Deep oil and gas reservoirs are under high-temperature conditions,but traditional coring methods do not consider temperature-preserved measures and ignore the influence of temperature on rock porosity and permeability...Deep oil and gas reservoirs are under high-temperature conditions,but traditional coring methods do not consider temperature-preserved measures and ignore the influence of temperature on rock porosity and permeability,resulting in distorted resource assessments.The development of in situ temperaturepreserved coring(ITP-Coring)technology for deep reservoir rock is urgent,and thermal insulation materials are key.Therefore,hollow glass microsphere/epoxy resin thermal insulation materials(HGM/EP materials)were proposed as thermal insulation materials.The materials properties under coupled hightemperature and high-pressure(HTHP)conditions were tested.The results indicated that high pressures led to HGM destruction and that the materials water absorption significantly increased;additionally,increasing temperature accelerated the process.High temperatures directly caused the thermal conductivity of the materials to increase;additionally,the thermal conduction and convection of water caused by high pressures led to an exponential increase in the thermal conductivity.High temperatures weakened the matrix,and high pressures destroyed the HGM,which resulted in a decrease in the tensile mechanical properties of the materials.The materials entered the high elastic state at 150℃,and the mechanical properties were weakened more obviously,while the pressure led to a significant effect when the water absorption was above 10%.Meanwhile,the tensile strength/strain were 13.62 MPa/1.3%and 6.09 MPa/0.86%at 100℃ and 100 MPa,respectively,which meet the application requirements of the self-designed coring device.Finally,K46-f40 and K46-f50 HGM/EP materials were proven to be suitable for ITP-Coring under coupled conditions below 100℃ and 100 MPa.To further improve the materials properties,the interface layer and EP matrix should be optimized.The results can provide references for the optimization and engineering application of materials and thus technical support for deep oil and gas resource development.展开更多
Deep oil exploration coring technology cannot accurately maintain the in-situ pressure and temperature of samples, which leads to a distortion of deep oil and gas resource reserve evaluations based on conventional cor...Deep oil exploration coring technology cannot accurately maintain the in-situ pressure and temperature of samples, which leads to a distortion of deep oil and gas resource reserve evaluations based on conventional cores and cannot guide the development of deep oil and gas resources on Earth. The fundamental reason is the lack of temperature and pressure control in in-situ coring environments. In this paper, a pressure control method of a coring device is studied. The theory and method of deep intelligent temperature-pressure coupling control are innovatively proposed, and a multifield coupling dynamic sealing model is established. The optimal cardinality three term PID (Proportional-Integral-Differential) intelligent control algorithm of pressure system is developed. The temperature-pressure characteristic of the gas-liquid two-phase cavity is analyzed, and the pressure intelligent control is carried out based on three term PID control algorithms. An in-situ condition-preserved coring (ICP-Coring) device is developed, and an intelligent control system for the temperature and pressure of the coring device is designed and verified by experiments. The results show that the temperature-pressure coupling control system can effectively realize stable sealing under temperature-pressure fields of 140 MPa and 150 °C. The temperature-pressure coupling control method can accurately realize a constant pressure inside the coring device. The maximum working pressure is 140 MPa, and the effective pressure compensation range is 20 MPa. The numerical simulation experiment of pressure system control algorithm is carried out, and the optimal cardinality and three term coefficients are obtained. The pressure steady-state error is less than 0.01%. The method of temperature-pressure coupling control has guiding significance for coring device research, and is also the basis for temperature-pressure decoupling control in ICP-Coring.展开更多
