Aiming at the problem of gliding near space hypersonic vehicle(NSHV)trajectory prediction,a trajectory prediction method based on aerodynamic acceleration empirical mode decomposition(EMD)is proposed.The method analyz...Aiming at the problem of gliding near space hypersonic vehicle(NSHV)trajectory prediction,a trajectory prediction method based on aerodynamic acceleration empirical mode decomposition(EMD)is proposed.The method analyzes the motion characteristics of the skipping gliding NSHV and verifies that the aerodynamic acceleration of the target has a relatively stable rule.On this basis,EMD is used to extract the trend of aerodynamic acceleration into multiple sub-items,and aggregate sub-items with similar attributes.Then,a prior basis function is set according to the aerodynamic acceleration stability rule,and the aggregated data are fitted by the basis function to predict its future state.After that,the prediction data of the aerodynamic acceleration are used to drive the system to predict the target trajectory.Finally,experiments verify the effectiveness of the method.In addition,the distribution of prediction errors in space is discussed,and the reasons are analyzed.展开更多
To address the issues of peak overlap caused by complex matrices in agricultural product terahertz(THz)spectral signals and the dynamic,nonlinear interference induced by environmental and system noise,this study explo...To address the issues of peak overlap caused by complex matrices in agricultural product terahertz(THz)spectral signals and the dynamic,nonlinear interference induced by environmental and system noise,this study explores the feasibility of adaptive-signal-decomposition-based denoising methods to improve THz spectral quality.THz time-domain spectroscopy(THz-TDS)combined with an attenuated total reflection(ATR)accessory was used to collect THz absorbance spectra from 48 peanut samples.Taking the quantitative prediction model of peanut moisture content based on THz-ATR as an example,wavelet transform(WT),empirical mode decomposition(EMD),local mean decomposition(LMD),and its improved methods-segmented local mean decomposition(SLMD)and piecewise mirror extension local mean decomposition(PME-LMD)-were employed for spectral denoising.The applicability of different denoising methods was evaluated using a support vector regression(SVR)model.Experimental results show that the peanut moisture content prediction model constructed after PME-LMD denoising achieved the best performance,with a root mean square error(RMSE),coefficient of determination(R^(2)),and mean absolute percentage error(MAPE)of 0.010,0.912,and 0.040,respectively.Compared with traditional methods,PME-LMD significantly improved spectral quality and model prediction performance.The PME-LMD denoising strategy proposed in this study effectively suppresses non-uniform noise interference in THz spectral signals,providing an efficient and accurate preprocessing method for THz spectral analysis of agricultural products.This research provides theoretical support and technical guidance for the application of THz technology for detecting agricultural product quality.展开更多
In order to analyze the influences of storage aging on the safety of typical elemental explosives,the aged cyclotrimethylene trinitramine(RDX)and cyclotetramethylene tetranitramine(HMX)were prepared by isothermal agin...In order to analyze the influences of storage aging on the safety of typical elemental explosives,the aged cyclotrimethylene trinitramine(RDX)and cyclotetramethylene tetranitramine(HMX)were prepared by isothermal aging tests.The reaction thresholds of aged RDX and HMX under any ignition probability were studied by Langlie-Optimal D method.The thermal decomposition characteristics of RDX and HMX after aging were analyzed by DSC and ARC.Experimental results showed that compared with unaged RDX and HMX,on the one hand,the critical impact energy and critical friction of RDX and HMX aged for 14,28,and 56 days are significantly reduced at an explosion probability of 50%,0.01%,and 0.0001%,respectively.With the increase of aging time,the mechanical sensitivity of RDX and HMX increases obviously.On the other hand,the initial decomposition temperature of RDX and HMX after 56 days of aging decreases,the decomposition heat decreases,the activation energy increases,and the reaction difficulty increases.展开更多
Flammable ionic liquids exhibit high conductivity and a broad electrochemical window,enabling the generation of combustible gases for combustion via electrochemical decomposition and thermal decomposition.This charact...Flammable ionic liquids exhibit high conductivity and a broad electrochemical window,enabling the generation of combustible gases for combustion via electrochemical decomposition and thermal decomposition.This characteristic holds significant implications in the realm of novel satellite propulsion.Introducing a fraction of the electrical energy into energetic ionic liquid fuels,the thermal decomposition process is facilitated by reducing the apparent activation energy required,and electrical energy can trigger the electrochemical decomposition of ionic liquids,presenting a promising approach to enhance combustion efficiency and energy release.This study applied an external voltage during the thermal decomposition of 1-ethyl-3-methylimidazole nitrate([EMIm]NO_(3)),revealing the effective alteration of the activation energy of[EMIm]NO_(3).The pyrolysis,electrochemical decomposition,and electron assisted enhancement products were identified through Thermogravimetry-Differential scanning calorimetry-Fourier transform infrared-Mass spectrometry(TG-DSC-FTIR-MS)and gas chromatography(GC)analyses,elucidating the degradation mechanism of[EMIm]NO_(3).Furthermore,an external voltage was introduced during the combustion of[EMIm]NO_(3),demonstrating the impact of voltage on the combustion process.展开更多
