A total of 45 alkylbenzenes were detected and identified in crude oils with different depositional environments and thermal maturities from the Tarim Basin,Beibuwan Basin,and Songliao Basin using comprehensive two-dim...A total of 45 alkylbenzenes were detected and identified in crude oils with different depositional environments and thermal maturities from the Tarim Basin,Beibuwan Basin,and Songliao Basin using comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry(GC×GCTOFMS).By analyzing the distribution characteristics of C0-C5alkylbenzenes,it is found that the content of some alkylbenzenes varies greatly in crude oils.Based on the distribution characteristics of 1,2,4,5-tetramethylbenzene(Te MB)and 1,2,3,4-Te MB,the ratio of 1,2,4,5-Te MB to 1,2,3,4-Te MB is proposed to indicate the organic matter origin and depositional environment of ancient sediments.Oil samples originated mainly from lower hydrobiont,algae,bacteria and source rocks deposited under reducing/anoxic conditions have low 1,2,4,5-/1,2,3,4-Te MB values(less than 0.6),while oil samples originated mainly from terrestrial higher plants and source rocks deposited under oxic/sub-oxic conditions have higher 1,2,4,5-/1,2,3,4-Te MB values(greater than 1.0).The significant difference of 1,2,4,5-/1,2,3,4-Te MB values is controlled by 1,2,4,5-Te MB content.1,2,4,5-Te MB content in oils derived from source rocks deposited in oxidized sedimentary environment(greater than 1.0 mg/g whole oil)is higher than that in oils from source rocks deposited in reduced sedimentary environment(less than 1.0 mg/g whole oil).1,2,4,5-/1,2,3,4-Te MB ratio might not or slightly be affected by evaporative fractionation,biodegradation and thermal maturity.1,2,4,5-/1,2,3,4-Te MB ratio and 1,2,4,5-Te MB content can be used as supplementary parameter for the identification of sedimentary environment and organic matter input.It should be noted that compared to the identification of organic matter sources,the 1,2,4,5-/1,2,3,4-Te MB parameter is more effective in identifying sedimentary environments.展开更多
Molecular biomarker and whole oil carbon isotope(δ^(13)C_(oil)) analyses were conducted on eleven typical crude oils from the Qiongdongnan Basin to investigate their biological sources and depositional environments. ...Molecular biomarker and whole oil carbon isotope(δ^(13)C_(oil)) analyses were conducted on eleven typical crude oils from the Qiongdongnan Basin to investigate their biological sources and depositional environments. Saturated hydrocarbon biomarkers in most samples are characterized by angiosperm-derived compounds, with aromatic compounds dominated by the naphthalene, phenanthrene, biphenyl, and fluorene series. The related source rocks of these oils were mainly deposited under oxic condition, but a subanoxic-suboxic and enclosed water column condition in the Central Depression during Oligocene.The identification of simonellite and related compounds in the aromatic fractions provides reliable evidence for the input of coniferous gymnosperms. Cadalene may also have a potential association with gymnosperms since it shows a strong positive correlation with simonellite. Evidence from density, nalkanes, short-chain alkylbenzenes and secondary brine inclusions indicates that the unique crude oil B13-1 may have suffered from thermal alteration. These crude oils(excluding B13-1) can be classified into four types based on the δ^(13)C_(oil)values and molecular biomarkers. Type A oil(solely S34-3) is characterized by non-angiosperm plants, with minor dinoflagellates and increasing contribution from conifer gymnosperms than others. Type B oils(L17-2, L18-1, L25-1, and L25-1W) show heavy δ^(13)C_(oil)(-24 ‰to-25 ‰) and mixed contributions from both angiosperms and marine algae, with the marine algae contribution increasing. Type C oils(L13-2 and B21-1) share similar biological sources with Type B, but the moderately δ^(13)C_(oil)(-25‰ to-26‰) and high level of terrestrial biomarkers suggesting a predominant contribution of angiosperms. Type D oils(Y13-1a, Y13-1b, and Y13-4) possess the lightestδ^(13)C_(oil)(mainly below-26‰) and are primarily derived from angiosperms, with mangrove vegetation playing an important role. Spearman correlation analysis among 14 source biomarker parameters withδ^(13)C_(oil)and geological setting of related source rocks implied that the marine algae should be responsible for the heavy δ^(13)C_(oil)in the Type B. The contribution of marine algae in the Central Depression may have been neglected in the past, as it is usually covered by remarkable angiosperm biomarkers.展开更多
