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Dynamic optimal allocation of energy storage systems integrated within photovoltaic based on a dual timescale dynamics model
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作者 Kecun Li Zhenyu Huang +2 位作者 Youbo Liu Yaser Qudaih Junyong Liu 《Global Energy Interconnection》 EI CSCD 2024年第4期415-428,共14页
Energy storage systems(ESSs)operate as independent market participants and collaborate with photovoltaic(PV)generation units to enhance the flexible power supply capabilities of PV units.However,the dynamic variations... Energy storage systems(ESSs)operate as independent market participants and collaborate with photovoltaic(PV)generation units to enhance the flexible power supply capabilities of PV units.However,the dynamic variations in the profitability of ESSs in the electricity market are yet to be fully understood.This study introduces a dual-timescale dynamics model that integrates a spot market clearing(SMC)model into a system dynamics(SD)model to investigate the profit-aware capacity growth of ESSs and compares the profitability of independent energy storage systems(IESSs)with that of an ESS integrated within a PV(PV-ESS).Furthermore,this study aims to ascertain the optimal allocation of the PV-ESS.First,SD and SMC models were set up.Second,the SMC model simulated on an hourly timescale was incorporated into the SD model as a subsystem,a dual-timescale model was constructed.Finally,a development simulation and profitability analysis was conducted from 2022 to 2040 to reveal the dynamic optimal range of PV-ESS allocation.Additionally,negative electricity prices were considered during clearing processes.The simulation results revealed differences in profitability and capacity growth between IESS and PV-ESS,helping grid investors and policymakers to determine the boundaries of ESSs and dynamic optimal allocation of PV-ESSs. 展开更多
关键词 Optimal allocation Profitability analysis PHOTOVOLTAIC Energy storage system dual timescale dynamics model Spot market clearing
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An approach to estimate tree height using PolInSAR data constructed by the Sentinel-1 dual-pol SAR data and RVoG model
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作者 Yin Zhang Ding-Feng Duan 《Journal of Electronic Science and Technology》 EI CAS CSCD 2024年第3期69-79,共11页
We estimate tree heights using polarimetric interferometric synthetic aperture radar(PolInSAR)data constructed by the dual-polarization(dual-pol)SAR data and random volume over the ground(RVoG)model.Considering the Se... We estimate tree heights using polarimetric interferometric synthetic aperture radar(PolInSAR)data constructed by the dual-polarization(dual-pol)SAR data and random volume over the ground(RVoG)model.Considering the Sentinel-1 SAR dual-pol(SVV,vertically transmitted and vertically received and SVH,vertically transmitted and horizontally received)configuration,one notes that S_(HH),the horizontally transmitted and horizontally received scattering element,is unavailable.The S_(HH)data were constructed using the SVH data,and polarimetric SAR(PolSAR)data were obtained.The proposed approach was first verified in simulation with satisfactory results.It was next applied to construct PolInSAR data by a pair of dual-pol Sentinel-1A data at Duke Forest,North Carolina,USA.According to local observations and forest descriptions,the range of estimated tree heights was overall reasonable.Comparing the heights with the ICESat-2 tree heights at 23 sampling locations,relative errors of 5 points were within±30%.Errors of 8 points ranged from 30%to 40%,but errors of the remaining 10 points were>40%.The results should be encouraged as error reduction is possible.For instance,the construction of PolSAR data should not be limited to using SVH,and a combination of SVH and SVV should be explored.Also,an ensemble of tree heights derived from multiple PolInSAR data can be considered since tree heights do not vary much with time frame in months or one season. 展开更多
关键词 Constructed polarimetric SAR data dual polarization Sentinel-1 SAR data Polarimetric interferometric SAR Random volume over the ground model Tree height estimation
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A data and physical model dual-driven based trajectory estimator for long-term navigation
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作者 Tao Feng Yu Liu +2 位作者 Yue Yu Liang Chen Ruizhi Chen 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第10期78-90,共13页
