期刊文献+
共找到89篇文章
< 1 2 5 >
每页显示 20 50 100
Influence of nano-scaled dispersed second phase on substructure of deformed dispersion strengthened copper alloy 被引量:2
1
作者 CHENG Jian-yi WANG Ming-pu CAO Jian-guo ZHAO Xue-long GUO Ming-xing 《Journal of Central South University of Technology》 2005年第z1期50-53,共4页
The deformation behavior of dispersion strengthened copper alloy Cu-Al2O3 was studied by TEM. The results show that nano-scaled dispersed second phase not only increases dislocation density in matrix, but also has an ... The deformation behavior of dispersion strengthened copper alloy Cu-Al2O3 was studied by TEM. The results show that nano-scaled dispersed second phase not only increases dislocation density in matrix, but also has an important influence on the dislocation substructure. The presence of fine dispersed Al2 O3 particles results in a uniform and random dislocation distribution in matrix copper and causes the difficulty in formation of dislocation cell structure and the decrease in the amount of cell structure during deformation. Deformation gives rise to much more dislocations and dislocation cells form more difficultly and the decrease in the cell size with the increase of dispersion degree. 展开更多
关键词 dispersed phase PARTICLE DISPERSION STRENGTHENED copper alloy DEFORMATION SUBSTRUCTURE
在线阅读 下载PDF
Research on a Dispersed Networked CAD/CAM System of Motorcycle
2
作者 WANG Xian-kun (Dept. of Mechanical Engineering, Fuzhou University, Fuzhou 350002, Ch ina) 《厦门大学学报(自然科学版)》 CAS CSCD 北大核心 2002年第S1期167-168,共2页
In order to improve competitive ability of market, mo torcycle enterprises, special the small and middle sized ones must use IT to org anize social resource and adopt effective production mode, namely the dispersed ne... In order to improve competitive ability of market, mo torcycle enterprises, special the small and middle sized ones must use IT to org anize social resource and adopt effective production mode, namely the dispersed networked design and manufacturing (DNDM), which was put forward and proved to b e one of vitality production modes in recent years. In responding to the new pro duction mode of VMCE, a dispersed networked CAD/CAM system (DNCADMS) of motorcyc le products should be developed. The objective of this paper is to investigate a new design and manufacturing mode and technical environment of motorcycle produ ction based on the concept of the DNDM for the small and meddle sized motorcycle enterprises. Because there are various CAx software systems, including differen t kinds of isolated CD, CAD, CAE, CAPP, CAM, PDM, and so on, are used at differe nt stages of the life period of motorcycle products under heterogeneous environm ents, to build a DNCADMS of motorcycle with high performance, some key issues, n amely the architecture of the DNCADMS, the integration of the isolated CAx softw are systems (CAxs), the data communication and exchange between these isolated s ystems and the data share problem under the dispersed heterogeneous database env ironment, should be solved well. For this, the idea we propose is the combinatio n of Web, CORBA, STEP and Java, which provides an effective mechanism to support the integration of isolated CAxs, and support communication and interoperabilit y among CAx systems. Each isolated CAx has been encapsulated respectively by a c ontainer, which is implemented by the ORBs and the IDL of the COBRA technology s tandard, and managed by the application index server. Each container is connecte d with the others by a local network or intranet/Extranet/internet