Thermal quenching(TQ)at elevated temperature is a major factor affecting the luminescent intensity and efficiency of phosphors.Improving the thermal stability of phosphors and weakening the TQ effect are of significan...Thermal quenching(TQ)at elevated temperature is a major factor affecting the luminescent intensity and efficiency of phosphors.Improving the thermal stability of phosphors and weakening the TQ effect are of significance for the high-quality illumination of phosphor-converted WLEDs.Here,a novel red-emitting phosphor K_(2)Zn(PO_(3))_(4)∶Mn^(2+)is synthesized by standard high temperature solid state reaction in ambient atmosphere,which is a new member of self-reduction system.An effective synthesis strategy is proposed to optimize its photoluminescent performances.Combined with X-ray photoelectron spectroscopy and X-ray absorption fine structure spectroscopy,oxygen vacancy defects introduced by Mn doping are proved to play an important role in the transition of Mn^(4+)→Mn^(2+).Thermoluminescence analysis reveals that the distribution of trap levels,especially the deep ones,is effectively regulated by the controllable crystallization and significantly affect the thermal stability of phosphors.Then a defect-assisted model is proposed to address the inner mechanism of the phenomenon.The carriers trapped by deep trap levels can be released under the high-temperature stimulus,which return back to the luminescent centers and participate in the radiative recombination to improve thermal stability.This study provides a new crystallographic idea and theoretical support for obtaining luminescent materials with high thermal stability.展开更多
Alpha-aluminum hydride(α-AlH_(3))is usually metastable due to the small enthalpy of formation,poor stability,high chemical activity,sensitivity to moisture and easy combination with water in the air.In order to inhib...Alpha-aluminum hydride(α-AlH_(3))is usually metastable due to the small enthalpy of formation,poor stability,high chemical activity,sensitivity to moisture and easy combination with water in the air.In order to inhibit the hygroscopicity ofα-AlH_(3) and improve its storage and stability,paraffin wax(PW)is selected as the coating material,and the solvent/non-solvent method is usually used to coat the surface ofα-AlH_(3).The structure and topography ofα-AlH_(3) before and after being coated by PW were characterized by Fourier transform infrared spectroscopy(FT-IR),X-ray diffractometer(XRD),X-ray electron spectroscopy(XPS),elemental analysis,and scanning electron microscopy(SEM).The results show that PW can form a uniform and complete coating layer on the surface ofα-AlH_(3),and the crystal structure and morphology of theα-AlH_(3) coated by PW are not changed.The moisture absorption weight gain rate is reduced from 12%to 0.8%,and the hygroscopicity is greatly reduced.Furthermore,theα-AlH_(3) coated by PW also showed excellent performance in resisting water erosion after theα-AlH_(3) coated by PW,and the hydrophobic angle increases from 27°to 98°after theα-AlH_(3) surface being coated by PW.展开更多
To study the rolling motion of a ship in the presence of water on its deck,a linear-plus-quadratic damping term was incorporated into its equation of motion.Ship model tests indicates that the key dynamics of the phys...To study the rolling motion of a ship in the presence of water on its deck,a linear-plus-quadratic damping term was incorporated into its equation of motion.Ship model tests indicates that the key dynamics of the physical system are preserved in the ship rolling equation with the linear-plus-quadratic type damping term.To take into account the presence of randomness in the excitation and the response,a new method was developed and a Melnikov criterion was obtained to provide an upper bound on the domain of the potential chaotic rolling motion(erratic rocking).Additionally,the Melnikov criterion proposed in this study was verified by the utilization of phase plane diagrams and Poincare maps.Furthermore,this research has made the initial endeavor to systematically modify the system parameters in the rolling equation of motion for ship stability analysis.展开更多
Lithium-sulfur(Li-S)batteries have great promise for next-generation energy storage devices due to the high theoretical specific capacity(1675 mAh g^(-1))of sulfur with chemical conversion for charge storage.However,t...Lithium-sulfur(Li-S)batteries have great promise for next-generation energy storage devices due to the high theoretical specific capacity(1675 mAh g^(-1))of sulfur with chemical conversion for charge storage.However,their practical use is hindered by the slow redox kinetics of sulfur and the“shuttle effect”arising from dissolved lithium polysulfides(LiPSs).In recent years,various carbon-based materials have served as sulfur hosts and catalysts for accelerating sulfur conversion redox kinetics and alleviating LiPS shuttling.However,they often suffer from irreversible passivation and structural changes that destroy their long-term performance.We consider the main problems limiting their stability,including excessive LiPS adsorption,passivation by insulating Li2S,and surface reconstruction,and clarify how these factors lead to capacity fade.We then outline effective strategies for achieving long-term sulfur catalysis,focusing on functional carbon,such as designing suitable carbon-supported catalyst interfaces,creating well-distributed active sites,adding cocatalysts to improve electron transfer,and using carbon-based protective layers to suppress unwanted side reactions.Using this information should enable the development of stable,high-activity catalysts capable of long-term operation under practical conditions in Li-S batteries.展开更多
