Traditional polymeric photocatalysts are typically constructed using aromatic building blocks to enhanceπ-conjugation.However,their inherent hydrophobicity and rigid structure lead to poor dispersibility in aqueous s...Traditional polymeric photocatalysts are typically constructed using aromatic building blocks to enhanceπ-conjugation.However,their inherent hydrophobicity and rigid structure lead to poor dispersibility in aqueous solutions,resulting in significant optical losses and exciton recombination.In this study,two series of six novel polymer photocatalysts(FLUSO,FLUSO-PEG10,FLUSO-PEG30;CPDTSO,CPDTSO-PEG10,CPDTSO-PEG30)are designed and synthesized by incorporating the hydrophilic,non-conjugated polyethylene glycol(PEG)chain,into both the main and side chains of polymers.By precisely optimizing the ratio of hydrophilic PEG segments,the water dispersibility is significantly improved while the light absorption capability of the polymer photocatalysts is well maintained.The experimental results confirm that the optimized FLUSO-PEG10 exhibits excellent photocatalytic hydrogen evolution rate,reaching up to 33.9 mmol/(g·h),which is nearly three times higher than that of fullyπ-conjugated counterparts.Water contact angles and particle size analyses reveal that incorporating non-conjugated segments into the main chains enhances the capacitance of the polymer/water interface and reduces particle aggregation,leading to improved photocatalyst dispersion and enhanced charge generation.展开更多
Solid-state lithium batteries have become a research hotspot in the field of large-scale energy storage due to their excellent safety performance.The development of high-voltage positive electrode materials matched wi...Solid-state lithium batteries have become a research hotspot in the field of large-scale energy storage due to their excellent safety performance.The development of high-voltage positive electrode materials matched with lithium metal anode have advanced the energy density of solid-state lithium batteries close to or even exceeding that of lithium batteries based on a liquid electrolyte,which is expected to be commercialized in the future.However,in high voltage conditions(>4.3 V),the decomposition of electrolyte components,structural degradation,and interface side reactions significantly reduce battery performance and hinder its further development.This review summarizes the latest research progress of inorganic electrolytes,polymer electrolytes,and composite electrolytes in high-voltage solid-state lithium batteries.At the same time,the designs of high-voltage polymer gel electrolyte and high-voltage quasi solid-state electrolyte are introduced in detail.In addition,interface engineering is crucial for improving the overall performance of high-voltage solid-state batteries.Finally,we highlight the challenges faced by high-voltage solid-state lithium batteries and put forward our own views on future research directions.This review offers instructive insights into the advancement of high-voltage solid-state lithium batteries for large-scale energy storage applications.展开更多
In the last decade,space solar power satellites(SSPSs)have been conceived to support net-zero carbon emissions and have attracted considerable attention.Electric energy is transmitted to the ground via a microwave pow...In the last decade,space solar power satellites(SSPSs)have been conceived to support net-zero carbon emissions and have attracted considerable attention.Electric energy is transmitted to the ground via a microwave power beam,a technology known as microwave power transmission(MPT).Due to the vast transmission distance of tens of thousands of kilometers,the power transmitting antenna array must span up to 1 kilometer in diameter.At the same time,the size of the rectifying array on the ground should extend over a few kilometers.This makes the MPT system of SSPSs significantly larger than the existing aerospace engineering system.To design and operate a rational MPT system,comprehensive optimization is required.Taking the space MPT system engineering into consideration,a novel multi-objective optimization function is proposed and further analyzed.The multi-objective optimization problem is modeled mathematically.Beam collection efficiency(BCE)is the primary factor,followed by the thermal management capability.Some tapers,designed to solve the conflict between BCE and the thermal problem,are reviewed.In addition to these two factors,rectenna design complexity is included as a functional factor in the optimization objective.Weight coefficients are assigned to these factors to prioritize them.Radiating planar arrays with different aperture illumination fields are studied,and their performances are compared using the multi-objective optimization function.Transmitting array size,rectifying array size,transmission distance,and transmitted power remaine constant in various cases,ensuring fair comparisons.The analysis results show that the proposed optimization function is effective in optimizing and selecting the MPT system architecture.It is also noted that the multi-objective optimization function can be expanded to include other factors in the future.展开更多