and communica tes through network. For exchanging design and manufacturing information and kno wledge via a local network or the Internet, a commmerical product data translato r has been employed as a product data translating server to complete product dat a communication and exchange between the isolated CAx systems. And for solving t he data share problem under the dispersed networked heterogeneous database envir onment, the idea we propose is to build a meta-database for the native database s, which is a dispersed database, and links various native databases into a whol e logical database. For managing the meta-database, the database index server, a Java-based integrating mechanism, has been also put forward in this paper. Th e application and database index servers have been implemented with Java lan guage. Moreover, the native data base and knowledge base related to each isolate d CAx are be integrated into a dispersed database system by a meta-base. 展开更多
关键词 dispersed networked CAD/CAM PDM MOTORCYCLE We b CORBA
在线阅读 下载PDF
Management and Control of Outsourcing in Dispersed Network Manufacturing Systems
3
作者 Rob Dekkers Luping Wang 《厦门大学学报(自然科学版)》 CAS CSCD 北大核心 2002年第S1期249-,共1页
The trend of economic globalisation and advances in i nformation technology has led to the emergence of dispersed manufacturing system s as a form of the virtual organisation. New manufacturing strategy pays more at t... The trend of economic globalisation and advances in i nformation technology has led to the emergence of dispersed manufacturing system s as a form of the virtual organisation. New manufacturing strategy pays more at tention to the management of the total value chain and therefore puts emphasis o n outsourcing. In fact, outsourcing is an efficient way of utilizing available r esources and has become one key aspect of the manufacturing strategy. Improved d ecision and organization on outsourcing will result in cost production and short er lead-times. However, most concepts and practice of traditional outsourcing do not adapt to t he changing environment and meet increasing performance requirements. On the oth er hand, virtual organisations might display instability between pure outsourcin g and establishing alliance. Balance and trade-off between independent agents a nd creating alliance are thus required. Therefore, the purpose of this paper is to develop a model to support decision-making, management and control on outsou rcing in a dispersed network manufacturing system and to discuss several key iss ues that are relevant to the relationship between the agents of the network. Dev elopment of the model will deploy Applied System Theory and will be built on fou ndations of earlier research on industrial management such the theories of Outso urcing, Order Entry Points, Design of Organisations and Logistic Control. The is sues that will be addressed in this paper are: · The selection of suppliers and co-makers; · Communication between suppliers and clients; · The mechanisms for profit-sharing between agents; · The product data management to integrate the knowledge of the different agent s into product design. Industrial companies will benefit from this research by the practical methods an d implementation extending their business models beyond concepts for outsourcing and alliances. Additionally, the exploration will lead to proactive contributio n of manufacturing during engineering, which would improve management and contro l of dispersed manufacturing systems. 展开更多
