Lithium(Li) metal,possessing ultrahigh theoretical capacity and the lowest electrode potential,is regarded as a promising new generation anode material.However,the uncontrollable growth of Li dendrites during cycling ...Lithium(Li) metal,possessing ultrahigh theoretical capacity and the lowest electrode potential,is regarded as a promising new generation anode material.However,the uncontrollable growth of Li dendrites during cycling process gives rise to problems as capacity decay and short circuit,suppressing the cycling and safety performances of Li metal battery.In this contribution,porous conductive interlayer(PCI),composed of carbon nanofibers(CNFs) and polyisophthaloyl metaphenylene diamine(PMIA),is developed to suppress Li dendrites and stabilize Li metal anode.PCI possesses the excellent conductive ability of CNFs and the preeminent mechanical properties of PMIA at the same time.When Li metal contacts with PCI during cycling process,an equipotential surface forms on their interface,which eliminates the tip effect on Li anode and homogenizes Li-ions flux in combination with the uniform porous structure of PCI.Employed PCI,the Li|Cu cell exhibits a remarkable cycling stability with a high average Coulombic efficiency of 97.5% for 100 cycles at 0.5 mA cm^(-2).And the Li|LiFePO_4 cell exhibits improved rate capability(114.7 mAh g^(-1) at 5.0 C) and enhanced cycling performance(78.9% capacity retention rate over 500 cycles at 1.0 C).This work provides a fresh and effective solving strategy for the problem of dendrites in Li metal battery.展开更多
This paper applies the multiple ellipsoid model to the 16Ne （20Ne, 28Ne, 34Ne）-Na2 collision systems, and calcu- lates integral cross sections for rotational excitation at the incident energy of 190 meV. It can be s...This paper applies the multiple ellipsoid model to the 16Ne （20Ne, 28Ne, 34Ne）-Na2 collision systems, and calcu- lates integral cross sections for rotational excitation at the incident energy of 190 meV. It can be seen that the accuracy of the integral cross sections can be improved by increasing the number of equipotential ellipsoid surfaces. Moreover, by analysing the differences of these integral cross sections, it obtains the change rules of the integral cross sections with the increase of rotational angular quantum number j＇, and with the change of the mass of isotope substitution neon atom. Finally, the contribution of different regions of the potential to inelastic cross sections for 20Ne-Na2 collision system is investigated at relative incident energy of 190 meV.展开更多
基金financially supported by the National Natural Science Foundation of China (Grant Nos. 21376001, 21576028 and 21506012)。
文摘Lithium(Li) metal,possessing ultrahigh theoretical capacity and the lowest electrode potential,is regarded as a promising new generation anode material.However,the uncontrollable growth of Li dendrites during cycling process gives rise to problems as capacity decay and short circuit,suppressing the cycling and safety performances of Li metal battery.In this contribution,porous conductive interlayer(PCI),composed of carbon nanofibers(CNFs) and polyisophthaloyl metaphenylene diamine(PMIA),is developed to suppress Li dendrites and stabilize Li metal anode.PCI possesses the excellent conductive ability of CNFs and the preeminent mechanical properties of PMIA at the same time.When Li metal contacts with PCI during cycling process,an equipotential surface forms on their interface,which eliminates the tip effect on Li anode and homogenizes Li-ions flux in combination with the uniform porous structure of PCI.Employed PCI,the Li|Cu cell exhibits a remarkable cycling stability with a high average Coulombic efficiency of 97.5% for 100 cycles at 0.5 mA cm^(-2).And the Li|LiFePO_4 cell exhibits improved rate capability(114.7 mAh g^(-1) at 5.0 C) and enhanced cycling performance(78.9% capacity retention rate over 500 cycles at 1.0 C).This work provides a fresh and effective solving strategy for the problem of dendrites in Li metal battery.
基金Project supported by the National Natural Science Foundation of China （Grant Nos. 10974139 and 10964002）, the Doctoral Program Foundation of Institution of Higher Education of China （Grant No. 20050610010）, the Science Technology Foundation of Guizhou Province of China （Grant No. [2009]2066） and Project of Aiding Elites＇ Research Condition of Guizhou Province （Grant No. TZJF-2008-42）.
文摘This paper applies the multiple ellipsoid model to the 16Ne （20Ne, 28Ne, 34Ne）-Na2 collision systems, and calcu- lates integral cross sections for rotational excitation at the incident energy of 190 meV. It can be seen that the accuracy of the integral cross sections can be improved by increasing the number of equipotential ellipsoid surfaces. Moreover, by analysing the differences of these integral cross sections, it obtains the change rules of the integral cross sections with the increase of rotational angular quantum number j＇, and with the change of the mass of isotope substitution neon atom. Finally, the contribution of different regions of the potential to inelastic cross sections for 20Ne-Na2 collision system is investigated at relative incident energy of 190 meV.