The mechanisms of lacustrine organic-rich shale formation have attracted attention due to its association with global shale oil and shale gas exploration.Samples of general-quality and excellent-quality source rocks,a...The mechanisms of lacustrine organic-rich shale formation have attracted attention due to its association with global shale oil and shale gas exploration.Samples of general-quality and excellent-quality source rocks,and oil shale from the Beibu Gulf Basin were analyzed to investigate their organic geochemistry,palynofacies,and trace elements.Hydrocarbon potential was higher in the oil shale(29.79 mg/g)than in the general-quality source rock(3.82 mg/g),and its kerogen type wasⅠ-Ⅱ2.Hydrogen-rich liptinite(cutinite and sporinite)components derived from terrigenous higher plants provided most of the hydrocarbon potential of excellent-quality source rock and oil shale.Under the influence of depressioncontrolling fault activity,a deeper subsidence center promotes the deposition of excellent-quality source rock and oil shale in brackish-hypoxic bottom water.A shallower subsidence center,due to subsag-controlling fault activity,promotes the formation of excellent-quality source rock under freshbrackish and weak oxidation-weak reducing conditions.The local uplift and shallow-slope led to the formation of general-quality source rock,under freshwater weak-oxidation conditions.A model was established for organic matter(OM)accumulation in organic-rich shales,accounting for fault activity,terrigenous hydrogen-rich OM,and the preservation conditions,to predict the development of excellent-quality source rock from areas with low levels of exploration.展开更多
Based on the systematic study of aromatic hydrocarbons in over 100 crude oil samples collected from the Tabei and Tazhong uplifts in the Tarim Basin,the western depression area in the Qaidam Basin and the Tabei depres...Based on the systematic study of aromatic hydrocarbons in over 100 crude oil samples collected from the Tabei and Tazhong uplifts in the Tarim Basin,the western depression area in the Qaidam Basin and the Tabei depression in the Turpan Basin,the geochemical characteristics of the marine（Tarim Basin）,saline lacustrine（Qaidam Basin）,and swamp（Turpan Basin） oils were investigated.The marine oils from the Tarim basin are characterized by relatively low abundance of diaromatic hydrocarbons such as biphenyl and naphthalene,and relatively high abundance of triaromatic hydrocarbons including phenanthrene,dibenzothiophene and fluorene.In contrast,the swamp oils from the Turpan Basin are dominated by the highest relative abundance of diaromatic hydrocarbons and the lowest relative abundance of triaromatic hydrocarbons in all the oil samples in this study.The relative abundance of diaromatic and triaromatic hydrocarbons in the saline lacustrine oils from Qaidam Basin is between that in Tarim oils and Turpan oils.Aromatic parameters based on the isomer distributions of dimethylnaphthalenes（DMN）,trimethylnaphthalenes（TMN）,tetramethylnaphthalenes（TeMN） and methylphenanthrenes（MP）,i.e.,1,2,5-trimethylnaphthalene（TMN）/1,3,6-TMN ratio,1,2,7-TMN/1,3,7TMN ratio,（2,6-＋2,7-）-dimethylnaphthalenes（DMN）/1,6-DMN ratio,1,3,7-TMN/（1,2,5-＋1,3,7-）TMN,1,3,6,7-TeMN/（1,3,6,7-＋1,2,5,6-＋1,2,3,5-）-TeMN ratio and MP index,may reflect the diversity of organic source input,thermal maturity and depositional environments.In addition,the dibenzothiophenes（DBTs）/fluorenes（Fs） and dibenzofurans（DBFs）/Fs ratios were found to the very useful and effective in determining genetic types of crude oils for the marine,saline lacustrine,and swamp depositional environments,and for oil-oil correlations.展开更多
