Flaking on high-moisture corn （wet corn） by hot-air heating was studied in the paper. The wet-heating approach was beneficial to improve corn gelatinization by experimental results. By the experiments, a set of opti...Flaking on high-moisture corn （wet corn） by hot-air heating was studied in the paper. The wet-heating approach was beneficial to improve corn gelatinization by experimental results. By the experiments, a set of optimal parameters was obtained： hot-air temperature 120-130℃, heating duration 70 min, gap between rollers 0.5 -1.0 mm, 150-200 r·min^-1 for rotational speed of rollers.展开更多
Magnesium potassium phosphate cement(MKPC)coatings exhibit potential for carbon steel protection but face challenges in practical application due to the preparation process and properties.This study develops flake gra...Magnesium potassium phosphate cement(MKPC)coatings exhibit potential for carbon steel protection but face challenges in practical application due to the preparation process and properties.This study develops flake graphite(FG)-modified MKPC coatings via spraying process,investigating the effects of FG size and dosage on phase composition,microstructure,mechanical properties,corrosion protection,and thermal conductivity.Results show that a low FG dosage(5 wt%)synergistically optimizes multifunctional performance.Compared to unmodified MKPC,FG2-1 exhibited exceptional impact resistance,associated with a 57%reduction in corrosion current density(icorr),a 356.3% increase in low-frequency impedance modulus(Z_(0.01 Hz))and a 37% increase in thermal conductivity.However,the coating with a high FG dosage(15 wt%)degraded performance due to defect accumulation and reduced crystallinity of KMgPO_(4)·6H_(2)O.This work advances the rational design of multifunctional inorganic coatings for extreme service environments requiring coupled corrosion protection and thermal management.展开更多
湖泊对气候变化非常敏感,是气候变化的指示器。青藏高原湖泊众多,但由于观测数据的缺乏,目前对全球变暖背景下高原湖泊热力状况的研究依然不足且多为短期研究。利用中国科学院青藏高原研究所(ITPCAS)开发的中国区域高时空分辨率地面气...湖泊对气候变化非常敏感,是气候变化的指示器。青藏高原湖泊众多,但由于观测数据的缺乏,目前对全球变暖背景下高原湖泊热力状况的研究依然不足且多为短期研究。利用中国科学院青藏高原研究所(ITPCAS)开发的中国区域高时空分辨率地面气象要素驱动数据集、MODIS地表温度数据、青海湖浮标观测数据,分析了Freshwater Lake Model(简称Flake模式)在青海湖的适用性,揭示了青海湖热力状况对气候变化的响应。结果表明,Flake模式能够很好的模拟出青海湖的热力状况,但对夏季与秋季的湖表面水温(特别是夜间)模拟偏高,部分是驱动数据误差造成的,修正驱动数据后模拟效果得到改善。对1989 2012年Flake模拟的湖表面温度与ITPCAS数据不同驱动要素之间的年际变化趋势与相关性进行分析,发现青海湖表面温度呈现上升趋势,与气温、向下长波辐射有较好的正相关性,而与风速负相关。内部热力状况的模拟结果显示,青海湖混合层温度基本全年呈上升趋势,其中5、6月及12月增温最显著;湖泊底层温度在5月以及12月的两次季节性翻转时期呈上升趋势,在6 10月湖水分层期呈下降趋势,分层期湖泊上层温度升高会加强湖水层结稳定性,使湖水混合减弱,导致底层温度下降。展开更多
一维湖泊模式是青藏高原湖泊研究的主要手段之一,但不同湖泊模式在青藏高原适用性及其差异依然不够明确。利用MODIS地表温度数据、青藏高原鄂陵湖站点观测的气象数据、湖温及湖面能量数据,驱动、评估和对比了目前应用最为广泛的两个一...一维湖泊模式是青藏高原湖泊研究的主要手段之一,但不同湖泊模式在青藏高原适用性及其差异依然不够明确。利用MODIS地表温度数据、青藏高原鄂陵湖站点观测的气象数据、湖温及湖面能量数据,驱动、评估和对比了目前应用最为广泛的两个一维湖泊模式Freshwater Lake Model(FLake)和Community Land Model version 4.5(CLM4.5)中耦合的湖泊模块在青藏高原典型湖泊的适用性。结果表明:FLake和CLM模式均能较好的对湖泊热力状况进行模拟,CLM模式对于湖表面温度和湖泊内部不同深度的温度模拟优于Flake模式,净辐射和能量的累积也是CLM模式的模拟值更接近观测值。造成Flake模式模拟偏差更大的原因与模式中计算感热、潜热的摩擦速度有关,观测的摩擦速度均值为0.22 m·s-1,CLM模式中的摩擦速度与观测值接近,为Flake模式的1.5倍,将CLM模式中的摩擦速度替换到Flake模式中后模拟结果有明显的改善。展开更多
