.05)O_(2)cathode exhibited a discharge capacity of approximately 100 mA h g^(-1)at 20 mA g^(-1)with 79%capacity retention over 50 cycles,and 73%capacity retention over 200 cycles at 200 mA g^(-1),showcased much better battery performance than the designed cathode with less robust M-O bonds.The properties of the formed M-O bonds were investigated using theoretical calculations.The enhanced dynamics,mitigated JT effect,and improved structural stability were elucidated through the in-situ X-ray diffractometer(XRD),in-situ electrochemical impedance spectroscopy(EIS)(and distribution of relaxation times(DRT)method),and ex-situ X-ray absorption fine structure(XAFS)tests.This study holds substantial reference value for the future design of costeffective Mn-based layered cathodes for PIBs.
基金Project supported by the National Natural Science Foundation of China(Grant No.12305303)the Natural Science Foundation of Hunan Province of China(Grant Nos.2023JJ40520,2024JJ2044,and 2021JJ40444)+3 种基金the Science and Technology Innovation Program of Hunan Province,China(Grant No.2020RC3054)the Postgraduate Scientific Research Innovation Project of Hunan Province,China(Grant No.CX20240831)the Natural Science Basic Research Plan in the Shaanxi Province of China(Grant No.2023-JC-QN0015)the Doctoral Research Fund of University of South China(Grant No.200XQD033)。
文摘The single event effects(SEEs)evaluations caused by atmospheric neutrons were conducted on three different convolutional neural network(CNN)models(Yolov3,MNIST,and ResNet50)in the atmospheric neutron irradiation spectrometer(ANIS)at the China Spallation Neutron Source(CSNS).The Yolov3 and MNIST models were implemented on the XILINX28-nm system-on-chip(So C).Meanwhile,the Yolov3 and ResNet50 models were deployed on the XILINX 16-nm Fin FET Ultra Scale+MPSoC.The atmospheric neutron SEEs on the tested CNN systems were comprehensively evaluated from six aspects,including chip type,network architecture,deployment methods,inference time,datasets,and the position of the anchor boxes.The various types of SEE soft errors,SEE cross-sections,and their distribution were analyzed to explore the radiation sensitivities and rules of 28-nm and 16-nm SoC.The current research can provide the technology support of radiation-resistant design of CNN system for developing and applying high-reliability,long-lifespan domestic artificial intelligence chips.
基金provided by the National Natural Science Foundation of China(Grant No.52373208 and 61831021)the ECNU Academic Innovation Promotion Program for Excellent Doctoral Students(YBNLTS2024-021).
文摘The coupling of fast redox kinetics,high-energy density,and prolonged lifespan is a permanent aspiration for aqueous rechargeable zinc batteries,but which has been severely hampered by a narrow voltage range and suboptimal compatibility between the electrolytes and electrodes.Here,we unprecedentedly introduced an electric ambipolar effect for synergistic manipulation on Zn^(2+)ternary-hydrated eutectic electrolyte(ZTE)enabling high-performance Zn-Br_(2)batteries.The electric ambipolar effect motivates strong dipole interactions among hydrated perchlorates and bipolar ligands of L-carnitine(L-CN)and sulfamide,which reorganized primary cations solvation sheath in a manner of forming Zn[(L-CN)(SA)(H_(2)O)_(4)]^(2+)configuration and dynamically restricting desolvated H2O molecules,thus ensuring a broadened electrochemical window of 2.9 V coupled with high ionic conductivity.Noticeably,L-CN affords an electrostatic shielding effect and an in situ construction of organic-inorganic interphase,endowing oriented Zn anode plating/stripping reversibly for over 2400 h.Therefore,with the synergy of electro/nucleophilicity and exceptional compatibility,the ZTE electrolyte dynamically boosts the conversion redox of Zn-Br_(2)batteries in terms of high specific capacity and stable cycling performance.These findings open a window for designing electrolytes with synergetic chemical stability and compatibility toward advanced zinc-ion batteries.
基金Project supported by the National Key R&D Program of China(Grant Nos.2022YFA1402400 and 2022YFA1405400)the National Natural Science Foundation of China(Grant Nos.11934011 and 12274365)+3 种基金Zhejiang Provincial Natural Science Foundation of China(Grant No.LR24A040001)Open project of Key Laboratory of Artificial Structures and Quantum Control(Ministry of Education)of Shanghai Jiao Tong Universitysupport from the JSPS KAKENHI(Grant Nos.20H00354 and 23H02052)World Premier International Research Center Initiative(WPI),MEXT,Japan。
文摘Semiconductor moirésuperlattices provide great platforms for exploring exotic collective excitations.Optical Stark effect,a shift of the electronic transition in the presence of a light field,provides an ultrafast and coherent method of manipulating matter states,which,however,has not been demonstrated in moirématerials.Here,we report the valleyselective optical Stark effect of moiréexcitons in the WSe_(2)/WS_(2)superlattice by using transient reflection spectroscopy.Prominent valley-selective energy shifts up to 7.8 meV have been observed for moiréexcitons,corresponding to pseudomagnetic fields as large as 34 T.Our results provide a route to coherently manipulate exotic states in moirésuperlattices.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.12033007,61801458,12103058,12203058,12074309,and 61875205)the Key Project of Frontier Science Research of the Chinese Academy of Sciences(Grant No.QYZDB-SSW-SLH007)+2 种基金the Strategic Priority Research Program of CAS(Grant No.XDC07020200)the Youth Innovation Promotion Association,CAS(Grant Nos.2021408,2022413,and 2023425)the Research on Highly Sensitive Long-Wave Receiver Based on Rydberg Atoms(Grant No.1P2024000059)。
文摘The Bessel-like vector vortex beam(BlVVB)has gained increasing significance across numerous applications.However,its practical application is restricted by manufacturing difficulties and polarization manipulation.Thus,the ability to manipulate its degrees of freedom is highly desirable.In this paper,the full-domain polarization modulation of BlVVB within a hot atomic ensemble has been investigated.We begin with the theoretical analysis of the resonant magneto-optical effect of atoms with a horizontal linear-polarized beam and experimentally demonstrate precise manipulation of the polarization state across the entire domain of the BlVVB,achieving an error margin of less than 3°at various cross-sectional points.Our study provides a novel approach for the modulation of BlVVB based on atomic media,which holds potential applications in sensitive vector magnetometers,optical communications,and signal processing.
