Magnetic properties of a two sublattice ferrimagnet with antiferromagnetic exchange interaction inside one of the sublattices are calculated within the framework of the molecular field theory taking into account the a...Magnetic properties of a two sublattice ferrimagnet with antiferromagnetic exchange interaction inside one of the sublattices are calculated within the framework of the molecular field theory taking into account the anisotropy of unstable sublattice. The magnetization curves of single crystal GdMn 2Ge 2 for the magnetic field parallel and perpendicular to the c axis at different temperatures are calculated. Field induced magnetic phase transitions in GdMn 2Ge 2 are discussed. Calculated H T magnetic phase diagrams are in fair agreement with experimental data.展开更多
Siderite,as an abundant iron ore,has not been effectively utilized,with a low utilization rate.In this study,the in-situ kinetics and mechanism of siderite during suspension magnetization roasting(SMR)were investigate...Siderite,as an abundant iron ore,has not been effectively utilized,with a low utilization rate.In this study,the in-situ kinetics and mechanism of siderite during suspension magnetization roasting(SMR)were investigated to improve the selective conversion of siderite to magnetite and CO,enriching the theoretical system of green SMR using siderite as a reductant.According to the gas products analyses,the peak value of the reaction rate increased with increasing temperature,and its curves presented the feature of an early peak and long tail.The mechanism function of the siderite pyrolysis was the contraction sphere model(R_(3)):f(α)=3(1−α)2/3;E_(α)was 46.4653 kJ/mol;A was 0.5938 s^(−1);the kinetics equation was k=0.5938exp[−46.4653/(RT)].The in-situ HT-XRD results indicated that siderite was converted into magnetite and wüstite that exhibited a good crystallinity in SMR under a N_(2) atmosphere.At 620℃,the saturation magnetization(M_(s)),remanence magnetization(Mr),and coercivity(Hc)of the product peaked at 53.63×10^(-3)A·m^(2)/g,10.23×10^(-3)A·m^(2)/g,and 12.40×10^(3)A/m,respectively.Meanwhile,the initial particles with a smooth surface were transformed into particles with a porous and loose structure in the roasting process,which would contribute to reducing the grinding cost.展开更多
The lattice parameters, magnetic phase transition, Curie temperature and magnetocaloric properties for (Gd1-xTbx)5Si1.72- Ge2.28 alloys with x = 0, 0.15, 0.20 and 0.25 were investigated by X-ray powder diffractometry ...The lattice parameters, magnetic phase transition, Curie temperature and magnetocaloric properties for (Gd1-xTbx)5Si1.72- Ge2.28 alloys with x = 0, 0.15, 0.20 and 0.25 were investigated by X-ray powder diffractometry and magnetization measurements. The results show that suitable partial substitution of Tb in Gd5Si1.72Ge2.28 compound remains the first-order magnetic-crystallographic transition and enhances the magnetic entropy change, although Tb substitution decreases the Curie temperature (TC) of the compounds. The magnetic entropy change of (Gd1-xTbx)5Si1.72Ge2.28 alloys retains a large value in the low magnetic field of 1.0 T. The maximum magnetic entropy change for (Gd0.80Tb0.20)5Si1.72Ge2.28 alloy in the magnetic field from 0 to 1.0 T reaches 8.7 J/(kg·K), which is nearly 4 times as large as that of (Gd0.3Dy0.7)5Si4 compound (|-Smax| = 2.24 J/(kg·K), T_C = 198 K).展开更多
为探究静磁场辅助冷冻(static magnetic field assisted freezing,SMAF)对牛肉品质的影响,采用不同强度SMAF(0、2、4、6、8、10 mT,-18℃),对比分析冷冻参数对牛背最长肌品质的影响。结果表明:与对照组相比,SMAF-6、8、10处理组相变时...为探究静磁场辅助冷冻(static magnetic field assisted freezing,SMAF)对牛肉品质的影响,采用不同强度SMAF(0、2、4、6、8、10 mT,-18℃),对比分析冷冻参数对牛背最长肌品质的影响。结果表明:与对照组相比,SMAF-6、8、10处理组相变时间分别显著缩短15%、25%和6.7%(P<0.05);SMAF处理有效提高了肌肉的持水性(解冻损失率、蒸煮损失率和离心损失率),降低了样品的ΔE(P<0.05),但对样品的pH值和硫代巴比妥酸反应物值无显著影响(P>0.05);此外,剪切力与肌原纤维小片化指数的结果一致,SMAF处理维持了牛肉的剪切力;十二烷基硫酸钠-聚丙烯酰胺凝胶电泳结果显示,SMAF处理可以减少肉品经冷冻-解冻后蛋白质含量的降低。综上,在适当的静磁场强度下辅助冷冻,可节省冻结时间,提高肌肉持水力,减少蛋白质含量的降低,从而改善牛肉品质,其中SMAF-8处理效果最佳。展开更多
文摘Magnetic properties of a two sublattice ferrimagnet with antiferromagnetic exchange interaction inside one of the sublattices are calculated within the framework of the molecular field theory taking into account the anisotropy of unstable sublattice. The magnetization curves of single crystal GdMn 2Ge 2 for the magnetic field parallel and perpendicular to the c axis at different temperatures are calculated. Field induced magnetic phase transitions in GdMn 2Ge 2 are discussed. Calculated H T magnetic phase diagrams are in fair agreement with experimental data.
