Chemical solvents instead of pure water being as hydraulic fracturing fluid could effectively increase permeability and improve clean methane extraction efficiency.However,pore-fracture variation features of lean coal...Chemical solvents instead of pure water being as hydraulic fracturing fluid could effectively increase permeability and improve clean methane extraction efficiency.However,pore-fracture variation features of lean coal synergistically affected by solvents have not been fully understood.Ultrasonic testing,nuclear magnetic resonance analysis,liquid phase mass spectrometry was adopted to comprehensively analyze pore-fracture change characteristics of lean coal treated by combined solvent(NMP and CS_(2)).Meanwhile,quantitative characterization of above changing properties was conducted using geometric fractal theory.Relationship model between permeability,fractal dimension and porosity were established.Results indicate that the end face fractures of coal are well developed after CS2and combined solvent treatments,of which,end face box-counting fractal dimensions range from 1.1227 to 1.4767.Maximum decreases in ultrasonic longitudinal wave velocity of coal affected by NMP,CS_(2)and combined solvent are 2.700%,20.521%,22.454%,respectively.Solvent treatments could lead to increasing amount of both mesopores and macropores.Decrease ratio of fractal dimension Dsis 0.259%–2.159%,while permeability increases ratio of NMR ranges from 0.1904 to 6.4486.Meanwhile,combined solvent could dissolve coal polar and non-polar small molecules and expand flow space.Results could provide reference for solvent selection and parameter optimization of permeability-enhancement technology.展开更多
Hydraulic slotting can induce drill spray in a gassy,low permeability coal seam.This then influences subsequent gas extraction.This paper describes the drill spray phenomenon from a mechanical perspective and analyzes...Hydraulic slotting can induce drill spray in a gassy,low permeability coal seam.This then influences subsequent gas extraction.This paper describes the drill spray phenomenon from a mechanical perspective and analyzes the effects of water jet damage during slotting.A simulation of the stresses around the drill hole and slot was prepared using FLAC-3D code.It helps explain the induction of drill spray during hydraulic slotting.The stress concentration around the bore increases as the diameter of the hole increases.As the hole enlarges the variation in stress also increases,which introduces an instability into the coal.This allows easy breaking and removal of the coal.Destruction of the coal structure by the water jet is the major factor causing drill spray.Energy stored as either strain or gas pressure is released by the water jet and this causes the coal to fracture and be expelled from the hole.Field tests showed the effect on gas extraction after slotting with drill spray.The concentration of gas increases after drilling.Compared to conventional techniques,the hydraulic slotted bore gives a gas concentration three times higher and has an effective range twice as far.This makes the gas extraction process more efficient and allows reduced construction effort.展开更多
In order to solve the problems of top-coal inadequate destruction and large amounts of gas emission in mining extra thick and hard coal seam,this study investigated the pre-splitting for deep borehole blasting and gas...In order to solve the problems of top-coal inadequate destruction and large amounts of gas emission in mining extra thick and hard coal seam,this study investigated the pre-splitting for deep borehole blasting and gas pre-draining technologies on top coal.The mechanism of the technologies was systematically expounded based on hard top-coal cracks development obtained by numerical simulation and theoretical analysis.The results show that explosive blasting in the hard rock results in a large number of cracks and large displacement in the rock mass due to the effect of explosion stress.Meanwhile,the thick top-coal caves,and desorbing gas flows along the cracks improve gas extraction.Finally,the pre-splitting for deep borehole blasting and gas pre-draining technologies was applied in No.3802 working face of Shui Liandong Coal Mine,which increases monthly output in the face to 67.34 kt and the drained gas concentration to 86.2%.The drained gas average concentration from each borehole reaches 40%,and the effect is remarkable.展开更多
