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A formation pursuit method integrated coordinated reciprocity for enhanced capture
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作者 XING Xiaoyu XIA Haoxiang 《Journal of Systems Engineering and Electronics》 2026年第1期211-224,共14页
Cooperative pursuit poses challenges across natural,social,and technical systems,particularly when decentralized,slow-speed pursuers attempt to capture a high-speed evader with limited observation.Most existing contri... Cooperative pursuit poses challenges across natural,social,and technical systems,particularly when decentralized,slow-speed pursuers attempt to capture a high-speed evader with limited observation.Most existing contributions place the focus on the greedy pursuit of the evader,overlooking potential collaborations among pursuers.To tackle this issue,a decisionmaking framework of multi-agent coordinated reciprocity formation pursuit(MACRFP)via deep reinforcement learning is introduced.This framework integrates the actor-critic algorithm with the coordinated reciprocity mechanism to enhance the capability of capturing a faster evader.Initially,a local perception model is created by utilizing a cellular network to simulate limitations caused by obstacles.Next,the formation coalition of pursuit is guided by the Cartesian Oval,enabling dispersed pursuers to create a siege against the faster evader.Furthermore,a coordinated reciprocity model based on the coordination graph and the attention-based graph neural networks is developed,addressing the global coordination problem by estimating a reciprocity coefficient to adjust agents'rewards.Numerical simulations demonstrate the emergence of cooperative behaviors in cooperative besiegement,target tracking,and intelligent interception during the pursuit,indicating that the proposed algorithm enhances the feasibility and effectiveness of capturing a fast-escaping target by integrating coordinated reciprocity and coalition formation. 展开更多
关键词 multi-agent system reinforcement learning cooperative pursuit coordinated reciprocity
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Optimal control based coordinated taxiing path planning and tracking for multiple carrier aircraft on flight deck 被引量:8
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作者 Xin-wei Wang Hai-jun Peng +3 位作者 Jie Liu Xian-zhou Dong Xu-dong Zhao Chen Lu 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2022年第2期238-248,共11页
Coordinated taxiing planning for multiple aircraft on flight deck is of vital importance which can dramatically improve the dispatching efficiency.In this paper,first,the coordinated taxiing path planning problem is t... Coordinated taxiing planning for multiple aircraft on flight deck is of vital importance which can dramatically improve the dispatching efficiency.In this paper,first,the coordinated taxiing path planning problem is transformed into a centralized optimal control problem where collision-free conditions and mechanical limits are considered.Since the formulated optimal control problem is of large state space and highly nonlinear,an efficient hierarchical initialization technique based on the Dubins-curve method is proposed.Then,a model predictive controller is designed to track the obtained reference trajectory in the presence of initial state error and external disturbances.Numerical experiments demonstrate that the proposed“offline planningþonline tracking”framework can achieve efficient and robust coordinated taxiing planning and tracking even in the presence of initial state error and continuous external disturbances. 展开更多
关键词 Carrier aircraft coordinated path planning Centralized optimal control Trajectory tracking Model predictive control
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Coordinated control strategy for robotic-assisted gait training with partial body weight support 被引量:6
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作者 秦涛 张立勋 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第8期2954-2962,共9页
Walking is the most basic and essential part of the activities of daily living. To enable the elderly and non-ambulatory gait-impaired patients, the repetitive practice of this task, a novel gait training robot(GTR) w... Walking is the most basic and essential part of the activities of daily living. To enable the elderly and non-ambulatory gait-impaired patients, the repetitive practice of this task, a novel gait training robot(GTR) was designed followed the end-effector principle, and an active partial body weight support(PBWS) system was introduced to facilitate successful gait training. For successful establishment of a walking gait on the GTR with PBWS, the motion laws of the GTR were planned to enable the phase distribution relationships of the cycle step, and the center of gravity(COG) trajectory of the human body during gait training on the GTR was measured. A coordinated control strategy was proposed based on the impedance control principle. A robotic prototype was developed as a platform for evaluating the design concepts and control strategies. Preliminary gait training with a healthy subject was implemented by the robotic-assisted gait training system and the experimental results are encouraging. 展开更多
关键词 robotic-assisted gait training gait training robot (GTR) partial body weight support (PBWS) center of gravity (COG) coordinated control strategy ground reaction force (GRF)