Assessing the vulnerability of a platform is crucial in its design.In fact,the results obtained from vulnerability analyses provide valuable information,leading to precise design choices or corrective solutions that e...Assessing the vulnerability of a platform is crucial in its design.In fact,the results obtained from vulnerability analyses provide valuable information,leading to precise design choices or corrective solutions that enhance the platform's chances of surviving different scenarios.Such scenarios can involve various types of threats that can affect the platform's survivability.Among such,blast waves impacting the platform's structure represent critical conditions that have not yet been studied in detail.That is,frameworks for vulnerability assessment that can deal with blast loading have not been presented yet.In this context,this work presents a fast-running engineering tool that can quantify the risk that a structure fails when it is subjected to blast loading from the detonation of high explosive-driven threats detonating at various distances from the structure itself.The tool has been implemented in an in-house software that calculates vulnerability to various impacting objects,and its capabilities have been shown through a simplified,yet realistic,case study.The novelty of this research lies in the development of an integrated computational environment capable of calculating the platform's vulnerability to blast waves,without the need for running expensive finite element simulations.In fact,the proposed tool is fully based on analytical models integrated with a probabilistic approach for vulnerability calculation.展开更多
Computer-integrated manufacturing (CIM) and revers e engineering (RE) have changed drastically the concept of product re-design, pla nning and manufacture of components. However, the main problems currently facing the...Computer-integrated manufacturing (CIM) and revers e engineering (RE) have changed drastically the concept of product re-design, pla nning and manufacture of components. However, the main problems currently facing the developers of reverse engineering system, is the time consuming digitis ation of 3D data and the conversion of large amounts of data into a concise and manageable format and linking it to a CAD/CAM system. Automated 3-D profile gen eration, measurements and inspection of manufactured component represents one of the important functions in reverse engineering and in the improvements in produ ct quality in rapid product developments. The paper presents a novel methodology for the development of a reverse enginee ring technique for use in the rapid product development in a CIM environment . The system developed provides integration, data capture and manipulation, dat a transfer between a CAD, CAM, Computer-aided inspection (CAI) and a 3-D profi le scanning system. An efficient scanning strategy has been developed for scann ing and surfaces data acquisition. The products were scanned using a laser scann ing system with a dedicated scan control card and the associated software packag es. A versatile rig was developed for the ease of data gathering of the profile scanning process. The surface data collected was then used to build a mathematic al surface model, which was then used to develop a virtual 3-D model of the pro duct. The resulting surface model provides the geometrical input to the subseque nt machining operation using either a CNC system or other manufacturing operatio n e.g. dies casting/mould casting etc. The prototypes developed were inspected u sing a state-of-the art CNC-CMM that was integrated to the CAD/CAM system. Si nce the scanning/digitised data captured by laser scanning probes requires no ma nual editing, significant time saving over most non-contact probe systems was a chieved. Since the creation of an accurate CAD model of a redesigned component o r a prototype constitute a major element of the total turnaround time; maximum r eturn can be achieved by increasing the efficiency of the redesigning process. T he paper also outlines with a case study the application of the developed system . The system developed offers the flexibility of using the concept of reverse en gineering of a variety of components with the complimentary facility of integrat ion between CAD/CAM Computer-aided Inspection (CAI) systems and a scanning syst em. The developed reverse engineering application in an integrated manufacturing system can increase the consistency, improve cost-efficiency, reduce produ ct turn around and skill levels required to redesign, reengineer and prototyping components and products.展开更多
The definitions, methodology, applications, and perspectives of process system engineering are discussed from a strategic point of view. The focal points in future development of process systems engineering are to bre...The definitions, methodology, applications, and perspectives of process system engineering are discussed from a strategic point of view. The focal points in future development of process systems engineering are to break through in methodology, to expand application fields, and to develop a new generation of process simulation systems.展开更多
Space robots possess unique distinguishing features unlike general robots on earth, due to the particular environments in space. The developing of various practical space robots promoting the improvement of space scie...Space robots possess unique distinguishing features unlike general robots on earth, due to the particular environments in space. The developing of various practical space robots promoting the improvement of space science and technology is a complex man-machine-environment engineering problem. This paper analyses from the systems engineering viewpoint the space robot system in the scope of the architecture of robotics discipline, space environment characteristics, man-machine-environment system of space robots, the general methodology of project systems engineering and the process of space robot systems engineering.展开更多