The analysis of the coupling mechanism of thermal-hydraulic-mechanical(THM)fields,and solid-liquidgas(SLG)phases during gas extraction process is of profound significance to explore its numerical application in the ga...The analysis of the coupling mechanism of thermal-hydraulic-mechanical(THM)fields,and solid-liquidgas(SLG)phases during gas extraction process is of profound significance to explore its numerical application in the gas occurrence regularity and its effective extraction radius.In this study,the Hudi coal mine in Qinshui basin is taken as the research area,the influencing factors of gas occurrence were analyzed,the differences in overburden load for gas pressure distribution and the factors influencing the effective extraction radius were further discussed by using the COMSOL software.The results show that the derivation of mathematical model in gas extraction shows that the process is a process the THM fields restrict each other,and the SLG phases influence each other.The longer the extraction time,the larger the influencing range of borehole,and the better the extraction effect.The larger the diameter of borehole,the larger the effective extraction radius,and the influence on gas extraction effect is smaller in the early stage and larger in the late stage.The borehole arrangement should be flexibly arranged according to the actual extraction situation.The higher the porosity,the higher the permeability,the better the gas extraction effect.The larger the overburden load of reservoir,the stronger the effective stress,which will result in the more severe the strain,and the closure of pore and fracture,which in turn will lead to the decrease of permeability and slow down the gas extraction.The relationship among extraction time,borehole diameter,negative pressure of gas extraction,permeability with effective extraction radius is exponential.This study has important theoretical and practical significance for clarifying and summarizing the gas occurrence regularity and its engineering practice.展开更多
To ensure the mining safety of working face in the protective seam and meanwhile extract pressure-relief gas of the lower protected seam and eliminate its outburst risk,the present study researched into fracture devel...To ensure the mining safety of working face in the protective seam and meanwhile extract pressure-relief gas of the lower protected seam and eliminate its outburst risk,the present study researched into fracture development of floor coal-rock mass of the protective seam and migration rule of pressure-relief gas from a protected seam so as to obtain an effective pressure- relief gas extraction method.The results show that after the upper protective seam was mined,mining-induced fracturing floor coal-rock mas...展开更多
A convenient,cost-effective and fast method using dynamic microwave-assisted extraction and liquid phase microextraction based on the solidification of a floating drop was proposed to analyze organochlorine pesticides...A convenient,cost-effective and fast method using dynamic microwave-assisted extraction and liquid phase microextraction based on the solidification of a floating drop was proposed to analyze organochlorine pesticides in grains including rice,maize and millet.Twelve samples can be processed simultaneously in the method.During the extraction process,10%acetonitrile-water solutions containing 110μL of n-hexadecane were used to extract organochlorine pesticides.Subsequently,1.0 g sodium chloride was placed in the extract,and then centrifuged and cooled.The n-hexadecane drops containing the analytes were solidifi ed and transferred for determination by gas chromatography-electron capture detector without any further filtration or cleaning process.Limits of detection for organochlorine pesticides were 0.97–1.01μg/kg and the RSDs were in the range of 2.6%–8.5%.The developed technology has succeeded in analyzing six real grains samples and the recoveries of the organochlorine pesticides were 72.2%–94.3%.Compared with the published extraction methods,the developed method was used to analyze organochlorine pesticides in grains,being more environmentally friendly,which is suitable for the daily determination of organochlorine pesticides.展开更多
采用顶空固相微萃取(headspace solid-phase microextraction,HS-SPME)和液液萃取(liquid-liquid extraction,LLE)结合全二维气相色谱飞行时间质谱(comprehensive two-dimensional gas chromatography time of flight mass spectrometry...采用顶空固相微萃取(headspace solid-phase microextraction,HS-SPME)和液液萃取(liquid-liquid extraction,LLE)结合全二维气相色谱飞行时间质谱(comprehensive two-dimensional gas chromatography time of flight mass spectrometry,GC×GC-TOF-MS)以及香气活度值(odour active value,OAV),对红星二锅头白酒的挥发性成分进行全面解析。研究发现,HS-SPME、LLE分别定性出928、802种挥发性化合物,共计定性出1304种挥发性化合物,共同定性出426种挥发性化合物。基于HS-SPME数据,通过香气数据库筛选出具有香气特征的382种香气化合物,其中酯类相对百分含量占比最高,其次是醇类、酸类和醛类。计算得到了49种香气化合物OAV>1,其中酯类(辛酸乙酯、异戊酸乙酯等)和萜烯类(β-大马酮)对白酒风味的贡献最大,醛类(异戊醛、己醛等)和含硫类(二甲基三硫)其次,醇类(1-辛烯-3-醇)和含氮类(2,3,5-三甲基吡嗪)也有一定风味贡献。该研究丰富了红星二锅头白酒的风味研究,也为下一步生产研究及调控提供了理论和数据支撑。展开更多
To improve the gas extraction efficiency of single seam with high gas and low air permeability,we developed the"fracturing-sealing"integration technology,and carried out the engineering experiment in the3305...To improve the gas extraction efficiency of single seam with high gas and low air permeability,we developed the"fracturing-sealing"integration technology,and carried out the engineering experiment in the3305 Tunliu mine.In the experiment,coal seams can achieve the aim of antireflection effect through the following process:First,project main cracks with the high energy pulse jet.Second,break the coal body by delaying the propellant blasting.Next,destroy the dense structure of the hard coal body,and form loose slit rings around the holes.Finally,seal the boreholes with the"strong-weak-strong"pressurized sealing technology.The results are as follows:The average concentration of gas extraction increases from8.3%to 39.5%.The average discharge of gas extraction increases from 0.02 to 0.10 m^3/min.The tunneling speeds up from 49.5 to 130 m/month.And the permeability of coal seams improves nearly tenfold.Under the same conditions,the technology is much more efficient in depressurization and antireflection than common methods.In other words,it will provide a more effective way for the gas extraction of single seam with high gas and low air permeability.展开更多
