The key exposure problem is a practical threat for many security applications. In wireless sensor networks (WSNs), keys could be compromised easily due to its limited hardware protections. A secure group key managemen...The key exposure problem is a practical threat for many security applications. In wireless sensor networks (WSNs), keys could be compromised easily due to its limited hardware protections. A secure group key management scheme is responsible for secure distributing group keys among valid nodes of the group. Based on the key-insulated encryption (KIE), we propose a group key management scheme (KIE-GKMS), which integrates the pair-wise key pre-distribution for WSN. The KIE-GKMS scheme updates group keys dynamically when adding or removing nodes. Moreover, the security analysis proves that the KIE-GKMS scheme not only obtains the semantic security, but also provides the forward and backward security. Finally, the theoretical analysis shows that the KIE-GKMS scheme has constant performance on both communication and storage costs in sensor nodes.展开更多
为了解决医疗系统中数据泄露和医疗机构间数据的孤岛问题,提出基于国密SM9的去中心化跨链医疗数据共享方案(SM9-based decentration cross-chain medical data sharing scheme, DCCMDSS).中继链和哈希时间锁定合约实现了医疗机构之间跨...为了解决医疗系统中数据泄露和医疗机构间数据的孤岛问题,提出基于国密SM9的去中心化跨链医疗数据共享方案(SM9-based decentration cross-chain medical data sharing scheme, DCCMDSS).中继链和哈希时间锁定合约实现了医疗机构之间跨链数据的可信共享,星际文件系统存储模式降低了区块链的存储压力并确保了医疗数据的完整性.SM9用于加密医疗数据,群签名允许群体成员代表集体签署数据而无需暴露个人身份,有效避免了隐私泄露问题并保证了签名的可追溯性.DCCMDSS降低了跨链交互中的计算复杂度,提升了医疗数据的安全性.展开更多
new coordination polymer {[Zn(CF3COO)2(C5H5ON)]·H2O}n was synthesized based on the reaction of zinc(Ⅱ) trifluoroacetate and 3-hydroxypyridine(C5H5ON) in methanol medium for the first time. The structure of the c...new coordination polymer {[Zn(CF3COO)2(C5H5ON)]·H2O}n was synthesized based on the reaction of zinc(Ⅱ) trifluoroacetate and 3-hydroxypyridine(C5H5ON) in methanol medium for the first time. The structure of the coordination polymer was confirmed by IR, 1H NMR, elemental analysis and thermal analysis. The crystal structure of the coordination polymer was also determined by X-ray single crystal diffraction. The crystal belongs to monoclinic system with space group P21/m, and crystallographic data of the coordination polymer are: a= 0.863 1(4) nm, b=0.717 7(3) nm, c=1.116 4(5) nm, α=γ=90°, β=107.542(6)°, V=0.659 4(5) nm3; Dc=2.037 g·cm-3; Z=2; F(000)=400; μ=1.969 mm-1. Zinc(Ⅱ) atom lies at the center of an octahedron formed by the coordination of zinc atom and six O atoms which come from four different trifluoroacetate ions and two different 3-hydroxypyridine molecules where each trifluoroacetate ion and 3-hydroxypyridine are coordinated to two different zinc ions to form coordination polymer. CCDC: 253909.展开更多
A one-dimensional double-chain coordination polymer [Mn(phen)(tsgluo)] was synthesized in a mixed solution and its crystal structure was determined by X-ray diffraction method. It crystallizes in orthorhombic system w...A one-dimensional double-chain coordination polymer [Mn(phen)(tsgluo)] was synthesized in a mixed solution and its crystal structure was determined by X-ray diffraction method. It crystallizes in orthorhombic system with space group P212121. The crystal data are: a=0.530 78(17) nm, b=1.723 9(5) nm, c=2.456 9(8) nm, Z=4, μ=0.729 mm-1, Dc=1.579 g·cm-3, V=2.248 1(12) nm3, R1=0.033 1, ωR2=0.078 9. In the title complex, each Mn(Ⅱ) ion presents a octahedral geometry with the coordination of two nitrogen atoms from 1,10-phenanthroline and four oxygen atoms from three different tsgluo2- ligands. The γ-carboxyl coordinates to Mn(Ⅱ) in the mode of bidentate chelate, while the α-carboxyl coordinates in a bidentate bridging mode. CCDC: 253910.展开更多
A new binuclear copper(Ⅱ) complex, [Cu2(phen)2(H2O)2( μ2-C2O4)](NO3)2, has been synthesized and characterized by elemental analysis, IR and UV-Vis spectrum. Its crystal structure was determined by single crystal X-r...A new binuclear copper(Ⅱ) complex, [Cu2(phen)2(H2O)2( μ2-C2O4)](NO3)2, has been synthesized and characterized by elemental analysis, IR and UV-Vis spectrum. Its crystal structure was determined by single crystal X-ray diffraction techniques. Crystal data: monoclinic, space group P21/c, a=0.712 21(8) nm, b=1.170 93(14) nm, c=1.783 7(2) nm, β=111.828(2)°, and V=1.380 8(3) nm3, Dc=1.769 Mg·m-3, Z=2, F(000)=744, R1=0.025 4, wR2=0.069 5, Gof=1.077, Δρ=328^-455 e·nm-3. The complex is packed by one centrosymmetry binuclear copper(Ⅱ) unit, oxalate dianion and NO3- anion. In the molecule structure of the title complex, two Cu(Ⅱ) ions are bridged by oxalate dianion and each Cu(Ⅱ) ions coordinates with two nitrogen atoms from 1,10-phenanthroline ligand and one oxygen atom from water to form a five-coordinate distorted square-pyramidal configuration. The hydrogen bonds are observed between coordinated water molecules and NO3- anions. The analysis of the crystal structure indicates that the complex has a two-dimensional stacking network structure, which is formed by intramolecular hydrogen bonds, intermolecular hydrogen bonds and stacking effect of aromatic ring. CCDC: 255345.展开更多
基金Project(61100201) supported by National Natural Science Foundation of ChinaProject(12ZZ019) supported by Technology Innovation Research Program,Shang Municipal Education Commission,China+1 种基金Project(LYM11053) supported by the Foundation for Distinguished Young Talents in Higher Education of Guangdong Province,ChinaProject(NCET-12-0358) supported by New Century Excellent Talentsin University,Ministry of Education,China
文摘The key exposure problem is a practical threat for many security applications. In wireless sensor networks (WSNs), keys could be compromised easily due to its limited hardware protections. A secure group key management scheme is responsible for secure distributing group keys among valid nodes of the group. Based on the key-insulated encryption (KIE), we propose a group key management scheme (KIE-GKMS), which integrates the pair-wise key pre-distribution for WSN. The KIE-GKMS scheme updates group keys dynamically when adding or removing nodes. Moreover, the security analysis proves that the KIE-GKMS scheme not only obtains the semantic security, but also provides the forward and backward security. Finally, the theoretical analysis shows that the KIE-GKMS scheme has constant performance on both communication and storage costs in sensor nodes.