The precise characterization of hypersonic glide vehicle(HGV) maneuver laws in complex flight scenarios still faces challenges. Non-stationary changes in flight state due to abrupt changes in maneuver modes place high...The precise characterization of hypersonic glide vehicle(HGV) maneuver laws in complex flight scenarios still faces challenges. Non-stationary changes in flight state due to abrupt changes in maneuver modes place high demands on the accuracy of modeling methods. To address this issue, a novel maneuver laws modeling and analysis method based on higher order multi-resolution dynamic mode decomposition(HMDMD) is proposed in this work. A joint time-space-frequency decomposition of the vehicle's state sequence in the complex flight scenario is achieved with the higher order Koopman assumption and standard multi-resolution dynamic mode decomposition, and an approximate dynamic model is established. The maneuver laws can be reconstructed and analyzed with extracted multi-scale spatiotemporal modes with clear physical meaning. Based on the dynamic model of HGV, two flight scenarios are established with constant angle of attack and complex maneuver laws, respectively. Simulation results demonstrate that the maneuver laws obtained using the HMDMD method are highly consistent with those derived from the real dynamic model, the modeling accuracy is better than other common modeling methods, and the method has strong interpretability.展开更多
The new technology of direct decomposition of H_(2)S into high value-added H_(2) and S,as an alternative to the Claus process in industry,is an ideal route that can not only deal with toxic and abundant H_(2)S waste g...The new technology of direct decomposition of H_(2)S into high value-added H_(2) and S,as an alternative to the Claus process in industry,is an ideal route that can not only deal with toxic and abundant H_(2)S waste gas but also recover clean energy H_(2),which has significant socio-economic and ecological advantages.However,the highly effective decomposition of H_(2)S at low temperatures is still a great challenge,because of the stringent thermodynamic equilibrium constraints(only 20% even at high temperature of 1010℃).Conventional microwave catalysts exhibit unsatisfactory performance at low temperatures(below 600℃).Herein,Mo_(2)C@CeO_(2) catalysts with a core-shell structure were successfully developed for robust microwave catalytic decomposition of H_(2)S at low temperatures.Two carbon precursors,para-phenylenediamine(Mo_(2)C-p)and meta-phenylenediamine(Mo_(2)C-m),were employed to tailor Mo_(2)C configurations.Remarkably,the H_(2)S conversion of Mo_(2)C-p@CeO_(2) catalyst at a low temperature of 550℃ is as high as 92.1%,which is much higher than the H_(2)S equilibrium conversion under the conventional thermal conditions(2.6% at 550℃).To our knowledge,this represents the most active catalyst for microwave catalytic decomposition of H_(2)S at low temperature of 550℃.Notably,Mo_(2)C-p demonstrated superior intrinsic activity(84%)compared to Mo_(2)C-m(6.4%),with XPS analysis revealing that its enhanced performance stems from a higher concentration of Mo_(2+)active sites.This work presents a substitute approach for the efficient utilization of H_(2)S waste gas and opens up a novel avenue for the rational design of microwave catalysts for microwave catalytic reaction at low-temperature.展开更多
Range-azimuth imaging of ground targets via frequency-modulated continuous wave(FMCW)radar is crucial for effective target detection.However,when the pitch of the moving array constructed during motion exceeds the phy...Range-azimuth imaging of ground targets via frequency-modulated continuous wave(FMCW)radar is crucial for effective target detection.However,when the pitch of the moving array constructed during motion exceeds the physical array aperture,azimuth ambiguity occurs,making range-azimuth imaging on a moving platform challenging.To address this issue,we theoretically analyze azimuth ambiguity generation in sparse motion arrays and propose a dual-aperture adaptive processing(DAAP)method for suppressing azimuth ambiguity.This method combines spatial multiple-input multiple-output(MIMO)arrays with sparse motion arrays to achieve high-resolution range-azimuth imaging.In addition,an adaptive QR decomposition denoising method for sparse array signals based on iterative low-rank matrix approximation(LRMA)and regularized QR is proposed to preprocess sparse motion array signals.Simulations and experiments show that on a two-transmitter-four-receiver array,the signal-to-noise ratio(SNR)of the sparse motion array signal after noise suppression via adaptive QR decomposition can exceed 0 dB,and the azimuth ambiguity signal ratio(AASR)can be reduced to below-20 dB.展开更多