关键词 Management and Control of Outsourcing in dispersed Network Manufacturing SYSTEMS
在线阅读 下载PDF
Pre-dispersed carbon black as conductive agent for LiFePO_4 cathodes 被引量:1
4
作者 张治安 屈长明 +2 位作者 贾明 赖延清 李劼 《Journal of Central South University》 SCIE EI CAS 2014年第7期2604-2611,共8页
High dispersed carbon black was applied for LiFePO4 cathodes as conductive agent.Nano-conductive carbon agent was pre-dispersed with poly acrylic acid(PAA) as dispersant in organic N-methyl-pyrrolidone(NMP) solvent sy... High dispersed carbon black was applied for LiFePO4 cathodes as conductive agent.Nano-conductive carbon agent was pre-dispersed with poly acrylic acid(PAA) as dispersant in organic N-methyl-pyrrolidone(NMP) solvent system.The dispersion property of nano-conductive carbon agent was evaluated using particle size distribution measurements,scanning electron microscopy(SEM) and transmission electron microscope(TEM).LiFePO4 cathode with as-received nano-conductive carbon agent(SP) and LiFePO4 cathode with pre-dispersed nano-conductive carbon agent(SP-PAA) were examined by scanning electron microscopy(SEM),cyclic voltammetry(CV),electrochemical impendence spectroscopy(EIS) and charge/discharge cycling performance.Results show that the dispersion property of carbon black is improved by using PAA as the dispersant.The LiFePO4 cathodes with SP-PAA exhibit improved rate behaviors(4C,135.1 mAh/g) and cycle performance(95%,200 cycles) compared to LiFePO4 cathodes with SP(4C,103.9 mAh/g and 83%,200 cycles).Because pre-dispersed carbon black(SP-PAA) is dispersed homogeneously in the dried composite electrode to form a more uniform conductive network between the active material particles,electrochemical performances of the LiFePO4 cathodes are improved. 展开更多
关键词 LiFePO4 cathode carbon black DISPERSION poly acrylic acid
在线阅读 下载PDF
Flatness detection method of splicing detector based on channel spectral dispersion
5
作者 ZHAO Hong-chao ZHANG Xiao-qian AN Qi-chang 《中国光学(中英文)》 北大核心 2025年第4期889-898,共10页
For segmented detectors,surface flatness is critical as it directly influences both energy resolution and image clarity.Additionally,the limited adjustment range of the segmented detectors necessitates precise benchma... For segmented detectors,surface flatness is critical as it directly influences both energy resolution and image clarity.Additionally,the limited adjustment range of the segmented detectors necessitates precise benchmark construction.This paper proposes an architecture for detecting detector flatness based on channel spectral dispersion.By measuring the dispersion fringes for coplanar adjustment,the final adjustment residual is improved to better than 300 nm.This result validates the feasibility of the proposed technology and provides significant technical support for the development of next-generation large-aperture sky survey equipment. 展开更多
关键词 large aperture telescope segmented detector surface wavefront detection channel spectral dispersion
在线阅读 下载PDF
Regulating the Fe/Mo ratio of FeMoO_(x)/LaTiO_(y) to boost aerobic oxidative desulfurization of diesel
6
作者 ZHANG Fengren YAN Ying +6 位作者 LIU Feng WU Yang LIANG Shuqin CHENG Huifang HAN Shanlei LIU Jixing ZHU Wenshuai 《燃料化学学报(中英文)》 北大核心 2025年第8期1255-1268,共14页