Twenty-two oil samples and eight source rock samples collected from the Tarim Basin, NW China were geochemically analyzed to investigate the occurrence and distribution of phenylphenanthrene （PhP）, phenylanthracene ...Twenty-two oil samples and eight source rock samples collected from the Tarim Basin, NW China were geochemically analyzed to investigate the occurrence and distribution of phenylphenanthrene （PhP）, phenylanthracene （PhA）, and binaphthyl （BIN） isomers and methylphenanthrene （MP） isomers in oils and rock extracts with different deposi- tional environments. Phenylphenanthrenes are present in significant abundance in Mesozoic lacustrine mudstones and related oils. The relative concentrations of PhPs are quite low or below detection limit by routine gas chromatogxaphy-mass spectrometry （GC-MS） in Ordovician oils derived from marine carbonates. The ratio of 3-PhP/3-MP was used in this study to describe the relative abundance of phenylphenanthrenes to their alkylated counterparts--methylphenanthrenes. The Ordovician oils in the Tabei Uplift have quite low 3-PhP/3-MP ratios （〈0.10）, indicating their marine carbonate origin, associating with low Pr/Ph ratios （pristane/phytane）, high ADBT/ ADBF values （relative abundance of alkylated dibenzothiophenes to alkylated dibenzofurans）, low C30 diahopane/C3o hopane ratios, and low Ts/（Ts ＋ Tm） （18α-22, 29, 30-trisnorneohopane/（18α-22, 29, 30-trisnorneohopane ＋ 17α-22, 29, 30-trisnorhopane）） values. In contrast, the oils from Mesozoic and Paleogene sandstone reservoirs and related Mesozoic lacustrine mudstones have relatively higher 3-PhP/3-MP ratios （〉0.10）, associating with high Pr/Ph, low ADBT/ ADBF, high Ts/（Ts ＋ Tm）, and C30 diahopane/C30 hopane ratios. Therefore, the occurrence of significant amounts of phenylphenanthrenes in oils typically indicates that the organic matter of the source rocks was deposited in a suboxic envi- ronment with mudstone deposition. The phenylphenanthrenes may be effective molecular markers, indicating depositional environment and lithology of source rocks.展开更多
The organic geochemistry and petrology of source rocks determine the hydrocarbon generation potential of the Banqiao Sag. In this study, organic geochemistry and petrology were used to determine the abundance of organ...The organic geochemistry and petrology of source rocks determine the hydrocarbon generation potential of the Banqiao Sag. In this study, organic geochemistry and petrology were used to determine the abundance of organic matter(OM), OM type, OM maturity, and sedimentary environments of the source rocks, collected from Cenozoic Shahejie Formation, Banqiao Sag, Bohai Bay Basin, China. Vitrinite and liptinite are the main maceral composition of the source rocks, and range from 18% to 81% and from 2% to82% on a mineral matter free(MMF) basis, respectively. The values of vitrinite reflectance(Ro)(0.36%-1.20%) and the Tmaxvalues(397-486.C) show that the thermal maturity range from low mature to peak-maturity. The abundance of OM varies between 0.22% and 4.37%, suggesting that the source rocks of the Shahejie(Es) Formation are mainly fair to good source rocks. The Rock-Eval pyrolysis results show that the source rocks have good petroleum generation potential. The amount of free hydrocarbons(S_1)and hydrocarbons generated from pyrolysis(S_(2)) range within 0.01-3.70 mg/g, and 0.04-29.17 mg/g. The hydrogen index(HI) varies between 18.18 and 741.13 mg HC/g TOC, with most of the samples appearing to be mainly Type II kerogen, and thereby exhibiting the ability to generate both oil and gas. The ratios of Pr/Ph, the cross plot of Pr/nC_(17)-Ph/nC_(18), the cross plot of C_(29)/C_(27)-Pr/Ph, and ternary of dibenzothiophene, dibenzofuran, and fluorene, indicate that the Shahejie Formation deposited in suboxic and weak reducing environments. The main biological source is from advanced plants. The maceral composition and rock pyrolysis data indicate the kerogen type is a humic type or mixed sapropelic-humic type. The source rocks of the Shahejie(Es) Formation occur in the oil window, and the abundant organic richness,humic kerogen demonstrate that these rocks are effective oil and gas source rocks. The mudstone rocks in the Shahejie Formation are the main source of oil and gas and represent the main exploration target for the Banqiao Sag. This study enhances the great prospect of oil and gas production in the Banqiao Sag.展开更多