In this paper,a high-fidelity computational fluid dynamics(CFD)and rigid body dynamics(RBD)coupled platform for virtual flight simulation is developed to investigate the flight stability of fixed canard dual-spin proj...In this paper,a high-fidelity computational fluid dynamics(CFD)and rigid body dynamics(RBD)coupled platform for virtual flight simulation is developed to investigate the flight stability of fixed canard dual-spin projectile.The platform's reliability is validated by reproducing the characteristic resonance instability of such projectiles.By coupling the solution of the Unsteady Reynolds-Averaged Navier-Stokes equations and the seven-degree-of-freedom RBD equations,the virtual flight simulations of fixed canard dual-spin projectiles at various curvature trajectories are achieved,and the dynamic mechanism of the trajectory following process is analyzed.The instability mechanism of the dynamic instability during trajectory following process of the fixed canard dual-spin projectile is elucidated by simulating the rolling/coning coupled forced motion,and subsequently validated through virtual flight simulations.The findings suggest that an appropriate yaw moment can drive the projectile axis to precession in the tangential direction of the trajectory,thereby enhancing the trajectory following stability.However,the damping of the projectile attains its minimum value when the forward body equilibrium rotational speed(-128 rad/s)is equal to the negative of the fast mode frequency of the projectile.Insufficient damping leads to the fixed canard dual-spin projectile exiting the dynamic stability domain during the trajectory following,resulting in weakly damped instability.Keeping the forward body not rotating or increasing the spin rates to-192 rad/s can enhance the projectile's damping,thereby improving its dynamic stability.展开更多
Rich-nickel layered ternary NCM811 has been widely used in the field of electric vehicles ascribed to its high theoretical specific capacity.However,poor cycling stability and rate-performance hindered its further dev...Rich-nickel layered ternary NCM811 has been widely used in the field of electric vehicles ascribed to its high theoretical specific capacity.However,poor cycling stability and rate-performance hindered its further development.Herein,different amounts of nitrogen-doped carbon were wrapped on the surface of NCM811 via a facile rheological phase method by regulating the amount of dopamine hydrochloride.The effects of the coating amounts on the structure and electrochemical performance are investigated.The DFT calculation,XRD,SEM and XPS reveal that an appropriate amount of nitrogen-doped carbon coating could uniformly form a protective layer on the NCM811 surface and the introduced N could anchor Ni atoms to inhibit the Li^(+)/Ni^(2+)mixing,but excessive amount would reduce Ni^(3+)to Ni^(2+)so as to conversely aggravate Li^(+)/Ni^(2+)mixing.Among the samples,the NCM811-CN0.75 sample exhibits the most excellent electrochemical performance,delivering a high-rate capacity of 151.6 mA·h/g at 10C,and long-term cyclability with 82.2%capacity retention after 300 cycles at 5C,exhibiting remarkable rate-performance and cyclability.展开更多
The simultaneous integration of high energy density,low sensitivity,and thermal stability in energetic materials has constituted a century-long scientific challenge.Herein,we address this through a dualzwitterionic el...The simultaneous integration of high energy density,low sensitivity,and thermal stability in energetic materials has constituted a century-long scientific challenge.Herein,we address this through a dualzwitterionic electronic delocalization strategy,yielding TYX-3,the first bis-inner salt triazolo-tetrazine framework combining these mutually exclusive properties.Uniformπ-electron distribution and elevated bond dissociation energy confer exceptional thermal stability(T_(d)=365℃)with TATB-level insensitivity(impact sensitivity IS>40 J,friction sensitivity FS>360 N).Engineeredπ-stacked networks enable record density(1.99 g·cm^(-3))with detonation performance surpassing HMX benchmarks(detonation velocity 9315 m·s^(-1),detonation pressure 36.6 GPa).Practical implementation in Poly(3-nitratomethyl-3-methyloxetane)(PNMMFO)solid propellants demonstrates 5.4-fold safety enhancement over conventional HMX-based formulations while maintaining equivalent specific impulse.This work establishes a new design paradigm for energetic materials,overcoming the historical trade-offs between molecular stability and energy output through rational zwitterionic engineering.展开更多
To accurately identify the factors affecting the formation of stable aggregates in bauxite residue during the soil formation process,the comprehensive effects of a combined chemical-biological amelioration strategy in...To accurately identify the factors affecting the formation of stable aggregates in bauxite residue during the soil formation process,the comprehensive effects of a combined chemical-biological amelioration strategy including solid wastes and a functional microorganism on aggregate size distribution and its stability in bauxite residue were investigated during a 365-d simulation experiment.The results showed that the combined amelioration effectively reduced the saline alkalinity of bauxite residue,and markedly changed the contents of aggregate-associated chemical binding agents.Desulfurization gypsum and maize straw-Penicillium oxalicum(P.oxalicum)differentiated the formation of aggregates within different sizes.Maize straw-P.oxalicum stimulated the formation of water-stable macroaggregates with more durable erosion resistance by the wet-sieving and laser dynamic diffraction analysis.The Pearson correlation analysis showed that exchangeable polyvalent metal ions,pyrophosphate extractable Fe oxide,and organic carbon exhibited positive correlations with aggregate stability during the 365-d incubation.The findings in this study may provide data support and engineering practical reference for ecological restoration in the disposal areas.展开更多
