When the proton exchange membrane fuel cell(PEMFC)system is running,there will be a condition that does not require power output for a short time.In order to achieve zero power output under low power consumption,it is...When the proton exchange membrane fuel cell(PEMFC)system is running,there will be a condition that does not require power output for a short time.In order to achieve zero power output under low power consumption,it is necessary to consider the diversity of control targets and the complexity of dynamic models,which brings the challenge of high-precision tracking control of the stack output power and cathode intake flow.For system idle speed control,a modelbased nonlinear control framework is constructed in this paper.Firstly,the nonlinear dynamic model of output power and cathode intake flow is derived.Secondly,a control scheme combining nonlinear extended Kalman filter observer and state feedback controller is designed.Finally,the control scheme is verified on the PEMFC experimental platform and compared with the proportion-integration-differentiation(PID)controller.The experimental results show that the control strategy proposed in this paper can realize the idle speed control of the fuel cell system and achieve the purpose of zero power output.Compared with PID controller,it has faster response speed and better system dynamics.展开更多
Removing copper from nickel electrolysis anode solution has been a major keypoint in the nickel metallurgy industry.In this study,we proposed a novel process flow to promote removing copper from nickel electrolysis an...Removing copper from nickel electrolysis anode solution has been a major keypoint in the nickel metallurgy industry.In this study,we proposed a novel process flow to promote removing copper from nickel electrolysis anode solution.A simulated nickel anode solution was designed,and static and dynamic adsorption experiments were conducted to determine the best of solution pH,adsorption time and temperature,resin dosage and particle size,and stirring speed.The optimal conditions were explored for copper removal from nickel electrolysis anode solution.Based on the optimal experimental conditions and the relevant experimental data,a novel process for copper removal from nickel electrolysis anodes was designed and verified.This novel process of copper removal from nickel electrolysis anodes was confirmed with nickel anolyte solution with nickel 50−60 g/L and copper 0.5 g/L.After finishing the novel process of copper removal,the nickel in the purified nickel anolyte became undetectable and copper concentration was 3 mg/L,the novel process of resin adsorption to remove copper from nickel anode solution through static and dynamic adsorptions has an efficacious copper removal.It is a beneficial supplement to traditional methods.展开更多
The purpose of the covert communication scheme is to conceal the communication behavior entirely.In such schemes,the sender and receiver rely on secret keys to establish a covert channel.However,conventional key excha...The purpose of the covert communication scheme is to conceal the communication behavior entirely.In such schemes,the sender and receiver rely on secret keys to establish a covert channel.However,conventional key exchange protocols would expose the key exchange process between them.An adversary who observes the key exchange would be aware of the existence of communication behavior.The keys used in covert communication are not suitable to be generated through conventional key exchange schemes.To address this,we propose a blockchain-based covert elliptic-curve Diffie-Hellman key exchange scheme(BCDH)to conceal the process of the key exchange in blockchain transactions.Following a straightforward setup,BCDH allows the sender and receiver to covertly exchange a secret key on a blockchain without direct communication.Furthermore,we expand the BCDH approach to operate across multiple blockchains,further enhancing its covertness and stability.We analyze BCDH from several perspectives,including covertness,security,randomness,etc.Additionally,we implement a prototype of BCDH on the Ethereum platform to assess its feasibility and performance.Our evaluation demonstrates that BCDH is efficient and well-suited for real-world applications.展开更多
In this research,the thermal performance of a single U-tube vertical ground heat exchanger is evaluated numerically as a function of the most influential flow parameters,namely,the soil porosity,volumetric heat capaci...In this research,the thermal performance of a single U-tube vertical ground heat exchanger is evaluated numerically as a function of the most influential flow parameters,namely,the soil porosity,volumetric heat capacity,and thermal conductivity of the backfill material,inlet volume flow rate,and inlet fluid temperature.The results are discussed in terms of the variations of the heat exchange rate,the effective thermal resistance,and the effectiveness of the ground heat exchanger.They show that the inlet volume flow rate,inlet fluid temperature,and backfill material thermal conductivity have significant effects on the thermal performance of the ground heat exchanger,such that by decreasing the inlet volume flow rate and increasing the backfill material thermal conductivity and inlet fluid temperature,the outlet fluid temperature decreases considerably.On the contrary,the soil porosity and backfill material volumetric heat capacity have negligible effects on the studied ground heat exchanger’s thermal performance.The lowest inlet fluid temperature reaches a the maximum effective thermal resistance of borehole and soil,and consequently the minimum heat transfer rate and effectiveness.Also,multilinear regression analyses are performed to determine the most feasible models able to predict the thermal properties of the single U-tube ground heat exchanger.展开更多