Concerns about China’s energy security have escalated because of the country’s high dependency on oil and gas imports, so it is necessary to calculate the availability of domestic oil and gas resources and China’s ...Concerns about China’s energy security have escalated because of the country’s high dependency on oil and gas imports, so it is necessary to calculate the availability of domestic oil and gas resources and China’s ability to obtain foreign energy through trade. In this work,the calculation was done by using the energy return on investment（EROI） method. The results showed that the EROIstnd（i.e., standard EROI） of China’s oil and gas extraction decreased from approximately 17.3：1 in 1986 to 8.4：1 in 2003, but it increased to 12.2：1 in 2013. From a company-level perspective, the EROIstnddiffered for different companies and was in the range of（8–12）：1. The EROI2,d（EROI considering energy outputs after processed and direct energy inputs） for different companies was in the range of（3–7）：1. The EROI of imported oil（EROIIO）declined from 14.8：1 in 1998 to approximately 4.8：1 in 2014, and the EROI of imported natural gas（EROIING）declined from 16.7：1 in 2009 to 8.6：1 in 2014. In 2015, the EROIIO and EROIING showed a slight increase due to decreasing import prices. In general, this paper suggests that from a net energy perspective, it has become more difficult for China to obtain oil and gas from both domestic production and imports. China is experiencing an EROI decline, which demonstrates the risk in the use of unsustainable fossil resources.展开更多
This paper takes Zhaozhuang mine in Shanxi province as an example to study the technology of hydraulic reaming drill hole for improving the gas extraction.The influence of the physical properties of coal seam on the h...This paper takes Zhaozhuang mine in Shanxi province as an example to study the technology of hydraulic reaming drill hole for improving the gas extraction.The influence of the physical properties of coal seam on the hydraulic reaming drill holes and the draining of coal mine gas were analyzed and discussed for different coal structure areas,and the following conclusions were made.Hydraulic drill hole reaming has had a positive impact in Zhaozhuang Mine,and can improve the efficiency of gas extraction to different degrees.The water jet pressure used in hydraulic drill hole reaming mainly depends on the structure of the coal.When the coal seam basically becomes integrated,the critical water jet pressure increases,the discharge becomes relatively easy to achieve,the blocking effect on the gas extraction decreases,and the gas extraction significantly increases after the reaming process.When the coal seam is broken,the critical water jet pressure decreases,the discharge becomes difficult to achieve,the blocking effect on the gas extraction becomes obvious,and the gas extraction changes slightly after reaming.展开更多
To achieve safe and highly efficient mining in the gassy, deep mines of the Huainan collieries simultaneous coal and gas extraction, and the corresponding ventilation methods were developed. This includes a set of min...To achieve safe and highly efficient mining in the gassy, deep mines of the Huainan collieries simultaneous coal and gas extraction, and the corresponding ventilation methods were developed. This includes a set of mining procedures and principles which help insure safe and efficient production. Furthermore, green mining, meaning the comprehensive use of emitted gas, proper treatment of the environment and appropriate mine temperature control, is now standard. The concepts of modem mining and the principles of pressure relief are described. Coal-gas simultaneous ex- traction and multi-pressure relief techniques were developed which require a combination of surface and underground gas extraction. The application of Y-ventilation systems, of roadways retained along goafs, of stress control techniques for highly fragile mine roofs and of powerful, automatic and reliable mining equipment contributes to safe operation of modem deep mines. Operating parameters for these techniques are described and the results of their use discussed.展开更多
