Metal-organic framework(MOF)nanostructures have emerged as a prominent class of materials in the advancement of electrochemical sensors.The rational design of bimetallic MOF-functionalized microelectrode is of importa...Metal-organic framework(MOF)nanostructures have emerged as a prominent class of materials in the advancement of electrochemical sensors.The rational design of bimetallic MOF-functionalized microelectrode is of importance for improv-ing the electrochemical performance but still in great challenge.In this work,the bimetallic FeCo-MOF nanostructures were assembled onto a gold disk ultramicroelectrode(Au UME,5.2μm in diameter)via an in-situ electrodeposition method,which enhanced the sensitive detection of epinephrine(EP).The in-situ electrodeposited FeCo-MOF exhibited a character-istic nanoflower-like morphology and was uniformly dispersed on the Au UME.The FeCo-MOF/Au UME demonstrated excellent electrochemical performance on the detection of EP with a high sensitivity of 36.93μA·μmol^(-1)·L·cm^(-2)and a low detection limit of 1.28μmol·L^(-1).It can be attributed to the nonlinear diffusion of EP onto the ultra-micro working substrate,coupled with synergistical catalytic activity of the bimetallic Fe,Co within MOF structure.Furthermore,the FeCo-MOF/Au UME has been successful applied to the analysis of EP in human serum samples,yielding high recovery rates.These results not only contribute to the expansion of the research area of electrochemical sensors,but also provide novel insights and directions into the development of high-performance MOF-based electrochemical sensors.展开更多
A detailed analysis of mode II stress intensity factors(SIFs) for the double edge cracked Brazilian disk subjected to different diametral compression is presented using a weight function method. The mode II SIFs at cr...A detailed analysis of mode II stress intensity factors(SIFs) for the double edge cracked Brazilian disk subjected to different diametral compression is presented using a weight function method. The mode II SIFs at crack tips can be obtained by simply calculating an integral of the product of mode II weight function and the shear stress on the prospective crack faces of uncracked disk loaded by a diametral compression. A semi-analytical formula for the calculation of normalized mode II SIF, f _Ⅱ, is derived for different crack lengths (from 0.1 to 0.7) and inclination angles (from 10° to 75°) with respect to loading direction. Comparison between the obtained results and finite element method solutions shows that the weight function method is of high precision. Combined with the authors previous work on mode I fracture analysis, the new specimen geometry can be used to study fracture through any combination of mode I and mode II loading by a simple alignment of the crack relative to the diameter of compression loading, and to obtain pure mode II crack extension. Another advantage of this specimen geometry is that it is available directly from rock core and is also easy to fabricate.展开更多
In order to describe and control the stress distribution and total deformation of bladed disk assemblies used in the aeroengine, a highly efficient and precise method of probabilistic analysis which is called extremum...In order to describe and control the stress distribution and total deformation of bladed disk assemblies used in the aeroengine, a highly efficient and precise method of probabilistic analysis which is called extremum response surface method(ERSM) is produced based on the previous deterministic analysis results with the finite element model(FEM). In this work, many key nonlinear factors, such as the dynamic feature of the temperature load, the centrifugal force and the boundary conditions, are taken into consideration for the model. The changing patterns with time of bladed disk assemblies about stress distribution and total deformation are obtained during the deterministic analysis, and at the same time, the largest deformation and stress nodes of bladed disk assemblies are found and taken as input target of probabilistic analysis in a scientific and reasonable way. Not only their reliability, historical sample, extreme response surface(ERS) and the cumulative probability distribution function but also their sensitivity and effect probability are obtained. Main factors affecting stress distribution and total deformation of bladed disk assemblies are investigated through the sensitivity analysis of the model. Finally, compared with the response surface method(RSM) and the Monte Carlo simulation(MCS), the results show that this new approach is effective.展开更多
A new specimen geometry-the double edge-cracked Brazilian disk and a relevant fracture analysis byweight function method are proposed for the investigation of rock fracture caused by compression-shear loading. Notonly...A new specimen geometry-the double edge-cracked Brazilian disk and a relevant fracture analysis byweight function method are proposed for the investigation of rock fracture caused by compression-shear loading. Notonly can the mixed mode fracture with any ratio of KⅠ/KⅡ be achieved, but also the pure mode Ⅱ crack extensioncan be obtained. The combined mode fracture analysis for this geometry shows that diametral compression in the far-field can induce a compression-shear stress state in the singular stress field ahead of crack tips. Experimental investi-gations conducted on marble specimens show that the pure mode Ⅱ crack extension can be obtained when the dimen-sionless crack length a＞0.7 and the inclined crack angle 5°≤ψ≤40°. Normalized mode Ⅰ and mode Ⅱ stress inten-sity factors decrease from -0.45 and 2.47 at ψ=5° to -1.65 and 1.52 at ψ=40°, respectively. The strains at threepoints of specimen are also measured in order to investigate the influence of stress singularity on initial crack exten-sion. The results show that the principal orientations of strain at three points are very stable in the loading process.The derived formulae are quite explicit, and the specimen geometry is easy to fabricate and convenient to achieve thepure mode Ⅱ crack extension. Therefore, it can hopefully be used to obtain mode Ⅱ fracture toughness of rock.展开更多