Aiming at the ground-coupled source heat pump that possesses the shortcomings of occupying larger land,this article studies the heat exchanged of heat exchanger in piling,and compares it with common heat exchangers bu...Aiming at the ground-coupled source heat pump that possesses the shortcomings of occupying larger land,this article studies the heat exchanged of heat exchanger in piling,and compares it with common heat exchangers buried directly. The result indicates that the heat exchanger makes the best use of structure of building,saves land,reduces the construction cost,and the heat exchanged is obviously more than exchangers buried directly. In winter condition,when W-shape pipe heat exchanger in pile foundation is 50 m deep and diameter is 800 mm,it transfers 1.2-1.3 times as large as the one of single U-shape buried directly at the flow rate of 0.6 m/s,whose borehole diameter is 300 mm. And in summer condition it does about 2.0-2.3 times as that of U-shape one.展开更多
The exchanged hypercube EH（s, t） （where s ≥ 1 and t ≥ 1） is obtained by systematically reducing links from a regular hypercube Q,＋t＋l. One-step diagnosis of exchanged hypercubes which involves only one testi...The exchanged hypercube EH（s, t） （where s ≥ 1 and t ≥ 1） is obtained by systematically reducing links from a regular hypercube Q,＋t＋l. One-step diagnosis of exchanged hypercubes which involves only one testing phase during which processors test each other is discussed. The diagnosabilities of exchanged hypercubes are studied by using the pessimistic one-step diagno- sis strategy under two kinds of diagnosis models： the PMC model and the MM model. The main results presented here are the two proofs that the degree of diagnosability of the EH（s, t） under pessimistic one-step tl/tl fault diagnosis strategy is 2s where I ≤ s ≤ t （respectively, 2t, where 1 ≤ t ≤ s） based on the PMC model and that it is also 2s where 1 ≤ s ≤ t （respectively, 2t, where 1 ≤ t ≤ s） based on the MM＊ model.展开更多
With the purpose of enhancing effective collaboration between architects and structural engineers in the building design field, an integration tool was developed for supporting information exchange from architectural ...With the purpose of enhancing effective collaboration between architects and structural engineers in the building design field, an integration tool was developed for supporting information exchange from architectural model to structural model. The PKPM （Bopomofo acronym, a Chinese building design software） structural model and an industry foundation classes （IFC） data model were adopted and analyzed to design the framework of the integration tool. The technique of mixed program languages （C＋＋ and FORTRAN） was applied to developing the tool software, and the connectivity relationships and intersection nodes between the structural elements were optimized and simplified. A case study was implemented to illustrate the method to use the integration tool for information exchange from IFC-format architectural model to PKPM structural model. The results show that the tool can extract the information of architectural model and form a corresponding structural model. The presented method can help to enhance the modeline efficiency at the structural design phase.展开更多
A process of removing impurities,such as Fe,Zr,Ti,Al,Si,from scandium solution by ion exchange was proposed.Various resins’selectivity was studied in scandium chloride solution.The results indicated that D851resin ha...A process of removing impurities,such as Fe,Zr,Ti,Al,Si,from scandium solution by ion exchange was proposed.Various resins’selectivity was studied in scandium chloride solution.The results indicated that D851resin had high selectivity of Sc at low acidity,and high selectivity of Zr at high acidity;D370resin had high selectivity of Fe and Si in high acidity.A new technical process of removing impurities from scandium chloride solution was proposed,which includes D370resin adsorbing Fe in high acidity,D851resin adsorbing Zr in medium acidity and D851resin adsorbing Sc at low acidity.Flow experimental results show that removal rates of Al,Ca,Fe,Zr,Ti and Si,were100%,99.6%,100%,100%,99.5%and100%respectively.展开更多