Based on the analysis of core,logging,and testing data,the fourth member of the Cretaceous Quantou Formation(K_(2)q^(4))in the Sanzhao depression,Songliao Basin,is investigated in order to understand the sedimentary c...Based on the analysis of core,logging,and testing data,the fourth member of the Cretaceous Quantou Formation(K_(2)q^(4))in the Sanzhao depression,Songliao Basin,is investigated in order to understand the sedimentary characteristics and hydrocarbon exploration significance of a retrograding shallow-water delta.The results show that during the sedimentary period of K_(2)q^(4),the Sanzhao depression with a gentle basement experienced stable tectonic subsidence and suffered a long-term lake level rise caused by paleoclimate changes(from semiarid to semihumid),the K_(2)q^(4)in the study area were dominated by a fining-upward deltaic succession and had relatively stable thickness.From the bottom to the top,the color of mudstone gradually changes from purplish-red to gray and grayish-green,the contents of caliche nodules decrease gradually,while the presence of pyrite in sediments becomes frequent.Channel sandstones mainly composed of siltstone and fine sandstone with developed high-energy sedimentary structures constitute the main sand bodies of deltaic deposits,but the scale of channel sandstones decrease upward.Despite the long-term lake level rise and fining-upward sedimentary succession,purplish-red mudstone,caliche nodules and thin channel sandstones are still broadly distributed in the study area,and thin channel sandstones can be found at the top of K_(2)q^(4)covered by the black oil shale of Qingshankou Formation.These assertations suggest that the study area was dominated by retrograding shallow-water delta deposits during the sedimentary period of K_(2)q^(4).In comparison with modern Poyang Lake,we infer that during the sedimentary period of K_(2)q^(4),the study area experienced frequent lake level fluctuations triggered by paleoclimate changes despite the long-term lake level rise,and the lake level fluctuations control the deposition of retrograding shallow-water delta.In addition,most of the thin channel sandstones distributed at the top of K_(2)q^(4)and covered by black oil shale are generally immersed in oil,indicating that the thin channel sandstones formed at the top of a retrograding shallow-water delta sedimentary succession are favorable targets for lithological reservoir exploration.展开更多
In this paper, the hydro-mechanical behavior and physical properties of mature fine tailings(MFT) under atmospheric drying are investigated through a column study. In the study, evaporation takes place in the developm...In this paper, the hydro-mechanical behavior and physical properties of mature fine tailings(MFT) under atmospheric drying are investigated through a column study. In the study, evaporation takes place in the development of suction in the upper parts of the column and increasing suction leads to higher strength in the tailings. After 5 days, the suction in the first lift is around 17 k Pa in the upper part of the column.When a second lift is added, the first lift initially loses strength but over a 30 days' period, the strength is recovered to its prior value and suction in the second lift reaches 500 k Pa. The vane shear strength values show a substantial increase in the strength of the MFT after 30 days under atmospheric drying and drainage. The 90% strength found in the column exceeds the threshold(5 k Pa). The hydraulic-mechanical properties of the deposited tailings are closely coupled due to several mechanisms, such as evaporation,drainage, self-consolidation, suction and crack development. The findings of this study will provide a better understanding of the placement behavior of multiple lifts of MFT and thus contribute to reclamation design standards and reduce the use of dedicated disposal areas.展开更多
基金supported by Doctor’s Scientific Research Initiation Project of Yan’an University(YAU202213093)National Natural Science Foundation of China(Grant No.41503029)。
