Catalytic conversion of synthesis gas （CO＋H2） into hydrocarbons, also known as Fischer-Tropsch （FT） synthesis, is a crucial reaction for the translbrmation of non-petroleum carbon resources such as coal, natural ...Catalytic conversion of synthesis gas （CO＋H2） into hydrocarbons, also known as Fischer-Tropsch （FT） synthesis, is a crucial reaction for the translbrmation of non-petroleum carbon resources such as coal, natural gas, shale gas, coal-bed gas and biogas, as well as biomass into liquid fuels and chemicals. Many factors can influence the catalytic behavior of a FT catalyst. This review highlights recent advances in understanding some key catalyst factors, including the chemical state of active phases, the promoters, the size and the microenvironment of active phase, which determine the CO conversion activity and the product selectivity, particularly the selectivity to C5 ＋ hydrocarbons.展开更多
基金the National Basic Research Program of China(No.2013CB933100)the National Natural Science Foundation of China(No.21173174,No.21161130522,No.21033006and No.20923004)the Program for Changjiang Scholars and Innovative Research Team in University(No.IRT1036)
文摘Catalytic conversion of synthesis gas （CO＋H2） into hydrocarbons, also known as Fischer-Tropsch （FT） synthesis, is a crucial reaction for the translbrmation of non-petroleum carbon resources such as coal, natural gas, shale gas, coal-bed gas and biogas, as well as biomass into liquid fuels and chemicals. Many factors can influence the catalytic behavior of a FT catalyst. This review highlights recent advances in understanding some key catalyst factors, including the chemical state of active phases, the promoters, the size and the microenvironment of active phase, which determine the CO conversion activity and the product selectivity, particularly the selectivity to C5 ＋ hydrocarbons.