A novel satellite fault diagnosis scheme is presented based on the predictive filter and empirical mode composition（EMD）.First,the predictive filter is utilized to obtain the fault estimation,which is corrupted by n...A novel satellite fault diagnosis scheme is presented based on the predictive filter and empirical mode composition（EMD）.First,the predictive filter is utilized to obtain the fault estimation,which is corrupted by noise.Then the EMD method is introduced to decompose the fault estimation into a finite number of intrinsic mode functions and extract the trend of faults for fault diagnosis.The proposed scheme has the ability of diagnosing both abrupt and incipient faults of the actuator in a satellite attitude control subsystem.A mathematical simulation is given to illustrate the effectiveness of the proposed scheme.展开更多
Ammonium dinitramide [NH4 N(NO_2)2, ADN] is considered as a possible replacement for ammonium perchlorate(AP) in nearly all kind of solid rocket propulsions in the coming future. The reason to use ADN instead of AP in...Ammonium dinitramide [NH4 N(NO_2)2, ADN] is considered as a possible replacement for ammonium perchlorate(AP) in nearly all kind of solid rocket propulsions in the coming future. The reason to use ADN instead of AP in solid rocket propulsion is because of its harmless combustion products, along with its capacity to generate high specific impulse(Isp). ADN is fairly a new member in the solid oxidizer community and is considered under green energetic material(GEM). Application and feasible utilization of ADN as an oxidizer for composite solid propellants(CSP's) requires complete knowledge of its thermal decomposition processes along with its combustion behavior. A detailed overview on the physical and chemical properties, thermal decomposition, and combustion behavior of ADN and ADN based propellants has been discussed in this paper. Catalytic effect on thermal decomposition, combustion wave structure, and burning rate of ADN is also discussed.展开更多
基金supported by the National High-Tech R&D Program of China(2015AA70560452015AA8017032P)the Postgraduate Funding Project(JW2018A039)。
文摘Aiming at the problem of gliding near space hypersonic vehicle(NSHV)trajectory prediction,a trajectory prediction method based on aerodynamic acceleration empirical mode decomposition(EMD)is proposed.The method analyzes the motion characteristics of the skipping gliding NSHV and verifies that the aerodynamic acceleration of the target has a relatively stable rule.On this basis,EMD is used to extract the trend of aerodynamic acceleration into multiple sub-items,and aggregate sub-items with similar attributes.Then,a prior basis function is set according to the aerodynamic acceleration stability rule,and the aggregated data are fitted by the basis function to predict its future state.After that,the prediction data of the aerodynamic acceleration are used to drive the system to predict the target trajectory.Finally,experiments verify the effectiveness of the method.In addition,the distribution of prediction errors in space is discussed,and the reasons are analyzed.
基金Supported by the National Key R&D Program of China(2023YFD2101001)National Natural Science Foundation of China(32202144,61807001)。
文摘To address the issues of peak overlap caused by complex matrices in agricultural product terahertz(THz)spectral signals and the dynamic,nonlinear interference induced by environmental and system noise,this study explores the feasibility of adaptive-signal-decomposition-based denoising methods to improve THz spectral quality.THz time-domain spectroscopy(THz-TDS)combined with an attenuated total reflection(ATR)accessory was used to collect THz absorbance spectra from 48 peanut samples.Taking the quantitative prediction model of peanut moisture content based on THz-ATR as an example,wavelet transform(WT),empirical mode decomposition(EMD),local mean decomposition(LMD),and its improved methods-segmented local mean decomposition(SLMD)and piecewise mirror extension local mean decomposition(PME-LMD)-were employed for spectral denoising.The applicability of different denoising methods was evaluated using a support vector regression(SVR)model.Experimental results show that the peanut moisture content prediction model constructed after PME-LMD denoising achieved the best performance,with a root mean square error(RMSE),coefficient of determination(R^(2)),and mean absolute percentage error(MAPE)of 0.010,0.912,and 0.040,respectively.Compared with traditional methods,PME-LMD significantly improved spectral quality and model prediction performance.The PME-LMD denoising strategy proposed in this study effectively suppresses non-uniform noise interference in THz spectral signals,providing an efficient and accurate preprocessing method for THz spectral analysis of agricultural products.This research provides theoretical support and technical guidance for the application of THz technology for detecting agricultural product quality.