In the practical slope engineering,the stability of lower sliding mass(region A)with back tensile cracks of the jointed rock slope attracts more attentions,but the upper rock mass(region B)may also be unstable.Therefo...In the practical slope engineering,the stability of lower sliding mass(region A)with back tensile cracks of the jointed rock slope attracts more attentions,but the upper rock mass(region B)may also be unstable.Therefore,in this study,based on the stepped failure mode of bedding jointed rock slopes,considering the influence of the upper rock mass on the lower stepped sliding mass,the improved failure model for analyzing the interaction force(F_(AB))between two regions is constructed,and the safety factors(F_(S))of two regions and whole region are derived.In addition,this paper proposes a method to determine the existence of F_(AB) using their respective acceleration values(a_(A) and a_(B))when regions A and B are unstable.The influences of key parameters on two regions and the whole region are analyzed.The results show that the variation of the F_(AB) and F_(S) of two regions can be obtained accurately based on the improved failure model.The accuracy of the improved failure model is verified by comparative analysis.The research results can explain the interaction mechanism of two regions and the natural phenomenon of slope failure caused by the development of cracks.展开更多
This study proposes an alternative calculation mode for stresses on the slip surface(SS).The calculation of the normal stress(NS)on the SS involves examining its composition and expanding its unknown using the Taylor ...This study proposes an alternative calculation mode for stresses on the slip surface(SS).The calculation of the normal stress(NS)on the SS involves examining its composition and expanding its unknown using the Taylor series.This expansion enables the reasonable construction of a function describing the NS on the SS.Additionally,by directly incorporating the nonlinear Generalized Hoke-Brown(GHB)strength criterion and utilizing the slope factor of safety(FOS)definition,a function of the shear stress on the SS is derived.This function considers the mutual feedback mechanism between the NS and strength parameters of the SS.The stress constraints conditions are then introduced at both ends of the SS based on the spatial stress relation of one point.Determining the slope FOS and stress solution for the SS involves considering the mechanical equilibrium conditions and the stress constraint conditions satisfied by the sliding body.The proposed approach successfully simulates the tension-shear stress zone near the slope top and provides an intuitive description of the concentration effect of compression-shear stress of the SS near the slope toe.Furthermore,compared to other methods,the present method demonstrates superior processing capabilities for the embedded nonlinear GHB strength criterion.展开更多
Objectives:To examine the effects of 16-week Tai Chi(TC) training on postural stability and associated physiological factors in older subjects,forty elderly individuals(aged ≥ 60 years) living in the community were r...Objectives:To examine the effects of 16-week Tai Chi(TC) training on postural stability and associated physiological factors in older subjects,forty elderly individuals(aged ≥ 60 years) living in the community were randomly placed into either the TC intervention group(n=22) or the control group(n=18).The former underwent a supervised TC exercise program for 16 weeks,while the latter received general education for a comparable time period.Measurements:Postural stability was assessed by timed stance tests in single-leg stance with the eyes open(SLO) or closed(SLC),and tandem stance with the eyes closed(TSC).Proprioceptive function was evaluated by measuring ankle and knee kinesthesia.The maximum concentric strength of the knee flexors and extensors,ankle plantarflexors and dorsiflexors was measured by isokinetic dynamometer.Moreover,the reaction time of different muscles in the lower extremity was also examined by measuring the onset latency of the muscles to perturbations on the ankle joint using an electromyography system.Results:After the 16-week TC intervention,significant TC training effects were gained on knee kinesthesia,knee flexor strength,latency of semitendinous muscle,and postural stability in SLO.For the other measures,no significant training effects were found.Conclusions:The 16-week TC intervention was found to be beneficial for the improvement of postural stability and associated physiological factors.However,there are discrepancies in TC training effects on different factors in the sensorimotor system.展开更多
In this paper we study the dynamic properties and stabilities of neural networks with delay-time (which includes the time-varying case) by differential inequalities and Lyapunov function approaches. The criteria of co...In this paper we study the dynamic properties and stabilities of neural networks with delay-time (which includes the time-varying case) by differential inequalities and Lyapunov function approaches. The criteria of connective stability, robust stability, Lyapunov stability, asymptotic atability, exponential stability and Lagrange stability of neural networks with delay-time are established, and the results obtained are very useful for the design, implementation and application of adaptive learning neural networks.展开更多