In the process of unconventional natural gas development practice,the"extreme utilization"concept that focuses on"continuously breaking through the limit of development technology"is gradually form...In the process of unconventional natural gas development practice,the"extreme utilization"concept that focuses on"continuously breaking through the limit of development technology"is gradually formed,and supports the scale benefit exploration of unconventional gas in China.On this basis,the development theory of"extreme utilization"is proposed,its theoretical connotation together with development technologies of unconventional natural gas are clarified.The theoretical connotation is that,aiming at"extreme gas reservoirs","extreme techniques"are utilized to build subsurface connected bodies,expand the discharge area,and enlarge the production range,to obtain the maximum single-well production,extreme recovery,and eventually achieve the"extreme effect"of production.The series of development technologies include micro/nano-scale reservoir evaluation,"sweet spot"prediction,unconventional percolation theory and production capacity evaluation,optimization of grid well pattern,optimal-fast drilling and volume fracturing,and working regulation optimization and"integrated"organizing system.The"extreme utilization"development theory has been successfully applied in the development of unconventional gas reservoirs such as Sulige tight gas,South Sichuan shale gas,and Qinshui coalbed methane.Such practices demonstrate that,the"extreme utilization"development theory has effectively promoted the development of unconventional gas industry in China,and can provide theoretical guidance for effective development of other potential unconventional and difficult-to-recovery resources.展开更多
A GC-MS method for the determination of 27 organochlorine pesticides and 15 Pyrethroid pesticides in animal food is established.The method was based on Gel Permeation chromatography combined with solid-phase extractio...A GC-MS method for the determination of 27 organochlorine pesticides and 15 Pyrethroid pesticides in animal food is established.The method was based on Gel Permeation chromatography combined with solid-phase extraction for sample preparation.Rapid qualitative and quantitative analyses was carried out by gas chromatography-mass spectrometry under the selective-ion monitoring mode.The experimental results showed that the correlation coefficients were better than 0.99,the recoveries for spiked standards were 70%-104%,the relative standard deviations were 2.1%-15.9%.展开更多
The metabolites and metabolic passways of nitrazepam in rat were confirmed.Wistar rats were feed a pill of nitrazepam,24 h urine reactions were collected.After β-Glucuronidase hydrolysis of the urine samples,the frac...The metabolites and metabolic passways of nitrazepam in rat were confirmed.Wistar rats were feed a pill of nitrazepam,24 h urine reactions were collected.After β-Glucuronidase hydrolysis of the urine samples,the fractions were extracted by Oasis HLB3cc solid-phase column and analyzed by gas chromatography-mass spectrometry with DB-35 MS column.7-Acetylaminonitrazepam,7-aminonitrazepam and 2-amino-5-nitrophenylphenylmethanone were identified as nitrazepam metabolites.The results suggested that two metabolic passways for nitrazepam may be operative in rat.The first passway leads to the corresponding 7-aminonimetazepam in which the amino group is subsequently acetylated.The second passway is open the parent compounds rings to 2-amino-5-nitrophenylphenylmethanone.Nitrazepam was metabolized quickly in rats and 7-acetylaminonitrazepam were the main metabolites in urine.展开更多
In this paper,the Illilium verum Hook.f.grow at mountain of Dayao of Jinxiu in Guangxi,Volatile oil was extracted by soxhet method and steam distillation.All the volatile oil was analyzed by GC-MS,the result show the ...In this paper,the Illilium verum Hook.f.grow at mountain of Dayao of Jinxiu in Guangxi,Volatile oil was extracted by soxhet method and steam distillation.All the volatile oil was analyzed by GC-MS,the result show the ingredients and rate of product were change greatly,The major chemical constituents were trans-anethole,estragole and anisaldehyde etc.展开更多
The cellulase was used for extracting the volatile constituents of the Leonurus japonicus Houtt.The effects of the pH,the amounts and the fineness of cellulase were discussed.The average yield obtained was 4.05%.16 ch...The cellulase was used for extracting the volatile constituents of the Leonurus japonicus Houtt.The effects of the pH,the amounts and the fineness of cellulase were discussed.The average yield obtained was 4.05%.16 chemical components were identified by gas chromatography-mass spectrometry (GC-MS)method.The cellulase extraction (CE)method was made a camparison with distillation extraction (DSE)method.展开更多
Labeled polychlorinated dibenzo-p-dioxins and dibenzofurans(PCDD/Fs)were extracted by three different methods,i.e.,soxhlet extraction,hot extraction and accelerated solvent extraction(ASE).The PCDD/Fs were detected by...Labeled polychlorinated dibenzo-p-dioxins and dibenzofurans(PCDD/Fs)were extracted by three different methods,i.e.,soxhlet extraction,hot extraction and accelerated solvent extraction(ASE).The PCDD/Fs were detected by high resolution gas chromatography-high resolution mass spectrometry.Comparisons of the three methods were carried out by recovery of PCDD/Fs,solvent consumption and extraction time.The results showed that all of the method could extract labeled PCDD/Fs efficiently.ASE was a time saving procedure with lowest consumption of solvents compared with the other two methods.展开更多