Long-term navigation ability based on consumer-level wearable inertial sensors plays an essential role towards various emerging fields, for instance, smart healthcare, emergency rescue, soldier positioning et al. The ... Long-term navigation ability based on consumer-level wearable inertial sensors plays an essential role towards various emerging fields, for instance, smart healthcare, emergency rescue, soldier positioning et al. The performance of existing long-term navigation algorithm is limited by the cumulative error of inertial sensors, disturbed local magnetic field, and complex motion modes of the pedestrian. This paper develops a robust data and physical model dual-driven based trajectory estimation(DPDD-TE) framework, which can be applied for long-term navigation tasks. A Bi-directional Long Short-Term Memory(Bi-LSTM) based quasi-static magnetic field(QSMF) detection algorithm is developed for extracting useful magnetic observation for heading calibration, and another Bi-LSTM is adopted for walking speed estimation by considering hybrid human motion information under a specific time period. In addition, a data and physical model dual-driven based multi-source fusion model is proposed to integrate basic INS mechanization and multi-level constraint and observations for maintaining accuracy under long-term navigation tasks, and enhanced by the magnetic and trajectory features assisted loop detection algorithm. Real-world experiments indicate that the proposed DPDD-TE outperforms than existing algorithms, and final estimated heading and positioning accuracy indexes reaches 5° and less than 2 m under the time period of 30 min, respectively. 展开更多
关键词 Long-term navigation Wearable inertial sensors Bi-LSTM QSMF Data and physical model dual-driven
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Electrode/Electrolyte Optimization‑Induced Double‑Layered Architecture for High‑Performance Aqueous Zinc‑(Dual)Halogen Batteries
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作者 Chengwang Zhou Zhezheng Ding +7 位作者 Shengzhe Ying Hao Jiang Yan Wang Timing Fang You Zhang Bing Sun Xiao Tang Xiaomin Liu 《Nano-Micro Letters》 SCIE EI CAS 2025年第3期121-137,共17页
Aqueous zinc-halogen batteries are promising candidates for large-scale energy storage due to their abundant resources,intrinsic safety,and high theoretical capacity.Nevertheless,the uncontrollable zinc dendrite growt... Aqueous zinc-halogen batteries are promising candidates for large-scale energy storage due to their abundant resources,intrinsic safety,and high theoretical capacity.Nevertheless,the uncontrollable zinc dendrite growth and spontaneous shuttle effect of active species have prohibited their practical implementation.Herein,a double-layered protective film based on zinc-ethylenediamine tetramethylene phosphonic acid(ZEA)artificial film and ZnF2-rich solid electrolyte interphase(SEI)layer has been successfully fabricated on the zinc metal anode via electrode/electrolyte synergistic optimization.The ZEA-based artificial film shows strong affinity for the ZnF2-rich SEI layer,therefore effectively suppressing the SEI breakage and facilitating the construction of double-layered protective film on the zinc metal anode.Such double-layered architecture not only modulates Zn2+flux and suppresses the zinc dendrite growth,but also blocks the direct contact between the metal anode and electrolyte,thus mitigating the corrosion from the active species.When employing optimized metal anodes and electrolytes,the as-developed zinc-(dual)halogen batteries present high areal capacity and satisfactory cycling stability.This work provides a new avenue for developing aqueous zinc-(dual)halogen batteries. 展开更多
关键词 Zn metal anodes Double-layered protective film Electrode/electrolyte optimization Aqueous zinc-(dual)halogen batteries
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Dynamics of a Stochastic Epidemic Model with Age-group
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作者 LAN Xiaomin CHEN Guangmin +5 位作者 ZHOU Ruiyang ZHENG Kuicheng CAI Shaojian WEI Fengying JIN Zhen MAO Xuerong 《应用数学》 北大核心 2025年第1期294-307,共14页
A stochastic epidemic model with two age groups is established in this study,in which the susceptible(S),the exposed(E),the infected(I),the hospitalized(H)and the recovered(R)are involved within the total population,t... A stochastic epidemic model with two age groups is established in this study,in which the susceptible(S),the exposed(E),the infected(I),the hospitalized(H)and the recovered(R)are involved within the total population,the aging rates between two age groups are set to be constant.The existence-and-uniqueness of global positive solution is firstly showed.Then,by constructing several appropriate Lyapunov functions and using the high-dimensional Itô’s formula,the sufficient conditions for the stochastic extinction and stochastic persistence of the exposed individuals and the infected individuals are obtained.The stochastic extinction indicator and the stochastic persistence indicator are less-valued expressions compared with the basic reproduction number.Meanwhile,the main results of this study are modified into multi-age groups.Furthermore,by using the surveillance data for Fujian Provincial Center for Disease Control and Prevention,Fuzhou COVID-19 epidemic is chosen to carry out the numerical simulations,which show that the age group of the population plays the vital role when studying infectious diseases. 展开更多