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Coordinated control method of intersection traffic light in one-way road based on V2X 被引量:4
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作者 GAO Kai HAN Fa-rong +3 位作者 WEN Meng-fei DU Rong-hua LI Shuo ZHOU Feng 《Journal of Central South University》 SCIE EI CAS CSCD 2019年第9期2516-2527,共12页
One-way roads have potential for improving vehicle speed and reducing traffic delay.Suffering from dense road network,most of adjacent intersections’distance on one-way roads becomes relatively close,which makes isol... One-way roads have potential for improving vehicle speed and reducing traffic delay.Suffering from dense road network,most of adjacent intersections’distance on one-way roads becomes relatively close,which makes isolated control of intersections inefficient in this scene.Thus,it is significant to develop coordinated control of multiple intersection signals on the one-way roads.This paper proposes a signal coordination control method that is suitable for one-way arterial roads.This method uses the cooperation technology of the vehicle infrastructure to collect intersection traffic information and share information among the intersections.Adaptive signal control system is adopted for each intersection in the coordination system,and the green light time is adjusted in real time based on the number of vehicles in queue.The offset and clearance time can be calculated according to the real-time traffic volume.The proposed method was verified with simulation results by VISSIM traffic simulation software.The results compared with other methods show that the coordinated control method proposed in this paper can effectively reduce the average delay of vehicles on the arterial roads and improve the traffic efficiency. 展开更多
关键词 INTERSECTION vehicle infrastructure cooperation coordinated control simulation evaluation
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Coordinated optimization setting of reagent dosages in roughing-scavenging process of antimony flotation 被引量:3
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作者 CAO Bin-fang XIE Yong-fang +2 位作者 GUI Wei-hua YANG Chun-hua LI Jian-qi 《Journal of Central South University》 SCIE EI CAS CSCD 2018年第1期95-106,共12页
Considering the influence of reagent adjustment in different flotation bank on the final production index and the difficulty of establishing an effective mathematical model,a coordinated optimization method for dosage... Considering the influence of reagent adjustment in different flotation bank on the final production index and the difficulty of establishing an effective mathematical model,a coordinated optimization method for dosage reagent based on key characteristics variation tendency and case-based reasoning is proposed.On the basis of the expert reagent regulation method in antimony flotation process,the reagent dosage pre-setting model of the roughing–scavenging bank is constructed based on case-based reasoning.Then,the sensitivity index is used to calculate the key features of reagent dosage.The reagent dosage compensation model is constructed based on the variation tendency of the key features in the roughing and scavenging process.At last,the prediction model is used to finish the classification and discriminant analysis.The simulation results and industrial experiment in antimony flotation process show that the proposed method reduces fluctuation of the tailings indicators and the cost of reagent dosage.It can lay a foundation for optimizing the whole process of flotation. 展开更多
关键词 froth flotation image features optimization setting coordinated optimization
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Intelligent coordinated control of power-plant main steam pressure and power output 被引量:1
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作者 刘红波 李少远 柴天佑 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2004年第3期350-358,共9页
An intelligent coordinated control strategy has been proposed and successfully applied to a 300MW boiler-turbine unit i. e. Unit 1 of Yuanbaoshan power plant in China. Load following operation of coal-fired boiler-tur... An intelligent coordinated control strategy has been proposed and successfully applied to a 300MW boiler-turbine unit i. e. Unit 1 of Yuanbaoshan power plant in China. Load following operation of coal-fired boiler-turbine unit in the power plant leads to changes in operating points which result in nonlinear variations of the plant variables and parameters. For the variation of operating condition and slowly varying dynamics, an intelligent control scheme has been developed by combining fuzzy self-tuning with adaptive control and auto-tuning techniques. As there exist strong couplings between control loops of main steam pressure and power output in the unit, a new design for static decoupler aimed at decoupling for setpoints and unmeasured pulverized coal disturbance of the system at the same time is presented. Satisfactory industrial application results show that such a control system has enhanced adaptability and robustness to the complex process, and better control performance and high economic benefit have been obtained. 展开更多
关键词 intelligent control boiler-turbine coordinated control fuzzy inference adaptive control static decoupling industrial application.