Catalytic oxidation desulfurization(CODS)technology has shown great promise for diesel desulfurization by virtue of its low cost,mild reaction conditions,and superior desulfurization performance.Herein,a series of FeM... Catalytic oxidation desulfurization(CODS)technology has shown great promise for diesel desulfurization by virtue of its low cost,mild reaction conditions,and superior desulfurization performance.Herein,a series of FeMoO_(x)/LaTiO_(y)-z samples with diverse Fe/Mo ratios were prepared via a facile citric acid-assisted method.The impact of Fe incorporation on the dispersion and surface elemental states of Mo species,as well as oxygen species content of the synthesized FeMoO_(x)/LaTiO_(y)-z catalysts were systematically characterized using TEM,BET,UV-vis DRS,XPS,XANES,and reaction kinetics,and their CODS performances were examined for 4,6-DMDBT removal.Experimental results demonstrated that Fe/Mo ratio significantly affected the Ti−O bond strength,surface dispersion and electronic structure of Mo O_(2)species on FeMoO_(x)/LaTiO_(y)-z catalysts.FeMoO_(x)/LaTiO_(y)-2 catalyst showed outstanding cycling durability and the best CODS performance with almost 100%removal of 4,6-DMDBT from model oil within 75 min due to its proper MoO3 dispersion,optimal redox property,and the most oxygen vacancy concentration.Nevertheless,further enhancing Fe content led to the increased dispersion of Mo species,while the decrease active Mo species as well as the increase of steric effect for 4,6-DMDBT accessing to the catalytic reactive sites considerably increase the apparent activation energy of FeMoO_(x)/LaTiO_(y)-z(z>2)catalysts during the CODS process,thereby seriously suppressing their CODS performances.Moreover,Radical trapping experiments reveal that the·,generated by the activation of O_(2)at the active sites,catalytic oxidized 4,6-DMDBT to the product of 4,6-DMDBTO_(2),thereby enabling both deep desulfurization and recovery of high-value 4,6-DMDBTO_(2).These findings offer an alternative strategy to achieve ultra deep desulfurization as well as separate and recover high economic value sulfone substances from diesel. 展开更多
关键词 catalytic oxidation desulfurization FeMoO_(x)/LaTiO_(y)catalyst Ti−O bond dispersion reaction kinetics
在线阅读 下载PDF
Positive role of regulator in desulfurization of chalcopyrite in seawater based on chelation and dispersion
7
作者 SONG Ning-bo YIN Wan-zhong +1 位作者 GONG Xiu-feng YAO Jin 《Journal of Central South University》 2025年第5期1791-1801,共11页
The chemical composition of seawater affects the desulfurization of chalcopyrite in flotation.In this study,desulfurization experiments of chalcopyrite were conducted in both deionized(DI)water and seawater.The result... The chemical composition of seawater affects the desulfurization of chalcopyrite in flotation.In this study,desulfurization experiments of chalcopyrite were conducted in both deionized(DI)water and seawater.The results showed that,the copper grade of the concentrate obtained from seawater flotation decreased to 24.30%,compared to 24.60%in DI water.Concurrently,the recovery of chalcopyrite decreased from 51.39%to 38.67%,while the selectivity index(SI)also had a reduction from 2.006 to 1.798.The incorporation of ethylene diamine tetraacetic acid(EDTA),sodium silicate(SS),and sodium hexametaphosphate(SHMP)yielded an enhancement in the SI value,elevating it from 1.798 to 1.897,2.250 and 2.153,separately.It is particularly noteworthy that an excess of EDTA resulted in a SI value of merely 1.831.The mechanism of action was elucidated through analysis of surface charge measurements,X-ray photoelectron spectroscopy(XPS),Fourier transform infrared spectroscopy(FT-IR),extended Derjaguin-Landau Verwey-Overbeek(E-DLVO)theory,and density functional theory(DFT)calculations. 展开更多
关键词 CHALCOPYRITE DESULFURIZATION CHELATION DISPERSION E-DLVO theory
在线阅读 下载PDF