Control systems contribute to every aspect of modem society.In our life control systems exist in almost everywhere such as toasters,VCRs and smart phones.In science and technology,control systems already have widespre...Control systems contribute to every aspect of modem society.In our life control systems exist in almost everywhere such as toasters,VCRs and smart phones.In science and technology,control systems already have widespread applications,for example,steering ships,guiding missiles and driving driverless cars in the near future.In all the control systems,systems are the key platform where control should be put into.It is at the system level that control shows its values.Extracting and formulating展开更多
The traditional stability analysis method of geogrid reinforced slopes does not consider the effect of lateral swelling,so it is not applicable to reinforced expansive soil slopes.This paper reports a new stability an...The traditional stability analysis method of geogrid reinforced slopes does not consider the effect of lateral swelling,so it is not applicable to reinforced expansive soil slopes.This paper reports a new stability analysis method for geogrid reinforced expansive soil slopes.The additional pullout force of the free zone due to the lateral swelling and the anti-pullout safety factor of each geogrid layer were obtained by ensuring the overall stability of the reinforced slope.The optimum design was carried out to treat an expansive soil cut slope in Hubei Province,China,by changing the spacing and length of geogrid reinforcement.Calculation results show that the additional pullout force caused by lateral swelling has a great influence on the anti-pullout stability of geogrids,and the local stability of the reinforced slope will be overestimated if the swelling effect of soil in the free zone is not considered.展开更多
Aiming at the intervention decision-making problem in manned/unmanned aerial vehicle（MAV/UAV） cooperative engagement, this paper carries out a research on allocation strategy of emergency discretion based on human f...Aiming at the intervention decision-making problem in manned/unmanned aerial vehicle（MAV/UAV） cooperative engagement, this paper carries out a research on allocation strategy of emergency discretion based on human factors engineering（HFE）.Firstly, based on the brief review of research status of HFE, it gives structural description to emergency in the process of cooperative engagement and analyzes intervention of commanders. After that,constraint conditions of intervention decision-making of commanders based on HFE（IDMCBHFE） are given, and the mathematical model, which takes the overall efficiency value of handling emergencies as the objective function, is established. Then, through combining K-best and variable neighborhood search（VNS） algorithm, a K-best optimization variable neighborhood search mixed algorithm（KBOVNSMA） is designed to solve the model. Finally,through three groups of simulation experiments, effectiveness and superiority of the proposed algorithm are verified.展开更多
This paper presents a principle and a method of col or 3D laser scanning measurement. Based on the fundamental monochrome 3D measureme nt study, color information capture, color texture mapping, coordinate computati o...This paper presents a principle and a method of col or 3D laser scanning measurement. Based on the fundamental monochrome 3D measureme nt study, color information capture, color texture mapping, coordinate computati on and other techniques are performed to achieve color 3D measurement. The syste m is designed and composed of a line laser light emitter, one color CCD camera, a motor-driven rotary filter, a circuit card and a computer. Two steps in captu ring object’s images in the measurement process: First, the color CCD camera ta kes the color picture of the object to be used for texture mapping in post proce ssing. Secondly, the monochrome data of the object is taken. The laser light emi tter is started; the light plane and the surface of the object intersect to form an undulate line, which forms an image on the CCD sensor. After the optic- electronics transformation, the electronic signals are captured and send to the computer. A new color 3D measurement model was derived, and a rapid calibra ting method to measure the system parameters was proposed--optical plane equat ion calibrating method. A calibrating drone was designed and built. 3D color sca nning system not only provides an object’s individual point information in the 3D coordinate, in the mean time, it provides the color information of each indiv idual point. This paper also advances a multi-frame auto-merging method, i.e. several frames of color 3D digital images measured are merged quickly according to their curvature characteristics and RGB information. Initial matching and fin e tune of the registration are completely performed by the computer; initial mat ching is via user interface in helping computer to find the transformation matri x. The transformation matrix is found according to the geometric characteristics chosen by hand. After the initial transformation matrix is found, fine tune of the registration is preformed to do the optimum adjustment to achieve a complete color textured 3D model. The system can be broadly used in the fields of produc t design, mold manufacture, multimedia, game development, animation, medical eng ineering, antique digitization, etc.展开更多
