期刊文献+
共找到1,314篇文章
< 1 2 66 >
每页显示 20 50 100
Controlling Reactivity of Palladium Amides for Selective Carbonylation towards Urea and Oxamide Derivatives 被引量:2
1
作者 WANG Jin-hui CAO Yan-wei HE Lin 《分子催化(中英文)》 CAS CSCD 北大核心 2024年第4期297-308,共12页
Carbonylation reactions,crucial for carbonyl group incorporation,struggle with the inherent complexity of achieving selective mono-or double-carbonylation on single substrates,often due to competing reaction pathways.... Carbonylation reactions,crucial for carbonyl group incorporation,struggle with the inherent complexity of achieving selective mono-or double-carbonylation on single substrates,often due to competing reaction pathways.Herein,our study introduces a strategy employing palladium amides,harnessing their unique reactivity control,to direct the selective carbonylation of amines for the targeted synthesis of urea and oxamide derivatives.The palladium amide structure was elucidated using single-crystal X-ray diffraction.Controlled experiments and cyclic voltammetry studies further elucidate that the oxidation of palladium amide or its insertion into a carbonyl group diverges into distinct pathways.By employing sodium percarbonate as an eco-friendly oxidant and base,we have successfully constructed a switchable carbonylation system co-catalyzed by palladium and iodide under room temperature.The utilizing strategy in this study not only facilitates effective control over reaction selectivity but also mitigates the risk of explosions,a critical safety concern in traditional carbonylation methods. 展开更多
关键词 selectivity control palladium catalysis oxidative carbonylation AMINOCARBONYLATION green reagents
在线阅读 下载PDF
Controlling factors of high-quality volcanic reservoirs of Yingcheng Formation in the Songnan gas field 被引量:3
2
作者 DU Shang SHAN Xuan-long +1 位作者 YI Jian LI Ji-yan 《Journal of Central South University》 SCIE EI CAS CSCD 2018年第4期892-902,共11页
Predicting high-quality volcanic reservoirs is one of the key issues for oil and gas exploration in the Songnan gas field.Core,seismic,and measurement data were used to study the lithologies,facies,reservoir porosity,... Predicting high-quality volcanic reservoirs is one of the key issues for oil and gas exploration in the Songnan gas field.Core,seismic,and measurement data were used to study the lithologies,facies,reservoir porosity,and reservoir types of the volcanic rocks in the Songnan gas field.The primary controlling factors and characteristics of the high-quality volcanic reservoirs of the Yingcheng Formation in the Songnan gas field were investigated,including the volcanic eruptive stage,edifice,edifice facies,cooling unit,lithology,facies,and diagenesis.Stages with more volatile content can form more high-quality reservoirs.The effusive rhyolite,explosive tuff,and tuff lava that formed in the crater,near-crater,and proximal facies and in the high-volatility cooling units of large acidic-lava volcanic edifices are the most favorable locations for the development of the high-quality reservoirs in the Songnan gas field.Diagenesis dissolution,which is controlled by tectonic action,can increase the size of secondary pores in reservoirs.Studying the controlling factors of the high-quality reservoirs can provide a theoretical basis for the prediction and analysis of high-quality volcanic reservoirs. 展开更多
关键词 Songnan gas field Yingcheng Formation high-quality volcanic reservoir controlling factor
在线阅读 下载PDF
Controlling Factors Affecting Pressure Differential Development of the Upper Paleozoic Gas Reservoir in the Sulige and Yulin Area of the Ordos Basin
3
作者 Hao Xu~1,Junfeng Zhang~2,Chengzao Jia~3,Dazhen Tang~1,Ming Li~3,Wenzhong Zhang~1 1.Key Laboratory of Marine Reservoir Evolution and Hydrocarbon Accumulation Mechanism,Ministry of Education,China University of Geosciences(Beijing),Beijing 100083,China. 2.PetroChina Exploration and Production Company,Beijing 100724,China 3.Research Institute of Petroleum Exploration & Development,Beijing 100083,China 《地学前缘》 EI CAS CSCD 北大核心 2009年第S1期126-127,共2页