Random walk dispersion model for missile contrail particles in cross-airspace environments
8
作者 Chenshuo Li Debin Fu Tianyu Wei 《Defence Technology(防务技术)》 2025年第7期307-320,共14页
Missiles provide long-range precision strike capabilities and have become a cornerstone of modern warfare.The contrail clouds formed by missile during their active flight phase present significant chal-lenges to high-... Missiles provide long-range precision strike capabilities and have become a cornerstone of modern warfare.The contrail clouds formed by missile during their active flight phase present significant chal-lenges to high-altitude environmental observation and target detection and tracking.Existing studies primarily focus on specific airspace regions,leaving critical gaps in understanding the effects of long dispersion times,wide altitude ranges,and variable atmospheric conditions on missile contrail clouds.To address these gaps,this article develops a numerical method based on the Lagrangian random walk model,which incorporates various velocity variation terms,including particle velocity caused by the difference of wind field,by the thermal motion of local gas molecules and by random collisions between contrail cloud particles to capture the influence of environmental wind fields,atmospheric conditions,and particle concentrations on the motion of contrail cloud particles.A general coordinate system aligned with the missile's flight trajectory is employed to represent particle distribution characteristics.The proposed method is in good agreement with the conducted experiments as well as with the available numerical simulations.The results demonstrate that the proposed model effectively simulates the dispersion state of contrail clouds,accurately reflecting the impact of large-scale wind field variations and altitude changes with high computational efficiency.Additionally,simulation results indicate that the increased distance between gas molecules in rarefied environments facilitates enhanced particle dispersion,while larger particles exhibit a faster dispersion rate due to their greater mass. 展开更多
关键词 Missile contrail Dispersion process Random walk model Concentration distribution Cross-airspace
在线阅读 下载PDF
分散固相萃取-高效液相色谱法快速检测猕猴桃中的氯吡脲 被引量:48
9
作者 胡江涛 盛毅 +2 位作者 方智 金晶 何开蓉 《色谱》 CAS CSCD 北大核心 2007年第3期441-442,共2页
建立了高效液相色谱快速检测猕猴桃中氯吡脲残留的方法。试样经乙腈提取、丙基乙二胺(PSA)分散固相萃取(DSPE)净化后在C18柱上以乙腈-0.01mol/L磷酸水溶液(体积比为35:65)为流动相进行分离,在260nm波长下检测。氯吡脲的检出限... 建立了高效液相色谱快速检测猕猴桃中氯吡脲残留的方法。试样经乙腈提取、丙基乙二胺(PSA)分散固相萃取(DSPE)净化后在C18柱上以乙腈-0.01mol/L磷酸水溶液(体积比为35:65)为流动相进行分离,在260nm波长下检测。氯吡脲的检出限为0.005mg/kg,在0.05~10.00mg/L时线性关系良好(r=1.000)。试样在0.05,0.60,1.20mg/kg三个添加水平的回收率为82.0%~112.0%,相对标准偏差(RSD)(n=5)为2.41%。该方法简便快速,准确灵敏,适合大批量样品的快速处理。 展开更多
关键词 分散固相萃取(dispersive solid phase extraction) 高效液相色谱(HPLC) 氯吡脲(forchlorfenuron) 猕猴桃(Chinese gooseberry)
在线阅读 下载PDF
分散固相萃取法对鸡精中3-氯-1,2-氯丙醇的测定 被引量:3
10
作者 王翔 宋国新 +1 位作者 赵建丰 胡耀铭 《分析测试学报》 CAS CSCD 北大核心 2008年第S1期207-208,共2页
A new method for determination of 3-MCPD in powder condiments was established by GC-MS method using 1,4-butanediol as an internal standard.Samples were ultrasonically extracted by ethyl acetate,and cleaned up by dispe... A new method for determination of 3-MCPD in powder condiments was established by GC-MS method using 1,4-butanediol as an internal standard.Samples were ultrasonically extracted by ethyl acetate,and cleaned up by dispersive solid-phase extraction(d-SPE) using octadecane sorbent(C18).Then the extract was derivatized with HFBI and detected by GC-MS.The detection limitation was 1.0 μg/kg,and spiked recoveries ranged from 97%-102% with RSD of 2.1%-4.1%. 展开更多