文摘A total of 45 alkylbenzenes were detected and identified in crude oils with different depositional environments and thermal maturities from the Tarim Basin,Beibuwan Basin,and Songliao Basin using comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry(GC×GCTOFMS).By analyzing the distribution characteristics of C0-C5alkylbenzenes,it is found that the content of some alkylbenzenes varies greatly in crude oils.Based on the distribution characteristics of 1,2,4,5-tetramethylbenzene(Te MB)and 1,2,3,4-Te MB,the ratio of 1,2,4,5-Te MB to 1,2,3,4-Te MB is proposed to indicate the organic matter origin and depositional environment of ancient sediments.Oil samples originated mainly from lower hydrobiont,algae,bacteria and source rocks deposited under reducing/anoxic conditions have low 1,2,4,5-/1,2,3,4-Te MB values(less than 0.6),while oil samples originated mainly from terrestrial higher plants and source rocks deposited under oxic/sub-oxic conditions have higher 1,2,4,5-/1,2,3,4-Te MB values(greater than 1.0).The significant difference of 1,2,4,5-/1,2,3,4-Te MB values is controlled by 1,2,4,5-Te MB content.1,2,4,5-Te MB content in oils derived from source rocks deposited in oxidized sedimentary environment(greater than 1.0 mg/g whole oil)is higher than that in oils from source rocks deposited in reduced sedimentary environment(less than 1.0 mg/g whole oil).1,2,4,5-/1,2,3,4-Te MB ratio might not or slightly be affected by evaporative fractionation,biodegradation and thermal maturity.1,2,4,5-/1,2,3,4-Te MB ratio and 1,2,4,5-Te MB content can be used as supplementary parameter for the identification of sedimentary environment and organic matter input.It should be noted that compared to the identification of organic matter sources,the 1,2,4,5-/1,2,3,4-Te MB parameter is more effective in identifying sedimentary environments.
基金supported by the National Natural Science Foundation of China (Grant No. 42302189)。
文摘Molecular biomarker and whole oil carbon isotope(δ^(13)C_(oil)) analyses were conducted on eleven typical crude oils from the Qiongdongnan Basin to investigate their biological sources and depositional environments. Saturated hydrocarbon biomarkers in most samples are characterized by angiosperm-derived compounds, with aromatic compounds dominated by the naphthalene, phenanthrene, biphenyl, and fluorene series. The related source rocks of these oils were mainly deposited under oxic condition, but a subanoxic-suboxic and enclosed water column condition in the Central Depression during Oligocene.The identification of simonellite and related compounds in the aromatic fractions provides reliable evidence for the input of coniferous gymnosperms. Cadalene may also have a potential association with gymnosperms since it shows a strong positive correlation with simonellite. Evidence from density, nalkanes, short-chain alkylbenzenes and secondary brine inclusions indicates that the unique crude oil B13-1 may have suffered from thermal alteration. These crude oils(excluding B13-1) can be classified into four types based on the δ^(13)C_(oil)values and molecular biomarkers. Type A oil(solely S34-3) is characterized by non-angiosperm plants, with minor dinoflagellates and increasing contribution from conifer gymnosperms than others. Type B oils(L17-2, L18-1, L25-1, and L25-1W) show heavy δ^(13)C_(oil)(-24 ‰to-25 ‰) and mixed contributions from both angiosperms and marine algae, with the marine algae contribution increasing. Type C oils(L13-2 and B21-1) share similar biological sources with Type B, but the moderately δ^(13)C_(oil)(-25‰ to-26‰) and high level of terrestrial biomarkers suggesting a predominant contribution of angiosperms. Type D oils(Y13-1a, Y13-1b, and Y13-4) possess the lightestδ^(13)C_(oil)(mainly below-26‰) and are primarily derived from angiosperms, with mangrove vegetation playing an important role. Spearman correlation analysis among 14 source biomarker parameters withδ^(13)C_(oil)and geological setting of related source rocks implied that the marine algae should be responsible for the heavy δ^(13)C_(oil)in the Type B. The contribution of marine algae in the Central Depression may have been neglected in the past, as it is usually covered by remarkable angiosperm biomarkers.