基金financially supported by National Natural Science Foundation of China(Grant Nos.52378401,52278504)the Fundamental Research Funds for the Central Universities(Grant No.30922010918)。
文摘Traffic engineering such as tunnels in various altitudinal gradient zone are at risk of accidental explosion,which can damage personnel and equipment.Accurate prediction of the distribution pattern of explosive loads and shock wave propagation process in semi-enclosed structures at various altitude environment is key research focus in the fields of explosion shock and fluid dynamics.The effect of altitude on the propagation of shock waves in tunnels was investigated by conducting explosion test and numerical simulation.Based on the experimental and numerical simulation results,a prediction model for the attenuation of the peak overpressure of tunnel shock waves at different altitudes was established.The results showed that the peak overpressure decreased at the same measurement points in the tunnel entrance under the high altitude condition.In contrast,an increase in altitude accelerated the propagation speed of the shock wave in the tunnel.The average error between the peak shock wave overpressure obtained using the overpressure prediction formula and the measured test data was less than15%,the average error between the propagation velocity of shock waves predicted values and the test data is less than 10%.The method can effectively predict the overpressure attenuation of blast wave in tunnel at various altitudes.
基金supported by the National Natural Science Foundation of China(Nos.U2468217,U2034205,and 52308391)。
文摘To elucidate the yielding performance of compact yielding anchor cables in working state,a yielding mechanical model incorporating extrusion friction and fastening rotation under confining pressure is constructed.The yielding resistance enhancement effect(ω)caused by working environment constraints is evaluated through multi-layer composite sleeve hole expansion analysis,forming a theoretical framework for calculating the working yielding force.Laboratory and in-situ pull-out tests are conducted to determine the yielding performance and validate the analytical theory.The main conclusions are:(1)Yielding force and energy-release capacity increase withω,significantly outperforming the unconfined state.(2)In-situ tests under varying rockmass and geostress conditions(F1–F3)determine the yielding force increases to 183.4–290.1,204.0–290.8,and 235.0–327.1 kN.(3)The slight deviation(–12.5%to 6.2%)between the theoretical and measured yielding force confirms that the analytical theory effectively describes the working yielding performance.(4)ωincreases with higher geostress and improved rock mechanical properties,with initial geostress(σ_(0))and elastic modulus of surrounding rock(E_(3))identified as critical parameters.
基金Project supported by the National Natural Science Foundation of China(Grant No.12271096)the Natural Science Foundation of Fujian Province(Grant No.2021J01302)。
文摘Under investigation is the n-component nonlinear Schrödinger equation with higher-order effects,which describes the ultrashort pulses in the birefringent fiber.Based on the Lax pair,the eigenfunction and generalized Darboux transformation are derived.Next,we construct several novel higher-order localized waves and classified them into three categories:(i)higher-order rogue waves interacting with bright/antidark breathers,(ii)higher-order breather fission/fusion,(iii)higherorder breather interacting with soliton.Moreover,we explore the effects of parameters on the structure,collision process and energy distribution of localized waves and these characteristics are significantly different from previous ones.Finally,the dynamical properties of these solutions are discussed in detail.
基金supported by the Priority Academic Program Development of Jiangsu Higher Education Institutions,the Fundamental Research Funds for the Central Universities(No.ILA220101A23)CARDC Fundamental and Frontier Technology Research Fund(No.PJD20200210)the Aeronautical Science Foundation of China(No.20200023052002).
文摘Under complex flight conditions,such as obstacle avoidance and extreme sea state,wing-in-ground(WIG)effect aircraft need to ascend to higher altitudes,resulting in the disappearance of the ground effect.A design of high-speed WIG airfoil considering non-ground effect is carried out by a novel two-step inverse airfoil design method that combines conditional generative adversarial network(CGAN)and artificial neural network(ANN).The CGAN model is employed to generate a variety of airfoil designs that satisfy the desired lift-drag ratios in both ground effect and non-ground effect conditions.Subsequently,the ANN model is utilized to forecast aerodynamic parameters of the generated airfoils.The results indicate that the CGAN model contributes to a high accuracy rate for airfoil design and enables the creation of novel airfoil designs.Furthermore,it demonstrates high accuracy in predicting aerodynamic parameters of these airfoils due to the ANN model.This method eliminates the necessity for numerical simulations and experimental testing through the design procedure,showcasing notable efficiency.The analysis of airfoils generated by the CGAN model shows that airfoils exhibiting high lift-drag ratios under both flight conditions typically have cambers of among[0.08c,0.105c],with the positions of maximum camber occurring among[0.35c,0.5c]of the chord length,and the leading-edge radiuses of these airfoils primarily cluster among[0.008c,0.025c]