This paper introduces some final results of some key technologies in magnetic disk drives. We dicuss the design and experiment of thin film head, magnetic fluid exclusion seal system, head disk interface and the engin...This paper introduces some final results of some key technologies in magnetic disk drives. We dicuss the design and experiment of thin film head, magnetic fluid exclusion seal system, head disk interface and the engineering appilcations of these technologies in magnetic disk drives.展开更多
The center cracked Brazilian disk subjected to diametral compressive stress uniformly distributed along parts of its cylindrical surface is used to investigate combined mode fracture of brittle material. A fracture a...The center cracked Brazilian disk subjected to diametral compressive stress uniformly distributed along parts of its cylindrical surface is used to investigate combined mode fracture of brittle material. A fracture analysis is made of this specimen configuration. Explicit formulae for mode Ⅰ and mode Ⅱ stress intensity factor calculation are derived based on boundary integral equation method and related numerical solution given by Atkinson. The proposed formulae are valid in wide range of crack length a/R . This configuration can avoid splitting along load line usually occuring in Brazilian test and permit one to achieve easily pure mode Ⅱ crack growth (crack coplanar extension) and any combination of K Ⅰ and K Ⅱ by a simple alignment of crack orientation with respect to load line. SIF values from the present calculation and finite element solution are also given for comparison.展开更多
The steady, laminar, incompressible and two dimensional micropolar flow between two porous disks was investigated using optimal homotopy asymptotic method(OHAM) and fourth order Runge–Kutta numerical method. Comparis...The steady, laminar, incompressible and two dimensional micropolar flow between two porous disks was investigated using optimal homotopy asymptotic method(OHAM) and fourth order Runge–Kutta numerical method. Comparison between OHAM and numerical method shows that OHAM is an exact and high efficient method for solving these kinds of problems. The results are presented to study the velocity and rotation profiles for different physical parameters such as Reynolds number, vortex viscosity parameter, spin gradient viscosity and microinertia density parameter. As an important outcome, the magnitude of the microrotation increases with an increase in the values of injection velocity while it decreases by increasing the values of suction velocity.展开更多
Aimed at the difficulty in revealing the vibration localization mechanism of mistuned bladed disks by using simple non-linear model,a mechanical model of the bladed disk with random mistuning of hysteretic dry frictio...Aimed at the difficulty in revealing the vibration localization mechanism of mistuned bladed disks by using simple non-linear model,a mechanical model of the bladed disk with random mistuning of hysteretic dry friction damping was established.Then,the incremental harmonic balance method was used to analyze the effects of the parameters of bladed disks,such as the mistuning strength of dry friction force,coupled strength,viscous damping ratio and friction strength,on the forced response of the bladed disks.The results show that the vibrational energy localization phenomenon turns up in the tuned bladed disks if the nonlinear friction damping exists,and the random mistuning of the dry friction force intensifies this kind of vibration localization.展开更多
Copolymer of acrylic acid and maleic acid(PMA)was used to remove Hg^2+from aqueous solution by complexation-ultrafiltration(C-UF)through rotating disk membrane(RDM).The effects of P/M(mass ratio of PMA to metal ions),...Copolymer of acrylic acid and maleic acid(PMA)was used to remove Hg^2+from aqueous solution by complexation-ultrafiltration(C-UF)through rotating disk membrane(RDM).The effects of P/M(mass ratio of PMA to metal ions),pH and rotation speed(N)on the interception of Hg^2+were investigated.The interception could reach 99.7%at pH 7.0,P/M 6 and N less than 1890 r/min.The shear stability of PMA-Hg complex was studied by RDM.The critical rotation speed,at which the interception starts to decrease,was 1890 r/min,and the critical shear rate,the smallest shear rate at which PMA-Hg complex begins to dissociate,was 2.50×10^5s^-1 at pH 7.0.Furthermore,the critical radii were obtained at different rotation speeds and pHs.The results showed that the critical radius decreased with the rotation speed and increased with pH.Shear induced dissociation coupling with ultra?ltration(SID-UF)was efficiently used to recover Hg^2+and PMA.展开更多
基金support from the National Key Research and Development Program of China(2021YFB3201400,2021YFB3201401,2020YFC1908602)the National Natural Science Foundation of China(21904001 and 61774159)+1 种基金the Anhui Provincial Natural Science Foundation(2008085QF288)the Scientific Research Foundation for the Returned Overseas Chinese Scholars,Anhui Province(2020LCX032).