关键词 Epidemic model Age groups PERSISTENCE EXTINCTION
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Tuning the interfacial reaction environment via pH-dependent and induced ions to understand C–N bonds coupling performance in NO_(3)-integrated CO_(2)reduction to carbon and nitrogen compounds over dual Cu-based N-doped carbon catalyst
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作者 Tianhang Zhou Chen Shen +2 位作者 Zhenghao Wu Xingying Lan Yi Xiao 《Journal of Energy Chemistry》 2025年第1期273-285,共13页
Dual atomic catalysts(DAC),particularly copper(Cu_(2))-based nitrogen(N)doped graphene,show great potential to effectively convert CO_(2)and nitrate(NO_(3)-)into important industrial chemicals such as ethylene,glycol,... Dual atomic catalysts(DAC),particularly copper(Cu_(2))-based nitrogen(N)doped graphene,show great potential to effectively convert CO_(2)and nitrate(NO_(3)-)into important industrial chemicals such as ethylene,glycol,acetamide,and urea through an efficient catalytical process that involves C–C and C–N coupling.However,the origin of the coupling activity remained unclear,which substantially hinders the rational design of Cu-based catalysts for the N-integrated CO_(2)reduction reaction(CO_(2)RR).To address this challenge,this work performed advanced density functional theory calculations incorporating explicit solvation based on a Cu_(2)-based N-doped carbon(Cu_(2)N_(6)C_(10))catalyst for CO_(2)RR.These calculations are aimed to gain insight into the reaction mechanisms for the synthesis of ethylene,acetamide,and urea via coupling in the interfacial reaction micro-environment.Due to the sluggishness of CO_(2),the formation of a solvation electric layer by anions(F^(-),Cl^(-),Br^(-),and I^(-))and cations(Na+,Mg^(2+),K+,and Ca^(2+))leads to electron transfer towards the Cu surface.This process significantly accelerates the reduction of CO_(2).These results reveal that*CO intermediates play a pivotal role in N-integrated CO_(2)RR.Remarkably,the Cu_(2)-based N-doped carbon catalyst examined in this study has demonstrated the most potential for C–N coupling to date.Our findings reveal that through the process of a condensation reaction between*CO and NH_(2)OH for urea synthesis,*NO_(3)-is reduced to*NH_(3),and*CO_(2)to*CCO at dual Cu atom sites.This dual-site reduction facilitates the synthesis of acetamide through a nucleophilic reaction between NH_(3)and the ketene intermediate.Furthermore,we found that the I-and Mg^(2+)ions,influenced by pH,were highly effective for acetamide and ammonia synthesis,except when F-and Ca^(2+)were present.Furthermore,the mechanisms of C–N bond formation were investigated via ab-initio molecular dynamics simulations,and we found that adjusting the micro-environment can change the dominant side reaction,shifting from hydrogen production in acidic conditions to water reduction in alkaline ones.This study introduces a novel approach using ion-H_(2)O cages to significantly enhance the efficiency of C–N coupling reactions. 展开更多
关键词 pH-dependent micro-environments C-N coupling N-integrated CO_(2)RR dual Cu-based nitrogen carbon catalysts Explicit solvation model lon stabilizer AIMD
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High-throughput screening of CO_(2) cycloaddition MOF catalyst with an explainable machine learning model
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作者 Xuefeng Bai Yi Li +3 位作者 Yabo Xie Qiancheng Chen Xin Zhang Jian-Rong Li 《Green Energy & Environment》 SCIE EI CAS 2025年第1期132-138,共7页
The high porosity and tunable chemical functionality of metal-organic frameworks(MOFs)make it a promising catalyst design platform.High-throughput screening of catalytic performance is feasible since the large MOF str... The high porosity and tunable chemical functionality of metal-organic frameworks(MOFs)make it a promising catalyst design platform.High-throughput screening of catalytic performance is feasible since the large MOF structure database is available.In this study,we report a machine learning model for high-throughput screening of MOF catalysts for the CO_(2) cycloaddition reaction.The descriptors for model training were judiciously chosen according to the reaction mechanism,which leads to high accuracy up to 97%for the 75%quantile of the training set as the classification criterion.The feature contribution was further evaluated with SHAP and PDP analysis to provide a certain physical understanding.12,415 hypothetical MOF structures and 100 reported MOFs were evaluated under 100℃ and 1 bar within one day using the model,and 239 potentially efficient catalysts were discovered.Among them,MOF-76(Y)achieved the top performance experimentally among reported MOFs,in good agreement with the prediction. 展开更多
关键词 Metal-organic frameworks High-throughput screening Machine learning Explainable model CO_(2)cycloaddition