The origin and distribution of Upper Paleozoic reservoirs pressure in mid-northem Ordos Basin has attracted widespread attention in recent years.The reservoir pressure of Sulige area shows characteristics of basically... The origin and distribution of Upper Paleozoic reservoirs pressure in mid-northem Ordos Basin has attracted widespread attention in recent years.The reservoir pressure of Sulige area shows characteristics of basically subnormal pressure,and the reservoir pressure of Yulin area shows characteristics of basically normal hydrostatic pressure.In the sense of structural location, 展开更多
关键词 ORDOS BASIN SULIGE area Yulin area formation PRESSURE controlling FACTORS
在线阅读 下载PDF
Identification of Quantitative Trait Loci Controlling Seed Physical and Nutrient Traits in Cotton
4
作者 SONG Xian-liang,ZHANG Tian-zhen(National Key Laboratory of Crop Genetics & Germplasm Enhancement,Cotton Research Institute,Nanjing Agricultural University,Nanjing 210095,China) 《棉花学报》 CSCD 北大核心 2008年第S1期32-,共1页
Cotton(Gossypium spp.) is the leading fiber crop,and an important source of the important edible oil and protein meals in the world.Complex genetics and strong environmental effects hinder
关键词 QTLs Identification of Quantitative Trait Loci controlling Seed Physical and Nutrient Traits in Cotton
在线阅读 下载PDF
Controlling roof with potential rock burst risk through different pre-crack length:Mechanism and effect research 被引量:8
5
作者 ZHAO Tong-bin ZHANG Peng-fei +3 位作者 GUO Wei-yao GONG Xu-fei WANG Chao CHEN Yang 《Journal of Central South University》 SCIE EI CAS CSCD 2022年第11期3706-3719,共14页
Roof pre-splitting is an effective method to control the roof with potential rock burst risk.In this study,three-point bending tests were carried out by using fine sandstone specimens with different pre-cracked length... Roof pre-splitting is an effective method to control the roof with potential rock burst risk.In this study,three-point bending tests were carried out by using fine sandstone specimens with different pre-cracked lengths as test objects,and digital speckle correlation method(DSCM)and acoustic emission(AE)technology were used to track the entire process of crack propagation.The effect of pre-cracks on the fracture of rock beams was evaluated,and the mechanical mechanism of the rock beam fracture process was analyzed.The rock beam pre-splitting design method was developed,and the application effect of the method was proved by the microseismic monitoring data obtained from the 10303 working face of Jining No.2 coal mine in China.The results show that the loading time history curve of pre-cracked beams exhibits obvious residual characteristics.Compared with the intact rock beam,the tensile strength,and maximum tensile strain of 35 mm pre-cracked rock beam are decreased by 32.4% and 33.1%,respectively and the acoustic emission b value is increased by 30.2%.According to the pre-splitting design method of rock beam,the maximum and average microseismic energy of the 10303 working face after pre-splitting construction are reduced by 25.6% and 6.4%,respectively,with excellent prevention and control effect of thick roof. 展开更多
关键词 three-point bending acoustic emission roof pre-splitting digital speckle correlation method rock burst control
在线阅读 下载PDF
Modeling and controlling of a flexible hydraulic manipulator 被引量:2
6
作者 李光 吴敏 《Journal of Central South University of Technology》 EI 2005年第5期578-583,共6页
A mathematical model was developed combining the dynamics of an Euler-Bernoulli beam, described by the assumed-mode method and hydraulic circuit dynamics. Only one matrix, termed drive Jacobian, was needed in the mode... A mathematical model was developed combining the dynamics of an Euler-Bernoulli beam, described by the assumed-mode method and hydraulic circuit dynamics. Only one matrix, termed drive Jacobian, was needed in the modeling of interaction between hydraulic circuit and flexible manipulator mechanism. Furthermore, a new robust controller based on mentioned above dynamic model was also considered to regulate both flexural vibrations and rigid body motion. The proposed controller combined sliding mode and backstepping techniques to deal with the nonlinear system with uncertainties. The sliding mode control was used to achieve an asymptotic joint angle and vibration regulation by providing a virtual force while the backstepping technique was used to regulate the spool position of a hydraulic valve to provide the required control force. Simulation results are presented to show the stabilizing effect and robustness of this control strategy. 展开更多