During deep water oil well testing, the low temperature environment is easy to cause wax precipitation, which affects the normal operation of the test and increases operating costs and risks. Therefore, a numerical me...During deep water oil well testing, the low temperature environment is easy to cause wax precipitation, which affects the normal operation of the test and increases operating costs and risks. Therefore, a numerical method for predicting the wax precipitation region in oil strings was proposed based on the temperature and pressure fields of deep water test string and the wax precipitation calculation model. And the factors affecting the wax precipitation region were analyzed. The results show that: the wax precipitation region decreases with the increase of production rate, and increases with the decrease of geothermal gradient, increase of water depth and drop of water-cut of produced fluid, and increases slightly with the increase of formation pressure. Due to the effect of temperature and pressure fields, wax precipitation region is large in test strings at the beginning of well production. Wax precipitation region gradually increases with the increase of shut-in time. These conclusions can guide wax prevention during the testing of deep water oil well, to ensure the success of the test.展开更多
Great quantities of light oil and gas are produced from deep buried hill reservoirs at depths of 5,641 m to 6,027 m and 190 ℃ to 201 ℃ in the Niudong-1 Well, representing the deepest and hottest commercial hydrocarb...Great quantities of light oil and gas are produced from deep buried hill reservoirs at depths of 5,641 m to 6,027 m and 190 ℃ to 201 ℃ in the Niudong-1 Well, representing the deepest and hottest commercial hydrocarbons discovered in the Bohai Bay Basin in eastern China. This discovery suggests favorable exploration prospects for the deep parts of the basin. However, the discovery raises questions regarding the genesis and accumulation of hydrocarbons in deep reservoirs. Based on the geochemical features of the hydrocarbons and characteristics of the source rocks as well as thermal simulation experiments of hydrocarbon generation, we conclude that the oil and gas were generated from the highly mature Sha-4 Member （Es4） source rocks instead of thermal cracking of crude oils in earlier accumulations. The source kitchen with abnormal pressures and karsted carbonate reservoirs control the formation of high-maturity hydrocarbon accumulations in the buried hills （i.e., Niudong-1） in conjunction with several structural-lithologic traps in the ES4 reservoirs since the deposition of the upper Minghuazhen Formation. This means the oil and gas exploration potential in the deep parts of the Baxian Depression is probably high.展开更多
On December 2, 2017, the 2nd Seminar on the Development Strategy of China＇s Oil and Gas Resources was held in Beijing. This seminar was hosted by the Strategic Research Center for Oil and Gas Resources, Ministry of L...On December 2, 2017, the 2nd Seminar on the Development Strategy of China＇s Oil and Gas Resources was held in Beijing. This seminar was hosted by the Strategic Research Center for Oil and Gas Resources, Ministry of Land （MLR） and Resources and sponsored by both the CNOOC Exploration Department and the School of Ocean and Earth Sciences of Tongji University. With the theme of ＂deepwater and deep-layer oil and gas resources and development strategy＂,展开更多
To thoroughly understand the dynamic mechanism of hydrocarbon expulsion from deep source rocks,in this study,five types of hydrocarbon expulsion dynamics(thermal expansion,hydrocarbon diffusion,compaction,product volu...To thoroughly understand the dynamic mechanism of hydrocarbon expulsion from deep source rocks,in this study,five types of hydrocarbon expulsion dynamics(thermal expansion,hydrocarbon diffusion,compaction,product volume expansion,and capillary pressure difference(CPD))are studied.A model is proposed herein to evaluate the relative contribution of different dynamics for hydrocarbon expulsion using the principle of mass balance,and the model has been applied to the Cambrian source rocks in the Tarim Basin.The evaluation results show that during hydrocarbon expulsion from the source rocks,the relative contribution of CPD is the largest(>50%),followed by compaction(10%-40%),product volume expansion(5%-30%),and thermal expansion(2%-20%).The relative contribution of diffusion to hydrocarbon expulsion is minimal(<10%).These results demonstrate that CPD plays an important role in the hydrocarbon expulsion process of deep source rocks.The hydrocarbon expulsion process of source rocks can be categorized into three stages based on the contribution of different dynamics to the process:the first stage is dominated by compaction and diffusion to expel hydrocarbons,the second stage is dominated by product volume expansion and CPD,and the third stage is dominated by product volume expansion and CPD.This research offers new insights into hydrocarbon exploration in tight oil and gas reservoirs.展开更多