基金supported by the National Key Laboratory of Energetic Materials, China (Grant No. 2023-LB-036-09).
文摘In order to analyze the influences of storage aging on the safety of typical elemental explosives,the aged cyclotrimethylene trinitramine(RDX)and cyclotetramethylene tetranitramine(HMX)were prepared by isothermal aging tests.The reaction thresholds of aged RDX and HMX under any ignition probability were studied by Langlie-Optimal D method.The thermal decomposition characteristics of RDX and HMX after aging were analyzed by DSC and ARC.Experimental results showed that compared with unaged RDX and HMX,on the one hand,the critical impact energy and critical friction of RDX and HMX aged for 14,28,and 56 days are significantly reduced at an explosion probability of 50%,0.01%,and 0.0001%,respectively.With the increase of aging time,the mechanical sensitivity of RDX and HMX increases obviously.On the other hand,the initial decomposition temperature of RDX and HMX after 56 days of aging decreases,the decomposition heat decreases,the activation energy increases,and the reaction difficulty increases.
基金supported by the National Natural Science Foundation of China(Grant No.52206165)。
文摘Flammable ionic liquids exhibit high conductivity and a broad electrochemical window,enabling the generation of combustible gases for combustion via electrochemical decomposition and thermal decomposition.This characteristic holds significant implications in the realm of novel satellite propulsion.Introducing a fraction of the electrical energy into energetic ionic liquid fuels,the thermal decomposition process is facilitated by reducing the apparent activation energy required,and electrical energy can trigger the electrochemical decomposition of ionic liquids,presenting a promising approach to enhance combustion efficiency and energy release.This study applied an external voltage during the thermal decomposition of 1-ethyl-3-methylimidazole nitrate([EMIm]NO_(3)),revealing the effective alteration of the activation energy of[EMIm]NO_(3).The pyrolysis,electrochemical decomposition,and electron assisted enhancement products were identified through Thermogravimetry-Differential scanning calorimetry-Fourier transform infrared-Mass spectrometry(TG-DSC-FTIR-MS)and gas chromatography(GC)analyses,elucidating the degradation mechanism of[EMIm]NO_(3).Furthermore,an external voltage was introduced during the combustion of[EMIm]NO_(3),demonstrating the impact of voltage on the combustion process.
基金supported by the National Natural Science Foundation of China (Grant No. 12302056)the Postdoctoral Fellowship Program of CPSF:GZC20233445。
文摘The precise characterization of hypersonic glide vehicle(HGV) maneuver laws in complex flight scenarios still faces challenges. Non-stationary changes in flight state due to abrupt changes in maneuver modes place high demands on the accuracy of modeling methods. To address this issue, a novel maneuver laws modeling and analysis method based on higher order multi-resolution dynamic mode decomposition(HMDMD) is proposed in this work. A joint time-space-frequency decomposition of the vehicle's state sequence in the complex flight scenario is achieved with the higher order Koopman assumption and standard multi-resolution dynamic mode decomposition, and an approximate dynamic model is established. The maneuver laws can be reconstructed and analyzed with extracted multi-scale spatiotemporal modes with clear physical meaning. Based on the dynamic model of HGV, two flight scenarios are established with constant angle of attack and complex maneuver laws, respectively. Simulation results demonstrate that the maneuver laws obtained using the HMDMD method are highly consistent with those derived from the real dynamic model, the modeling accuracy is better than other common modeling methods, and the method has strong interpretability.
基金supported by the National Natural Science Foundation of China(22178295,21706225)Natural Science Foundation of Hunan Province(2025JJ50085)Hunan Collaborative Innovation Center of New Chemical Technologies for Environmental Benignity and Efficient Resource Utilization.