基金supported by the Certificate of National Science and Technology Major Project of the Ministry of Science and Technology of China(2016ZX05006-007-004)National Natural Science Foundation of China(41702139,41772138,41602142,42072130)the Fundamental Research Funds for the Central Universities(18CX02008A)。
文摘The mechanisms of lacustrine organic-rich shale formation have attracted attention due to its association with global shale oil and shale gas exploration.Samples of general-quality and excellent-quality source rocks,and oil shale from the Beibu Gulf Basin were analyzed to investigate their organic geochemistry,palynofacies,and trace elements.Hydrocarbon potential was higher in the oil shale(29.79 mg/g)than in the general-quality source rock(3.82 mg/g),and its kerogen type wasⅠ-Ⅱ2.Hydrogen-rich liptinite(cutinite and sporinite)components derived from terrigenous higher plants provided most of the hydrocarbon potential of excellent-quality source rock and oil shale.Under the influence of depressioncontrolling fault activity,a deeper subsidence center promotes the deposition of excellent-quality source rock and oil shale in brackish-hypoxic bottom water.A shallower subsidence center,due to subsag-controlling fault activity,promotes the formation of excellent-quality source rock under freshbrackish and weak oxidation-weak reducing conditions.The local uplift and shallow-slope led to the formation of general-quality source rock,under freshwater weak-oxidation conditions.A model was established for organic matter(OM)accumulation in organic-rich shales,accounting for fault activity,terrigenous hydrogen-rich OM,and the preservation conditions,to predict the development of excellent-quality source rock from areas with low levels of exploration.
基金funded by the National Natural Science Foundation of China (Grant No. 40973041)
文摘Based on the systematic study of aromatic hydrocarbons in over 100 crude oil samples collected from the Tabei and Tazhong uplifts in the Tarim Basin,the western depression area in the Qaidam Basin and the Tabei depression in the Turpan Basin,the geochemical characteristics of the marine（Tarim Basin）,saline lacustrine（Qaidam Basin）,and swamp（Turpan Basin） oils were investigated.The marine oils from the Tarim basin are characterized by relatively low abundance of diaromatic hydrocarbons such as biphenyl and naphthalene,and relatively high abundance of triaromatic hydrocarbons including phenanthrene,dibenzothiophene and fluorene.In contrast,the swamp oils from the Turpan Basin are dominated by the highest relative abundance of diaromatic hydrocarbons and the lowest relative abundance of triaromatic hydrocarbons in all the oil samples in this study.The relative abundance of diaromatic and triaromatic hydrocarbons in the saline lacustrine oils from Qaidam Basin is between that in Tarim oils and Turpan oils.Aromatic parameters based on the isomer distributions of dimethylnaphthalenes（DMN）,trimethylnaphthalenes（TMN）,tetramethylnaphthalenes（TeMN） and methylphenanthrenes（MP）,i.e.,1,2,5-trimethylnaphthalene（TMN）/1,3,6-TMN ratio,1,2,7-TMN/1,3,7TMN ratio,（2,6-＋2,7-）-dimethylnaphthalenes（DMN）/1,6-DMN ratio,1,3,7-TMN/（1,2,5-＋1,3,7-）TMN,1,3,6,7-TeMN/（1,3,6,7-＋1,2,5,6-＋1,2,3,5-）-TeMN ratio and MP index,may reflect the diversity of organic source input,thermal maturity and depositional environments.In addition,the dibenzothiophenes（DBTs）/fluorenes（Fs） and dibenzofurans（DBFs）/Fs ratios were found to the very useful and effective in determining genetic types of crude oils for the marine,saline lacustrine,and swamp depositional environments,and for oil-oil correlations.