The temperature of proton exchange membrane fuel cell stack and the stoichiometric oxygen in cathode have relationship with the performance and life span of fuel cells closely. The thermal coefficients were taken as i...The temperature of proton exchange membrane fuel cell stack and the stoichiometric oxygen in cathode have relationship with the performance and life span of fuel cells closely. The thermal coefficients were taken as important factors affecting the temperature distribution of fuel cells and components. According to the experimental analysis, when the stoichiometric oxygen in cathode is greater than or equal to 1.8, the stack voltage loss is the least. A novel genetic algorithm was developed to identify and optimize the variables in dynamic thermal model of proton exchange membrane fuel cell stack, making the outputs of temperature model approximate to the actual temperature, and ensuring that the maximal error is less than 1 ℃. At the same time, the optimum region of stoichiometric oxygen is obtained, which is in the range of 1.8-2.2 and accords with the experimental analysis results. The simulation and experimental results show the effectiveness of the proposed algorithm.展开更多
The effectiveness of a magnetic ion exchange resin （MIEX） for the treatment of Hongze Lake water in China was evaluated, The kinetics of natural organic matter （NOM） removal at various MIEX doses and contact time,...The effectiveness of a magnetic ion exchange resin （MIEX） for the treatment of Hongze Lake water in China was evaluated, The kinetics of natural organic matter （NOM） removal at various MIEX doses and contact time, multiple-loading experiments, impacts of MIEX prior to coagulation on coagulant demands and the effectiveness of combination of MIEX, pre-chlorination and coagulation were investigated. Kinetic experimental results show that more than 80% UV254 and 67% dissolved organic carbon （DOC） from raw water can be removed by the use of MIEX alone. 94% sulfate, 69% nitrate and 98% bromide removals are obtained after the first use of MIEX in multiple-loading experiments. It is suggested that MIEX can be loaded up to 1 250 bed volume （BV, volume ratio of tested water to resin） or more without saturation when regarding organics removal as a target. MIEX can remove organics to a greater extend than coagulation and lower the coagulant demand when combining with coagulation. Chlorination experimental results show that MIEX can remove 57% chlorine demand and 77% trihalomethane formation potential （THMFP） for raw water. Pre-chlorination followed by MIEX and coagulation can give additional organic and THMFP removals. The results suggest that MIEX provides a new method to solve thc problem algae reproduction.展开更多
基金Supported by the Major Science and Technology Projects in Jilin Province and Changchun City(20220301010GX).
文摘When the proton exchange membrane fuel cell(PEMFC)system is running,there will be a condition that does not require power output for a short time.In order to achieve zero power output under low power consumption,it is necessary to consider the diversity of control targets and the complexity of dynamic models,which brings the challenge of high-precision tracking control of the stack output power and cathode intake flow.For system idle speed control,a modelbased nonlinear control framework is constructed in this paper.Firstly,the nonlinear dynamic model of output power and cathode intake flow is derived.Secondly,a control scheme combining nonlinear extended Kalman filter observer and state feedback controller is designed.Finally,the control scheme is verified on the PEMFC experimental platform and compared with the proportion-integration-differentiation(PID)controller.The experimental results show that the control strategy proposed in this paper can realize the idle speed control of the fuel cell system and achieve the purpose of zero power output.Compared with PID controller,it has faster response speed and better system dynamics.
基金Project(2019yff0216502)supported by the National Key Research&Development Plan of Ministry of Science and Technology of ChinaProject(2021SK1020-4)supported by the Major Science and Technological Innovation Project of Hunan Province,China。
文摘Removing copper from nickel electrolysis anode solution has been a major keypoint in the nickel metallurgy industry.In this study,we proposed a novel process flow to promote removing copper from nickel electrolysis anode solution.A simulated nickel anode solution was designed,and static and dynamic adsorption experiments were conducted to determine the best of solution pH,adsorption time and temperature,resin dosage and particle size,and stirring speed.The optimal conditions were explored for copper removal from nickel electrolysis anode solution.Based on the optimal experimental conditions and the relevant experimental data,a novel process for copper removal from nickel electrolysis anodes was designed and verified.This novel process of copper removal from nickel electrolysis anodes was confirmed with nickel anolyte solution with nickel 50−60 g/L and copper 0.5 g/L.After finishing the novel process of copper removal,the nickel in the purified nickel anolyte became undetectable and copper concentration was 3 mg/L,the novel process of resin adsorption to remove copper from nickel anode solution through static and dynamic adsorptions has an efficacious copper removal.It is a beneficial supplement to traditional methods.