文摘为了解决医疗系统中数据泄露和医疗机构间数据的孤岛问题,提出基于国密SM9的去中心化跨链医疗数据共享方案(SM9-based decentration cross-chain medical data sharing scheme, DCCMDSS).中继链和哈希时间锁定合约实现了医疗机构之间跨链数据的可信共享,星际文件系统存储模式降低了区块链的存储压力并确保了医疗数据的完整性.SM9用于加密医疗数据,群签名允许群体成员代表集体签署数据而无需暴露个人身份,有效避免了隐私泄露问题并保证了签名的可追溯性.DCCMDSS降低了跨链交互中的计算复杂度,提升了医疗数据的安全性.
文摘new coordination polymer {[Zn(CF3COO)2(C5H5ON)]·H2O}n was synthesized based on the reaction of zinc(Ⅱ) trifluoroacetate and 3-hydroxypyridine(C5H5ON) in methanol medium for the first time. The structure of the coordination polymer was confirmed by IR, 1H NMR, elemental analysis and thermal analysis. The crystal structure of the coordination polymer was also determined by X-ray single crystal diffraction. The crystal belongs to monoclinic system with space group P21/m, and crystallographic data of the coordination polymer are: a= 0.863 1(4) nm, b=0.717 7(3) nm, c=1.116 4(5) nm, α=γ=90°, β=107.542(6)°, V=0.659 4(5) nm3; Dc=2.037 g·cm-3; Z=2; F(000)=400; μ=1.969 mm-1. Zinc(Ⅱ) atom lies at the center of an octahedron formed by the coordination of zinc atom and six O atoms which come from four different trifluoroacetate ions and two different 3-hydroxypyridine molecules where each trifluoroacetate ion and 3-hydroxypyridine are coordinated to two different zinc ions to form coordination polymer. CCDC: 253909.
文摘A one-dimensional double-chain coordination polymer [Mn(phen)(tsgluo)] was synthesized in a mixed solution and its crystal structure was determined by X-ray diffraction method. It crystallizes in orthorhombic system with space group P212121. The crystal data are: a=0.530 78(17) nm, b=1.723 9(5) nm, c=2.456 9(8) nm, Z=4, μ=0.729 mm-1, Dc=1.579 g·cm-3, V=2.248 1(12) nm3, R1=0.033 1, ωR2=0.078 9. In the title complex, each Mn(Ⅱ) ion presents a octahedral geometry with the coordination of two nitrogen atoms from 1,10-phenanthroline and four oxygen atoms from three different tsgluo2- ligands. The γ-carboxyl coordinates to Mn(Ⅱ) in the mode of bidentate chelate, while the α-carboxyl coordinates in a bidentate bridging mode. CCDC: 253910.
文摘A new binuclear copper(Ⅱ) complex, [Cu2(phen)2(H2O)2( μ2-C2O4)](NO3)2, has been synthesized and characterized by elemental analysis, IR and UV-Vis spectrum. Its crystal structure was determined by single crystal X-ray diffraction techniques. Crystal data: monoclinic, space group P21/c, a=0.712 21(8) nm, b=1.170 93(14) nm, c=1.783 7(2) nm, β=111.828(2)°, and V=1.380 8(3) nm3, Dc=1.769 Mg·m-3, Z=2, F(000)=744, R1=0.025 4, wR2=0.069 5, Gof=1.077, Δρ=328^-455 e·nm-3. The complex is packed by one centrosymmetry binuclear copper(Ⅱ) unit, oxalate dianion and NO3- anion. In the molecule structure of the title complex, two Cu(Ⅱ) ions are bridged by oxalate dianion and each Cu(Ⅱ) ions coordinates with two nitrogen atoms from 1,10-phenanthroline ligand and one oxygen atom from water to form a five-coordinate distorted square-pyramidal configuration. The hydrogen bonds are observed between coordinated water molecules and NO3- anions. The analysis of the crystal structure indicates that the complex has a two-dimensional stacking network structure, which is formed by intramolecular hydrogen bonds, intermolecular hydrogen bonds and stacking effect of aromatic ring. CCDC: 255345.