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Physical Modeling of Reconfigurable Intelligent Surface for Channel Modeling
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作者 MiaoWei Dou Jianwu +1 位作者 Cui Yijun Yang Zhenyu 《China Communications》 2025年第2期128-142,共15页
In this paper,a physical model of RIS of bistatic polarized radar cross section is derived starting from the Stratton-Chu equations under the assumptions of physical optics,PEC,far field and rectangular RIS element.In... In this paper,a physical model of RIS of bistatic polarized radar cross section is derived starting from the Stratton-Chu equations under the assumptions of physical optics,PEC,far field and rectangular RIS element.In the context of important physical characteristics of the backscattering polarization of RIS,the modeling of the RIS wireless channel requires a tradeoff between complexity and accuracy,as well as usability and simplicity.For channel modeling of RIS systems,RIS is modelled as multi-equivalent virtual base stations(BSs)induced by multi polarized electromagnetic waves from different incident directions.The comparison between test and simulation results demonstrates that the proposed algorithm effectively captures the key characteristics of the general RIS element polarization physical model and provides accurate results. 展开更多
关键词 channel modeling map-based hybrid channel model polarized model Reconfigurable intelligent surface(RIS)
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Taming of trinitromethyl-oxadiazole to access high density and high oxygen balance via a dual modulation strategy
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作者 Jinya Zhang Teng Fei +4 位作者 Jingwei Meng Jinxiong Cai Lei Zhang Siping Pang Chunlin He 《Defence Technology(防务技术)》 2025年第1期142-149,共8页
Energetic compounds bearing the trinitromethyl group are garnering broad attraction as potential candidates for a new generation of high energy dense oxidizers.In this work,an effective dual modulation strategy involv... Energetic compounds bearing the trinitromethyl group are garnering broad attraction as potential candidates for a new generation of high energy dense oxidizers.In this work,an effective dual modulation strategy involving both molecular isomerization and crystal morphology control was employed to design and optimize trinitromethyl-oxadiazole with improved comprehensive performance.Utilizing this dual strategy,3,5-bis(trinitromethyl)-1,2,4-oxadiazole(3)was synthesized,resulting in the formation of two distinct crystal morphologies(needle and sheet)corresponding to two crystal forms(3-a and3-b).Encouragingly,while maintaining ultra-high oxygen balance(21.73%),3 achieves impressive densities(1.97-1.98 g/cm^(3)).To our knowledge,the density of 1.98 g/cm^(3)for 3-a sets a new record among that of nitrogen-rich monocyclic compounds.Notably,practical crystal morphology prediction was creatively introduced to guide the experimental crystallization conditions of 3,increasing the impact sensitivity and friction sensitivity from 1 J to 80 N(3-a)to 10 J and 240 N(3-b),respectively.Additionally,the crystal structural analyses and theoretical calculations were conducted to elucidate the reasons of differences between 3-a and 3-b in density and stability.This work provides an efficient strategy to enhance performance of trinitromethyl derivatives,broadening the path and expanding the toolbox for energetic materials. 展开更多
关键词 Energetic materials High oxygen balance High density dual modulation Trinitromethyl group
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Ammonia pyrolysis oxidation excited by nanosecond pulsed discharge:Global/fluid models hybrid solution
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作者 Mingming Zhang Hanyu Wu +2 位作者 Qi Chen Jiaxin Yang Bonan Liu 《Journal of Energy Chemistry》 2025年第1期385-396,共12页
The kinetic characteristics of plasma-assisted oxidative pyrolysis of ammonia are studied by using the global/fluid models hybrid solution method.Firstly,the stable products of plasma-assisted oxidative pyrolysis of a... The kinetic characteristics of plasma-assisted oxidative pyrolysis of ammonia are studied by using the global/fluid models hybrid solution method.Firstly,the stable products of plasma-assisted oxidative pyrolysis of ammonia are measured.The results show that the consumption of NH_(3)/O_(2)and the production of N_(2)/H_(2)change linearly with the increase of voltage,which indicates the decoupling of nonequilibrium molecular excitation and oxidative pyrolysis of ammonia at low temperatures.Secondly,the detailed reaction kinetics mechanism of ammonia oxidative pyrolysis stimulated by a nanosecond pulse voltage at low pressure and room temperature is established.Based on the reaction path analysis,the simplified mechanism is obtained.The detailed and simplified mechanism simulation results are