文摘The purpose of the covert communication scheme is to conceal the communication behavior entirely.In such schemes,the sender and receiver rely on secret keys to establish a covert channel.However,conventional key exchange protocols would expose the key exchange process between them.An adversary who observes the key exchange would be aware of the existence of communication behavior.The keys used in covert communication are not suitable to be generated through conventional key exchange schemes.To address this,we propose a blockchain-based covert elliptic-curve Diffie-Hellman key exchange scheme(BCDH)to conceal the process of the key exchange in blockchain transactions.Following a straightforward setup,BCDH allows the sender and receiver to covertly exchange a secret key on a blockchain without direct communication.Furthermore,we expand the BCDH approach to operate across multiple blockchains,further enhancing its covertness and stability.We analyze BCDH from several perspectives,including covertness,security,randomness,etc.Additionally,we implement a prototype of BCDH on the Ethereum platform to assess its feasibility and performance.Our evaluation demonstrates that BCDH is efficient and well-suited for real-world applications.
文摘In this research,the thermal performance of a single U-tube vertical ground heat exchanger is evaluated numerically as a function of the most influential flow parameters,namely,the soil porosity,volumetric heat capacity,and thermal conductivity of the backfill material,inlet volume flow rate,and inlet fluid temperature.The results are discussed in terms of the variations of the heat exchange rate,the effective thermal resistance,and the effectiveness of the ground heat exchanger.They show that the inlet volume flow rate,inlet fluid temperature,and backfill material thermal conductivity have significant effects on the thermal performance of the ground heat exchanger,such that by decreasing the inlet volume flow rate and increasing the backfill material thermal conductivity and inlet fluid temperature,the outlet fluid temperature decreases considerably.On the contrary,the soil porosity and backfill material volumetric heat capacity have negligible effects on the studied ground heat exchanger’s thermal performance.The lowest inlet fluid temperature reaches a the maximum effective thermal resistance of borehole and soil,and consequently the minimum heat transfer rate and effectiveness.Also,multilinear regression analyses are performed to determine the most feasible models able to predict the thermal properties of the single U-tube ground heat exchanger.
基金Project(2006BAJ03A10) supported by the National Key Technology R&D Program of China
文摘Aiming at the ground-coupled source heat pump that possesses the shortcomings of occupying larger land,this article studies the heat exchanged of heat exchanger in piling,and compares it with common heat exchangers buried directly. The result indicates that the heat exchanger makes the best use of structure of building,saves land,reduces the construction cost,and the heat exchanged is obviously more than exchangers buried directly. In winter condition,when W-shape pipe heat exchanger in pile foundation is 50 m deep and diameter is 800 mm,it transfers 1.2-1.3 times as large as the one of single U-shape buried directly at the flow rate of 0.6 m/s,whose borehole diameter is 300 mm. And in summer condition it does about 2.0-2.3 times as that of U-shape one.
基金supported by the National Natural Science Fundation of China(61363002)
文摘The exchanged hypercube EH（s, t） （where s ≥ 1 and t ≥ 1） is obtained by systematically reducing links from a regular hypercube Q,＋t＋l. One-step diagnosis of exchanged hypercubes which involves only one testing phase during which processors test each other is discussed. The diagnosabilities of exchanged hypercubes are studied by using the pessimistic one-step diagno- sis strategy under two kinds of diagnosis models： the PMC model and the MM model. The main results presented here are the two proofs that the degree of diagnosability of the EH（s, t） under pessimistic one-step tl/tl fault diagnosis strategy is 2s where I ≤ s ≤ t （respectively, 2t, where 1 ≤ t ≤ s） based on the PMC model and that it is also 2s where 1 ≤ s ≤ t （respectively, 2t, where 1 ≤ t ≤ s） based on the MM＊ model.