Silver-tin oxide powders were synthesized by the hydrothermal method with Ag(NH_3)_2^+ solution and Na_2SnO_3 solution as raw materials and Na_2SO_3 as reductant. The precipitation conditions of Na2SnO3 solution and t...Silver-tin oxide powders were synthesized by the hydrothermal method with Ag(NH_3)_2^+ solution and Na_2SnO_3 solution as raw materials and Na_2SO_3 as reductant. The precipitation conditions of Na2SnO3 solution and the reduction conditions of Ag(NH_3)_2^+ were also investigated. The powders prepared were characterized by differential thermal analysis (DTA), X-ray diffraction analysis (XRD), scanning electron microscope (SEM) and energy spectrum analysis. The results show that pH value of the solution is a key parameter in the formation of Sn(OH)_4 precipitate and the reduction reaction of Ag(NH_3)_2^+ can release H+ ions, which results in synchronous precipitation of Sn(OH)_6~2- as Sn(OH)_4. The reduction of Ag(NH_3)_2^+ and precipitation of Na_2SnO_3 occur simultaneously and the coprecipitation of silver and tin oxide is reached by the hydrothermal method. The silver-tin oxide composite powders have mainly flake shape of about 0.3 μm in thickness and there exists homogeneous distribution of tin oxide and silver in the powder synthesized.展开更多
Micaceous iron oxide （MIO） with a hexagonal flaky shape was prepared by hydrothermal method. The ferric hydroxide used as precursor was obtained by an acidic leaching solution of pyrite cinders reacting with ammonia...Micaceous iron oxide （MIO） with a hexagonal flaky shape was prepared by hydrothermal method. The ferric hydroxide used as precursor was obtained by an acidic leaching solution of pyrite cinders reacting with ammonia solution. The optimal experimental conditions for preparing micaceous iron oxide were investigated by orthogonal experiments. Micaceous iron oxide can be successfully prepared when optimal parameters of total iron concentration of 2.0 mol/L, pH value of 8, n（Fe2＋）/n（Fe3＋） of 0.1, mass of seed crystal of 1 g, reaction temperature of 260 ℃ and reaction time of 30 min are applied. X-ray diffractometry （XRD）, scanning electron microscopy （SEM）, transmission electron microscopy （TEM） and selected area electron diffractometry （SAEM） were adopted to characterize the hydrothermal products prepared under optimal conditions. The results indicate that highly crystallized α-Fe2O3 hexagonal flakes, about 1.0-1.5 μm in diameter and 0.1 μm in thickness, are prepared. Furthermore, the quality of micaceous iron oxide prepared can meet the required characteristics of micaceous iron oxide pigments for paints （ISO 10601--2007）.展开更多
Magnesium oxysulfate （MgSO4·5Mg（OH）2·2H2O） flake powders with an average diameter of 2 ~tm and a thickness of 0.052 μm were prepared using magnesium sulfate and sodium hydroxide as raw materials by hydr...Magnesium oxysulfate （MgSO4·5Mg（OH）2·2H2O） flake powders with an average diameter of 2 ~tm and a thickness of 0.052 μm were prepared using magnesium sulfate and sodium hydroxide as raw materials by hydrothermal synthesis process. The composition, morphology and structural features of the hydrothermal products were examined with X-ray powder diffraction （XRD）, scanning electron microscopy （SEM） and Fourier transform infrared spectroscopy （FTIR）. The experimental results indicate that in the conditions of n（NaOH）/n（MgSO4） of 1.25, the dosage of w（Na3PO4） crystal additives of 1.0% w（MgSO4）, stirring for 5 h at 180 ℃, the morphology of MgSO4·5Mg（OH）2·2H2O products is flaky and laminar, which is a kind of complex magnesium singlecrystal. The recycling of MgSO4 mother liquor was also investigated to make a full use of the materials and reduce disposal. The results prove that there is no adverse effect on the yield and purity of the products.展开更多