A rapid pretreatment method of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) in soil and analysis by high resolution gas chromatograph-high resolution mass spectrometry was present.The extraction and a...A rapid pretreatment method of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) in soil and analysis by high resolution gas chromatograph-high resolution mass spectrometry was present.The extraction and alumina clean up of PCDD/Fs in soil was achieved by accelerated solvent extractor.Then the multi-layer silica-gel column was used for further clean up.The whole method has been evaluated on certified reference soil and farm soil.Accuracy and precision of this method was tested with satisfactory results.展开更多
基金financially supported by National Natural Science Foundation of China(No.52274171)Joint National-Local Engineering Research Centre for Safe and Precise Coal Mining Fund(No.EC2023015)+1 种基金Excellent Youth Project of Universities in Anhui Province(No.2023AH030042)Unveiled List of Bidding Projects of Shanxi Province(No.20201101001)。
文摘Chemical solvents instead of pure water being as hydraulic fracturing fluid could effectively increase permeability and improve clean methane extraction efficiency.However,pore-fracture variation features of lean coal synergistically affected by solvents have not been fully understood.Ultrasonic testing,nuclear magnetic resonance analysis,liquid phase mass spectrometry was adopted to comprehensively analyze pore-fracture change characteristics of lean coal treated by combined solvent(NMP and CS_(2)).Meanwhile,quantitative characterization of above changing properties was conducted using geometric fractal theory.Relationship model between permeability,fractal dimension and porosity were established.Results indicate that the end face fractures of coal are well developed after CS2and combined solvent treatments,of which,end face box-counting fractal dimensions range from 1.1227 to 1.4767.Maximum decreases in ultrasonic longitudinal wave velocity of coal affected by NMP,CS_(2)and combined solvent are 2.700%,20.521%,22.454%,respectively.Solvent treatments could lead to increasing amount of both mesopores and macropores.Decrease ratio of fractal dimension Dsis 0.259%–2.159%,while permeability increases ratio of NMR ranges from 0.1904 to 6.4486.Meanwhile,combined solvent could dissolve coal polar and non-polar small molecules and expand flow space.Results could provide reference for solvent selection and parameter optimization of permeability-enhancement technology.
基金support provided by the State Key Basic Research Program of China(No.2011CB201205)the National Natural Science Foundation of China(No.51074161)+3 种基金the National Science and Technology Support Program(No.2012BAK04B07)the project funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions(No.CXZZ12_0958)the Open Foundation project of Hunan Provincial Key Laboratory of Safe Mining Techniques of Coal Mines(201201)support for the field application and tests of the technology
文摘Hydraulic slotting can induce drill spray in a gassy,low permeability coal seam.This then influences subsequent gas extraction.This paper describes the drill spray phenomenon from a mechanical perspective and analyzes the effects of water jet damage during slotting.A simulation of the stresses around the drill hole and slot was prepared using FLAC-3D code.It helps explain the induction of drill spray during hydraulic slotting.The stress concentration around the bore increases as the diameter of the hole increases.As the hole enlarges the variation in stress also increases,which introduces an instability into the coal.This allows easy breaking and removal of the coal.Destruction of the coal structure by the water jet is the major factor causing drill spray.Energy stored as either strain or gas pressure is released by the water jet and this causes the coal to fracture and be expelled from the hole.Field tests showed the effect on gas extraction after slotting with drill spray.The concentration of gas increases after drilling.Compared to conventional techniques,the hydraulic slotted bore gives a gas concentration three times higher and has an effective range twice as far.This makes the gas extraction process more efficient and allows reduced construction effort.
基金financially supported by the National Natural Science Fund of China(Nos.51004003 and 51474009)Anhui Province Education Department Natural Science Fund Key Project of China(No.KJ2010A091)
文摘In order to solve the problems of top-coal inadequate destruction and large amounts of gas emission in mining extra thick and hard coal seam,this study investigated the pre-splitting for deep borehole blasting and gas pre-draining technologies on top coal.The mechanism of the technologies was systematically expounded based on hard top-coal cracks development obtained by numerical simulation and theoretical analysis.The results show that explosive blasting in the hard rock results in a large number of cracks and large displacement in the rock mass due to the effect of explosion stress.Meanwhile,the thick top-coal caves,and desorbing gas flows along the cracks improve gas extraction.Finally,the pre-splitting for deep borehole blasting and gas pre-draining technologies was applied in No.3802 working face of Shui Liandong Coal Mine,which increases monthly output in the face to 67.34 kt and the drained gas concentration to 86.2%.The drained gas average concentration from each borehole reaches 40%,and the effect is remarkable.