文摘Metal-organic framework(MOF)nanostructures have emerged as a prominent class of materials in the advancement of electrochemical sensors.The rational design of bimetallic MOF-functionalized microelectrode is of importance for improv-ing the electrochemical performance but still in great challenge.In this work,the bimetallic FeCo-MOF nanostructures were assembled onto a gold disk ultramicroelectrode(Au UME,5.2μm in diameter)via an in-situ electrodeposition method,which enhanced the sensitive detection of epinephrine(EP).The in-situ electrodeposited FeCo-MOF exhibited a character-istic nanoflower-like morphology and was uniformly dispersed on the Au UME.The FeCo-MOF/Au UME demonstrated excellent electrochemical performance on the detection of EP with a high sensitivity of 36.93μA·μmol^(-1)·L·cm^(-2)and a low detection limit of 1.28μmol·L^(-1).It can be attributed to the nonlinear diffusion of EP onto the ultra-micro working substrate,coupled with synergistical catalytic activity of the bimetallic Fe,Co within MOF structure.Furthermore,the FeCo-MOF/Au UME has been successful applied to the analysis of EP in human serum samples,yielding high recovery rates.These results not only contribute to the expansion of the research area of electrochemical sensors,but also provide novel insights and directions into the development of high-performance MOF-based electrochemical sensors.
文摘A detailed analysis of mode II stress intensity factors(SIFs) for the double edge cracked Brazilian disk subjected to different diametral compression is presented using a weight function method. The mode II SIFs at crack tips can be obtained by simply calculating an integral of the product of mode II weight function and the shear stress on the prospective crack faces of uncracked disk loaded by a diametral compression. A semi-analytical formula for the calculation of normalized mode II SIF, f _Ⅱ, is derived for different crack lengths (from 0.1 to 0.7) and inclination angles (from 10° to 75°) with respect to loading direction. Comparison between the obtained results and finite element method solutions shows that the weight function method is of high precision. Combined with the authors previous work on mode I fracture analysis, the new specimen geometry can be used to study fracture through any combination of mode I and mode II loading by a simple alignment of the crack relative to the diameter of compression loading, and to obtain pure mode II crack extension. Another advantage of this specimen geometry is that it is available directly from rock core and is also easy to fabricate.
基金Projects(51375032,51175017,51245027)supported by the National Natural Science Foundation of China
文摘In order to describe and control the stress distribution and total deformation of bladed disk assemblies used in the aeroengine, a highly efficient and precise method of probabilistic analysis which is called extremum response surface method(ERSM) is produced based on the previous deterministic analysis results with the finite element model(FEM). In this work, many key nonlinear factors, such as the dynamic feature of the temperature load, the centrifugal force and the boundary conditions, are taken into consideration for the model. The changing patterns with time of bladed disk assemblies about stress distribution and total deformation are obtained during the deterministic analysis, and at the same time, the largest deformation and stress nodes of bladed disk assemblies are found and taken as input target of probabilistic analysis in a scientific and reasonable way. Not only their reliability, historical sample, extreme response surface(ERS) and the cumulative probability distribution function but also their sensitivity and effect probability are obtained. Main factors affecting stress distribution and total deformation of bladed disk assemblies are investigated through the sensitivity analysis of the model. Finally, compared with the response surface method(RSM) and the Monte Carlo simulation(MCS), the results show that this new approach is effective.