compared with experimental data to verify the accuracy of the simplified mechanism.Finally,based on the simplified mechanism,the fluid model of ammonia oxidative pyrolysis stimulated by the nanosecond pulse plasma is established to study the pre-sheath/sheath behavior and the resultant consumption and formation of key species.The results show that the generation,development,and propagation of the pre-sheath have a great influence on the formation and consumption of species.The consumption of NH_(3)by the cathode pre-sheath is greater than that by the anode pre-sheath,but the opposite is true for OH and O(1S).However,within the sheath,almost all reactions do not occur.Further,by changing the parameters of nanosecond pulse power supply voltage,it is found that the electron number density,electron current density,and applied peak voltages are not the direct reasons for the structural changes of the sheath and pre-sheath.Furthermore,the discharge interval has little effect on the sheath structure and gas mixture breakdown.The research results of this paper not only help to understand the kinetic promotion of non-equilibrium excitation in the process of oxidative pyrolysis but also help to explore the influence of transport and chemical reaction kinetics on the oxidative pyrolysis of ammonia. 展开更多
关键词 Nanosecond pulsed discharge AMMONIA Oxidative pyrolysis Fluid model Global model
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Hybrid ecophysiological growth model for deciduous Populus tomentosa plantation in northern China
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作者 Serajis Salekin Mark Bloomberg +4 位作者 Benye Xi Jinqiang Liu Yang Liu Doudou Li Euan G.Mason 《Forest Ecosystems》 2025年第1期112-120,共9页
Short rotation plantation forestry(SRF)is being widely adopted to increase wood production,in order to meet global demand for wood products.However,to ensure maximum gains from SRF,optimised management regimes need to... Short rotation plantation forestry(SRF)is being widely adopted to increase wood production,in order to meet global demand for wood products.However,to ensure maximum gains from SRF,optimised management regimes need to be established by integrating robust predictions and an understanding of mechanisms underlying tree growth.Hybrid ecophysiological models,such as potentially useable light sum equation(PULSE)models,are useful tools requiring minimal input data that meet the requirements of SRF.PULSE models have been tested and calibrated for different evergreen conifers and broadleaves at both juvenile and mature stages of tree growth with coarse soil and climate data.Therefore,it is prudent to question:can adding detailed soil and climatic data reduce errors in this type of model?In addition,PULSE techniques have not been used to model deciduous species,which are a challenge for ecophysiological models due to their phenology.This study developed a PULSE model for a clonal Populus tomentosa plantation in northern China using detailed edaphic and climatic data.The results showed high precision and low bias in height(m)and basal area(m^(2)·ha^(-1))predictions.While detailed edaphoclimatic data produce highly precise predictions and a good mechanistic understanding,the study suggested that local climatic data could also be employed.The study showed that PULSE modelling in combination with coarse level of edaphic and local climate data resulted in reasonably precise tree growth prediction and minimal bias. 展开更多
关键词 Growth-yield model Populus species Hybrid ecophysiological modelling Deciduous trees PHENOLOGY
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C^(1,1) REGULARITY FOR SOLUTIONS TO THE DEGENERATE DUAL ORLICZ-MINKOWSKI PROBLEM
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作者 Di WU 《Acta Mathematica Scientia》 2025年第2期327-337,共11页
In this paper,C1,1 regularity for solutions to the degenerate dual Orlicz-Minkowski problem is considered.The dual Orlicz-Minkowski problem is a generalization of the Lp dual Minkowski problem in convex geometry.The p... In this paper,C1,1 regularity for solutions to the degenerate dual Orlicz-Minkowski problem is considered.The dual Orlicz-Minkowski problem is a generalization of the Lp dual Minkowski problem in convex geometry.The proof is adapted from Guan-Li[17]and Chen-Tu-Wu-Xiang[11]. 展开更多
关键词 C^(1 1)regularity Monge-Ampere type equation dual Orlicz-Minkowski problem
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Trending and emerging prospects of physics-based and ML-based wildfire spread models:a comprehensive review
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作者 Harikesh Singh Li‑Minn Ang +4 位作者 Tom Lewis Dipak Paudyal Mauricio Acuna Prashant Kumar Srivastava Sanjeev Kumar Srivastava 《Journal of Forestry Research》 2025年第1期27-59,共33页