基金financially supported by the National Natural Science Foundation of China(Grant No.41272158)the State Key Laboratory of Petroleum Resources and Prospecting(PRP/indep-2-1402)
文摘Twenty-two oil samples and eight source rock samples collected from the Tarim Basin, NW China were geochemically analyzed to investigate the occurrence and distribution of phenylphenanthrene （PhP）, phenylanthracene （PhA）, and binaphthyl （BIN） isomers and methylphenanthrene （MP） isomers in oils and rock extracts with different deposi- tional environments. Phenylphenanthrenes are present in significant abundance in Mesozoic lacustrine mudstones and related oils. The relative concentrations of PhPs are quite low or below detection limit by routine gas chromatogxaphy-mass spectrometry （GC-MS） in Ordovician oils derived from marine carbonates. The ratio of 3-PhP/3-MP was used in this study to describe the relative abundance of phenylphenanthrenes to their alkylated counterparts--methylphenanthrenes. The Ordovician oils in the Tabei Uplift have quite low 3-PhP/3-MP ratios （〈0.10）, indicating their marine carbonate origin, associating with low Pr/Ph ratios （pristane/phytane）, high ADBT/ ADBF values （relative abundance of alkylated dibenzothiophenes to alkylated dibenzofurans）, low C30 diahopane/C3o hopane ratios, and low Ts/（Ts ＋ Tm） （18α-22, 29, 30-trisnorneohopane/（18α-22, 29, 30-trisnorneohopane ＋ 17α-22, 29, 30-trisnorhopane）） values. In contrast, the oils from Mesozoic and Paleogene sandstone reservoirs and related Mesozoic lacustrine mudstones have relatively higher 3-PhP/3-MP ratios （〉0.10）, associating with high Pr/Ph, low ADBT/ ADBF, high Ts/（Ts ＋ Tm）, and C30 diahopane/C30 hopane ratios. Therefore, the occurrence of significant amounts of phenylphenanthrenes in oils typically indicates that the organic matter of the source rocks was deposited in a suboxic envi- ronment with mudstone deposition. The phenylphenanthrenes may be effective molecular markers, indicating depositional environment and lithology of source rocks.
基金financially supported by the National Key Research and Development Program of China (Grant No. 2017YFC0603106)。
文摘The organic geochemistry and petrology of source rocks determine the hydrocarbon generation potential of the Banqiao Sag. In this study, organic geochemistry and petrology were used to determine the abundance of organic matter(OM), OM type, OM maturity, and sedimentary environments of the source rocks, collected from Cenozoic Shahejie Formation, Banqiao Sag, Bohai Bay Basin, China. Vitrinite and liptinite are the main maceral composition of the source rocks, and range from 18% to 81% and from 2% to82% on a mineral matter free(MMF) basis, respectively. The values of vitrinite reflectance(Ro)(0.36%-1.20%) and the Tmaxvalues(397-486.C) show that the thermal maturity range from low mature to peak-maturity. The abundance of OM varies between 0.22% and 4.37%, suggesting that the source rocks of the Shahejie(Es) Formation are mainly fair to good source rocks. The Rock-Eval pyrolysis results show that the source rocks have good petroleum generation potential. The amount of free hydrocarbons(S_1)and hydrocarbons generated from pyrolysis(S_(2)) range within 0.01-3.70 mg/g, and 0.04-29.17 mg/g. The hydrogen index(HI) varies between 18.18 and 741.13 mg HC/g TOC, with most of the samples appearing to be mainly Type II kerogen, and thereby exhibiting the ability to generate both oil and gas. The ratios of Pr/Ph, the cross plot of Pr/nC_(17)-Ph/nC_(18), the cross plot of C_(29)/C_(27)-Pr/Ph, and ternary of dibenzothiophene, dibenzofuran, and fluorene, indicate that the Shahejie Formation deposited in suboxic and weak reducing environments. The main biological source is from advanced plants. The maceral composition and rock pyrolysis data indicate the kerogen type is a humic type or mixed sapropelic-humic type. The source rocks of the Shahejie(Es) Formation occur in the oil window, and the abundant organic richness,humic kerogen demonstrate that these rocks are effective oil and gas source rocks. The mudstone rocks in the Shahejie Formation are the main source of oil and gas and represent the main exploration target for the Banqiao Sag. This study enhances the great prospect of oil and gas production in the Banqiao Sag.