As it is commonly known,the estimation of physical and mechanical characteristics of rocks is very important issue in various geotechnical projects.The characteristics are mainly influenced by the microfabric-texture ...As it is commonly known,the estimation of physical and mechanical characteristics of rocks is very important issue in various geotechnical projects.The characteristics are mainly influenced by the microfabric-texture features of rocks.In this research,dry unit weight,effective porosity,point load index,Schmidt rebound hardness,uniaxial compressive strength,and texture coefficient were measured with the aim of correlating the physical and mechanical properties to the texture coefficient.For this purpose,a comprehensive laboratory testing program was conducted after collecting twenty sedimentary block samples including nine limestones and eleven mudstones,taken from Kalidromo(central Greece)in accordance with ASTM and ISRM standards.Also,mineralogical and petrographic properties,textural characteristics as well as X-ray diffractions were studied and the obtained results were statistically described and analysed.The maximum and minimum values of the texture coefficient were 0.13 and 0.50,respectively.The highest value was obtained for the rocks with a large amount of grains.Regression analyses were used to investigate the relationships between the texture coefficient and the engineering properties.Thus,empirical equations were developed and because of the good determination coefficients,they showed that all of the engineering properties were well correlated to the texture coefficient.展开更多
Vanadium redox flow batteries(VRFBs)are one of the most promising energy storage systems owing to their safety,efficiency,flexibility and scalability.However,the commercial viability of VRFBs is still hindered by the ...Vanadium redox flow batteries(VRFBs)are one of the most promising energy storage systems owing to their safety,efficiency,flexibility and scalability.However,the commercial viability of VRFBs is still hindered by the low electrochemical performance of the available carbon-based electrodes.Defect engineering is a powerful strategy to enhance the redox catalytic activity of carbon-based electrodes for VRFBs.In this paper,uniform carbon defects are introduced on the surfaces of carbon felt(CF)electrode by Ar plasma etching.Together with a higher specific surface area,the Ar plasma treated CF offers additional catalytic sites,allowing faster and more reversible oxidation/reduction reactions of vanadium ions.As a result,the VRFB using plasma treated electrode shows a power density of 1018.3 mW/cm^(2),an energy efficiency(EE)of 84.5%,and the EE remains stable over 1000 cycles.展开更多
The bone is a naturally occurring composite system comprising collagen matrix and hydroxyapatites capable of generating sufficient strength and toughness to support mechanical loads and resist fracture,respectively.Th...The bone is a naturally occurring composite system comprising collagen matrix and hydroxyapatites capable of generating sufficient strength and toughness to support mechanical loads and resist fracture,respectively.The material strength depends largely on the elastic properties,whereas the toughness depends on not only the elastic,but also the plastic properties.Thus,both elastic and plastic properties must be considered in the analysis of bone biomechanics and the design of osteogenic materials.The bone is capable of optimizing its elastic and plastic properties by integrating stiff hydroxyapatites and ductile collagen fibrils into a hierarchically ordered architecture,an effective mechanism to support the bone strength and toughness.Such a mechanism can be used as a model for designing osteogenic materials.展开更多
5-amino-4-nitrobenzo[1,2-c:3,4-c']bis([1,2,5]oxadiazole)1,6-dioxide(CL-18)exhibits significant potential as an initiating explosive.However,its current synthesis process remains non-scalable due to low yields and ...5-amino-4-nitrobenzo[1,2-c:3,4-c']bis([1,2,5]oxadiazole)1,6-dioxide(CL-18)exhibits significant potential as an initiating explosive.However,its current synthesis process remains non-scalable due to low yields and safety risks.In this study,we have developed a simple and safe synthetic route for CL-18.It was synthesized from 3,5-dihaloanisole in a four-step reaction with an overall yield exceeding 60%,surpassing all reported yields in the literature.Subsequently,recrystallization of CL-18 was successfully achieved by carefully selecting appropriate solvents and antisolvents to reduce its mechanical sensitivity.Ultimately,when DMF-ethanol was employed as the recrystallization solvent system,satisfactory product yield(>90%)and reduced mechanical sensitivity(IS=15 J;FS=216 N)were obtained.Additionally,CL-18 is derived from the rearrangement of oxygen atoms on i-CL-18 furoxan,and a comparative analysis of their physicochemical properties was conducted.The thermal stability of both compounds is similar,with onset decomposition temperatures recorded at 186 and 182℃respectively.Similarly,they exhibit 5 s breaking point temperatures of 236 and 237℃.Additionally,we present novel insights into the positional-isomerization-laser-ignition performance of CL-18 and its isomer i-CL-18 using laser irradiation for the first time.Remarkably,our findings demonstrate that i-CL-18 exhibits enhanced laser sensitivity,as it can be directly ignited by a 1064 nm wavelength laser,whereas CL-18 lacks this characteristic.展开更多