The stability of room mining coal pillars during their secondary mining for recovering coal was analyzed. An analysis was performed for the damage and instability mechanism of coal pillars recovered by the caving mini...The stability of room mining coal pillars during their secondary mining for recovering coal was analyzed. An analysis was performed for the damage and instability mechanism of coal pillars recovered by the caving mining method. During the damage progression of a single room coal pillar, the shape of the stress distribution in the pillar transformed from the initial stable saddle shape to the final arch-shaped distribution of critical instability. By combining the shapes of stress distribution in the coal pillars with the ultimate strength theory, the safe-stress value of coal pillar was obtained as 11.8 MPa. The mechanism of instability of coal pillar groups recovered by the caving mining method was explained by the domino effect. Since the room coal pillars mined and recovered by the traditional caving mining method were significantly influenced by the secondary mining during recovery, the coal pillars would go through a chain-type instability failure. Because of this limitation, the method of solid backfilling was proposed for mining and recovering room coal pillars, thus changing the transfer mechanism of stress caused by the secondary mining(recovery) of coal pillars. The mechanical model of the stope in the case of backfilling and recovering room coal pillars was built. The peak stress values inside coal pillars varied with the variance of backfilling ratio when the working face was advanced by 150 m. Furthermore, when the critical backfilling ratio was 80.6%, the instability failure of coal pillars would not occur during the solid backfill mining process. By taking Bandingliang Coal Mine as an example, the coal pillars' stability of stope under this backfilling ratio was studied, and a project scheme was designed.展开更多
Modified DB propellants, based on energetic nitramine(RDX) were manufactured by solventless extrusion process. Thermal stability and shelf life assessment of modified DB propellant were investigated. Shelf life assess...Modified DB propellants, based on energetic nitramine(RDX) were manufactured by solventless extrusion process. Thermal stability and shelf life assessment of modified DB propellant were investigated. Shelf life assessment was evaluated using Van’t Hoff’s formula and artificial aging at 70℃ up to120 days. Quantification of total heat released and heat flow with aging time was conducted using differential scanning calorimetry(DSC) and thermal activity monitoring(TAMIII) respectively. Modified DB formulation based on 20 wt % RDX demonstrated enhanced thermal stability in terms of controlled heat flow, and slow decomposition reactions at elevated temperature. This formulation demonstrated extended service life up to 56 years compared with reference formulation. These novel finding was ascribed to the high thermal stability of RDX and its compatibility with DB constituents. This manuscript shaded the light on novel and effective approach for thermal stability via monitoring thermal activity with aging.展开更多
Existing literature has shown that the control force at the nose could cause dynamic instability for controlled projectiles. To lower the adverse impact on the dual-spin projectile with fixed canards under the premise...Existing literature has shown that the control force at the nose could cause dynamic instability for controlled projectiles. To lower the adverse impact on the dual-spin projectile with fixed canards under the premise of meeting guidance system requirements, the influence of control moment provided by a motor on the flight stability is analyzed in this paper. Firstly, the effect of the rolling movement on stability is analyzed based on the stability criterion derived using the Hurwitz stability theory. Secondly, the evaluation parameters combining the features of different control periods that could assess the variation of stability features after the motor torque are obtained. These effective formulas are used to indicate that, to reduce the flight instability risks, the stabilized rolling speed of roll speed keeping period should be as small as possible; the variation trend of motor torque during the rolling speed controlling period and the roll angle of the forward body during roll angle switching period are recommended corresponding to the projectile and trajectory characteristics. Moreover,detailed numerical simulations of 155 mm dual-spin projectile are satisfactory agreement with the theoretical results.展开更多
Stability analysis and stabilization for discrete-time singular delay systems are addressed,respectively.Firstly,a sufficient condition for regularity,causality and stability for discrete-time singular delay systems i...Stability analysis and stabilization for discrete-time singular delay systems are addressed,respectively.Firstly,a sufficient condition for regularity,causality and stability for discrete-time singular delay systems is derived.Then,by applying the skill of matrix theory,the state feedback controller is designed to guarantee the closed-loop discrete-time singular delay systems to be regular,casual and stable.Finally,numerical examples are given to demonstrate the effectiveness of the proposed method.展开更多
The purpose of this work was to explore the influence law of vibration load on rock mass structure and slope stability.Based on the type and transmission way of vibration stress wave,the main stress in the horizontal ...The purpose of this work was to explore the influence law of vibration load on rock mass structure and slope stability.Based on the type and transmission way of vibration stress wave,the main stress in the horizontal and vertical directions was analyzed and the superposition effect of the stress wave was revealed.After the mechanical analysis of the sliding mass,the calculation formulas of the anti-sliding force and the sliding force were derived and the damage mechanism of blasting vibration to the structural plane was defined.In addition,according to the structure and lithologic parameter of the slope as well as the vibration monitoring data,the west slope stability of Xiaolongtan open pit mine was analyzed.The results show that the time-dependent stability factor is proportional to the vibration speed and the peak values appear at the same time.Vibration load promotes the breakage of the structural plane leading to the drop of the west slope stability factor by 0.23%.Under the multipoint simultaneous blasting,the fluctuating laws of the stability factors are consistent.The more the start-up points are,the higher the weakening degree to the slope stability is.Under the multipoint allochronic blasting,the stability factor depends on the synthetic waveform structure of all vibration waves.The greater the blasting time difference is,the lower the weakening degree to the slope stability is.Selecting the reasonable quantity of start-up points and time difference could fully reduce the adverse influence of vibration load to slope stability.展开更多