To achieve aluminum particles with ultrafine granularity and high reactivity,the mechanical ball-milling method was adopted and three kinds of coatings,including stearic acid(SA),viton and dinitrotoluene(DNT),were add...To achieve aluminum particles with ultrafine granularity and high reactivity,the mechanical ball-milling method was adopted and three kinds of coatings,including stearic acid(SA),viton and dinitrotoluene(DNT),were added.The effects of milling time and different coatings on granularity and reactivity of ultrafine aluminum particles were studied.The structures of prepared ultrafine aluminum were characterized by scanning electron microscopy,X-ray particle diffraction and the thermal properties were analyzed by TG/DSC.Besides,the reactivity of prepared ultrafine aluminum particles was comprehensively analyzed and judged according to several thermodynamic parameters,the maximal oxidation rate,the oxidation degree of aluminum and the enthalpy change.The results revealed that aluminum particles prepared by the mechanical ball milling method were all flake-like and the particle sizes were below5 mm with nanometer-scale thickness.And the crystal form of aluminum was found to be unchanged.Besides,the ultrafine flake aluminum coated with stearic acid after milling for 5 h showed the highest reactivity with 56.1% of oxidation degree before 660℃,0.945 mg/℃ of maximal oxidation rate and 20491 J/g of enthalpy change.展开更多
基金Supported by Heilongjiang Provincial Scientific Research Project(GC04B509-02)
文摘Flaking on high-moisture corn （wet corn） by hot-air heating was studied in the paper. The wet-heating approach was beneficial to improve corn gelatinization by experimental results. By the experiments, a set of optimal parameters was obtained： hot-air temperature 120-130℃, heating duration 70 min, gap between rollers 0.5 -1.0 mm, 150-200 r·min^-1 for rotational speed of rollers.
基金National Key Research and Development Program of China(2024YFB3714804)National Natural Science Foundation of China(52171277)+1 种基金Baima Lake Laboratory Joint Funds of the Zhejiang Provincial Natural Science Foundation of China(LBMHZ24E020001)Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering(2022SZ-TD006).
文摘Magnesium potassium phosphate cement(MKPC)coatings exhibit potential for carbon steel protection but face challenges in practical application due to the preparation process and properties.This study develops flake graphite(FG)-modified MKPC coatings via spraying process,investigating the effects of FG size and dosage on phase composition,microstructure,mechanical properties,corrosion protection,and thermal conductivity.Results show that a low FG dosage(5 wt%)synergistically optimizes multifunctional performance.Compared to unmodified MKPC,FG2-1 exhibited exceptional impact resistance,associated with a 57%reduction in corrosion current density(icorr),a 356.3% increase in low-frequency impedance modulus(Z_(0.01 Hz))and a 37% increase in thermal conductivity.However,the coating with a high FG dosage(15 wt%)degraded performance due to defect accumulation and reduced crystallinity of KMgPO_(4)·6H_(2)O.This work advances the rational design of multifunctional inorganic coatings for extreme service environments requiring coupled corrosion protection and thermal management.