The significant threat of wildfires to forest ecology and biodiversity,particularly in tropical and subtropical regions,underscores the necessity for advanced predictive models amidst shifting climate patterns.There i... The significant threat of wildfires to forest ecology and biodiversity,particularly in tropical and subtropical regions,underscores the necessity for advanced predictive models amidst shifting climate patterns.There is a need to evaluate and enhance wildfire prediction methods,focusing on their application during extended periods of intense heat and drought.This study reviews various wildfire modelling approaches,including traditional physical,semi-empirical,numerical,and emerging machine learning(ML)-based models.We critically assess these models’capabilities in predicting fire susceptibility and post-ignition spread,highlighting their strengths and limitations.Our findings indicate that while traditional models provide foundational insights,they often fall short in dynamically estimating parameters and predicting ignition events.Cellular automata models,despite their potential,face challenges in data integration and computational demands.Conversely,ML models demonstrate superior efficiency and accuracy by leveraging diverse datasets,though they encounter interpretability issues.This review recommends hybrid modelling approaches that integrate multiple methods to harness their combined strengths.By incorporating data assimilation techniques with dynamic forecasting models,the predictive capabilities of ML-based predictions can be significantly enhanced.This review underscores the necessity for continued refinement of these models to ensure their reliability in real-world applications,ultimately contributing to more effective wildfire mitigation and management strategies.Future research should focus on improving hybrid models and exploring new data integration methods to advance predictive capabilities. 展开更多
关键词 Wildfire spread Fire prediction models Cellular automata model WRF-Fire/SFire FIRETEC CAWFE WFDS
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Solubility and Thermodynamic Modeling of 3⁃Nitro⁃1,2,4⁃triazole⁃5⁃one(NTO)in Different Binary Solvents
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作者 GUO Hao-qi YANG Yu-lin 《含能材料》 北大核心 2025年第3期295-303,共9页
Using a dynamic laser monitoring technique,the solubility of 3-nitro-1,2,4-triazole-5-one(NTO)was investigated in two different binary systems,namely hydroxylamine nitrate(HAN)-water and boric acid(HB)-water ranging f... Using a dynamic laser monitoring technique,the solubility of 3-nitro-1,2,4-triazole-5-one(NTO)was investigated in two different binary systems,namely hydroxylamine nitrate(HAN)-water and boric acid(HB)-water ranging from 278.15 K to 318.15 K.The solubility in each system was found to be positively correlated with temperature.Furthermore,solubility data were analyzed using four equations:the modified Apelblat equation,Van’t Hoff equation,λh equation and CNIBS/R-K equations,and they provided satisfactory results for both two systems.The average root-mean-square deviation(105RMSD)values for these models were less than 13.93.Calculations utilizing the Van’t Hoff equation and Gibbs equations facilitated the derivation of apparent thermodynamic properties of NTO dissolution in the two systems,including values for Gibbs free energy,enthalpy and entropy.The%ζ_(H)is larger than%ζ_(TS),and all the%ζ_(H)data are≥58.63%,indicating that the enthalpy make a greater contribution than entropy to theΔG_(soln)^(Θ). 展开更多
关键词 3-nitro-l 2 4-triazole-5-one(NTO) SOLUBILITY thermodynamic models apparent thermodynamic analysis
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Optimization of Skanavi model and its application to high permittivity materials
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作者 Hao Luo Xinrui Qin +2 位作者 Kejia Geng Cuncun Kong Pengfei Cheng 《Chinese Physics B》 2025年第1期458-466,共9页
A novel method is introduced to optimize the traditional Skanavi model by decomposing the electric field of molecules into the electric field of ions and quantitatively describing the ionic-scale electric field by the... A novel method is introduced to optimize the traditional Skanavi model by decomposing the electric field of molecules into the electric field of ions and quantitatively describing the ionic-scale electric field by the structural coefficient of the effective electric field.Furthermore,the optimization of the Skanavi model is demonstrated and the ferroelectric phase transition of BaTiO_(3)crystals is revealed by calculating the optical and static permittivities of BaTiO_(3),CaTiO_(3),and SrTiO_(3)crystals and the structure coefficients of the effective electric field of BT crystals after Ti4+displacement.This research compensates for the deficiencies of the traditional Skanavi model and refines the theoretical framework for analyzing dielectric properties in high permittivity materials. 展开更多
关键词 electric field structural coefficient PERMITTIVITY Skanavi model