Series of 2-alkyl-1,3,4-trimethylbenzenes(ATMBs)were detected in most of crude oils and source rocks collected from various strata and locations of the Tarim Basin.They appeared to have heavy carbon isotopic signatur...Series of 2-alkyl-1,3,4-trimethylbenzenes(ATMBs)were detected in most of crude oils and source rocks collected from various strata and locations of the Tarim Basin.They appeared to have heavy carbon isotopic signatures(δ13C,up to~-16‰)compared to those hydrocarbons from oxygenic phototrophic organisms,indicating that the unequivocal source of green sulfur bacteria(GSB)and photic zone euxinia(PZE)existed in the original environment.Considering the high paleoproductivity,the PZE may have enhanced the preservation of organic matter,which triggered the formation of extremely organic-rich source rocks with TOC up to 29.8%for the Lower Cambrian Yuertus Formation(€1y).The coexistence of ATMBs and the diagnostic products from secondary alterations(e.g.,abundant 25-norhopanes,thiadiamondoids,and diamondoids)indicated a stronger ability of anti-second-alterations.Combined with the results of quantitatively de-convoluting mixed oil,the oil-source correlation based on ATMBs from a large number of Lower Paleozoic samples of the Tarim Basin suggested that the abundant deep crude oil resources co ntained a dominant contribution(>50%)from the€1y source rocks.Therefore,the ATMBs,as diagnostic biomarkers indicating unequivocal precursors under special habitat conditions,might provide important insights for the exploration of deep Lower Paleozoic crude oils in the Tarim Basin.展开更多
This study reviews the development history of PetroChina’s overseas oil and gas field development technologies, summarizes the characteristic technologies developed, and puts forward the development goals and technol...This study reviews the development history of PetroChina’s overseas oil and gas field development technologies, summarizes the characteristic technologies developed, and puts forward the development goals and technological development directions of overseas business to overcome the challenges met in overseas oil and gas production. In the course of PetroChina’s overseas oil and gas field production practice of more than 20 years, a series of characteristic technologies suitable for overseas oil and gas fields have been created by combining the domestic mature oil and gas field production technologies with the features of overseas oil and gas reservoirs, represented by the technology for high-speed development and stabilizing oil production and controlling water rise for overseas sandstone oilfields, high efficiency development technology for large carbonate oil and gas reservoirs and foamy oil depletion development technology in use of horizontal wells for extra-heavy oil reservoirs. Based on in-depth analysis of the challenges faced by overseas oil and gas development and technological requirements, combined with the development trends of oil and gas development technologies in China and abroad, overseas oil and gas development technologies in the future are put forward, including artificial intelligence reservoir prediction and 3 D geological modeling, secondary development and enhanced oil recovery(EOR) of overseas sandstone oilfields after high speed development, water and gas injection to improve oil recovery in overseas carbonate oil and gas reservoirs, economic and effective development of overseas unconventional oil and gas reservoirs, efficient development of marine deep-water oil and gas reservoirs. The following goals are expected to be achieved: keep the enhanced oil recovery(EOR) technology for high water-cut sandstone oilfield at international advanced level, and make the development technology for carbonate oil and gas reservoirs reach the international advanced level, and the development technologies for unconventional and marine deep-water oil and gas reservoirs catch up the level of international leading oil companies quickly.展开更多
To compare the oil displacement mechanisms and performances of continuous phase flooding agent(traditional polymer solution) and dispersed phase flooding agent(particle-type polymer SMG dispersion), the particle phase...To compare the oil displacement mechanisms and performances of continuous phase flooding agent(traditional polymer solution) and dispersed phase flooding agent(particle-type polymer SMG dispersion), the particle phase separation of SMG dispersion migrating in pores was simulated by using the microfluidic technology. Theoretically guided by the tree fork concentration distribution of red cells in biological fluid mechanics, the concentration distribution mathematical model of SMG in different pores is established. Furthermore, the micro and macro physical simulation experiments of continuous and dispersed phase flooding agents were carried out. The results show that the continuous flooding agent enters all the swept zones and increases the flow resistance in both larger and small pores. On the contrary, the particle phase separation phenomenon occurs during the injection process of dispersed flooding agent. The SMG particles gather in the larger pore to form bridge blinding, and the carrier fluid displace oil in the small pore. Working in cooperation, the SMG particle and carrier fluid drive the residual oil in the low permeability layers step by step and achieve the goal of enhanced oil recovery. The laboratory experimental results indicate that, the oil increment and water reduction effect of dispersed flooding agent is much better than that of continuous flooding agent, which is consistent with the field test results.展开更多