文摘The new technology of direct decomposition of H_(2)S into high value-added H_(2) and S,as an alternative to the Claus process in industry,is an ideal route that can not only deal with toxic and abundant H_(2)S waste gas but also recover clean energy H_(2),which has significant socio-economic and ecological advantages.However,the highly effective decomposition of H_(2)S at low temperatures is still a great challenge,because of the stringent thermodynamic equilibrium constraints(only 20% even at high temperature of 1010℃).Conventional microwave catalysts exhibit unsatisfactory performance at low temperatures(below 600℃).Herein,Mo_(2)C@CeO_(2) catalysts with a core-shell structure were successfully developed for robust microwave catalytic decomposition of H_(2)S at low temperatures.Two carbon precursors,para-phenylenediamine(Mo_(2)C-p)and meta-phenylenediamine(Mo_(2)C-m),were employed to tailor Mo_(2)C configurations.Remarkably,the H_(2)S conversion of Mo_(2)C-p@CeO_(2) catalyst at a low temperature of 550℃ is as high as 92.1%,which is much higher than the H_(2)S equilibrium conversion under the conventional thermal conditions(2.6% at 550℃).To our knowledge,this represents the most active catalyst for microwave catalytic decomposition of H_(2)S at low temperature of 550℃.Notably,Mo_(2)C-p demonstrated superior intrinsic activity(84%)compared to Mo_(2)C-m(6.4%),with XPS analysis revealing that its enhanced performance stems from a higher concentration of Mo_(2+)active sites.This work presents a substitute approach for the efficient utilization of H_(2)S waste gas and opens up a novel avenue for the rational design of microwave catalysts for microwave catalytic reaction at low-temperature.
基金supported by the National Natural Science Foundation of China under Grant 62301051.
文摘Range-azimuth imaging of ground targets via frequency-modulated continuous wave(FMCW)radar is crucial for effective target detection.However,when the pitch of the moving array constructed during motion exceeds the physical array aperture,azimuth ambiguity occurs,making range-azimuth imaging on a moving platform challenging.To address this issue,we theoretically analyze azimuth ambiguity generation in sparse motion arrays and propose a dual-aperture adaptive processing(DAAP)method for suppressing azimuth ambiguity.This method combines spatial multiple-input multiple-output(MIMO)arrays with sparse motion arrays to achieve high-resolution range-azimuth imaging.In addition,an adaptive QR decomposition denoising method for sparse array signals based on iterative low-rank matrix approximation(LRMA)and regularized QR is proposed to preprocess sparse motion array signals.Simulations and experiments show that on a two-transmitter-four-receiver array,the signal-to-noise ratio(SNR)of the sparse motion array signal after noise suppression via adaptive QR decomposition can exceed 0 dB,and the azimuth ambiguity signal ratio(AASR)can be reduced to below-20 dB.
基金supported by the National Natural Science Foundation of China (60874054)
文摘A novel satellite fault diagnosis scheme is presented based on the predictive filter and empirical mode composition（EMD）.First,the predictive filter is utilized to obtain the fault estimation,which is corrupted by noise.Then the EMD method is introduced to decompose the fault estimation into a finite number of intrinsic mode functions and extract the trend of faults for fault diagnosis.The proposed scheme has the ability of diagnosing both abrupt and incipient faults of the actuator in a satellite attitude control subsystem.A mathematical simulation is given to illustrate the effectiveness of the proposed scheme.
文摘Ammonium dinitramide [NH4 N(NO_2)2, ADN] is considered as a possible replacement for ammonium perchlorate(AP) in nearly all kind of solid rocket propulsions in the coming future. The reason to use ADN instead of AP in solid rocket propulsion is because of its harmless combustion products, along with its capacity to generate high specific impulse(Isp). ADN is fairly a new member in the solid oxidizer community and is considered under green energetic material(GEM). Application and feasible utilization of ADN as an oxidizer for composite solid propellants(CSP's) requires complete knowledge of its thermal decomposition processes along with its combustion behavior. A detailed overview on the physical and chemical properties, thermal decomposition, and combustion behavior of ADN and ADN based propellants has been discussed in this paper. Catalytic effect on thermal decomposition, combustion wave structure, and burning rate of ADN is also discussed.