关键词 dynamic modeling flexible manipulator sliding mode control backstepping control hydraulic actuator
在线阅读 下载PDF
Multiparameter Optimization and Controlling for Cylindrical Grinding Process 被引量:1
7
作者 LI Guo-fa, WANG Long-shan, YANG Lian-bo (College of Mechanical Science and Engineering, Jilin University, Changchun 130025, China) 《厦门大学学报(自然科学版)》 CAS CSCD 北大核心 2002年第S1期24-,共1页
This paper bursts the bondage of conventional no-burn thought, presents an optimum strategy permitting burn appear in grinding roughing stage, but the burning layer can be summed on the following finishing stage. On t... This paper bursts the bondage of conventional no-burn thought, presents an optimum strategy permitting burn appear in grinding roughing stage, but the burning layer can be summed on the following finishing stage. On the base of the basic grinding models, the objective function and constrained functions for the multiparameter optimum grinding models had been built in this paper. By the computer simulation, the nonlinear optimum grinding control parameters had been obtained, and the truth grinding process had been controlled by these parameters. The results of simulation and the experiments proved the exactitude of the optimum models and the feasibility of the optimum strategy. This paper had also created the precondition for the grinding automation, virtual grinding and intelligent grinding system for cylindrical grinding process. 展开更多
关键词 grinding process multiparameter optimization computer simulation depth of burn optimum control
在线阅读 下载PDF
EXPERT SYSTEM FOR CONTROLLING THE STATE OF SINTERING PROCESS
8
作者 Wang Haidong Jiang Bo (Department of Mineral Processing Engineering,Central South University of Technology,Changsha 410083, China) 《Journal of Central South University》 SCIE EI CAS 1999年第1期42-43,共2页
In order to control sintering process,improve permeability and stabilize burn through point, a control scheme which combines thermal state with permeability state is proposed, and an expert system for controlling sint... In order to control sintering process,improve permeability and stabilize burn through point, a control scheme which combines thermal state with permeability state is proposed, and an expert system for controlling sintering process state is developed, the software which includes about 1000 expert rules is successfully applied to off line control of sintering process. 展开更多
关键词 SINTERING PROCESS STATE CONTROL EXPERT SYSTEM
在线阅读 下载PDF
Controlling the probability density of quantum systems
9
作者 Yifan Xing Jun Wu 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2011年第6期975-981,共7页
A new method to design a quantum controller which directly controls the probability density function(PDF) of quantum systems is proposed.Based on the quantum model from the PDF perspective,two specific control algor... A new method to design a quantum controller which directly controls the probability density function(PDF) of quantum systems is proposed.Based on the quantum model from the PDF perspective,two specific control algorithms are proposed with uniform and non-uniform fields,respectively.Then a detailed control algorithm with convergence analysis is given for the small error case.By appropriately estimating the selected Lyapunov function,more accurate control effect is achieved.The proposed scheme provides a constructive method to find appropriate parameters for controller design. 展开更多
关键词 quantum control probability density control stochastic distribution control.