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Constrained Power Plant Coordinated Predictive Control Using Neurofuzzy Model 被引量:1
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作者 LIU Xiang-Jie LIU Ji-Zhen 《自动化学报》 EI CSCD 北大核心 2006年第5期785-790,共6页
In unit steam-boiler generation, a coordinated control strategy is required to ensure a higher rate of load change without violating thermal constraints. The process is characterized by nonlinearity and uncertainty. W... In unit steam-boiler generation, a coordinated control strategy is required to ensure a higher rate of load change without violating thermal constraints. The process is characterized by nonlinearity and uncertainty. While neural networks can model highly complex nonlinear dynamical systems, they produce black box models. This has led to significant interest in neuro-fuzzy networks (NFNs) to represent a nonlinear dynamical process by a set of locally valid and simpler submodels. Two alternative methods of exploiting the NFNs within a generalised predictive control (GPC) framework for nonlinear model predictive control are described. Coordinated control of steam-boiler generation using the two nonlinear GPC methods show excellent tracking and disturbance rejection results and improved performance compared with conventional linear GPC. 展开更多
关键词 coordinated control neuro-fuzzy networks GPC
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Disturbance observer based finite-time coordinated attitude tracking control for spacecraft on SO(3) 被引量:1
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作者 SHI Zhen XIE Yaen +3 位作者 DENG Chengchen ZHAO Kun HE Yushan HAO Yong 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2020年第6期1274-1285,共12页
To solve the problem of attitude synchronization control for spacecraft formation flying(SFF)suffering from external disturbances under a directed communication topology,a sliding mode disturbance observer(SMDO)based ... To solve the problem of attitude synchronization control for spacecraft formation flying(SFF)suffering from external disturbances under a directed communication topology,a sliding mode disturbance observer(SMDO)based on the finite-time control strategy is developed to observe the time-varying external disturbance via estimating the upper bound of its first derivative.Meanwhile,the rotation matrix is employed to describe the attitude of SFF for the purpose of the avoidance of singularity and unwinding phenomenon.As for the attitude synchronization and the tracking control architecture,a sliding mode surface(SMS)is given such that the control objective can be achieved.The effectiveness and the validity of the proposed method are elaborated via theoretical analysis and numerical simulations. 展开更多
关键词 coordinated attitude control disturbance observer rotation matrix attitude synchronization control
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Coordinated scheduling model for intermodal transit hubs based on GI/M^K/1 queuing system
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作者 贾洪飞 曹雄赳 杨丽丽 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第8期3247-3256,共10页
Coordinated scheduling of multimode plays a pivotal role in the rapid gathering and dissipating of passengers in transport hubs. Based on the survey data, the whole-day reaching time distribution at transfer points of... Coordinated scheduling of multimode plays a pivotal role in the rapid gathering and dissipating of passengers in transport hubs. Based on the survey data, the whole-day reaching time distribution at transfer points of passengers from the dominant mode to the connecting mode was achieved. A GI/M K/1 bulk service queuing system was constituted by putting the passengers' reaching time distribution as the input and the connecting mode as the service institution. Through queuing theory, the relationship between average queuing length under steady-state and headway of the connecting mode was achieved. By putting the minimum total cost of system as optimization objective, the headway as decision variable, a coordinated scheduling model of multimode in intermodal transit hubs was established. At last, a dynamic scheduling strategy was generated to cope with the unexpected changes of the dominant mode. The instance analysis indicates that this model can significantly reduce passengers' queuing time by approximately 17% with no apparently increase in departure frequency, which provides a useful solution for the coordinated scheduling of different transport modes in hubs. 展开更多
关键词 traffic engineering coordinated scheduling queuing theory intermodal transit hub HEADWAY
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Coordinated Bayesian optimal approach for the integrated decision between electronic countermeasure and firepower attack
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作者 Zheng Tang Xiaoguang Gao Chao Sun 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2010年第3期449-454,共6页
The coordinated Bayesian optimization algorithm(CBOA) is proposed according to the characteristics of the function independence,conformity and supplementary between the electronic countermeasure(ECM) and the firep... The coordinated Bayesian optimization algorithm(CBOA) is proposed according to the characteristics of the function independence,conformity and supplementary between the electronic countermeasure(ECM) and the firepower attack systems.The selection criteria are combinations of probabilities of individual fitness and coordinated degree and can select choiceness individual to construct Bayesian network that manifest population evolution by producing the new chromosome.Thus the CBOA cannot only guarantee the effective pattern coordinated decision-making mechanism between the populations,but also maintain the population multiplicity,and enhance the algorithm performance.The simulation result confirms the algorithm validity. 展开更多
关键词 electronic countermeasure firepower attack coordinated Bayesian optimization algorithm(CBOA).