基金supported by the Sichuan Science and Technology Program (Grant Nos.2023NSFSC0004,2023NSFSC0790)the National Natural Science Foundation of China (Grant Nos.51827901,52304033)the Sichuan University Postdoctoral Fund (Grant No.2024SCU12093)。
文摘Deep oil and gas reservoirs are under high-temperature conditions,but traditional coring methods do not consider temperature-preserved measures and ignore the influence of temperature on rock porosity and permeability,resulting in distorted resource assessments.The development of in situ temperaturepreserved coring(ITP-Coring)technology for deep reservoir rock is urgent,and thermal insulation materials are key.Therefore,hollow glass microsphere/epoxy resin thermal insulation materials(HGM/EP materials)were proposed as thermal insulation materials.The materials properties under coupled hightemperature and high-pressure(HTHP)conditions were tested.The results indicated that high pressures led to HGM destruction and that the materials water absorption significantly increased;additionally,increasing temperature accelerated the process.High temperatures directly caused the thermal conductivity of the materials to increase;additionally,the thermal conduction and convection of water caused by high pressures led to an exponential increase in the thermal conductivity.High temperatures weakened the matrix,and high pressures destroyed the HGM,which resulted in a decrease in the tensile mechanical properties of the materials.The materials entered the high elastic state at 150℃,and the mechanical properties were weakened more obviously,while the pressure led to a significant effect when the water absorption was above 10%.Meanwhile,the tensile strength/strain were 13.62 MPa/1.3%and 6.09 MPa/0.86%at 100℃ and 100 MPa,respectively,which meet the application requirements of the self-designed coring device.Finally,K46-f40 and K46-f50 HGM/EP materials were proven to be suitable for ITP-Coring under coupled conditions below 100℃ and 100 MPa.To further improve the materials properties,the interface layer and EP matrix should be optimized.The results can provide references for the optimization and engineering application of materials and thus technical support for deep oil and gas resource development.
基金supported by the National Natural Science Foundation of China(grant numbers 51827901,51805340)funded by the Program for Guangdong Introducing Innovative and Enterpreneurial Teams(No.2019ZT08G315)Shenzhen Basic Research Program(General Program)(No.JCYJ20190808153416970).
文摘Deep oil exploration coring technology cannot accurately maintain the in-situ pressure and temperature of samples, which leads to a distortion of deep oil and gas resource reserve evaluations based on conventional cores and cannot guide the development of deep oil and gas resources on Earth. The fundamental reason is the lack of temperature and pressure control in in-situ coring environments. In this paper, a pressure control method of a coring device is studied. The theory and method of deep intelligent temperature-pressure coupling control are innovatively proposed, and a multifield coupling dynamic sealing model is established. The optimal cardinality three term PID (Proportional-Integral-Differential) intelligent control algorithm of pressure system is developed. The temperature-pressure characteristic of the gas-liquid two-phase cavity is analyzed, and the pressure intelligent control is carried out based on three term PID control algorithms. An in-situ condition-preserved coring (ICP-Coring) device is developed, and an intelligent control system for the temperature and pressure of the coring device is designed and verified by experiments. The results show that the temperature-pressure coupling control system can effectively realize stable sealing under temperature-pressure fields of 140 MPa and 150 °C. The temperature-pressure coupling control method can accurately realize a constant pressure inside the coring device. The maximum working pressure is 140 MPa, and the effective pressure compensation range is 20 MPa. The numerical simulation experiment of pressure system control algorithm is carried out, and the optimal cardinality and three term coefficients are obtained. The pressure steady-state error is less than 0.01%. The method of temperature-pressure coupling control has guiding significance for coring device research, and is also the basis for temperature-pressure decoupling control in ICP-Coring.