在线阅读 下载PDF
Methods for Controlling and Reduction of Pollutions by Using Electromagnetic Field
10
作者 Munendra Jain Neeraj Jain 《地学前缘》 EI CAS CSCD 北大核心 2009年第S1期78-78,共1页
Man made activities are changing environment of our planet earth.Various methods are used to reduce the environmental pollution.In this paper the methods of air/water/soil pollution mitigation/reduction using electrom... Man made activities are changing environment of our planet earth.Various methods are used to reduce the environmental pollution.In this paper the methods of air/water/soil pollution mitigation/reduction using electromagnetic fields is discussed.Air/water/soil contains ions and the energy transfer for living organisms takes place by ion exchange processes.Ions are affected by electric/magnetic fields.Many investigators 展开更多
关键词 air IONS ION DEFICIENCY MAGNETIZED water MAGNETIC treatment POLLUTION control
在线阅读 下载PDF
Thruster direction controlling of assembled spacecraft based on gimbal suspension
11
作者 Hongliang Xu Hai Huang 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2016年第2期442-448,共7页
The attitude control system design and its control effect are affected considerably by the mass-property parameters of the spacecraft. In the mission of on-orbit servicing, as fuel is expended, or the payloads are add... The attitude control system design and its control effect are affected considerably by the mass-property parameters of the spacecraft. In the mission of on-orbit servicing, as fuel is expended, or the payloads are added or removed, the center of mass will be changed in certain axe; consequently, some thrusters' directions are deviated from the center of mass(CM) in certain plane. The CM of assembled spacecraft estimation and thruster direction control are studied. Firstly, the attitude dynamics of the assembled spacecraft is established based on the Newton-Euler method. Secondly, the estimation can be identified by the least recursive squares algorithm. Then, a scheme to control the thrusters' directions is proposed. By using the gimbal installed at the end of the boom, the angle of the thruster is controlled by driving the gimbal; therefore, thrusters can be directed to the CM again. Finally, numerical simulations are used to verify this scheme. Results of the numerical simulations clearly show that this control scheme is rational and feasible. 展开更多
关键词 on-orbit servicing thruster's direction control assembled spacecraft center of mass(CM) identification
在线阅读 下载PDF
Fault-observer-based iterative learning model predictive controller for trajectory tracking of hypersonic vehicles 被引量:1
12
作者 CUI Peng GAO Changsheng AN Ruoming 《Journal of Systems Engineering and Electronics》 2025年第3期803-813,共11页
This work proposes the application of an iterative learning model predictive control(ILMPC)approach based on an adaptive fault observer(FOBILMPC)for fault-tolerant control and trajectory tracking in air-breathing hype... This work proposes the application of an iterative learning model predictive control(ILMPC)approach based on an adaptive fault observer(FOBILMPC)for fault-tolerant control and trajectory tracking in air-breathing hypersonic vehicles.In order to increase the control amount,this online control legislation makes use of model predictive control(MPC)that is based on the concept of iterative learning control(ILC).By using offline data to decrease the linearized model’s faults,the strategy may effectively increase the robustness of the control system and guarantee that disturbances can be suppressed.An adaptive fault observer is created based on the suggested ILMPC approach in order to enhance overall fault tolerance by estimating and compensating for actuator disturbance and fault degree.During the derivation process,a linearized model of longitudinal dynamics is established.The suggested ILMPC approach is likely to be used in the design of hypersonic vehicle control systems since numerical simulations have demonstrated that it can decrease tracking error and speed up convergence when compared to the offline controller. 展开更多
关键词 hypersonic vehicle actuator fault tracking control iterative learning control(ILC) model predictive control(MPC) fault observer
在线阅读 下载PDF
Effective implementation of controlled blasting methodology during excavation of hard rock in the close proximity of earthen dam and tunnel 被引量:1
13