基金financially supported by the University Synergy Innovation Program of Anhui Province(No.GXXT-2021-018)the National Natural Science Foundation of China(No.42102217)+3 种基金the Natural Science Research Project of Anhui University(Nos.KJ2020A0315,KJ2020A0317)the Institute of Energy,Hefei Comprehensive National Science Center(No.21KZS218)the Natural Science Foundation of Anhui Province(No.2108085MD134)the Foundation of State Key Laboratory of Petroleum Resources and Prospecting,China University of Petroleum,Beijing(No.PRP/open-2005)
文摘The analysis of the coupling mechanism of thermal-hydraulic-mechanical(THM)fields,and solid-liquidgas(SLG)phases during gas extraction process is of profound significance to explore its numerical application in the gas occurrence regularity and its effective extraction radius.In this study,the Hudi coal mine in Qinshui basin is taken as the research area,the influencing factors of gas occurrence were analyzed,the differences in overburden load for gas pressure distribution and the factors influencing the effective extraction radius were further discussed by using the COMSOL software.The results show that the derivation of mathematical model in gas extraction shows that the process is a process the THM fields restrict each other,and the SLG phases influence each other.The longer the extraction time,the larger the influencing range of borehole,and the better the extraction effect.The larger the diameter of borehole,the larger the effective extraction radius,and the influence on gas extraction effect is smaller in the early stage and larger in the late stage.The borehole arrangement should be flexibly arranged according to the actual extraction situation.The higher the porosity,the higher the permeability,the better the gas extraction effect.The larger the overburden load of reservoir,the stronger the effective stress,which will result in the more severe the strain,and the closure of pore and fracture,which in turn will lead to the decrease of permeability and slow down the gas extraction.The relationship among extraction time,borehole diameter,negative pressure of gas extraction,permeability with effective extraction radius is exponential.This study has important theoretical and practical significance for clarifying and summarizing the gas occurrence regularity and its engineering practice.
基金Funded by the Major State Basic Research Development Program of China(No.2005CB221503)the Key Program of the Natural Science Foundation of China(No.70533050,50904068 and 50674089)
文摘To ensure the mining safety of working face in the protective seam and meanwhile extract pressure-relief gas of the lower protected seam and eliminate its outburst risk,the present study researched into fracture development of floor coal-rock mass of the protective seam and migration rule of pressure-relief gas from a protected seam so as to obtain an effective pressure- relief gas extraction method.The results show that after the upper protective seam was mined,mining-induced fracturing floor coal-rock mas...
基金The study was financially supported by the National Science and Technology Support Program of China(Grant No.2013BAD16B08).
文摘A convenient,cost-effective and fast method using dynamic microwave-assisted extraction and liquid phase microextraction based on the solidification of a floating drop was proposed to analyze organochlorine pesticides in grains including rice,maize and millet.Twelve samples can be processed simultaneously in the method.During the extraction process,10%acetonitrile-water solutions containing 110μL of n-hexadecane were used to extract organochlorine pesticides.Subsequently,1.0 g sodium chloride was placed in the extract,and then centrifuged and cooled.The n-hexadecane drops containing the analytes were solidifi ed and transferred for determination by gas chromatography-electron capture detector without any further filtration or cleaning process.Limits of detection for organochlorine pesticides were 0.97–1.01μg/kg and the RSDs were in the range of 2.6%–8.5%.The developed technology has succeeded in analyzing six real grains samples and the recoveries of the organochlorine pesticides were 72.2%–94.3%.Compared with the published extraction methods,the developed method was used to analyze organochlorine pesticides in grains,being more environmentally friendly,which is suitable for the daily determination of organochlorine pesticides.