文摘Traditional polymeric photocatalysts are typically constructed using aromatic building blocks to enhanceπ-conjugation.However,their inherent hydrophobicity and rigid structure lead to poor dispersibility in aqueous solutions,resulting in significant optical losses and exciton recombination.In this study,two series of six novel polymer photocatalysts(FLUSO,FLUSO-PEG10,FLUSO-PEG30;CPDTSO,CPDTSO-PEG10,CPDTSO-PEG30)are designed and synthesized by incorporating the hydrophilic,non-conjugated polyethylene glycol(PEG)chain,into both the main and side chains of polymers.By precisely optimizing the ratio of hydrophilic PEG segments,the water dispersibility is significantly improved while the light absorption capability of the polymer photocatalysts is well maintained.The experimental results confirm that the optimized FLUSO-PEG10 exhibits excellent photocatalytic hydrogen evolution rate,reaching up to 33.9 mmol/(g·h),which is nearly three times higher than that of fullyπ-conjugated counterparts.Water contact angles and particle size analyses reveal that incorporating non-conjugated segments into the main chains enhances the capacitance of the polymer/water interface and reduces particle aggregation,leading to improved photocatalyst dispersion and enhanced charge generation.
基金supported by the National Key R&D Program of China(2024YFA1211100)the National Natural Science Foundation of China(52301278,22479080,52202254,92372001,22393900,and 92372203)+2 种基金the Natural Science Foundation of Jiangsu Province(BK20230937,BK20220966)the Science and Technology Plans of Tianjin(23JCYBJC00170,24JCJQJC00220,and 24ZXZSSS00390)the Fundamental Research Funds for the Central Universities(02063253167,30922010708)。
文摘Solid-state lithium batteries have become a research hotspot in the field of large-scale energy storage due to their excellent safety performance.The development of high-voltage positive electrode materials matched with lithium metal anode have advanced the energy density of solid-state lithium batteries close to or even exceeding that of lithium batteries based on a liquid electrolyte,which is expected to be commercialized in the future.However,in high voltage conditions(>4.3 V),the decomposition of electrolyte components,structural degradation,and interface side reactions significantly reduce battery performance and hinder its further development.This review summarizes the latest research progress of inorganic electrolytes,polymer electrolytes,and composite electrolytes in high-voltage solid-state lithium batteries.At the same time,the designs of high-voltage polymer gel electrolyte and high-voltage quasi solid-state electrolyte are introduced in detail.In addition,interface engineering is crucial for improving the overall performance of high-voltage solid-state batteries.Finally,we highlight the challenges faced by high-voltage solid-state lithium batteries and put forward our own views on future research directions.This review offers instructive insights into the advancement of high-voltage solid-state lithium batteries for large-scale energy storage applications.
文摘In the last decade,space solar power satellites(SSPSs)have been conceived to support net-zero carbon emissions and have attracted considerable attention.Electric energy is transmitted to the ground via a microwave power beam,a technology known as microwave power transmission(MPT).Due to the vast transmission distance of tens of thousands of kilometers,the power transmitting antenna array must span up to 1 kilometer in diameter.At the same time,the size of the rectifying array on the ground should extend over a few kilometers.This makes the MPT system of SSPSs significantly larger than the existing aerospace engineering system.To design and operate a rational MPT system,comprehensive optimization is required.Taking the space MPT system engineering into consideration,a novel multi-objective optimization function is proposed and further analyzed.The multi-objective optimization problem is modeled mathematically.Beam collection efficiency(BCE)is the primary factor,followed by the thermal management capability.Some tapers,designed to solve the conflict between BCE and the thermal problem,are reviewed.In addition to these two factors,rectenna design complexity is included as a functional factor in the optimization objective.Weight coefficients are assigned to these factors to prioritize them.Radiating planar arrays with different aperture illumination fields are studied,and their performances are compared using the multi-objective optimization function.Transmitting array size,rectifying array size,transmission distance,and transmitted power remaine constant in various cases,ensuring fair comparisons.The analysis results show that the proposed optimization function is effective in optimizing and selecting the MPT system architecture.It is also noted that the multi-objective optimization function can be expanded to include other factors in the future.