作者 Prakash K.Palei Vijay K.Ghodake +5 位作者 S.Santhosh Kumar R.S.Gurjar Chaman Singh M.Meena Rizwan Ali R.S.Kankara 《Defence Technology(防务技术)》 2025年第6期306-316,共11页
The present technical paper outlines the details of the controlled blasting techniques used to optimize blasting pattern for excavation of hard rock near the Bhira Earthen Dam in Maharashtra,India.In this connection,a... The present technical paper outlines the details of the controlled blasting techniques used to optimize blasting pattern for excavation of hard rock near the Bhira Earthen Dam in Maharashtra,India.In this connection,a series of experimental blasts were conducted by adjusting various blast design parameters at project site.The safe charge weight per delay was kept between 0.125 and 0.375 kg.The outcomes of these experimental blasts were analyzed to recommend optimized blasting patterns and methods for the overall excavation process during actual blasting operations.Blast design parameters,including the maximum quantity of explosive per delay,hole depth,burden and spacing between holes were optimized by using a site-specific attenuation equation,taking into account the proximity of the dam and tunnel from the blasting area.Peak particle velocity(PPV)level of 10 mm/s and 50 mm/s respectively were adopted as the safe vibration level for ensuring safety of the Bhira Earthen Dam and the nearby tunnel from the adverse effects of blast vibrations by analyzing the dominant frequency of ground vibrations observed and also by reviewing various international standards.Frequency of the ground vibrations observed on the dam and tunnel from majority of the blasts was found to be more than 10 Hz and 50 Hz respectively.During the entire period of blasting,the blast vibrations were recorded to be far lower than the safe vibration level set for these structures.Maximum Vibration level of about 0.8 mm/s and 35 mm/s were observed on dam and tunnel respectively which are far lower than the safe vibration level adopted for these structures.Hence,the entire excavation work was completed successfully and safely,without endangering the safety of dam or tunnel. 展开更多
关键词 Controlled blasting Civil structure Ground vibration Attenuation relation
在线阅读 下载PDF
Research on multi-scale simulation and dynamic verification of high dynamic MEMS components in additive manufacturing 被引量:1
14
作者 Sining Lv Hengzhen Feng +2 位作者 Wenzhong Lou Chuan Xiao Shiyi Li 《Defence Technology(防务技术)》 2025年第5期275-291,共17页
Metal Additive Manufacturing(MAM) technology has become an important means of rapid prototyping precision manufacturing of special high dynamic heterogeneous complex parts. In response to the micromechanical defects s... Metal Additive Manufacturing(MAM) technology has become an important means of rapid prototyping precision manufacturing of special high dynamic heterogeneous complex parts. In response to the micromechanical defects such as porosity issues, significant deformation, surface cracks, and challenging control of surface morphology encountered during the selective laser melting(SLM) additive manufacturing(AM) process of specialized Micro Electromechanical System(MEMS) components, multiparameter optimization and micro powder melt pool/macro-scale mechanical properties control simulation of specialized components are conducted. The optimal parameters obtained through highprecision preparation and machining of components and static/high dynamic verification are: laser power of 110 W, laser speed of 600 mm/s, laser diameter of 75 μm, and scanning spacing of 50 μm. The density of the subordinate components under this reference can reach 99.15%, the surface hardness can reach 51.9 HRA, the yield strength can reach 550 MPa, the maximum machining error of the components is 4.73%, and the average surface roughness is 0.45 μm. Through dynamic hammering and high dynamic firing verification, SLM components meet the requirements for overload resistance. The results have proven that MEM technology can provide a new means for the processing of MEMS components applied in high dynamic environments. The parameters obtained in the conclusion can provide a design basis for the additive preparation of MEMS components. 展开更多
关键词 Additive manufacturing High dynamic MEMS components Multiscale control Process optimization High dynamic verification
在线阅读 下载PDF
Graded density impactor design via machine learning and numerical simulation:Achieve controllable stress and strain rate 被引量:1