文摘采用顶空固相微萃取(headspace solid-phase microextraction,HS-SPME)和液液萃取(liquid-liquid extraction,LLE)结合全二维气相色谱飞行时间质谱(comprehensive two-dimensional gas chromatography time of flight mass spectrometry,GC×GC-TOF-MS)以及香气活度值(odour active value,OAV),对红星二锅头白酒的挥发性成分进行全面解析。研究发现,HS-SPME、LLE分别定性出928、802种挥发性化合物,共计定性出1304种挥发性化合物,共同定性出426种挥发性化合物。基于HS-SPME数据,通过香气数据库筛选出具有香气特征的382种香气化合物,其中酯类相对百分含量占比最高,其次是醇类、酸类和醛类。计算得到了49种香气化合物OAV>1,其中酯类(辛酸乙酯、异戊酸乙酯等)和萜烯类(β-大马酮)对白酒风味的贡献最大,醛类(异戊醛、己醛等)和含硫类(二甲基三硫)其次,醇类(1-辛烯-3-醇)和含氮类(2,3,5-三甲基吡嗪)也有一定风味贡献。该研究丰富了红星二锅头白酒的风味研究,也为下一步生产研究及调控提供了理论和数据支撑。
基金financial support provided by the State Key Basic Research Program of China(No.2011CB201205)the National Natural Science Foundation of China(No.51074161)the National Science and Technology Support Program(No.2012BAK04B07)
文摘To improve the gas extraction efficiency of single seam with high gas and low air permeability,we developed the"fracturing-sealing"integration technology,and carried out the engineering experiment in the3305 Tunliu mine.In the experiment,coal seams can achieve the aim of antireflection effect through the following process:First,project main cracks with the high energy pulse jet.Second,break the coal body by delaying the propellant blasting.Next,destroy the dense structure of the hard coal body,and form loose slit rings around the holes.Finally,seal the boreholes with the"strong-weak-strong"pressurized sealing technology.The results are as follows:The average concentration of gas extraction increases from8.3%to 39.5%.The average discharge of gas extraction increases from 0.02 to 0.10 m^3/min.The tunneling speeds up from 49.5 to 130 m/month.And the permeability of coal seams improves nearly tenfold.Under the same conditions,the technology is much more efficient in depressurization and antireflection than common methods.In other words,it will provide a more effective way for the gas extraction of single seam with high gas and low air permeability.
基金supported by the National Natural Science Foundation of China(No.71273277)the Philosophy and Social Sciences Major Research Project of the Ministry of Education(No.11JZD048)
文摘Concerns about China’s energy security have escalated because of the country’s high dependency on oil and gas imports, so it is necessary to calculate the availability of domestic oil and gas resources and China’s ability to obtain foreign energy through trade. In this work,the calculation was done by using the energy return on investment（EROI） method. The results showed that the EROIstnd（i.e., standard EROI） of China’s oil and gas extraction decreased from approximately 17.3：1 in 1986 to 8.4：1 in 2003, but it increased to 12.2：1 in 2013. From a company-level perspective, the EROIstnddiffered for different companies and was in the range of（8–12）：1. The EROI2,d（EROI considering energy outputs after processed and direct energy inputs） for different companies was in the range of（3–7）：1. The EROI of imported oil（EROIIO）declined from 14.8：1 in 1998 to approximately 4.8：1 in 2014, and the EROI of imported natural gas（EROIING）declined from 16.7：1 in 2009 to 8.6：1 in 2014. In 2015, the EROIIO and EROIING showed a slight increase due to decreasing import prices. In general, this paper suggests that from a net energy perspective, it has become more difficult for China to obtain oil and gas from both domestic production and imports. China is experiencing an EROI decline, which demonstrates the risk in the use of unsustainable fossil resources.
基金the National Natural Science Foundation of China (No. 51404094)Postdoctoral Science Foundation of China (No. 2014M561988)Doctor Funds of Henan Polytechnic University of China (No. B2012-026) for their support with this project
文摘This paper takes Zhaozhuang mine in Shanxi province as an example to study the technology of hydraulic reaming drill hole for improving the gas extraction.The influence of the physical properties of coal seam on the hydraulic reaming drill holes and the draining of coal mine gas were analyzed and discussed for different coal structure areas,and the following conclusions were made.Hydraulic drill hole reaming has had a positive impact in Zhaozhuang Mine,and can improve the efficiency of gas extraction to different degrees.The water jet pressure used in hydraulic drill hole reaming mainly depends on the structure of the coal.When the coal seam basically becomes integrated,the critical water jet pressure increases,the discharge becomes relatively easy to achieve,the blocking effect on the gas extraction decreases,and the gas extraction significantly increases after the reaming process.When the coal seam is broken,the critical water jet pressure decreases,the discharge becomes difficult to achieve,the blocking effect on the gas extraction becomes obvious,and the gas extraction changes slightly after reaming.
基金Projects 2001BA803B04 and 2004BA803B01 supported by the National Key Projects for Tackling Scientific and Technological Problems during the 10thFive-Year Plan
文摘To achieve safe and highly efficient mining in the gassy, deep mines of the Huainan collieries simultaneous coal and gas extraction, and the corresponding ventilation methods were developed. This includes a set of mining procedures and principles which help insure safe and efficient production. Furthermore, green mining, meaning the comprehensive use of emitted gas, proper treatment of the environment and appropriate mine temperature control, is now standard. The concepts of modem mining and the principles of pressure relief are described. Coal-gas simultaneous ex- traction and multi-pressure relief techniques were developed which require a combination of surface and underground gas extraction. The application of Y-ventilation systems, of roadways retained along goafs, of stress control techniques for highly fragile mine roofs and of powerful, automatic and reliable mining equipment contributes to safe operation of modem deep mines. Operating parameters for these techniques are described and the results of their use discussed.