文摘Assessing the vulnerability of a platform is crucial in its design.In fact,the results obtained from vulnerability analyses provide valuable information,leading to precise design choices or corrective solutions that enhance the platform's chances of surviving different scenarios.Such scenarios can involve various types of threats that can affect the platform's survivability.Among such,blast waves impacting the platform's structure represent critical conditions that have not yet been studied in detail.That is,frameworks for vulnerability assessment that can deal with blast loading have not been presented yet.In this context,this work presents a fast-running engineering tool that can quantify the risk that a structure fails when it is subjected to blast loading from the detonation of high explosive-driven threats detonating at various distances from the structure itself.The tool has been implemented in an in-house software that calculates vulnerability to various impacting objects,and its capabilities have been shown through a simplified,yet realistic,case study.The novelty of this research lies in the development of an integrated computational environment capable of calculating the platform's vulnerability to blast waves,without the need for running expensive finite element simulations.In fact,the proposed tool is fully based on analytical models integrated with a probabilistic approach for vulnerability calculation.
文摘Computer-integrated manufacturing (CIM) and revers e engineering (RE) have changed drastically the concept of product re-design, pla nning and manufacture of components. However, the main problems currently facing the developers of reverse engineering system, is the time consuming digitis ation of 3D data and the conversion of large amounts of data into a concise and manageable format and linking it to a CAD/CAM system. Automated 3-D profile gen eration, measurements and inspection of manufactured component represents one of the important functions in reverse engineering and in the improvements in produ ct quality in rapid product developments. The paper presents a novel methodology for the development of a reverse enginee ring technique for use in the rapid product development in a CIM environment . The system developed provides integration, data capture and manipulation, dat a transfer between a CAD, CAM, Computer-aided inspection (CAI) and a 3-D profi le scanning system. An efficient scanning strategy has been developed for scann ing and surfaces data acquisition. The products were scanned using a laser scann ing system with a dedicated scan control card and the associated software packag es. A versatile rig was developed for the ease of data gathering of the profile scanning process. The surface data collected was then used to build a mathematic al surface model, which was then used to develop a virtual 3-D model of the pro duct. The resulting surface model provides the geometrical input to the subseque nt machining operation using either a CNC system or other manufacturing operatio n e.g. dies casting/mould casting etc. The prototypes developed were inspected u sing a state-of-the art CNC-CMM that was integrated to the CAD/CAM system. Si nce the scanning/digitised data captured by laser scanning probes requires no ma nual editing, significant time saving over most non-contact probe systems was a chieved. Since the creation of an accurate CAD model of a redesigned component o r a prototype constitute a major element of the total turnaround time; maximum r eturn can be achieved by increasing the efficiency of the redesigning process. T he paper also outlines with a case study the application of the developed system . The system developed offers the flexibility of using the concept of reverse en gineering of a variety of components with the complimentary facility of integrat ion between CAD/CAM Computer-aided Inspection (CAI) systems and a scanning syst em. The developed reverse engineering application in an integrated manufacturing system can increase the consistency, improve cost-efficiency, reduce produ ct turn around and skill levels required to redesign, reengineer and prototyping components and products.
文摘The definitions, methodology, applications, and perspectives of process system engineering are discussed from a strategic point of view. The focal points in future development of process systems engineering are to break through in methodology, to expand application fields, and to develop a new generation of process simulation systems.
文摘Space robots possess unique distinguishing features unlike general robots on earth, due to the particular environments in space. The developing of various practical space robots promoting the improvement of space science and technology is a complex man-machine-environment engineering problem. This paper analyses from the systems engineering viewpoint the space robot system in the scope of the architecture of robotics discipline, space environment characteristics, man-machine-environment system of space robots, the general methodology of project systems engineering and the process of space robot systems engineering.