15
作者 Yahui Huang Ruizhi Zhang +6 位作者 Shuaixiong Liu Jian Peng Yong Liu Han Chen Jian Zhang Guoqiang Luo Qiang Shen 《Defence Technology(防务技术)》 2025年第9期262-273,共12页
The graded density impactor(GDI)dynamic loading technique is crucial for acquiring the dynamic physical property parameters of materials used in weapons.The accuracy and timeliness of GDI structural design are key to ... The graded density impactor(GDI)dynamic loading technique is crucial for acquiring the dynamic physical property parameters of materials used in weapons.The accuracy and timeliness of GDI structural design are key to achieving controllable stress-strain rate loading.In this study,we have,for the first time,combined one-dimensional fluid computational software with machine learning methods.We first elucidated the mechanisms by which GDI structures control stress and strain rates.Subsequently,we constructed a machine learning model to create a structure-property response surface.The results show that altering the loading velocity and interlayer thickness has a pronounced regulatory effect on stress and strain rates.In contrast,the impedance distribution index and target thickness have less significant effects on stress regulation,although there is a matching relationship between target thickness and interlayer thickness.Compared with traditional design methods,the machine learning approach offers a10^(4)—10^(5)times increase in efficiency and the potential to achieve a global optimum,holding promise for guiding the design of GDI. 展开更多
关键词 Machine learning Numerical simulation Graded density impactor Controllable stress-strain rate loading Response surface methodology
在线阅读 下载PDF
Fixed-time Target-guided Coordinate Control of Unmanned Surface Vehicles Based on Dynamic Surface Control
16
作者 LI Chao−yi XU Hai−xiang +2 位作者 YU Wen−zhao DU Zhe DING Ya−nan 《船舶力学》 北大核心 2025年第6期849-862,共14页
This paper presents an investigation on the target-guided coordinated control(TACC)of unmanned surface vehicles(USVs).In the scenario of tracking non-cooperative targets,the status information of the target can only b... This paper presents an investigation on the target-guided coordinated control(TACC)of unmanned surface vehicles(USVs).In the scenario of tracking non-cooperative targets,the status information of the target can only be obtained by some USVs.In order to achieve semi-encirclement tracking of noncooperative targets under maritime security conditions,a fixed-time tracking control method based on dynamic surface control(DSC)is proposed in this paper.Firstly,a novel TACC architecture with decoupled kinematic control law and decoupled kinetic control law was designed to reduce the complexity of control system design.Secondly,the proposed DSC-based target-guided kinematic control law including tracking points pre-allocation strategy and sigmoid artificial potential functions(SigAPFs)can avoid collisions during tracking process and optimize kinematic control output.Finally,a fixed-time TACC system was proposed to achieve fast convergence of kinematic and kinetics errors.The effectiveness of the proposed TACC approach in improving target tracking safety and reducing control output chattering was verified by simulation comparison results. 展开更多
关键词 unmanned surface vehicle distributed control target-guided coordinate control fixed-time convergence dynamic surface control
在线阅读 下载PDF
Temperature control for liquid-cooled fuel cells based on fuzzy logic and variable-gain generalized supertwisting algorithm
17
作者 CHEN Lin JIA Zhi-huan +1 位作者 DING Tian-wei GAO Jin-wu 《控制理论与应用》 北大核心 2025年第8期1596-1605,共10页
The liquid cooling system(LCS)of fuel cells is challenged by significant time delays,model uncertainties,pump and fan coupling,and frequent disturbances,leading to overshoot and control oscillations that degrade tempe... The liquid cooling system(LCS)of fuel cells is challenged by significant time delays,model uncertainties,pump and fan coupling,and frequent disturbances,leading to overshoot and control oscillations that degrade temperature regulation performance.To address these challenges,we propose a composite control scheme combining fuzzy logic and a variable-gain generalized supertwisting algorithm(VG-GSTA).Firstly,a one-dimensional(1D)fuzzy logic controler(FLC)for the pump ensures stable coolant flow,while a two-dimensional(2D)FLC for the fan regulates the stack temperature near the reference value.The VG-GSTA is then introduced to eliminate steady-state errors,offering resistance to disturbances and minimizing control oscillations.The equilibrium optimizer is used to fine-tune VG-GSTA parameters.Co-simulation verifies the effectiveness of our method,demonstrating its advantages in terms of disturbance immunity,overshoot suppression,tracking accuracy and response speed. 展开更多