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Coordinated dynamic mission planning scheme for intelligent multi-agent systems
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作者 彭军 文孟飞 +2 位作者 谢国祺 张晓勇 Kuo-chi LIN 《Journal of Central South University》 SCIE EI CAS 2012年第11期3170-3179,共10页
Mission planning was thoroughly studied in the areas of multiple intelligent agent systems,such as multiple unmanned air vehicles,and multiple processor systems.However,it still faces challenges due to the system comp... Mission planning was thoroughly studied in the areas of multiple intelligent agent systems,such as multiple unmanned air vehicles,and multiple processor systems.However,it still faces challenges due to the system complexity,the execution order constraints,and the dynamic environment uncertainty.To address it,a coordinated dynamic mission planning scheme is proposed utilizing the method of the weighted AND/OR tree and the AOE-Network.In the scheme,the mission is decomposed into a time-constraint weighted AND/OR tree,which is converted into an AOE-Network for mission planning.Then,a dynamic planning algorithm is designed which uses task subcontracting and dynamic re-decomposition to coordinate conflicts.The scheme can reduce the task complexity and its execution time by implementing real-time dynamic re-planning.The simulation proves the effectiveness of this approach. 展开更多
关键词 weighted AND/OR tree multiple intelligent agent coordinated dynamic mission planning AOE-NETWORK
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Research on Coordinated Antisumarine Attack Effeciency of Two Helicopters Under Countermeasures
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作者 丁红岩 董晓明 蹇明裕 《Defence Technology(防务技术)》 CAS 2012年第1期47-51,共5页
The organization of coordinated attack and the selection of aiming point which affect hit probability were analyzed for the countermeasures taken by the hostile submarines at two helicopters' coordinated attack.A ... The organization of coordinated attack and the selection of aiming point which affect hit probability were analyzed for the countermeasures taken by the hostile submarines at two helicopters' coordinated attack.A computational model of coordinated attack parameters,a model of submarine maneuver,and a model of noise jammer were established.Compared to single helicopter' torpedo attack,the coordinated attack of two helicopters can effectively increase the hit probability of torpedo and achieve the higher target detecting probability under counterwork condition. 展开更多
关键词 analysis on system assessment and feasibility coordinated attack torpedo anti-submarine probability simulation
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Design of Tracking Controller for Coordinated Boiler-turbine Control System Based on Fuzzy Lyapunov Functions
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作者 LIU Shanjian SHEN Jiong +2 位作者 LIU Xichui LI Yiguo WU Jie 《中国电机工程学报》 EI CSCD 北大核心 2013年第11期I0014-I0014,共1页
The thermal power boiler-turbine system is a complex system with high nonlinearity,time-delay and strong coupling.It is difi cult to obtain an excellent dynamic response by means of traditional PI/PID control when the... The thermal power boiler-turbine system is a complex system with high nonlinearity,time-delay and strong coupling.It is difi cult to obtain an excellent dynamic response by means of traditional PI/PID control when the power system load changes in a wide range.So far many advanced control strategies have been presented to solve the above problem,but most of these strategies are dependent on an accurate object model. 展开更多