文摘湖泊对气候变化非常敏感,是气候变化的指示器。青藏高原湖泊众多,但由于观测数据的缺乏,目前对全球变暖背景下高原湖泊热力状况的研究依然不足且多为短期研究。利用中国科学院青藏高原研究所(ITPCAS)开发的中国区域高时空分辨率地面气象要素驱动数据集、MODIS地表温度数据、青海湖浮标观测数据,分析了Freshwater Lake Model(简称Flake模式)在青海湖的适用性,揭示了青海湖热力状况对气候变化的响应。结果表明,Flake模式能够很好的模拟出青海湖的热力状况,但对夏季与秋季的湖表面水温(特别是夜间)模拟偏高,部分是驱动数据误差造成的,修正驱动数据后模拟效果得到改善。对1989 2012年Flake模拟的湖表面温度与ITPCAS数据不同驱动要素之间的年际变化趋势与相关性进行分析,发现青海湖表面温度呈现上升趋势,与气温、向下长波辐射有较好的正相关性,而与风速负相关。内部热力状况的模拟结果显示,青海湖混合层温度基本全年呈上升趋势,其中5、6月及12月增温最显著;湖泊底层温度在5月以及12月的两次季节性翻转时期呈上升趋势,在6 10月湖水分层期呈下降趋势,分层期湖泊上层温度升高会加强湖水层结稳定性,使湖水混合减弱,导致底层温度下降。
文摘一维湖泊模式是青藏高原湖泊研究的主要手段之一,但不同湖泊模式在青藏高原适用性及其差异依然不够明确。利用MODIS地表温度数据、青藏高原鄂陵湖站点观测的气象数据、湖温及湖面能量数据,驱动、评估和对比了目前应用最为广泛的两个一维湖泊模式Freshwater Lake Model(FLake)和Community Land Model version 4.5(CLM4.5)中耦合的湖泊模块在青藏高原典型湖泊的适用性。结果表明:FLake和CLM模式均能较好的对湖泊热力状况进行模拟,CLM模式对于湖表面温度和湖泊内部不同深度的温度模拟优于Flake模式,净辐射和能量的累积也是CLM模式的模拟值更接近观测值。造成Flake模式模拟偏差更大的原因与模式中计算感热、潜热的摩擦速度有关,观测的摩擦速度均值为0.22 m·s-1,CLM模式中的摩擦速度与观测值接近,为Flake模式的1.5倍,将CLM模式中的摩擦速度替换到Flake模式中后模拟结果有明显的改善。
基金Project(2001BA901A09)supported by the Key Program of Science and Technology Action of West China Development
文摘Silver-tin oxide powders were synthesized by the hydrothermal method with Ag(NH_3)_2^+ solution and Na_2SnO_3 solution as raw materials and Na_2SO_3 as reductant. The precipitation conditions of Na2SnO3 solution and the reduction conditions of Ag(NH_3)_2^+ were also investigated. The powders prepared were characterized by differential thermal analysis (DTA), X-ray diffraction analysis (XRD), scanning electron microscope (SEM) and energy spectrum analysis. The results show that pH value of the solution is a key parameter in the formation of Sn(OH)_4 precipitate and the reduction reaction of Ag(NH_3)_2^+ can release H+ ions, which results in synchronous precipitation of Sn(OH)_6~2- as Sn(OH)_4. The reduction of Ag(NH_3)_2^+ and precipitation of Na_2SnO_3 occur simultaneously and the coprecipitation of silver and tin oxide is reached by the hydrothermal method. The silver-tin oxide composite powders have mainly flake shape of about 0.3 μm in thickness and there exists homogeneous distribution of tin oxide and silver in the powder synthesized.