基金financially supported by the National Science and Technology Major Project of China(H.M.Y.,grant number 2016ZX05013006-006)Natural Science Foundation of Hubei Province of China(L.H.,grant number 2020CFB745)
文摘Based on the analysis of core,logging,and testing data,the fourth member of the Cretaceous Quantou Formation(K_(2)q^(4))in the Sanzhao depression,Songliao Basin,is investigated in order to understand the sedimentary characteristics and hydrocarbon exploration significance of a retrograding shallow-water delta.The results show that during the sedimentary period of K_(2)q^(4),the Sanzhao depression with a gentle basement experienced stable tectonic subsidence and suffered a long-term lake level rise caused by paleoclimate changes(from semiarid to semihumid),the K_(2)q^(4)in the study area were dominated by a fining-upward deltaic succession and had relatively stable thickness.From the bottom to the top,the color of mudstone gradually changes from purplish-red to gray and grayish-green,the contents of caliche nodules decrease gradually,while the presence of pyrite in sediments becomes frequent.Channel sandstones mainly composed of siltstone and fine sandstone with developed high-energy sedimentary structures constitute the main sand bodies of deltaic deposits,but the scale of channel sandstones decrease upward.Despite the long-term lake level rise and fining-upward sedimentary succession,purplish-red mudstone,caliche nodules and thin channel sandstones are still broadly distributed in the study area,and thin channel sandstones can be found at the top of K_(2)q^(4)covered by the black oil shale of Qingshankou Formation.These assertations suggest that the study area was dominated by retrograding shallow-water delta deposits during the sedimentary period of K_(2)q^(4).In comparison with modern Poyang Lake,we infer that during the sedimentary period of K_(2)q^(4),the study area experienced frequent lake level fluctuations triggered by paleoclimate changes despite the long-term lake level rise,and the lake level fluctuations control the deposition of retrograding shallow-water delta.In addition,most of the thin channel sandstones distributed at the top of K_(2)q^(4)and covered by black oil shale are generally immersed in oil,indicating that the thin channel sandstones formed at the top of a retrograding shallow-water delta sedimentary succession are favorable targets for lithological reservoir exploration.
基金the University of Ottawa and the National Natural Sciences and Engineering Research Council of Canada(NSERC)for supporting this research
文摘In this paper, the hydro-mechanical behavior and physical properties of mature fine tailings(MFT) under atmospheric drying are investigated through a column study. In the study, evaporation takes place in the development of suction in the upper parts of the column and increasing suction leads to higher strength in the tailings. After 5 days, the suction in the first lift is around 17 k Pa in the upper part of the column.When a second lift is added, the first lift initially loses strength but over a 30 days' period, the strength is recovered to its prior value and suction in the second lift reaches 500 k Pa. The vane shear strength values show a substantial increase in the strength of the MFT after 30 days under atmospheric drying and drainage. The 90% strength found in the column exceeds the threshold(5 k Pa). The hydraulic-mechanical properties of the deposited tailings are closely coupled due to several mechanisms, such as evaporation,drainage, self-consolidation, suction and crack development. The findings of this study will provide a better understanding of the placement behavior of multiple lifts of MFT and thus contribute to reclamation design standards and reduce the use of dedicated disposal areas.