关键词 boiler-turbine coordinate system tracking control linear matrix inequalities(LMI) uncertain parameter model fuzzy Lyapunov functions
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基于改进YOLOv5的砖石建筑裂缝检测方法
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作者 翁文杏 余兆钗 +2 位作者 李佐勇 李炜 吴景岚 《计算机应用与软件》 北大核心 2026年第2期189-196,222,共9页
砖石建筑极易出现裂缝,严重威胁建筑寿命和人民生命财产安全,因此,裂缝检测是建筑维护的重要基础。为了提升砖石建筑裂缝的检测精度,应用YOLOv5s的改进方法。将SPD-Conv引入到骨干网络中,提高细粒度特征的检测能力;使用BiFPN并结合Coord... 砖石建筑极易出现裂缝,严重威胁建筑寿命和人民生命财产安全,因此,裂缝检测是建筑维护的重要基础。为了提升砖石建筑裂缝的检测精度,应用YOLOv5s的改进方法。将SPD-Conv引入到骨干网络中,提高细粒度特征的检测能力;使用BiFPN并结合Coordinate Attention模块来代替YOLOv5的特征融合网络,提升检测精度;使用SIoU Loss来代替原有损失函数,改善在复杂环境下检测不佳的情况。在砖石建筑裂缝数据集上的实验结果表明,所提方法的平均均值精度(mAP@0.5)达到96.0%,比原YOLOv5s提高了4.0百分点,比2023年提出的YOLOv8s提高了2.0百分点,可以有效地检测砖石建筑裂缝。 展开更多
关键词 砖石建筑 裂缝检测 YOLOv5 SPD-Conv BiFPN Coordinate Attention SIoU Loss
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Syntheses and fluorescent sensing properties of two coordination polymers based on 9,9′‑dihexyl‑2,7‑di(pyridin‑4‑yl)fluorene
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作者 WANG Gaofeng SUN Shuwen +1 位作者 Meng Lixin PENG Dequn 《无机化学学报》 北大核心 2026年第2期331-339,共9页
Under solvothermal conditions,1,4‑naphthalenedicarboxylic acid(H_(2)ndc)and 9,9′‑dihexyl‑2,7‑di(pyridin‑4‑yl)fluorene(hfdp)reacted with Co^(2+)ions and Cd^(2+)ions to form two coordination polymers,[Co(hfdp)(ndc)(H2O... Under solvothermal conditions,1,4‑naphthalenedicarboxylic acid(H_(2)ndc)and 9,9′‑dihexyl‑2,7‑di(pyridin‑4‑yl)fluorene(hfdp)reacted with Co^(2+)ions and Cd^(2+)ions to form two coordination polymers,[Co(hfdp)(ndc)(H2O)]·DMA}n(1)and{[Cd(hfdp)(ndc)(H_(2)O)]·DMA}_(n)(2),respectively(DMA=N,N‑dimethylacetamide).Single‑crystal X‑ray diffraction analyses showed that both complexes 1 and 2 contain similar structures.Topological analysis indicates that complexes 1 and 2 have a{44·62}planar structure.In addition,both complexes reveal good thermal stability and fluorescence sensing performance.They exhibited good sensitivity and selectivity towards 2,4,6‑trinitrophenol(TNP)by fluorescent quenching.The limits of detection of 1 and 2 for TNP were 0.107 and 0.327μmol·L^(-1),respectively.CCDC:2475515,1;2475516,2. 展开更多
关键词 coordination polymers cadmium(Ⅱ) TOPOLOGY FLUORESCENCE FLUORENE
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Synthesis,characterization,and ion exchange properties of octamolybdate-based Cu(Ⅱ)coordination polymer
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作者 HAO Xiuli ZHANG Chenhao +3 位作者 FENG Chenkun HAN Haolin ZHAO Xudong SHI Guoliang 《无机化学学报》 北大核心 2026年第4期883-896,共14页
The ionothermal reaction between CuCl_(2),1,4-bis(1,2,4-triazol-1-ylmethyl)benzene(BBTZ),and(NH_(4))_(6)Mo_(7)O_(24) in 1-ethyl-3-methylimidazolium bromide((Emim)Br)led to a new octamolybdate-based coordination polyme... The ionothermal reaction between CuCl_(2),1,4-bis(1,2,4-triazol-1-ylmethyl)benzene(BBTZ),and(NH_(4))_(6)Mo_(7)O_(24) in 1-ethyl-3-methylimidazolium bromide((Emim)Br)led to a new octamolybdate-based coordination polymer(Emim)2[Cu(BBTZ)_(2)(β-Mo_(8)O_(26))](Mo_(8)-CP).Mo_(8)-CP was characterized by elemental analysis,thermogravime-try,IR,powder X-ray diffraction,and single-crystal X-ray diffraction.In Mo_(8)-CP,structural analysis reveals that Cu coordinates with BBTZ ligands to form an interlocked 1D chain.These chains are further bridged by(β-Mo_(8)O_(26))^(4-)to construct a 3D coordination polymer.Notably,(Emim)^(+)acts as a structure-directing agent,occupying the channels of the 3D coordination polymer.Based on this unique structure,the ion exchange properties of Mo_(8)-CP toward rare-earth ions were investigated.It has been found that the luminescent color of the material can be successfully regulat-ed by introducing Eu^(3+)or Tb^(3+)through ion exchange.CCDC:2475110,Mo_(8)-CP. 展开更多