文摘Control systems contribute to every aspect of modem society.In our life control systems exist in almost everywhere such as toasters,VCRs and smart phones.In science and technology,control systems already have widespread applications,for example,steering ships,guiding missiles and driving driverless cars in the near future.In all the control systems,systems are the key platform where control should be put into.It is at the system level that control shows its values.Extracting and formulating
基金Project(51978085)supported by the National Natural Science Foundation of ChinaProject(201808430102)supported by the China Scholarship Council+1 种基金Project(JTG-201507)supported by the Highway Industry Standard Compilation Project of Ministry of Transportation,ChinaProject(kfj180102)supported by the Open Fund of Changsha University of Science&Technology,China。
文摘The traditional stability analysis method of geogrid reinforced slopes does not consider the effect of lateral swelling,so it is not applicable to reinforced expansive soil slopes.This paper reports a new stability analysis method for geogrid reinforced expansive soil slopes.The additional pullout force of the free zone due to the lateral swelling and the anti-pullout safety factor of each geogrid layer were obtained by ensuring the overall stability of the reinforced slope.The optimum design was carried out to treat an expansive soil cut slope in Hubei Province,China,by changing the spacing and length of geogrid reinforcement.Calculation results show that the additional pullout force caused by lateral swelling has a great influence on the anti-pullout stability of geogrids,and the local stability of the reinforced slope will be overestimated if the swelling effect of soil in the free zone is not considered.
基金supported by the National Natural Science Foundation of China(61573017)the Doctoral Foundation of Air Force Engineering University(KGD08101604)
文摘Aiming at the intervention decision-making problem in manned/unmanned aerial vehicle（MAV/UAV） cooperative engagement, this paper carries out a research on allocation strategy of emergency discretion based on human factors engineering（HFE）.Firstly, based on the brief review of research status of HFE, it gives structural description to emergency in the process of cooperative engagement and analyzes intervention of commanders. After that,constraint conditions of intervention decision-making of commanders based on HFE（IDMCBHFE） are given, and the mathematical model, which takes the overall efficiency value of handling emergencies as the objective function, is established. Then, through combining K-best and variable neighborhood search（VNS） algorithm, a K-best optimization variable neighborhood search mixed algorithm（KBOVNSMA） is designed to solve the model. Finally,through three groups of simulation experiments, effectiveness and superiority of the proposed algorithm are verified.
文摘This paper presents a principle and a method of col or 3D laser scanning measurement. Based on the fundamental monochrome 3D measureme nt study, color information capture, color texture mapping, coordinate computati on and other techniques are performed to achieve color 3D measurement. The syste m is designed and composed of a line laser light emitter, one color CCD camera, a motor-driven rotary filter, a circuit card and a computer. Two steps in captu ring object’s images in the measurement process: First, the color CCD camera ta kes the color picture of the object to be used for texture mapping in post proce ssing. Secondly, the monochrome data of the object is taken. The laser light emi tter is started; the light plane and the surface of the object intersect to form an undulate line, which forms an image on the CCD sensor. After the optic- electronics transformation, the electronic signals are captured and send to the computer. A new color 3D measurement model was derived, and a rapid calibra ting method to measure the system parameters was proposed--optical plane equat ion calibrating method. A calibrating drone was designed and built. 3D color sca nning system not only provides an object’s individual point information in the 3D coordinate, in the mean time, it provides the color information of each indiv idual point. This paper also advances a multi-frame auto-merging method, i.e. several frames of color 3D digital images measured are merged quickly according to their curvature characteristics and RGB information. Initial matching and fin e tune of the registration are completely performed by the computer; initial mat ching is via user interface in helping computer to find the transformation matri x. The transformation matrix is found according to the geometric characteristics chosen by hand. After the initial transformation matrix is found, fine tune of the registration is preformed to do the optimum adjustment to achieve a complete color textured 3D model. The system can be broadly used in the fields of produc t design, mold manufacture, multimedia, game development, animation, medical eng ineering, antique digitization, etc.