The stability and stabilization of a class of linear switched time-varying delay systems are investigated. A piecewise quadratic Lyapunov function （PWQLF） is constructed and is used to obtain the stability condition...The stability and stabilization of a class of linear switched time-varying delay systems are investigated. A piecewise quadratic Lyapunov function （PWQLF） is constructed and is used to obtain the stability conditions based on the linear matrix inequalities （LMIs）. The stabilizing controller for this class of system is then designed and the solution of the desired controller can be obtained by a cone complementary linearization algorithm. Numerical examples are provided to illustrate the less conservativeness of the new stability and the validity of the controller design procedures.展开更多
文摘Thermal quenching(TQ)at elevated temperature is a major factor affecting the luminescent intensity and efficiency of phosphors.Improving the thermal stability of phosphors and weakening the TQ effect are of significance for the high-quality illumination of phosphor-converted WLEDs.Here,a novel red-emitting phosphor K_(2)Zn(PO_(3))_(4)∶Mn^(2+)is synthesized by standard high temperature solid state reaction in ambient atmosphere,which is a new member of self-reduction system.An effective synthesis strategy is proposed to optimize its photoluminescent performances.Combined with X-ray photoelectron spectroscopy and X-ray absorption fine structure spectroscopy,oxygen vacancy defects introduced by Mn doping are proved to play an important role in the transition of Mn^(4+)→Mn^(2+).Thermoluminescence analysis reveals that the distribution of trap levels,especially the deep ones,is effectively regulated by the controllable crystallization and significantly affect the thermal stability of phosphors.Then a defect-assisted model is proposed to address the inner mechanism of the phenomenon.The carriers trapped by deep trap levels can be released under the high-temperature stimulus,which return back to the luminescent centers and participate in the radiative recombination to improve thermal stability.This study provides a new crystallographic idea and theoretical support for obtaining luminescent materials with high thermal stability.
文摘Alpha-aluminum hydride(α-AlH_(3))is usually metastable due to the small enthalpy of formation,poor stability,high chemical activity,sensitivity to moisture and easy combination with water in the air.In order to inhibit the hygroscopicity ofα-AlH_(3) and improve its storage and stability,paraffin wax(PW)is selected as the coating material,and the solvent/non-solvent method is usually used to coat the surface ofα-AlH_(3).The structure and topography ofα-AlH_(3) before and after being coated by PW were characterized by Fourier transform infrared spectroscopy(FT-IR),X-ray diffractometer(XRD),X-ray electron spectroscopy(XPS),elemental analysis,and scanning electron microscopy(SEM).The results show that PW can form a uniform and complete coating layer on the surface ofα-AlH_(3),and the crystal structure and morphology of theα-AlH_(3) coated by PW are not changed.The moisture absorption weight gain rate is reduced from 12%to 0.8%,and the hygroscopicity is greatly reduced.Furthermore,theα-AlH_(3) coated by PW also showed excellent performance in resisting water erosion after theα-AlH_(3) coated by PW,and the hydrophobic angle increases from 27°to 98°after theα-AlH_(3) surface being coated by PW.
文摘To study the rolling motion of a ship in the presence of water on its deck,a linear-plus-quadratic damping term was incorporated into its equation of motion.Ship model tests indicates that the key dynamics of the physical system are preserved in the ship rolling equation with the linear-plus-quadratic type damping term.To take into account the presence of randomness in the excitation and the response,a new method was developed and a Melnikov criterion was obtained to provide an upper bound on the domain of the potential chaotic rolling motion(erratic rocking).Additionally,the Melnikov criterion proposed in this study was verified by the utilization of phase plane diagrams and Poincare maps.Furthermore,this research has made the initial endeavor to systematically modify the system parameters in the rolling equation of motion for ship stability analysis.
文摘Lithium-sulfur(Li-S)batteries have great promise for next-generation energy storage devices due to the high theoretical specific capacity(1675 mAh g^(-1))of sulfur with chemical conversion for charge storage.However,their practical use is hindered by the slow redox kinetics of sulfur and the“shuttle effect”arising from dissolved lithium polysulfides(LiPSs).In recent years,various carbon-based materials have served as sulfur hosts and catalysts for accelerating sulfur conversion redox kinetics and alleviating LiPS shuttling.However,they often suffer from irreversible passivation and structural changes that destroy their long-term performance.We consider the main problems limiting their stability,including excessive LiPS adsorption,passivation by insulating Li2S,and surface reconstruction,and clarify how these factors lead to capacity fade.We then outline effective strategies for achieving long-term sulfur catalysis,focusing on functional carbon,such as designing suitable carbon-supported catalyst interfaces,creating well-distributed active sites,adding cocatalysts to improve electron transfer,and using carbon-based protective layers to suppress unwanted side reactions.Using this information should enable the development of stable,high-activity catalysts capable of long-term operation under practical conditions in Li-S batteries.