关键词 OCTAMOLYBDATE coordination polymer ion exchange property fluorescent materials
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Synthesis and crystal structures of Co(Ⅱ)/Cu(Ⅱ)coordination polymers based on solvent and ligand concentration regulation strategy
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作者 SUN Yinxia LIU Liping +7 位作者 BAI Xue SUN Yu SUN Wanhong DENG Zhepeng CHEN Jianghai WANG Jianjun XU Li ZHANG Shuzhen 《无机化学学报》 北大核心 2026年第2期340-354,共15页
Four distinct coordination polymers(CPs)were successfully synthesized by altering solvent types and adjusting ligand concentrations,and their crystal structures were investigated.[Co(L)(FDCA)(H_(2)O)_(2)]·0.5H_(2... Four distinct coordination polymers(CPs)were successfully synthesized by altering solvent types and adjusting ligand concentrations,and their crystal structures were investigated.[Co(L)(FDCA)(H_(2)O)_(2)]·0.5H_(2)O(1)was synthesized as a 2D structure using Coas the metal source,methanol‑water(4∶6,V/V)as the solvent,and specific concentrations of 2,5‑furandicarboxylic acid(H_(2)FDCA)and 1,3,5‑triimidazole benzene(L).Adjusting to pure water and lowering the concentration of L yielded the 1D chain structure of[Co(HL)2(H_(2)O)_(2)](FDCA)_(2)·6H_(2)O(2).Using Cu(Ⅱ)as the metal source,methanol/water(9∶1,V/V)as the solvent,and specific concentrations of L and H2FDCA,the 1D chain structure of[Cu(L)(FDCA)(H_(2)O)]·2H_(2)O(3)was synthesized.Upon increasing the concentrations of L and H2FDCA,and switching the solvent to pure water,the 1D chain structure of[Cu(HL)_(2)(H_(2)O)_(2)](FDCA)_(2)·6H_(2)O(4)was obtained.This shows that changing the solvent and ligand concentrations can affect the structural changes of CPs.In addition,the solid‑state photoluminescence of CPs 1‑4 at room temperature was studied,and their morphological changes were observed via scanning electron microscopy.Density functional theory calculations revealed that the negative charge concentrates on the O and N atoms of the ligand,facilitating ligand‑metal ion coordination.CCDC:2403934,1;2403935,2;2403936,3;2403938,4. 展开更多
关键词 Co(Ⅱ)/Cu(Ⅱ)coordination polymer crystal structure solvent system ligand concentration regulation strategy
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Crystal structures and luminescent properties of two isostructural Zn complexes constructed from L-tert-leucine Schiff bases ligands
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作者 XU Xuebin CHEN Jie +1 位作者 WANG Gaofeng SONG Shaofei 《无机化学学报》 北大核心 2026年第6期1312-1320,共9页
Two isostructural coordination polymers[Zn(L)(HCOO)]n(Zn-LFor)and[Zn(L)Cl]n(Zn-LCl)were synthesized by a hydrothermal method based on HL·NaX(HL=2-{[(pyridin-4-yl)methyl]amino}-3,3-dimethylbutanoic acid,X-=HCOO^(-... Two isostructural coordination polymers[Zn(L)(HCOO)]n(Zn-LFor)and[Zn(L)Cl]n(Zn-LCl)were synthesized by a hydrothermal method based on HL·NaX(HL=2-{[(pyridin-4-yl)methyl]amino}-3,3-dimethylbutanoic acid,X-=HCOO^(-),Cl^(-)).Zn-LFor and Zn-LCl belong to the orthorhombic system with space group P2_(1)2_(1)2_(1),which exhibit distorted square pyramidal structures.Interestingly,the values of the trigonality factor(τ5)are distinctively different.Zn-LCl has aτ5 value of 0.144,while the value ofτ5 for Zn-LFor is only 0.089.Zn-LFor displayed an excellent fluorescence property,which can be used as a fluorescence probe to detect Cr_(2)O_(7)^(2-)in H2O solution with high selectivity and sensitivity,with a quenching constant(KSV)of 2.23×10^(4) L·mol^(-1).The detection limit of Cr_(2)O_(7)^(2-)was calculated from the experimental data,and the value was 1.03μmol·L^(-1).CCDC:2503298,Zn-LFor;2503302,Zn-LCl. 展开更多