关键词 3-MCPD solid CONDIMENTS DISPERSIVE SOLID-PHASE extraction(d-SPE) GC-MS
在线阅读 下载PDF
风险投资的风险分散机制研究 被引量:4
11
作者 彭福扬 曾广波 彭祝斌 《财经理论与实践》 CSSCI 北大核心 2003年第2期41-45,共5页
在高科技风险投资的众多风险中 ,投资环境不完善造成的环境风险以及由于投资者经验不足 ,不能巧妙运用各种投资技巧所引起的经验风险是两种主要的风险。
关键词 风险投资 风险分散 环境风险 经验风险
在线阅读 下载PDF
世界麦双尾蚜研究进展:分布、危害和生物学特性 被引量:2
12
作者 张润志 梁宏斌 张广学 《昆虫学报》 CAS CSCD 北大核心 1999年第S1期130-140,共11页
The Russian wheat aphid (RWA), Diuraphis noxia (Mordvilko), has become a worldwide cereal pest with its dispersion to over 30 countries in this century. According to the natural history of its occurrence around the wo... The Russian wheat aphid (RWA), Diuraphis noxia (Mordvilko), has become a worldwide cereal pest with its dispersion to over 30 countries in this century. According to the natural history of its occurrence around the world, it is postulated RWA originated from western or central Asia. The aphid dispersed gradually to Europe and northern Africa, but its big jump across the ocean to North America is still a mystery. There are two overwintering strategies in RWA. The anholocyclic biotype, often reproducing earlier and more offsprings than the holocyclic one, has greater impact on crops in South Africa and United States. According to the experiments on its thermal response, RWA could withstand temperatures below -20℃, while temperatures above 30℃ would be harmful to its survival. The preference to colder condition may determine its distribution on the world. RWA has made great damages to cereal crops worldwide. It caused loss in crop yield by directly feeding on plant nutrition and disturbing the plant metabolism. But its status as plant virus transporter is open to question. By now, the aphid is still a serious pest in many countries and its invasion to more countries and areas maybe continues. Therefore, the research on its biological characteristics as well as its dispersion apparently needs to be enhanced in the future. 展开更多
关键词 RUSSIAN WHEAT APHID (Diuraphis noxia (Mordvilko)) DISPERSION distribution ECONOMIC impact thermal response
在线阅读 下载PDF
超临界CO_2中分散红54在涤纶织物中的扩散研究 被引量:1
13
作者 李雁 徐明仙 +2 位作者 董萍 沈元 林春绵 《高校化学工程学报》 EI CAS CSCD 北大核心 2014年第3期549-552,共4页
超临界CO 2染色技术是一种新型的绿色环保染色技术,超临界CO 2中分散染料在涤纶织物中的扩散性能是超临界CO 2染色技术的一个重要基础。为了研究超临界CO 2中分散染料在涤纶织物中的扩散性能,研究采用“卷层法”,在温度70~110℃,压... 超临界CO 2染色技术是一种新型的绿色环保染色技术,超临界CO 2中分散染料在涤纶织物中的扩散性能是超临界CO 2染色技术的一个重要基础。为了研究超临界CO 2中分散染料在涤纶织物中的扩散性能,研究采用“卷层法”,在温度70~110℃,压力16~24 MPa下,选用分散红54在自行研制的超临界CO2染色装置中对涤纶织物进行超临界CO2染色扩散实验。实验结果表明,染料在涤纶织物中的扩散过程是一边上染纤维一边向纤维内部扩散的过程,所建立的染色-扩散模型成功地描述了这一过程。随着温度的升高,染色速率系数与扩散系数之比随之增大,随着压力的升高,两者之比先升后降。 展开更多
关键词 超临界CO 2 涤纶 分散红54 扩散 SUPERCRITICAL CO2 disperse RED 54
在线阅读 下载PDF
乳化剂在肉制品加工中的应用 被引量:9
14
作者 刘士江 《肉类研究》 2003年第4期36-36,45,共2页
讨论了肉食加工中常用的几种乳化剂,并就其性质、应用及安全性进行了说明。
关键词 乳化剂 肉制品 性质 应用 安全性 酪朊酸钠 甘油脂肪酸酯 蔗糖脂肪酸酯
在线阅读 下载PDF
论计算课程理论的重要性(英文)
15
作者 ROSEN C C H ALDRIDGE S 《中山大学学报(自然科学版)》 CAS CSCD 北大核心 2007年第S2期24-27,共4页
In 1995 Ince[1] wrote an article for the Times Higher Educational Supplement noting that there was little theoretical understanding of software engineering and that therefore computer studies did not constitute an aca... In 1995 Ince[1] wrote an article for the Times Higher Educational Supplement noting that there was little theoretical understanding of software engineering and that therefore computer studies did not constitute an academic discipline.Computing departments should be balkanised.Computing staff should be dispersed to other departments such as maths,psychology and business studies.This contro.ersy has recently been rein.igorated by McBride’s article[2] in the same paper and on the British Computer Society web site[3] arguing that in face of the massi.e decline in computing student intake onto uni.ersity undergraduate courses that the future for traditional courses is bleak.The reaction generated[3-4] reflects the anxiety within computing departments.The concern is e.ident. 展开更多