基金Projects(51874071,52022019,51734005)supported by the National Natural Science Foundation of ChinaProject(161045)supported by the Fok Ying Tung Education Foundation for Yong Teachers in the Higher Education Institutions of China。
文摘Siderite,as an abundant iron ore,has not been effectively utilized,with a low utilization rate.In this study,the in-situ kinetics and mechanism of siderite during suspension magnetization roasting(SMR)were investigated to improve the selective conversion of siderite to magnetite and CO,enriching the theoretical system of green SMR using siderite as a reductant.According to the gas products analyses,the peak value of the reaction rate increased with increasing temperature,and its curves presented the feature of an early peak and long tail.The mechanism function of the siderite pyrolysis was the contraction sphere model(R_(3)):f(α)=3(1−α)2/3;E_(α)was 46.4653 kJ/mol;A was 0.5938 s^(−1);the kinetics equation was k=0.5938exp[−46.4653/(RT)].The in-situ HT-XRD results indicated that siderite was converted into magnetite and wüstite that exhibited a good crystallinity in SMR under a N_(2) atmosphere.At 620℃,the saturation magnetization(M_(s)),remanence magnetization(Mr),and coercivity(Hc)of the product peaked at 53.63×10^(-3)A·m^(2)/g,10.23×10^(-3)A·m^(2)/g,and 12.40×10^(3)A/m,respectively.Meanwhile,the initial particles with a smooth surface were transformed into particles with a porous and loose structure in the roasting process,which would contribute to reducing the grinding cost.
基金Project (50371058) supported by the National Natural Science Foundation of China
文摘The lattice parameters, magnetic phase transition, Curie temperature and magnetocaloric properties for (Gd1-xTbx)5Si1.72- Ge2.28 alloys with x = 0, 0.15, 0.20 and 0.25 were investigated by X-ray powder diffractometry and magnetization measurements. The results show that suitable partial substitution of Tb in Gd5Si1.72Ge2.28 compound remains the first-order magnetic-crystallographic transition and enhances the magnetic entropy change, although Tb substitution decreases the Curie temperature (TC) of the compounds. The magnetic entropy change of (Gd1-xTbx)5Si1.72Ge2.28 alloys retains a large value in the low magnetic field of 1.0 T. The maximum magnetic entropy change for (Gd0.80Tb0.20)5Si1.72Ge2.28 alloy in the magnetic field from 0 to 1.0 T reaches 8.7 J/(kg·K), which is nearly 4 times as large as that of (Gd0.3Dy0.7)5Si4 compound (|-Smax| = 2.24 J/(kg·K), T_C = 198 K).
文摘为探究静磁场辅助冷冻(static magnetic field assisted freezing,SMAF)对牛肉品质的影响,采用不同强度SMAF(0、2、4、6、8、10 mT,-18℃),对比分析冷冻参数对牛背最长肌品质的影响。结果表明:与对照组相比,SMAF-6、8、10处理组相变时间分别显著缩短15%、25%和6.7%(P<0.05);SMAF处理有效提高了肌肉的持水性(解冻损失率、蒸煮损失率和离心损失率),降低了样品的ΔE(P<0.05),但对样品的pH值和硫代巴比妥酸反应物值无显著影响(P>0.05);此外,剪切力与肌原纤维小片化指数的结果一致,SMAF处理维持了牛肉的剪切力;十二烷基硫酸钠-聚丙烯酰胺凝胶电泳结果显示,SMAF处理可以减少肉品经冷冻-解冻后蛋白质含量的降低。综上,在适当的静磁场强度下辅助冷冻,可节省冻结时间,提高肌肉持水力,减少蛋白质含量的降低,从而改善牛肉品质,其中SMAF-8处理效果最佳。