关键词 Schiff bases coordination polymer Cr_(2)O_(7)^(2-) luminescent property
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STRUCTURE AND CATALYTIC ACTIVITY OF RHODIUM COMPLEX COORDINATED ON 2-VINYLPYRIDINE-METHYL ACRYLATE COPOLYMER FOR THE CARBONYLATION OF METHANOL
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作者 Chen Yuying Yuan Guoqing Wang Dianxun Chen Rongyao (Institute of Chemistry, Academia Sinica, Beijing, China) 《分子催化》 EI CAS CSCD 1990年第S1期61-67,共7页
A series of rhodium complexes coordinated on the hybrid ligand. 2-vinylpyridine-methyl acrylate copolymers, as catalyst for the carbonylation of methanol were synthesized by the reaction of the copolymers with tetraca... A series of rhodium complexes coordinated on the hybrid ligand. 2-vinylpyridine-methyl acrylate copolymers, as catalyst for the carbonylation of methanol were synthesized by the reaction of the copolymers with tetracarbonyldichlorodirhodium. These complexes were in general very reactive in carbonylation of methanol to form acetic acid and methyl acetate without other by-product. The XPS studies of the complexes showed that the binding energies of Nls(399.1-399.4 eV) and that of Ols(532.5-532.9 eV) were higher than that of the copolymer ligand (Nls 398.1-398.3 eV and Ols 532.2-532.3 eV), indicating the fromation of N→Rh and O→Rh coordination bonds. The IR spectra of complexes showed that the appearance of two absorption peaks of terminal carbonyl at 1990-2100 cm<sup>-1</sup>, characteristic of the cis-dicarbonyl rhodium moiety. These XPS and IR studies confirm the formation of cis-dicarbonylrhodium complex with the active centers(A) and (B) as shown in the text. The increase of activity of the complex in the 展开更多
关键词 COPOLYMER complexes acrylate coordinated MOIETY carbonyl METHANOL acetate acetic bonds
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A cadmium(Ⅱ)coordination polymer based on a semirigid tetracarboxylate ligand for highly selective detection of Fe^(3+)and 4-nitrophenol 被引量:2
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作者 BAI Yu WANG Jijiang +4 位作者 TANG Long YUE Erlin BAI Chao WANG Xiao ZHANG Yuqi 《无机化学学报》 北大核心 2025年第6期1217-1226,共10页
A novel coordination polymer(CP){[Cd_(2)(L)(1,4-bimb)_(1.5)(DMF)_(2)]·DMF}n(1)(H_(4)L=5,5'-[1,1'-biphenyl-4,4'-diylbis(oxy)]diisophthalic acid,1,4-bimb=1,4-bis(imidazole-1-ylmethyl)-benzene)has been d... A novel coordination polymer(CP){[Cd_(2)(L)(1,4-bimb)_(1.5)(DMF)_(2)]·DMF}n(1)(H_(4)L=5,5'-[1,1'-biphenyl-4,4'-diylbis(oxy)]diisophthalic acid,1,4-bimb=1,4-bis(imidazole-1-ylmethyl)-benzene)has been designed and synthesized through solvothermal reaction.Structural analysis shows that Cd(Ⅱ)is connected by H4L and 1,4-bimb to form a 2D network,and 1,4-bimb further expands the 2D network into a 3D framework.CP 1 can be used as an excellent fluorescence sensor for Fe^(3+)and 4-nitrophenol(4-NP),with low detection limits and good anti-interference.The detection limits of Fe^(3+)and 4-NP were 0.034 and 0.031μmol·L^(-1),respectively.In addition,the fluorescence quenching mechanism was studied.1 was successfully applied to determine Fe^(3+)and 4-NP content in the Yanhe River water sample.CCDC:2351092. 展开更多
关键词 coordination polymer Fe^(3+) 4-NITROPHENOL fluorescence sensing
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