基金Supported by the National Key Basic Research and Development Program(973 Program),China(2015CB251205)
文摘During deep water oil well testing, the low temperature environment is easy to cause wax precipitation, which affects the normal operation of the test and increases operating costs and risks. Therefore, a numerical method for predicting the wax precipitation region in oil strings was proposed based on the temperature and pressure fields of deep water test string and the wax precipitation calculation model. And the factors affecting the wax precipitation region were analyzed. The results show that: the wax precipitation region decreases with the increase of production rate, and increases with the decrease of geothermal gradient, increase of water depth and drop of water-cut of produced fluid, and increases slightly with the increase of formation pressure. Due to the effect of temperature and pressure fields, wax precipitation region is large in test strings at the beginning of well production. Wax precipitation region gradually increases with the increase of shut-in time. These conclusions can guide wax prevention during the testing of deep water oil well, to ensure the success of the test.
文摘Great quantities of light oil and gas are produced from deep buried hill reservoirs at depths of 5,641 m to 6,027 m and 190 ℃ to 201 ℃ in the Niudong-1 Well, representing the deepest and hottest commercial hydrocarbons discovered in the Bohai Bay Basin in eastern China. This discovery suggests favorable exploration prospects for the deep parts of the basin. However, the discovery raises questions regarding the genesis and accumulation of hydrocarbons in deep reservoirs. Based on the geochemical features of the hydrocarbons and characteristics of the source rocks as well as thermal simulation experiments of hydrocarbon generation, we conclude that the oil and gas were generated from the highly mature Sha-4 Member （Es4） source rocks instead of thermal cracking of crude oils in earlier accumulations. The source kitchen with abnormal pressures and karsted carbonate reservoirs control the formation of high-maturity hydrocarbon accumulations in the buried hills （i.e., Niudong-1） in conjunction with several structural-lithologic traps in the ES4 reservoirs since the deposition of the upper Minghuazhen Formation. This means the oil and gas exploration potential in the deep parts of the Baxian Depression is probably high.
文摘On December 2, 2017, the 2nd Seminar on the Development Strategy of China＇s Oil and Gas Resources was held in Beijing. This seminar was hosted by the Strategic Research Center for Oil and Gas Resources, Ministry of Land （MLR） and Resources and sponsored by both the CNOOC Exploration Department and the School of Ocean and Earth Sciences of Tongji University. With the theme of ＂deepwater and deep-layer oil and gas resources and development strategy＂,
基金This study is financially supported by the Joint Fund of the National Natural Science Foundation of China under grant number U19B6003-02-04the Science Foundation of China University of Petroleum,Beijing,under grant number 2462020BJRC005 and 2462022YXZZ007+1 种基金the National Natural Science Foundation of China under grant number 42102145the China National Petroleum Corporation's"14th Five-Year Plan"major scientific projecs under grant number 2021DJ0101.
文摘To thoroughly understand the dynamic mechanism of hydrocarbon expulsion from deep source rocks,in this study,five types of hydrocarbon expulsion dynamics(thermal expansion,hydrocarbon diffusion,compaction,product volume expansion,and capillary pressure difference(CPD))are studied.A model is proposed herein to evaluate the relative contribution of different dynamics for hydrocarbon expulsion using the principle of mass balance,and the model has been applied to the Cambrian source rocks in the Tarim Basin.The evaluation results show that during hydrocarbon expulsion from the source rocks,the relative contribution of CPD is the largest(>50%),followed by compaction(10%-40%),product volume expansion(5%-30%),and thermal expansion(2%-20%).The relative contribution of diffusion to hydrocarbon expulsion is minimal(<10%).These results demonstrate that CPD plays an important role in the hydrocarbon expulsion process of deep source rocks.The hydrocarbon expulsion process of source rocks can be categorized into three stages based on the contribution of different dynamics to the process:the first stage is dominated by compaction and diffusion to expel hydrocarbons,the second stage is dominated by product volume expansion and CPD,and the third stage is dominated by product volume expansion and CPD.This research offers new insights into hydrocarbon exploration in tight oil and gas reservoirs.