基金supported by the National Natural Science Foundation of China(Grant Nos.U2141254 and U23B6009)。
文摘In this paper,a high-fidelity computational fluid dynamics(CFD)and rigid body dynamics(RBD)coupled platform for virtual flight simulation is developed to investigate the flight stability of fixed canard dual-spin projectile.The platform's reliability is validated by reproducing the characteristic resonance instability of such projectiles.By coupling the solution of the Unsteady Reynolds-Averaged Navier-Stokes equations and the seven-degree-of-freedom RBD equations,the virtual flight simulations of fixed canard dual-spin projectiles at various curvature trajectories are achieved,and the dynamic mechanism of the trajectory following process is analyzed.The instability mechanism of the dynamic instability during trajectory following process of the fixed canard dual-spin projectile is elucidated by simulating the rolling/coning coupled forced motion,and subsequently validated through virtual flight simulations.The findings suggest that an appropriate yaw moment can drive the projectile axis to precession in the tangential direction of the trajectory,thereby enhancing the trajectory following stability.However,the damping of the projectile attains its minimum value when the forward body equilibrium rotational speed(-128 rad/s)is equal to the negative of the fast mode frequency of the projectile.Insufficient damping leads to the fixed canard dual-spin projectile exiting the dynamic stability domain during the trajectory following,resulting in weakly damped instability.Keeping the forward body not rotating or increasing the spin rates to-192 rad/s can enhance the projectile's damping,thereby improving its dynamic stability.
基金Project(2021H0028) supported by the Natural Scienceof Fujian Province,ChinaProject(JAT200455) supported by the Fujian Provincial Young and Middle-aged Teacher Education Project,ChinaProject(fma2023003) supported by the Open Fund of Fujian Provincial Key Laboratory of Functional Materials and Applications,China。
文摘Rich-nickel layered ternary NCM811 has been widely used in the field of electric vehicles ascribed to its high theoretical specific capacity.However,poor cycling stability and rate-performance hindered its further development.Herein,different amounts of nitrogen-doped carbon were wrapped on the surface of NCM811 via a facile rheological phase method by regulating the amount of dopamine hydrochloride.The effects of the coating amounts on the structure and electrochemical performance are investigated.The DFT calculation,XRD,SEM and XPS reveal that an appropriate amount of nitrogen-doped carbon coating could uniformly form a protective layer on the NCM811 surface and the introduced N could anchor Ni atoms to inhibit the Li^(+)/Ni^(2+)mixing,but excessive amount would reduce Ni^(3+)to Ni^(2+)so as to conversely aggravate Li^(+)/Ni^(2+)mixing.Among the samples,the NCM811-CN0.75 sample exhibits the most excellent electrochemical performance,delivering a high-rate capacity of 151.6 mA·h/g at 10C,and long-term cyclability with 82.2%capacity retention after 300 cycles at 5C,exhibiting remarkable rate-performance and cyclability.
基金supported by the National Natural Science Foundation of China(Grant Nos.22105156,22175139,22171136,and 22302156)the China National Science Fund for Distinguished Young Scholars(Grant No.22325504)。
文摘The simultaneous integration of high energy density,low sensitivity,and thermal stability in energetic materials has constituted a century-long scientific challenge.Herein,we address this through a dualzwitterionic electronic delocalization strategy,yielding TYX-3,the first bis-inner salt triazolo-tetrazine framework combining these mutually exclusive properties.Uniformπ-electron distribution and elevated bond dissociation energy confer exceptional thermal stability(T_(d)=365℃)with TATB-level insensitivity(impact sensitivity IS>40 J,friction sensitivity FS>360 N).Engineeredπ-stacked networks enable record density(1.99 g·cm^(-3))with detonation performance surpassing HMX benchmarks(detonation velocity 9315 m·s^(-1),detonation pressure 36.6 GPa).Practical implementation in Poly(3-nitratomethyl-3-methyloxetane)(PNMMFO)solid propellants demonstrates 5.4-fold safety enhancement over conventional HMX-based formulations while maintaining equivalent specific impulse.This work establishes a new design paradigm for energetic materials,overcoming the historical trade-offs between molecular stability and energy output through rational zwitterionic engineering.
基金Projects(42177391,42477437)supported by the National Natural Science Foundation of ChinaProject(2024RC3041)supported by the Science and Technology Innovation Program of Hunan Province,China+1 种基金Project(2023CXQD064)supported by the Innovation-Driven Research Programme of Central South University,ChinaProject(242102321124)supported by the Henan Provincal Science and Technology Research Project,China。
文摘To accurately identify the factors affecting the formation of stable aggregates in bauxite residue during the soil formation process,the comprehensive effects of a combined chemical-biological amelioration strategy including solid wastes and a functional microorganism on aggregate size distribution and its stability in bauxite residue were investigated during a 365-d simulation experiment.The results showed that the combined amelioration effectively reduced the saline alkalinity of bauxite residue,and markedly changed the contents of aggregate-associated chemical binding agents.Desulfurization gypsum and maize straw-Penicillium oxalicum(P.oxalicum)differentiated the formation of aggregates within different sizes.Maize straw-P.oxalicum stimulated the formation of water-stable macroaggregates with more durable erosion resistance by the wet-sieving and laser dynamic diffraction analysis.The Pearson correlation analysis showed that exchangeable polyvalent metal ions,pyrophosphate extractable Fe oxide,and organic carbon exhibited positive correlations with aggregate stability during the 365-d incubation.The findings in this study may provide data support and engineering practical reference for ecological restoration in the disposal areas.