文摘As it is commonly known,the estimation of physical and mechanical characteristics of rocks is very important issue in various geotechnical projects.The characteristics are mainly influenced by the microfabric-texture features of rocks.In this research,dry unit weight,effective porosity,point load index,Schmidt rebound hardness,uniaxial compressive strength,and texture coefficient were measured with the aim of correlating the physical and mechanical properties to the texture coefficient.For this purpose,a comprehensive laboratory testing program was conducted after collecting twenty sedimentary block samples including nine limestones and eleven mudstones,taken from Kalidromo(central Greece)in accordance with ASTM and ISRM standards.Also,mineralogical and petrographic properties,textural characteristics as well as X-ray diffractions were studied and the obtained results were statistically described and analysed.The maximum and minimum values of the texture coefficient were 0.13 and 0.50,respectively.The highest value was obtained for the rocks with a large amount of grains.Regression analyses were used to investigate the relationships between the texture coefficient and the engineering properties.Thus,empirical equations were developed and because of the good determination coefficients,they showed that all of the engineering properties were well correlated to the texture coefficient.
基金Project(Xiang Zu [2016] 91) supported by the “100 Talented Teams” of Hunan Province,ChinaProject(2018RS3077) supported by the Huxiang High-level Talents Program,China+2 种基金Project(22002009) supported by the National Natural Science Foundation of ChinaProject(2021JJ40565) supported by the Natural Science Foundation of Hunan Province,ChinaProject(19C0054) supported by the Scientific Research Foundation of Hunan Provincial Education Department,China。
文摘Vanadium redox flow batteries(VRFBs)are one of the most promising energy storage systems owing to their safety,efficiency,flexibility and scalability.However,the commercial viability of VRFBs is still hindered by the low electrochemical performance of the available carbon-based electrodes.Defect engineering is a powerful strategy to enhance the redox catalytic activity of carbon-based electrodes for VRFBs.In this paper,uniform carbon defects are introduced on the surfaces of carbon felt(CF)electrode by Ar plasma etching.Together with a higher specific surface area,the Ar plasma treated CF offers additional catalytic sites,allowing faster and more reversible oxidation/reduction reactions of vanadium ions.As a result,the VRFB using plasma treated electrode shows a power density of 1018.3 mW/cm^(2),an energy efficiency(EE)of 84.5%,and the EE remains stable over 1000 cycles.
文摘The bone is a naturally occurring composite system comprising collagen matrix and hydroxyapatites capable of generating sufficient strength and toughness to support mechanical loads and resist fracture,respectively.The material strength depends largely on the elastic properties,whereas the toughness depends on not only the elastic,but also the plastic properties.Thus,both elastic and plastic properties must be considered in the analysis of bone biomechanics and the design of osteogenic materials.The bone is capable of optimizing its elastic and plastic properties by integrating stiff hydroxyapatites and ductile collagen fibrils into a hierarchically ordered architecture,an effective mechanism to support the bone strength and toughness.Such a mechanism can be used as a model for designing osteogenic materials.
基金support from the National Natural Science Foundation of China(Grant No.22175160)the Science Challenge Project(Grant No.TZ2018004)。
文摘5-amino-4-nitrobenzo[1,2-c:3,4-c']bis([1,2,5]oxadiazole)1,6-dioxide(CL-18)exhibits significant potential as an initiating explosive.However,its current synthesis process remains non-scalable due to low yields and safety risks.In this study,we have developed a simple and safe synthetic route for CL-18.It was synthesized from 3,5-dihaloanisole in a four-step reaction with an overall yield exceeding 60%,surpassing all reported yields in the literature.Subsequently,recrystallization of CL-18 was successfully achieved by carefully selecting appropriate solvents and antisolvents to reduce its mechanical sensitivity.Ultimately,when DMF-ethanol was employed as the recrystallization solvent system,satisfactory product yield(>90%)and reduced mechanical sensitivity(IS=15 J;FS=216 N)were obtained.Additionally,CL-18 is derived from the rearrangement of oxygen atoms on i-CL-18 furoxan,and a comparative analysis of their physicochemical properties was conducted.The thermal stability of both compounds is similar,with onset decomposition temperatures recorded at 186 and 182℃respectively.Similarly,they exhibit 5 s breaking point temperatures of 236 and 237℃.Additionally,we present novel insights into the positional-isomerization-laser-ignition performance of CL-18 and its isomer i-CL-18 using laser irradiation for the first time.Remarkably,our findings demonstrate that i-CL-18 exhibits enhanced laser sensitivity,as it can be directly ignited by a 1064 nm wavelength laser,whereas CL-18 lacks this characteristic.