关键词 liquid-cooled fuel cell temperature control generalized supertwisting algorithm fuzzy control equilibrium optimizer
在线阅读 下载PDF
Fault-tolerant control for diesel engine air path system via sliding mode surface
18
作者 WU Wen-jie ZHANG Yi-xin +4 位作者 WANG Xing-jian WANG Shao-ping ZHANG Jian ZHENG Wei TAO Mo 《控制理论与应用》 北大核心 2025年第8期1570-1577,共8页
The operating environment of the diesel engine air path system is complex and may be affected by external random disturbances.Potentially leading to faults.This paper addresses the fault-tolerant control problem of th... The operating environment of the diesel engine air path system is complex and may be affected by external random disturbances.Potentially leading to faults.This paper addresses the fault-tolerant control problem of the diesel engine air path system,assuming that the system may simultaneously be affected by actuator faults and external random disturbances,a disturbance observer-based sliding mode controller is designed.Through the linear matrix inequality technique for solving observer and controller gains,optimal gain matrices can be obtained,eliminating the manual adjustment process of controller parameters and reducing the chattering phenomenon of the sliding mode surface.Finally,the effectiveness of the proposed method is verified through simulation analysis. 展开更多
关键词 disel engine air path fault-tolerant control sliding mode control disturbance observer
在线阅读 下载PDF
Projective synchronization control and simulation of drive system and response network
19
作者 LI De-kui 《兰州大学学报(自然科学版)》 北大核心 2025年第2期208-214,共7页
Projective synchronization problems of a drive system and a particular response network were investigated,where the drive system is an arbitrary system with n+1 dimensions;it may be a linear or nonlinear system,and ev... Projective synchronization problems of a drive system and a particular response network were investigated,where the drive system is an arbitrary system with n+1 dimensions;it may be a linear or nonlinear system,and even a chaotic or hyperchaotic system,the response network is complex system coupled by N nodes,and every node is showed by the approximately linear part of the drive system.Only controlling any one node of the response network by designed controller can achieve the projective synchronization.Some numerical examples were employed to verify the effectiveness and correctness of the designed controller. 展开更多
关键词 pinning control projective synchronization drive system response network
在线阅读 下载PDF
Enhanced selectivity of catalytic hydrogenation of halogenated nitroaromatics by interfacial effects
20
作者 HUANG Rui LIU Shengjie +1 位作者 WU Qingyuan ZHENG Nanfeng 《无机化学学报》 北大核心 2025年第1期201-212,共12页
The highly selective catalytic hydrogenation of halogenated nitroaromatics was achieved by employing Pd‑based catalysts that were co‑modified with organic and inorganic ligands.It was demonstrated that the catalysts c... The highly selective catalytic hydrogenation of halogenated nitroaromatics was achieved by employing Pd‑based catalysts that were co‑modified with organic and inorganic ligands.It was demonstrated that the catalysts contained Pd species in mixed valence states,with high valence Pd at the metal‑support interface and zero valence Pd at the metal surface.While the strong coordination of triphenylphosphine(PPh3)to Pd0 on the Pd surface prevents the adsorption of halogenated nitroaromatics and thus dehalogenation,the coordination of sodium metavanadate(NaVO3)to high‑valence Pd sites at the interface helps to activate H2 in a heterolytic pathway for the selective hydrogenation of nitro‑groups.The excellent catalytic performance of the interfacial active sites enables the selective hydrogenation of a wide range of halogenated nitroaromatics. 展开更多
关键词 halogenated nitroaromatic heterogeneous catalysis HYDROGENATION selectivity control interfacial effect
在线阅读 下载PDF
上一页 1 2 66 下一页 到第
使用帮助 返回顶部