基金Projects(52208369,52309138,52108320)supported by the National Natural Science Foundation of ChinaProjects(2023NSFSC0284,2025ZNSFSC0409)supported by the Sichuan Science and Technology Program,ChinaProject(U22468214)supported by the Joint Fund Project for Railway Basic Research by the National Natural Science Foundation of China and China State Railway Group Co.,Ltd.
文摘In the practical slope engineering,the stability of lower sliding mass(region A)with back tensile cracks of the jointed rock slope attracts more attentions,but the upper rock mass(region B)may also be unstable.Therefore,in this study,based on the stepped failure mode of bedding jointed rock slopes,considering the influence of the upper rock mass on the lower stepped sliding mass,the improved failure model for analyzing the interaction force(F_(AB))between two regions is constructed,and the safety factors(F_(S))of two regions and whole region are derived.In addition,this paper proposes a method to determine the existence of F_(AB) using their respective acceleration values(a_(A) and a_(B))when regions A and B are unstable.The influences of key parameters on two regions and the whole region are analyzed.The results show that the variation of the F_(AB) and F_(S) of two regions can be obtained accurately based on the improved failure model.The accuracy of the improved failure model is verified by comparative analysis.The research results can explain the interaction mechanism of two regions and the natural phenomenon of slope failure caused by the development of cracks.
基金Project(52278380)supported by the National Natural Science Foundation of ChinaProject(2023JJ30670)supported by the National Science Foundation of and Technology Major Project of Hunan Province,China。
文摘This study proposes an alternative calculation mode for stresses on the slip surface(SS).The calculation of the normal stress(NS)on the SS involves examining its composition and expanding its unknown using the Taylor series.This expansion enables the reasonable construction of a function describing the NS on the SS.Additionally,by directly incorporating the nonlinear Generalized Hoke-Brown(GHB)strength criterion and utilizing the slope factor of safety(FOS)definition,a function of the shear stress on the SS is derived.This function considers the mutual feedback mechanism between the NS and strength parameters of the SS.The stress constraints conditions are then introduced at both ends of the SS based on the spatial stress relation of one point.Determining the slope FOS and stress solution for the SS involves considering the mechanical equilibrium conditions and the stress constraint conditions satisfied by the sliding body.The proposed approach successfully simulates the tension-shear stress zone near the slope top and provides an intuitive description of the concentration effect of compression-shear stress of the SS near the slope toe.Furthermore,compared to other methods,the present method demonstrates superior processing capabilities for the embedded nonlinear GHB strength criterion.
文摘Objectives:To examine the effects of 16-week Tai Chi(TC) training on postural stability and associated physiological factors in older subjects,forty elderly individuals(aged ≥ 60 years) living in the community were randomly placed into either the TC intervention group(n=22) or the control group(n=18).The former underwent a supervised TC exercise program for 16 weeks,while the latter received general education for a comparable time period.Measurements:Postural stability was assessed by timed stance tests in single-leg stance with the eyes open(SLO) or closed(SLC),and tandem stance with the eyes closed(TSC).Proprioceptive function was evaluated by measuring ankle and knee kinesthesia.The maximum concentric strength of the knee flexors and extensors,ankle plantarflexors and dorsiflexors was measured by isokinetic dynamometer.Moreover,the reaction time of different muscles in the lower extremity was also examined by measuring the onset latency of the muscles to perturbations on the ankle joint using an electromyography system.Results:After the 16-week TC intervention,significant TC training effects were gained on knee kinesthesia,knee flexor strength,latency of semitendinous muscle,and postural stability in SLO.For the other measures,no significant training effects were found.Conclusions:The 16-week TC intervention was found to be beneficial for the improvement of postural stability and associated physiological factors.However,there are discrepancies in TC training effects on different factors in the sensorimotor system.
文摘In this paper we study the dynamic properties and stabilities of neural networks with delay-time (which includes the time-varying case) by differential inequalities and Lyapunov function approaches. The criteria of connective stability, robust stability, Lyapunov stability, asymptotic atability, exponential stability and Lagrange stability of neural networks with delay-time are established, and the results obtained are very useful for the design, implementation and application of adaptive learning neural networks.