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Evaluating research quality with Large Language Models:An analysis of ChatGPT’s effectiveness with different settings and inputs
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作者 Mike Thelwall 《Journal of Data and Information Science》 2025年第1期7-25,共19页
Purpose:Evaluating the quality of academic journal articles is a time consuming but critical task for national research evaluation exercises,appointments and promotion.It is therefore important to investigate whether ... Purpose:Evaluating the quality of academic journal articles is a time consuming but critical task for national research evaluation exercises,appointments and promotion.It is therefore important to investigate whether Large Language Models(LLMs)can play a role in this process.Design/methodology/approach:This article assesses which ChatGPT inputs(full text without tables,figures,and references;title and abstract;title only)produce better quality score estimates,and the extent to which scores are affected by ChatGPT models and system prompts.Findings:The optimal input is the article title and abstract,with average ChatGPT scores based on these(30 iterations on a dataset of 51 papers)correlating at 0.67 with human scores,the highest ever reported.ChatGPT 4o is slightly better than 3.5-turbo(0.66),and 4o-mini(0.66).Research limitations:The data is a convenience sample of the work of a single author,it only includes one field,and the scores are self-evaluations.Practical implications:The results suggest that article full texts might confuse LLM research quality evaluations,even though complex system instructions for the task are more effective than simple ones.Thus,whilst abstracts contain insufficient information for a thorough assessment of rigour,they may contain strong pointers about originality and significance.Finally,linear regression can be used to convert the model scores into the human scale scores,which is 31%more accurate than guessing.Originality/value:This is the first systematic comparison of the impact of different prompts,parameters and inputs for ChatGPT research quality evaluations. 展开更多
关键词 ChatGPT Large Language models LLMs SCIENTOMETRICS Research Assessment
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Orbital XY models in moiré superlattices
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作者 Yanqi Li Yi-Jie Wang Zhi-Da Song 《Chinese Physics B》 2025年第2期19-29,共11页
Moiré superlattices provide a new platform to engineer various many-body problems. In this work, we consider arrays of quantum dots(QD) realized on semiconductor moiré superlattices with a deep moiré po... Moiré superlattices provide a new platform to engineer various many-body problems. In this work, we consider arrays of quantum dots(QD) realized on semiconductor moiré superlattices with a deep moiré potential. We diagonalize single QD with multiple electrons, and find degenerate ground states serving as local degrees of freedom(qudits) in the superlattice. With a deep moiré potential, the hopping and exchange interaction between nearby QDs become irrelevant,and the direct Coulomb interaction of the density–density type dominates. Therefore, nearby QDs must arrange the spatial densities to optimize the Coulomb energy. When the local Hilbert space has a two-fold orbital degeneracy, we find that a square superlattice realizes an anisotropic XY model, while a triangular superlattice realizes a generalized XY model with geometric frustration. 展开更多
关键词 moirésuperlattices quantum dots XY model
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A predictive model for intracranial hemorrhage in adult patients receiving extracorporeal membrane oxygenation
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作者 Yi Zhu Lina Mao +7 位作者 Zhongman Zhang Sae Rom Lee Tianshi Li Hao Zhou Yanbin Dong Di An Wei Li Xufeng Chen 《World Journal of Emergency Medicine》 2025年第2期153-160,共8页
BACKGROUND:Intracranial hemorrhage (ICH),a severe complication among adults receiving extracorporeal membrane oxygenation (ECMO),is often related to poor outcomes.This study aimed to establish a predictive model for I... BACKGROUND:Intracranial hemorrhage (ICH),a severe complication among adults receiving extracorporeal membrane oxygenation (ECMO),is often related to poor outcomes.This study aimed to establish a predictive model for ICH in adults receiving ECMO treatment.METHODS:Adults who received ECMO between January 2017 and June 2022 were the subjects of a single-center retrospective study.Patients under the age of 18 years old,with acute ICH before ECMO,with less than 24 h of ECMO support,and with incomplete data were excluded.ICH was diagnosed by a head computed tomography scan.The outcomes included the incidence of ICH,in-hosptial mortality and 28-day mortality.Multivariate logistic regression analysis was used to identify relevant risk factors of ICH,and a predictive model of ICH with a nomogram was constructed.RESULTS:Among the 227 