基金Project (50274074) supported by the National Natural Science Foundation of China
文摘A new specimen geometry-the double edge-cracked Brazilian disk and a relevant fracture analysis byweight function method are proposed for the investigation of rock fracture caused by compression-shear loading. Notonly can the mixed mode fracture with any ratio of KⅠ/KⅡ be achieved, but also the pure mode Ⅱ crack extensioncan be obtained. The combined mode fracture analysis for this geometry shows that diametral compression in the far-field can induce a compression-shear stress state in the singular stress field ahead of crack tips. Experimental investi-gations conducted on marble specimens show that the pure mode Ⅱ crack extension can be obtained when the dimen-sionless crack length a＞0.7 and the inclined crack angle 5°≤ψ≤40°. Normalized mode Ⅰ and mode Ⅱ stress inten-sity factors decrease from -0.45 and 2.47 at ψ=5° to -1.65 and 1.52 at ψ=40°, respectively. The strains at threepoints of specimen are also measured in order to investigate the influence of stress singularity on initial crack exten-sion. The results show that the principal orientations of strain at three points are very stable in the loading process.The derived formulae are quite explicit, and the specimen geometry is easy to fabricate and convenient to achieve thepure mode Ⅱ crack extension. Therefore, it can hopefully be used to obtain mode Ⅱ fracture toughness of rock.
文摘This paper introduces some final results of some key technologies in magnetic disk drives. We dicuss the design and experiment of thin film head, magnetic fluid exclusion seal system, head disk interface and the engineering appilcations of these technologies in magnetic disk drives.
文摘The center cracked Brazilian disk subjected to diametral compressive stress uniformly distributed along parts of its cylindrical surface is used to investigate combined mode fracture of brittle material. A fracture analysis is made of this specimen configuration. Explicit formulae for mode Ⅰ and mode Ⅱ stress intensity factor calculation are derived based on boundary integral equation method and related numerical solution given by Atkinson. The proposed formulae are valid in wide range of crack length a/R . This configuration can avoid splitting along load line usually occuring in Brazilian test and permit one to achieve easily pure mode Ⅱ crack growth (crack coplanar extension) and any combination of K Ⅰ and K Ⅱ by a simple alignment of crack orientation with respect to load line. SIF values from the present calculation and finite element solution are also given for comparison.
文摘The steady, laminar, incompressible and two dimensional micropolar flow between two porous disks was investigated using optimal homotopy asymptotic method(OHAM) and fourth order Runge–Kutta numerical method. Comparison between OHAM and numerical method shows that OHAM is an exact and high efficient method for solving these kinds of problems. The results are presented to study the velocity and rotation profiles for different physical parameters such as Reynolds number, vortex viscosity parameter, spin gradient viscosity and microinertia density parameter. As an important outcome, the magnitude of the microrotation increases with an increase in the values of injection velocity while it decreases by increasing the values of suction velocity.
基金Project(2007CB707706) supported by the National Basic Research Program of China
文摘Aimed at the difficulty in revealing the vibration localization mechanism of mistuned bladed disks by using simple non-linear model,a mechanical model of the bladed disk with random mistuning of hysteretic dry friction damping was established.Then,the incremental harmonic balance method was used to analyze the effects of the parameters of bladed disks,such as the mistuning strength of dry friction force,coupled strength,viscous damping ratio and friction strength,on the forced response of the bladed disks.The results show that the vibrational energy localization phenomenon turns up in the tuned bladed disks if the nonlinear friction damping exists,and the random mistuning of the dry friction force intensifies this kind of vibration localization.
基金Project(21476265)supported by the National Natural Science Foundation of China。
文摘Copolymer of acrylic acid and maleic acid(PMA)was used to remove Hg^2+from aqueous solution by complexation-ultrafiltration(C-UF)through rotating disk membrane(RDM).The effects of P/M(mass ratio of PMA to metal ions),pH and rotation speed(N)on the interception of Hg^2+were investigated.The interception could reach 99.7%at pH 7.0,P/M 6 and N less than 1890 r/min.The shear stability of PMA-Hg complex was studied by RDM.The critical rotation speed,at which the interception starts to decrease,was 1890 r/min,and the critical shear rate,the smallest shear rate at which PMA-Hg complex begins to dissociate,was 2.50×10^5s^-1 at pH 7.0.Furthermore,the critical radii were obtained at different rotation speeds and pHs.The results showed that the critical radius decreased with the rotation speed and increased with pH.Shear induced dissociation coupling with ultra?ltration(SID-UF)was efficiently used to recover Hg^2+and PMA.