基金Project(2008A090300016) supported by Major Science & Technology Special Program of Guangdong Province,China
文摘Micaceous iron oxide （MIO） with a hexagonal flaky shape was prepared by hydrothermal method. The ferric hydroxide used as precursor was obtained by an acidic leaching solution of pyrite cinders reacting with ammonia solution. The optimal experimental conditions for preparing micaceous iron oxide were investigated by orthogonal experiments. Micaceous iron oxide can be successfully prepared when optimal parameters of total iron concentration of 2.0 mol/L, pH value of 8, n（Fe2＋）/n（Fe3＋） of 0.1, mass of seed crystal of 1 g, reaction temperature of 260 ℃ and reaction time of 30 min are applied. X-ray diffractometry （XRD）, scanning electron microscopy （SEM）, transmission electron microscopy （TEM） and selected area electron diffractometry （SAEM） were adopted to characterize the hydrothermal products prepared under optimal conditions. The results indicate that highly crystallized α-Fe2O3 hexagonal flakes, about 1.0-1.5 μm in diameter and 0.1 μm in thickness, are prepared. Furthermore, the quality of micaceous iron oxide prepared can meet the required characteristics of micaceous iron oxide pigments for paints （ISO 10601--2007）.
基金Project(50704036) supported by the National Natural Science Foundation of ChinaProject(08JJ3027) supported by the Natural Science Foundation of Hunan Province, China
文摘Magnesium oxysulfate （MgSO4·5Mg（OH）2·2H2O） flake powders with an average diameter of 2 ~tm and a thickness of 0.052 μm were prepared using magnesium sulfate and sodium hydroxide as raw materials by hydrothermal synthesis process. The composition, morphology and structural features of the hydrothermal products were examined with X-ray powder diffraction （XRD）, scanning electron microscopy （SEM） and Fourier transform infrared spectroscopy （FTIR）. The experimental results indicate that in the conditions of n（NaOH）/n（MgSO4） of 1.25, the dosage of w（Na3PO4） crystal additives of 1.0% w（MgSO4）, stirring for 5 h at 180 ℃, the morphology of MgSO4·5Mg（OH）2·2H2O products is flaky and laminar, which is a kind of complex magnesium singlecrystal. The recycling of MgSO4 mother liquor was also investigated to make a full use of the materials and reduce disposal. The results prove that there is no adverse effect on the yield and purity of the products.
基金supported by the Natural Science Foundation of China (Project No51606102)the Fundamental Research Funds for the Central Universities (No. 30916011315)+3 种基金the Qing Lan Project, the Weapon Research Support Fund (No. 62201070827)a Project funded by the Priority Academic Program Development of Jiangsu Higher Education Institutionsthe Shanghai Aerospace Science and Technology Innovation Fund (SAST2015020)Basic Product Innovation Technology Research Project of Explosives
文摘To achieve aluminum particles with ultrafine granularity and high reactivity,the mechanical ball-milling method was adopted and three kinds of coatings,including stearic acid(SA),viton and dinitrotoluene(DNT),were added.The effects of milling time and different coatings on granularity and reactivity of ultrafine aluminum particles were studied.The structures of prepared ultrafine aluminum were characterized by scanning electron microscopy,X-ray particle diffraction and the thermal properties were analyzed by TG/DSC.Besides,the reactivity of prepared ultrafine aluminum particles was comprehensively analyzed and judged according to several thermodynamic parameters,the maximal oxidation rate,the oxidation degree of aluminum and the enthalpy change.The results revealed that aluminum particles prepared by the mechanical ball milling method were all flake-like and the particle sizes were below5 mm with nanometer-scale thickness.And the crystal form of aluminum was found to be unchanged.Besides,the ultrafine flake aluminum coated with stearic acid after milling for 5 h showed the highest reactivity with 56.1% of oxidation degree before 660℃,0.945 mg/℃ of maximal oxidation rate and 20491 J/g of enthalpy change.