基金financial support provided by the National Science and Technology Major Project of the Ministry of Science and Technology of China (2016ZX04004-004)National Natural Science Foundation of China (41672125)
文摘Series of 2-alkyl-1,3,4-trimethylbenzenes(ATMBs)were detected in most of crude oils and source rocks collected from various strata and locations of the Tarim Basin.They appeared to have heavy carbon isotopic signatures(δ13C,up to~-16‰)compared to those hydrocarbons from oxygenic phototrophic organisms,indicating that the unequivocal source of green sulfur bacteria(GSB)and photic zone euxinia(PZE)existed in the original environment.Considering the high paleoproductivity,the PZE may have enhanced the preservation of organic matter,which triggered the formation of extremely organic-rich source rocks with TOC up to 29.8%for the Lower Cambrian Yuertus Formation(€1y).The coexistence of ATMBs and the diagnostic products from secondary alterations(e.g.,abundant 25-norhopanes,thiadiamondoids,and diamondoids)indicated a stronger ability of anti-second-alterations.Combined with the results of quantitatively de-convoluting mixed oil,the oil-source correlation based on ATMBs from a large number of Lower Paleozoic samples of the Tarim Basin suggested that the abundant deep crude oil resources co ntained a dominant contribution(>50%)from the€1y source rocks.Therefore,the ATMBs,as diagnostic biomarkers indicating unequivocal precursors under special habitat conditions,might provide important insights for the exploration of deep Lower Paleozoic crude oils in the Tarim Basin.
文摘This study reviews the development history of PetroChina’s overseas oil and gas field development technologies, summarizes the characteristic technologies developed, and puts forward the development goals and technological development directions of overseas business to overcome the challenges met in overseas oil and gas production. In the course of PetroChina’s overseas oil and gas field production practice of more than 20 years, a series of characteristic technologies suitable for overseas oil and gas fields have been created by combining the domestic mature oil and gas field production technologies with the features of overseas oil and gas reservoirs, represented by the technology for high-speed development and stabilizing oil production and controlling water rise for overseas sandstone oilfields, high efficiency development technology for large carbonate oil and gas reservoirs and foamy oil depletion development technology in use of horizontal wells for extra-heavy oil reservoirs. Based on in-depth analysis of the challenges faced by overseas oil and gas development and technological requirements, combined with the development trends of oil and gas development technologies in China and abroad, overseas oil and gas development technologies in the future are put forward, including artificial intelligence reservoir prediction and 3 D geological modeling, secondary development and enhanced oil recovery(EOR) of overseas sandstone oilfields after high speed development, water and gas injection to improve oil recovery in overseas carbonate oil and gas reservoirs, economic and effective development of overseas unconventional oil and gas reservoirs, efficient development of marine deep-water oil and gas reservoirs. The following goals are expected to be achieved: keep the enhanced oil recovery(EOR) technology for high water-cut sandstone oilfield at international advanced level, and make the development technology for carbonate oil and gas reservoirs reach the international advanced level, and the development technologies for unconventional and marine deep-water oil and gas reservoirs catch up the level of international leading oil companies quickly.
基金Supported by the China Postdoctoral Science Foundation(Grant No.2018M641610)China National Science and Technology Major Project(2016ZX05025-003)
文摘To compare the oil displacement mechanisms and performances of continuous phase flooding agent(traditional polymer solution) and dispersed phase flooding agent(particle-type polymer SMG dispersion), the particle phase separation of SMG dispersion migrating in pores was simulated by using the microfluidic technology. Theoretically guided by the tree fork concentration distribution of red cells in biological fluid mechanics, the concentration distribution mathematical model of SMG in different pores is established. Furthermore, the micro and macro physical simulation experiments of continuous and dispersed phase flooding agents were carried out. The results show that the continuous flooding agent enters all the swept zones and increases the flow resistance in both larger and small pores. On the contrary, the particle phase separation phenomenon occurs during the injection process of dispersed flooding agent. The SMG particles gather in the larger pore to form bridge blinding, and the carrier fluid displace oil in the small pore. Working in cooperation, the SMG particle and carrier fluid drive the residual oil in the low permeability layers step by step and achieve the goal of enhanced oil recovery. The laboratory experimental results indicate that, the oil increment and water reduction effect of dispersed flooding agent is much better than that of continuous flooding agent, which is consistent with the field test results.