基金Project(2006BAJ01B01-01) supported by the National Key Technologies R&D Program of China during the 11th Five-Year Plan Period
文摘With the purpose of enhancing effective collaboration between architects and structural engineers in the building design field, an integration tool was developed for supporting information exchange from architectural model to structural model. The PKPM （Bopomofo acronym, a Chinese building design software） structural model and an industry foundation classes （IFC） data model were adopted and analyzed to design the framework of the integration tool. The technique of mixed program languages （C＋＋ and FORTRAN） was applied to developing the tool software, and the connectivity relationships and intersection nodes between the structural elements were optimized and simplified. A case study was implemented to illustrate the method to use the integration tool for information exchange from IFC-format architectural model to PKPM structural model. The results show that the tool can extract the information of architectural model and form a corresponding structural model. The presented method can help to enhance the modeline efficiency at the structural design phase.
基金Project(2015BAB19B03)supported by the National Science and Technology Supporting Plan of China
文摘A process of removing impurities,such as Fe,Zr,Ti,Al,Si,from scandium solution by ion exchange was proposed.Various resins’selectivity was studied in scandium chloride solution.The results indicated that D851resin had high selectivity of Sc at low acidity,and high selectivity of Zr at high acidity;D370resin had high selectivity of Fe and Si in high acidity.A new technical process of removing impurities from scandium chloride solution was proposed,which includes D370resin adsorbing Fe in high acidity,D851resin adsorbing Zr in medium acidity and D851resin adsorbing Sc at low acidity.Flow experimental results show that removal rates of Al,Ca,Fe,Zr,Ti and Si,were100%,99.6%,100%,100%,99.5%and100%respectively.
基金Project (2003AA517020) supported by the National High-Technology Research Plan of China
文摘The temperature of proton exchange membrane fuel cell stack and the stoichiometric oxygen in cathode have relationship with the performance and life span of fuel cells closely. The thermal coefficients were taken as important factors affecting the temperature distribution of fuel cells and components. According to the experimental analysis, when the stoichiometric oxygen in cathode is greater than or equal to 1.8, the stack voltage loss is the least. A novel genetic algorithm was developed to identify and optimize the variables in dynamic thermal model of proton exchange membrane fuel cell stack, making the outputs of temperature model approximate to the actual temperature, and ensuring that the maximal error is less than 1 ℃. At the same time, the optimum region of stoichiometric oxygen is obtained, which is in the range of 1.8-2.2 and accords with the experimental analysis results. The simulation and experimental results show the effectiveness of the proposed algorithm.
基金Project(2008ZX07421-002) supported by the Key National Science and Technology Project of ChinaProject(50638020) supported by the National Natural Science Foundation of China
文摘The effectiveness of a magnetic ion exchange resin （MIEX） for the treatment of Hongze Lake water in China was evaluated, The kinetics of natural organic matter （NOM） removal at various MIEX doses and contact time, multiple-loading experiments, impacts of MIEX prior to coagulation on coagulant demands and the effectiveness of combination of MIEX, pre-chlorination and coagulation were investigated. Kinetic experimental results show that more than 80% UV254 and 67% dissolved organic carbon （DOC） from raw water can be removed by the use of MIEX alone. 94% sulfate, 69% nitrate and 98% bromide removals are obtained after the first use of MIEX in multiple-loading experiments. It is suggested that MIEX can be loaded up to 1 250 bed volume （BV, volume ratio of tested water to resin） or more without saturation when regarding organics removal as a target. MIEX can remove organics to a greater extend than coagulation and lower the coagulant demand when combining with coagulation. Chlorination experimental results show that MIEX can remove 57% chlorine demand and 77% trihalomethane formation potential （THMFP） for raw water. Pre-chlorination followed by MIEX and coagulation can give additional organic and THMFP removals. The results suggest that MIEX provides a new method to solve thc problem algae reproduction.