基金Project(2014ZDPY02)supported by the Fundamental Research Funds for the Central Universities
文摘The stability of room mining coal pillars during their secondary mining for recovering coal was analyzed. An analysis was performed for the damage and instability mechanism of coal pillars recovered by the caving mining method. During the damage progression of a single room coal pillar, the shape of the stress distribution in the pillar transformed from the initial stable saddle shape to the final arch-shaped distribution of critical instability. By combining the shapes of stress distribution in the coal pillars with the ultimate strength theory, the safe-stress value of coal pillar was obtained as 11.8 MPa. The mechanism of instability of coal pillar groups recovered by the caving mining method was explained by the domino effect. Since the room coal pillars mined and recovered by the traditional caving mining method were significantly influenced by the secondary mining during recovery, the coal pillars would go through a chain-type instability failure. Because of this limitation, the method of solid backfilling was proposed for mining and recovering room coal pillars, thus changing the transfer mechanism of stress caused by the secondary mining(recovery) of coal pillars. The mechanical model of the stope in the case of backfilling and recovering room coal pillars was built. The peak stress values inside coal pillars varied with the variance of backfilling ratio when the working face was advanced by 150 m. Furthermore, when the critical backfilling ratio was 80.6%, the instability failure of coal pillars would not occur during the solid backfill mining process. By taking Bandingliang Coal Mine as an example, the coal pillars' stability of stope under this backfilling ratio was studied, and a project scheme was designed.
文摘Modified DB propellants, based on energetic nitramine(RDX) were manufactured by solventless extrusion process. Thermal stability and shelf life assessment of modified DB propellant were investigated. Shelf life assessment was evaluated using Van’t Hoff’s formula and artificial aging at 70℃ up to120 days. Quantification of total heat released and heat flow with aging time was conducted using differential scanning calorimetry(DSC) and thermal activity monitoring(TAMIII) respectively. Modified DB formulation based on 20 wt % RDX demonstrated enhanced thermal stability in terms of controlled heat flow, and slow decomposition reactions at elevated temperature. This formulation demonstrated extended service life up to 56 years compared with reference formulation. These novel finding was ascribed to the high thermal stability of RDX and its compatibility with DB constituents. This manuscript shaded the light on novel and effective approach for thermal stability via monitoring thermal activity with aging.
文摘Existing literature has shown that the control force at the nose could cause dynamic instability for controlled projectiles. To lower the adverse impact on the dual-spin projectile with fixed canards under the premise of meeting guidance system requirements, the influence of control moment provided by a motor on the flight stability is analyzed in this paper. Firstly, the effect of the rolling movement on stability is analyzed based on the stability criterion derived using the Hurwitz stability theory. Secondly, the evaluation parameters combining the features of different control periods that could assess the variation of stability features after the motor torque are obtained. These effective formulas are used to indicate that, to reduce the flight instability risks, the stabilized rolling speed of roll speed keeping period should be as small as possible; the variation trend of motor torque during the rolling speed controlling period and the roll angle of the forward body during roll angle switching period are recommended corresponding to the projectile and trajectory characteristics. Moreover,detailed numerical simulations of 155 mm dual-spin projectile are satisfactory agreement with the theoretical results.
基金supported by the National Natural Science Foundation of China (6090400960974004)
文摘Stability analysis and stabilization for discrete-time singular delay systems are addressed,respectively.Firstly,a sufficient condition for regularity,causality and stability for discrete-time singular delay systems is derived.Then,by applying the skill of matrix theory,the state feedback controller is designed to guarantee the closed-loop discrete-time singular delay systems to be regular,casual and stable.Finally,numerical examples are given to demonstrate the effectiveness of the proposed method.
基金Project(2015M580491)supported by the China Postdoctoral Science FoundationProject(51404262)supported by the National Natural Science Foundation of China+1 种基金Project(2014XT01)supported by the Research Funds for the Central Universities,ChinaProject supported by the Priority Academic Program Development of Jiangsu Higher Education Institutions,China
文摘The purpose of this work was to explore the influence law of vibration load on rock mass structure and slope stability.Based on the type and transmission way of vibration stress wave,the main stress in the horizontal and vertical directions was analyzed and the superposition effect of the stress wave was revealed.After the mechanical analysis of the sliding mass,the calculation formulas of the anti-sliding force and the sliding force were derived and the damage mechanism of blasting vibration to the structural plane was defined.In addition,according to the structure and lithologic parameter of the slope as well as the vibration monitoring data,the west slope stability of Xiaolongtan open pit mine was analyzed.The results show that the time-dependent stability factor is proportional to the vibration speed and the peak values appear at the same time.Vibration load promotes the breakage of the structural plane leading to the drop of the west slope stability factor by 0.23%.Under the multipoint simultaneous blasting,the fluctuating laws of the stability factors are consistent.The more the start-up points are,the higher the weakening degree to the slope stability is.Under the multipoint allochronic blasting,the stability factor depends on the synthetic waveform structure of all vibration waves.The greater the blasting time difference is,the lower the weakening degree to the slope stability is.Selecting the reasonable quantity of start-up points and time difference could fully reduce the adverse influence of vibration load to slope stability.
基金the National Natural Science Foundation of China (69874008).
文摘The stability and stabilization of a class of linear switched time-varying delay systems are investigated. A piecewise quadratic Lyapunov function （PWQLF） is constructed and is used to obtain the stability conditions based on the linear matrix inequalities （LMIs）. The stabilizing controller for this class of system is then designed and the solution of the desired controller can be obtained by a cone complementary linearization algorithm. Numerical examples are provided to illustrate the less conservativeness of the new stability and the validity of the controller design procedures.