patients included,22 developed ICH during ECMO.Patients with ICH had higher in-hospital mortality (90.9%vs.47.8%,P=0.001) and higher 28-day mortality (81.8%vs.47.3%,P=0.001) than patients with non-ICH.ICH was associated with decreased grey-white-matter ratio (GWR)(OR=0.894,95%CI:0.841–0.951,P<0.001),stroke history (OR=4.265,95%CI:1.052–17.291,P=0.042),fresh frozen plasma (FFP) transfusion (OR=1.208,95%CI:1.037–1.408,P=0.015)and minimum platelet (PLT) count during ECMO support (OR=0.977,95%CI:0.958–0.996,P=0.019).The area under the receiver operating characteristic curve of the ICH predictive model was 0.843 (95%CI:0.762–0.924,P<0.001).CONCLUSION:ECMO-treated patients with ICH had a higher risk of death.GWR,stroke history,FFP transfusion,and the minimum PLT count were independently associated with ICH,and the ICH predictive model showed that these parameters performed well as diagnostic tools. 展开更多
关键词 Extracorporeal membrane oxygenation Intracranial hemorrhage Predictive model Grey-white-matter ratio
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Predicting the rate of spread of mixed-fuel surface fires in northeastern China using the Rothermel wildfire behaviour model:a laboratory study
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作者 Hui Yang Huiying Cai +2 位作者 Guang Yang Daotong Geng Long Sun 《Journal of Forestry Research》 2025年第1期379-390,共12页
The rate of fire spread is a key indicator for assessing forest fire risk and developing fire management plans.The Rothermel model is the most widely used fire spread model,established through laboratory experiments o... The rate of fire spread is a key indicator for assessing forest fire risk and developing fire management plans.The Rothermel model is the most widely used fire spread model,established through laboratory experiments on homogeneous fuels but has not been validated for conifer-deciduous mixed fuel.In this study,Pinus koraiensis and Quercus mongolica litter was used in a laboratory burning experiment to simulate surface fire spread in the field.The effects of fuel moisture content,mixed fuel ratio and slope on spread rate were analyzed.The optimum packing ratio,moisture-damping coefficient and slope parameters in the Rothermel model were modified using the measured spread rate which was positively correlated with slope and negatively with fuel moisture content.As the Q.mongolica load increased,the spread rate increased and was highest at a fuel ratio of 4:6.The model with modified optimal packing ratio and slope parameters has a significantly lower spread rate prediction error than the unmodified model.The spread rate prediction accuracy was significantly improved after modifying the model parameters based on spread rates from laboratory burning simulations. 展开更多
关键词 Rothermel model Mixed fuel Fuel moisture content SLOPE Parameter modification
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Data Gathering Based on Hybrid Energy Efficient Clustering Algorithm and DCRNN Model in Wireless Sensor Network
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作者 Li Cuiran Liu Shuqi +1 位作者 Xie Jianli Liu Li 《China Communications》 2025年第3期115-131,共17页
In order to solve the problems of short network lifetime and high data transmission delay in data gathering for wireless sensor network(WSN)caused by uneven energy consumption among nodes,a hybrid energy efficient clu... In order to solve the problems of short network lifetime and high data transmission delay in data gathering for wireless sensor network(WSN)caused by uneven energy consumption among nodes,a hybrid energy efficient clustering routing base on firefly and pigeon-inspired algorithm(FF-PIA)is proposed to optimise the data transmission path.After having obtained the optimal number of cluster head node(CH),its result might be taken as the basis of producing the initial population of FF-PIA algorithm.The L′evy flight mechanism and adaptive inertia weighting are employed in the algorithm iteration to balance the contradiction between the global search and the local search.Moreover,a Gaussian perturbation strategy is applied to update the optimal solution,ensuring the algorithm can jump out of the local optimal solution.And,in the WSN data gathering,a onedimensional signal reconstruction algorithm model is developed by dilated convolution and residual neural networks(DCRNN).We conducted experiments on the National Oceanic and Atmospheric Administration(NOAA)dataset.It shows that the DCRNN modeldriven data reconstruction algorithm improves the reconstruction accuracy as well as the reconstruction time performance.FF-PIA and DCRNN clustering routing co-simulation reveals that the proposed algorithm can effectively improve the performance in extending the network lifetime and reducing data transmission delay. 展开更多
关键词 CLUSTERING data gathering DCRNN model network lifetime wireless sensor network
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