基金Supported by the China National Science and Technology Major Project(2017ZX05035,2016ZX05037)。
文摘In the process of unconventional natural gas development practice,the"extreme utilization"concept that focuses on"continuously breaking through the limit of development technology"is gradually formed,and supports the scale benefit exploration of unconventional gas in China.On this basis,the development theory of"extreme utilization"is proposed,its theoretical connotation together with development technologies of unconventional natural gas are clarified.The theoretical connotation is that,aiming at"extreme gas reservoirs","extreme techniques"are utilized to build subsurface connected bodies,expand the discharge area,and enlarge the production range,to obtain the maximum single-well production,extreme recovery,and eventually achieve the"extreme effect"of production.The series of development technologies include micro/nano-scale reservoir evaluation,"sweet spot"prediction,unconventional percolation theory and production capacity evaluation,optimization of grid well pattern,optimal-fast drilling and volume fracturing,and working regulation optimization and"integrated"organizing system.The"extreme utilization"development theory has been successfully applied in the development of unconventional gas reservoirs such as Sulige tight gas,South Sichuan shale gas,and Qinshui coalbed methane.Such practices demonstrate that,the"extreme utilization"development theory has effectively promoted the development of unconventional gas industry in China,and can provide theoretical guidance for effective development of other potential unconventional and difficult-to-recovery resources.
文摘A GC-MS method for the determination of 27 organochlorine pesticides and 15 Pyrethroid pesticides in animal food is established.The method was based on Gel Permeation chromatography combined with solid-phase extraction for sample preparation.Rapid qualitative and quantitative analyses was carried out by gas chromatography-mass spectrometry under the selective-ion monitoring mode.The experimental results showed that the correlation coefficients were better than 0.99,the recoveries for spiked standards were 70%-104%,the relative standard deviations were 2.1%-15.9%.
文摘The metabolites and metabolic passways of nitrazepam in rat were confirmed.Wistar rats were feed a pill of nitrazepam,24 h urine reactions were collected.After β-Glucuronidase hydrolysis of the urine samples,the fractions were extracted by Oasis HLB3cc solid-phase column and analyzed by gas chromatography-mass spectrometry with DB-35 MS column.7-Acetylaminonitrazepam,7-aminonitrazepam and 2-amino-5-nitrophenylphenylmethanone were identified as nitrazepam metabolites.The results suggested that two metabolic passways for nitrazepam may be operative in rat.The first passway leads to the corresponding 7-aminonimetazepam in which the amino group is subsequently acetylated.The second passway is open the parent compounds rings to 2-amino-5-nitrophenylphenylmethanone.Nitrazepam was metabolized quickly in rats and 7-acetylaminonitrazepam were the main metabolites in urine.
文摘In this paper,the Illilium verum Hook.f.grow at mountain of Dayao of Jinxiu in Guangxi,Volatile oil was extracted by soxhet method and steam distillation.All the volatile oil was analyzed by GC-MS,the result show the ingredients and rate of product were change greatly,The major chemical constituents were trans-anethole,estragole and anisaldehyde etc.
文摘The cellulase was used for extracting the volatile constituents of the Leonurus japonicus Houtt.The effects of the pH,the amounts and the fineness of cellulase were discussed.The average yield obtained was 4.05%.16 chemical components were identified by gas chromatography-mass spectrometry (GC-MS)method.The cellulase extraction (CE)method was made a camparison with distillation extraction (DSE)method.
文摘Labeled polychlorinated dibenzo-p-dioxins and dibenzofurans(PCDD/Fs)were extracted by three different methods,i.e.,soxhlet extraction,hot extraction and accelerated solvent extraction(ASE).The PCDD/Fs were detected by high resolution gas chromatography-high resolution mass spectrometry.Comparisons of the three methods were carried out by recovery of PCDD/Fs,solvent consumption and extraction time.The results showed that all of the method could extract labeled PCDD/Fs efficiently.ASE was a time saving procedure with lowest consumption of solvents compared with the other two methods.
文摘A rapid pretreatment method of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) in soil and analysis by high resolution gas chromatograph-high resolution mass spectrometry was present.The extraction and alumina clean up of PCDD/Fs in soil was achieved by accelerated solvent extractor.Then the multi-layer silica-gel column was used for further clean up.The whole method has been evaluated on certified reference soil and farm soil.Accuracy and precision of this method was tested with satisfactory results.