关键词 dispersed COURSES noting UNDERGRADUATE DISCIPLINE ANXIETY ident INTAKE perception projection
在线阅读 下载PDF
气相色谱-负化学源质谱联用法测定水产品及食用油中氟乐灵的残留量 被引量:9
16
作者 王莉 夏广辉 +5 位作者 沈伟健 吴斌 张睿 陆慧媛 沈崇钰 赵增运 《色谱》 CAS CSCD 北大核心 2014年第3期314-317,共4页
建立了一种可用于水产品及食用油中氟乐灵残留量分析的分散型固相萃取-气相色谱-负化学离子源质谱方法。水产品及食用油经乙腈提取,4℃冷藏后,采用分散型固相萃取法净化,由气相色谱-负化学离子源质谱选择离子监测技术进行测定与确证... 建立了一种可用于水产品及食用油中氟乐灵残留量分析的分散型固相萃取-气相色谱-负化学离子源质谱方法。水产品及食用油经乙腈提取,4℃冷藏后,采用分散型固相萃取法净化,由气相色谱-负化学离子源质谱选择离子监测技术进行测定与确证,同位素内标法定量。在1~40μg / L 范围内氟乐灵农药的线性关系良好;方法定量限(LOQ)为0.02μg / kg;对鳗鱼、烤鳗、梭子蟹、小龙虾、猪油和橄榄油等6种复杂基质进行1.0、2.0和3.0μg / kg 等3个水平的添加回收试验,平均回收率均处于80%~100%之间,RSD≤10.3%;无干扰现象出现。该方法可作为水产品及食用油中氟乐灵残留检测的确证方法。 展开更多
关键词 分散型固相萃取 气相色谱-负化学离子源质谱联用 选择离子监测 氟乐灵 水产品 食用油 disperse solid phase extraction( DSPE) gas chromatography-negative chemical ionization mass SPECTROMETRY ( GC-MS NCI ) selected ion monitoring ( SIM )
在线阅读 下载PDF
分散液液微萃取-反相液液微萃取-扫集-胶束电动色谱法测定红酒中的3种氯酚类物质 被引量:7
17
作者 孙建芝 贺晖 刘书慧 《色谱》 CAS CSCD 北大核心 2014年第3期256-262,共7页
建立了分散液液微萃取(DLLME)-反相液液微萃取(RP-LLME)-扫集-胶束电动色谱富集模型,并用于红酒中五氯酚(PCP)、2,4,6-三氯酚(TCP)和2,4-二氯酚(DCP)3种氯酚的测定。实验考察了两步微萃取的萃取参数对氯酚萃取率的影响和... 建立了分散液液微萃取(DLLME)-反相液液微萃取(RP-LLME)-扫集-胶束电动色谱富集模型,并用于红酒中五氯酚(PCP)、2,4,6-三氯酚(TCP)和2,4-二氯酚(DCP)3种氯酚的测定。实验考察了两步微萃取的萃取参数对氯酚萃取率的影响和样品分离富集的电泳条件。最佳萃取条件 DLLME 为:3.5 mL 红酒( pH 3.0,120 g / L NaCl),300μL 正己烷(萃取剂);RP-LLME 为:25μL 0.16 mol / L NaOH(萃取剂)。最佳电泳条件:25 mmol / L NaH2 PO4,100 mmol / L 十二烷基硫酸钠( SDS),30%( v / v)乙腈,pH 2.3;分离电压-15 kV;样品基质为80 mmol / L NaH2 PO4;压力进样20 s×20.67 kPa(3 psi)。PCP 和 TCP 的线性范围为0.5~100μg / L( r≥0.9910), DCP 的线性范围为1.5~80μg / L(r =0.9851)。3种分析物的检出限( S / N =3)为0.035~0.114μg / L,加标回收率为75.2%~104.7%,相对标准偏差≤6.17%。该方法富集倍数高、灵敏度高、重现性好、分析速度快,可为不同样品基质中痕量氯酚污染物及某些弱酸性有机污染物测定提供参考。 展开更多
关键词 分散液液微萃取 反相液液微萃取 扫集 胶束电动色谱 氯酚 红酒 dispersive LIQUID-LIQUID microextraction( DLLME ) reversed phase LIQUID-LIQUID microextraction( RP-LLME ) micellar electrokinetic chromatography ( MEKC ) chlorophenols(CPs)
在线阅读 下载PDF
多层圆柱体锚固结构中超声导波频散特征的研究 被引量:1
18
作者 白雨佳 张昌锁 +2 位作者 牛潘宇 张玥 赵金昌 《计算力学学报》 CAS CSCD 北大核心 2023年第5期773-780,共8页
超声导波无损检测技术因其高效和快捷的优点成为检测锚杆锚固质量的有效方法。但锚固锚杆结构中超声导波的多模态性、频散性与能量泄露导致完整的锚杆底端反射信号的获得具有不确定性。应用弹性动力学理论并采用全局矩阵法建立超声导波... 超声导波无损检测技术因其高效和快捷的优点成为检测锚杆锚固质量的有效方法。但锚固锚杆结构中超声导波的多模态性、频散性与能量泄露导致完整的锚杆底端反射信号的获得具有不确定性。应用弹性动力学理论并采用全局矩阵法建立超声导波在多层圆柱体锚固结构中的频散方程的通用表达式,然后通过非线性外推法和二分法两步算法求解频散方程的精确解,解决了频散曲线的分类和相交等难题,获得了具有自主知识产权的求解多层圆柱体锚固结构频散曲线的程序。利用该程序计算了不同锚固锚杆结构的频散曲线,并与商用软件Disperse计算的结果吻合较好。同时用本程序计算了实验室有限锚固结构中的频散曲线,验证了低频导波在有限与无限结构中的巨大差异,而这一结构特征的频散特性Disperse并未给出相关算例。 展开更多
关键词 无损检测 锚固锚杆 全局矩阵法 超声导波 Disperse软件
在线阅读 下载PDF
工作休假和休假中止的M/G/1排队模型的适定性 被引量:1
19
作者 图尔逊艾力·尼亚孜 艾合买提·阿不来提 《运筹与管理》 CSSCI CSCD 北大核心 2012年第2期106-115,共10页
主要研究工作休假和休假中止的M/G/1排队系统,首先将对应于此系统的数学模型转化为抽象Cauchy问题,其次证明对应于此排队模型的主算子生成正压缩C0半群T(t),然后证明T(t)是局部等距的,最后证明此模型存在唯一的非负时间依赖解。
关键词 工作休假和休假中止的M/G/1排队系统 C0半群 dispersive算子 局部等距算子
在线阅读 下载PDF
附有不可靠服务台和无等待能力的M/G/1/1排队模型时间依赖解的渐近性分析(英文) 被引量:2
20
作者 阿力木·米吉提 《应用数学》 CSCD 北大核心 2018年第1期60-78,共19页
本文研究附有不可靠服务台和无等待能力的M/G/1/1排队模型时间依赖解的渐近行为.首先利用强连续算子半群理论证明此排队系统模型正时间依赖解的存在唯一性.然后通过研究该模型相应主算子的谱,分别得到0是其主算子及其共轭算子的几何重数... 本文研究附有不可靠服务台和无等待能力的M/G/1/1排队模型时间依赖解的渐近行为.首先利用强连续算子半群理论证明此排队系统模型正时间依赖解的存在唯一性.然后通过研究该模型相应主算子的谱,分别得到0是其主算子及其共轭算子的几何重数为1的特征值与虚轴上除了0外其他所有点都属于该模型主算子的豫解集.最后将上述结果结合在一起推出该模型的时间依赖解强收敛于其稳态解. 展开更多
关键词 C0-半群 dispersive算子 特征值 几何重数 豫解集
在线阅读 下载PDF
上一页 1 2 5 下一页 到第
使用帮助 返回顶部